CA2080372A1 - Landfill and process for developing same - Google Patents
Landfill and process for developing sameInfo
- Publication number
- CA2080372A1 CA2080372A1 CA 2080372 CA2080372A CA2080372A1 CA 2080372 A1 CA2080372 A1 CA 2080372A1 CA 2080372 CA2080372 CA 2080372 CA 2080372 A CA2080372 A CA 2080372A CA 2080372 A1 CA2080372 A1 CA 2080372A1
- Authority
- CA
- Canada
- Prior art keywords
- landfill
- per
- matter
- stabilized
- compost
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 238000000034 method Methods 0.000 title claims abstract description 52
- 230000008569 process Effects 0.000 title claims abstract description 44
- 239000002361 compost Substances 0.000 claims abstract description 55
- 238000003860 storage Methods 0.000 claims abstract description 11
- 239000000463 material Substances 0.000 claims description 26
- 239000000654 additive Substances 0.000 claims description 17
- 230000000996 additive effect Effects 0.000 claims description 13
- 238000005056 compaction Methods 0.000 claims description 13
- 238000009833 condensation Methods 0.000 claims description 13
- 230000005494 condensation Effects 0.000 claims description 13
- 239000000203 mixture Substances 0.000 claims description 11
- 230000003139 buffering effect Effects 0.000 claims description 10
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 10
- 239000011707 mineral Substances 0.000 claims description 10
- 230000000274 adsorptive effect Effects 0.000 claims description 6
- 229910052791 calcium Inorganic materials 0.000 claims description 6
- 239000011575 calcium Substances 0.000 claims description 6
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 5
- 239000004927 clay Substances 0.000 claims description 5
- 238000006243 chemical reaction Methods 0.000 claims description 4
- 229910000358 iron sulfate Inorganic materials 0.000 claims description 4
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 claims description 4
- 239000002023 wood Substances 0.000 claims description 4
- 238000001035 drying Methods 0.000 claims description 3
- -1 lignocellulose Substances 0.000 claims description 2
- 230000001747 exhibiting effect Effects 0.000 claims 5
- FOGYNLXERPKEGN-UHFFFAOYSA-N 3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfopropyl)phenoxy]propane-1-sulfonic acid Chemical compound COC1=CC=CC(CC(CS(O)(=O)=O)OC=2C(=CC(CCCS(O)(=O)=O)=CC=2)OC)=C1O FOGYNLXERPKEGN-UHFFFAOYSA-N 0.000 claims 1
- 230000001737 promoting effect Effects 0.000 claims 1
- 150000002500 ions Chemical class 0.000 description 9
- 230000000813 microbial effect Effects 0.000 description 9
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 8
- 238000009264 composting Methods 0.000 description 8
- 230000009466 transformation Effects 0.000 description 8
- 230000009467 reduction Effects 0.000 description 7
- 239000000126 substance Substances 0.000 description 7
- 229910001385 heavy metal Inorganic materials 0.000 description 6
- 239000002699 waste material Substances 0.000 description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 5
- 229910052799 carbon Inorganic materials 0.000 description 5
- 239000003153 chemical reaction reagent Substances 0.000 description 5
- 238000011038 discontinuous diafiltration by volume reduction Methods 0.000 description 5
- 239000002663 humin Substances 0.000 description 5
- 239000003864 humus Substances 0.000 description 5
- 230000004888 barrier function Effects 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- 230000000035 biogenic effect Effects 0.000 description 4
- 239000001569 carbon dioxide Substances 0.000 description 4
- 229910002092 carbon dioxide Inorganic materials 0.000 description 4
- 231100000331 toxic Toxicity 0.000 description 4
- 230000002588 toxic effect Effects 0.000 description 4
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 238000010276 construction Methods 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Chemical group N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 239000002689 soil Substances 0.000 description 3
- 238000001179 sorption measurement Methods 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 238000011065 in-situ storage Methods 0.000 description 2
- 244000005706 microflora Species 0.000 description 2
- 230000007935 neutral effect Effects 0.000 description 2
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 2
- 229910052757 nitrogen Chemical group 0.000 description 2
- 239000005416 organic matter Substances 0.000 description 2
- 239000010815 organic waste Substances 0.000 description 2
- 238000007789 sealing Methods 0.000 description 2
- 239000010865 sewage Substances 0.000 description 2
- 150000003568 thioethers Chemical class 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- VOXZDWNPVJITMN-ZBRFXRBCSA-N 17β-estradiol Chemical compound OC1=CC=C2[C@H]3CC[C@](C)([C@H](CC4)O)[C@@H]4[C@@H]3CCC2=C1 VOXZDWNPVJITMN-ZBRFXRBCSA-N 0.000 description 1
- QGZKDVFQNNGYKY-OUBTZVSYSA-N Ammonia-15N Chemical compound [15NH3] QGZKDVFQNNGYKY-OUBTZVSYSA-N 0.000 description 1
- 241001553178 Arachis glabrata Species 0.000 description 1
- BSYNRYMUTXBXSQ-UHFFFAOYSA-N Aspirin Chemical compound CC(=O)OC1=CC=CC=C1C(O)=O BSYNRYMUTXBXSQ-UHFFFAOYSA-N 0.000 description 1
- 208000035404 Autolysis Diseases 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- 239000002028 Biomass Substances 0.000 description 1
- 206010057248 Cell death Diseases 0.000 description 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 241000238631 Hexapoda Species 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 241000282320 Panthera leo Species 0.000 description 1
- 101100311221 Streptomyces toyocaensis staL gene Proteins 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 101150053801 adiC gene Proteins 0.000 description 1
- 238000003915 air pollution Methods 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- 230000003851 biochemical process Effects 0.000 description 1
- 239000000872 buffer Substances 0.000 description 1
- 239000007853 buffer solution Substances 0.000 description 1
- 229940057344 bufferin Drugs 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 1
- 239000000292 calcium oxide Substances 0.000 description 1
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000010791 domestic waste Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000000284 extract Substances 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- ZZUFCTLCJUWOSV-UHFFFAOYSA-N furosemide Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC(C(O)=O)=C1NCC1=CC=CO1 ZZUFCTLCJUWOSV-UHFFFAOYSA-N 0.000 description 1
- 239000010440 gypsum Substances 0.000 description 1
- 229910052602 gypsum Inorganic materials 0.000 description 1
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 239000010813 municipal solid waste Substances 0.000 description 1
- APVPOHHVBBYQAV-UHFFFAOYSA-N n-(4-aminophenyl)sulfonyloctadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(=O)NS(=O)(=O)C1=CC=C(N)C=C1 APVPOHHVBBYQAV-UHFFFAOYSA-N 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 235000020232 peanut Nutrition 0.000 description 1
- 239000003415 peat Substances 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 230000002786 root growth Effects 0.000 description 1
- 230000028043 self proteolysis Effects 0.000 description 1
- 101150115956 slc25a26 gene Proteins 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 239000003440 toxic substance Substances 0.000 description 1
- 239000003053 toxin Substances 0.000 description 1
- 231100000765 toxin Toxicity 0.000 description 1
- 108700012359 toxins Proteins 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
- B09B—DISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
- B09B1/00—Dumping solid waste
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/40—Bio-organic fraction processing; Production of fertilisers from the organic fraction of waste or refuse
Landscapes
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Fertilizers (AREA)
- Processing Of Solid Wastes (AREA)
- Superconductors And Manufacturing Methods Therefor (AREA)
Abstract
Abstract Summary Landfill and Process for Developing Same A landfill and a process for developing same distinguish themselves through compacted storage of previously microbially stabilized, decayed matter of varied origin, herein being called a stabilized compost -Illustration 3-
Description
20~372 L~ndfill ulld Process ~or l)eveloping Samc Technic~l Aspect:
The in~entior, deals in generlll wilh the stora~e of residual m~l~erial; sp~cifically, ~he invenliondeals with a landfill and a process for developing same.
Basis of the Technology:
5 It is customary to transfer biogenic residual matter in its original st~te to a landfill and to store it there. Condensation measures aid in the reduction of volume (residential waste) or the technical man&geAbility (sewage). The storage of fresh biogenic material leads to lhoroughly wetled decomposition, the creation of decomposition gases ~me~hane, hydrogen sulfide) and a broad spectrum of odiferous matter. Expensive landfill safety measures are necessary to be able to I0 contend with these drawbacks.
It is known, for example, from the document "Techniques Sciences Methods, 81 (l), 31-34 (1986)" - GARRIDO, LE~ROY, that fresh organic matter can be compacted for tl1e purpose of in-situ composting. This composting, also kno~vn AS direct composting, is designed to avoid the odor burden or the development of insect populations. With disinte~ration of the material, the 15 condensation or compaction process proceeds in such A manner so as to preserve aerobic condi~ions. Anaerobic conditions are reluctantly accepted. Over the years, a compost-like product is generated. The process cannot be considered as having a biological foundation. The illustrated : process is similar to that of conventional trash compaction, with îhe diff'erence that the mechanically reduced volume of the biogsnic maîerial is more or less accidentally linked with 20 the in-situ composting process.
Disclosule of the Invention:
With thc problems associated witl1 conventionally man~ged landfills in mind, it is the purpose ...
.. . . . ..
: '. ' ' ' -. , . , . - . , . . ~ ~ . ,.: ~ ., , ,: , . . : : - - . , :
of the invention to make an alternative manner tor Ihe slora~e of bioL~enic or~anic wasle malerial available.
This ~oal is achieved by a landfill thal distin~,uishes itself fiom olhers by utilizin~ compac~ed storage of previously microbially stabilized decayed matler of varied ori~in (Claim 1).
5 As it relates to the process, this L~oal is achieved via a melhod for developing a landflll, in which previously microbially stabilized decayed matter of varied orighl is slored in a compacted manner, resulting in a stabilized compost (Claim 13).
The microbial stabilization is a component of the process of decay arld is achieved prior to stora~e. Tlle addilion of various microor~anisms intlerent in the compost flora to the slarlin~
10 material is not usually necessary but may be beneficial in rare instances. The subsequent compaction may be accomplished before stora~e if possible; e.g. if contaminated material exhibits cohesive properties and is allowed to be compacted with tl-e stabili~ed compost material. As a rule however, the stabilized compost is rolled firm in a layer-wise manner.
;:
The basis for the science utilized in the invention is ~he deliberale meshin~ of physical, chemical 15 and biolo~ical mechanisms of Ihe terrestrial eco-system whilst keepinu environmenlal objectives in mind. Tlle landfill described in the invenlion will subsequenlly be hlown as aul eco-landfill or as an inerl-landfill~ It extracts organic matter and toxic subslances from the naturally occurring ~ycles and enders these materials inert amidst volume reduction. When composlin~ unburdened rnaterial, tlle eco-landfill can serve lo make Ihe resulting microbially stabili~e(J, decayed matler 2G a desirable product. It may also serve as a decontaminalion pool for the removal of toxic substances, provided these can be mixed in appropriate proportions with tlle stabilized composl.
The composting, alonL~ with the subsequent compaction, is associated with a volume reduction which is not achieved with inechallical compaction at conventionally managed landfills. With conventionaJly managed landfills, the high backpressure of spon~y, often bulky material, reduces ~S the efficiency of the volume reduction.
.
.
.
.- ' 20~03~2 The invention seeks to set ilself apart by offering stora~e of stabilized compost in a suitable landfill in a physically, chemically and biologically inelt manner. ~labilized compost is achieved in this case throu~h the biochemical transformation o~` the bio~enic, or~anic waste Matter. The biochemical process u!ilized is tlle well-defined compostinL~ process, which transforms the 5 biogenic, or~anic waste matter h~to a permallent or stable compost whicl- h~ turn, under anaerobic conditions, is deprived of Ihe process of microbial transt`orMation of matter. The compacted storage of the stabilized compost results in the environmentally neutral stora~e of biogenic organic waste matter. This differs sharply t`rom conventional landfills with respect to construction as well as management. The waste material ~reated with lhe afore mentioned process is endowed 10 with characteristics which are environmelltally sound. In Ihis manner, the current elaborate sat`ety measures directed towards soil, wa~er and air pollution created by reactive biolo~ical material are supertluous and can be replaced with substan~ially cheaper measures.
The invention has the followin~ benefits:
- the Deutral p~l of the compost promotes the immobilizulion of heavy metal ions eilher as 15 insoluble bonds to- or throu~ll adsorption ~o- the permanent humus, i.e. the stabilized compost.
The compact storage of the stabilized compost compleles tbe immobilization of the heavy metal lons.
- the compaction of the stabilizesJ compost fllso leads to ~he immobiliza~ion of nitro~en and phosphate. The same is true for harmful aromatics.
20 - due to its environmentally nelltral properties, ~he eco-landfill can be managed wi~hout underground sealing barriers and without a sealed under~round foundation.
- the immobilization of reduced carbon in the inert stabilized compost is viewed as an added benefit towards the reduction of the ~enerally well known carbon dioxide problem.
- finally, landfill space is conserved to volume reduction associated with ~he stabilized 25 ~ompost.
The invention will subsequently be elaborated more extensiYely with the help of examples. The included illustrations will be referred lo.
- - - . , .: . -. . : . - , .
. - , .. ~ - : . -.. .. ..
.
~8037~ .
A SllOlt descril)tioll Or tl~e illl~tralioll~:
The illustrations depict:
Illustration I the dyllamics hlvolved hl material Iranst`ormalioll durinL~ composthlg;
Illustration 2 the transformation of ma~ter within lhe eco-landfill, and 5 Illustration 3 the developmenl of an eco-landfill for sewage waste compost Methods for applying the invel~lion:
Decayed matter is obtained from compostin~, particularly Ille decay of organic màtter under natural conditions. Along ttle way a microbial matter transforlllation takes place per a well defined scheme depicted in Illustration 1. The transformation of matter may be intensified with 10 technical measures and lhrou~h control of ~he manner in whicll the process is carried out.
Initially, the easily utilizesl carbon and nitrogen bonds are mineralized. Since this is a rapid process, an increase in temperature up to 80 ~C occurs. This phase of the compostin~ process serves to sanitize au~d reduce the odi~erous matter.
After the reduction of s~id matter, pref~sably by mixe~l bacterial flora, cross-over populations are 15 created. Thes~ consist of bacteria and t;Ulgi, as depicted in Illustration 1. The composting process subsequently enters into a state of virtually total decay. Durin~ this phase, mostly aerobic funL~al flora are involved in the slow reduction of lignocellulose.
It is characteristic of the composting process to initially convert malter both under aerobic and anaerobic conditions. This is precisely the reason why the decay of fresh matter leads to the 20 formation of foul gases. The composting process leads into a matter transformation whicll necessitates strict aerobic conditions, as depicted in Illustration 1. At this staL~e the microbial transformation of the matter ceases whell Ihe oxygen supply is removed. Ttlis may be easily demonstrated. Stabilized compost pncked into an airtight plaslic bag takes on the appearance of .
-. . ~ . . - . . .
.: ':,, . .:: . , ': . .' :
- :. . : . ~ ~ : :
.. : . . . ~ - :
. . . ' ' : ~
.
The in~entior, deals in generlll wilh the stora~e of residual m~l~erial; sp~cifically, ~he invenliondeals with a landfill and a process for developing same.
Basis of the Technology:
5 It is customary to transfer biogenic residual matter in its original st~te to a landfill and to store it there. Condensation measures aid in the reduction of volume (residential waste) or the technical man&geAbility (sewage). The storage of fresh biogenic material leads to lhoroughly wetled decomposition, the creation of decomposition gases ~me~hane, hydrogen sulfide) and a broad spectrum of odiferous matter. Expensive landfill safety measures are necessary to be able to I0 contend with these drawbacks.
It is known, for example, from the document "Techniques Sciences Methods, 81 (l), 31-34 (1986)" - GARRIDO, LE~ROY, that fresh organic matter can be compacted for tl1e purpose of in-situ composting. This composting, also kno~vn AS direct composting, is designed to avoid the odor burden or the development of insect populations. With disinte~ration of the material, the 15 condensation or compaction process proceeds in such A manner so as to preserve aerobic condi~ions. Anaerobic conditions are reluctantly accepted. Over the years, a compost-like product is generated. The process cannot be considered as having a biological foundation. The illustrated : process is similar to that of conventional trash compaction, with îhe diff'erence that the mechanically reduced volume of the biogsnic maîerial is more or less accidentally linked with 20 the in-situ composting process.
Disclosule of the Invention:
With thc problems associated witl1 conventionally man~ged landfills in mind, it is the purpose ...
.. . . . ..
: '. ' ' ' -. , . , . - . , . . ~ ~ . ,.: ~ ., , ,: , . . : : - - . , :
of the invention to make an alternative manner tor Ihe slora~e of bioL~enic or~anic wasle malerial available.
This ~oal is achieved by a landfill thal distin~,uishes itself fiom olhers by utilizin~ compac~ed storage of previously microbially stabilized decayed matler of varied ori~in (Claim 1).
5 As it relates to the process, this L~oal is achieved via a melhod for developing a landflll, in which previously microbially stabilized decayed matter of varied orighl is slored in a compacted manner, resulting in a stabilized compost (Claim 13).
The microbial stabilization is a component of the process of decay arld is achieved prior to stora~e. Tlle addilion of various microor~anisms intlerent in the compost flora to the slarlin~
10 material is not usually necessary but may be beneficial in rare instances. The subsequent compaction may be accomplished before stora~e if possible; e.g. if contaminated material exhibits cohesive properties and is allowed to be compacted with tl-e stabili~ed compost material. As a rule however, the stabilized compost is rolled firm in a layer-wise manner.
;:
The basis for the science utilized in the invention is ~he deliberale meshin~ of physical, chemical 15 and biolo~ical mechanisms of Ihe terrestrial eco-system whilst keepinu environmenlal objectives in mind. Tlle landfill described in the invenlion will subsequenlly be hlown as aul eco-landfill or as an inerl-landfill~ It extracts organic matter and toxic subslances from the naturally occurring ~ycles and enders these materials inert amidst volume reduction. When composlin~ unburdened rnaterial, tlle eco-landfill can serve lo make Ihe resulting microbially stabili~e(J, decayed matler 2G a desirable product. It may also serve as a decontaminalion pool for the removal of toxic substances, provided these can be mixed in appropriate proportions with tlle stabilized composl.
The composting, alonL~ with the subsequent compaction, is associated with a volume reduction which is not achieved with inechallical compaction at conventionally managed landfills. With conventionaJly managed landfills, the high backpressure of spon~y, often bulky material, reduces ~S the efficiency of the volume reduction.
.
.
.
.- ' 20~03~2 The invention seeks to set ilself apart by offering stora~e of stabilized compost in a suitable landfill in a physically, chemically and biologically inelt manner. ~labilized compost is achieved in this case throu~h the biochemical transformation o~` the bio~enic, or~anic waste Matter. The biochemical process u!ilized is tlle well-defined compostinL~ process, which transforms the 5 biogenic, or~anic waste matter h~to a permallent or stable compost whicl- h~ turn, under anaerobic conditions, is deprived of Ihe process of microbial transt`orMation of matter. The compacted storage of the stabilized compost results in the environmentally neutral stora~e of biogenic organic waste matter. This differs sharply t`rom conventional landfills with respect to construction as well as management. The waste material ~reated with lhe afore mentioned process is endowed 10 with characteristics which are environmelltally sound. In Ihis manner, the current elaborate sat`ety measures directed towards soil, wa~er and air pollution created by reactive biolo~ical material are supertluous and can be replaced with substan~ially cheaper measures.
The invention has the followin~ benefits:
- the Deutral p~l of the compost promotes the immobilizulion of heavy metal ions eilher as 15 insoluble bonds to- or throu~ll adsorption ~o- the permanent humus, i.e. the stabilized compost.
The compact storage of the stabilized compost compleles tbe immobilization of the heavy metal lons.
- the compaction of the stabilizesJ compost fllso leads to ~he immobiliza~ion of nitro~en and phosphate. The same is true for harmful aromatics.
20 - due to its environmentally nelltral properties, ~he eco-landfill can be managed wi~hout underground sealing barriers and without a sealed under~round foundation.
- the immobilization of reduced carbon in the inert stabilized compost is viewed as an added benefit towards the reduction of the ~enerally well known carbon dioxide problem.
- finally, landfill space is conserved to volume reduction associated with ~he stabilized 25 ~ompost.
The invention will subsequently be elaborated more extensiYely with the help of examples. The included illustrations will be referred lo.
- - - . , .: . -. . : . - , .
. - , .. ~ - : . -.. .. ..
.
~8037~ .
A SllOlt descril)tioll Or tl~e illl~tralioll~:
The illustrations depict:
Illustration I the dyllamics hlvolved hl material Iranst`ormalioll durinL~ composthlg;
Illustration 2 the transformation of ma~ter within lhe eco-landfill, and 5 Illustration 3 the developmenl of an eco-landfill for sewage waste compost Methods for applying the invel~lion:
Decayed matter is obtained from compostin~, particularly Ille decay of organic màtter under natural conditions. Along ttle way a microbial matter transforlllation takes place per a well defined scheme depicted in Illustration 1. The transformation of matter may be intensified with 10 technical measures and lhrou~h control of ~he manner in whicll the process is carried out.
Initially, the easily utilizesl carbon and nitrogen bonds are mineralized. Since this is a rapid process, an increase in temperature up to 80 ~C occurs. This phase of the compostin~ process serves to sanitize au~d reduce the odi~erous matter.
After the reduction of s~id matter, pref~sably by mixe~l bacterial flora, cross-over populations are 15 created. Thes~ consist of bacteria and t;Ulgi, as depicted in Illustration 1. The composting process subsequently enters into a state of virtually total decay. Durin~ this phase, mostly aerobic funL~al flora are involved in the slow reduction of lignocellulose.
It is characteristic of the composting process to initially convert malter both under aerobic and anaerobic conditions. This is precisely the reason why the decay of fresh matter leads to the 20 formation of foul gases. The composting process leads into a matter transformation whicll necessitates strict aerobic conditions, as depicted in Illustration 1. At this staL~e the microbial transformation of the matter ceases whell Ihe oxygen supply is removed. Ttlis may be easily demonstrated. Stabilized compost pncked into an airtight plaslic bag takes on the appearance of .
-. . ~ . . - . . .
.: ':,, . .:: . , ': . .' :
- :. . : . ~ ~ : :
.. : . . . ~ - :
. . . ' ' : ~
.
2~80~7~
a vacuum-packed ba~ of peanuts a~ter a wl)ile. Due lo tl-e consumptiol- of oxygen by Ihe microflora, a vacuum is created within the plastic bag. Ilad the conditions ~or a s~abilize~i compost not been reached, i.e. under present conditions ~ulaerobic microflora could still flourish,-the established development of ~ases (carbon dioxide, melllalle, oùorous malerial) would have 5 occurred. The bag would have inflated.
Durin~ compostin~ carried out under volume reducing conditions (approx. 50% loss due to decay), a permanent humus is ~enerateà, which is based on the following path of matler transformation. The oxidative reduction of Ihree-dimensionally linked macromolecules evolves from fragmented debris which l-as eitl-er been completely mineralized or has been re-polymerized 10 to humin matter with the aid of microbially formed auto-oxidative phenols. This biologically induced and chemica!ly catalyzed process is in this way enveloped witl-in Ihe dynamics of matter transformalion so that a compost is produced who's orL~anic ma~ler displays an increasing resistance so microbial reduction under aerobic conditions. This slaL~e is the premise for the invention-based inertness of the stabilized compost. The compacled storaue of the eco-landfill 15 leads to the inert condition of the ma~ter. 'I lle compacted storage permits anaerobic conditions.
The stora~e of the stabilized compost in a con-pacted state eliminates tlle conveclive exchanL~e of ~ases Once Ihe matter conversion activity of the aerobic fi~n~al flora subsides, tlle system rapidly converts to anaerobic conditions. Tl~e oriL~inal oxygen dependent, livinL~ biomass moves into sutolysis, wherein nitro~en- and sulfur- containin~ bonds are liberated. The producls of 20 autolysis serve as nulrients for the resullin~ anaerobic flora, which are hardly relevant due to Iheir lacl~ of useful, or~ulically bound carbon. As a result, ammonia is liberaled, wl-ich at pl~ 7.0 is predominately adsorbed as ammonia-N to ~he permanent humus- see Illustralion 2 (1-3). Under these conditions, hydro~en sulf;de is produced whicil in lurn forms insoluble sulfides with Ihe heavy metal ions- see Illustration 2 (4). Subsequently, the stabilized compost moves into a s~ate 25 of absolute microbial quiescènce, since the compaction prevents lhe relurn of aerobic conditions.
The compacted, slabilized COII-pOSt may be compared to a peat bed. Aside from its ability to naturally render or~anic substances inert, there are also examples of anthropological preservation, . . ... . - . . . - . . - : -. .. : ~ . -- :- .. - . .
-. - -- .
,: . .. . : , : . : . . -.. : -.
7 ~
i.e. humin matter as relics from ancient seltlemellts. E~ven intact liL~nocellulose can be spared from microbial malter transf`ormatioll as ill~lstrat~d by dallls located hl clay d~posits (lack of air), wooLI
kept underwater (piling constmction) and cily foundatiolls, e.~. Bru~ge ~Bel~ium), Venice (l~aly).
Storéd timbers may be préserved by weltinU.
5 The neutral pH values of the stabilized compost l`avor the immobilization of heavy metal ions through insoluble bonds or via adsorption to the permanent llUmUS- see Illustralion 2 (4). For tllis reason it is difficult to leacll the heavy metal ions out of the decayed malter used t`or enrichmel)t of the soil. With the compacted storage of the stabilized, decayed matter, i.e. the stabilizeJ
compost, this immobilization is completed, since neilher microbially in~luced mobili7ations nor 10 water storage are present. The relatively hiL~h water retaining càpacity of the composl sur~:dce prevents aqueous infiltration Or Ille deeper layers durin)s lleavy rainfall. The capillary action of the compost surface promotes evaporation.
The compaction of the stabilized compost also leads lo immobilization of nitrogen and phosphate-see Illustration 2 (3). The same is true for harmful aromatics-see Illustralion 2 (5)- whicll are 15 either bound via adsorption or have already been absorbed into tlle process of microbiul transformation of maner durhlg compostin~.
, The aromatic-reducing enzyme systen~s are non-specific enougl to also irreversibly bind syn~hetic aromatics to the permanent humus.
The eco-lau~dfill, see Illustration 3, can essenlially exist withoul an underl round barrier seal.
20 However, to exclude any possible risk to the ouler perimeler, a buffer zone loay be installed, providinu ad~litional protection from the leaching of toxic matler. In contrast lo the riuid system employed in conventional under~round barriers, the above mentioned buffer system is able to adapt and react to shifting. Due to its physical and chemical properties it can act in a self-sealing manner.
:. . , . .. :
: ~ :
.
- : .. i. . . . : -.
. . : . ;
.. - . .. ~ . . ~,............................ .
,. . : .
. . ~ - .-2~037~3 In regards lo ~he carbon dioxide problem, the eco-landfill possesses an environmelI~ally relevanl aspect. It is well known that no pl~ysi~al or chemichi metlIods exisl whh:l~ remove carbon dioxide from the actual gaseous content generaled in the matler transf`orma~ion cycle. The immobiliza~ion - of reduced carbon in the inert permanent humus has a siglliflcallt impact on the reduction of 5 excess carbon dioxide-see Illustration 2 (7).
The inert landfill operates on the premise of storage of COll)pOStS in a permanellt humws condition.
The process of making the landf~lll inert possesses not only a high degree of ecological value but is in itself particularly economical. 'I`he flchieved volume reduction conserves landfill space, reduces the cost of landfill construction and facilita~es site selection.
10 Prerequisite for the development of the eco-landfill (as described in the invention) is the formation of stabilized compost, i.e. permanent humus which has preferably been removed from the anaerobic conditions of malter transformation. This condition is determined with appropriate analytical methods.
With the aid of machinery, the stabilized compost is preferably compacted in layers tl-rou~hout 15 the landfill so as to achieve a high degree of condensatiolI (Claim 14). As per an a~ditional working example of the invention, the stabilized compost is pre-condensed and/or rolled firm at the site (Claim 15). Taking the technical aspects of the compos~ing process into account, a pre-condensation of the stabilized compost is particularly desirable when additive matter (Claim 6) is effectively mixed in under various conditions prior to fmal s~orage.
20 The compacted, stabilized compost is preferably stored in al least two compartment of the landfill. It is benef'lcial to separate these IWO compartments with an intermediate layer containing or constructed of materillls which possess soli(lifying, adsorptive an(l/or buffering properlies. The above mentioned measures serve as additiollal envir~nmental safegllards and offer advanta~es towards the storage of contaminated compost (Clain~s 2 and 16).
25 The sam¢ holds true for the landfill foundation, where Illese measures afford prolection against - - . . :
2~8~37~ ~
leachin~, from the waterlo~ged land~ïll (Claims 3 an~l 17) An additional advantage is the fact that Ihe surface of Ihe eco-landfill is composed of a malerial which also possesses solidifyhlg, adsorplive and/or bufferillg properlies Willloul such a surface cover, the eco-landtlll presents as an open-air syslem hl a state ot` lransilioll lowards ve~elalion S This means that root growth, rodenl activi~y or atmospl)eric h~ Jellces n-ay elicit changes in the peripheral zones of the landfill The above mentioned surface cover prevents these ullcontrolled influences or at least works a~ainst them (Claims 4 and 18) As per an additional workhlg exarmple of tl-e invention, the stabilized compost is Ireated wilh compaction-promotin~ substances, especially condensing and cross-linkinL~ materials l`hese 10 materials improve the condel-satiol- properties of Ihe stabilized compost, especially where condensation and con-paction are mechallically acl-ieved ~CIaims 5 and 19) The structure-lendh condensinu substances contaill malerials whicll pos~ess soli~lifyillg, adsorplive andlor bufferin~
properties l`he measures also serve to provide additional environmental protection (Claims 6 and 20)~
15 As per an a~iditional preferred workin~ exiample of the invenlion, organic and/or inGr~aniC
additive malter is contained in the inlermediate layer, the landfill foundation, Ihe landfill surface and/or 1he structure-lending condensing material Particularly suitable additive malter is shredded wood, lignocellulose, mineral Inixtures, clay or a mixture Ihereof (Claims ~ and 21) Processed construction debris is an appropriate mineral mixture, especially for the intermediate 20 layers separating landfill compartments In prhlciple, the hlclusion of foils between compartments would be possible~
As per another preferred working example of ~he invention, Ihe calcium-containmg mineral aclditives are comprised of either lime (calcium carbonale) parliculate andlor gypsum (caicium sulfate) particulate~ The lime-containin~ mineral compositions are preferably mixed wi~h 25 additional additives such as iron sulfate Such additive materials promote not only the . . - . . . .
. -.
.
2~377 immobilization of displace(i or~anic and inorL~anic compost compollenls, bul also promote (wilhi Ihe framework of tlle inYen~ioll), soli ;lificalion (~ue lo re~ional hardenin~. Re~ional hardeni customarily occurs when humin matter creates alumhlulIl-, iron- and calcium- hunlus' by formh - colloids wilh soil components in ~he landfill foundalion ~CIaims 9, I0, 23 and 24).
S Waste materials which contain predomhlalllly li~nocellulose are suitable for structure-lending condensation matter. 1nclIlded are Ihe previously menlioned addilive materials, wood chips and organic waste matter. Asbestos-like products are useful as inorlganic additives. The stabilized compost rnay also be compacled or condensed by mud-linL~-up (clog~inL~ wilh mud or silt). In this manner, Ihe surface of Ille compost layers may periodically be mudded over and end up hi~hly lG condensed (Claim 27). The addilion of liL~nosulfonic acid or lJecaying mud improves compactioll (Claim 28). The mixin~ of addilive matter wilh lhe s~able compost has been proven as beneficial.
In this manner, the additive matler is enriched by ~he humin matter (Claims 8 and 22).
As per an additional working example of the inventio(l, materials or additive matter treated wilh the DCR (Dispersed-Chemical-Reaction)- process make up, either wholly or in part, the 15 intermediate layers betweetl compar~ments, the landfill fowldatioll, ~he landfill surface cover and/or the structure-lending condensatioll malerial (Claims l l and 25). The DCR-process was developed by Bolsing and is described in EP 326 561-A. We specifically make reference to Ihe contents of this publication. Ilarmful orL~anic and inorganic matter (e.L~. mineral oils, aromalics, heavy metals) are immobilized throu~ll tlle application of hydropllobic calcium oxide combined 20 with an appropriate carrier, e.~. clay and waste reagents. The alterna~ion belween hydrophobic and hydrophilic conditions includes the chemical reaclion with loxic matter.
Tlle additional safety measures presenled in claims 2 Ihrou~ll lO and 16 throu~h 24 may be carried out more efficienlly when combined with Ihe DCR-process. The added benefit lies in lhe fact that the size and guAlity oP Ihe safety layers does not rely solely on their inherent properlies, 25 e.g. the formation of insoluble calcium bonds wilh humin acids. The safety layers can be variably instituted based on the potential toxic burden on each compartment. Towards this end, stoichiometric calculations are used to determine the concentration of the rea~ents to be applied .
2 ~ 8 ~
~o (e.g. iron sulfate; sulfide). l`he combination of a chemical foulldation with appropriately reacting and chemically synthesized molecular dispersion malrices presents a dynamically functioning, synergistic system. The çalcium oxide contained in lhe addilives lo Ihe landfill foundation, the landfill surface cover or the intermediflle layers is converted to calcium carbonate after treatment 5 with the DCR-process. This leads to increased hardening of the respective layers. Together with a high pH valtle, these layers take on an addi~ional f;mc~ion as a barrier.
The principle of molecularly dispersed distribulion of reagents in the foundation, the intermediate layers or the surface cover of the landfill also applies to lhe stabilized compost. Moreover, auto-stabilizing systems can be established to select reagents and to compensate for the changes in the 10 system. In this manner, a buffering system can prevent a drop hl p~l value which would lead to altered solubility of precipitated or immobilized toxins or perhaps favor îhe initiation of microbial activity in response to a slowly changing landfill.
With these considerations in mind and as per a preferre(l working example of the invention, the stabilized compost is treated wi~h a broad spectrum of arresting reagents or specifically targeted 15 reagents, even after DCR-processing, to create insoluble sulfide compounds or metallorganic complexes. In this manner, one can render toxic burdens inert, neutralize introduced matter and peripherally rnonitor the cessation of microbial activily (Claims l2 and 26).
A per an additional working example, Ihe stabilized compost is exposed to a drying s~age prior tô compaction, perhaps via a naturally occurrin~ drying of the stacks or possibly under cover or 20 by forced ventilation. This facilitates the compaction process at the landfilll site(Claim 29).
~. ... ~ . .
' ' ' , ' ' -'' '
a vacuum-packed ba~ of peanuts a~ter a wl)ile. Due lo tl-e consumptiol- of oxygen by Ihe microflora, a vacuum is created within the plastic bag. Ilad the conditions ~or a s~abilize~i compost not been reached, i.e. under present conditions ~ulaerobic microflora could still flourish,-the established development of ~ases (carbon dioxide, melllalle, oùorous malerial) would have 5 occurred. The bag would have inflated.
Durin~ compostin~ carried out under volume reducing conditions (approx. 50% loss due to decay), a permanent humus is ~enerateà, which is based on the following path of matler transformation. The oxidative reduction of Ihree-dimensionally linked macromolecules evolves from fragmented debris which l-as eitl-er been completely mineralized or has been re-polymerized 10 to humin matter with the aid of microbially formed auto-oxidative phenols. This biologically induced and chemica!ly catalyzed process is in this way enveloped witl-in Ihe dynamics of matter transformalion so that a compost is produced who's orL~anic ma~ler displays an increasing resistance so microbial reduction under aerobic conditions. This slaL~e is the premise for the invention-based inertness of the stabilized compost. The compacled storaue of the eco-landfill 15 leads to the inert condition of the ma~ter. 'I lle compacted storage permits anaerobic conditions.
The stora~e of the stabilized compost in a con-pacted state eliminates tlle conveclive exchanL~e of ~ases Once Ihe matter conversion activity of the aerobic fi~n~al flora subsides, tlle system rapidly converts to anaerobic conditions. Tl~e oriL~inal oxygen dependent, livinL~ biomass moves into sutolysis, wherein nitro~en- and sulfur- containin~ bonds are liberated. The producls of 20 autolysis serve as nulrients for the resullin~ anaerobic flora, which are hardly relevant due to Iheir lacl~ of useful, or~ulically bound carbon. As a result, ammonia is liberaled, wl-ich at pl~ 7.0 is predominately adsorbed as ammonia-N to ~he permanent humus- see Illustralion 2 (1-3). Under these conditions, hydro~en sulf;de is produced whicil in lurn forms insoluble sulfides with Ihe heavy metal ions- see Illustration 2 (4). Subsequently, the stabilized compost moves into a s~ate 25 of absolute microbial quiescènce, since the compaction prevents lhe relurn of aerobic conditions.
The compacted, slabilized COII-pOSt may be compared to a peat bed. Aside from its ability to naturally render or~anic substances inert, there are also examples of anthropological preservation, . . ... . - . . . - . . - : -. .. : ~ . -- :- .. - . .
-. - -- .
,: . .. . : , : . : . . -.. : -.
7 ~
i.e. humin matter as relics from ancient seltlemellts. E~ven intact liL~nocellulose can be spared from microbial malter transf`ormatioll as ill~lstrat~d by dallls located hl clay d~posits (lack of air), wooLI
kept underwater (piling constmction) and cily foundatiolls, e.~. Bru~ge ~Bel~ium), Venice (l~aly).
Storéd timbers may be préserved by weltinU.
5 The neutral pH values of the stabilized compost l`avor the immobilization of heavy metal ions through insoluble bonds or via adsorption to the permanent llUmUS- see Illustralion 2 (4). For tllis reason it is difficult to leacll the heavy metal ions out of the decayed malter used t`or enrichmel)t of the soil. With the compacted storage of the stabilized, decayed matter, i.e. the stabilizeJ
compost, this immobilization is completed, since neilher microbially in~luced mobili7ations nor 10 water storage are present. The relatively hiL~h water retaining càpacity of the composl sur~:dce prevents aqueous infiltration Or Ille deeper layers durin)s lleavy rainfall. The capillary action of the compost surface promotes evaporation.
The compaction of the stabilized compost also leads lo immobilization of nitrogen and phosphate-see Illustration 2 (3). The same is true for harmful aromatics-see Illustralion 2 (5)- whicll are 15 either bound via adsorption or have already been absorbed into tlle process of microbiul transformation of maner durhlg compostin~.
, The aromatic-reducing enzyme systen~s are non-specific enougl to also irreversibly bind syn~hetic aromatics to the permanent humus.
The eco-lau~dfill, see Illustration 3, can essenlially exist withoul an underl round barrier seal.
20 However, to exclude any possible risk to the ouler perimeler, a buffer zone loay be installed, providinu ad~litional protection from the leaching of toxic matler. In contrast lo the riuid system employed in conventional under~round barriers, the above mentioned buffer system is able to adapt and react to shifting. Due to its physical and chemical properties it can act in a self-sealing manner.
:. . , . .. :
: ~ :
.
- : .. i. . . . : -.
. . : . ;
.. - . .. ~ . . ~,............................ .
,. . : .
. . ~ - .-2~037~3 In regards lo ~he carbon dioxide problem, the eco-landfill possesses an environmelI~ally relevanl aspect. It is well known that no pl~ysi~al or chemichi metlIods exisl whh:l~ remove carbon dioxide from the actual gaseous content generaled in the matler transf`orma~ion cycle. The immobiliza~ion - of reduced carbon in the inert permanent humus has a siglliflcallt impact on the reduction of 5 excess carbon dioxide-see Illustration 2 (7).
The inert landfill operates on the premise of storage of COll)pOStS in a permanellt humws condition.
The process of making the landf~lll inert possesses not only a high degree of ecological value but is in itself particularly economical. 'I`he flchieved volume reduction conserves landfill space, reduces the cost of landfill construction and facilita~es site selection.
10 Prerequisite for the development of the eco-landfill (as described in the invention) is the formation of stabilized compost, i.e. permanent humus which has preferably been removed from the anaerobic conditions of malter transformation. This condition is determined with appropriate analytical methods.
With the aid of machinery, the stabilized compost is preferably compacted in layers tl-rou~hout 15 the landfill so as to achieve a high degree of condensatiolI (Claim 14). As per an a~ditional working example of the invention, the stabilized compost is pre-condensed and/or rolled firm at the site (Claim 15). Taking the technical aspects of the compos~ing process into account, a pre-condensation of the stabilized compost is particularly desirable when additive matter (Claim 6) is effectively mixed in under various conditions prior to fmal s~orage.
20 The compacted, stabilized compost is preferably stored in al least two compartment of the landfill. It is benef'lcial to separate these IWO compartments with an intermediate layer containing or constructed of materillls which possess soli(lifying, adsorptive an(l/or buffering properlies. The above mentioned measures serve as additiollal envir~nmental safegllards and offer advanta~es towards the storage of contaminated compost (Clain~s 2 and 16).
25 The sam¢ holds true for the landfill foundation, where Illese measures afford prolection against - - . . :
2~8~37~ ~
leachin~, from the waterlo~ged land~ïll (Claims 3 an~l 17) An additional advantage is the fact that Ihe surface of Ihe eco-landfill is composed of a malerial which also possesses solidifyhlg, adsorplive and/or bufferillg properlies Willloul such a surface cover, the eco-landtlll presents as an open-air syslem hl a state ot` lransilioll lowards ve~elalion S This means that root growth, rodenl activi~y or atmospl)eric h~ Jellces n-ay elicit changes in the peripheral zones of the landfill The above mentioned surface cover prevents these ullcontrolled influences or at least works a~ainst them (Claims 4 and 18) As per an additional workhlg exarmple of tl-e invention, the stabilized compost is Ireated wilh compaction-promotin~ substances, especially condensing and cross-linkinL~ materials l`hese 10 materials improve the condel-satiol- properties of Ihe stabilized compost, especially where condensation and con-paction are mechallically acl-ieved ~CIaims 5 and 19) The structure-lendh condensinu substances contaill malerials whicll pos~ess soli~lifyillg, adsorplive andlor bufferin~
properties l`he measures also serve to provide additional environmental protection (Claims 6 and 20)~
15 As per an a~iditional preferred workin~ exiample of the invenlion, organic and/or inGr~aniC
additive malter is contained in the inlermediate layer, the landfill foundation, Ihe landfill surface and/or 1he structure-lending condensing material Particularly suitable additive malter is shredded wood, lignocellulose, mineral Inixtures, clay or a mixture Ihereof (Claims ~ and 21) Processed construction debris is an appropriate mineral mixture, especially for the intermediate 20 layers separating landfill compartments In prhlciple, the hlclusion of foils between compartments would be possible~
As per another preferred working example of ~he invention, Ihe calcium-containmg mineral aclditives are comprised of either lime (calcium carbonale) parliculate andlor gypsum (caicium sulfate) particulate~ The lime-containin~ mineral compositions are preferably mixed wi~h 25 additional additives such as iron sulfate Such additive materials promote not only the . . - . . . .
. -.
.
2~377 immobilization of displace(i or~anic and inorL~anic compost compollenls, bul also promote (wilhi Ihe framework of tlle inYen~ioll), soli ;lificalion (~ue lo re~ional hardenin~. Re~ional hardeni customarily occurs when humin matter creates alumhlulIl-, iron- and calcium- hunlus' by formh - colloids wilh soil components in ~he landfill foundalion ~CIaims 9, I0, 23 and 24).
S Waste materials which contain predomhlalllly li~nocellulose are suitable for structure-lending condensation matter. 1nclIlded are Ihe previously menlioned addilive materials, wood chips and organic waste matter. Asbestos-like products are useful as inorlganic additives. The stabilized compost rnay also be compacled or condensed by mud-linL~-up (clog~inL~ wilh mud or silt). In this manner, Ihe surface of Ille compost layers may periodically be mudded over and end up hi~hly lG condensed (Claim 27). The addilion of liL~nosulfonic acid or lJecaying mud improves compactioll (Claim 28). The mixin~ of addilive matter wilh lhe s~able compost has been proven as beneficial.
In this manner, the additive matler is enriched by ~he humin matter (Claims 8 and 22).
As per an additional working example of the inventio(l, materials or additive matter treated wilh the DCR (Dispersed-Chemical-Reaction)- process make up, either wholly or in part, the 15 intermediate layers betweetl compar~ments, the landfill fowldatioll, ~he landfill surface cover and/or the structure-lending condensatioll malerial (Claims l l and 25). The DCR-process was developed by Bolsing and is described in EP 326 561-A. We specifically make reference to Ihe contents of this publication. Ilarmful orL~anic and inorganic matter (e.L~. mineral oils, aromalics, heavy metals) are immobilized throu~ll tlle application of hydropllobic calcium oxide combined 20 with an appropriate carrier, e.~. clay and waste reagents. The alterna~ion belween hydrophobic and hydrophilic conditions includes the chemical reaclion with loxic matter.
Tlle additional safety measures presenled in claims 2 Ihrou~ll lO and 16 throu~h 24 may be carried out more efficienlly when combined with Ihe DCR-process. The added benefit lies in lhe fact that the size and guAlity oP Ihe safety layers does not rely solely on their inherent properlies, 25 e.g. the formation of insoluble calcium bonds wilh humin acids. The safety layers can be variably instituted based on the potential toxic burden on each compartment. Towards this end, stoichiometric calculations are used to determine the concentration of the rea~ents to be applied .
2 ~ 8 ~
~o (e.g. iron sulfate; sulfide). l`he combination of a chemical foulldation with appropriately reacting and chemically synthesized molecular dispersion malrices presents a dynamically functioning, synergistic system. The çalcium oxide contained in lhe addilives lo Ihe landfill foundation, the landfill surface cover or the intermediflle layers is converted to calcium carbonate after treatment 5 with the DCR-process. This leads to increased hardening of the respective layers. Together with a high pH valtle, these layers take on an addi~ional f;mc~ion as a barrier.
The principle of molecularly dispersed distribulion of reagents in the foundation, the intermediate layers or the surface cover of the landfill also applies to lhe stabilized compost. Moreover, auto-stabilizing systems can be established to select reagents and to compensate for the changes in the 10 system. In this manner, a buffering system can prevent a drop hl p~l value which would lead to altered solubility of precipitated or immobilized toxins or perhaps favor îhe initiation of microbial activity in response to a slowly changing landfill.
With these considerations in mind and as per a preferre(l working example of the invention, the stabilized compost is treated wi~h a broad spectrum of arresting reagents or specifically targeted 15 reagents, even after DCR-processing, to create insoluble sulfide compounds or metallorganic complexes. In this manner, one can render toxic burdens inert, neutralize introduced matter and peripherally rnonitor the cessation of microbial activily (Claims l2 and 26).
A per an additional working example, Ihe stabilized compost is exposed to a drying s~age prior tô compaction, perhaps via a naturally occurrin~ drying of the stacks or possibly under cover or 20 by forced ventilation. This facilitates the compaction process at the landfilll site(Claim 29).
~. ... ~ . .
' ' ' , ' ' -'' '
Claims (29)
PROPERTY OR PRIVILEGE IS CLAIMED ARE DEFINED AS FOLLOWS:
1. Landfill, characterized by a compacted storage of previously microbially stabilized decayed matter of varied origin, resulting in a stabilized compost.
2. Landfill as in Claim 1, characterized by at least two compartments with compacted stabilized compost and a solidifying, adsorptive and\or buffering intermediate layer between compartments.
3. Landfill as per Claim 1 or 2, characterized by a landfill foundation consisting of materials exhibiting solidifying, absorptive and\or buffering properties.
4. Landfill as per at least one of the previous claims, characterized by a surface area covered by material exhibiting solidifying, adsorptive and\or buffering properties.
5. Landfill as per at least one of the above claims, characterized by a stabilized compost that is treated with compaction promoting and structure-lending condensation materials.
6. Landfill as per claim 5, characterized by structure-lending condensation materials that exhibit solidifying, absorptive and\or buffering properties.
7. Landfill as per at least one of the claims in 2 through 6, characterized by the intermediate layer, the landfill foundation, the landfill surface cover and\or the structure-lending condensation matter which contain or are consists of or contain organic and inorganic additive materials, in particular shredded wood lignocellulose, mineral mixtures, clay or a mixture thereof.
8. Landfill as per claim 7, characterized by stabilized compost mixed with additive materials.
9. Landfill as per claims 7 or 8, characterized by additive matter consisting of calcium-containing mineral mixtures.
10. Landfill as per claim 9, characterized by calcium-containing mineral mixtures with additional additives like iron sulfate.
11. Landfill as per at least one of the claims in 2 through 10, characterized by the intermediate layer, the landfill foundation, the landfill surface cover and\or the structure-lending condensation matter which contain material or additive matter which is in part or wholly comprised of DCR (Dispersed-Chemical-Reaction) treated matter.
12. Landfill as per at least one of the above claims, characterized by the stabilized compost treated with the DCR-process.
13. Process for the development of a landfill, characterized by compacted, previously microbially stabilized decayed matter of varied origin and stored as a stabilized compost.
14. Process as per claim 13, characterized by the stabilized compost that is stored in compacted layers.
15. Process as per claim 13 or 14, characterized by the stabilized compost which is pre-condensed or condensed at the site.
16. Process as per at least on of the claims in 13 through 15, characterized by a stabilized compost, compacted and stored in at least two compartments and that the two compartments are separated by an intermediate layer exhibiting solidifying, adsorptive and\or buffering properties.
17. Process as per at least one of the claims in 13 through 16, characterized by the use of a landfill foundation consisting of material exhibiting solidifying, absorptive and\or buffering properties.
18. Process as per at least one of the claims in 13 through 17, characterized by the use of a surface cover consisting of material exhibiting solidifying, adsorptive and\or buffering properties.
19. Process as per at least one of the claims in 13 through 18, characterized by the treatment of the stabilized compost with compaction-promoting and stucture-lending condensation matter.
20. Process as per claim 19, characterized by condensation matter containing materials which exhibit solidifying, adsorptive and\or buffering properties.
21. Process as per at least one of the claims in 16 through 20, characterized by the intermediate layer, the landfill foundation, the landfill surface cover and\or the structure-lending condensation matter which consist of or are mixed with organic and inorganic additive matter, in particular shredded wood, lignocellulose, mineral mixtures, clay or a mixture thereof.
22. Process as per claim 21, characterized by the stabilized compost being mixed with the additive matter.
23. Process as per claim 21 or 22, characterized by the use of additive matter consisting of calcium-containing mineral mixtures.
24. Process as per claim 23, characterized by the calcium-containing mineral mixture which has been treated with additional additives such as iron sulfate.
25. Process as per at least one of the claims in 16 through 24, characterized by the use of DPR
(Dispersed-Chemical-Reaction)-processed materials to create the intermediate layer, the landfill foundation, the landfill surface cover and\or the structure-lending condensation matter.
(Dispersed-Chemical-Reaction)-processed materials to create the intermediate layer, the landfill foundation, the landfill surface cover and\or the structure-lending condensation matter.
26. Process as per one of the claims in 13 through 25, characterized by the stabilized compost itself being treated with the DCR-process.
27. Process as per at least one of the claims in 13 through 26, characterized by stabilized compost that is compacted or condensed via over-mudding.
28. Process as per at least one of the claims in 13 through 17, characterized by the addition of lignosulfonic acid or decayed mud to the compaction process of the stabilized compost.
29. Process at per at least one of the claims in 13 through 28, characterized by the stabilized compost being subjected to a drying step prior to compaction.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19904012670 DE4012670A1 (en) | 1990-04-20 | 1990-04-20 | Landfill and method for inerting compost |
DEP4012670.6 | 1990-04-20 |
Publications (1)
Publication Number | Publication Date |
---|---|
CA2080372A1 true CA2080372A1 (en) | 1991-10-21 |
Family
ID=6404771
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA 2080372 Abandoned CA2080372A1 (en) | 1990-04-20 | 1991-04-19 | Landfill and process for developing same |
Country Status (6)
Country | Link |
---|---|
EP (1) | EP0525092B2 (en) |
JP (1) | JPH05507261A (en) |
AT (1) | ATE107545T1 (en) |
CA (1) | CA2080372A1 (en) |
DE (2) | DE4012670A1 (en) |
WO (1) | WO1991016153A1 (en) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5336290A (en) * | 1991-09-27 | 1994-08-09 | Jermstad David B | Semi-solid activated sludge bioremediation of hydrocarbon-affected soil |
LU88493A1 (en) * | 1994-06-02 | 1994-12-01 | Marc Watgen | Process for sealing by means of earth barriers, in particular for the production of orderly landfills without drainage |
ITVI20020196A1 (en) * | 2002-09-12 | 2004-03-13 | Sist Ecodeco Spa | METHOD FOR SURFACE RECLAMATION OF EXHAUSTED LANDFILLS OF URBAN SOLID WASTE. |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3586624A (en) * | 1970-03-02 | 1971-06-22 | Werner Co | Waste disposal method and system |
US4643111A (en) * | 1985-08-21 | 1987-02-17 | Jones Robert L | Resource recovery utility |
DE3632365A1 (en) * | 1986-09-24 | 1988-03-31 | Friedrich Boelsing | METHOD FOR IMMOBILIZING POLLUTANTS IN THE FLOOR OR FLOOR-LIKE MATERIALS |
DE3921066A1 (en) * | 1988-06-27 | 1989-12-28 | Rethmann Staedtereinigung Gmbh | Process and plant for microbiological decontamination of contaminated soils |
US4838733A (en) * | 1988-12-05 | 1989-06-13 | Katz Albert A | Landfill compaction |
-
1990
- 1990-04-20 DE DE19904012670 patent/DE4012670A1/en not_active Withdrawn
-
1991
- 1991-04-19 JP JP91508132A patent/JPH05507261A/en active Pending
- 1991-04-19 DE DE59102029T patent/DE59102029D1/en not_active Expired - Fee Related
- 1991-04-19 WO PCT/EP1991/000756 patent/WO1991016153A1/en active IP Right Grant
- 1991-04-19 CA CA 2080372 patent/CA2080372A1/en not_active Abandoned
- 1991-04-19 EP EP19910908719 patent/EP0525092B2/en not_active Expired - Lifetime
- 1991-04-19 AT AT91908719T patent/ATE107545T1/en not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
DE4012670A1 (en) | 1991-10-24 |
EP0525092B1 (en) | 1994-06-22 |
EP0525092A1 (en) | 1993-02-03 |
WO1991016153A1 (en) | 1991-10-31 |
JPH05507261A (en) | 1993-10-21 |
DE59102029D1 (en) | 1994-07-28 |
EP0525092B2 (en) | 1998-04-01 |
ATE107545T1 (en) | 1994-07-15 |
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Legal Events
Date | Code | Title | Description |
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FZDE | Discontinued |