CA2075002A1 - Reactor quenching for catalytic olefin hydration in ether production - Google Patents

Abstract

ABSTRACT

REACTOR QUENCHING FOR CATALYTIC OLEFIN
HYDRATION IN ETHER PRODUCTION

A process for production of ether by catalytic hydration and etherification of olefinic feedstock containing at least one lower alkene by contacting the olefinic feedstock and water in a plurality of catalytic reaction zones containing porous solid metal oxide acidic olefin hydration and etherification catalyst under hydration and etherification conditions.
Improved operation is achieved by recovering a first effluent stream from at least one fixed bed hydration zone;
splitting the first effluent stream into a product recovery stream and a plurality of recycle streams; and passing at least a portion of cooled recycle streams comprising olefin, alcohol and ether in effluent stream component proportions for quenching at least one fixed bed reaction zone along with hot effluent from a preceding reaction zone.

Description

2~75~0~2 REACTOR QUENCHING FOR C~TALYTIC OLEFIN
HYDRATION IN ETHER PRODUCTION

This invention relates to olefin hydration, especially for the production of di-isopropyl ether (DIPE) from C3+ olefinic feedstocks. Particularly, this invention relates to a novel technique for operating a fixed bed multizone reactor with a solid hydration catalyst.
The need to eliminate lead-based octane enhancers in gasoline has provided incentive for the development of processes to produce high octane gasolines blended with lower aliphatic alkyl ethers as octane boosters.
Supplementary fuels are being vigorously developed in the petroleum refining industry. Lower molecular weight alcohols and ethers such as isopropyl alcohol (IPA~, isopropyl t-butyl ether (IPTBE), and diisopropyl ether (DIPE) are in the boiling range of gasoline fuels and are known to have a high blending octane number.
They are useful octane enhancers. In addition, by-product propene (propylene) from which IPA and DIPE
can be made is usually available in a fuels refinery, typically as a C3+ aliphatic stream rich in propene and propane. The petrochemicals industry also produces mixtures of light olefin streams in the C2-C7 molecular weight range and the conversion of such streams or fractions thereof to alcohols and/or ethers can also provide products useful as solvents and blending stocks for gasoline.
Adapting available refinery feedstock to produce these oxygenates simultaneously as octane enhancers can involve two different olefin hydration and etherification processes, i.e. propene hydration-etherification to give DIPE and IPA.
Accordingly, a challenge is provided to explore these processes to discover how they may be integrated in a F-5819 - 2 - ~ 2 manner more beneficial to the production of high octane gasoline.
Catalytic hydration of olefins to provide alcohols and ethers is established technology for the production of IPA and DIPE and is of significant commercial importance. Representative olefin hydration processes are disclosed in U.S. Patents Nos. 4,334,890 (Xochar), 3,912,463 (Kozlowski et al.); 4,042,633 (Woods);

4,499,313 (Okumura et al.); 4,886,918 (Sorensen et al).
Olefin hydration employing medium pore and large pore zeolite catalyst is a known synthesis method. As disclosed in U.S. Patent No. 4,214,107 (Chang et al.), lower olefins, in particular propylene, are catalytically hydrated over a crystalline aluminosilicate zeolite catalyst having a silica to alumina ratio of at least 12 and a Constraint Index of from 1 to 12, e.g., acidic ZSM-5 type zeolite, to provide the corresponding alcohol, essentially free of ether and hydrocarbon by-product. Acid resin catalysts such as "Amberlyst ~5" may also be used for the hydration of light olefins.
Production of ether from secondary alcohols such as isopropanol and light olefins is known. As disclosed in U.S. Patent No. 4,182,914 (Imaizumi), DIPE
is produced from IPA and propylene in a series of operations employing a strongly acidic cation exchange resin as catalyst. Recently, processes for the direct hydration of olefins to provide alcohols and ethers using porous shape selective metallosilicate zeolite catalyst, such as zeolite Beta have been disclosed in U.S. Patent No. 4,857,664 (Huang et al.). Prior processes for hydrating olefins have often been found to be inefficient with regard to catalyst life.
Poor distribution of water and hydrocarbon reactants may cause deactivation, especially with solid metallosilicate catalysts having large pores (i.e. 7+
Angstroms) or medium pores (5-7 A).

2~7~0~2 This invention provides a novel process for the production of ether/alcohol from lower olefins. In the preferred embodiments, di-isopropyl ether (DIPE) is produced by the hydration of a feedstock containing propene, which comprises contacting the propene feedstock and water in a catalytic reactor having a series of fixPd bed hydration zones with porous solid acidic olefin hydration catalyst under olefin hydration conditions. Improved operation is achieved by recovering a first liquid effluent stream from the catalytic reactor; splitting the first liquid effluent stream into a liquid product recovery stream and a liquid recycle stream; cooling at least a portion of the liquid recycle stream; and passing the cooled liquid recycled stream as interstage quench between fixed bed hydration zones for controlling reaction temperature.
The preferred solid catalyst comprises acidic zeolite, such as zeolite Beta, and hydration zone conditions comprise temperature of 50 to 220C.
Advantageously, total liquid recycle is combined with fresh feed at a weight ratio of 2:1 to 10:1 recycle:feed. Typically, liquid product stream is separated into at least two streams for recycle to separate reaction zones, and wherein at least a portion of cooled liquid recycle is injected between separated fixed catalyst beds. The fixed bed hydration zones may be maintained in a vertical downflow reactor; and wherein the solid catalyst comprises at least one metal oxide catalyst.
These and other advantages and features of the invention will be seen in the description and drawing.
Fig. 1 is a schematic process flow diagram of the improved process.
35The preferred embodiments of the invention are described with reference to propylene hydration and 2~75002 F-5819 - 4 ~

zeolite catalysts. Metric units and parts by weight are employed unless otherwise indicated.
The olefins hydration and etherification process employs the reaction of propylene with water catalyzed by strong acid to form isopropanol. Reaction may be allowed to continua in the hydration zone to form di-isopropyl ether. The operating conditions of the olefin hydration step include a temperature of 50 to 450C, preferably from 100 to 250~C and most preferably from 120 to 220C. The pressure is 700 to 24000 kPa (100 to 3500 psi, preferably 3500-14000 kPa (500-2000 psi)). Water to olefin reactant concentrations are maintained at mole ratio of 0.1 to 30, preferably 0.3-5.
Olefin hydration to provide ethers and alcohols to produce DIPE and byproduct isopropyl alcohol (IPA) is described in U. S. Patents 4,214,107 and 4,499,313. The preferred catalytic methods for making DIPE employ porous solid acid catalysts, such as zeolites Y, Beta, ZSM-35 and/or MCM-22 aluminosilicate. DIPE
etherification conditions may vary widely in choice of temperature, pressure and reaction time. The preferred method of Bell et al reacts propene with water in an adiabatic downflow reactor containing a fixed bed of 25 zeolite Beta at about 90 to 200C and pressure of at least 4000 kPa. However, it is understood that the unit operations described herein can be conducted with any number of specific process steps within the skill of the art.
The olefin hydration process of this invention are carried out in liquid phase, sup~rcritical dense phase, or mixtures of these phases in continuous manner using a fixed bed flow reactor. Weight hourly space velocity, based on catalyst weight is maintained in the range of 0.1 to 10/hour when operating continuously.
Various modifications can be made within the inventive concept, especially with regard to reactor 2~30~2 F-5819 ~ 5 ~

system configuration. Although a single reactor bed may be employed, it is advantageous to employ a series of fixed bed reactor units to permit adequate control of reaction conditions, especially temperature phase behavior and flow parameters.
It may be feasible to recover any unreacted olefin and recycle it to the reactor. Unconverted isopropanol recovered from the final reactor effluent may also be recycled to further conversion to ether.
The preferred hydration/etherification catalyst comprises acidic shape selective porous zeolite having a pore size of 5-8 x 10 mm (5-8 Angstroms), such as aluminosilicate zeolite Beta. Also, MCM-22, having pores similar to zeolite Beta and ZSM-5, is known for etherification catalysis.
Referring to Fig. 1 of the drawing, a process flow diagram depicts production of diisopropyl ether by hydration of fresh olefinic feedstock stream, which is introduced as a propane-propene mixture via inlet 1 to feed splitter tower 2 to recover a propane-rich bottoms stream 3. An overhead stream consisting essentially of propene (C3=, propylene) is pumped along with water from stream 12 through heat exchanger 14 to bring the reactants and recycle stream 16 to the process conditions for etherification in vertical reactor 20 in contact with porous solid acidic olefin hydration catalyst.
The reactor vessel 20 contains a series of fixed bed adiabatic hydration reaction zones 20A, 20B, 20C
maintained under olefin hydration conditions. Static mixers and liquid distributors may be employed before each bed to promote operation in a single homogeneous phase, as localized high concentrations of water or propylene are known to deactivate acidic catalysts (both zeolites and resins). Preferably, at least one hydration reaction zone contains porous zeolite catalyst, such as zeolite Beta.

2~7 ;Y~2 A fluid handling system is operatively connected for recovering a liquid reactor effluent stream 22 from the last zone 20C. This can be achieved by splitting effluent stream 22 into a liquid product recovery stream 24 and a liquid recycle stream 16A, which is recycled to the multizone reactor 20 as a plurality of flow-controlled recycle streams R1, R2, R3. Heat exchanger 16H cools the interstage quench streams R2, R3 below the process reaction, thus balancing the adiabatic heat of reaction from the preceding zone.
Reactor 20 is operated continuously by passing the liquid recycle stream 16A substantially unfractionated.
Reaction temperature can be controlled in zones 20B, 20C by varying the degree of cooling and/or flow rate of the recycle stream in unit 16H.
The amount of unfractionated liquid recycle stream 16 may be sufficient to maintain a substantially homogeneous single liquid reaction phase in the primary hydration zone 20A under reaction conditions. Use of DIPE, IPA containing product for quench will also promote single phase operation. The first liquid product stream 24 is passed via exchangers 14, 28 and fluid handling unit 29 to the product fractionation system, as described. Effluent stream 24 is ractionated in the product recovery system first in column 30 to recover ether-rich stream 32 and a propene-rich vapor stream 34, which may be recycled to tower 2 via line 35. Some of the steam may be purged from the system via line 36. It is advantageous to recover isopropanol for recycle to the reactor to provide isopropanol byproduct stream for further conversion to di-isopropyl ether. In the DIPE system depicted, unfractionated liquid recycle stream 16A is passed to reactor 20 at a rate which is about four times the total weight of propene and water reactants in the product recovery stream 24: the exact quantity depends an conversion targets, feed properties, etc..

2~7~0(~2 F-5819 - 7 ~

Ether-rich stream 3~ containing byproduct isopropanol, unreacted propene, water and C6+
hydrocarbon oligomer is further separated after passing through heat exchangers 38, 39 to extractor unit 40, where it is contacted with fresh feed water 42 and water recycle stream 52 to extract isopropanol in an aqueous phase 44. A product stream 46 consisting essentially of DIPE and byproduct C6+ propene oligomer is recovered from the extraction unit 40. The extract phase 44 is passed via exchangers 38, 48 to distillation column 50 to obtain an overhead isopropanol recycle stream 12 and liquid aqueous stream 52 for use in extraction unit 40.
The process flow scheme for olefin hydration to ethers over a zeolite Beta catalyst as disclosed utilizes product recycle and reactor quench for improved catalyst life and temperature control. The example system utilizes three catalyst beds in a single vertical reactor shell with mixing with inter-bed quench to reduce cost while controlling system phase behavior in comparison to other designs (tubular reactor).
The example shows improved catalyst life and yield benefits when recycling reactor product (pumparound) for propene hydration to di-isopropylether (DIPE) over typical porous acid solid catalyst. Product pumparound is advantageous as a means of controlling reactor temperature rise and therefore reduces equipment cost, as compared to a conventional isothermal tubular reactor or the like. The use of the product recycle for inter-bed quench eliminates inter-reactor coolers while giving benefits in control of phase behavior.
The three 'oeds are contained in a single reactor vessel. This reactor design is lower cost than other reactor designs.
This preferred process design, which is suitable for commercial design, utilizes feed purification, 2~7~0~32 F-581g - 8 -product recycle, and reactor quench for hydration of propene to DIPE to achieve high propylene conversion (~95% overall). The design also takes advantage of reactor recycle and quench with interstage mixing-distribution to provide reduced catalyst aging and reactor temperature control (heat removal).
In the following example, 65% zeolite Beta is used in extrudate form with an alumina binder; however, other binders such as silica, zirconia, etc may be used. Continuous runs are made, with weight hourly space velocity of 0.33 charged to catalyst basis for propene. Unless otherwise indicated, reaction conditions include reactor inlet temperature of about 165C and pressure of about 10,000 kPa. comparative runs include a single zone adiabatic downflow reactor with fixed bed extrudate catalyst. Tables 1 and 2 give data for a typical DIPE production system, based on 100 parts by weight of fresh propene feed.

2~7~g2 Stream Component Flowrates Stream No. 1 3 10 12 C3= 100 4.24 237.910.00 C3 91.27 90.77 59.60o.oo Water 50.12 IPA 51.37 DIPE Trace 5.49 c6=+ Trace 0.50 TOTAL191.27 95.01 297.51107.48 Stream No.15 24 35 32 C3=237.91 142.64 142.14000.498 C3 59.60 59.60 59.10200.498 Water50.12 32.67 0.000032.670 IPA 51.37 Sl.S2 0.000051.621 DIPE 5.49 106.23 0.0022106.234 C6=+ 0.5 12.22 0.000212.220 TOTAL404.99404.99 201.2500203.740 Stream No.46 44 52 42 C3= 0.498 0.000 0.00 0.00 C3 0.498 0.000 0.00 0.00 Water0.748 176.560 126.4318.20 IPA 0.249 51.370 0.00 0.00 DIPE100.748 5.490 0.00 0.00 c6=+11.720 0.498 0.00 0.00 TOTAL114.463233.92 126.4318.20 F-5819 - 10 - 2~7~002 TABI~E 2 Reactor Recycle/Ouench Component Flowrates Rl R2 R3 Recycle to Recycle to Recycle to First Bed Second Bed Third Bed C3= 49~.8 71.6 79.3 C3 208.2 29.9 33.2 Water114.0 16.5 18.2 IPA 180.3 25.9 28.7 10 DIPE371.1 53.1 59.1 C6=+ 42.6 6.2 6.7 TOTAL1415 203.2 225.2 Average Temperature,C (F) 165(330) 54(129) 54(129) T, C (F)/bed11(20) 11(20) 11(20) Bed Inlet Temp. C (F)(SOC) 155(310~ 155(310) 155(310) Bed Inlet Temp. C (F)(EOC) 177(350) 177(350) 177(350) Bed Inlet Temp. C (F) (SOC) 165(330)165(330)165(330) Bed Inlet Temp. C (-F) (EOC) 188(370)188(370)188(370) 2~75~
F-58l9 In fixed bed hydration of propene to di-isopropylether (DIPE), catalyst aging has been found to limit cycle length and catalyst life during single pass operation. When effluent recycle with mixing and quenching are employed, propene conversion and DIPE
yield increase and aging is significantly reduced.
This effect is unexpected, since pump-around type of reactor operation (i.e., back mixed) generally reduces conversion compared to plug flow (single pass).
Catalyst life is increased compared to conventional process flow schemes. Product pumparound recycle is ordinarily expec~ed to lower yields (back-mixed versus plug flow) and reduce catalyst life (coke/polymer formation). The opposite occurs in both instances.
This advantage in yield and catalyst aging is unexpected. Product recycle is believed to improve overall distribution in the reactor due to higher flux and improving phase behavior (a single liquid phase versus water-rirh and water-lean phases). The ~ increased DIPE at the reactor inlet might act as a solvent to remove coke precursors. Temperature control by product recycle guench is also a primary benefit for process with a small window of operation.
This flow scheme provides significant benefits beyond simple heat control. It is possible to adjust pumparound composition by adjusting reactor effluent temperature, separating out a water rich phase, and recycling a separated ether-rich phase which may further improve performance. This same effect in water reduction might also be accomplished by reducing the water content or amount of the IPA/water recycle from distillation.
A theoretical explanation for the observed increase in yields results from the strong solvents isopropanol/ether sa~urating the catalyst pores. This prevents the formation of any separate water or olefin 2~7~2 phases in the pores during operation. The aqueous or hydrocarbon phases can cause catalyst deactivation.
The water phase may attack the crystalline structure of the catalyst, while a highly olefinic phase would deactivate the catalyst via rapid coke formation. The isopropanol/ether mixture also allows controlled quantities of water and propylene to be present homogeneously in the catalyst pores, which allows the reactions to proceed properly at reaction temperature.
For the recycle techni~ue to be effective, the recycled liquid must dissolve the water and olefin present in fresh feedstock and the quench must be used with good mixing and distribution.

Claims (9)

1. A process for the production of di-isopropyl ether by hydration and etherification of fresh olefinic feedstock containing propene with water, which comprises the steps of:
contacting the propene feedstock and water with porous solid acidic olefin hydration/etherification catalyst in a series of primary and secondary fixed bed adiabatic reaction zones under olefin hydration and etherification conditions with interstage mixing and redistribution, including at least one reaction zone containing shape selective medium pore zeolite comprising zeolite Beta;
recovering a first fluid effluent stream from at least one fixed bed hydration zone;
splitting the first fluid effluent stream into a product recovery stream and a fluid recycle stream;
cooling and passing a first portion of the fluid recycle stream comprising olefin, alcohol and ether in effluent stream component proportions for quenching the secondary fixed bed reaction zone along with hot effluent from the primary reaction zone, wherein the recycle stream comprises 0-10 wt % water, 20-60 wt% propene, 20-30 wt% di-isopropyl ether and 10-15 wt% ispropanol and is fed to the primary fixed bed reaction zone along with fresh propene feedstock and fresh water in amount sufficient to maintain a substantially homogeneous single fluid reaction phase in the primary reaction zone.

2. The process of claim 1 wherein the reaction zones have a temperature of 50 to 220°C.

3. The process of claim 1 wherein total liquid recycle is combined with fresh feed at a weight ratio of 2:1 to 10:1 recycle:feed.

4. The process of claim 1 wherein the product recovery stream is separated into at least two streams for recycle to separate reaction zones, and wherein at least a portion of the cooled liquid recycle is injected between separated fixed catalyst beds.

5. The process of claim 1 wherein the fixed bed reaction zones are maintained in a vertical downflow reactor; and wherein the solid catalyst comprises at least one metal oxide catalyst.

6. The process of claim 1 wherein the liquid product recovery stream is fractionated to recover a di-isopropyl ether stream, a byproduct stream containing isopropanol and an unreacted propene stream;
and wherein the isopropanol byproduct stream is recycled to the primary reaction zone for further conversion to di-isopropyl ether.

7. The process of claim 1 wherein substantially unfractionated product recovery stream comprises 0-10 wt % water, 20-60 wt% propene, 20-30 wt% di-isopropyl ether, and 10-15 wt% isopropanol.

8. A reactor system for production of ether by hydration of olefinic feedstock containing at least one lower alkene, comprising:
multizone reactor means contacting the olefinic feedstock and water in a plurality of catalytic reaction zones containing porous solid metal oxide acidic olefin hydration-etherification catalyst under olefin hydration and etherification conditions;
fluid handling means for recovering a first liquid effluent stream from at least one fixed bed hydration zone and splitting the first liquid effluent stream into a liquid product recovery stream and a plurality of liquid recycle streams;
heat exchange means for cooling a first portion of the liquid recycle stream comprising olefin, alcohol and ether in effluent stream component proportions; and interzone quenching means for introducing cooled recycle liquid to at least one the fixed bed reaction zone along with hot effluent from a preceding reaction zone.

9. The reactor system of claim 8 including interzone static mixer means and liquid distributor means for controlling composition/phase behavior in the reaction zones.