CA2034490C - Battery charging system - Google Patents
Battery charging systemInfo
- Publication number
- CA2034490C CA2034490C CA002034490A CA2034490A CA2034490C CA 2034490 C CA2034490 C CA 2034490C CA 002034490 A CA002034490 A CA 002034490A CA 2034490 A CA2034490 A CA 2034490A CA 2034490 C CA2034490 C CA 2034490C
- Authority
- CA
- Canada
- Prior art keywords
- housing
- voltage
- battery
- disposed
- battery assembly
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/42—Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
- H01M10/44—Methods for charging or discharging
-
- H—ELECTRICITY
- H02—GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
- H02J—ELECTRIC POWER NETWORKS; CIRCUIT ARRANGEMENTS OR SYSTEMS FOR SUPPLYING OR DISTRIBUTING ELECTRIC POWER; SYSTEMS FOR STORING ELECTRIC ENERGY
- H02J7/00—Circuit arrangements for charging or discharging batteries or for supplying loads from batteries
- H02J7/50—Circuit arrangements for charging or discharging batteries or for supplying loads from batteries acting upon multiple batteries simultaneously or sequentially
-
- H—ELECTRICITY
- H02—GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
- H02J—ELECTRIC POWER NETWORKS; CIRCUIT ARRANGEMENTS OR SYSTEMS FOR SUPPLYING OR DISTRIBUTING ELECTRIC POWER; SYSTEMS FOR STORING ELECTRIC ENERGY
- H02J7/00—Circuit arrangements for charging or discharging batteries or for supplying loads from batteries
- H02J7/60—Circuit arrangements for charging or discharging batteries or for supplying loads from batteries including safety or protection arrangements
- H02J7/64—Circuit arrangements for charging or discharging batteries or for supplying loads from batteries including safety or protection arrangements against overvoltage
-
- H—ELECTRICITY
- H02—GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
- H02J—ELECTRIC POWER NETWORKS; CIRCUIT ARRANGEMENTS OR SYSTEMS FOR SUPPLYING OR DISTRIBUTING ELECTRIC POWER; SYSTEMS FOR STORING ELECTRIC ENERGY
- H02J7/00—Circuit arrangements for charging or discharging batteries or for supplying loads from batteries
- H02J7/60—Circuit arrangements for charging or discharging batteries or for supplying loads from batteries including safety or protection arrangements
- H02J7/663—Circuit arrangements for charging or discharging batteries or for supplying loads from batteries including safety or protection arrangements using battery or load disconnect circuits
-
- H—ELECTRICITY
- H02—GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
- H02J—ELECTRIC POWER NETWORKS; CIRCUIT ARRANGEMENTS OR SYSTEMS FOR SUPPLYING OR DISTRIBUTING ELECTRIC POWER; SYSTEMS FOR STORING ELECTRIC ENERGY
- H02J7/00—Circuit arrangements for charging or discharging batteries or for supplying loads from batteries
- H02J7/70—Circuit arrangements for charging or discharging batteries or for supplying loads from batteries characterised by the mechanical construction
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/42—Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
- H01M2010/4292—Aspects relating to capacity ratio of electrodes/electrolyte or anode/cathode
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S320/00—Electricity: battery or capacitor charging or discharging
- Y10S320/12—Precharging analysis, e.g. determining presence of battery
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S320/00—Electricity: battery or capacitor charging or discharging
- Y10S320/13—Fault detection
Landscapes
- Engineering & Computer Science (AREA)
- Power Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Charge And Discharge Circuits For Batteries Or The Like (AREA)
- Secondary Cells (AREA)
Abstract
A battery charging system including a battery of one chemistry type and a battery charger for a different battery type is dis-closed. If a battery over-discharge condition or if an electrochemical cell (201, 202, 203, 204) imbalance is detected within the bat-tery, the battery prevents charging by the battery charger by means of a resettable switch (226, 227, 228, 229, 217).
Description
WO 9l/00623 ; . pcr/usso/p3l3~7~ ,, .
BATTERY CHARGING ~Y~i'l'~;M
203449~
Ra~k~round of the Inven~ion This invention relates generally to a system of charging rechargeable batteries and more particularly to a battery 10 charging system for a lithium electrode rechargeable battery which may be incomr~t;ble with early battery chargers.
Battery chargers usually contain all the circuitry 1 5 needed to charge a battery except for s~n~ing devices such as thermistors. Batteries typically cont~in no electrical circuitry except for sensing devices such as thermistors or type determining circuitry such as that described in U.S.
Patent Application No. 341, 778, "Method and Apparatus for 2 0 Determining Battery Type", filed on behalf of Johnson et al.
on 04/21/89. However, it has been noted that some 3esi~ners have placed some active ci,cuil" ~ within the battery housing primarily to protect the electrochemical cells from ~l~m~ge due to accidental short circuits during transport or use.
Rechargeable batteries employing a lithium electrode generally provide a greater energy storage capacity per unit volume than other commercially available batteries used in portable products. A lithium battery is a desirable addition 3 0 to such a portable product. Lithium batteries, however, have charging characteristics which are different than other types of rechargeable batteries.
- --WQ Q1/00623 2 0 3 4 ~ ~ O PCI/US90/03137 r ~
; - 2 ~ s ~
When a new battery type becomes available, full comp~tibility between currently available battery chargersand the new battery type i8 usually not present; the new battery type cannot be optimally charged by the chargers optimized for previously existing battery types.
Other charging systems exist using batteries which cont~in additional ci~cuilly within the battery housing to accomplish temperature sensing of the electro~hemic~1 cells, which is coupled to me charger circuitry for modification of the charter perform~nce. Any additional current drain placed on the battery by this circuitry causes reduced storage life for the battery. In order to reduce this additional current drain, expensive low power circuit element~ have been used.
~urnm~ry of the Invention Therefore, the present invention solves the problem of 2 0 battery and charger jncomp~tibility by providing circuitry for regulating charging within the battery itself and has the circuitry active only when the battery is in the charger and deriving its power from the charger.
2 5 Accordingly, it is one object of the present invention to detect an over-discharge condition and lJlevellt the battery from being charged when it has been over-tli.sch~rged.
It is another object of the present invention to detect electrochemical cell imbalance within the battery and 3 0 prevent the battery from being charged when there is an imbalance.
Wo 9l/00623 2 o 3 4 4 9 o Pcr/US9o/03l37 It is a further object of the present invention to reset the battery charge prevention if the battery electrochemical cell or cells are healed.
,~
5 Brief nescri~tion of the 1 )r~wir~s Fig. 1 is a schem~tic diagram of a conventional battery charger.
Figure 2 is a sçhem~tic diagram of the battery and 1 0 associated circuitry in accordance with the present invention.
T3etailed 1 )escri~tion of the Preferre~ F,mho(liment 1 5 The invention disclosed herein is of a battery charging system. It can be used on different types of batteries but in the preferred embodiment it is for use with lithium batteries and provides backwalds co np~tibility with existing battery chargers ~esigne-l for nickel-cad~iu or other types of 2 0 rechargeable batteries. It is ant;~ip~terl that batteries employing the present invention will be used for portable radiotelephone equipment such as cellular portable radiotelephone model number F09HGD8453AA av7.il~qhle from Motorola, Inc.
Fig. 1 is a schematic of a collvelltional battery charger having the capability of charging convention~l batteries. A
more complic~te~l battery charger such as that described in U.S. Patent Application No. (docket CE00132R), "Multiple 3 0 Battery Multiple Rate Battery Charger", filed on behalf of Johnson et al. on 05/3V89 may also be used. In Fig. 1, a transformer 101 may be a direct plug-in wall mount transformer unit provides an AC ou~u~ to supply power to -4 ~ 2 0 3 4 ~ 9 0 the charger. This AC output causes rectifier diode 103 to conduct on half of the AC cycle. When diode 103 conducts, the capacitor 105 charges. The energy stored in capacitor 105 allows for charging during the half of the AC cycle 5 when the diode 103 is not conducting. The charging current is determined by the effective resistance between c~p~r,itor 105 and the charging termin~l~ 107 and 109. When a battery is present in the charger and current begins to flow into the charger positive terminal 107 through the LED (light 1 0 emitting diode) indicator 111 and resistor 1i3. Additional charging current is supplied through resistor 117.
The charger circuitry of Fig. 1 is merely a source of charging current and will continue to source current to any 1 ~ battery coupled to it. A battery having the circuitry shown in the schematic of Fig. 2 provides a built-in int,P!lligence to protect and properly charge a battery which is particular about the type of charge it rece*es. This intelligence includes: (1) Voltage Cutoff: in which the charging of the 2 0 battery will be termin~ted when the battery voltage exceeds a threshold. In the preferred embo~iment~ this threshold is -7.2 volts. (2) Hysteresis: Once the charging is termin~ted, the voltage at the termin~l~ of the electrochemical cells will drop and unless there is hysteresis the charger will osrill~te 2 5 in and out of charge. The hysteresis of the preferred embocliment will disallow charge until the battery positive voltage is reduced to ~lox;m~tely 6.2 volts. (3) (~ontact Debounce: If the battery were to see intermittent coT-~rt with the charger terminAl~, charger + power may be 3 0 removed for a moment and the hysteresis may be reset.
Using a charged up capacitor, contact bounces of at least one second in duration will not reset the hysteresis. (4) Over- A
rhz~rge charge disable: With lithium batteries, if the WO 9l/00623 Pcr/us90/03137 ~- 5 2~3~49~ ~
cells are over-discharged or if they are l~mAged, repeated charging may cause a possible safety problem. Charge is denied when the battery is over-discharged. In the 5 preferred embodiment this condition is es~hli.~hed when the battery voltage is 3.5 volts or less. (5) Cell string imbalance charge disable: When near the end of the life of a cell the cell's voltage becomes subst~nt,iAlly reduced with respect to the other cells in the battery; the battery develops a 1 0 potential safety problem. Charge is disabled to avoid abuse when the defective cell voltage is less than 40% of the total cell string voltage.
F'ig. 2 is an electrical schemAtic of the circuitry disposed 1 5 within a battery housing 200, shown in broken line in the schematic. The lithium electrochemical cells 201, 202, 203, and 204 of the preferred embo-liment are assembled in a series-parallel coTnhinAtion of two cell strings. At the center of each cell string is a thermal fuse 206, 207 which is 2 0 thermally coupled to its associated series-co~necte~l cells to provide protection for the cells 201-204. If the cells 201-204 reach a temperature greater than the trip point of the thermal fuses (207 or 207) will open and the cells will be discorlnected from use. The two cell strings are run 25 through a current-activated circuit breaker 209, commonly known as a "polyswitch" available from Raychem, Inc., which will trigger under short circuit conditions across the BATTERY POSITIVE t~llllil.al 211 and the BATTERY
NEGATIVE terminal 212 on the outside of the battery 3 0 housing 200. The center points of each series-parallel cell string are denoted by CSC1 or CSC2.
The CHARGER POSITIVE terminal 214, which appears on the outer surface of the battery housing 200 is internally J
-WO 9l/00623 Pcr/usso/o3l3~
BATTERY CHARGING ~Y~i'l'~;M
203449~
Ra~k~round of the Inven~ion This invention relates generally to a system of charging rechargeable batteries and more particularly to a battery 10 charging system for a lithium electrode rechargeable battery which may be incomr~t;ble with early battery chargers.
Battery chargers usually contain all the circuitry 1 5 needed to charge a battery except for s~n~ing devices such as thermistors. Batteries typically cont~in no electrical circuitry except for sensing devices such as thermistors or type determining circuitry such as that described in U.S.
Patent Application No. 341, 778, "Method and Apparatus for 2 0 Determining Battery Type", filed on behalf of Johnson et al.
on 04/21/89. However, it has been noted that some 3esi~ners have placed some active ci,cuil" ~ within the battery housing primarily to protect the electrochemical cells from ~l~m~ge due to accidental short circuits during transport or use.
Rechargeable batteries employing a lithium electrode generally provide a greater energy storage capacity per unit volume than other commercially available batteries used in portable products. A lithium battery is a desirable addition 3 0 to such a portable product. Lithium batteries, however, have charging characteristics which are different than other types of rechargeable batteries.
- --WQ Q1/00623 2 0 3 4 ~ ~ O PCI/US90/03137 r ~
; - 2 ~ s ~
When a new battery type becomes available, full comp~tibility between currently available battery chargersand the new battery type i8 usually not present; the new battery type cannot be optimally charged by the chargers optimized for previously existing battery types.
Other charging systems exist using batteries which cont~in additional ci~cuilly within the battery housing to accomplish temperature sensing of the electro~hemic~1 cells, which is coupled to me charger circuitry for modification of the charter perform~nce. Any additional current drain placed on the battery by this circuitry causes reduced storage life for the battery. In order to reduce this additional current drain, expensive low power circuit element~ have been used.
~urnm~ry of the Invention Therefore, the present invention solves the problem of 2 0 battery and charger jncomp~tibility by providing circuitry for regulating charging within the battery itself and has the circuitry active only when the battery is in the charger and deriving its power from the charger.
2 5 Accordingly, it is one object of the present invention to detect an over-discharge condition and lJlevellt the battery from being charged when it has been over-tli.sch~rged.
It is another object of the present invention to detect electrochemical cell imbalance within the battery and 3 0 prevent the battery from being charged when there is an imbalance.
Wo 9l/00623 2 o 3 4 4 9 o Pcr/US9o/03l37 It is a further object of the present invention to reset the battery charge prevention if the battery electrochemical cell or cells are healed.
,~
5 Brief nescri~tion of the 1 )r~wir~s Fig. 1 is a schem~tic diagram of a conventional battery charger.
Figure 2 is a sçhem~tic diagram of the battery and 1 0 associated circuitry in accordance with the present invention.
T3etailed 1 )escri~tion of the Preferre~ F,mho(liment 1 5 The invention disclosed herein is of a battery charging system. It can be used on different types of batteries but in the preferred embodiment it is for use with lithium batteries and provides backwalds co np~tibility with existing battery chargers ~esigne-l for nickel-cad~iu or other types of 2 0 rechargeable batteries. It is ant;~ip~terl that batteries employing the present invention will be used for portable radiotelephone equipment such as cellular portable radiotelephone model number F09HGD8453AA av7.il~qhle from Motorola, Inc.
Fig. 1 is a schematic of a collvelltional battery charger having the capability of charging convention~l batteries. A
more complic~te~l battery charger such as that described in U.S. Patent Application No. (docket CE00132R), "Multiple 3 0 Battery Multiple Rate Battery Charger", filed on behalf of Johnson et al. on 05/3V89 may also be used. In Fig. 1, a transformer 101 may be a direct plug-in wall mount transformer unit provides an AC ou~u~ to supply power to -4 ~ 2 0 3 4 ~ 9 0 the charger. This AC output causes rectifier diode 103 to conduct on half of the AC cycle. When diode 103 conducts, the capacitor 105 charges. The energy stored in capacitor 105 allows for charging during the half of the AC cycle 5 when the diode 103 is not conducting. The charging current is determined by the effective resistance between c~p~r,itor 105 and the charging termin~l~ 107 and 109. When a battery is present in the charger and current begins to flow into the charger positive terminal 107 through the LED (light 1 0 emitting diode) indicator 111 and resistor 1i3. Additional charging current is supplied through resistor 117.
The charger circuitry of Fig. 1 is merely a source of charging current and will continue to source current to any 1 ~ battery coupled to it. A battery having the circuitry shown in the schematic of Fig. 2 provides a built-in int,P!lligence to protect and properly charge a battery which is particular about the type of charge it rece*es. This intelligence includes: (1) Voltage Cutoff: in which the charging of the 2 0 battery will be termin~ted when the battery voltage exceeds a threshold. In the preferred embo~iment~ this threshold is -7.2 volts. (2) Hysteresis: Once the charging is termin~ted, the voltage at the termin~l~ of the electrochemical cells will drop and unless there is hysteresis the charger will osrill~te 2 5 in and out of charge. The hysteresis of the preferred embocliment will disallow charge until the battery positive voltage is reduced to ~lox;m~tely 6.2 volts. (3) (~ontact Debounce: If the battery were to see intermittent coT-~rt with the charger terminAl~, charger + power may be 3 0 removed for a moment and the hysteresis may be reset.
Using a charged up capacitor, contact bounces of at least one second in duration will not reset the hysteresis. (4) Over- A
rhz~rge charge disable: With lithium batteries, if the WO 9l/00623 Pcr/us90/03137 ~- 5 2~3~49~ ~
cells are over-discharged or if they are l~mAged, repeated charging may cause a possible safety problem. Charge is denied when the battery is over-discharged. In the 5 preferred embodiment this condition is es~hli.~hed when the battery voltage is 3.5 volts or less. (5) Cell string imbalance charge disable: When near the end of the life of a cell the cell's voltage becomes subst~nt,iAlly reduced with respect to the other cells in the battery; the battery develops a 1 0 potential safety problem. Charge is disabled to avoid abuse when the defective cell voltage is less than 40% of the total cell string voltage.
F'ig. 2 is an electrical schemAtic of the circuitry disposed 1 5 within a battery housing 200, shown in broken line in the schematic. The lithium electrochemical cells 201, 202, 203, and 204 of the preferred embo-liment are assembled in a series-parallel coTnhinAtion of two cell strings. At the center of each cell string is a thermal fuse 206, 207 which is 2 0 thermally coupled to its associated series-co~necte~l cells to provide protection for the cells 201-204. If the cells 201-204 reach a temperature greater than the trip point of the thermal fuses (207 or 207) will open and the cells will be discorlnected from use. The two cell strings are run 25 through a current-activated circuit breaker 209, commonly known as a "polyswitch" available from Raychem, Inc., which will trigger under short circuit conditions across the BATTERY POSITIVE t~llllil.al 211 and the BATTERY
NEGATIVE terminal 212 on the outside of the battery 3 0 housing 200. The center points of each series-parallel cell string are denoted by CSC1 or CSC2.
The CHARGER POSITIVE terminal 214, which appears on the outer surface of the battery housing 200 is internally J
-WO 9l/00623 Pcr/usso/o3l3~
connected to and denoted by C~harger +. When the battery is being charged from a battery charger circuit like that of Fig.
1, the charge current is p~se-l to the electrochemical cells 201-204 through a diode 216 and a transistor switch 217. The charge current is also connecte-l to a resistor 219 and to charger supply line CSUP which supplies power to operate the internal circuitry from the charger rather than from the electrochemical cells 201-204. A Zener diode 220 is used to 1 0 protect the circuitry from voltages in excess of the electrical parts ratings.
When the battery is not present in a charger, there is no power supplied to (:~harger +. In this condition, all the comp~rators 222, 223, 224, 225,226, 227, 228, and 229 (which 1 5 may be comparator type number LM2901D available from Motorola, Inc. having PNP input junctions) do not have a power supply and are essentially in an off state because, king a power supply input, they eæs~nti~lly draw no current. ~imil~rly, the conventional voltage reference 231 2 0 (which in the preferred embodiment is a 2.5 volt reference) also draws no current. Therefore all the active circuitry draws no current when the battery is not in the charger.
However, there are two resistor dividers which draw a small amount of current from the electrochemical cells.
2 5 First is the series connection of resistors 233, 234, and 235.
This resistor divider uses high value resistors to minimi~e the current drain from the battery. The other resistor divider is that forrned by resistors 237, 238, 239, and 240, which also minimi7:es the amount of current by using high 3 0 value resistors. Because the active devices do not draw any current from the electrochemical cells and the comparator inputs are PNP junction inputs, the present invention minimi7eS the amount of power that is drained from the Wo 9l/00623 Pcr/usso/03l37 7 ~ ~ 0 3 ~ ~ 9 ~
battery when the battery is not being charged. This feature gives the battery greater storage life. In the case of a battery employing a lithium electrode in the electro~hemic~l cells, 5 the additional circuitry of the present invention does not degrade the shelf life subst~nti~lly.
The circuitry within the battery housing 200 is used when the battery is placed into the charger, the c~p~-~itor 1 0 242 is at zero volts relative to commor-, initially holding the positive input terminal of compArator 226 low relative to the inverting input which is connected to the voltage reference from reference 231. This initial condition gives a "low"
output ~ign.ql. Because the output is low, the signal 1 5 provided via series resistor 244 and shunt resistors 234 and 236 drives the non-inverting input of comp~rator 228 low.
The inverting input terminal of comparator 228 is connected to the voltage reference 231 through resistor 246. The resistor 244 is chosen so that the voltage at the non-i,lve~ ~ing 2 0 input of comparator 228 will be below the voltage reference 231. This creates a "false" condition wherein the output of the comparator 228 goes low. When the output of comparator 228 is low, the resistor 248 is ess~nti~lly placed in parallel across resistor 235 further re~ inF the voltage 2 5 at the non-inverting input of comparator 228.
Since the battery has been placed in the charger, the initial (non-charged) condition across capacitor 242 will change. Capacitor 242 charges with a time constant 3 0 determined by its capacity and resistor 252. When the voltage across capacitor 242 exceeds the value of the voltage from voltage reference 231, the output of comp~rator 226 becomes an open circuit. This open circuit essqnt~ y WO gl/00623 PCr/USso/03l37 8 ~ 4 9 ~
removes resistor 244 from the circuit so that the voltage at the non-inverting input of comr~rator 228 increases. This sequence of events sets the resistor divider of resistors 23, 234, and 235, in parallel with resistor 248. When the voltage at the termin~l~ of the electroçh~mic~l cells 201-204 is such that the voltage at the non-illvel ling input of comr~rator 228 exceeds the reference voltage supplied by voltage .efelellce 231, the electro~hemic~l cells of the battery are deemed to be 1 0 fully charged.
In the preferred embodiment employing lithium electrode cells, this happens when the battery has an output voltage across terminAl~ 211 and 212 of a~l,.oxi..~tsly 7.2 1 5 volts. VVhen the battery charges above 7.2 volts the input at the positive terminal comparator 228 is greater than the reference voltage, the output becomes an open circuit, and resistor 248 essentially is icol~ed from the resistor divider of resistors 233, 234, and 235. Thus, the voltage at the positive 2 0 terminal of comparator 228 increases. This provides a hysteresis effect so that one the circuit switches and the battery stops being charged, the circuit does not oscillate back and forth as the battery voltage settles.
When the output of comparator 228 becomes an open 2 5 circuit, the voltage at the non-inverting input of comr~rator 229 is essenti~lly the divided down voltage present at the node between resistors 234 and 235. This voltage is compared against the divided down Lefe.~llce voltage from reference 231 (by resistors 250 and 251 with the common 3 0 point between them driving the illVt:l lillg input of comparator 229). When the o~ u~ voltage of comr~rator 228 (the voltage at comparator 229 non-illvel ling input) is greater than the voltage at the inverting input of comp~rator WO 91/00623 PCI~/US90/03137 _ ~ 9 20~4490 229, a "true" condition is created and comparator 229 output becomes an open circuit. When the output of comparator 228 is low, the non-inverting input of comparator 229 is low.
When the outputs of these comp~rators are low, they will sink current. Thus, when the oul,l ul of cQmr~rator 229 is low, current will be drawn from the base of the tr~n~istor 217 through resistor 253, thereby turning transistor 217 on.
When it is on, current will flow from the Charger + line 1 0 through the transistor 217, through diode ~16, and into the electrochemical cells 201-204 to charge them. When the output of comp~rator 229 is open, there will not be base current flowing through resistor 253 and tr~n~i~tor 217 will be off and the electroch~mic~l cells will not charge. Resistor 1 5 255 provides pull-up for the base of transistor 217 when the output of comparator 229 is open to insure that the tr~n~i~tor 217 is off. The diode 216 ~ v~nts the electrochemical cells from ~Lai-li,lg back through the transistor 217 when the battery is not in a charger.
2 0 Zener diode 220 is coupled in series with resistor 219 to create the supply line of CSUP. CSUP is limited to the Zener voltage so ~SUP to the co...p~. ators will not exceed their m~imum ratings.
In accordance with one feature of the present inveIltion, 2 5 the battery may automatically be ~. ~vented from accel.tillg charging current if the voltage available from the electroch~mic~l cells is below a threshold voltage. This low voltage threshold (determined by the l~hemi.stry of the lithium system in the ~lefel-~ed embo~liment) can be 3 0 re~che~ if the battery is over-charged. At this voltage, the electrochemical cells have most likely been ~m~ged and the safety of the battery may be col--p,vmised. To ~ccomE-lish an automatic removal of the electro~hamicsll WO 9l/00623 Pcr/usso/o3l37 cells, a voltage detection circuit is employed in the preferred embodiment. Comparator 227 is used to disable the charging of an over-~i.cch~rged battery. This is accomplished by using the voltage from voltage reference 231 driving the inverting input of comr~rator 227 and a divided-down voltage derived from the resistor network of resistors 237, 238, 239, and 240 and voltage coupled form the BAl~ERY POSITIVE terminal 211. The node between 1 0 resistor 237 and resistor 238 is coupled to the non-inverting input of comp~rator 227 such that when, in the preferred embo-liment the battery voltage goes below appro~im~tely 3.5 volts, the output of comparator 227 goes low. Upon this occurrence the reference voltage is effectively removed from 1 5 the inverting input of comparator 228. This causes the output of comparator 228 to become an open circuit, turning off comparator 229, turning off the transistor 217 and stopping charge from going into the electrochemical cells.
2 0 A further protection av~ilAhle in the charging system of the present invention is that of electrochemical cell imb2~l~nce. If one of the four electrochemical cells has been l~m~ged or if the electro-~hemic~l cell has re~r~h~ its end of life before the other cells, its voltage will be less than that of 2 5 the other cells. If the voltage is less than that applied to the opposite input of either comp~rator 222 or comr~qrator 225 coupled to the electrochemical cells, or if the voltage is greater than that applied to the opposite input of either comp~rator 223 or comparator 224 coupled to the 3 0 electrochemical cells, one of the outputs of the associ~e-l comparators will go low. By going low the comr~rator output changes the resistor divider consisting of resistors 237,238, 239, and 240 so that the divider has been ~ bled WO 91/00623 PCI~/US90/03137 11 2~34~90 and the voltage at the node between resistors 237 and 238 approaches ground potent;~ql. By going to ground, the voltage at the node l~t~hes the output of comp~rator 227 to 5 ground potent.i~l .
For either protection mode, low battery voltage or cell ;mh~l~nce, if the defective cell later corrects itself, the circuit will not be reset and charging will not recommence unless the battery is removed from the charger. This low 1 0 voltage state at the nodes of CSC1 and CSC2 is detected and the outputs of comparators 222, 223, 224, and 225 are logic ORed, to drive the non-inverting input of comp~rator 227 low. The comparison to the reference voltage at the inverting input of comparator 227 creates a "false" condition 1 5 and prevents charging of the electrochçmical cells. As a failsafe, resistors 260 and 261 are present so that if the connections to he center of both the cell strings become broken, these resistors will pull down the voltages to ground or near ground potential and creates a "false" condition as 2 0 though one of the cells was below voltage. However, the removal of the battery from the charger removes the supply from CSUP and allows the circuit to relax. If a defective cell corrects itself, the battery can again be recharged.
To reduce co~t~ct bounce, the voltage at the positive 2 5 input of comp~rator 228 does not go away because it is coupled to the electro~hemic~l cells through resistors 233, 234, and 23~. When the reference voltage disappears the inverting input of comparator 228 goes low to create a "true"
condition (the output of comparator 228 becomes an open 3 0 circuit). Thus, if the battery were being charged prior to a contact bounce caused by, for e~mple a brief extraction and reinsertion of the battery into a charger, the circuit would allow the battery to continue to be charged after the co~t~ct 4 4 (~ a ., .
bounce. This protection lasts long enough for c~p~ritor 242 to llisrh~rge below the lerelellce voltage obt~ine-l from reference 231.
To m~int~in compatibility with battery chargers which use a thermistor to est~blish and end of charge condition such as a nickel cadmium electro~hemic~l cell battery, a fixed value resistor 259 is connecte~ to ground. In the preferred embodiment, the resistor value is chosen such 1 0 that the lithium electrochemical cells of the present invention cannot be fast charged. The battery charger having fast and slow charge modes thus is constrained to the slow rate of charge. This rate is the desired rate for the lithium battery of the present invention 1 5 Thus a rechargeable battery system for batteries of a type having charge characteristics which may be incompatible with previously made battery chargers has been shown and described. The circuitry which makes the battery compatible draws little current from the 2 0 electrochemical cells, relying mainly upon power from the charger for operation. If a battery over~ h~rge condition is detected as a battery voltage below a predetermined voltage threshold or if a battery electrorhemir~l cell imh~l~nce is detected as a difference in one cell voltage 2 5 relative to another, charging of the battery is prevented by a resettable semiconductor switch.
I Claim:
1, the charge current is p~se-l to the electrochemical cells 201-204 through a diode 216 and a transistor switch 217. The charge current is also connecte-l to a resistor 219 and to charger supply line CSUP which supplies power to operate the internal circuitry from the charger rather than from the electrochemical cells 201-204. A Zener diode 220 is used to 1 0 protect the circuitry from voltages in excess of the electrical parts ratings.
When the battery is not present in a charger, there is no power supplied to (:~harger +. In this condition, all the comp~rators 222, 223, 224, 225,226, 227, 228, and 229 (which 1 5 may be comparator type number LM2901D available from Motorola, Inc. having PNP input junctions) do not have a power supply and are essentially in an off state because, king a power supply input, they eæs~nti~lly draw no current. ~imil~rly, the conventional voltage reference 231 2 0 (which in the preferred embodiment is a 2.5 volt reference) also draws no current. Therefore all the active circuitry draws no current when the battery is not in the charger.
However, there are two resistor dividers which draw a small amount of current from the electrochemical cells.
2 5 First is the series connection of resistors 233, 234, and 235.
This resistor divider uses high value resistors to minimi~e the current drain from the battery. The other resistor divider is that forrned by resistors 237, 238, 239, and 240, which also minimi7:es the amount of current by using high 3 0 value resistors. Because the active devices do not draw any current from the electrochemical cells and the comparator inputs are PNP junction inputs, the present invention minimi7eS the amount of power that is drained from the Wo 9l/00623 Pcr/usso/03l37 7 ~ ~ 0 3 ~ ~ 9 ~
battery when the battery is not being charged. This feature gives the battery greater storage life. In the case of a battery employing a lithium electrode in the electro~hemic~l cells, 5 the additional circuitry of the present invention does not degrade the shelf life subst~nti~lly.
The circuitry within the battery housing 200 is used when the battery is placed into the charger, the c~p~-~itor 1 0 242 is at zero volts relative to commor-, initially holding the positive input terminal of compArator 226 low relative to the inverting input which is connected to the voltage reference from reference 231. This initial condition gives a "low"
output ~ign.ql. Because the output is low, the signal 1 5 provided via series resistor 244 and shunt resistors 234 and 236 drives the non-inverting input of comp~rator 228 low.
The inverting input terminal of comparator 228 is connected to the voltage reference 231 through resistor 246. The resistor 244 is chosen so that the voltage at the non-i,lve~ ~ing 2 0 input of comparator 228 will be below the voltage reference 231. This creates a "false" condition wherein the output of the comparator 228 goes low. When the output of comparator 228 is low, the resistor 248 is ess~nti~lly placed in parallel across resistor 235 further re~ inF the voltage 2 5 at the non-inverting input of comparator 228.
Since the battery has been placed in the charger, the initial (non-charged) condition across capacitor 242 will change. Capacitor 242 charges with a time constant 3 0 determined by its capacity and resistor 252. When the voltage across capacitor 242 exceeds the value of the voltage from voltage reference 231, the output of comp~rator 226 becomes an open circuit. This open circuit essqnt~ y WO gl/00623 PCr/USso/03l37 8 ~ 4 9 ~
removes resistor 244 from the circuit so that the voltage at the non-inverting input of comr~rator 228 increases. This sequence of events sets the resistor divider of resistors 23, 234, and 235, in parallel with resistor 248. When the voltage at the termin~l~ of the electroçh~mic~l cells 201-204 is such that the voltage at the non-illvel ling input of comr~rator 228 exceeds the reference voltage supplied by voltage .efelellce 231, the electro~hemic~l cells of the battery are deemed to be 1 0 fully charged.
In the preferred embodiment employing lithium electrode cells, this happens when the battery has an output voltage across terminAl~ 211 and 212 of a~l,.oxi..~tsly 7.2 1 5 volts. VVhen the battery charges above 7.2 volts the input at the positive terminal comparator 228 is greater than the reference voltage, the output becomes an open circuit, and resistor 248 essentially is icol~ed from the resistor divider of resistors 233, 234, and 235. Thus, the voltage at the positive 2 0 terminal of comparator 228 increases. This provides a hysteresis effect so that one the circuit switches and the battery stops being charged, the circuit does not oscillate back and forth as the battery voltage settles.
When the output of comparator 228 becomes an open 2 5 circuit, the voltage at the non-inverting input of comr~rator 229 is essenti~lly the divided down voltage present at the node between resistors 234 and 235. This voltage is compared against the divided down Lefe.~llce voltage from reference 231 (by resistors 250 and 251 with the common 3 0 point between them driving the illVt:l lillg input of comparator 229). When the o~ u~ voltage of comr~rator 228 (the voltage at comparator 229 non-illvel ling input) is greater than the voltage at the inverting input of comp~rator WO 91/00623 PCI~/US90/03137 _ ~ 9 20~4490 229, a "true" condition is created and comparator 229 output becomes an open circuit. When the output of comparator 228 is low, the non-inverting input of comparator 229 is low.
When the outputs of these comp~rators are low, they will sink current. Thus, when the oul,l ul of cQmr~rator 229 is low, current will be drawn from the base of the tr~n~istor 217 through resistor 253, thereby turning transistor 217 on.
When it is on, current will flow from the Charger + line 1 0 through the transistor 217, through diode ~16, and into the electrochemical cells 201-204 to charge them. When the output of comp~rator 229 is open, there will not be base current flowing through resistor 253 and tr~n~i~tor 217 will be off and the electroch~mic~l cells will not charge. Resistor 1 5 255 provides pull-up for the base of transistor 217 when the output of comparator 229 is open to insure that the tr~n~i~tor 217 is off. The diode 216 ~ v~nts the electrochemical cells from ~Lai-li,lg back through the transistor 217 when the battery is not in a charger.
2 0 Zener diode 220 is coupled in series with resistor 219 to create the supply line of CSUP. CSUP is limited to the Zener voltage so ~SUP to the co...p~. ators will not exceed their m~imum ratings.
In accordance with one feature of the present inveIltion, 2 5 the battery may automatically be ~. ~vented from accel.tillg charging current if the voltage available from the electroch~mic~l cells is below a threshold voltage. This low voltage threshold (determined by the l~hemi.stry of the lithium system in the ~lefel-~ed embo~liment) can be 3 0 re~che~ if the battery is over-charged. At this voltage, the electrochemical cells have most likely been ~m~ged and the safety of the battery may be col--p,vmised. To ~ccomE-lish an automatic removal of the electro~hamicsll WO 9l/00623 Pcr/usso/o3l37 cells, a voltage detection circuit is employed in the preferred embodiment. Comparator 227 is used to disable the charging of an over-~i.cch~rged battery. This is accomplished by using the voltage from voltage reference 231 driving the inverting input of comr~rator 227 and a divided-down voltage derived from the resistor network of resistors 237, 238, 239, and 240 and voltage coupled form the BAl~ERY POSITIVE terminal 211. The node between 1 0 resistor 237 and resistor 238 is coupled to the non-inverting input of comp~rator 227 such that when, in the preferred embo-liment the battery voltage goes below appro~im~tely 3.5 volts, the output of comparator 227 goes low. Upon this occurrence the reference voltage is effectively removed from 1 5 the inverting input of comparator 228. This causes the output of comparator 228 to become an open circuit, turning off comparator 229, turning off the transistor 217 and stopping charge from going into the electrochemical cells.
2 0 A further protection av~ilAhle in the charging system of the present invention is that of electrochemical cell imb2~l~nce. If one of the four electrochemical cells has been l~m~ged or if the electro-~hemic~l cell has re~r~h~ its end of life before the other cells, its voltage will be less than that of 2 5 the other cells. If the voltage is less than that applied to the opposite input of either comp~rator 222 or comr~qrator 225 coupled to the electrochemical cells, or if the voltage is greater than that applied to the opposite input of either comp~rator 223 or comparator 224 coupled to the 3 0 electrochemical cells, one of the outputs of the associ~e-l comparators will go low. By going low the comr~rator output changes the resistor divider consisting of resistors 237,238, 239, and 240 so that the divider has been ~ bled WO 91/00623 PCI~/US90/03137 11 2~34~90 and the voltage at the node between resistors 237 and 238 approaches ground potent;~ql. By going to ground, the voltage at the node l~t~hes the output of comp~rator 227 to 5 ground potent.i~l .
For either protection mode, low battery voltage or cell ;mh~l~nce, if the defective cell later corrects itself, the circuit will not be reset and charging will not recommence unless the battery is removed from the charger. This low 1 0 voltage state at the nodes of CSC1 and CSC2 is detected and the outputs of comparators 222, 223, 224, and 225 are logic ORed, to drive the non-inverting input of comp~rator 227 low. The comparison to the reference voltage at the inverting input of comparator 227 creates a "false" condition 1 5 and prevents charging of the electrochçmical cells. As a failsafe, resistors 260 and 261 are present so that if the connections to he center of both the cell strings become broken, these resistors will pull down the voltages to ground or near ground potential and creates a "false" condition as 2 0 though one of the cells was below voltage. However, the removal of the battery from the charger removes the supply from CSUP and allows the circuit to relax. If a defective cell corrects itself, the battery can again be recharged.
To reduce co~t~ct bounce, the voltage at the positive 2 5 input of comp~rator 228 does not go away because it is coupled to the electro~hemic~l cells through resistors 233, 234, and 23~. When the reference voltage disappears the inverting input of comparator 228 goes low to create a "true"
condition (the output of comparator 228 becomes an open 3 0 circuit). Thus, if the battery were being charged prior to a contact bounce caused by, for e~mple a brief extraction and reinsertion of the battery into a charger, the circuit would allow the battery to continue to be charged after the co~t~ct 4 4 (~ a ., .
bounce. This protection lasts long enough for c~p~ritor 242 to llisrh~rge below the lerelellce voltage obt~ine-l from reference 231.
To m~int~in compatibility with battery chargers which use a thermistor to est~blish and end of charge condition such as a nickel cadmium electro~hemic~l cell battery, a fixed value resistor 259 is connecte~ to ground. In the preferred embodiment, the resistor value is chosen such 1 0 that the lithium electrochemical cells of the present invention cannot be fast charged. The battery charger having fast and slow charge modes thus is constrained to the slow rate of charge. This rate is the desired rate for the lithium battery of the present invention 1 5 Thus a rechargeable battery system for batteries of a type having charge characteristics which may be incompatible with previously made battery chargers has been shown and described. The circuitry which makes the battery compatible draws little current from the 2 0 electrochemical cells, relying mainly upon power from the charger for operation. If a battery over~ h~rge condition is detected as a battery voltage below a predetermined voltage threshold or if a battery electrorhemir~l cell imh~l~nce is detected as a difference in one cell voltage 2 5 relative to another, charging of the battery is prevented by a resettable semiconductor switch.
I Claim:
Claims (19)
PROPERTY OR PRIVILEGE IS CLAIMED ARE DEFINED AS FOLLOWS:
1. A battery assembly including a housing enclosing at least one electrochemical cell and having protection from unsuitable charging from a battery charger providing a charging current, the protection disposed within thehousing of the battery assembly, characterized by:
means, disposed within the battery housing, for determining when the voltage of the at least one electrochemical cell is less than a predetermined voltage; and means, disposed within the battery housing and responsive to said means for determining, for resettably interrupting the charging current.
means, disposed within the battery housing, for determining when the voltage of the at least one electrochemical cell is less than a predetermined voltage; and means, disposed within the battery housing and responsive to said means for determining, for resettably interrupting the charging current.
2. A battery assembly in accordance with claim 1 comprising at least two electrochemical cells disposed within the battery housing, further characterizedby:
means, disposed within the battery housing, for detecting when a first electrochemical cell of the battery assembly produces a voltage which is a predetermined amount smaller than a voltage produced by a second electrochemical cell of the battery assembly.
means, disposed within the battery housing, for detecting when a first electrochemical cell of the battery assembly produces a voltage which is a predetermined amount smaller than a voltage produced by a second electrochemical cell of the battery assembly.
3. A battery assembly in accordance with claim 2 wherein said means for resettably interrupting the charging current is further characterized by means responsive to said means for detecting.
4. A battery assembly charging system characterized by:
means for supplying direct current (DC) electrical energy to a battery assembly;
a battery assembly comprising:
(a) a housing, (b) a plurality of electrochemical cells disposed within said housing, (c) means, disposed within said housing and coupled to said means for supplying DC electrical energy, for producing a reference voltage, (d) means, disposed within said housing, for determining when said electrochemical cells produce a terminal voltage exceeding a predetermined proportion of said reference voltage, (e) means, disposed within said housing, for detecting when a first electrochemical cell produces a voltage which is a predetermined amount smaller than a voltage produced by a second electrochemical cell, and (f) means, disposed within said housing and responsive to at least one of said means for determining and said means for detecting, for resettably interrupting said DC electrical energy supply to said plurality of electrochemical cells.
means for supplying direct current (DC) electrical energy to a battery assembly;
a battery assembly comprising:
(a) a housing, (b) a plurality of electrochemical cells disposed within said housing, (c) means, disposed within said housing and coupled to said means for supplying DC electrical energy, for producing a reference voltage, (d) means, disposed within said housing, for determining when said electrochemical cells produce a terminal voltage exceeding a predetermined proportion of said reference voltage, (e) means, disposed within said housing, for detecting when a first electrochemical cell produces a voltage which is a predetermined amount smaller than a voltage produced by a second electrochemical cell, and (f) means, disposed within said housing and responsive to at least one of said means for determining and said means for detecting, for resettably interrupting said DC electrical energy supply to said plurality of electrochemical cells.
5. A battery assembly charging system in accordance with claim 4 wherein said plurality of electrochemical cells comprises at least two electrochemical cells in a series circuit arrangement and wherein said means for determining is further characterized by a comparator coupled to a voltage divider which is coupled to said series circuit arrangement of said electrochemical cells.
6. A battery assembly employing a predetermined chemistry system and capable of being recharged with a recharging current from a battery charger adapted to charge batteries employing a chemistry system of a type different than the predetermined chemistry system, characterized by:
a housing;
a plurality of electrochemical cells disposed within said housing;
means, disposed within said housing, for producing a reference voltage;
means, disposed within said housing, for determining when said electrochemical cells produce a terminal voltage exceeding a predetermined proportion of said reference voltage; and means, disposed within said housing and responsive to said means for determining, for interrupting the recharging current to said plurality of electrochemical cells.
a housing;
a plurality of electrochemical cells disposed within said housing;
means, disposed within said housing, for producing a reference voltage;
means, disposed within said housing, for determining when said electrochemical cells produce a terminal voltage exceeding a predetermined proportion of said reference voltage; and means, disposed within said housing and responsive to said means for determining, for interrupting the recharging current to said plurality of electrochemical cells.
7. A battery assembly in accordance with claim 6 further characterized by means, disposed within said housing, for detecting when a first electrochemical cell produces a voltage which is a predetermined amount smaller than a voltage produced by a second electrochemical cell.
8. A battery assembly in accordance with claim 6 wherein said plurality of electrochemical cells further comprises at least two electrochemical cells in a series circuit arrangement and wherein said means for determining is further characterized by a comparator coupled to a voltage divider which is coupled to said series circuit arrangement of said electrochemical cells.
9. A battery assembly employing a predetermined chemistry system and capable of being recharged with a recharging current from a battery charger adapted to charge batteries employing a chemistry system of a type different than the predetermined chemistry system, characterized by:
a housing;
a plurality of electrochemical cells disposed within said housing;
means, disposed within said housing, for detecting when a first electrochemical cell produces a voltage which is a predetermined amount smaller than a voltage produced by a second electrochemical cell; and means, disposed within said housing and responsive to said means for detecting, for resettably interrupting the recharging current to said plurality of electrochemical cells.
a housing;
a plurality of electrochemical cells disposed within said housing;
means, disposed within said housing, for detecting when a first electrochemical cell produces a voltage which is a predetermined amount smaller than a voltage produced by a second electrochemical cell; and means, disposed within said housing and responsive to said means for detecting, for resettably interrupting the recharging current to said plurality of electrochemical cells.
10. A battery assembly in accordance with claim 9 further characterized by:
means, disposed within said housing, for producing a reference voltage; and means, disposed within said housing, for determining when said electrochemical cells produce a voltage exceeding a predetermined proportion of said reference voltage.
means, disposed within said housing, for producing a reference voltage; and means, disposed within said housing, for determining when said electrochemical cells produce a voltage exceeding a predetermined proportion of said reference voltage.
11. A battery assembly in accordance with claim 9 wherein said plurality of electrochemical cells further comprises at least two electrochemical cells in a series circuit arrangement.
12. A battery assembly in accordance with claim 11 wherein said means for determining further comprises a comparator coupled to a voltage divider which is coupled to said series circuit arrangement of said electrochemical cells.
13. A battery assembly in accordance with claim 9 wherein said means for producing a reference voltage further comprises a zener diode.
14. A battery assembly in accordance with claim 9 wherein said means for interrupting further comprises resettable means for interrupting the recharging current.
15. A battery assembly employing a predetermined chemistry system and capable of being recharged with a recharging current from a battery charger adapted to charge batteries employing a chemistry system of a type different than the predetermined chemistry system, comprising:
a housing;
a plurality of electrochemical cells disposed within said housing;
means, disposed within said housing, for detecting when a first electrochemical cell produces a voltage which is a predetermined amount smaller than a voltage produced by a second electrochemical cell; and means, disposed within said housing and responsive to said means for detecting, for resettably interrupting the recharging current to said plurality of electrochemical cells.
a housing;
a plurality of electrochemical cells disposed within said housing;
means, disposed within said housing, for detecting when a first electrochemical cell produces a voltage which is a predetermined amount smaller than a voltage produced by a second electrochemical cell; and means, disposed within said housing and responsive to said means for detecting, for resettably interrupting the recharging current to said plurality of electrochemical cells.
16. A battery assembly in accordance with claim 15 further comprising means, disposed within said housing, for producing a reference voltage.
17. A battery assembly in accordance with claim 16 further comprising means, disposed within said housing, for determining when said electrochemical cells produce a voltage exceeding a predetermined proportion of said reference voltage.
18. A battery assembly in accordance with claim 16 wherein said means for producing a reference voltage further comprises a zener diode.
19. A battery assembly in accordance with claim 15 wherein the predetermined chemistry system further comprises a lithium electrode.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US07/374,373 US5017856A (en) | 1989-06-30 | 1989-06-30 | Battery charging system |
| US374,373 | 1989-06-30 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2034490A1 CA2034490A1 (en) | 1990-12-31 |
| CA2034490C true CA2034490C (en) | 1996-01-23 |
Family
ID=23476529
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002034490A Expired - Fee Related CA2034490C (en) | 1989-06-30 | 1990-06-08 | Battery charging system |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US5017856A (en) |
| EP (2) | EP0440756B1 (en) |
| KR (1) | KR940003003B1 (en) |
| AR (1) | AR245546A1 (en) |
| AT (1) | ATE157821T1 (en) |
| AU (1) | AU624255B2 (en) |
| BR (1) | BR9006822A (en) |
| CA (1) | CA2034490C (en) |
| DE (1) | DE69031382T2 (en) |
| ES (1) | ES2106034T3 (en) |
| FI (1) | FI911033A7 (en) |
| MX (1) | MX167300B (en) |
| WO (1) | WO1991000623A2 (en) |
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| JPH0192064U (en) * | 1987-12-10 | 1989-06-16 | ||
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-
1989
- 1989-06-30 US US07/374,373 patent/US5017856A/en not_active Expired - Lifetime
-
1990
- 1990-05-29 MX MX020923A patent/MX167300B/en unknown
- 1990-06-08 BR BR909006822A patent/BR9006822A/en not_active IP Right Cessation
- 1990-06-08 CA CA002034490A patent/CA2034490C/en not_active Expired - Fee Related
- 1990-06-08 KR KR1019910700225A patent/KR940003003B1/en not_active Expired - Fee Related
- 1990-06-08 FI FI911033A patent/FI911033A7/en unknown
- 1990-06-08 DE DE69031382T patent/DE69031382T2/en not_active Expired - Fee Related
- 1990-06-08 EP EP90910022A patent/EP0440756B1/en not_active Expired - Lifetime
- 1990-06-08 AT AT90910022T patent/ATE157821T1/en not_active IP Right Cessation
- 1990-06-08 ES ES90910022T patent/ES2106034T3/en not_active Expired - Lifetime
- 1990-06-08 AU AU58505/90A patent/AU624255B2/en not_active Ceased
- 1990-06-08 EP EP97101217A patent/EP0773618A3/en not_active Ceased
- 1990-06-08 WO PCT/US1990/003137 patent/WO1991000623A2/en not_active Ceased
- 1990-06-29 AR AR90317282A patent/AR245546A1/en active
Also Published As
| Publication number | Publication date |
|---|---|
| EP0773618A3 (en) | 1997-06-04 |
| MX167300B (en) | 1993-03-15 |
| EP0440756A1 (en) | 1991-08-14 |
| EP0440756A4 (en) | 1992-12-09 |
| AU624255B2 (en) | 1992-06-04 |
| BR9006822A (en) | 1991-08-06 |
| ES2106034T3 (en) | 1997-11-01 |
| AU5850590A (en) | 1991-01-17 |
| KR920702056A (en) | 1992-08-12 |
| WO1991000623A2 (en) | 1991-01-10 |
| DE69031382T2 (en) | 1998-01-15 |
| EP0773618A2 (en) | 1997-05-14 |
| CA2034490A1 (en) | 1990-12-31 |
| DE69031382D1 (en) | 1997-10-09 |
| FI911033A0 (en) | 1991-02-28 |
| FI911033A7 (en) | 1991-02-28 |
| EP0440756B1 (en) | 1997-09-03 |
| WO1991000623A3 (en) | 1991-04-04 |
| AR245546A1 (en) | 1994-01-31 |
| US5017856A (en) | 1991-05-21 |
| KR940003003B1 (en) | 1994-04-09 |
| ATE157821T1 (en) | 1997-09-15 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request | ||
| MKLA | Lapsed |