CA2032803A1 - Process for the preparation of a polypropylene molding composition - Google Patents

Process for the preparation of a polypropylene molding composition

Info

Publication number
CA2032803A1
CA2032803A1 CA002032803A CA2032803A CA2032803A1 CA 2032803 A1 CA2032803 A1 CA 2032803A1 CA 002032803 A CA002032803 A CA 002032803A CA 2032803 A CA2032803 A CA 2032803A CA 2032803 A1 CA2032803 A1 CA 2032803A1
Authority
CA
Canada
Prior art keywords
preparation
molding composition
polymerization
stage
prepared
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002032803A
Other languages
French (fr)
Other versions
CA2032803C (en
Inventor
Michael Schreck
Andreas Winter
Walter Spaleck
Hartmut Kondoch
Jurgen Rohrmann
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Basell Polyolefine GmbH
Original Assignee
Hoechst AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hoechst AG filed Critical Hoechst AG
Publication of CA2032803A1 publication Critical patent/CA2032803A1/en
Application granted granted Critical
Publication of CA2032803C publication Critical patent/CA2032803C/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/06—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
    • C08F297/08—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
    • C08F297/083—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins the monomers being ethylene or propylene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C08L23/14—Copolymers of propene
    • C08L23/142—Copolymers of propene at least partially crystalline copolymers of propene with other olefins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/16—Ethene-propene or ethene-propene-diene copolymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2308/00—Chemical blending or stepwise polymerisation process with the same catalyst
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2314/00—Polymer mixtures characterised by way of preparation
    • C08L2314/06—Metallocene or single site catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Graft Or Block Polymers (AREA)
  • Polymerisation Methods In General (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

A propylene block copolymer having good flow properties and a very good low temperature impact strength is obtained in a high yield if a catalyst which consists of a chiral metallocene, containing a bridge, of the for-mula I
(see formula I) and an aluminoxane is used for the polymerization of propylene and the comonomers.
The polymerization is carried out in two stages, a crystalline propylene polymer in liquid monomers being prepared in the first stage and a copolymer in the gas phase being prepared in the second stage.
CA002032803A 1989-12-21 1990-12-20 Process for the preparation of a polypropylene molding composition Expired - Lifetime CA2032803C (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE3942364A DE3942364A1 (en) 1989-12-21 1989-12-21 METHOD FOR PRODUCING A POLYPROPYLENE MOLDING MATERIAL
DEP3942364.6 1989-12-21

Publications (2)

Publication Number Publication Date
CA2032803A1 true CA2032803A1 (en) 1991-06-22
CA2032803C CA2032803C (en) 2002-06-04

Family

ID=6396072

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002032803A Expired - Lifetime CA2032803C (en) 1989-12-21 1990-12-20 Process for the preparation of a polypropylene molding composition

Country Status (7)

Country Link
EP (1) EP0433990B1 (en)
JP (1) JP3124558B2 (en)
AU (1) AU647433B2 (en)
CA (1) CA2032803C (en)
DE (2) DE3942364A1 (en)
ES (1) ES2072361T3 (en)
ZA (1) ZA9010266B (en)

Families Citing this family (39)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5391629A (en) * 1987-01-30 1995-02-21 Exxon Chemical Patents Inc. Block copolymers from ionic catalysts
DE3942365A1 (en) * 1989-12-21 1991-06-27 Hoechst Ag METHOD FOR PRODUCING A POLYPROPYLENE MOLDING MATERIAL
DE3942366A1 (en) * 1989-12-21 1991-06-27 Hoechst Ag METHOD FOR PRODUCING A SYNDIOTACTIC PROPYLENE COPOLYMER
EP0457455B2 (en) † 1990-05-14 2008-07-02 Union Carbide Chemicals & Plastics Technology Corporation Polymer compositions
ES2090209T3 (en) 1990-11-12 1996-10-16 Hoechst Ag METALLOCENES WITH LIGANDS BASED ON SUBSTITUTED INDENYL DERIVATIVES IN POSITION 2, PROCEDURE FOR THEIR PREPARATION AND USE AS CATALYSTS.
USRE39561E1 (en) 1990-11-12 2007-04-10 Basell Polyoefine Gmbh Metallocenes containing ligands of 2-substituted indenyl derivatives, process for their preparation, and their use as catalysts
TW300901B (en) * 1991-08-26 1997-03-21 Hoechst Ag
DE4130429A1 (en) * 1991-09-13 1993-03-18 Basf Ag METHOD FOR PRODUCING MULTI-PHASE BLOCK COPOLYMERISATS BASED ON ALK-1-ENEN
US5932669A (en) * 1991-11-30 1999-08-03 Targor Gmbh Metallocenes having benzo-fused indenyl derivatives as ligands, processes for their preparation and their use as catalysts
US5830821A (en) * 1991-11-30 1998-11-03 Targor Gmbh Process for olefin preparation using metallocenes having benzo-fused indenyl derivatives as ligands
DE59206948D1 (en) * 1991-11-30 1996-09-26 Hoechst Ag Metallocenes with benzo-fused indenyl derivatives as ligands, processes for their preparation and their use as catalysts
TW309523B (en) * 1991-11-30 1997-07-01 Hoechst Ag
TW259804B (en) * 1992-01-18 1995-10-11 Hoechst Ag
JPH05230321A (en) * 1992-02-21 1993-09-07 Mitsubishi Petrochem Co Ltd Thermoplastic polymer composition
DE59308494D1 (en) * 1992-08-03 1998-06-10 Targor Gmbh Process for the preparation of an olefin polymer using metallocenes with specially substituted indenyl ligands
USRE39156E1 (en) 1992-08-15 2006-07-04 Basell Polyolefine Gmbh Process for the preparation of polyolefins
US6156844A (en) * 1993-01-11 2000-12-05 Mitsui Chemicals Inc Propylene polymer compositions containing a propylene homo- or co-polymer obtained using a bridged metallocene catalyst and another propylene homo- or co-polymer
KR100314971B1 (en) * 1993-05-25 2002-07-03 엑손모빌 케미칼 패턴츠 인코포레이티드 Supported Metallocene Catalyst System for Olefin Polymerization, Its Manufacturing Method and Application
DE4317654A1 (en) * 1993-05-27 1994-12-01 Basf Ag Statistical copolymers of propylene
DE4317655A1 (en) * 1993-05-27 1994-12-01 Basf Ag Multi-phase block copolymers of propylene
CA2157399C (en) * 1994-04-11 2003-04-08 Takashi Ueda Process for preparing propylene polymer composition and propylene polymer composition
KR100388331B1 (en) * 1994-04-11 2003-10-11 미쓰이 가가쿠 가부시키가이샤 Process for producing propylene polymer composition and propylene polymer composition
JP3357186B2 (en) 1994-07-14 2002-12-16 三菱化学株式会社 Method for producing propylene block copolymer
IT1273660B (en) * 1994-07-20 1997-07-09 Spherilene Srl PROCEDURE FOR THE PREPARATION OF AMORPHOUS PROPYLENE POLYMERS
JP3275223B2 (en) * 1994-09-22 2002-04-15 科学技術振興事業団 Polypropylene-b-poly (ethylene-co-propylene) and method for producing the same
IT1270125B (en) * 1994-10-05 1997-04-28 Spherilene Srl PROCESS FOR THE (CO) POLYMERIZATION OF OLEFINE
IT1274469B (en) * 1995-05-11 1997-07-17 Spherilene Spa DYNAMICALLY VULCANIZABLE POLYOLEFINIC COMPOSITIONS
EP0816394B1 (en) * 1996-06-26 2002-01-30 BP Chemicals S.N.C. Process for polymerising ethylene in the gas phase
DE69713343T2 (en) * 1996-09-04 2002-10-10 Exxonmobil Chemical Patents Inc., Baytown IMPROVED PROPYLENE POLYMERS FOR ORIENTED FILMS
TW442528B (en) * 1996-12-02 2001-06-23 Chisso Corp Polypropylene composition
EP1022308B1 (en) * 1997-09-18 2004-01-07 Chisso Corporation Polypropylene composition
KR20010030929A (en) 1998-08-04 2001-04-16 고토 기치 Propylene//propylene/olefin block copolymer and process for producing the same
JP4688247B2 (en) * 1998-08-25 2011-05-25 株式会社プライムポリマー Propylene resin composition, production method and use thereof
JP4582911B2 (en) * 1998-10-19 2010-11-17 チッソ石油化学株式会社 Propylene / ethylene block copolymer
US7732530B2 (en) * 2002-06-12 2010-06-08 Basell Polyolefine Gmbh Flexible propylene copolymer compositions having a high transparency
EP1523509A1 (en) * 2002-07-24 2005-04-20 Basell Polyolefine GmbH At least two-stage process for preparing propylene polymer compositions
JP4097581B2 (en) * 2003-08-22 2008-06-11 三井化学株式会社 Propylene copolymer
JP5097366B2 (en) * 2005-07-29 2012-12-12 日本ポリプロ株式会社 Propylene block copolymer
EP1911779B1 (en) 2005-07-29 2012-12-19 Japan Polypropylene Corporation Process for production of propylene block copolymer

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3331877A1 (en) * 1983-09-03 1985-03-21 Hoechst Ag, 6230 Frankfurt METHOD FOR PRODUCING A POLYPROPYLENE MOLD
US4882380A (en) * 1987-07-07 1989-11-21 Union Carbide Chemicals And Plastics Company Inc. Process for the production of impact polypropylene copolymers
IL89525A0 (en) * 1988-03-21 1989-09-10 Exxon Chemical Patents Inc Silicon-bridged transition metal compounds
JP2818199B2 (en) * 1989-06-12 1998-10-30 三井化学株式会社 Syndiotactic polypropylene resin composition and method for producing the same
IL95097A0 (en) * 1989-08-23 1991-06-10 Himont Inc Thermoplastic olefin polymer and its preparation
DE3942365A1 (en) * 1989-12-21 1991-06-27 Hoechst Ag METHOD FOR PRODUCING A POLYPROPYLENE MOLDING MATERIAL
DE3942363A1 (en) * 1989-12-21 1991-06-27 Hoechst Ag METHOD FOR PRODUCING A POLYPROPYLENE MOLDING MATERIAL

Also Published As

Publication number Publication date
AU647433B2 (en) 1994-03-24
CA2032803C (en) 2002-06-04
DE3942364A1 (en) 1991-06-27
ZA9010266B (en) 1991-10-30
JP3124558B2 (en) 2001-01-15
DE59008936D1 (en) 1995-05-24
EP0433990A3 (en) 1992-09-02
EP0433990A2 (en) 1991-06-26
AU6830190A (en) 1991-06-27
ES2072361T3 (en) 1995-07-16
JPH06206921A (en) 1994-07-26
EP0433990B1 (en) 1995-04-19

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Legal Events

Date Code Title Description
EEER Examination request
MKLA Lapsed
MKEC Expiry (correction)

Effective date: 20121202