CA2026665A1 - Method and arrangement for the disposal of gas space contents of large-volume containers in the case of components which load the environment - Google Patents

Method and arrangement for the disposal of gas space contents of large-volume containers in the case of components which load the environment

Info

Publication number
CA2026665A1
CA2026665A1 CA002026665A CA2026665A CA2026665A1 CA 2026665 A1 CA2026665 A1 CA 2026665A1 CA 002026665 A CA002026665 A CA 002026665A CA 2026665 A CA2026665 A CA 2026665A CA 2026665 A1 CA2026665 A1 CA 2026665A1
Authority
CA
Canada
Prior art keywords
tank
gas
cooling trap
contents
gas space
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
CA002026665A
Other languages
French (fr)
Inventor
Peter Weil
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Publication of CA2026665A1 publication Critical patent/CA2026665A1/en
Abandoned legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B67OPENING, CLOSING OR CLEANING BOTTLES, JARS OR SIMILAR CONTAINERS; LIQUID HANDLING
    • B67DDISPENSING, DELIVERING OR TRANSFERRING LIQUIDS, NOT OTHERWISE PROVIDED FOR
    • B67D7/00Apparatus or devices for transferring liquids from bulk storage containers or reservoirs into vehicles or into portable containers, e.g. for retail sale purposes
    • B67D7/04Apparatus or devices for transferring liquids from bulk storage containers or reservoirs into vehicles or into portable containers, e.g. for retail sale purposes for transferring fuels, lubricants or mixed fuels and lubricants
    • B67D7/0476Vapour recovery systems
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • B01D53/0407Constructional details of adsorbing systems
    • B01D53/0415Beds in cartridges
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D90/00Component parts, details or accessories for large containers
    • B65D90/22Safety features
    • B65D90/30Recovery of escaped vapours
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2253/00Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10Inorganic adsorbents
    • B01D2253/102Carbon
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/70Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
    • B01D2257/708Volatile organic compounds V.O.C.'s

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Analytical Chemistry (AREA)
  • Filling Or Discharging Of Gas Storage Vessels (AREA)
  • Treating Waste Gases (AREA)
  • Vaporization, Distillation, Condensation, Sublimation, And Cold Traps (AREA)
  • Electrical Discharge Machining, Electrochemical Machining, And Combined Machining (AREA)
  • Catching Or Destruction (AREA)
  • Sampling And Sample Adjustment (AREA)
  • Processing Of Solid Wastes (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)

Abstract

Abstract:

A solution is to be provided by means of a method and an arrangement for disposal of the gas space contents of large-volume containers, such as tanks or the like, when emptying one tank and filling another tank with materials whose gas phase loads the environment, is harmful to the environment or is to be reclaimed as valuable material, wherein the gas space of the tank being emptied is filled with a substitute material and the gas contents of the tank being filled are directed via a cooling trap, by means of which solution the gas space contents can be disposed of in a simple manner, wherein the solution is to be effected in such a way that the arrangements and devices which are utilized have the smallest possible volume and are simple to manage, in that they can also be used in conventional tank vehicles regardless of whether or not the latter are road vehicles or track-bound vehicles.
This is achieved in that the cooling trap is operated with a liquid inert gas, wherein the inert gas operating the cooling trap is used as substitute material for filling the tank being emptied.
A single drawing is disclosed.

Description

2~2~
liETHOD AND ARRANGEMENT FOR THE DISPOSAL OF GAS SPACE CONTENTS
OF LARGE-VOLUME CONTAINERS IN THE CASE OF COMPONENTS WHICH
LOAD THE ENVIRONMENT

The invention is directed to a method and an arrangement for disposing of gas space contents of large-volume containers such as tanks or the like when emptying one tank and filling another tank with materials whose gas phase loads and is harmful to the environment or is to be reclaimed as valuable material, wherein the gas space of the tank being emptied is filled with a substitute material and the gas contents of the tank being filled are guided via a cooling trap.
Chemicals are often not only stored in tanks but also transported by means of tank cars, i.e. from the producer to the consumer, from the producer to intermediate storage and from there to the consumer or in another manner, wherein the operators of such tank vehicles are instructed to transport very different products with their vehicles. When such a tank is emptied, volatile materials form in its gas space, often the gas phase of the corresponding products, wherein this gas phase escapes, at the latest, when refilling the tank. It works out in practice that the tanks are opened frequently while being transported in the empty state, so that the surrounding air blows out the harmful gas phase of the components which are then given off into the environment. If the emptying is not complete, it can happen during the refilling of the tank that the product with which the tank is subsequently filled combines in a dangerous way with the gas phase of the previously transported product; this can be not only toxic but also e.g. highly explosive.
On the other hand, the material flowing into the tank being filled drives out the corresponding gas volume from this tank, which gas volume must then escape if the filling is not effected against a developing counterpressure; the so-called gas displacement method is used for this purpose, e.g. when filling gasoline tanks, i.e. the expelled gas volume is redirected into the gas space of the tank vehicle being emptied in order to ensure uniformity of pressure. This gas ~2~

displacement method makes sense so long as a single material is being transported by the tank vehicle.
However, if the product is changed, and this is most frequently the case, since transport containers are rarely always used for the same medium, the gas displacement method no longer works. The gaseous material would contaminate the new material to be transported in the transport container. In the worst case, chemical reactions (explosions) occur. For this reason, the transport containers are rinsed or neutralized when dealing with water-soluble components. This is usually not possible with organic solvents, since the latter are frequently not mixable with water. Moreover, this results in contaminated water which must be disposed of in turn in a costly manner.
This creates the opportunity for criminal action. The transporter will employ the gas displacement method during the emptying process at the location of the client, but leaves open the dome cover in transit so that the head wind removes the gas from the tank. This is strictly prohibited for reasons of environmental protection. However, there is no usable solution, since rinsing with water is usually unsuccessful. Thus, in the case of combustible liquids, an explosive mixture of air and gas can occur which can lead to catastrophe in the event of a spark.
It is the object of the invention to provide a solution with which the gas space contents can be disposed of in a simple manner, wherein the solution is to be effected in such a way that the devices which are used have the smallest possible volume and are simple to manage and can also be used with conventional tank vehicles regardless of whether the latter are road vehicles or rail-bound vehicles.
This object is met, according to the invention, in that the cooling trap is operated with a liquid inert gas, wherein the inert gas operating the cooling trap is used as substitute material for filling the tank being emptied.

2 ~ 6 ~

The proposed filling of the gas space of the tank being emptied with a substitute material on the one hand and the disposal of the gas volume of the tank to be filled via a cooling trap on the other hand has the special advantage that it makes no difference for the tank vehicle being emptied whether or not the product is changed when next used. The substitute material makes the operation of the tank vehicle independent of the transported material. On the other hand, by means of providing a cooling trap, the product which is guided via the cooling trap and then condenses can be supplied directly to the consumer again, so that there is no discrepancy in volume for the consumer with respect to the quantities agreed upon. As in the gas displacement method, emptying and filling can be effected without the occurrence of pressure differences in this case as well.
Moreover, the directing of gases via a cooling trap has the advantage that these materials are condensed out in the cooling trap and can possibly be placed at the disposal of the consumer again, since he shares in the cost of these materials in practice. It is also possible to receive the materials exiting via the cooling trap in containers having a very small volume and to use them for other purposes. A number of materials can be utilized as substitute materials, including in some cases surrounding air entering the tanks.
A method is known from DE-A-12 51 233 by means of which industrial scale vapors can be reclaimed, wherein the vapors are guided via cooling stages. This text does not describe the type of filling or the volumes involved when reclamation is effected, rather the overall disclosure concerns the surrounding air. The reclamation of a gasoline-vapor mixture is shown also in DE-A-23 37 055, in which a gasoline-air mixture is likewise cooled in such a way that the hydrocarbons contained therein are condensed and frozen out.
The special advantage of the present invention consists in that the inert gas with which the gas space is filled is made available as coolant or, conversely, in that the coolant 2 ~ 6 3 --''I--is utilized, after the gas volume has cooled, as an inert gas which fills up the gas space according to corresponding evaporation. In so doing, the invention makes use of the understanding that an environmentally friendly inert gas coolant increases extremely in volume when evaporated.
It is advantageous to use nitrogen as the inert gas operating the cooling trap and filling the gas space in the gas phase.
The use of nitrogen is particularly advantageous, since this is often available in liquid form and the gaseous phase effects an increase in volume from approximately 1 to 800 compared to the liquid phase. Moreover, nitrogen prevents explosions and is also completely harmless to the environment.
Since nitrogen atmospheres do not enter into chemical reactions with air under normal conditions, peroxide formation and the like can no longer come about e.g. with solvents which react with air.
The invention also provides that the cooling trap for the precipitation and condensation of the expelled gases is operated in a temperature range of -10 to 50C. The utilized devices can be constructed so as to be comparatively small with respect to volume in this temperature range, wherein the selected temperatures ensure that e.g. at least 80~ of the solvent cools out below its dew point and can accordingly be reclaimed as condensate.
The highly volatile portion which is not included can then be guided e.g. via an activated charcoal system which can likewise be constructed so as to have a small volume, as is likewise provided according to the invention.
If nitrogen is available in the area of the tanks being processed, the invention likewise provides that the cooling trap is used as a partial evaporator for the substitute gas, particularly for the liquid nitrogen, i.e. the operating medium of the cooling trap is simultaneously the substitute gas.

, The invention also provides an arrangement for carrying out the method which is distinguished by a cooling trap with condensate collector and residual gas cleaner.
An activated charcoal filter, for example, can be used as residual gas cleaner according to the invention.
As already stated in the beginning, different materials are often transported successively in a tank vehicle, so that different residual gas compositions also come about. In this respect, the invention provides that the arrangement comprises a plurality of separately connectable filters for different residual gases.
The invention is explained in more detail in the following by way of example with the aid of a drawing. The single drawing shows a basic diagram of the arrangement according to the invention.
The arrangement, designated in general by 1, substantially shows the connection between a first tank 2 of a tank vehicle 3 and a second tank 4, wherein the outlet connection piece 5 of the tank 2 is connected with the filling connection piece 6 of the tank 4 via a filling line 7.
A eooling trap, designated in general by 8, is provided in addition; liquid nitrogen (N2) flows through its cooling eoils, shown in a sehematie manner, whieh is indieated by arrow 9. The liquid nitrogen whieh heats up in the cooling trap 8 is gasified and enters in the head area 10 into the gas spaee of the tank 2 when the latter is emptied, the gas spaee being designated in general by 11.
The gas eseaping in the gas space 12 of the tank 4 to be filled is directed via a line 13 into the cooling space of the cooling trap 8 and condensed in the latter, and the condensate thus obtained is guided again via a condensate line 14 to the product line 7 and accordingly flows back into the tank 4.
Uncondensed residual gas is given off into the environment via a line 15, wherein an activated charcoal filter 16 can be provided.

-6~

The control and regulating of the entire arrangement is effected in such a way that no pressure difference prevails between the gas spaces 11 and 12 of the two tanks 2 and 4, i.e. the evaporating nitrogen can be supplied either in excess, when greater volumes are needed than would be necessary per se by the operation of the cooling trap, or in deficit, i.e. gasified N2 not required in the gas space 11 is then given off into the environment.
Also indicated is the possibility, designated in general by 16', to provide a plurality of cartridges with different filter fillings according to the material to be processed; the uncondensed residual gas then enters via the line 15 into the respective cartridge 16 needed at the time.
Naturally, the described embodiment example of the invention can be modified in many respects without departing from the basic idea. Thus, the invention is not limited to the spatial arrangement of the cooling trap 8, which is only shown schematically here; this cooling trap 8 can be provided at the face as a securely installed structural component part in the area of the tank 4 and as an integrated component part of the tank vehicle 3 and the like.

Claims (6)

THE EMBODIMENTS OF THE INVENTION IN WHICH AN EXCLUSIVE
PROPERTY OR PRIVILEGE IS CLAIMED ARE DEFINED AS FOLLOWS:
1. Arrangement for the disposal of the contents of the gas spaces (11, 12) of tanks (2, 4) when emptying one tank and filling another tank with materials whose gas phase loads and is harmful to the environment or is to be reclaimed as valuable material, wherein the contents of the gas space (11 and 12, respectively) of the tank (2 and 4, respectively) being emptied are filled with a substitute material and the contents of the gas space (12 and 11, respectively) of the tank (4 and 2, respectively) being filled are directed via a cooling trap (8), characterized in that the cooling trap (8) can be operated with a liquid inert gas from at least one reservoir (9) assigned to the cooling trap (8), wherein the inert gas operating the cooling trap is used as substitute material for filling the tank being emptied.
2. Arrangement according to claim 1, characterized in that the cooling trap (8) is constructed as a device operated by means of nitrogen.
3. Arrangement according to claim 1 or 2, characterized in that Page 11a the cooling trap (8) for the precipitation of condensing gas contents of the expelled gases is designed for a temperature range of -10 to -50°C.
4. Arrangement according to one of the preceding claims, characterized by a cooling trap (8) with condensate collector (14) and residual gas cleaner.
5. Arrangement according to one of the preceding claims, characterized by an activated charcoal filter for the residual gas.
6. Arrangement according to one of the preceding claims, characterized by a plurality of separately connectable filters (16) for different residual gases.
CA002026665A 1989-02-10 1990-02-06 Method and arrangement for the disposal of gas space contents of large-volume containers in the case of components which load the environment Abandoned CA2026665A1 (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
DEP3903938.2 1989-02-10
DE3903938A DE3903938A1 (en) 1989-02-10 1989-02-10 METHOD FOR DISPOSING THE GAS SPACE CONTENT OF LARGE-VOLUME CONTAINERS FOR ENVIRONMENTALLY DANGEROUS INGREDIENTS
PCT/EP1990/000192 WO1990009343A1 (en) 1989-02-10 1990-02-06 Process and device for evacuating the content of gas spaces of large containers containing pollutant substances
EPPCT/EP90/00192 1990-02-06

Publications (1)

Publication Number Publication Date
CA2026665A1 true CA2026665A1 (en) 1990-08-11

Family

ID=6373771

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002026665A Abandoned CA2026665A1 (en) 1989-02-10 1990-02-06 Method and arrangement for the disposal of gas space contents of large-volume containers in the case of components which load the environment

Country Status (14)

Country Link
EP (1) EP0409945B1 (en)
JP (1) JPH03503875A (en)
AT (1) ATE98203T1 (en)
AU (1) AU629902B2 (en)
CA (1) CA2026665A1 (en)
DE (2) DE3903938A1 (en)
DK (1) DK0409945T3 (en)
ES (1) ES2047316T3 (en)
FI (1) FI93637C (en)
HU (1) HU208289B (en)
NO (1) NO176015C (en)
RO (1) RO105895B1 (en)
RU (1) RU1806084C (en)
WO (1) WO1990009343A1 (en)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT1289562B1 (en) * 1995-10-05 1998-10-15 Oliviero Pettazzoni METHOD FOR THE RECOVERY OF GASEOUS RESIDUES IN REFUELING SYSTEMS AND IN FUEL TANKS AND RELATED EQUIPMENT.
FR2740436B1 (en) * 1995-10-27 1998-01-09 Cochery Bourdin Chausse METHOD AND APPARATUS FOR TREATING RELEASED VENTS FROM TANK STORAGE OF LIQUID PRODUCTS CONTAINING VOLATILE COMPONENTS
FR2799389B1 (en) * 1999-10-12 2001-12-07 Sofrance Sa PROCESS AND DEVICE FOR TREATING VAPORS EMITTED DURING THE PUMPING OF LIQUIDS CONTAINING VOLATILE COMPOUNDS DURING CLEANING OR FILLING OPERATIONS.
FR2827268B1 (en) * 2001-07-12 2004-03-26 Sellco Sa FUEL STORAGE INSTALLATION IN A SERVICE STATION AND METHOD FOR FILLING A SERVICE STATION TANK
DE102005019971B4 (en) * 2005-04-27 2007-03-01 Rainer Boeck Method and device for emptying and degassing mobile tanks
GB0714399D0 (en) * 2007-07-24 2007-09-05 Vapasava Vr Ltd System and method of petrol vapour recovery
EP2524894B1 (en) 2011-05-14 2013-07-03 Dorincourt S.A. Method for emptying the residue in tank facilities
GB2536928B (en) 2015-03-31 2017-08-09 Risbridger Ltd A vent system for a fuel storage tank
CN109386736A (en) * 2017-08-09 2019-02-26 中国石油化工股份有限公司 The collection method of chemicals shipment process Volatile Gas

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1251233B (en) * 1965-01-14
US3581782A (en) * 1968-12-23 1971-06-01 Burdsall & Ward Co Vapor emission control system
US3972201A (en) * 1975-01-29 1976-08-03 Process Products, Inc. Vapor recovery system
FR2554212B1 (en) * 1983-11-02 1989-01-06 Gallo Michel PROCESS FOR THE DRAINING OF TANKS CONTAINING LIQUEFIED GAS FROM PETROLEUM AND / OR THE CHEMICAL OR PETROCHEMICAL INDUSTRY, PLANT FOR IMPLEMENTING THIS PROCESS AND ITS APPLICATIONS
FR2561751B1 (en) * 1984-03-23 1988-11-10 Air Liquide TANK PURGE AND INERTAGE PROCESS AND INSTALLATION
DE3713035A1 (en) * 1987-04-16 1988-10-27 Kurt W Ing Grad Hofmann Tanker

Also Published As

Publication number Publication date
RU1806084C (en) 1993-03-30
WO1990009343A1 (en) 1990-08-23
DK0409945T3 (en) 1994-02-14
FI93637B (en) 1995-01-31
DE3903938A1 (en) 1990-08-23
AU629902B2 (en) 1992-10-15
NO903432L (en) 1990-08-23
EP0409945A1 (en) 1991-01-30
NO176015C (en) 1995-01-18
HUT55315A (en) 1991-05-28
HU208289B (en) 1993-09-28
EP0409945B1 (en) 1993-12-08
NO903432D0 (en) 1990-08-06
HU901530D0 (en) 1991-03-28
ES2047316T3 (en) 1994-02-16
FI904839A0 (en) 1990-10-01
AU4965890A (en) 1990-09-05
FI93637C (en) 1995-05-10
DE59003767D1 (en) 1994-01-20
NO176015B (en) 1994-10-10
JPH03503875A (en) 1991-08-29
RO105895B1 (en) 1993-01-30
ATE98203T1 (en) 1993-12-15

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Legal Events

Date Code Title Description
FZDE Discontinued