CA2026530C - Graphic architectural glass - Google Patents

Graphic architectural glass Download PDF

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Publication number
CA2026530C
CA2026530C CA 2026530 CA2026530A CA2026530C CA 2026530 C CA2026530 C CA 2026530C CA 2026530 CA2026530 CA 2026530 CA 2026530 A CA2026530 A CA 2026530A CA 2026530 C CA2026530 C CA 2026530C
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CA
Canada
Prior art keywords
glass
ink
polyurethane
architectural
laminate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CA 2026530
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French (fr)
Other versions
CA2026530A1 (en
Inventor
Claudio Cesar
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Individual
Original Assignee
Individual
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Publication date
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Priority to CA 2026530 priority Critical patent/CA2026530C/en
Publication of CA2026530A1 publication Critical patent/CA2026530A1/en
Application granted granted Critical
Publication of CA2026530C publication Critical patent/CA2026530C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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  • Joining Of Glass To Other Materials (AREA)
  • Laminated Bodies (AREA)

Abstract

A graphic glass laminate is created by heat-laminating a printed sheet of extruded polyurethane between two plates of glass, using normal autoclave process. The polyurethane interlayer bonds directly to the glass with very little distortion to the color or registration of the printed ink.
The resulting composite is extremely strong and safe, having better structural and superior heat-resistant characteristics compared to regular safety glass and may contain an extremely artistic and decorative look. The interlayer graphics can be made "light-fast" when proper inks are used. Transparent and translucent inks may be employed and the glass may be used with different lighting techniques, such as edge-lighting.

Description

ii ~~ V
Ca~,~'HIC ~1RGH~TIrGTCTRFaL G~SS
TEL O~ INVE'NfION
The present vplnposition and method pertains to laminated architect~uxal glass. l~ora speoifically, it pertains to lama.nated architectural glass having a decorative interlayer.
~~G;ROL11~ ~ .~T.~EN~ ~~~~I~ION gF_ "BFI R 4 Laminated glass is mast ac~mmc~nly found in automotive windshields and architectural ~au~,lding glass. 7Cwo outer sheets of glass are vulcanized to an interlayer, usually composed aE polyvinyl buvyral. polyvinyl butyral is commonly used as an interlayer for safety glass and ~.s used in sheet foam, heat~laminated be~.w~:ezx glass sheets under ."
pressure. However, polyvinyl. butyral (1~~'~3) compounds are vexy sensitive to warm temperatures, humidity, and most solvents prior to lamination, sa that using them with any combination of paint or ink directly applied is al~nast impossible.
There has br~en very little use of daCaxat~.ve interlayer materials in order to create architectural glass graphics for applications, such as windaw~ and signage. Printing directly onto the glass and 'then laminating w~,th PVI3 is a method currently used, however, it is cumbersome arid ineffective because the ~,ntsrlayer is laminating to the ink film and not bonding directly to the glass in areas where the paint or ink covers the PvB interlayer. This me~thcra, therefore, works only when small areas of glass are used for a graphic display. Another method used to Create glass graphics is the vinyl-stencil method. Cutout vinyJ.s are first adhexed to the glass and 'then ~.aminat~:d with pVB. inhere is same success with this process, however, it is very Costly and time-., ~,~.
2~~~~~~~
consuming and there is a very high failure rate with large surface areas covered by the graphic. Also, most polyvinyl.
stenciling materials are not l~,ght-fast.
It is known to replaaa thc~ polyvinyl butyral interlayeac with a composition of polyurethane as taught in U.S. Patent 3,509,015. In this instance, the polyurethane int~rlayer is cast in place from a pourable resin. Decorative affects may be obtained by CoxArix~~J the resin prir~r to lamination.
U.S. Patent 3,64p,79~i discloses a method of applying a colored self-vulcanizing paste onto a cellular foam plastic interlayer, which ~,s then mechanically sandwiched between two pieces of glass. The paste must be~hand applied raith a knife, or be applied by stamping ox molding processes, app~.ied directly to the cellular foam plastic interlayer.
This construction limits the ma.bs production posaibilities.
As outlined above, the varicaus processes which have been used to create a graphic Qr cr~lox imac~a sealed between layers of glass rec,~uire heavy or large machinery and, in some cases, very expensive die-cutting materials. Most of the processes must be maintained in 'temperature and humidity-controlled environments which axe required for handling the pa~.xv~,nyJ.
butyral materials. zn addition, only s~mald, areas where the graphic covers tha glass are possible, the coloring materials are not lightTfast and a very high failure rate usually occurs. Where the znatexials are not molecularly fused (heat laminated), the compos~,te is often not permanent.
rya one before has been a'bJ.e to achieve mass production printing on a transparent interlayar fused bx heat lamination between sheets of glass to yi~:~.d ~ unitary, permanent, graphic panel.
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To overCOm~: the problems in the prior art described above, a decorative laminated glass has been devised from the composition and method as follows. It has been found that mass production printing processes, such as automated silk screening, can be used to apply non-solvent-based inks directly on sheet polyurethane. Sheet polyurethane is extremely easy to handle and will accept a wide variety of inks. Because of this ease of handling, printing of inks on the polyurethane interlayer can be separated from the laminating process, both in time and distance. The printed polyurethane sheets can easily be rolled up for storage or shipment to the glass production site. These factors make the instant process both convenient and inexpensive, since handling and transporting the glass components is kept to a minimum.
The printed polyurethane interlayer is then heat-laminated between two pieces of glass using standard autoclave laminating procedures without the use of adhesives. The polyurethane interlayer bonds directly to the glass with very little distortion to the color or registration of the printed ink. The resulting composite is extremely strong and safe, having better structural and superior heat resistance characteristics compared to polyvinyl butyral safety glass, and may also contain an extremely artistic and decorative look.
Furthermore, the interlayer graphics can be made "light-fast"
when proper inks are used. Transparent and translucent inks may be employed so that the glass may be used with different lighting techniques, such as edge-lighting. The results are both permanent, inexpensive, and visually unique.
Thus the invention provides an architectural glass laminate, comprising:
a. two sheets of rigid, transparent material, b. an interlayer sheet of extruded polyurethane, heat-laminated between said sheets of rigid material, and c. non-solvent based ink containing solid pigments printed on said polyurethane interlayer, prior to lamination, to provide a permanent graphic panel of unitary construction.
The invention further provides a method of manufacturing an architectural glass graphic panel, comprising the steps of:
a. printing a graphic onto a flexible sheet of extruded polyurethane using non-solvent based inks containing solid pigments, and b. heat-laminating said polyurethane between two sheets of glass using autoclave laminating procedures without the use of adhesives.
It is important that the ink or paint be chemically compatible and self-adhesive to the urethane sheet material.
It may be applied by brushing, spraying or printing to the extruded urethane interlayer. The paint or ink film may be 3a ~~~~J~ ~~~~
dried by air, or ;force-dried by ultraviolet light using light-GUrsd ink. The urethane interlayer may 1~e placed between glass or polycarbonate, or a combination of both.
,~ variety of uses are possible gor th3.s new graphic glass. Far instance, one color mar be applied to create a graphic effect to resemble sandblasting or etching. Also, by using a faux-color praaess, a photographic effect can be aahieved that can be vi~:wed from either side of the g~,ass.
Finally, the polyurethane interlayer can be used in combination with photosensitive ar e7,ectrically-~conduativs materials, inks, or resins.
in yet another embodiment, a light-reacting material, such as phosphorous, interference pigments or any light-reacting material, can be ground or blended in a t~°ax~sparent workable vehicle that is applied to the urethane sheet. In this embodiment, the laminate would appear transparent; but, when exposed to various lights by either edge-lighting or planing a light at certain angles, it would react to the material and .a graphic image would appear on the interlayer substrate. Other adaptations and modifications will be readily apparent to those of ordinary skill in the art from th~ following drawings and desoription of the preferred embodiment.
T~~~~FtI'PTIOD1 o~"~F ~t ~?..~,~~N~S
Figure 1 is a (rant view of applicant°s invention having indicia denoting "X Y Z'°.
F~,gure 2 is a side sectional view showing the three-layer ~:QnstruGtion of the present invention.
~u cR m~'.o~r ~ ~.~~m~o~x~
Referring now to Figure 1, the letters "X Y ~'~ are shown printed an a urethane ~,nterlayer between two 6heets of glass.
_g..

is ?~
Top sheet ~, is transparent, the indicia 7 are printed an interlayer 3 which is like~wi,se a transparent sheet. mhe rear plate 5 is a second sheet a~ transparent glass. In this embodiment, the let~.ers k Y Z appoar '~Q be floating in a transparent baCkgxound. The intexlayer 3 is sheet pa~,yurethana o~ the type supplied by KsH, 2nc., o~ ~.009~, Manchester Road, St. Louia, M0. 2t is sold under the name nTHERMAL P~.~P.ST~C A~xPHAT~~ ~'OLYETHER UR~'f~iANE~~ . figure 2 shawl the simp7.e three~layer sandwich lamination of glass sheets ~, and 5 with interlayer 3 located therebetween.
The production of 'the present invention is a simple, two-step process. First, graphics are applied tp sheet urethane by directly printing thexeon using mass producta,on techniques, such as siikscreening, and then the urethane is bonded to the g~.ass plates through the standard glass-laminatiz~c~ autaciave prooess, The surprising discovery of this invention is that the printed substrate maintains its quality and registrat~.on throughout the a~xtoC~,ave process and does not ,inhibit the quality o~ the lamination between the urethane and the glass. vax~.ous inks can be used but must be ton-solvent-based ~so that there is no chemiCaJ, reaction with the urethane. polymer inks and polyvinyls that adhere to urethane are possible choices. Also, 'eso~.id inks~o, such as ~UV-drying inks and various other inks that do rat use salv~tnts such as THF ax ~MF keytonesr should also work well.
An important charaateristio o~ the ink is that it adheres well to the urethane without reacting to it. 2t is also necessary that the ink be vary glexibJ.e la that it will not crank when the sheet ur~thane is wound ~.nto a roll Eor storage or trar~spartati.on. Also, the film thickness of the ink should be kept to a mfn~.mum so there is a seepage effect of the urethane thxough the ink during the laminating process. Thig is a key facto~c and par~n~.ts molecular bonding _~_ ~~~f.°'y ryy];
L S ~ ,~ ', ~ ~l !J
,etween the ink, urethane and the glass. It has be~:n found that using this process, the urethane sheet and ~.nk combination adhere directly to the glass without distortion or loss of quality of the printed g~;aplaic.
As explained above, sheet urethane is extremely easy to ~,andle and laminates well with g~,ass, even when used in very large a~ceas. Contrary to the laminating process using PVC, which requires large or heavy machinery and expensive die-cutting materials, the present process does not have to be maintained in a temperature and humid3.ty~GOntxolled environment. this ease of handling permits large pieces of graphic glass try be manufactured very inea~pensively.
Printing may bc~ applied to the sheet urethane with standard s~.lks~creen process and th~ urethane ;may be fed into the printing presses in tall form ox in cut sheets.
r.Che printing may be to apply lettering or othex° graphics ;for various effects. For instance, a single off-white color can be applied to create the graphic effeot o~ sandblasting or etching. A four-color process using standard four-color inks (yellow, magenta, cyan and black) can be used to create any tones ox shades of color'. Furthex~~nore, by using transparent inks, one is able to create di~~~:rent hue effects by printing one ink cover another. In yet a~aother embodiment cantemplated by this invention, the ink may include materia7.s such as phosphorus, interference pigments or any yight~-reacting material that oan be ground and blended into a tr~nspaxent, workable material that can be printed or applied to the urethane. This last embs~diment may be used in combination with various lighting teahni~ues, such as edgew lighting.
The advantages of the present invention era as followsc (a) printing directly on the urethane and then laminating the urethane between two sheets of glass is a simple, two-~st~:p ~~
method; (b) the glass laminate: then beGOmes safety glass and suitable for architectural use because of its strength and non-shatter qualities: (o) light-fast inks can be used and, hence, the quality of thc~ ~arinting on the urethane will not degrade over time; (d) the use of urethane pexmi.ts the laminate to Withstand temperatures up to 300 degrees ~ahxenheit; and, (e) the urethane and the graphic create a molecular band to th,e glass so that there is no chance of the graphic becoming separated from the glass, Creating bubbles or pookets of air in the laminate.
The various uses for the present invention arcs only limited by the imagination of the designer. However, it is Contemplated that this ~,nvention will ba partioul2trly useful in: architectural glazing and spandrels, signage, doorways and ~.nterior enclosures, wall finishes, tables and furnishings, waterproof 3.nterior partitions, bus shelter and exterior partitions, and packaging and other manufactured articles.
2t should be understood that the above description d3.scloses specific embodiments of the pxes~:nt a~nvention and axe for purposes of illustration only. there may tae other modifications and changes obvious tca those of ordinary skill in the art which fall within the scope of the present invention which should be limited only by the following claims and their l~:ga~. equivalents.
~7~

Claims (11)

1. An architectural laminate, comprising:
a. two sheets of rigid, transparent material, b. an interlayer sheet of extruded polyurethane, heat-laminated between said sheets of rigid material, and c. non-solvent based ink, the ink being chemically compatible and self-adhesive to the urethane sheet material and flexible so as not to crack, and containing solid pigments printed on said polyurethane interlayer, prior to lamination, to provide a permanent graphic panel of unitary construction.
2. The architectural laminate of claim 1, wherein said sheets of rigid, transparent material are glass.
3. The architectural laminate of claim 1, wherein one or more of said sheets of rigid, transparent material are composed of a polycarbonate.
4. The architectural laminate of claim 1, 2 or 3 wherein said extruded polyurethane is in flexible sheet form.
5. The architectural laminate of any one of claims 1 to 4, wherein said ink is a polyvinyl, which is light-fast and is applied in a very thin layer to said polyurethane sheet.
6. The architectural laminate of any one of claims 1 to 5, wherein said ink further includes a light-reacting material and said lamination being in combination with edge-lighting.
7. The architectural laminate of any one of claims 1 to 6, wherein said ink is electrically conductive.
8. The architectural laminate of any one of claims 1 to 7, wherein said ink is UV-drying ink.
9. The architectural laminate of any one of claims 1 to 8, wherein said ink is printed using silk-screen contact printing.
10. The architectural laminate of any one of claims 1 to 9, wherein said ink is printed sequentially in four printing steps using four different colors.
11. A method of manufacturing an architectural glass graphic panel, comprising the steps of:
a. printing a graphic onto a flexible sheet of extruded polyurethane using non-solvent based ink, the ink being chemically compatible and self-adhesive to the polyurethane sheet and flexible so as not to crack, and containing solid pigments, and b. heat-laminating said polyurethane between two sheets of glass using autoclave laminating procedures without the use of adhesives.
CA 2026530 1990-09-28 1990-09-28 Graphic architectural glass Expired - Fee Related CA2026530C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CA 2026530 CA2026530C (en) 1990-09-28 1990-09-28 Graphic architectural glass

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CA 2026530 CA2026530C (en) 1990-09-28 1990-09-28 Graphic architectural glass

Publications (2)

Publication Number Publication Date
CA2026530A1 CA2026530A1 (en) 1992-03-29
CA2026530C true CA2026530C (en) 2003-05-27

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