CA2024346A1 - Laminated organic photosensitive material - Google Patents
Laminated organic photosensitive materialInfo
- Publication number
- CA2024346A1 CA2024346A1 CA 2024346 CA2024346A CA2024346A1 CA 2024346 A1 CA2024346 A1 CA 2024346A1 CA 2024346 CA2024346 CA 2024346 CA 2024346 A CA2024346 A CA 2024346A CA 2024346 A1 CA2024346 A1 CA 2024346A1
- Authority
- CA
- Canada
- Prior art keywords
- charge
- photosensitive material
- layer
- organic photosensitive
- laminated organic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
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- Photoreceptors In Electrophotography (AREA)
Abstract
ABSTRACT OF THE DISCLOSURE
A laminated organic photosensitive material which comprises an electroconductive support, a charge producing layer and a charge transporting layer formed thereon wherein the charge producing layer contains X-type nonmetal phthalocyanine as a charge producing substance and a halogen-containing resin as a binder resin for the layer, and the charge transporting layer contains a hydrazone compound of the formula:
A laminated organic photosensitive material which comprises an electroconductive support, a charge producing layer and a charge transporting layer formed thereon wherein the charge producing layer contains X-type nonmetal phthalocyanine as a charge producing substance and a halogen-containing resin as a binder resin for the layer, and the charge transporting layer contains a hydrazone compound of the formula:
Description
2~2~6 LAMlNATEn ORG~NIC PHOTOSENSITIVE MATERIAL
BACKGROUND OF THE INYENTION
Field of the Invention This invention relates to a laminated organic photo-sentive material which has a charge producing layer and acharge transporting layer formed on an electroconductive support and which has in particular a high sensitivity to a semiconductor laser region wavelength so as to be suitable for use as a photosentive material for a laser beam printer.
Description of the Prior Art A composite or laminated type organic photosensitive material has been developed and put to practical use in recent years. This type of organic photosensitive material is disclosed in, for example, Japanese Patent Publications Nos. 42380/1980 and 34099/1985. It comprises an electro-conductive support, and a charge producing layer and a charge transporting layer formed on the support. For instance, such a composite photosensitive material has an electroconductive support 1 of aluminum layer 2 deposited on a polyester fil0 3, a charge producing layer 4 formed on the aluminum layer, and a charge transporting layer 5 formed on the charge producing layer, as illustrated in Fig. 2 The charge producing layer is formed by, for example, preparing a dispersion of a charge producing substance together with an organic solvent, a binder resin, and if necessary a plasticizer, applying the dispersion onto the support, and drying to a thin film. The charge trans-porting layer is formed by, for example, dissolving a charge ~ ~ 2 '~ ~ 4 6 transporting substance in an organic solvent together with a binder resin, and if required a plasticizer, applYing the solution onto the charge producing layer, and drying to a thin fiIm. A charge transporting laYer may be first formed on the support, and then a charge producing layer on the charge transporting layer.
There are alreadY known a number of laminated type organic photosensitive materials containing a variety of charge producing substances and charge transporting substances in the charge producing layer and charge transporting layer, respectively. For example, there is described in Japanese Patent Laid-Open No. 60-255854, a photosensitive material which contains a hydrazone compound represented by the formula:
~ CHz ~ CHz ~ CH3 as a charge transporting substance, and a metal phthalo-cyanine compound such as copper phthalocyanine or a nonmetal phthalocyanine such as tetramethylphthalocyanine or dialkylaminophthalocyanine as a charge producing substance. However, these known photosensitive materials are still unsatifactory in charging properties or sensitivity.
As above set forth, it is already known that a metal phthalocyanine and a nonmetal phthalocyanine are photo-conductive, and in particular, a single layer photosensitive material which employs the X-type nonmetal phthalocyanine as a photoconductive material is disclosed in U.S. Patent No. 3,816,118. However, this known photosensitive material has a very low sensitivitY.
Meanwhile, there has been a demand for a laminated 3 ~ ~
organic photosensitive material for use in a laser beam printer which is sensitive to a long wavelength region from about 750 nm to about 850 nm, and for such a purpose the use of a variety of charge producing substances and charge transporting substances have hitherto been proposed.
However, any of these known laminated organic photosensitive materials which employ the beforementioned specific hydrazone compound as a charge transporting substance has a low sensitivity to a semiconductor laser region long wavelength from about 750 nm to about 850 nm.
SUMMARY OF THE INYENTION
The present inventors have made an extensive investi-gation to solve the problems as above set forth involved in the known laminated organic photosensitive materials.
in particular to obtain a laminated organic photosensitive material having a high sensitivity to the long wavelength region of 750-850 nm. ~s results the inventors have found that the co-use of the aforementioned specific hydrazone compound as a charge transporting substance and X-type nonmetal phthalocyanine as a charge producing substance together with a halogen-containing resin as a binder resin for a charge producing layer provides a laminated organic photosensitive material very sensitive to the laser region long wavelength of 750-850 nm.
In accordance with the invention, there is provided a laminated organic photosensitive material which comprises an electroconductive support, a charge producing layer and a charge transporting layer formed thereon wherein the charge producing layer contains X-type nonmetal phthalo-cyanine as a charge producing substance and a halogen-containing resin as a binder resin for the layer, and the charge transporting layer contains a hydrazone compound of the formuia:
BACKGROUND OF THE INYENTION
Field of the Invention This invention relates to a laminated organic photo-sentive material which has a charge producing layer and acharge transporting layer formed on an electroconductive support and which has in particular a high sensitivity to a semiconductor laser region wavelength so as to be suitable for use as a photosentive material for a laser beam printer.
Description of the Prior Art A composite or laminated type organic photosensitive material has been developed and put to practical use in recent years. This type of organic photosensitive material is disclosed in, for example, Japanese Patent Publications Nos. 42380/1980 and 34099/1985. It comprises an electro-conductive support, and a charge producing layer and a charge transporting layer formed on the support. For instance, such a composite photosensitive material has an electroconductive support 1 of aluminum layer 2 deposited on a polyester fil0 3, a charge producing layer 4 formed on the aluminum layer, and a charge transporting layer 5 formed on the charge producing layer, as illustrated in Fig. 2 The charge producing layer is formed by, for example, preparing a dispersion of a charge producing substance together with an organic solvent, a binder resin, and if necessary a plasticizer, applying the dispersion onto the support, and drying to a thin film. The charge trans-porting layer is formed by, for example, dissolving a charge ~ ~ 2 '~ ~ 4 6 transporting substance in an organic solvent together with a binder resin, and if required a plasticizer, applYing the solution onto the charge producing layer, and drying to a thin fiIm. A charge transporting laYer may be first formed on the support, and then a charge producing layer on the charge transporting layer.
There are alreadY known a number of laminated type organic photosensitive materials containing a variety of charge producing substances and charge transporting substances in the charge producing layer and charge transporting layer, respectively. For example, there is described in Japanese Patent Laid-Open No. 60-255854, a photosensitive material which contains a hydrazone compound represented by the formula:
~ CHz ~ CHz ~ CH3 as a charge transporting substance, and a metal phthalo-cyanine compound such as copper phthalocyanine or a nonmetal phthalocyanine such as tetramethylphthalocyanine or dialkylaminophthalocyanine as a charge producing substance. However, these known photosensitive materials are still unsatifactory in charging properties or sensitivity.
As above set forth, it is already known that a metal phthalocyanine and a nonmetal phthalocyanine are photo-conductive, and in particular, a single layer photosensitive material which employs the X-type nonmetal phthalocyanine as a photoconductive material is disclosed in U.S. Patent No. 3,816,118. However, this known photosensitive material has a very low sensitivitY.
Meanwhile, there has been a demand for a laminated 3 ~ ~
organic photosensitive material for use in a laser beam printer which is sensitive to a long wavelength region from about 750 nm to about 850 nm, and for such a purpose the use of a variety of charge producing substances and charge transporting substances have hitherto been proposed.
However, any of these known laminated organic photosensitive materials which employ the beforementioned specific hydrazone compound as a charge transporting substance has a low sensitivity to a semiconductor laser region long wavelength from about 750 nm to about 850 nm.
SUMMARY OF THE INYENTION
The present inventors have made an extensive investi-gation to solve the problems as above set forth involved in the known laminated organic photosensitive materials.
in particular to obtain a laminated organic photosensitive material having a high sensitivity to the long wavelength region of 750-850 nm. ~s results the inventors have found that the co-use of the aforementioned specific hydrazone compound as a charge transporting substance and X-type nonmetal phthalocyanine as a charge producing substance together with a halogen-containing resin as a binder resin for a charge producing layer provides a laminated organic photosensitive material very sensitive to the laser region long wavelength of 750-850 nm.
In accordance with the invention, there is provided a laminated organic photosensitive material which comprises an electroconductive support, a charge producing layer and a charge transporting layer formed thereon wherein the charge producing layer contains X-type nonmetal phthalo-cyanine as a charge producing substance and a halogen-containing resin as a binder resin for the layer, and the charge transporting layer contains a hydrazone compound of the formuia:
4 h.i ~ 2 l~ 3 4 6 CHz ~ CHz ~ CH3 as a charge transporting substance and a halogen-containing resin as a binder resin for the charge producing layer.
BRIEF DESCRIPTION OF ~HE DRAWINGS
Fig. 1 is an X-ray diffraction diagram (CuK ~, powder method) of X-type nonmetal phthalocyanine used as a charge producing substance in the laminated organic photo-sensitive material of the invention, and Fig. 2 is a section of a known laminated organic photosensitive material.
The laminated organic photosensitive material of the invention contains X-type nonmetal phthalocyanine as a charge producing substance. It is represented by the formula:
~
N N N
~ NH HN
N
N 4 ~ N
~,.D
3 ~ ~
Tn the production of the laminated organic photo-sensitive material of the invention. a dispersion or a solution of the nonmetal X-type phthalocyanine as a charge producing substance, a halogen-containing polymer as a binder resin, and if necessary a plasticizer, is coated on an electroconductive support and dried to form a charge producing layer, and then a solution of the hydrazone compound as a charge transporting substance and a binder resin, and if necessary a plasticizer, is coated on the charge producing layer and dried to a form a charge transporting layer. The charge producing layer and the charge transporting layer may be laminated in the reverse order, that is, the charge transporting layer may be first formed on the support, and then the charge producing layer on the charge producing layer.
The halogen-containing resin as a binder resin for the charge producing layer is exemplified by polyvinyl chloride, vinyl chloride-vinyl acetate copolymer, ethylene-vinyl chloride copolymer or vinyl chloride-vinyl acetate-maleic anhydride copolymer. The copolymer may be a graftcopolymer. When a vinyl chloride copolymer is used, it is preferred that the copolymer contains a vinyl chloride content of not less than 20 % by weight.
The smaller the content of the binder resin in the charge producing layer, the better, but it is usually in the range of about 5-50 % by weight based on the layer.
The charge producing layer has a thickness usually of about 0.05-20 microns, preferably of 0.1-10 microns.
The charge transporting substance used in the invention is a hydrazone compound as rePresented by the formula hereinbefore given. The hydrazone compound is contained in the charge transporting layer usually in an amount of 10-60 % by weight based on the laye, and the layer has a thickness usually of 5-100 microns.
The binder resin for the charge transporting layer is of the type which is soluble in an organic solvent and is highly compatible with the charge transporting substance so that a stable solution thereof may be prepared easily.
Moreover, it is preferable to use a resin which is inexpensive and can form a film of high mechanical strength, transparency and electrical insulation. Preferred examples of the binder resin may be exemplified by, for example, polycarbonate, polystyrene, styrene-acrylon.trile copolymer, polyester resin or polyvinyl chloride.
The organic solvent used for the preparation either of the charge transporting layer or of the charge producing layer is not specifically limited, but it may include, for example, chloroform, 1,2-dichloroethane, 1,1,2,2-tetra-chloroethane, tetrahydrofuran or dioxane, The invention will now be described more specifically with reference to examples, however, the invention is not limited thereto.
ExamPle Polyvinyl chloride having an average polymerization degree of 800 (PVC-SR from Chisso K.K.) was purified by a reprecipitation method using tetrahydrofuran and n-hexane as solvents therefor and then vacuum dried.
An amount of 1.6 parts by weight of the polyvinyl chloride and 2.2 parts by weight of X-type nonmetal phthalocyanine (8120B from Dainippon Ink Kagaku Kogyo K.K.) were milled together in 96.2 parts by weight of tetrahydro-furan to prepare a dispersion.
The dispersion was applied by a doctor blade onto an aluminum film deposited on a polyethylene terephthalate film, allowed to dry at room temperature and then dried by heating at 80C for 60 minutes, to form a charge producing layer having a thickness of 0.6 microns.
An amount of 10 parts by weight of polycarbonate ~2~3~
~Yupiron E-2000 from Mitsubishi Gas Kagaku Kogyo K.K.) an~
8 parts by weight of the aforesaid hydrazone compound as a charge transporting substance were dissolved in 82 parts by weight of chloroform to prepare a solution. ~he solution was applied onto the charge producing layer by a doctor blade having a clearance of 100 microns, allowed to dry at room temperature and then dried by heating at lOO'C
for 60 minutes to form a charge transporting layer having a thickness of 20 microns, whereby a laminated organic photosensitive material was obtained.
Example 2 ~ laminated photosensitive material was prepared in the same manner as in the Example 1 using vinyl chloride-vinyl acetate copolymer having a vinyl acetate content of 15 % by weight (from Nippon Kayaku K.K.) as a binder resin for the charge producing layer.
Example 3 A laminated photosensitive material was prepared in the same manner as in the Example 1 using vinyl chloride-vinyl acetate graft copolymer having a vinyl chloride content of 50 mol % (Graftmer R-5 from Nippon Zeon K.K.) as a binder resin for the charge producing layer.
Example 4 ~ laminated photosensitive material was prepared in the same manner as in the Example 1 using vinyl chloride-vinyl acetate-maleic anhydride copolymer (Esleck MF-10 from Sekisui Kagaku Kogyo K.K.) as a binder resin for the charge producing layer having a thickness of 0.3 microns.
Comparative ExamPle A laminated photosensitive material was prepared in the same manner as in the Example 1 using N,N-diethylamino-benzaldehyde diphenylhydrazone as a charge transportingsubstance.
Comparative ExamP!e 2 A laminated photosensitive material was prepared in the same manner as in the Example 1 using the same polycarbonate as before mentioned as a binder resin for the charge producing layer.
Comparative Example 3 A laminated photosensitive material was prepared in the same manner as in the Example 3 using N,N-diethylamino-benzaldehyde diphenylhydrazone as a charge transporting substance.
The laminated photosensitive materials prepared as above set forth were each evaluated for electrostatic charging characteristics by use of an electrostatic charging testing device (Model EPA 8100 from Kawaguchi Denki Seisakusho~.
The surface of photosensitive material was negatively charged with a charge corona of -6 KV, and the surface potential was measured as an initial potential. Then, after the photosensitive material was left standing in the dark over a period of five seconds, the surface potential was measured as a charge retention rate.
Then the surface was irradiated at an illuminance of 5 lux with a halogen lamp, and the length of time was measured until the point at which the surface potential 3 ~ ~
dropped to a half of its initial value, and the half-time exposure El~2 (lux) of the photosensitive material to that point of time was determined as its photosensitivity.
Further, the surface was irradiated with a monochro-matic light having a wavelength of 750 nm and a luminousintensity of 0.5 ~ W/cmZ. The length of time was measured until the point at which the surface potential dropped to a half of its initial value, and the half-time exposure El~z (~ J/cm2) of the photosensitive material to that point of time was determined as its photosensitivity.
The surface potential after five seconds from the irradiation of light was also measured as a residual potential in eiher cases above.
As the results are shown in Table 1, the photo-sensitive material of the invention has a small half-time exposure E,~z when irradiated with either white light or monochromatic light (750 nm), and has a high photo-sensitivity.
lo ~43~
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*
BRIEF DESCRIPTION OF ~HE DRAWINGS
Fig. 1 is an X-ray diffraction diagram (CuK ~, powder method) of X-type nonmetal phthalocyanine used as a charge producing substance in the laminated organic photo-sensitive material of the invention, and Fig. 2 is a section of a known laminated organic photosensitive material.
The laminated organic photosensitive material of the invention contains X-type nonmetal phthalocyanine as a charge producing substance. It is represented by the formula:
~
N N N
~ NH HN
N
N 4 ~ N
~,.D
3 ~ ~
Tn the production of the laminated organic photo-sensitive material of the invention. a dispersion or a solution of the nonmetal X-type phthalocyanine as a charge producing substance, a halogen-containing polymer as a binder resin, and if necessary a plasticizer, is coated on an electroconductive support and dried to form a charge producing layer, and then a solution of the hydrazone compound as a charge transporting substance and a binder resin, and if necessary a plasticizer, is coated on the charge producing layer and dried to a form a charge transporting layer. The charge producing layer and the charge transporting layer may be laminated in the reverse order, that is, the charge transporting layer may be first formed on the support, and then the charge producing layer on the charge producing layer.
The halogen-containing resin as a binder resin for the charge producing layer is exemplified by polyvinyl chloride, vinyl chloride-vinyl acetate copolymer, ethylene-vinyl chloride copolymer or vinyl chloride-vinyl acetate-maleic anhydride copolymer. The copolymer may be a graftcopolymer. When a vinyl chloride copolymer is used, it is preferred that the copolymer contains a vinyl chloride content of not less than 20 % by weight.
The smaller the content of the binder resin in the charge producing layer, the better, but it is usually in the range of about 5-50 % by weight based on the layer.
The charge producing layer has a thickness usually of about 0.05-20 microns, preferably of 0.1-10 microns.
The charge transporting substance used in the invention is a hydrazone compound as rePresented by the formula hereinbefore given. The hydrazone compound is contained in the charge transporting layer usually in an amount of 10-60 % by weight based on the laye, and the layer has a thickness usually of 5-100 microns.
The binder resin for the charge transporting layer is of the type which is soluble in an organic solvent and is highly compatible with the charge transporting substance so that a stable solution thereof may be prepared easily.
Moreover, it is preferable to use a resin which is inexpensive and can form a film of high mechanical strength, transparency and electrical insulation. Preferred examples of the binder resin may be exemplified by, for example, polycarbonate, polystyrene, styrene-acrylon.trile copolymer, polyester resin or polyvinyl chloride.
The organic solvent used for the preparation either of the charge transporting layer or of the charge producing layer is not specifically limited, but it may include, for example, chloroform, 1,2-dichloroethane, 1,1,2,2-tetra-chloroethane, tetrahydrofuran or dioxane, The invention will now be described more specifically with reference to examples, however, the invention is not limited thereto.
ExamPle Polyvinyl chloride having an average polymerization degree of 800 (PVC-SR from Chisso K.K.) was purified by a reprecipitation method using tetrahydrofuran and n-hexane as solvents therefor and then vacuum dried.
An amount of 1.6 parts by weight of the polyvinyl chloride and 2.2 parts by weight of X-type nonmetal phthalocyanine (8120B from Dainippon Ink Kagaku Kogyo K.K.) were milled together in 96.2 parts by weight of tetrahydro-furan to prepare a dispersion.
The dispersion was applied by a doctor blade onto an aluminum film deposited on a polyethylene terephthalate film, allowed to dry at room temperature and then dried by heating at 80C for 60 minutes, to form a charge producing layer having a thickness of 0.6 microns.
An amount of 10 parts by weight of polycarbonate ~2~3~
~Yupiron E-2000 from Mitsubishi Gas Kagaku Kogyo K.K.) an~
8 parts by weight of the aforesaid hydrazone compound as a charge transporting substance were dissolved in 82 parts by weight of chloroform to prepare a solution. ~he solution was applied onto the charge producing layer by a doctor blade having a clearance of 100 microns, allowed to dry at room temperature and then dried by heating at lOO'C
for 60 minutes to form a charge transporting layer having a thickness of 20 microns, whereby a laminated organic photosensitive material was obtained.
Example 2 ~ laminated photosensitive material was prepared in the same manner as in the Example 1 using vinyl chloride-vinyl acetate copolymer having a vinyl acetate content of 15 % by weight (from Nippon Kayaku K.K.) as a binder resin for the charge producing layer.
Example 3 A laminated photosensitive material was prepared in the same manner as in the Example 1 using vinyl chloride-vinyl acetate graft copolymer having a vinyl chloride content of 50 mol % (Graftmer R-5 from Nippon Zeon K.K.) as a binder resin for the charge producing layer.
Example 4 ~ laminated photosensitive material was prepared in the same manner as in the Example 1 using vinyl chloride-vinyl acetate-maleic anhydride copolymer (Esleck MF-10 from Sekisui Kagaku Kogyo K.K.) as a binder resin for the charge producing layer having a thickness of 0.3 microns.
Comparative ExamPle A laminated photosensitive material was prepared in the same manner as in the Example 1 using N,N-diethylamino-benzaldehyde diphenylhydrazone as a charge transportingsubstance.
Comparative ExamP!e 2 A laminated photosensitive material was prepared in the same manner as in the Example 1 using the same polycarbonate as before mentioned as a binder resin for the charge producing layer.
Comparative Example 3 A laminated photosensitive material was prepared in the same manner as in the Example 3 using N,N-diethylamino-benzaldehyde diphenylhydrazone as a charge transporting substance.
The laminated photosensitive materials prepared as above set forth were each evaluated for electrostatic charging characteristics by use of an electrostatic charging testing device (Model EPA 8100 from Kawaguchi Denki Seisakusho~.
The surface of photosensitive material was negatively charged with a charge corona of -6 KV, and the surface potential was measured as an initial potential. Then, after the photosensitive material was left standing in the dark over a period of five seconds, the surface potential was measured as a charge retention rate.
Then the surface was irradiated at an illuminance of 5 lux with a halogen lamp, and the length of time was measured until the point at which the surface potential 3 ~ ~
dropped to a half of its initial value, and the half-time exposure El~2 (lux) of the photosensitive material to that point of time was determined as its photosensitivity.
Further, the surface was irradiated with a monochro-matic light having a wavelength of 750 nm and a luminousintensity of 0.5 ~ W/cmZ. The length of time was measured until the point at which the surface potential dropped to a half of its initial value, and the half-time exposure El~z (~ J/cm2) of the photosensitive material to that point of time was determined as its photosensitivity.
The surface potential after five seconds from the irradiation of light was also measured as a residual potential in eiher cases above.
As the results are shown in Table 1, the photo-sensitive material of the invention has a small half-time exposure E,~z when irradiated with either white light or monochromatic light (750 nm), and has a high photo-sensitivity.
lo ~43~
_ ~r ~ ~ u~
C~
o ~ o ~ . ~ CO ~ C`l ~ o~ ~ ~
~ s ~ .~ ~ ~ u~ ~O ~ ~ a~ ~
~ ~
~1~
~1 E ~
~ tl) ~ c~
_~ S~ C~C`lC~C`~ ~
O
CC) C~ U~ O ~D C~
S~ ~ ~ ~ . . . . .
L~ ~ ~ U~ ~ cr~
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Q. Q 1~) X E
*
Claims (9)
1. A laminated organic photosensitive material which comprises an electroconductive support, a charge producing layer and a charge transporting layer formed thereon wherein the charge producing layer contains X-type nonmetal phthalocyanine as a charge producing substance and a halogen-containing resin as a binder resin for the layer, and the charge transporting layer contains a hydrazone compound of the formula:
as a charge transporting substance and a halogen-containing resin as a binder resin for the charge producing layer.
as a charge transporting substance and a halogen-containing resin as a binder resin for the charge producing layer.
2. The laminated organic photosensitive material as claimed in claim 1 wherein the halogen-containing resin is polyvinyl chloride.
3. The laminated organic photosensitive material as claimed in claim 1 wherein the halogen-containing resin is a vinyl chloride copolymer which has a chloride content of not less than 20 % by weight.
4. The laminated organic photosensitive material as claimed in claim 1 wherein the charge producing layer contains the halogen-containing resin in an amount of 5-50 % by weight based on the layer.
5. The laminated organic photosensitive material as claimed in claim 1 wherein the vinyl chloride copolymer is vinyl chloride-vinyl acetate copolymer.
6. The laminated organic photosensitive material as claimed in claim 1 wherein the vinyl chloride copolymer is vinyl chloride-vinyl acetate-maleic anhydride copolymer.
7. The laminated organic photosensitive material as claimed in claim 1 wherein the charge transporting layer contains the hydrazone compound in an amount of 10-60 % by weight based on the layer.
8. The laminated organic photosensitive material as claimed in claim 1 wherein the charge transporting layer has a thickness of 5-100 microns.
9. The laminated organic photosensitive material as claimed in claim 1 wherein the charge producing layer has a thickness of 0.1-10 microns.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CA 2024346 CA2024346A1 (en) | 1990-08-30 | 1990-08-30 | Laminated organic photosensitive material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CA 2024346 CA2024346A1 (en) | 1990-08-30 | 1990-08-30 | Laminated organic photosensitive material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA2024346A1 true CA2024346A1 (en) | 1992-03-01 |
Family
ID=4145854
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA 2024346 Abandoned CA2024346A1 (en) | 1990-08-30 | 1990-08-30 | Laminated organic photosensitive material |
Country Status (1)
| Country | Link |
|---|---|
| CA (1) | CA2024346A1 (en) |
-
1990
- 1990-08-30 CA CA 2024346 patent/CA2024346A1/en not_active Abandoned
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