CA2017526C - Extrusion shaping method - Google Patents

Extrusion shaping method

Info

Publication number
CA2017526C
CA2017526C CA 2017526 CA2017526A CA2017526C CA 2017526 C CA2017526 C CA 2017526C CA 2017526 CA2017526 CA 2017526 CA 2017526 A CA2017526 A CA 2017526A CA 2017526 C CA2017526 C CA 2017526C
Authority
CA
Canada
Prior art keywords
profiled strip
predetermined shape
extrusion die
predetermined
compression molding
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CA 2017526
Other languages
French (fr)
Other versions
CA2017526A1 (en
Inventor
Donald Lawrence Franck
Lawrence David Zabel
Suresh Deepchand Shah
Manu K. Sheth
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Motors Liquidation Co
Original Assignee
Motors Liquidation Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Motors Liquidation Co filed Critical Motors Liquidation Co
Publication of CA2017526A1 publication Critical patent/CA2017526A1/en
Application granted granted Critical
Publication of CA2017526C publication Critical patent/CA2017526C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C43/00Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
    • B29C43/02Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor of articles of definite length, i.e. discrete articles
    • B29C43/04Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor of articles of definite length, i.e. discrete articles using movable moulds
    • B29C43/06Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor of articles of definite length, i.e. discrete articles using movable moulds continuously movable in one direction, e.g. mounted on chains, belts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C43/00Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
    • B29C43/22Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor of articles of indefinite length
    • B29C43/28Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor of articles of indefinite length incorporating preformed parts or layers, e.g. compression moulding around inserts or for coating articles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C43/00Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
    • B29C43/02Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor of articles of definite length, i.e. discrete articles
    • B29C43/04Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor of articles of definite length, i.e. discrete articles using movable moulds
    • B29C2043/046Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor of articles of definite length, i.e. discrete articles using movable moulds travelling between different stations, e.g. feeding, moulding, curing stations
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C43/00Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
    • B29C43/32Component parts, details or accessories; Auxiliary operations
    • B29C43/34Feeding the material to the mould or the compression means
    • B29C2043/3433Feeding the material to the mould or the compression means using dispensing heads, e.g. extruders, placed over or apart from the moulds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C43/00Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
    • B29C43/32Component parts, details or accessories; Auxiliary operations
    • B29C43/44Compression means for making articles of indefinite length
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2705/00Use of metals, their alloys or their compounds, for preformed parts, e.g. for inserts

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Extrusion Moulding Of Plastics Or The Like (AREA)

Abstract

AN EXTRUSION SHAPING METHOD A method of extruding a profiled strip of polymeric material off the extrusion die of a plastic extruder and immediately thereafter compression forming a predetermined section of the profiled strip into a predetermined shape when temperature of the polymeric material is sufficiently high to allow plastic flow in the profiled strip. The method including the steps of first extruding a profiled strip of polymeric material through the extrusion die and compression molding a predetermined section of the profiled strip into a predetermined shape at a close proximity from the extrusion die with a set of compression molding dies capable of traveling with the profiled strip at substantially the same speed for a sufficient length of time to permanently set the predetermined shape, disengaging the compression molding dies from the profiled strip at a predetermined distance from the extrusion die; cooling the profiled strip having the compression molded predetermined shape in a suitable cooling fluid such that the predetermined shape is permanently maintained, and then trimming the extruded profiled strip into discontinuous pieces each having the compression molded predetermined shape.

Description

. ~ . "-"-.`~' '.: , ,v C-4169 . `:`
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AN EXTRUSION SHAPING METtlOD `
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Field of the invention This invention generally relates to a method of extruding a profiled strip of polymeric material and, more particularly, relates to a method of extruding a profiled strip of polymeric material and immediately after extrusion, re~haping a leading and a trailing end of a molding piece in the strip by a set of compression molding dies such that molding pieces having prefinished ends are readily obtained after routing of the flash.
Background of the invention Profiled strips extruded of polymeric materials are widely used in automobile body applications as molding pieces. Molding pieces such as body side moldings or wheel well moldings are used to protect a vehicle body from impact damage and to protect edges of sheet metal paneIs from -~ corrosion. Most of these molding pieces are extruded of thermoplastic materials such as PVC (polyvinyl chloride), thermoplastic rubber, thermoplastic urethane, or other flexible polymeric materials. PVC is one of the most widely used materials for its low cost and good physical properties. ~ ~ i Molding pieces such as a body side molding may be extruded of a plastic material alone or extruded in an i extrusion coating process where plastic material is extruded on a metal reinforcing substrate. In an extrusion coating ;
: ~

20~75~6 process where plastic material is combined with a more rigid ;-metal substrate, a cross-head extrusion technique is used.
In cross-head extrusion, a continuous length of metal reinforcing substrate is pulled through an extrusion die at 90 angle to the direction of the plastic flow while molten plastic material is being extruded onto the metal substrate. `~
The metal reinforcing substrate is usually cleaned and dried `~
through a multi-station process and formed by a series of ~- .:`*'t' metal roll formers prior to the entry into the extrusion die. ;~
However, such metal reinforcing substrate may also be in the form of a thin metal foil which does not require preforming.
In automobile body parts, the aesthetic appearance of the part is one of the most important criteria that must -be satisfied. In the extrusion of vinyl or vinyl/metal substrate reinforced molding pieces, the quality of the appearance of the molding pieces obtained is dependent upon many variables. One of these variables is how well the ends of the molding pieces are finished.
Currently, the industry practice i6 to cut the continuous length extrudate into appropriate lengths in-line after cooling of the extrudate. Even though this is a relatively efficient process, the parts produced, particularly the shear cut ends, are crude and unfinished.
The metal substrate running through the center of the extrusion is frequently exposed at both ends of the cut molding pieces which is aesthetically unacceptable.
It is, therefore, an object of the present invention to provide a method of extrusion shaping profiled strips of polymeric material with smooth finished ends. ;~
It is another object of the present invention to ;
produce extruded profiled strips of polymeric material that have substantially no exposed metal substrate in the ends.
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It is a further object of the present invention to extrude profiled strips of polymeric material having smooth finished ends without using labor intensive secondary finishing steps.
Summary of the invention ~ i~{~
The aforementioned objects can be achieved by the `
practice of our novel extrusion shaping technique. In our extrusion shaping technique, an extrudate, while still hot ` `~
immediately after the extrusion die, is compression molded to form a leading and a trailing end of a molding piece by a set ~ ~ -of matched molding dies. The extrudate having finished ~ s leading and trailing ends of a molding piece is then cooled ~
in a cooling tank prior to being cut into separate molding ; i~-pieces. .
In practice, two sets of matched molding dies are :~
used to alternately synchronize with the extrudate at a suitable line speed. Each set of molding dies is mounted on a reciprocating precision die carrier which allows lateral movement of the dies, while the die carrier is mounted on a reciprocating extensible shuttle to allow precision movement ;1 parallel to the extrudate. The extrusion die design, the die carrier design, and the extensible shuttle movement design ;
are critical in the production of defect-free extruded molding pieces with finished ends. Imperfection in any of these three design areas would produce molding pieces with ` ;~
drag-type defects such as shock lines and dimensional variations. ~ ~/ t''~6 Brief description of the drawings ;~
Figure 1 is a flow chart showing the relevant steps of the extrusion shaping process. : -;
Figure 2 is a schematic of the equipment setup of ........
the extrusion shaping process.
3 ~ `~
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201~526 :`

Figure 3 is a perspective view of the die carriers and the extensible shuttles.
Figure 4 is an enlarged cross-sectional view of a ~-matched molding die taken along the length of the die. `~
Figure 5 is an enlarged cross-sectional view of the ` -matched molding dies taken along the width of the die.
Figure 6 is a perspective view of the die carriers ~
in the alternate embodiment. ` `=
Detailed description of the preferred embodiment In our preferred embodiment, a PVC extrudate is ~ `-first made by extrusion coating a PVC resin composition onto a continuous length of reinforcing metal substrate. The extrudate is then compression molded to form a trailing and leading ends of a molding piece immediately after the -extrucion die by a set of compression molding dies. A flow chart showing this process is shown in Figure 1. The individual processing steps shown in Figure 1 may be more easily explained by the schematic of the equipment set up shown in Figure 2. ~;
In our preferred embodiment, a 2-1/2 inch standard plaetic extruder 10 is used for the extrusion coating process. It is obvious that any standard size plastic extruder may be used determined by the size of the extrudate de6ired. A metal foil 12 is being fed from metal foil roll `~
14 into extrusion die 16. It is desirable to locate the ,;, extruder on an overhead platform and orient the extrusion die 16 such that plastic flow is directed straight down as shown in Figure 2.
Immediately after the extrudate 20 exits the extrusion die 16, approximately at a distance of 8 to 10 inches from the extrusion die, the extrudate 20 enters into an extensible die shuttle carrier station 30. An enlarged ' ' : ~, ; `1 ,~

20175~6 - ~

:': "',' .,,' ' detailed construction of the extensible die shuttle carrier 30 is shown in Figure 3.
As shown in Figure 3, the extensible die shuttle carrier 30 is mounted on a fixed position metal plate 32 in a vertical direction situated behind the extrudate 20. Two extensible die shuttles 40 and 50 are mounted on the carrier -~
plate 32 in a parallel relationship. The extensible shuttles 40 and 50 are operated by a reciprocating ball linear motion screw mechanism 42 capable of precision tracking the line ~;`
speed of the extrudate while producing zero backlash. Our .. ",?`"'~'`'~"':';' tests have shown that at an extrusion line speed of lS to 30 feet per minute, an accuracy of 0.001 mm in stop point repeatability can be obtained with our reciprocating ball',,3,,~,~J;~
linear motion screw mechanisms. ~ m The design of the extensible die shuttle is a very important step of our novel extrusion shaping process. The shuttle must be a highly precise mechanical device capable of functioning with exact movement repeatability. It must also i ,;`
be designed to respond to a built-in electronic controller to ~`, not only control the shuttle, but also coordinate it with the extruder and the haul off device. The shuttle should also ~`
have wide and accurate adjustment capability.
On the reciprocating extensible shuttle 40, a ~ ;
reciprocating precision die carrier 60 is mounted. The ~ ~ :
reciprocating precision die carrier 60 is operated by an ~ ` ~
electrical worm gear linear actuator 62 which is dicectly~ ,9 coupled to a two-way variable speed servo motor (not shown).
The linear actuator 62 carries the die carrier 60 and guided by two linear motion travel guides 66. Another linear actuator 58 allows die assembly 70 mounted on the die mounting plates 64 to move laterally in tracking the ~ ;
extrudate. The linear actuator 58 must be able to move ` ~
. ,., ,~,,~,, 20175f~

precisely and rapidly in the tracking of the extrudate.
Locating pins 68 are mounted on the die mounting plates 64 for the mounting of the die assembly.
A quick change molding die clamp assembly 70, as shown in Figure 3, is mounted on the die mounting plates 64.
The die clamp assembly is controlled by a two-way hydraulic valve 72 and a hydraulic solenoid 74. The design of the mounting of the shaping dies 76 and 78 is such that they can be quickly exchanged. The shaping dies should be drilled~ y~
(not shown) for high volume water flow to provide quick `~
response temperature control to maintain an optimum 60 to 80F surface temperature of the dies. This temperature control is desirable in order to set the thermoplastic extrudate and to maintain a surface matching the extruded unshaped section.
Figures 4 and 5 show enlarged cross-sectional views of the molding dies. Figure 4 shows a view taken along the length of the die while Figure 5 shows a view taken along the width of the die. The design of the molding dies is another important factor for the successful practice of our novel invention. The die cavity must be designed to avoid the formation of mold edge marks at the prefinished ends. The ellmlnatlon of mold marks is accomplished by constructing the opening in the upper female die 76 (Fig. 5) to fade away -proportionately from the forming area to the extreme end of the die in both directions, i.e., the trailing end and the~;~ "`';;
leading end. We have discovered that the optimum opening for fade away is approximately 1 mm over 300 mm. Other fade away opening ratios may also produce good parts, but some degree 30 of distortion may be noticeable. Leveling pads 92 (Figure 4)~i ~
are provided to better control the leveling of the upper~ ~ , female die 76 and the lower die 78. ~;
6 :; ~
, , ...,: :, , ~....~;
2~17~26 : ~`
7 ~ `
Another important design factor to be considered in the construction of the die is that the cavity in the lower die must be precisely cut to accept the material displaced locally during shaping. We have determined that the cavity opening 80 (Fig. 5) must inversely profile the upper die section with a volume that is approximately 1/64 les~ than -~ - r~' the volu~e di~placed. Thi~ ratio is reguired to provide --slight back pressure and to prevent sink marks in the shaped extrudate. The lower die 78 is not required to fade away open but it must regi~ter the extruded section on center.
The design of the fade away open in the upper die 76 is important in order to eliminate mold marks which tend to form ;
at the point where the mold no longer touches the extrudate.
The properly designed tapered fade open also avoid~ shearing `~ ~
15 action and minimize~ a drag-type defect commonly known as ~ r\-f shock lines. By the precise combination of a properly designed fade away open and a suitably sizod lower die cavity, smooth finished leading and trailing ends can be ~ `';
obtained on continuou~ length extrudate. The trailing end '~
and the leading end are shown as 84 and 86 in Fig. 5.
The practice of our novel invention may now be described a~ follow~. In Figure 2, it i~ see~ that two mold carriers 60 and 85 each mounted on a reciprocating exten~ible shuttle 40 and 50 are u~ed to engage the extrudate 20 one at a tlme in a hand-over-hand manner. A set of molding dies 76 and 78 fir~t extends in open positlon to a point directly over the extrudate 20 and moves down at a speed slightly faster than the movement of the extrudate. When propsr speed 18 attained, moldlng dies 76 and 78 close and form a leading and tralling end simultaneously. Moldlng dies 76 and 78 continue to move wlth the extrudate untll it reaches a -`
predetermined set point which actuates the second set of 7 ~'`

201'75'`6 ~

molding dies 46 and 48 causing it to close at precise timing to establish the length of the molded part.
The second set of molding dies 46 and 48 then extends to a position directly over the extrudate and moves with the extrudate until a speed slightly faster than the movement of the extrudate is achieved. Molding dies 46 and 48 then close to form a leading and trailing end simultaneously. Molding dies 76 and 78 then open and retract away from the extrusion and quickly returns to home position.
When the second set of molding 46 and dies 48 reaches the predetermined set point, molding dies 76 and 78 extend and u~
repeat the sequence.
Repeated actions of molding dies 76, 78 and 46, 48 create a continuous series of formed areas on the extrudate precisely spaced to preset lengths. This continuous extrudate flows directly into a vertical water bath 28 approximately 10 feet deep. It should be noted that in Figure 2, the extrudate after shaping is rotated 90 to better illustrate the process. The extrudate then passes ~-around a combination idler drum puller mechanism driven at a speed synchronized with the basic extrusion rate. From the idler drum 90, the extrudate is guided into a grooved fixture 94 and pulled by puller 95 through a router machining a66embly 96 which removes a thin layer of flash material on `~
the extrudate. ~ "
The router 96 is arranged such that the blades just clear the shoulders opposite the groove and shave the flesh and excess material from the lower side of both the leading ~ ;~
and the trailing ends. This effectively produces a finished part cut precisely to length which has two formed and ~ ~ :
finished ends. Our novel process thus produces a continuous series of cut-to-length extruded parts with both ends neatly ;

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20175;~6 ~ ~

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shaped, ready for application of adhesive tape ror mounting `-purposes.
In an alternate embodiment, we have developed a simpler mold shuttle mechanism which eliminates the need for horizontal lateral movement. This is shown in Figure 6.
In our alternate embodiment, the horizontal acting `~
carriers are replaced by a pair of power jaw clamps 106 and 108 which allow the molding dies 110 and 112 to pass during vertical movement. The alligator type jaws are designed to open wide enough to allow the opposite clamp and mold dies to ` ^
pass between them in closed position. ~ ~-All other machine functions would be the same as that in the preferred embodiment except for the fact that -~
opening and closing of the power jaws must be coordinated and ;~ `
fitted with safeties to ensure that one clamp is open and one is closed anytime the two pass each other.
AS shown in in Figure 6, starting at home position , with the mold carrier 102 full up toward the extrusion die and the other mold carrier 104 full down at the end of travel the extru8ion is started to establish proper extruded profile and line speed8. Once the extruder has reached equilibrium ~;
and i~ making an acceptable profile, the mold carrier mechanism begins to function. Mold carrier 102 advances, attains line speed, and forms a leading and trailing end into ;~ ;~
the extrudate. Simultaneously mold carrier 104 quickly moves to full up position. Mold carrier 102 continues to advance until a preset point is reached which causes mold carrier 104 to advance, attain line speed and close onto the extrudate. , ;
Once carrier 104 is closed, carrier 102 opens and returns to `-full up position. Meanwhile carrier 104 continues to advance until it reaches a preset point which signals mold carrier 102 and causes it to advance, attain line speed, and close.

20175~6 ~ ~

: '' These actions continue in precise harmony creating a continuous length of extrudate with ends formed equally spaced over its length. All of these operations occur at full line speed with no stops or pauses.
While our invention has been described in terms of a preferred embodiment and an alternate embodiment thereof, it is to be appreciated that those skilled in the art will `~
readily apply these teachings to other possible variationfi of the invention.

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Claims (6)

The embodiments of the invention in which an exclusive property or privilege is claimed are defined as follows:
1. A method of extruding a profiled strip of polymeric material off the extrusion die of a plastic extruder and immediately thereafter compression forming a predetermined section of said profiled strip into a predetermined shape while the temperature of said extruded material is still eufficiently high for plastic flow, said method comprising the steps of:
extruding a profiled strip of polymeric material at a thermoformable temperature above 200°F through an extrusion die;
compression molding a predetermined section of said profiled strip while it is still at a temperature no less than 200°F into a predetermined shape at a close proximity from the extrusion die with a set of compression molding dies capable of traveling with the profiled strip at substantially the same speed for a sufficient length of time to permanently set said predetermined shape;
disengaging said compression molding dies from said profiled strip at a predetermined distance from said extrusion die;
cooling said profiled strip having said compression molded predetermined shape in a suitable cooling fluid such that said predetermined shape is permanently maintained; and trimming said extruded profiled strip into discontinuous pieces each having said compression molded predetermined shape.
2. A method of extruding a profiled strip of polymeric material off the extrusion die of a plastic extruder and immediately thereafter compression forming a predetermined section of said profiled strip into a predetermined shape while the temperature of said extruded material is still sufficiently high for plastic flow, said method comprising the steps of:
extruding a profiled strip of polymeric material at a thermoformable temperature through an extrusion die;
compression molding a predetermined section of said profiled strip while it is still in a thermoformable state into a predetermined shape at a close proximity from the extrusion die with a set of compression molding dies capable of traveling with the profiled strip at substantially the same speed for a sufficient length of time to permanently set said predetermined shapes said compression molding dies equipped with a fade away open of at least 1 mm per 300 mm die length;
disengaging said compression molding dies from said profiled strip at a predetermined distance from said extrusion die;
cooling said profiled strip having said compression molded predetermined shape in a suitable cooling fluid such that said predetermined shape is permanently maintained; and trimming said extruded profiled strip into discontinuous pieces each having said compression molded predetermined shape.
3. In the method of claim 1, said polymeric material being selected from the group containing polyvinyl chloride, polyethylene, polypropylene, and acrylonitrile-butadiene-styrene polymer.
4. In the method of claim 1, said compression molding dies are further equipped with cooling means to maintain said dies at a temperature between 50°F to 90°F.
5. In the method of claim 1, said predetermined shape being a leading end and a trailing end of a molding piece.
6. In the method of claim 1, said profiled strip being a reinforcing metal foil extrusion coated with said polymeric material.
CA 2017526 1989-11-13 1990-05-25 Extrusion shaping method Expired - Fee Related CA2017526C (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US43415689A 1989-11-13 1989-11-13
US07/434,156 1989-11-13

Publications (2)

Publication Number Publication Date
CA2017526A1 CA2017526A1 (en) 1991-05-13
CA2017526C true CA2017526C (en) 1994-06-14

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
CA 2017526 Expired - Fee Related CA2017526C (en) 1989-11-13 1990-05-25 Extrusion shaping method

Country Status (1)

Country Link
CA (1) CA2017526C (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2015042128A3 (en) * 2013-09-20 2015-07-09 3M Innovative Properties Company Masking tape comprising a gap filling portion

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107498886B (en) * 2017-07-31 2024-03-26 东莞市那宏五金科技有限公司 Silica gel and metal combined treatment process

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2015042128A3 (en) * 2013-09-20 2015-07-09 3M Innovative Properties Company Masking tape comprising a gap filling portion

Also Published As

Publication number Publication date
CA2017526A1 (en) 1991-05-13

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