CA1338926C

CA1338926C - Heat reflecting sandwich plate

Info

Publication number: CA1338926C
Application number: CA000606636A
Authority: CA
Inventors: Jun Kawaguchi; Tatsuya Hyodo; Takaharu Miyazaki
Original assignee: Nippon Sheet Glass Co Ltd
Current assignee: Nippon Sheet Glass Co Ltd
Priority date: 1988-07-27
Filing date: 1989-07-25
Publication date: 1997-02-25
Anticipated expiration: 2014-02-25
Also published as: IT1230990B; GB2222984A; DE3924935C2; GB2222984B; GB8917008D0; DE3924935A1; FR2634904A1; IT8921306A0; FR2634904B1

Abstract

Disclosed herein is a heat reflecting sandwich plate made up of a first and a second transparent plates bonded together with a transparent resin film. The first transparent plate is coated on the inside thereof with a heat reflecting film which is a laminate composed of two metal oxide layers, with a noble metal layer intervening between them. The noble metal layer has a sheet resistance of 4-10 ohms/square. The first and second metal oxide layers have thicknesses controlled such that their ratio is in the range of 1.1 to 1.6.
The heat reflecting sandwich plate produces reflected rays which have a chromaticness specified by -1 a 1 and -1 b 1, where a and b denote the chromaticness indices of Hunter's color specification system, and has a visible light reflectivity lower than 10%.
Because of these characteristic properties, the heat reflecting sandwich plate has high strength and safety, exhibits outstanding heat reflecting performance, and assumes almost no color and looks good despite its comparatively high visible light transmittance.

Description

BACKGROUND OF THE INVENTION
Field of the Invention:
The present invention relates to a sandwich plate composed of a pair of transparent plates such as glass, synthetic resin or the like, and a transparent interlayer of synthetic resin, said sandwich plate being rendered capable of heat reflection. The heat reflecting sandwich plate is suitable as vehicle and building window glass.
Description of the Prior Art:
There has been known sandwich glass made up of a pair of glass sheets (made by, for example, float process) bonded together with an interlayer of transparent synthetic resin such as polyvinyl butyral.
The sandwich glass of such multilayered structure has high strength and safety owing to the interlayer's ability to prevent the glass plates from shattering in the event of breakage.
A disadvantage of the sandwich glass used as vehicle and building window glass is that it transmits a large amount of solar radiant energy into the vehicle and building, causing the room temperature to rise unnecessarily, particularly in summer.
~' There is disclosed in U.S. Patent No. 4,337,990 a heat reflecting glass prepared by forming a first metal oxide layer, a noble metal layer, and a second metal oxide layer consecutively on a glass sheet. The first and second metal oxide layers have almost the same thickness so that the three layers give rise to, by their light interference, a low reflectivity for light of wavelength 550 nm(nanometer) having a high visual sensitivity and yet give rise to a high transmittance for visible light.
The heat reflecting glass disclosed in the above-mentioned U.S. Patent gives a reflective spectrum which indicates the strong reflection in the longer (red) side and shorter (blue) side of the visible region. This spectral characteristic causes the heat reflecting glass to produce a dazzling reflected ray of purplish color for the incident rays on either sides.
Because of this colored reflected rays, the heat reflecting glass as vehicle and building window glass is out of harmony with the exterior of the vehicle and building.
SUMMARY OF THE INVENTION
It is an object of the present invention to provide a heat reflecting sandwich plate which has high strength, high safety (ability to prevent shattering in the event of breakage), outstanding performance of heat reflection, and comparatively high transmittance for visible light, and yet looks good and takes on almost no color.
The present invention provides a heat reflecting sandwich plate made up of a first and a second transparent plates such as glass, synthetic resin or the like, bonded together with a transparent resin film, characterized in that the first transparent plate is coated on the inside thereof with a heat reflecting film which intervenes between the first transparent plate and the transparent resin film, said heat reflecting film being a laminate composed of a first metal oxide layer, a noble metal layer, and a seco~d metal oxide layer formed consecutively on the inside of the first transparent plate, and the first and second metal oxide layers having thicknesses controlled such that their total thickness is 500-900 ~ and the ratio of the thickness of the first metal oxide layer to the thickness of the second metal oxide layer or the ratio of the thickness of the second metal oxide layer to the thickness of the first metal oxide layer is in the range of 1.1 to 1.6, preferably 1.2 to 1.5, the noble metal layer has a sheet resistance of 4-lO ohms/square, and the heat reflecting sandwich plate produces reflected rays which have a chromaticness specified by -1 ~ a < l and -1 < b < 1, where a and b denote the chromaticness indices of Hunter's color specification system, and has a visible light reflectivity lower than 10%.
According to the present invention, the noble metal layer is required to have a sheet resistance of 4-10 ohms/square for the reason mentioned below. With a sheet resistance smaller than 4 ohms/square, the noble metal layer produces such a striking chromaticness on account of its excessively high visible light reflectance that the reflected rays from the sandwich plate has a chromaticness whose "a" and "b" are outside the range specified above. Conversely, with a sheet resistance greater than lO ohms/square, the noble metal layer does not reflect heat rays consistently and tends to decrease in visible light transmittance on account of its oxidation. In the case where the noble metal layer is made of silver and has a sheet resistance of 4 ohms/square, it would have a thickness of 130 to 270 ~, depending on the method of preparation. With a sheet resistance of 10 ohms/square, it would have a thickness of 60 to 150 ~, depending on the method of preparation.

Therefore, the noble metal layer may be 60-270 ~ thick if it is made of silver or a silver alloy.
According to the present invention, the first and second transparent plates should preferably be sheet glass made by, for example, float process. They may be properly colored according to need so long as they have a visible light transmittance required. In addition, they may have any desired thickness according to applications; but the adequate thickness is in the range of 0.5 to 5 mm, preferably 1 to 3 mm.
According to the present invention, the first and second metal oxide layers have thicknesses which are controlled such that their total thickness is 500-900 A
and the ratio of the thickness of the first metal oxide layer to the thickness of the second metal oxide layer or the ratio of the thicknéss of the second metal oxide layer to the thickness of the first metal oxide layer is in the range of 1.1 to 1.6. These requirements are essential for the heat reflecting sandwich plate to produce reflected rays which have a chromaticness specified by -1 < a < 1 and -1 < b < 1, where a and b denote the chromaticness indices of Hunter's color specification system. Thus, the sandwich plate takes on a quiet color.

According to the present invention, the first and second metal oxide layers each may have a refractive index in the range of 1.9 to 2.1 and a thickness in the range of 190 to 690 ~.
According to the present invention, the first and second metal oxide layers each may be made of any of tin oxide, indium oxide, tin oxide-containing indium oxide (referred to as ITO hereinafter), zinc oxide, or antimony oxide. The two metal oxide layers may be made of the same oxide or different oxides. Usually, the tin oxide is stannic oxide (SnO2), the indium oxide is diindium trioxide (In2O3), the zinc oxide is zinc oxide (ZnO) free of zinc suboxide, and the antimony oxide is diantimony pentoxide (Sb2O5) .
According to the present invention, the noble metal layer may be made of one or more than one member selected from gold, silver, copper, palladium, and rhodium. Preferable among them is silver because of its low visible ray absorption. It is desirable that silver be used in combination with a small amount of at least one member selected from gold, copper, palladium, and rhodium, because silver alone lacks sufficient chemical resistance such as moisture resistance, alkali resistance, and arid resistance. The amount of gold and copper should preferably be less than 2% and the amount of palladium and rhodium should preferably be less than 1%,and in the case where two or more kinds of minor noble metals are used, their total amount should be less than 2%; otherwise, the minor noble metal changes the color of the noble metal layer made of silver alone, decreasing the visible light transmittance. The noble metal layer should preferably have a thickness in the range of 30 to 300 ~.
According to the present invention, the transparent resin film may be made of any material so long as it is transparent in the visible region, has almost the same refractive index as that of the transparent plate (about 1.52 in the case of sheet glass), and has good adhesion to both the transparent plates and the heat reflecting film. An example of the transparent resin film is the one made of polyvinyl alcohol resin (such as polyvinyl butyral), vinyl acetate resin (such as ethylene vinyl acetate), thermoplastic polyurethane resin, or polyvinyl chloride resin.
Polyvinyl butyral film is preferable. The film thickness may be in the range of 0.05 to 0.4 mm, preferably 0.1 to 0.2 mm.

1 33892~

According to the present invention, the heat reflecting sandwich plate should preferably have a visible light transmittance higher than 80% and a solar radiant energy transmittance lower than 75%, so that it permits the sufficient transmission of visible light and yet cuts off a certain amount of solar radiant energy.
The heat reflecting sandwich plate of the present invention may be produced in the following manner. On the inside of the first glass plate are formed the first metal oxide layer, the noble metal layer, and the second metal oxide layer consecutively.
The first glass plate, the transparent resin film (in the form of sheet), and the second glass plate are laminated one top after another. The resulting laminate is heated at 130-180C under a pressure of 1-5 kg/cm2, so that the transparent resin film is fusion-bonded to the second metal oxide layer on the first glass plate and also to the inside of the second glass plate. The laminate is cut to desired size and shape.
Where the heat reflecting sandwich plate of the present invention is used as vehicle and building window glass, it is usually mounted such that the first transparent plate (on which the heat reflecting film is coated) faces outside. The thus mounted heat reflecting sandwich plate reflects light on both sides, the reflected rays assuming substantially the same chromaticness. Since vehicles and buildings are usually bright outside and dark inside, the reflected light is a matter of concern when viewed from outside and the transmitted light is a matter of concern when viewed from inside. The heat reflecting sandwich plate of the present invention gives almost colorless reflected light and transmits visible light sufficiently.
The heat reflecting sandwich plate of the present invention has a high strength and is hard to break, because it is of multilayered structure composed of the first transparent plate (on which the heat reflecting film is coated), and the second transparent plate which are bonded together with the transparent resin film. =-The heat reflecting sandwich plate of thepresent invention prevents shattering and hence secures great safety because the first and second transparent plates are bonded together with the transparent resin film, so that, when broken, the transparent plates tend to adhere to the resin film rather than fly.
According to the present invention, the heat reflecting film coated on the inside of the first _g_ transparent plate is composed of two metal oxide layers and one noble metal layer intervening between them. The two metal oxide layers have thicknesses which are controlled such that their total thickness is in the range of 500 to 900 ~, with their ratio being 1.1 to 1.6. The sandwich plate produces reflected rays which have a chromaticness specified by -1 < a < 1 and -1 < b ~ 1, where a and b denote the chromaticness indices of Hunter's color specification system, and has a visible light reflectivity lower than 10%. Thus, the present invention provides a heat reflecting sandwich plate which exhibits good performance of heat reflection and permits a comparatively high visible light transmittance, and yet assumes almost no color and looks good.
The above and other objects, features, and advantages of the present invention will be readily understood by the following detailed description in conjunction with the accompanying drawing.
BRIEF DESCRIPTION OF THE DRAWING
The single drawing is a partial longitudinal sectional view showing the heat reflecting sandwich plate of the present invention.
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

A glass plate 10 (for example 2.1 mm thick) was coated with a first metal oxide layer (for example 238 thick) 11 of ITO (which is tin oxide-containing indium oxide composed of 10% tin oxide and 90% indium oxide, the same shall apply hereinafter) by sputtering. The sputtering was carried out in an atmosphere composed of argon and oxygen at a pressure of, for example, 0.4 Pa (Pascal [neuton/m2]), using a sintered body composed of tin oxide and indium oxide as the target. The first metal oxide layer 11 was further coated with a noble metal layer 12 of silver having a sheet resistance of 9 ohms/square by sputtering. The sputtering was carried out in an argon atmosphere at a pressure of, for example, 0.4 Pa, using silver as the target. The noble metal layer 12 was further coated with a second metal oxide layer (for example, 262 A thick) 13 of ITO by sputtering. The sputtering was carried out in an atmosphere composed of argon and oxygen at a pressure of, for example, 0.4 Pa, using a sintered body composed of tin oxide and indium oxide as the target. On the second metal oxide layer 13 were laminated a, for example, 0.15 mm thick transparent resin film of polyvinyl butyral 14 and a, for example, 2.1 mm thick glass plate 15 on top after another. The resulting 1 33~926 laminate was heated at, for example, 150C and pressed under a pressure of, for example, 3 kg/cm2 so that the polyvinyl butyral film 14 was fusion-bonded to the second metal oxide layer 13 on the glass plate 10 and also to the glass plate 15. The laminated product was trimmed to desired size. Thus there was obtained a transparent heat reflecting sandwich plate as shown in the accompanying drawing.
Heat reflecting sandwich plates of the same structure as mentioned above were prepared except that ITO for the first metal oxide layer 11 was replaced by ZnO, ITO for the second metal oxide layer 13 was replaced by ZnO or SnO2, and silver for the noble metal layer 12 was replaced by Ag-0.5%Cu alloy or Ag-1%Au alloy. In addition, heat reflecting sandwich plates of the same structure as mentioned above were prepared except that the thicknesses of the first and second metal oxide layers 11 and 13 were varied in the range of 200 to 540 ~ and the sheet resistance of the noble metal layer 12 was varied in the range of 6 to 9 ohms/square.
Tables 1 to 12 given below show the performance of the heat reflecting sandwich plates prepared in Examples of this invention as mentioned above. Table 13 shows the per~ormance of the heat reflecting sandwich plate prepared in Comparative Example. In tables 1 to 13, Hunter Chroma. means the chromaticness indices of Hunter's color specification system. The heat reflecting sandwich plates shown in Tables 1 to 13 have the first metal oxide layer 11, the noble metal layer 12, and the second metal oxide layer 13 which were made of the following materials.
Examples Table 1 ITO / Ag / ITO
Table 2 ITO / Ag / ITO
Table 3 ITO / Ag / ITO
Table 4 ITO / Ag / ITO
Table 5 ITO / Ag / ITO
Table 6 ITO / Ag / ITO
Table 7 ITO / Ag / ITO
Table 8 ITO / Ag / ITO
Table 9 ZnO / Ag / SnO2 Table 10 ZnO / Ag / ZnO
Table 11 ITO / Ag-0.5%Cu / ITO
Table 12 ITO / Ag-1%Au / ITO
Comparative Example Table 13 ITO / Ag / ITO

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Tables 1 to 13 indicate the following.
(1) In Comparative Example shown in Table 13, the heat reflecting sandwich plate gives the Hunter chromaticness "a" and "b" whose absolute values are greater than 1, because the first metal oxide layer (11) and the second metal oxide layer (13) have such thicknesses that their ratio is 1Ø

(2) In Examples of this invention shown in Table 1 to 12, the heat reflecting sandwich plates give the Hunter chromaticness "a" and "b" whose absolute values are smaller than 1. In the case where the ratio of the thicknesses of the first and second metal oxide layers 11 and 13 is in the range of 1.2 to l.S, the heat reflecting sandwich plate gives the Hunter chromaticness "a" and "b" whose absolute value are sufficiently smaller than 1, compared with the case in which the ratio is 1.1.
Therefore, the heat reflecting sandwich plate in Comparative Example shown in Table 13 gives dazzling reflected light of purplish color, as mentioned above as prior art, whereas those in Examples of this invention shown in Tables 1 to 12 give almost colorless reflected light and hence look good.

Having described illustrative embodiments of the invention with reference to the accompanying drawing, it is to be understood that the invention is not limited to such precise embodiments, and that various changes and modifications may be effected therein by one skilled in the art without departing from the scope and spirit of the invention as defined in the appended claims.

Claims

1. A heat reflecting sandwich plate made up of a first and a second transparent plates bonded together with a transparent resin film, characterized in that the first transparent plate is coated on the inside thereof with a heat reflecting film which intervenes between the first transparent plate and the transparent resin film, said heat reflecting film being a laminate composed of a first metal oxide layer, a noble metal layer, and a second metal oxide layer formed consecutively on the inside of the first transparent plate, and the first and second metal oxide layers having thicknesses controlled such that their total thickness is 500-900 .ANG. and the ratio of the thickness of the first metal oxide layer to the thickness of the second metal oxide layer or the ratio of the thickness of the second metal oxide layer to the thickness of the first metal oxide layer is in the range of 1.1 to 1.6, the noble metal layer has a sheet resistance of 4-10 ohms/square, and the heat reflecting sandwich plate produces reflected rays which have a chromaticness specified by -1 a 1 and -1 b 1, where a and b denote the chromaticness indices of Hunter's color specification system, and having a visible light reflectivity lower than 10%.

2. A heat reflecting sandwich plate as claimed in Claim 1, wherein the first and second transparent plates are sheet glass.

3. A heat reflecting sandwich plate as claimed in Claim 2, wherein the first and second metal oxide layers have a refractive index in the range of 1.9 to 2.1.

4. A heat reflecting sandwich plate as claimed in Claim 2, wherein the ratio of the thickness of the first metal oxide layer to the thickness of the second metal oxide layer or the ratio of the thickness of the second metal oxide layer to the thickness of the first metal oxide layer is in the range of 1.2 to 1.5.

5. A heat reflecting sandwich plate as claimed in Claim 4, wherein the first and second metal oxide layers each is made of any of tin oxide, indium oxide, tin oxide-containing indium oxide, zinc oxide, or antimony oxide (the two metal oxide layers may be made of the same oxide or different oxides).

6. A heat reflecting sandwich plate as claimed in Claim 4, wherein the noble metal layer is made of one or more than one member selected from gold, silver, copper, palladium, and rhodium.

7. A heat reflecting sandwich plate as claimed in Claim 6, wherein the noble metal layer is made of silver as the major constituent and a small amount of at least one member selected from gold, copper, palladium, and rhodium.

8. A heat reflecting sandwich plate as claimed in Claim 6, wherein the noble metal layer is made of silver.

9. A heat reflecting sandwich plate as claimed in Claim 6, wherein the transparent resin film is made of polyvinyl butyral.

10. A heat reflecting sandwich plate as claimed in any one of Claims 1 to 9, which has a visible light transmittance higher than 80% and a solar radiant energy transmittance lower than 75%.