CA1313175C - Aqueous fluid absorbing polymer beads produced from a suspension polymerization of water soluble monomers and methods for improving the hydration rate of such beads - Google Patents

Abstract

ABSTRACT
This invention relates to suspension polymerization processes, to aqueous fluid-absorbing polymer beads prodiced from those processes, to suspending agents employed in said processes and to a method of using wetting agents to improve the hydration rate of the aqueous fluid-absorbing polymer beads.
Wetting agents such as polyols which do not reduce the surface tension of a supernate (provided by a standard test method) below 56 dynes/cm, can improve the hydration rate of aqueous fluid absorbent polymer beads produced by a suspension polymerization process. The wetting agent is useful in a water-in-oil suspension polymerization process wherein the suspending agent comprises a fumed silica particulate having a hydrophobic character and a hydrophobia polymer.

34,000B-F

Description

l 131317S

AQUEOUS FLUID ABSORBENT POLYME~ BEADS, PROCESS FOR PREPARING THE SAME
AND SUSPENDING AG~NT EMPLOYED THEREIN

This invention relates to suspension polymerization processes, to aqueous fluid-absorbing polymer beads produced from those processes, to suspending agents employed in said process and to a method of using wetting agents to improve the hydration rate of the aqueous fluid absorbing polymer beads.

Various water-soluble polymers such as polyacrylamide and copolymers of acrylamide with other anionic, cationic or nonionic monomers are well-known to be precipitants or flocculants for many substrates including sewage, cellulosic fibers and fines for retention and freeness, effluent waste for metal production and coal tailings. Such polymers are also known to exhibit superior thickening propePties when said polymers are dissolved in aqueous media.
Particularly well known for this purpose are the anionic polyacrylamides such as acrylamide/acrylic acid copolymers, including those prepared by hydrolysis of polyacrylamide. Such polymers are also very useful as .~ ~ ~

~ 34,000B-F -1-.

. .
. . .

fluid mobillty control agent~ in enhanced oll recovery processes.
In the past, water-soluble polymers have been made available commercially as powders or finely divided solids which are dlssolved in an aqueous medium ~ in order to be used. ~Becaue such dissolution steps are sometimes time consuming and often require rather expensive mixing equipmentl it has become a common praotice to formulate the water-soluble polymers in water-in-oil emulsions wherein the polymer is dissolved in the dispersed aqueous phase. Such emulsions, as well as methods for preparing them, are described in U.S. Patents 3,284,393; 3,826,771 and 4,052,353.
More recently, water-swellable polymers which absorb aqueous fluids have been sought. These aqueous fluid absorbents are conveniently prepared by polymerizing water-soluble monomers such as acrylic acid in the presence of a crosslinking agent in order to provide highly swellable polymeric materials. Such water-swellable polymers have been used in articles which absorb body fluids such as sanitary napkins, incontinent devices and disposable baby diapers. Such types of aqueous fluid absorbents (water-swellable polymers) and materials provided therefrom are disclosed in U.S. Patents 4~511,477; 4,500,-670;
4,424,247; and 4,293,609.
Suspension polymerization processes provide several advantages in the preparation of water-soluble polymers and water-swellable polymers. The reaction temperature and rate of reaction can be controlled due to the heat transfer properties attendant in such types of polymerization processes. For example, the reaction 34,000B-F -2-3 ~31:3~75 temperature can be controlled by means o~ ebullient cooling. In addition, the polymer product so provided in water-in-oil suspension polymerization processes can be conveniently separated from the oil phase using relatively efficient and cost-effectlve technlques such as filtration or centrifugation because such polymer is shaped like a bead. Unfortunately, a suspension polymerization process for such water-swellable polymers can cause a reduced hydration rate or decreased hydrophilicity, of the resulting water-swellable polymer beads. Therefore, improvements in the preparation of water-swellable polymers is clearly desirable.
Surfactants in suspension polymerizations of water-swellable polymers have been shown to be useful during polymerizations, for example, in U.S. Patent No.
4,446,261. Such surfactants have also been introduced in post polymerization additions or during polymerization additions for example in U.~. Patent Nos. 4,459,396 and 4,270,977, The use of these nonionic, ionic and cationic surfactants may improve the hydration rate of the water-swellable polymer but 25 they can inhibit the fluid absorbency of the resulting fluid absorbent device in which the water-swellable polymers are incorporated. For example, surfactants may interfere with the desired wicking of fluids by fibers in.the absorbent s~ruc~ture of a disposable .
3 diaper.

In view of the deficiencies of the prior art, it would be highly desirable to provide an improved process for polymerizing water-soluble monomers using water-in-oil suspension polymerization techniques;
; which process is capable of employing high concen-- 34,000B-F -3-4 i;31;~75 trations of monomer ln the aqueous phase without substantial agglomeration of polymer, and which process can be employed in providing crosslinked water-swellable polymers of a controlled particle size resulting in a polymer bead.
Accordingly, it wou~d also be desirable to improve the hydration rate of the polymer beads once polymerized from a suspension polymerization process without decreasing the hydration rate of the resultant fluid absorbing device which can be accomplished by using a wetting agent which does not reduce the surface tension of a supernate (provided by a standard test method described herein below~ below 56 dynes/cm.
The present invention is a suspending agent useful in suspension polymerization processes, said suspending agent comprising (1) a particulate material comprising a hydrophobic character, and (2) a polymer having a substantially hydrophobic character said polymer having hydrophobic moieties pendant from the backbone thereof.
The aforementioned suspending agent is particularly useful in water-in-oil suspension polymer-ization processes.
In another aspect, the present invention is an .oil phase useful in water-in-oil suspension polymeri-3 zation processes, said oil phase comprising the afore-mentioned suspending agent.
In yet another aspect, the present invention is a water-in-oil suspension polymerization process wherein water-soluble monomers are polymerized, said process comprising:
.

34,000B-F -4- .

(1) providing an aqueous phase comprising water and at least one water-soluble monomer;

(2) providing an oil phase comprising an inert hydrophobic liquid and the aforementioned suspending agent; and (3) contacting the aqueous phase and the oil phase under conditions such that a water--in-oil sus.pension of polymer comprising polymerized water-soluble monomer is provided.
Another aspect of the present invention is the aqueou~-fluid absorbent polymer beads prepared from the water-in-oil suspension polymerization of water soluble monomers which comprises:
(1) providing an aqueous phase comprising water and at least one water-soluble monomer;
(2) providing an oil phase comprising an inert hydrophobic liquid and a suspending agent comprising:
(a) a particulate material comprising a hydrophobic character, and (b) a polymer having a substantially hydrophobic character said polymer having hydrophobic moieties pendant .from the backbone thereof;.and 3 ~3) contacting the aqueous phase and the oil - phase under.conditions such-that a water-in-oil suspension of polymer beads - . comprising polymerized water-soluble monomer is provided.

34,000B-F . -5- .

131~i~5 In yet another aspect, the present invention is a method for improving the hydration rate of polymer beads prepared from a suspension polymerization by using a wetting agent which does not reduce the surface tension of a supernate (provided by a standard test method described herein below) bel`ow 56 dynes/cm. The wetting agent can be used in the water-in-oil suspension polymerization stated above or in other suspension polymerization processes where improved 0 hydration rate in the resultant water-swellable polymer or bead is desired.
In one aspect, the method for improving the hydration rate of aqueous-fluid absorbing beads from a suspension polymerization of water soluble monomers comprises:
(1) suspension polymerizing the water-soluble monomers to produce aqueous fluid-absorbing beads;
(2) removing the water from the suspension;
(3) adding a wetting agent which does not reduce the surface tension of a supernate (provided by a standard test method) below . 56 dynes/cm, in an amount sufficient to improve the hydration-rate of.the beads;
and (4) drying the-beads.
Ideally, the hydration rate of the polymer beads is improved without destroying the advantageous properties which the polymer bead provides in aqueous--fluid absorbing polymer materials.
Another aspect of the present ~invention is the improved hydration rate of the water-swellable polymer 34,000B-F -6-beads achieved by reducing the molecular weight of the polymer portion of the suspending agent used.
In another aspect, the ~ethod for improving the hydration rate of aqueous-fluid absorbing beads from a suspension polymerization of water soluble monomers comprises:
(1) providing an aqueous phase comprising ~ water and at least one water-soluble~
monomer;
(2) providing an oil phase comprising an inert hydrophobic liquid and a suspending agent comprising:
(a) hydrophobic fumed silicon dioxide and (b) a copolymer of acrylic acid and lauryl methacrylate having a molecular weight of from 100,000 to 300,000; and (3) contacting the aqueous phase and the oil phasé under conditions such that a water-in-oil suspension of polymer beads comprising the polymeri~ed water-soluble monomer is provided.

A final aspect of the present invention is the method of using the wetting agent in the suspension pOlymerization of water-soluble monomers which comprises:
(1) providing an aqueous phase comprising water and at least one water-soluble monomer;
(2) providing an oil phase comprising an inert hydrophobic liquid and a suspending agent comprising: `
. (a) hydrophobic fumed silicon dioxide and 34,000B-F -7-. .. .

'` iT~1.3~75 ~b) a copolymer of acrylic acid and lauryl methacrylate;
(3) contacting the aqueous phase and the oil phase under conditions such that a water--in-oil suspension of polymer comprising polymerized water-soluble monomer is provided;
(4) removing the water from the suspension;

(5) adding a wetting agent which does not ! 1O reduce the surface tension of a supernate tprovided by a standard test method) below 56 dynes/cm, in an amount sufficient to improve the hydration rate of the bead;
and (6) drying the polymer beads.
In addition to their utility as additives in drilling muds, fracturing fluids and fluid mobility : 20 control agents in enhanced oil recovery methods, the water-soluble polymers or water-swellable polymer beads prepared in accordance with the practice of the present invention are also useful as flocculating agents for sewages, industrial wastes, mining streams such as coal slurries and mining effluents, as thickeners for coating formulations, as additives for the manu~acture of paper, and in a variety of other uses common for ! , ~uch polymers prepared by other conventional . polymerization methods.
Polymers comprising a crosslinked character and which are swellable in aqueous fluids are useful as aqueous fluid absorbent compositions. In preferred embodiments, such aqueous fluid absorbent polymer compositions can absorb several times their weight of an aqueous liquid, preferably more than 15 times their 34,000B-F -8- . .

9 13~75 weight in water. Such compositions can be employed in a wide variety of applications as are disclosed in U.S.
Patents 4,424,247; 4,511,477; 4,293,609 and 4,486,374.
Surprisingly, the use of the aforementioned suspending agent, when employed in suspension polymeri-zation procèsses, can~provide a polymerization product which exhibits a controlled particle size distribution, `a polymer bead. In addition, the polymerization products can be effectively dried using relatively energy efficient techniques such as steam distillation or azeotropic distillation. Of particular interest is the use of the suspending agent of this invention in providing water-swellable polymer bead products o~
controlled particle size. Further, the hydration rate of the beads can then be improved by the addition of a wetting agent which does not reduce the surface tension of a supernate (provided by a standard test method described herein below) below 56 dynes/cm.
Further, the process of making the beads can be more efficient when the wetting agent is added after polymerization but prior to the actual drying of the beads, resulting in the need for drying the beads only once. If the wetting agent is added after the beads have been dried, a second drying is required to drive off the diluent for the wetting agent.
The present invention is practiced in the preparation of water-in-oil suspensions containing a polymer prepared from water-soluble monomers. Such suspensions are those wherein the dispersed phase is an aqueous phase having contained therein said polymer, and the continuous oil phase is a water-immiscible inert organic liquid. Advantageously, the suspension 34,000B-F -9~ -- l o- 1313~75 comprises preferably from 90 to 30, preferably from 60 to 40, weight percent dispersed (i.e., aqueous) phase based on the total weight of the suspension. The amount of polymer contained in the suspension can vary providing that the resulting suspension is stable, and is advantageously from 10 to`50, more preferably from 20 to 40, weight percent polymer based on the total weight of the suspension. In the suspensions, the weight ratio of water to polymer in the aqueous phase can vary and is desirably from 0.01:99 to 9:1, more preferably from 4:1 to 0.67:1, and most preferably from 2.33:1 to 1.5:1.
For the purposes of this invention, the water--soluble polymer contained in the aqueous phase of the suspension is one that forms a thermodynamically stable mixture when combined with water. These mixtures form spontaneously and include true solutions in which the individual polymer molecules are dispersed as well as micellar or colloidal solutions wherein the polymer molecules are aggregated to some extent, but wherein such aggregates are no larger than colloidal size.
Accordingly, such water-soluble polymers are generally homopolymers and copolymers of water-soluble ethylen-ically unsaturated monomers.
Suitable water-soluble monomers include those that are at least water-miscible and that are preferably ~ufficiently water-soluble to form at least a 5 weight percent solution when dissolved in water and readily undergo addition polymerization to form polymers that are water-soluble. Exemplary water--soluble mono~ers include ethylenically unsaturated amides such as ~crylamide, methacry~lamide and fumaramide; their N-substituted derivatives such as 34,00.0B-F -10-- l l 1313175 2-acrylamide-2-methylpropane sulfonic acid (AMPS), N-(dimethylaminomethyl)acrylamide as well as N-(trimethylammoniummethyl)acrylamide chloride and N-(trimethylammoniumpropyl)methacrylamide chloride;
ethylenically unsaturated carboxylic aoids such as acrylic acid, methacrylic acid, itaoonic acid and fumaric acid; ethylenically unsaturated quaternary ~ammonium compQunds such as vinylbenzyl trimethyl ammonium chloride, sulfoalkyl esters of unsaturated 0 carboxylic acids such as 2-sulfoethyl methacrylate;
aminoalkyl esters of unsaturated`carboxylic acids such as 2-aminoethyl methacrylate and 2-(N,N-dimethylamino)--ethyl methacrylate as well as the quaternized deriva-tives thereof such as acryloylethyl trimethyl ammonium chloride; vinyl amines such as vinyl pyridine and vinyl morpholine, diallyl amines and diallyl ammonium com-pounds such as diallyl dimethyl ammonium chloride;
vinyl heterocyclic amides such as vinyl pyrrolidone;
vinylaryl sulfonates such as vinylbenzyl sulfonate as well as the salts of the foregoing monomers. Of the foregoing water-soluble monomers, acrylamide and combinations of acryla~ide and acrylic acid are preferred. Homopolymers of acrylic acid can also be prepared. Homopolymers prepared from acrylamide and copolymers prepared from combinations thereof with other water-soluble monomers are more preferred. Also preferred are polymers wherein the water-soluble monomers range from 5 to 99 mole percent of acryiamide and/or partially hydrolyzed acrylamide and from 1 to 5 mole percent of other water-soluble monomers. Of particular interest are lightly crosslinked polymers such as polyacrylic acid polymers, sodium polyacrylate polymers, and copolymers of polymerized acrylic acid and sodium acrylate; which polymers are copolymerized ~ , -` 34,000B-F -11-1~13175 with polyvinyl monomers such as trimethylolpropane triacrylate.
The water-immiscible oil phase of the suspen-sion generally comprises at least one inert hydrophobicliquid. Usually such liquid is an organic compound which,is normally liquid at the conditions at which the suspension is used in the polymerization process.
Operable liquids include hydrocarbons or substituted hydrocarbons. Preferred organic liquids are the halogenated hydrocarbons such as, for example, perchloroethylene and methylene chloride as well as liquid hydrocarbon having from 4 to 15 carbons per molecule, including aromatic and aliphatic hydrocarbons and mixtures thereof, e.g., benzene 9 xylene, toluene, mineral oils and liquid paraffins such as kerosene and naphtha. Of the foregoing organic liquids, the hydrocarbons are the more preferred, with aliphatic hydrocarbons being most preferred.
The suspension polymerization processes are performed by following the general procedures described in the art as exemplified in U.S. Patents 4,340,706;
4,367,323 and 4,446,261. In the process of this invention, an aqueous phase containing water-soluble monomer(s) typically is dispersed in the inert hydrophobic liquid which contains the suspending agent of this invention. Typically, it is desirable to agitate the resulting composition. Factors, such as the rate of agitation of the composition, control properties such as the droplet or particle size of the suspended aqueous phase.
The suspending agent of this invention comprises two necessary components; the particulate 34,000B-F -12-1 3 1:3131~5 material having a hydrophobio character and the polymer having a substantially hydrophobic character.
The particulate material comprising a hydrophobic character can be descri'bed as an amorphous, highly oil dispersible, approximately micron size, substantially wat'er-insoluble particulate material.
Typioally, the size of the particulate material ranges from less 'than 1 micron to several microns in diameter. ~ ' The particulate material is most preferably hydrophobic, for example, silicon dioxide, the particulate material provided by the reaction of silica with polydimethyldichlorosilane. Other useful particulate materials include hydrophobic clays such as the cationic surfactant treated bentonite clays. An example of a hydrophobic clay is sold commercially as Bentone~ 34 by N. L. Industries.
The polymer having a substantially hydrophobic character has hydrophobic moieties pendant from the backbone thereof. The hydrophobic groups of the polymer having a substantially hydrophobic character are preferably pendant organic groups having hydro-phobicities comparable to one of the following:aliphatic hydrocarbon groups having at least four - . carbons such as C4 to C20 alkyls and cycloalkyls;
aromatic hydrocarbon groups such as alkylaryls wherein alkyl has one or more carbons, preferably 4 to 8 30' carbons; haloalkyls of 4 or more carbons, preferably perfluoroalkyls; polyalkyleneoxy groups wherein alkylene is propylene or higher alkylene and there is at least 1 alkyleneoxy unit per hydrophobic moiety.
3~ Suitable hydrophobic monomers include those which are (1) water-insoluble, i.e., less than 0.4, 34,000B-F -13-13~317~;

preferably 0.2, weight part of the hydrophobic monomer will dissolve in lO0 weight parts water and (2) ethylenically unsaturated compounds having hydrophobic groups as defined hereinbefore. Exemplary hydrophobic monomers include the higher alkyl esters of ~ ethylenically unsaturated carboxylic acids such as dodecyl acrylate, dodecyl methacrylate, tridecyl acrylate~, tridecyl methacrylate, tetradecyl acrylate, tetradecyl methacrylate, octadecyl acrylate, octadecyl 0 methacrylate, ethyl half ester of maleic anhydride, diethyl maleate, and other alkyl esters derived from the reactions of alkanols having from 4 to 20, preferably from 8 to 20, carbon atoms with ethylenically unsaturated carboxylic acids such as acrylic acid, methacrylic acid, fumaric acid, itaconic acid and aconitic acid, and maleic anhydride; alkylaryl esters of ethylenically unsaturated carboxylic acids such as nonyl-~-phenyl acrylate, nonyl-a-phenyl methacrylate, dodecyl-~-phenyl acrylate and dodecyl-~-phenyl methacrylate; N-alkyl, ethylenically unsaturated amides such as N-octadecyl acrylamide, N-octadecyl methacrylamide, N,N-dioctyl acrylamide and similar derivatives thereof; ~-olefins of at least 8 carbon atoms, such as octene-1, decene-1, dodecene-1 and hexadecene-1; vinyl alkylates wherein alkyl'has at least 8 carbons such as vinyl laurate and vinyl stearate; vinyl alkyl ethers such as dodecyl vinyl' ether and hexadecyl vinyl ether;'N-vinyl amides such as N-vinyl lauramide and N-vinyl stearamide; and arylalkylstyrenes such as t-butyl styrene. Of the foregoing hydrophobic monomers, the alkyl esters of acrylio acid, methacrylic acid, N-alkyl acrylamides and N-alkyl methacrylamides wherein alkyl has from 8 to 20 carbon atoms, the alkyl styrenes wherein alkyl has from .
.

34,000B-F -14-~31317S

4 to 8 carbons such as t-butyl, are preferred. The alkylmethacrylates and alkylacrylates wherein alkyl has from 10 to 20 carbon atoms are more preferred. Dodecyl methacrylate and N-dodecyl methacrylamide are the most preferred where hydrolysis i9 not a problem.
The polymer having a substantially hydrophobic character is advantageously p-~epared by polymerizing the aforementioned hydrophobic monomers and optionally other monomers such as hydrophilic monomers in an oil phase using conventional initiators or catalysts.
Suitable hydrophilic monomers are those described above as water-soluble monomers. The polymers typically have molecular weights of 100,000 to 5 million. All molecular weights herein are determined by size exclusion chromatography.
The molecular weights of the polymer having a substantially hydrophobic character can affect the hydration rate of the resultant water-swellable polymer. The hydration rate of the resultant water--swellable polymer can be improved using a polymer having a lower molecular weight. When a lower molecular weight polymer is used in the suspending agent the resultant smaller water-swellable polymer beads generally have an improved hydration rate. ~or example, a water-swellable polymer b.ead having a mesh size of from 100 mesH (150 ~m3 to 325 mesh (45 ~m) can be produced using a polymer of the suspending agent having a molecular weight of from 100,000 to 300,000.
Aqueous fluid absorbing polymer beads can be produced having mesh sizes of from 30 mesh (550 ~m) to 200 mesh (75 ~m). Such beads can be pro~uced from the molecular 34,000B-F -15-- 1 6- 13~317~;

weight of the suspending agent polymer whlch can be from 500,000 to 5,000,000.
, The molecular weight of the suspending agent polymer can be controlled through conventional methods known in the art. For example, agents such as chain transfelr agents, mercaptans, alcohol's, and chlorinated hydrocarbons can be added or parameters can be controlled'during the polymerizatlon of the suspending agent polymer to control the molecular weight. The use of such agents and parameters to vary molecular weight is generally known to one skilled in the art.
The amount of hydrophilic monomer polymerized with the hydrophobic monomers depends upon factors such as the types of water-soluble polymers which are provided and typically ranges from greater than 0 to 15 percent. For example, the amount of hydrophilic monomer which is polymerized in the polymer having the substantially hydrophobic character can vary depending upon factors such as those attendant when water-soluble copolymers are prepared from two or more varying monomers.
The amount of components comprising the suspending agent can vary. ~he amount of each component depends upon factors such as the desired particle size distribution of the polymer product. The amou~t of each can conveniently range from 5 to 95 weight percent, relative to one another.
The amount of suspending agent employed depends upon factors such as that amount necessary to provide a suspended aqueous phase in the oil phase while employing an amount which'is economically.low. The ~ , 34,000B-F - , -16-i3~3~7S

amount typlcally ranges from 0.05 to 10 weight percent relative to the amount of water-soluble monomer which is being polymerized.
The suspending agent is incorporated into the oil phase using a variety of techniques. For example, it is desirable to contact the oi~ phase with the suspending agent under conditions which produce good mixing such as agitation.
Polymerization of the water-in-oil suspension of the water-soluble monomer(s) is advantageously effected under conventional conditions such as described in U.S. Patents 4,340,706; 4,367,323 and 4,446,261. Normally, such polymerization is practiced in the presence of a polymerization initiator capable of generating free-radicals. Preferably, this free-radical initiator is employed in amounts of from 0.01 to 0.1 weight percent of initiator based on the monomers. Exemplary polymerization initiators include the inorganic persulfates such as potassium persulfate, ammonium persulfate and sodium persulfate; azo catalysts such as azobisisobutyronitrile and 2~ dimethylazoisobutyrate; organic peroxygen compounds such as benzyl peroxide, t-butylperoxide, diisopropyl-benzene hydroperoxide, t-butyl hydroperoxide; and compounds such as sodium borohydride. Of these initiators, the organic types such as t-butyl hydroperoxide are preferred. In addition to the afore-mentioned ingredients, the suspension polymerization recipe optionally includes other ingredients, such as, for-example, chain transfer agents, chelating agents, buffers and salts.
s .

34,000B-F -17-~3175 - t 8 -.
If desired, a cro~slinking agent can be incorporated into the polymerization process. The crosslinking agent can be incorporated into the aqueous phase, the oil phase, or in the presence of both the aqueous phase and the oil phase. Preferably, the crosslinking agent is incorporated into the aqueous phase. The crosslinking agent can be employed in an amount sufficient to provide to the polymerization product an effective increase in molecular weight, or to impart to the polymerization product a water-swellable charaoter as is desirable in aqueous fluid absorbent compositions, or to provide a hydrogel product. For example, oil-soluble polyvinyl cross-linking monomers can be incorporated into the oil phase. Examples of polyvinyl crosslinking monomers include divinylbenzene, diethylene glycol diacrylate, propylene glycol dimethacrylate, allyl acrylate, diallyl fumarate and trimethylolpropanetriacrylate.
Examples of other crosslinking monomers include polyhaloalkanols; sulfonium zwitterions;
haloepoxyalkanes; polyglycidyl ethers;
aminoepihalohydrin adducts; multivalent metal ions such as aluminum or calcium and glycidyl acrylates. The amount of crosslinking agent depends upon a variety of factors, but typically ranges from 0.01 to 1 percent based on the weight of the polymer.
- A~ter the poIymeriza*ion reaction is complete, 3 the suspension can be employed in a variety of ways.
- For example, the suspension can be (a) employed às is, (b) treated using centrifugal techniques in order to - separate the polymer from the oil, (c) precipitated using agents such as methanoi or acetone, (d) filtered, or (e) spray dried.
' ' , .

34,000B-F -18-~13~7~;
_19_ The wetting agent can be added after the beads have been dried. Most economically, however, the wetting agent can be added after polymerization but prior to drying to allow for a single drying step of the polymer bead.
A wetting agent is defined as an agent which improves the hydration rate of the bead and does-not reduce the surface-tension of a supernate (provided by a standard test method) below 56 dynes/cm. The "standard test method" is described below.
Standard Test Method for Determinin Surface Tension of suPernate 1. Treat dry polymer beads with 0.4 weight percent (based on dry weight of polymer beads) of polyol;
2. Dissolve 1 g of the treated polymer beads in 150 g of 0.9 percent saline solution;
3. Filter off the supernate; and 4. Determine the surface tension of the supernate by using a duNouy surface tension apparatus.
Ideally, the hydration rate.of the bead is-improved without significantly reducing the absorbency . properties of the aqueous fluid ab~sorbent material in .
which the bead is incorporated. Therefore, examples of such a wetting agent are non-surfactant or non-detergent type wetting agents such as polyols.
Voranol~ (from The Dow Chemical Company) brand wetting agent is a preferred example of such a polyol.

34,000B-F -19-Typically, ~he wetting agent is lntroduced to the polymer bead as an aqueous solution in an amount sufficient to increase the hydration rate of the polymer bead. Preferably, an amount of from 0.2 to 2.0 weight percent of wetting agent based on the weight of polymer beads will be a sufficlent amount. Most preferab!ly, the wetting agent is from 0.3 to 0.4 weight percent of wetting agent based on the weight of polymer beads.
If the beads are dried and then surface treated with the wetting agent aqueous solution, the process entails several energy and time consuming steps. The beads require drying off the oil phase and water phase, then spraying the wetting agent solution on the beads and finally redrying the beads.
However, the intermediate drying step can be substantially reduced if,~-after the polymerization is complete, the water is removed from the suspension, leaving the oil phase remaining with the polymer beads.
A wetting agent in an aqùeous solution is then added.
Preferably the solution is added to the polymer beads slowly; most preferably the addition occurs over a period of from 1 to 30 minutes. The water can then be vacuum stripped and the oil can be removed by filtration or centrifugation. A final drying yields polymer beads having an improved hydration rate over beads which have not been treated with the wetting agent.
The molecular weight of the water-soluble polymer or water-swellable po~lymer is not particularly critical and may vary over a wide range. However, as stated above, a smaller water-swellable polymer bead . .
34,000B-F -20--21- ~13175 can improve the hydration rate of the polymer.
Typically, molecular weights range from 100,000 to 50 million depending on the desired use of the polymer.
Preferred polymers have weight average molecular weight in the range of from 2 to 25 million. It i9 undergtood that the molecular weights of the crosslinked polymer beads can be essentially infinite.
The following examples are given to further i!llustrate the invention but not to limit its scope.
All parts and percentages are given by weight unless otherwise indicated.
Example 1 A. Preparation of Laurvlmethacrylate/AcrYlic Acid Copolymer To 795.4 g of laurylmethacrylate was added 4.64 g of glacial acrylic acid and 800 g of liquid hydrocarbon sold commercially as Isopar~ M by Exxon.
Then 0.8 g of 2,2'-azobis(2,~-dimethylvaleronitrile) which is sold commercially as Vazo~ 52 by E. I. duPont de Nemours Corporation was added. The solution was agitated, purged with nitrogen for 1 hour and then heated to 50C. After 12 hours of heating, the temperature of the thickened solution was increased to 60C and held there for 2 hours. It was then cooled and mixed with another 800 g of the aforementioned liquid hydrocarbon to give a 33 percent polymer solution.
3 B. SusDension Polymerization of Crosslinked : Sodium Pol~acrYlate 131 g of glacial acrylic acid was mixed with 167 g of water. Then a 50 percent aqueous solution of sodium hydroxide was added dropwise, while keeping the temperature less than 50C. Addition was continued 34,OOOB-F -21-, -22- i~3~7S

until the pH of the solution was 6Ø To this mixture was added 0.6 g of pentasodium salt of diethylenetriamine pentaacetic acid sold commerclally as Versenex~ 80 by The Dow Chemical Company, and the total weight of the aqueous phase was adjusted to 490 g with additional water.
, The oil phase was prepared by adding 4.28 g of hydrophobic fumed silica sold as Aerosil~ R-972 by Degussa and 12.82 g of 33.3 percent 99 mole percent laurylmethacrylate/l mole percent acrylic acid copolymer in the liquid hydrocarbon to 432.9 g of the liquid hydrocarbon.
The aforementioned Aerosil~ R-972 component was dispersed by mixing the mixture with a Waring blender at medium agitation. The oil phase was then transferred to a 1-liter reactor. The crosslinking agent, 0.4275 g of trimethylolpropane triacrylate, was added to the oil phase. Then 0.0684 g of sodium persulfate and 0.0977 g of a 70 percent aqueous solution of t-butylhydroperoxide were added to the aqueous phase. The agitator on the l-liter reactor was set at 500 rpm and the aqueous phase was added quickly to the oil phase. The reactor was purged with N2 for 1 hour and the polymerization was initiated by adding a nitrogen stream containing 1000 ppm S02 at a rate of ~ 50 cm3/min through a dip tube. The reactor jacket was heated to 40C over a 10-minute period. This controls the actual polymerization temperature to 50C. After an hour, the jacket was heated to 60C and maintained at that temperature for an additional hour. The slurry was then cooled, centrifuged to remove excess liquid hydrocarbon a*d the product was air dried.

34,000B-F -22-Example 2 A water-soluble copolymer of acrylamide and acrylic acid was provided as follows:

An aqueous phase was provided by mixing 241.8 g - of aqueous acrylamide~,solution (48 percent acrylamide) and 16.85 g of glacial acrylic acid with 69.8 g of - -water. To this mixture was added 0.28 g of the afore- .
mentioned Versenex 80 and enough of a 50 percent sodium hydroxide solution to bring the pH of the mixture to 6.5. Additional water was added to give a total weight of the mixture of 350 g.

An oil phase was provided by adding 3.5 g of the aforementioned Aerosil~ R-972 and 10.5 g ~f a 33 percent solution of a copolymer of lauryl-methacrylate and acrylic acid. The mole ratio of laurylmethacrylate to acrylic acid was 95:5. The 20 copolymer was blended with 336 g of the af,orementioned Isopar M hydrocarbon.
To the aforementioned aqueous phase was added 0.7 g of isopropyl alcohol and 0.05 g of a 70 percent 25 aqueous solution of t-butylhydroperoxide. ,The oil phase was transferred to a 1-liter reactor and stirred at 300 rpm. The aqueous phase was added to the oil phase and then the suspension was purged for 1 hour - . with nitrogen. The polymerization was initiated by 30 adding S02 at a flow rate of 0.05 cm3/minutes. The reaction was held at 50C for 1 hour and then heated to 60C for an additional hour.
The polymer was is,olated by filtering off the ' - 3 hydrocarbon phase and d~rying (i.e., the Isopar M) the - beads in a forced air dryer at 90C. The~product was a 34,000B-F -23-.
-24- 1~1317S

spherical free-flowing solid. The viscosity of 0.3 peroent solution of the polymer in 3 percent sodium chloride at a pH of 7 was 16 cps (0.016 Pas) as determined using an Ostwald viscometer.
Exam~le 3 A copolymer comprised of 70 mole percent acrylamide and 30 mole percent acrylic acid was provided as follows:
An aqueous phase weighing 318 g`was provided by mixing 165 g of a 49.4 percent aqueous acrylamide solution with 35 g of glacial acrylic acid and 0.254 g of the aforementioned Versenex 80. To this solution was added enough of a 5~ percent sodium hydroxide solution to adjust the pH to 6.5, 0.0727 g of tertiary butyl hydroperoxide and water to provide the aforementioned 318 g total weight.
An oil phase weighing 381.86 g was provided by mixing 3.18 g of the aforementioned Aerosil~ R-972 composition with 3.18 g of a p~lylaurylmethacrylate polymer with 375.5 g of the Isopar M hydrocarbon.
The aqueous phase was added to the oil phase in a 1-liter reactor while agitating at 450 rpm. The mixture was purged for 1 hour with nitrogen and the polymerization was initiated by adding S02 at a flow rate of 0.05. cm3/minute. Shortly after initiation the suspension failed, coalescing into large mass of polymer.
The aforementioned experiment was repeated, except that the polylaurylmethacrylate polymer was replaced with 3.18 g of a copolymer of 99 mole percent 34,~0OB-F . -24-.

laurylmethacrylate and 1 mole pcroent acrylic acid. The suspension was agitated with S02 and heated to 50C for 1 hour. The suspension partially failed giving large chunks of agglomerated beads.
The above experiment was further repeated replacing the 1 mole percent acrylic acid/99 mole per-cent laurylmethacrylate copolymer, with 3.18 g of a 2.5 mole percent acrylic acid/97.5 mole percent lauryl-methacrylate copolymer. The polymerization proceeded smoothly. After polymerizing at 50C for one hour, the product was isolated by filtering off the hydrocarbon ~i.e., the Isopar~ M) and drying the beads. Microscopic examination shows that the polymer consisted of small agglomerates of polymer beads.
The above experiment was further repeated by replacing the 2.5 mole percent acrylic acid/97.5 mole percent laurylmethacrylate copolymer with 3.18 g of a 5 mole percent acrylic acid/95 mole percent lauryl-methacrylate copolymer. The polymerization was run as described hereinbefore. Microscopic examination showed that the product consisted of spherical polymer beads free from any signs of agglomeration.

Example 4 A crosslinked polymer was provided as follows:
An aqueous phase was provided by mixing 116.4 g 3 of glacial acrylic acid, 0.53 g of the aforementioned VERSENEX~ 80 (a chelating agent of The Dow Chemical Company), enough of a 50 percent aqueous sodium hydroxide solution to adjust the pH to 6 and enough water to provide a 400 g total aqueous phase.

34,000B-F -25--26- l3l3l7S

An oil phase weighing 400 g was provided by mixing 1.14 g of the aforementioned Aerosil~ R-972, a copolymer of 99 mole percent laurylmethacrylate and mole percent acrylic acid, 0.456 g of trimethylol-5 propanetriacrylate and 397.7 g of Isopar M hydrocarbon.
To the aqueous phase was added 0.0868 g oft-butyl hydroperoxide and 0.0608 g of sodium persulfate which was in turn added to a 1-liter reactor containing 10 the oil phase. The agitator on the reactor was set at 450 rpm. The mixture was purged with nitrogen for 1 hour and polymerization was then initiated at 25C by the addition oP S02 at the rate of 0.0833 cm3/minute.
The reaction was heated to 50C and was held at this 5 temperature for 1 hour. The temperature was then increased to 60C and held there for an additional hour.
The reaction mixture was cooled to room temperature and the Isopar M hydrocarbon was removed by 20 filtration. The polymer beads were dried in a forced--air dryer at 90C.
The water-retention capacity of the polymer so-provided was determined to be 75 g of a 0.9 percent 25 aqueous sodium chloride solution per gram of polymer.
The amount of extractable polymer was 2.5 percent. The extractable polymer was determined by contacting a polyme-r sample in a 0. 9 percent aqueous sodium chloride 30 solution and shaking for 16 hours.
The extractable polymer test was rerun except that a mixture of 0.9 percent aqueous sodium chloride and polymer beads were sheared for 10 seconds in a 35 Waring blender at high speed. The sample was filtered . I .

34,000B-F -26-~1317S

and titrated as usual. The extractables of this sample increased to 5.6 percent.
The afnrementioned polymerization process was repeated except that the S02 flow rate initiation was incre-ased to 0~108 cm3/minute. The polymer was isolated as described hereinbefore. The resulting polymer exhi-bitèd a higher capacity whi-~e maintaining low extractables as indicated by a retention capacity!
of the 0.9 percent aqueous sodium chloride solution of 90 g per gram of polymer and the polymer extractables value of 5.36 percent and a further extractable of a similarly shear product of 11.8 percent.
The aforementioned experiments indicate that - the polymerization conditions can affect polymer water--retention capacity. For example, increasing the S02 flow rate increased the capacity of the polymer. The above experiment also indicates that due to the fact that a higher percentage of polymer extractables were provided in the shear bead examples that it was believed that the copolymer beads were more highly crosslinked near the surface of the particles.
ExamDle 5 A crosslinked polymer was provided as follow!s:
An aqueous phase weighing ~08 g was provided by mixing 87 g of glacial acrylic acid, 0.228 g of the aforementioned Versenex 80 and enough of a 50 percent sodium hydroxide solution to adjust the pH to 6 and water to give a total weight of 308 g.
An oil phase was provided by mixing 4.27 g of Aerosil~ R-972, 1.42 g of a 99 mole percent 34,000B-F -27--28- l al 3l7 S

laurylmethacrylate/1 mole percent acrylic acid copolymer, 0.456 g of diethyleneglycoldiacrylate and 336.76 g of Isopar M hydrocarbon.
The aqueous phase was mixed with 0.0468 g of a 70 percent solution of t-butyl hydroperoxide and 0.0468 g oP sodium persulfate with the aqueous phase.
This aqueous phase was added to the oil phase in a 1-liter reactor. Agitation during ad`dition was 450 rpm. The reactor was purged with nitrogen for 1 hour and then the polymerization was started by adding S2 at the rate of 0.0833 cm3/minute. The polymerization was held at 50C for 1 hour and then the mixture was heated to 60C for an additional hour. The beads were separated by filtering off the excess Isopar M and dried in a forced-air oven at 90C. The water-retention capacity of the beads so provided was 59 g of the 0.9 percent sodium chloride solution per gram of polymer-ExamDle 6 A crosslinked polymer bead, 250 to 300 microns in size, having an improved hydr~tion rate after having been treated with a wetting agent, was prepared as follows.
An aqueous phase was provided by mLxing 43 lbs.
(19.5 kg) of glacial acrylic.acid, 88 g of the aforementioned Versenex 80, 44 lbs. ~19.9 kg) of a 50 percent sodium hydroxide solution, 53 lbs. (24 kg) of water and 76 g of trimethylolpropanetriacrylate.
An oil phase was provided by mixing 186 g of Aerosil~ R-972, 233g of a 98 mole percent laurylmethacrylate/2 mole percent acrylic acid 34,OOOB-F -28-.

, 131~175 g .
copolymer having a molecular weight of 590,000, and 13g lbs. (63 kg) of Isopar M hydrocarbon.
The aqueous phase was mixed with 14.5 g of a 70 percent solution of t-butyl hydroperoxide and 15 g o~
sodium persulfate with the aqueous phase~. This aqueous phase was added to the oil phase in a 50 gallon reactor at 20C. Agitation duri~g addition was 90 rpm. The-reactor was purged with nitrogen for 1 hour and then the polymerization was started by adding S02 at the rate of 0.1-1 cm3/minute. After polymerizing for two hours, agitation was increased to 120 rpm and the temperature was increased to 90C with a vacuum on the reactor to strip off the water. Later a solution of g5 g of Voranol~ wetting agent in 10 lbs (4.5 kg). of water was slowly added to the reactor at a rate of 2 lb./min. (0.9 kg/min). The beads were separated by filtering off the excess Isopar M and dried in a forced-air oven at 90C. The water-swellable polymer bead made by the above process had a particle size distribution centered around 50 to 80 mesh (180 ~m to 300 ~m).

The hydration rate of the polymer beads treated with wetting agent and the untreated, beads were tested by adding 50 g of a 0.9 percent sodium chloride solution to a beaker equipped with a stir bar adjusted to a brisk stir rate. Two grams of the beads were added to the solution and the rate in seconds was the time for the vorte,x of the solution to disappear.
The untreated beads were made in the same manner as above with the exception of the wetting - 35 agent. The hydration rate of the untreated beads was , 134 seconds and the hydration rate of the treated beads 34,000B-F -29-was 83 seconds. The data indicates the improved hydration rate of the beads having been treated with the wetting agent.
Example 7 . A ~rosslinked polymer bead havin~ a particle size distribution of from 75-90 microns and having an improved hydration rate after having been treated with a wetting agent was prepared as in example 6 except the molecular weight of the 98 mole percent laurylmethacrylate/2 mole percent acrylic acid was as low as 200,000.
The bead of Example 7 had a particle size distribution centered at 170-200 mesh or 75-90 microns.
The hydration rate measured as in Example 6 for the untreated beads was 94 seconds and the treated beads had a hydration rate of 23 seconds.

Therefore, by decreasing the molecular weight of the polymer portion of the suspending agent, the untreated beads produced are smaller and have a faster hydration rate than the untreated larger beads made with a suspending agent having a polymer portion with a larger molecular weight. The treated smaller beads also hydrate faster than the treated larger beads as . shown in E~ample 6.
.

34,000B-F -30- .

Claims (35)

1. Aqueous-fluid absorbent polymer beads produced by a process of suspension polymerization of water-soluble monomers, said process comprising:
(1) providing an aqueous phase comprising water and at least one water-soluble monomer, (2) providing an oil phase comprising an inert hydrophobic liquid and a suspending agent comprising:
(a) a particulate material comprising a hydrophobic character and (b) a polymer having a substantially hydrophobic character said polymer having hydrophobic moieties pendant from the backbone thereof, and (3) contacting the aqueous phase and the oil phase under conditions such that a water-in-oil suspension of polymer comprising polymerized water-soluble monomer is provided.

34,000B-F

2. The beads of Claim 1 wherein the polymer having a substantially hydrophobic character is selected from the group consisting of: higher alkyl esters of .alpha.,.beta.-ethylenically unsaturated carboxylic acids, and other alkyl esters derived from the reactions of alkanols having from 4 to about 20 carbon atoms with ethylenically unsaturated carboxylic acids; alkylaryl esters of ethylenically unsaturated carboxylic acids;
unsaturated amides; .alpha.-olefins of at least 8 carbon atoms; vinyl alkylates wherein alkyl has at least 8 carbons; N-vinyl amides and arylalkylstyrenes.

3. The beads of Claim 1 wherein further said process comprises::
(4) removing the water from the suspension, (5) adding a wetting agent which does not reduce the surface-tension of a supernate (provided by a standard test method) below 56 dynes/cm, in an amount sufficient to improve the hydration rate of the beads, and (6) drying the beads; and wherein the particulate material which comprises a hydrophobic character, is hydrophobic fumed silicon dioxide and the polymer having a substantially hydrophobic character said polymer having hydrophobic moieties pendant from the backbone thereof, is a copolymer of acrylic acid and lauryl methacrylate.

4. The beads of Claim 1 wherein said beads are crosslinked by polymerizing the water-soluble monomers in the presence of a crosslinking agent.

34,000B-F -32-

5. The beads of Claim 4 wherein said crosslinking agent is provided in said aqueous phase.

6. The beads of Claim 4 wherein said crosslinking agent is provided in said oil phase.

7. The beads of Claim 4 wherein said crosslinking agent is provided in said aqueous phase and said oil phase.

8. The beads of Claim 3 wherein the amount of suspending agent ranges from 0.05 to 10 weight percent relative to the amount of water-soluble monomer which is polymerized.

9. The beads of Claim 3 wherein said aqueous phase is dispersed in said oil phase.

10. The beads of Claim, 3 wherein the wetting agent is added over a period of from 1 to 30 minutes.

11. A process for the suspension polymerization of water-soluble monomers comprising:
(1) providing an aqueous phase comprising water and at least one water-soluble monomer, (2) providing an oil phase comprising an inert hydrophobic liquid and a suspending agent comprising (a) hydrophobic fumed silicon dioxide, and (b) a copolymer of acrylic acid and lauryl methacrylate, and (3) contacting the aqueous phase and the oil phase under conditions such that a water-in-soil suspension of polymer comprising 34,000B-F -33-polymerized water-soluable monomer is provided.

12. The process of Claim 11 wherein said water-soluble monomers are polymerized in the presence of a crosslinking agent.

13. The process of Claim 12 wherein said crosslinking agent is provided in said aqueous phase.

14. The process of Claim 12 wherein said crosslinking agent is provided in said oil phase.

15. The process of Claim 12 wherein said crosslinking agent is provided in said aqueous phase and said oil phase.

16. The process of Claim 11 wherein the amount of suspending agent ranges from about 0.05 to about 10 weight percent relative to the amount of water-soluble monomer which is polymerized.

17. The process of Claim 11 wherein said aqueous phase is dispersed in said oil phase.

18. A method for improving the hydration rate of aqueous-fluid absorbing beads by preparing said beads through a water-in-oil suspension polymerization of water-soluble monomers which comprises, (1) providing an aqueous phase comprising water and at least one water-soluble monomer, and (2) providing an oil phase comprising an inert hydrophobic liquid and a suspending agent comprising:
(a) a particulate material comprising a hydrophobic character and (b) a polymer having a substantially hydrophobic character, said polymer having hydrophobic moieties pendent from the backbone thereof, and (3) contacting the aqueous phase and the oil phase under conditions such that a water-in-oil suspension of polymer comprising polymerized water-soluble monomer is provided, and (4) removing the water from the suspension to leave an oil phase containing the beads, and (5) adding to the oil phase a wetting agent which does not reduce the surface tension of a supernate (provided by a standard test method) below 56 dynes/cm, in an amount sufficient to improve the hydration rate of the beads, and (6) drying the polymer beads.

19. The method of claim 18 wherein the polymerizing step (1) comprises.
(1) providing an aqueous phase comprising water and at least one water-soluble monomer, (2) providing an oil phase comprising an inert hydrophobic liquid and a suspending agent comprising:
(a) hydrophobic fumed silicon dioxide and (b) a copolymer of acrylic acid and lauryl (b) a copolymer of acrylic acid and lauryl methacrylate, and (3) contacting the aqueous phase and the oil phase under conditions such that a water-in-oil suspension of polymer comprising polymerized water-soluble monomer is provided.

20. The method of Claim 18 wherein the wetting agent of (3) is a polyol.

21. The method of Claim 20 whereby the polyol is present in an amount of from 0.2 to 2.0 weight percent of polyol based on the weight of the polymer beads.

22. The method of Claim 20 whereby the polyol in present in an amount of from 0.3 to 0.4 weight percent of polyol based on the weight of the polymer beads.

23. A method for improving the hydration rate of aqueous-fluid absorbing beads from a suspension polymerization of water soluble monomers which comprises:
(1) providing an aqueous phase comprising water and at least one water-soluble monomer;
(2) providing an oil phase comprising an inert hydrophobic liquid and a suspending agent comprising:
(a) hydrophobic fumed silicon dioxide and (b) a copolymer of acrylic acid and lauryl methacrylate - 36a - 64693-4150 having a molecular weight of 100,000 to 300,000;
and (3) contacting the aqueous phase and the oil phase under conditions such that a water-in-oil suspension of polymer beads comprising polymerized water-soluble monomer is provided.

24. A suspending agent useful in suspension polymerization processes, said suspending agent comprising, (1) a particulate comprising a hydrophobic character, and (2) a polymer having a substantially hydrophobic character, said polymer having hydrophic moieties pendent from the backbone thereof

25. The suspending agent of Claim 1 wherein said particulate comprising a hydrophobic character is hydrophobic fumed silicon dioxide.

26. The suspending agent of Claim 1 wherein said polymer having a substantially hydrophobic character is a copolymer of acrylic acid and laurylmethacrylate .

27. The suspending agent of Claim 1 wherein said particulate is used in an amount ranging from 5 to 95 weight percent of the suspending agent.

28. The suspending agent of Claim 1 wherein said polymer is used in an amount ranging from 95 to 5 weight percent of the suspending agent.

29. The suspending agent of Claim 4 wherein the particulate comprising hydrophobic character ranges in diameter from less than 1 micron to 20 microns.

30. The suspending agent of Claim 4 wherein the polymer having a substantially hydrophobic character is a copolymer of acrylic acid and laurylmethacrylate.

31. The suspending agent of Claim l wherein said particulate is used in an amount ranging from about 5 to about 95 weight percent of the suspending agent.

32. The suspending agent of Claim 1 wherein the polymer having a substantially hydrophobic character has a molecular-weight in the range of 1,000 to 100,000.

34,000B-E -37-

33. The suspending agent of Claim 1 wherein the polymer having a substantially hydrophobic character is a copolymer comprising hydrophobic monomers selected from the group consisting of the alkyl esters of acrylic acid, methacrylic acid, N-alkyl acrylamides and N-alkylmethacrylamides wherein the alkyl has from 8 to 20 carbon atoms.

34. The suspending agent of Claim 1 wherein the polymer having a substantially hydrophobic character is a copolymer comprising hydrophobic monomers selected from the group consisting of alkyl styrenes wherein the alkyl has from 4 to 8 carbons.

35. The suspending agent of Claim 1 wherein the polymer having a substantially hydrophobic character is a copolymer comprising hydrophobic monomers selected from the group consisting of alkylmethacrylates and alkylacrylates wherein the alkyl has from 10 to 20 carbon atoms.

34,000B-F -38-