CA1312759C - Phase retarder and liquid crystal display using the same - Google Patents
Phase retarder and liquid crystal display using the sameInfo
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- CA1312759C CA1312759C CA000570770A CA570770A CA1312759C CA 1312759 C CA1312759 C CA 1312759C CA 000570770 A CA000570770 A CA 000570770A CA 570770 A CA570770 A CA 570770A CA 1312759 C CA1312759 C CA 1312759C
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Abstract
ABSTRACT OF THE DISCLOSURE
A phase retarder obtained by uniaxially stretching a thermoplastic resin film, whose retardation value ranges from 30 to 1200 nm and whose color difference .DELTA.E* is not more than 30 as defined with the phase retarder being set between crossed polarizers in such a manner that the optical axis thereof makes an angle of 45° with respect to the planes of polarization of the polarizers, and a liquid crystal display using the phase retarder are disclosed. The phase retarder has a fixed optical axis, a retardation value suited for new optical uses including liquid crystal displays, and freedom from optical color unevenness. The liquid crystal display using the phase retarder exhibits markedly improved image quality.
A phase retarder obtained by uniaxially stretching a thermoplastic resin film, whose retardation value ranges from 30 to 1200 nm and whose color difference .DELTA.E* is not more than 30 as defined with the phase retarder being set between crossed polarizers in such a manner that the optical axis thereof makes an angle of 45° with respect to the planes of polarization of the polarizers, and a liquid crystal display using the phase retarder are disclosed. The phase retarder has a fixed optical axis, a retardation value suited for new optical uses including liquid crystal displays, and freedom from optical color unevenness. The liquid crystal display using the phase retarder exhibits markedly improved image quality.
Description
FIELD OF THE INVEN~ION
This invention relates to a novel phase retarder, and a polarizing sheet and a liquid crystal display using the same.
BACKGROUND OF THE INVENTION
A phase retarder is a film or sheet showing birefringence. Since a phase retarder has different refractive indices in two directions crossing at right angles to each other, light transmittance by the phase retarder produces light rays whose planes of polarization make a phase difference.
Phase retarders which are currently available on the market and have been in practical use include a so-called 1/4~ retarder or quarter retarder having a function to cause incident li~ht having a wavelength of to produce a phase difference of 1/4~o The quarter retarder is prepared by uniaxially stretching a cellulose acetate-based film. The quarter retarder serves as a circular polarizer when it is combined with a linear polarizer in such a manner that the optical axis thereof makes an angle of 45~ with respect to the planes of polarization of the linear polarizer. A
linear polarizer is also utilized as anti-glare ~3J~
1 materials, for example, a VDT (visual display terminal) filter, making use of its function to cut reflected light.
In liquid crystal display systems, it has been proposed to improve image quality of TN (twisted nematic) type liquid crystal displays, in which nematic liquid crystal molecules have a twisted angle of gO and a liquid crystal cell is sandwitched by a pair of polarizing sheets with their planes of polarization 1~ crossing or being parallel, by interposing a phase retarder between one of the polarizing sheets and the liquid crystal cell, as disclosed in Japanese Patent Application (OPI) Nos. 186937/86 and 26322/85 (the term "OPI" as used herein means "unexamined published 1~ Japanese patent application").
To cope with the demands for an increased display capacity and an enlarged display screen, generally called STN ~ super twisted nematic) type liquid crystal displays have recently been developed, in which the nematic liquid crystal molecules are twisted at an angle of about 180 to 270. However, the STN type liquid crystal display suffers from colori.ng ascribed to birefringence of liquid crystal molecules, resulting in the failure of B/W display. In order to solve this problem, it has been suggested that a liquid crystal l cell for color removal is added to the STN type liquid crystal cell as an optical compensator to thereby eliminate the color and to enable B/W display, as described, e.g., in the October issue of Nikkei Micro Device, 84 (1987). It-wouLd be possible, in principle, to use a phase retarder in place of the above-described liquid crystal cell for color removal.
Conventional quarter retardersl however, do not serve for the new uses including these liquid crystal l~ display systems for reasons that 1) the retardation value (hereinafter defined) does not meet with the purposes, 2) the optical axis thereof is not fixed, 3) they suffer considerable optical color unevenness, and the like. That is, it has been keenly demanded to develop a phase retarder having a fixed optical axis, freedom from optical color unevenness and a retardation value between 200 nm and 1000 nm, which would be promising for application to the above-described new optical uses including liguid crystal displays, but none of the state-of-the-art phase retarders satisfies these requirements.
SU~MARY OF THE INVENTION
Accordingly, one object of this invention is to provide a phase retarder having a retardation value in 2~
1 3 ~ 2759 1 the range of from 200 to 1000 nm, a fixed optical axis, and substantial freedom from optical color unevenness.
This invention relates to a phase retarder obtained by uniaxially stretching a thermoplastic resin film or sheet so as to have a retardation value between 30 and 1200 nm, preferably between 200 and 1000 nm, and more preferably between 200 and 350 nm or between 475 and 625 nm; a color difference ~E* of not more than 30 and preferably not more than 20 as defined with the 1~ phase retarder being set between crossed polarizers in such a manner that the optical axis thereof makes an angle of 45 with respect to the planes of polarization of the polarizers; and an a-value, as defined hereinafter, of 1.00 or more and preferably 1.03 or more.
This invention further relates to a polarizing sheet composed of the above-described phase retarder and a linear polarizer.
The present invention furthermore relates to a ~n liquid crystal display comprising a liquid crystal cell sandwitched between a pair of polarizing sheets, wherein the above-described phase retarder is provided between the liquid crystal cell and one of the polarizing sheets.
1 The terminology "retardation value" as used herein means a product of a thickness (d) of a film or sheet and a birefringence (an) of the film or sheet (hereinafter referred to as R value).
BRIEF DESCRIP~ION OF THE DRAWINGS
.
Figures 1, 2, and 3 each shows a transmittance light spectrum of background of the STN type li~uid crystal display wherein the phase retarder has an ~-value of 1.00, 1.03, or 1.06 respectively.
n DETAILED DESCRIPTION OF THE INVENTION
The film or sheet to be used in the present invention as a phase retarder can be prepared from any kind of thermoplastic resins irrespective of` whether they are crystalline or amorphous as long as the uniaxially stretched film or sheet obtained therefrom has an average transmittance of at least 50% and preferably at least 80~ in the visible wavelength region. In view of transparency and a proper R value, amorphous resins are preferred. Examples of these ~ resins include poly(meth)acrylate resins, such as polymethyl methacrylate and methyl methacrylate copolymers comprising methyl methacrylate as a main component and other ethylenic comonomer~; polystyrene resins, such as polystyrene and styrene copolymers comprising styrene as a main component and other 1 ethylenic comonomers; polyacrylonitrile resins, such as polyacrylonitrile and acrylonitrile copolymers; poly-ester resins, such as polyethylene terephthalate and polyester copolymers; polyamide resins, such as 6 nylon and 66 nylon; polyvinyl chloride resins, such as polyvinyl chloride and vinyl chloride copolymers;
polyvinyl alcohol and derivatives thereof; polyolefin resins, su~h as polyethylene, polypropylene, ethylene copolymers, and propylene copolymers; polysulfones;
polyether sulfones; polycarbonates; fluorine-containing resins; modified resins thereof; and resin compositions prepared by blending the aforesaid resins with transparent low-molecular weight organic compounds or transparent inorganic compounds. These resins may be used either individually or in combinations thereof.
Preferred among them are polyester resins, e.g., poly-ethylene terephthalate and polyester copolymers; poly-sulones; polyvinyl chloride resins, e.~., polyvinyl chloride and vinyl chloride copolymers; and 2n polyacrylonitrile resins, e.g., polyacrylonitrile and acrylonitrile copolymers.
In order to improve image guality of liquid crystal displays, the phase retarder to he used therein is preferably prepared from a thermoplastic resin having 1 an ~-value, as defined by equation 11) shown below, of 1.00 or more and preferably 1.03 or more.
RF
RD (1) wherein R~ represents an R value determined using F-line of sodium (~86.1 nm); and RD represents an R value determined by using D-line oE sodium (589.3 nm).
When a phase retarder is applied to an STN type liquid cxystal display, ~-value dependence of imaye quality is explained below.
When a retarder is set between parallel polarizers in such a manner that the optical axis therof makes an angle of 45 with respect to the planes of polarization of the polarizers, the transmittance (T) of the optical system is obtained by equation (2):
~Rr T = Tr x Tp x cos2 ~ t2) wherein Rr represents an R value ~nm) of the retarder; ~
represents a light wavelength (nm); and Tr and Tp represent transmittances of the retarder and of the parallel polarizers, respectively.
An STN type liquid crystal display composed of a liquid crystal cell containing liquid crystals having a twisted angle o about 200 and an R value [a product of 131275~
l a birefringence (~n) and a thickness (d)] of about 850 nm, which is sandwitched between parallel polarizers, with a phase retarder having an Rr value of about 550 nm being provided between the upper polarizing sheet and the liquid crystal cell in such a manner that the optical axis thereof makes an angle of about 45v with respect to the planes of polarization of the parallel polarizers, has improved image quality, i.e., it is substantially free from coloring.
n Image quality can be judged more excellent as the color of background in the display has a more distinct white color.
Such quality can be attained by satisfying a condition for constant transmittance in the visible wavelength region, i.e., a condition for attaining T =
constant in equation 12). Such condition can be represented by equation (3):
1rRc _ = o (3) 2~ Accordingly, the Rc value of the birefringent body (a combination of the liquid crystal cell and the phase retarder in this particular case) should satisfy equation (4):
Rc =
~5 1 Therefore, a perfect white background in the display can be made, exhibiting satisfactory image quality, if the R value of liquid crystal cell is compensated by R~ of retarcler as represented by equation (4) and T is constant throughout the visible wavelength region.
A transmittance spectrum of the STN type liquid crystal display wherein the phase retarder has an ~-value of 1.00, 1.03, or 1.06 is shown in Figure 1, 2, or 3, respectively. As can be seen from these fiqures, the larger the ~-value, the lesser the coloring, approaching to a perfect white display.
As elucidated above, the ~-value of a phase retarder to be used in a liguid crystal display is 1.00 or more and preferably 1.03 or more, to thereby attain satisfactory image quality.
Preferred examples of thermoplastic resins having an ~-value of 1O03 or more are resins containing an aromatic ring in the main chain thereof, such as ~ polysulfones, polyether sulfones, polyetherether ketones, polyesters, polyarylates, polystyrenes, polycarbonates, and the like; and resins containing a polar functional group in the sequential unit thereof, such as polyvinyl chloride, fluorine-containing polymers, polyacrylonitrile, and the like.
1 The phase retarder according to the present invention can be obtained by molding the above-described thermoplastic resins into a film or sheet by known technigues, such as solvent casting, calendering or extrusion, and uniaxially stretching the film or sheet to an appropriate degree.
For the purpose of obtaininy a phase retarder having a fixed optical axis and being substantially free from optical color unevenness, the film or sheet to be lo stretched is required to have satisfactory thickness precision and optical uniformity. Formation of die lines, etc~ during molding is unfavorable. Since films or sheets generally undergo minute orientation during molding, it lS favorable to diminish such minute 1~ orientation prior to s~retching. The minute orientation can effectively be reduced by subjecting the film or sheet to heat treatment at a temperature in the vicinity of heat distortion temperature of the film or sheet prior to stretching. By effecting such heat treatment, 2n the birefringence (~n) of the film or sheet becomes virtually zero, which indicates substantial freedom from orientation.
The uniaxial stretching of the film or sheet can be carried out by conventional methods, such as transverse uniaxial stretching by tentering, compression ~ 3 1 2759 1 stretching by rolling~ and longitudinal uniaxial stretching between rolls having different peripheral speeds.
In order to obtain a phase retarder free fro~
optical color unevenness and narrow fluctuations o~
retardation, a neck-in ratio, lOOx(A-B)/A, wherein A i5 a film width before stretching and B is a film width after stretching, should be controlled not to exceed 10%, preferably not to exceed 5%, more preferably be reduced virtually to zero. In this connection, the most effective stretching method is the transverse uniaxial stretching method by tentering that does not cause substantial neck-in.
The transverse uniaxial stretching by tentering generally comprises three steps of preheating, stretching, and heat set. The preheating plays the same role as the above-described heat treatment for reducing the birefringence of the film or sheet to substantially zero. The stretching is the most important for 2~ transforming the film or sheet to a phase retarder.
Conditions of stretching should be varied depending on the kind of the thermoplastic resin to be used, thickness of the ilm or sheet, desired Rr value, and the like. The heat set after stretching is efective to 1 improve dimensional stability and retardation evenness of the phase retarder.
The terminology "average transmittance in the visible wavelen~th region" as used herein means an average value calculated from 31 transmittance values measured at every 10 nm wlthin a wavelength region of from 400 to 700 nm by the use of a spectrophotometer or spectrometer. In order to assure suitability for optical application, the average transmittance of the l~ phase retarder of the present invention is preferably as high as possible and should be at least 50%, preferably at least 80%, and more preferably at least B5%.
The terminology "optical color unevenness" used herein can be expressed quantitatively by aE* as hereinafter defined. With the phase retarder being set between crossed polarizers in such a manner that the optical axis thereof makes an angle of 45 with respect to the planes of polarization of the polarizers, L*, a*, and b* of the phase retarder are determined with the transmittance spectrum measured by a spectrophotometer or spectrometer using parallel polarizers as a reference material in accordance with JIS Z 8729 ~Specification of Colour of Materials according to the CIE 1976 (L*a*b*) Space and the CIE 1976 ~L*u*v*) Space). The determination is made on n samples from different l locations of the film or sheet, and (~E*)i,j is calculated from the determined values, L*, a*, and b*
according to equation:
(~E*)ilj = [((~L*)i,j)2 + ((~a*)i,j)2 + ((ab*)i,j)2]~
wherein (~L*)i,j = (L*)i - (L*)j;
(~a*)i~j ~ (a*)i - (a*)j;
(~b*)i,j = (b*)i - (b*)j;
i = 1 to n;
J = l to n; and $ 1-The highest of the calculated (~E*)i,j values is taken as ~E*. The more the number of measurement (n), the higher the precision of the result. Usually, the measurement is carried out on ten random locations o~ a sheet or film (30 cm length x 30 cm width) to determine ~E*. If a phase retarder has ~E* exceeding 30, color unevenness and a rainbow pattern would be visually observed under crossed polarizers. Such a film can never be used as an optical film.
The thus obtained phase retarder can be applied to novel uses, such as polarizing sheets, liquid crystal displays, optical filters, and the like.
The liquid crystal display a~cording to the present invention comprises a liquid crystal cell .
1sandwitched between a pair of polarizing sheets, wherein the phase retarder according to the present invention is interposed between one of the polarizing sheets and the liquid crystal cell.
5The liquid crystal display systems in which the phase retarder of the present invention can be used includes a TN type liquid crystal display using liquid crystal molecules having a twisted angle of 90 and an STN type liquid crystal display using liquid crystal 10molecules having a twisted angle of from 180 to 270~.
Inter alia, the STN type liquid crystal display using the phase retarder of the present invention exhibits markedly improved image quality as compared with the conventional STN type liquid crystal displays.
15In applying the phase retarder of the present invention to liquid crystal displays, it is necessary to set its R value to the optimum in accordance with the twisted angle and the birefringence (~n) of liquid crystal molecules, the thickness (d) of the liquid 20crystal cell, and the like.
The ima~e quality can be best conditioned by settin~ the phase retarder of the invention and the polarizing sheets in such a manner that the optical axis makes an angle of from 30 to 60 and preferably from 40 25to 50 with respect to the planes of polarization of the l polariæers. Further, the image quality can also be best conditioned by arranging the pair of ~olarizing sheets in such a manner that their planes of polarization may cross or nearly cross or be parallel or nearly parallel to each other.
The present invention is now illustrated in greater detail with reference to Examples in view of Comparative Examples, but it should be understood that the present invention is not deemed to be limited o thereto. In these examples, R values were measured by using a polarizing microscope with a Senarmont compensator at 546 nm. ~E* values were determined by the use of a spectrophotometer and calculated according to the above-described equation. Transmittance spectra were measured by means of a spectrophotometer or a spectrometer and averaged in accordance with the above-described method.
~-values of phase retarders as defined by equation (1) were obtained by the use of an Abbe's 2~ refractometer in accordance with the following calculations (I) to (IV).
(I) A refractive index in the direction of the optical axis (nDl) and a refractive index in the direction perpendicular to the optical axis (nD2) were measured using D-line of sodium (589.3 nm) and assigned l to equation (5) shown below to calculate an R value at 589.3 nm (RD) -RD1 = ¦nD~ ~ nD2l X d ~ 5) wherein d represents a thickness (nm~ of a phase retarder.
(II~ An apparent refractive index in the di.rection of the optical axis (NF1) and that in the direction lQ perpendicular to the optical axis (NF2) were measured by using F-line of sodium (486.1 nm) and assigned to equations (6) and (7) shown below, respectively, to obtain actual refractive indices (nFl~ and (nF2).
~; nFI = P X sin[63--s~n 1{ p X sin{63--sin 1( 4 )}}] (6) nE~2= P X si~[63D--sin~l{ p X sin{63~--sin~l(l 74)}}] (7) ~0 wherein P represents a refractive index of a main prism of the reractometer at 486.1 nm, measuring 1.7589.
(III) The nFl and nF2 values thus obtained are assigned to equation (8) shown below to ob~ain an R v~lue at 486,1 nm (RF)-~F ~ F1--np2¦ x d (8) wherein d is as defined above.
(IV~ The ~-value can be calculated from the RF and RD
values according to equations (1).
EXA~PLE 1 An about 200 ~m thick and 300 mm wide poly-ethylene terephthalate film was preheated at about 210C
and then subjected to transverse uniaxial stretchin~ by n tentering at about 195C to obtain a stretched film having a thickness of about 140 ~m and a width of 430 mm.
The resulting phase retarder was found to have an average transmittance of about 9o%r an R value of about 915 nm, a QE* of 12.8 and an ~-value of about 1.05 with uniform quality and was substantially free from optical color unevenness.
An about 400 ~m thick and 300 mm wide polyester 2n copolymer film ("PETG 6763" produced by Eastman Chemical Co., Ltd.) was preheated at about 135C and then subjected to transverse uniaxial stretching by tenterin~
at about 120~C to obtain a stretched film having a thickness of about 2S0 ~m and a width of 480 mm.
1 31 275q 1 The resulting phase retarder was found to have an average transmittance of about 89~, an R value of about 535 nm, a ~E* of 11.0 and an ~-value o~ about 1.06 with uniform quality, and be substantially free from optical color unevenness.
An about 250 ~m thick and 300 mm wide polyvinyl chloride film ("SUNLOID VIP CHA 150" produced by Tsutsunaka Plastic Industry Co., Ltd.) was preheated at 1~ about 110C and then subjected to transverse uniaxial stretching b~ tentering at about 100C to obtain a stretched film having a thickness of about 140 ~m and a width of 540 mm.
The resulting phase retarder was found to have an average transmittance of about 87~, an R value of about 300 nm, a ~E* of 8.0 and an ~-value of about 1.02 with uniform quality, and be substantially free from optical color unevenness.
An about 150 ~m thick and 300 mm wide polysulfone film ("SUMILITE FS-1200" produced by Sumitomo Bakelite Co., Ltd.~ was preheated at about 230C and then subjected to transverse uniaxial stretching by tentering at about 210C to obtain a 131275q 1 stretched film having a thickness of about 75 ~m and a width of 600 mm.
The resulting phase retarder was found to have an average transmittance of about 89%, an R value of about 590 nm, a ~E* of 9.5 and an ~-value of about 1.10 with uniform quality, and be substantially free from optical color unevenness.
An about 220 ~m thick and 300 mm wide extruded polymethyl methacrylate film ("SUMIPEX-MMO" produced by Sumitomo Chemical Co., Ltd.) was preheated at about 90C
and then subjected to transverse uniaxial stretching by tentering at about 80C to obtain a stretched film having a thickness of about 150 ~m and a width of 440 mm.
The resulting phase retarder had an average transmittance of about 9o%l an R value of about 570 nm, a ~E* of 7.2 and an ~-value of about 1.01 with uniform ~uality and be substantially free from optical color unevenness.
A 60 ~m thick low-density polyethylene film ("SUMIKATHENE F-208-1" produced by Sumitomo Chemical Co., Ltd.) was subjected to compres~ion stretching by rolling at a roll surface temperature of about 100C
1 under a linear pressure of 250 kg/cm to obtain a stretched film having a thickness of about 15 ~m (neck-in ratio: about 3%).
The resulting phase retarder had an average transmittance of about 86%, an R value of about 630 nm, a ~E* of 14.4 and an ~-value of about 1.00 with uniform quality and was substantia:lly free from optical color unevenness.
n The same polysulfone film as used in Example 4 was preheated at 215C and then subjected to longitudinal uniaxial stretching between rolls having different peripheral speeds to obtain a stretched film having a thickness of about 70 ~m (neck-in ratio: about 6%).
The resulting phase retarder had an average transmittance of about B8%, an R value of about 560 nm, a ~E* of 15.0 with uniform quality and be substantially free from optical color unevenness.
A 7S ~m thick polyvinyl alcohol film ("Kuraray Vinylon VF-9P75R" produced by Kuraray Co., Ltd.) was stretched by rollinq at a roll surface temperature of about 130C under a linear pr~essure of 200 kg/cm2 to l obtain a stretched film having a thickness of about 16 ~m (neck-in ratio: about 13%).
The resulting stretched film, with its both ends being fixed, was dipped in a 7.5 wt~, aqueous solution of boric acid at 65C for 3 minutes, followed by drying.
Cellulose triacetate films having a thickness of 80 ~m ("Fujitack" produced by Fuji Photo Film Co., Ltd~) were laminated on both sides of the stretched film by using a urethane adhesive to obtain a phase retarder.
The resulting phase retarder had a transmittance of about 9o%~ an R value of about 565 nm, a aE* of 9.4, and an ~-value of about 1.01 with uniform quality and was substantially free from optical color unevenness.
An about 300 ~m thick and 300 mm wide polycarbonate film (average molecular weight: about 26,000) was preheated at about 185C and then subjected to transverse uniaxial stretching by tentering at about 175C to obtain a stretched film having a thickness of about 160 ~m and a width of 560 mm.
The resulting phase retarder was found to have an average transmittance of about 91%, an R value of about 885 nm, a ~E* of 9.3, and an ~-value of about l.Q6 with uniform quality and was substantially free from optical color unevenness.
1 31 275q An about 200 ~m thick and 300 mm wide polycarbonate film (average molecular weight: about 26,000) was preheated at about 190C and subjected to transverse uniaxial stretching by tentering at about 175C, followed by heating at about 180C for 2 minutes.
The resulting phase retarder was found to have an average transmittance of about 91%, an R value of about 60 nm, a ~E* of 13.1, and an ~-value of about 1.06 nwith uniform quality and was substantially free from optical color unevenness.
EXAMPLES 11 to 19 Each of the phase retarders obtained in Examples 1 to 9 was interposed between a liquid crystal cell and an upper polarizing sheet of a liquid crystal display by the use of an adhesive. The liquid crystal molecules in the cell had a twisted angle of about 200 and a - retardation value (Qn x d) of about 850 nm. The resulting display could make a B/W display comprising a 2~ black image on a white background with satisfactory image quality, suffering from neither appearance of a rainbow pattern nor color unevenness.
COMPARATIVE EXI~MPLE 1 `The same procedure of Example 7 was repeated, except that the distance between rolls was extended, to 1 obtain a stretched film having a thickness of about 80~m (neck-in ratlo: about 30%).
The resulting phase retarder had an average transmittance of about 88% and an R value o~ about 560 nm but was observed to have serious optical color unevenness as having a ~E* of 32.4. When the phase retarder was used in the same liquid crystal display as described in Example 17, the display suffered from serious color unevenness such as a rainbow pattern, lo rater exhibiting deteriorated image quality.
A 250 ~m thick polyester copolymer film ("PETG
6763") was uniaxially stretched at about llO~C by the use of the same stretching machine as used in lS Comparative Example 1 to obtain a stretched film having a thickness of about 170 ~m tneck-in ratio: about 40%).
~he resulting phase retarder had an average transmittance of about 89% and an R value of about 535 nm, but was ~ound to have serious optical color unevenness as having a ~E* of 34.5. When the phase retarder was used in the same liquid crystal display as described in Example 12, the display suffered from serious color unevenness such as a rainbow pattern~
rater exhibiting deteriorated image quality.
~ 23 -1 While the invention has been described in detail and with reference to specific embodiments thereof, it will be apparent to one skilled in the art that various changes and modifications can be made therein without departing from the spirit and scope thereof.
This invention relates to a novel phase retarder, and a polarizing sheet and a liquid crystal display using the same.
BACKGROUND OF THE INVENTION
A phase retarder is a film or sheet showing birefringence. Since a phase retarder has different refractive indices in two directions crossing at right angles to each other, light transmittance by the phase retarder produces light rays whose planes of polarization make a phase difference.
Phase retarders which are currently available on the market and have been in practical use include a so-called 1/4~ retarder or quarter retarder having a function to cause incident li~ht having a wavelength of to produce a phase difference of 1/4~o The quarter retarder is prepared by uniaxially stretching a cellulose acetate-based film. The quarter retarder serves as a circular polarizer when it is combined with a linear polarizer in such a manner that the optical axis thereof makes an angle of 45~ with respect to the planes of polarization of the linear polarizer. A
linear polarizer is also utilized as anti-glare ~3J~
1 materials, for example, a VDT (visual display terminal) filter, making use of its function to cut reflected light.
In liquid crystal display systems, it has been proposed to improve image quality of TN (twisted nematic) type liquid crystal displays, in which nematic liquid crystal molecules have a twisted angle of gO and a liquid crystal cell is sandwitched by a pair of polarizing sheets with their planes of polarization 1~ crossing or being parallel, by interposing a phase retarder between one of the polarizing sheets and the liquid crystal cell, as disclosed in Japanese Patent Application (OPI) Nos. 186937/86 and 26322/85 (the term "OPI" as used herein means "unexamined published 1~ Japanese patent application").
To cope with the demands for an increased display capacity and an enlarged display screen, generally called STN ~ super twisted nematic) type liquid crystal displays have recently been developed, in which the nematic liquid crystal molecules are twisted at an angle of about 180 to 270. However, the STN type liquid crystal display suffers from colori.ng ascribed to birefringence of liquid crystal molecules, resulting in the failure of B/W display. In order to solve this problem, it has been suggested that a liquid crystal l cell for color removal is added to the STN type liquid crystal cell as an optical compensator to thereby eliminate the color and to enable B/W display, as described, e.g., in the October issue of Nikkei Micro Device, 84 (1987). It-wouLd be possible, in principle, to use a phase retarder in place of the above-described liquid crystal cell for color removal.
Conventional quarter retardersl however, do not serve for the new uses including these liquid crystal l~ display systems for reasons that 1) the retardation value (hereinafter defined) does not meet with the purposes, 2) the optical axis thereof is not fixed, 3) they suffer considerable optical color unevenness, and the like. That is, it has been keenly demanded to develop a phase retarder having a fixed optical axis, freedom from optical color unevenness and a retardation value between 200 nm and 1000 nm, which would be promising for application to the above-described new optical uses including liguid crystal displays, but none of the state-of-the-art phase retarders satisfies these requirements.
SU~MARY OF THE INVENTION
Accordingly, one object of this invention is to provide a phase retarder having a retardation value in 2~
1 3 ~ 2759 1 the range of from 200 to 1000 nm, a fixed optical axis, and substantial freedom from optical color unevenness.
This invention relates to a phase retarder obtained by uniaxially stretching a thermoplastic resin film or sheet so as to have a retardation value between 30 and 1200 nm, preferably between 200 and 1000 nm, and more preferably between 200 and 350 nm or between 475 and 625 nm; a color difference ~E* of not more than 30 and preferably not more than 20 as defined with the 1~ phase retarder being set between crossed polarizers in such a manner that the optical axis thereof makes an angle of 45 with respect to the planes of polarization of the polarizers; and an a-value, as defined hereinafter, of 1.00 or more and preferably 1.03 or more.
This invention further relates to a polarizing sheet composed of the above-described phase retarder and a linear polarizer.
The present invention furthermore relates to a ~n liquid crystal display comprising a liquid crystal cell sandwitched between a pair of polarizing sheets, wherein the above-described phase retarder is provided between the liquid crystal cell and one of the polarizing sheets.
1 The terminology "retardation value" as used herein means a product of a thickness (d) of a film or sheet and a birefringence (an) of the film or sheet (hereinafter referred to as R value).
BRIEF DESCRIP~ION OF THE DRAWINGS
.
Figures 1, 2, and 3 each shows a transmittance light spectrum of background of the STN type li~uid crystal display wherein the phase retarder has an ~-value of 1.00, 1.03, or 1.06 respectively.
n DETAILED DESCRIPTION OF THE INVENTION
The film or sheet to be used in the present invention as a phase retarder can be prepared from any kind of thermoplastic resins irrespective of` whether they are crystalline or amorphous as long as the uniaxially stretched film or sheet obtained therefrom has an average transmittance of at least 50% and preferably at least 80~ in the visible wavelength region. In view of transparency and a proper R value, amorphous resins are preferred. Examples of these ~ resins include poly(meth)acrylate resins, such as polymethyl methacrylate and methyl methacrylate copolymers comprising methyl methacrylate as a main component and other ethylenic comonomer~; polystyrene resins, such as polystyrene and styrene copolymers comprising styrene as a main component and other 1 ethylenic comonomers; polyacrylonitrile resins, such as polyacrylonitrile and acrylonitrile copolymers; poly-ester resins, such as polyethylene terephthalate and polyester copolymers; polyamide resins, such as 6 nylon and 66 nylon; polyvinyl chloride resins, such as polyvinyl chloride and vinyl chloride copolymers;
polyvinyl alcohol and derivatives thereof; polyolefin resins, su~h as polyethylene, polypropylene, ethylene copolymers, and propylene copolymers; polysulfones;
polyether sulfones; polycarbonates; fluorine-containing resins; modified resins thereof; and resin compositions prepared by blending the aforesaid resins with transparent low-molecular weight organic compounds or transparent inorganic compounds. These resins may be used either individually or in combinations thereof.
Preferred among them are polyester resins, e.g., poly-ethylene terephthalate and polyester copolymers; poly-sulones; polyvinyl chloride resins, e.~., polyvinyl chloride and vinyl chloride copolymers; and 2n polyacrylonitrile resins, e.g., polyacrylonitrile and acrylonitrile copolymers.
In order to improve image guality of liquid crystal displays, the phase retarder to he used therein is preferably prepared from a thermoplastic resin having 1 an ~-value, as defined by equation 11) shown below, of 1.00 or more and preferably 1.03 or more.
RF
RD (1) wherein R~ represents an R value determined using F-line of sodium (~86.1 nm); and RD represents an R value determined by using D-line oE sodium (589.3 nm).
When a phase retarder is applied to an STN type liquid cxystal display, ~-value dependence of imaye quality is explained below.
When a retarder is set between parallel polarizers in such a manner that the optical axis therof makes an angle of 45 with respect to the planes of polarization of the polarizers, the transmittance (T) of the optical system is obtained by equation (2):
~Rr T = Tr x Tp x cos2 ~ t2) wherein Rr represents an R value ~nm) of the retarder; ~
represents a light wavelength (nm); and Tr and Tp represent transmittances of the retarder and of the parallel polarizers, respectively.
An STN type liquid crystal display composed of a liquid crystal cell containing liquid crystals having a twisted angle o about 200 and an R value [a product of 131275~
l a birefringence (~n) and a thickness (d)] of about 850 nm, which is sandwitched between parallel polarizers, with a phase retarder having an Rr value of about 550 nm being provided between the upper polarizing sheet and the liquid crystal cell in such a manner that the optical axis thereof makes an angle of about 45v with respect to the planes of polarization of the parallel polarizers, has improved image quality, i.e., it is substantially free from coloring.
n Image quality can be judged more excellent as the color of background in the display has a more distinct white color.
Such quality can be attained by satisfying a condition for constant transmittance in the visible wavelength region, i.e., a condition for attaining T =
constant in equation 12). Such condition can be represented by equation (3):
1rRc _ = o (3) 2~ Accordingly, the Rc value of the birefringent body (a combination of the liquid crystal cell and the phase retarder in this particular case) should satisfy equation (4):
Rc =
~5 1 Therefore, a perfect white background in the display can be made, exhibiting satisfactory image quality, if the R value of liquid crystal cell is compensated by R~ of retarcler as represented by equation (4) and T is constant throughout the visible wavelength region.
A transmittance spectrum of the STN type liquid crystal display wherein the phase retarder has an ~-value of 1.00, 1.03, or 1.06 is shown in Figure 1, 2, or 3, respectively. As can be seen from these fiqures, the larger the ~-value, the lesser the coloring, approaching to a perfect white display.
As elucidated above, the ~-value of a phase retarder to be used in a liguid crystal display is 1.00 or more and preferably 1.03 or more, to thereby attain satisfactory image quality.
Preferred examples of thermoplastic resins having an ~-value of 1O03 or more are resins containing an aromatic ring in the main chain thereof, such as ~ polysulfones, polyether sulfones, polyetherether ketones, polyesters, polyarylates, polystyrenes, polycarbonates, and the like; and resins containing a polar functional group in the sequential unit thereof, such as polyvinyl chloride, fluorine-containing polymers, polyacrylonitrile, and the like.
1 The phase retarder according to the present invention can be obtained by molding the above-described thermoplastic resins into a film or sheet by known technigues, such as solvent casting, calendering or extrusion, and uniaxially stretching the film or sheet to an appropriate degree.
For the purpose of obtaininy a phase retarder having a fixed optical axis and being substantially free from optical color unevenness, the film or sheet to be lo stretched is required to have satisfactory thickness precision and optical uniformity. Formation of die lines, etc~ during molding is unfavorable. Since films or sheets generally undergo minute orientation during molding, it lS favorable to diminish such minute 1~ orientation prior to s~retching. The minute orientation can effectively be reduced by subjecting the film or sheet to heat treatment at a temperature in the vicinity of heat distortion temperature of the film or sheet prior to stretching. By effecting such heat treatment, 2n the birefringence (~n) of the film or sheet becomes virtually zero, which indicates substantial freedom from orientation.
The uniaxial stretching of the film or sheet can be carried out by conventional methods, such as transverse uniaxial stretching by tentering, compression ~ 3 1 2759 1 stretching by rolling~ and longitudinal uniaxial stretching between rolls having different peripheral speeds.
In order to obtain a phase retarder free fro~
optical color unevenness and narrow fluctuations o~
retardation, a neck-in ratio, lOOx(A-B)/A, wherein A i5 a film width before stretching and B is a film width after stretching, should be controlled not to exceed 10%, preferably not to exceed 5%, more preferably be reduced virtually to zero. In this connection, the most effective stretching method is the transverse uniaxial stretching method by tentering that does not cause substantial neck-in.
The transverse uniaxial stretching by tentering generally comprises three steps of preheating, stretching, and heat set. The preheating plays the same role as the above-described heat treatment for reducing the birefringence of the film or sheet to substantially zero. The stretching is the most important for 2~ transforming the film or sheet to a phase retarder.
Conditions of stretching should be varied depending on the kind of the thermoplastic resin to be used, thickness of the ilm or sheet, desired Rr value, and the like. The heat set after stretching is efective to 1 improve dimensional stability and retardation evenness of the phase retarder.
The terminology "average transmittance in the visible wavelen~th region" as used herein means an average value calculated from 31 transmittance values measured at every 10 nm wlthin a wavelength region of from 400 to 700 nm by the use of a spectrophotometer or spectrometer. In order to assure suitability for optical application, the average transmittance of the l~ phase retarder of the present invention is preferably as high as possible and should be at least 50%, preferably at least 80%, and more preferably at least B5%.
The terminology "optical color unevenness" used herein can be expressed quantitatively by aE* as hereinafter defined. With the phase retarder being set between crossed polarizers in such a manner that the optical axis thereof makes an angle of 45 with respect to the planes of polarization of the polarizers, L*, a*, and b* of the phase retarder are determined with the transmittance spectrum measured by a spectrophotometer or spectrometer using parallel polarizers as a reference material in accordance with JIS Z 8729 ~Specification of Colour of Materials according to the CIE 1976 (L*a*b*) Space and the CIE 1976 ~L*u*v*) Space). The determination is made on n samples from different l locations of the film or sheet, and (~E*)i,j is calculated from the determined values, L*, a*, and b*
according to equation:
(~E*)ilj = [((~L*)i,j)2 + ((~a*)i,j)2 + ((ab*)i,j)2]~
wherein (~L*)i,j = (L*)i - (L*)j;
(~a*)i~j ~ (a*)i - (a*)j;
(~b*)i,j = (b*)i - (b*)j;
i = 1 to n;
J = l to n; and $ 1-The highest of the calculated (~E*)i,j values is taken as ~E*. The more the number of measurement (n), the higher the precision of the result. Usually, the measurement is carried out on ten random locations o~ a sheet or film (30 cm length x 30 cm width) to determine ~E*. If a phase retarder has ~E* exceeding 30, color unevenness and a rainbow pattern would be visually observed under crossed polarizers. Such a film can never be used as an optical film.
The thus obtained phase retarder can be applied to novel uses, such as polarizing sheets, liquid crystal displays, optical filters, and the like.
The liquid crystal display a~cording to the present invention comprises a liquid crystal cell .
1sandwitched between a pair of polarizing sheets, wherein the phase retarder according to the present invention is interposed between one of the polarizing sheets and the liquid crystal cell.
5The liquid crystal display systems in which the phase retarder of the present invention can be used includes a TN type liquid crystal display using liquid crystal molecules having a twisted angle of 90 and an STN type liquid crystal display using liquid crystal 10molecules having a twisted angle of from 180 to 270~.
Inter alia, the STN type liquid crystal display using the phase retarder of the present invention exhibits markedly improved image quality as compared with the conventional STN type liquid crystal displays.
15In applying the phase retarder of the present invention to liquid crystal displays, it is necessary to set its R value to the optimum in accordance with the twisted angle and the birefringence (~n) of liquid crystal molecules, the thickness (d) of the liquid 20crystal cell, and the like.
The ima~e quality can be best conditioned by settin~ the phase retarder of the invention and the polarizing sheets in such a manner that the optical axis makes an angle of from 30 to 60 and preferably from 40 25to 50 with respect to the planes of polarization of the l polariæers. Further, the image quality can also be best conditioned by arranging the pair of ~olarizing sheets in such a manner that their planes of polarization may cross or nearly cross or be parallel or nearly parallel to each other.
The present invention is now illustrated in greater detail with reference to Examples in view of Comparative Examples, but it should be understood that the present invention is not deemed to be limited o thereto. In these examples, R values were measured by using a polarizing microscope with a Senarmont compensator at 546 nm. ~E* values were determined by the use of a spectrophotometer and calculated according to the above-described equation. Transmittance spectra were measured by means of a spectrophotometer or a spectrometer and averaged in accordance with the above-described method.
~-values of phase retarders as defined by equation (1) were obtained by the use of an Abbe's 2~ refractometer in accordance with the following calculations (I) to (IV).
(I) A refractive index in the direction of the optical axis (nDl) and a refractive index in the direction perpendicular to the optical axis (nD2) were measured using D-line of sodium (589.3 nm) and assigned l to equation (5) shown below to calculate an R value at 589.3 nm (RD) -RD1 = ¦nD~ ~ nD2l X d ~ 5) wherein d represents a thickness (nm~ of a phase retarder.
(II~ An apparent refractive index in the di.rection of the optical axis (NF1) and that in the direction lQ perpendicular to the optical axis (NF2) were measured by using F-line of sodium (486.1 nm) and assigned to equations (6) and (7) shown below, respectively, to obtain actual refractive indices (nFl~ and (nF2).
~; nFI = P X sin[63--s~n 1{ p X sin{63--sin 1( 4 )}}] (6) nE~2= P X si~[63D--sin~l{ p X sin{63~--sin~l(l 74)}}] (7) ~0 wherein P represents a refractive index of a main prism of the reractometer at 486.1 nm, measuring 1.7589.
(III) The nFl and nF2 values thus obtained are assigned to equation (8) shown below to ob~ain an R v~lue at 486,1 nm (RF)-~F ~ F1--np2¦ x d (8) wherein d is as defined above.
(IV~ The ~-value can be calculated from the RF and RD
values according to equations (1).
EXA~PLE 1 An about 200 ~m thick and 300 mm wide poly-ethylene terephthalate film was preheated at about 210C
and then subjected to transverse uniaxial stretchin~ by n tentering at about 195C to obtain a stretched film having a thickness of about 140 ~m and a width of 430 mm.
The resulting phase retarder was found to have an average transmittance of about 9o%r an R value of about 915 nm, a QE* of 12.8 and an ~-value of about 1.05 with uniform quality and was substantially free from optical color unevenness.
An about 400 ~m thick and 300 mm wide polyester 2n copolymer film ("PETG 6763" produced by Eastman Chemical Co., Ltd.) was preheated at about 135C and then subjected to transverse uniaxial stretching by tenterin~
at about 120~C to obtain a stretched film having a thickness of about 2S0 ~m and a width of 480 mm.
1 31 275q 1 The resulting phase retarder was found to have an average transmittance of about 89~, an R value of about 535 nm, a ~E* of 11.0 and an ~-value o~ about 1.06 with uniform quality, and be substantially free from optical color unevenness.
An about 250 ~m thick and 300 mm wide polyvinyl chloride film ("SUNLOID VIP CHA 150" produced by Tsutsunaka Plastic Industry Co., Ltd.) was preheated at 1~ about 110C and then subjected to transverse uniaxial stretching b~ tentering at about 100C to obtain a stretched film having a thickness of about 140 ~m and a width of 540 mm.
The resulting phase retarder was found to have an average transmittance of about 87~, an R value of about 300 nm, a ~E* of 8.0 and an ~-value of about 1.02 with uniform quality, and be substantially free from optical color unevenness.
An about 150 ~m thick and 300 mm wide polysulfone film ("SUMILITE FS-1200" produced by Sumitomo Bakelite Co., Ltd.~ was preheated at about 230C and then subjected to transverse uniaxial stretching by tentering at about 210C to obtain a 131275q 1 stretched film having a thickness of about 75 ~m and a width of 600 mm.
The resulting phase retarder was found to have an average transmittance of about 89%, an R value of about 590 nm, a ~E* of 9.5 and an ~-value of about 1.10 with uniform quality, and be substantially free from optical color unevenness.
An about 220 ~m thick and 300 mm wide extruded polymethyl methacrylate film ("SUMIPEX-MMO" produced by Sumitomo Chemical Co., Ltd.) was preheated at about 90C
and then subjected to transverse uniaxial stretching by tentering at about 80C to obtain a stretched film having a thickness of about 150 ~m and a width of 440 mm.
The resulting phase retarder had an average transmittance of about 9o%l an R value of about 570 nm, a ~E* of 7.2 and an ~-value of about 1.01 with uniform ~uality and be substantially free from optical color unevenness.
A 60 ~m thick low-density polyethylene film ("SUMIKATHENE F-208-1" produced by Sumitomo Chemical Co., Ltd.) was subjected to compres~ion stretching by rolling at a roll surface temperature of about 100C
1 under a linear pressure of 250 kg/cm to obtain a stretched film having a thickness of about 15 ~m (neck-in ratio: about 3%).
The resulting phase retarder had an average transmittance of about 86%, an R value of about 630 nm, a ~E* of 14.4 and an ~-value of about 1.00 with uniform quality and was substantia:lly free from optical color unevenness.
n The same polysulfone film as used in Example 4 was preheated at 215C and then subjected to longitudinal uniaxial stretching between rolls having different peripheral speeds to obtain a stretched film having a thickness of about 70 ~m (neck-in ratio: about 6%).
The resulting phase retarder had an average transmittance of about B8%, an R value of about 560 nm, a ~E* of 15.0 with uniform quality and be substantially free from optical color unevenness.
A 7S ~m thick polyvinyl alcohol film ("Kuraray Vinylon VF-9P75R" produced by Kuraray Co., Ltd.) was stretched by rollinq at a roll surface temperature of about 130C under a linear pr~essure of 200 kg/cm2 to l obtain a stretched film having a thickness of about 16 ~m (neck-in ratio: about 13%).
The resulting stretched film, with its both ends being fixed, was dipped in a 7.5 wt~, aqueous solution of boric acid at 65C for 3 minutes, followed by drying.
Cellulose triacetate films having a thickness of 80 ~m ("Fujitack" produced by Fuji Photo Film Co., Ltd~) were laminated on both sides of the stretched film by using a urethane adhesive to obtain a phase retarder.
The resulting phase retarder had a transmittance of about 9o%~ an R value of about 565 nm, a aE* of 9.4, and an ~-value of about 1.01 with uniform quality and was substantially free from optical color unevenness.
An about 300 ~m thick and 300 mm wide polycarbonate film (average molecular weight: about 26,000) was preheated at about 185C and then subjected to transverse uniaxial stretching by tentering at about 175C to obtain a stretched film having a thickness of about 160 ~m and a width of 560 mm.
The resulting phase retarder was found to have an average transmittance of about 91%, an R value of about 885 nm, a ~E* of 9.3, and an ~-value of about l.Q6 with uniform quality and was substantially free from optical color unevenness.
1 31 275q An about 200 ~m thick and 300 mm wide polycarbonate film (average molecular weight: about 26,000) was preheated at about 190C and subjected to transverse uniaxial stretching by tentering at about 175C, followed by heating at about 180C for 2 minutes.
The resulting phase retarder was found to have an average transmittance of about 91%, an R value of about 60 nm, a ~E* of 13.1, and an ~-value of about 1.06 nwith uniform quality and was substantially free from optical color unevenness.
EXAMPLES 11 to 19 Each of the phase retarders obtained in Examples 1 to 9 was interposed between a liquid crystal cell and an upper polarizing sheet of a liquid crystal display by the use of an adhesive. The liquid crystal molecules in the cell had a twisted angle of about 200 and a - retardation value (Qn x d) of about 850 nm. The resulting display could make a B/W display comprising a 2~ black image on a white background with satisfactory image quality, suffering from neither appearance of a rainbow pattern nor color unevenness.
COMPARATIVE EXI~MPLE 1 `The same procedure of Example 7 was repeated, except that the distance between rolls was extended, to 1 obtain a stretched film having a thickness of about 80~m (neck-in ratlo: about 30%).
The resulting phase retarder had an average transmittance of about 88% and an R value o~ about 560 nm but was observed to have serious optical color unevenness as having a ~E* of 32.4. When the phase retarder was used in the same liquid crystal display as described in Example 17, the display suffered from serious color unevenness such as a rainbow pattern, lo rater exhibiting deteriorated image quality.
A 250 ~m thick polyester copolymer film ("PETG
6763") was uniaxially stretched at about llO~C by the use of the same stretching machine as used in lS Comparative Example 1 to obtain a stretched film having a thickness of about 170 ~m tneck-in ratio: about 40%).
~he resulting phase retarder had an average transmittance of about 89% and an R value of about 535 nm, but was ~ound to have serious optical color unevenness as having a ~E* of 34.5. When the phase retarder was used in the same liquid crystal display as described in Example 12, the display suffered from serious color unevenness such as a rainbow pattern~
rater exhibiting deteriorated image quality.
~ 23 -1 While the invention has been described in detail and with reference to specific embodiments thereof, it will be apparent to one skilled in the art that various changes and modifications can be made therein without departing from the spirit and scope thereof.
Claims (13)
1. A liquid crystal display comprising a liquid crystal cell sandwiched between a pair of polarizing sheets, wherein a phase retarder obtained by uniaxially stretching a thermoplastic resin film, whose retardation value ranges from 30 to 1200 nm and whose color difference .DELTA.E* is not more than 30 as defined with the phase retarder being set between crossed polarizers in such a manner that the optical axis thereof makes an angle of 45° with respect to the planes of polarization of the polarizers is provided between the liquid crystal cell and one of the polarizing sheets.
2. A liquid crystal display comprising a liquid crystal cell containing liquid crystals, said liquid crystal cell being sandwiched between a pair of parallel polarizing sheets and a phase retarder provided between a polarizing sheet and the liquid crystal cell in such a manner that the optical axis thereof makes an angle of about 45° with respect to the planes of polarization of the parallel polarizing sheets, said phase retarder being obtained by uniaxially stretching a thermoplastic resin film, whose retardation value ranges from 30 to 1200 nm whose color difference .DELTA.E* is not more than 30 as defined with the phase retarder being set between crossed polarizers in such a manner that the optical axis thereof makes an angle of 45°
with respect to the planes of polarization of the polarizers.
with respect to the planes of polarization of the polarizers.
3. A liquid crystal display comprising a liquid crystal cell containing liquid crystals, said liquid crystal cell being sandwiched between an upper and a lower parallel polarizing sheet, and a phase retarder provided between the upper polarizing sheet and the liquid crystal cell in such a manner that the optical axis thereof makes an angle of about 45° with respect to the planes of polarization of the parallel polarizing sheets, said phase retarder being obtained by uniaxially stretching a thermoplastic resin film, whose retardation value ranges from 30 to 1200 nm whose color difference .DELTA.E* is not more than 30 as defined with the phase retarder being set between crossed polarizers in such a manner that the optical axis thereof makes an angle of 45° with respect to the planes of polarization of the polarizers.
4. A liquid crystal display comprising a liquid crystal cell containing liquid crystals, said liquid crystal cell being sandwiched between a pair of parallel polarizing sheets and a phase retarder provided between a polarizing sheet and the liquid crystal cell in such a manner that the optical axis thereof makes an angle of from 30° to 60° with respect to the planes of polarization of the parallel polarizing sheets, said phase retarder being obtained by uniaxially stretching a thermoplastic resin film, whose retardation value ranges from 30 to 1200 nm and whose color difference .DELTA.E* is not more than 30 as defined with the phase retarder being set between crossed polarizers in such a manner that the optical axis thereof makes an angle of 45°
with respect to the planes of polarization of the polarizers.
with respect to the planes of polarization of the polarizers.
5. A liquid crystal display comprising a liquid crystal cell containing liquid crystals, said liquid crystal cell being sandwiched between an upper and a lower parallel polarizing sheet, and a phase retarder provided between the upper polarizing sheet and the liquid crystal cell in such a manner that the optical axis thereof makes an angle of from 30° to 60° with respect to the planes of polarization of the parallel polarizing sheets, said phase retarder being obtained by uniaxially stretching a thermoplastic resin film, whose retardation value ranges from 30 to 1200 nm and whose color difference .DELTA.E* is not more than 30 as defined with the phase retarder being set between crossed polarizers in such a manner that the optical axis thereof makes an angle of 45° with respect to the planes of polarization of the polarizers.
6. A liquid crystal display as claimed in claim 4 or claim 5, wherein the phase retarder is provided between the upper polarizing sheet and the liquid crystal cell in such a manner that the optical axis thereof makes an angle of from 40° to 50° with respect to the planes of polarization of the parallel polarizing sheets.
7. A polarizing sheet comprising a linear polarizer and a phase retarder obtained by uniaxially stretching a thermoplastic resin film, whose retardation value ranges from 30 to 1200 nm and whose color difference .DELTA.E* is not more than 30 as defined with the phase retarder being set between crossed polarizers in such a manner that the optical axis thereof makes an angle of 45° with respect to the planes of polarization of the polarizers.
8. A phase retarder obtained by uniaxially stretching a thermoplastic film, whose retardation value ranges from 30 to 1200 nm and whose color difference .DELTA.E* is not more than 30 as defined with the phase retarder being set between crossed polarizers in such a manner that the optical axis thereof makes an angle of 45° with respect to the planes of polarization of the polarizers.
9. A phase retarder as claimed in claim 8 wherein said uniaxial stretching is carried out so that the stretched film has a neck-in ratio of not more than 10%.
10. A phase retarder as claimed in claim 8 wherein said uniaxial stretching is carried out by transverse uniaxial stretching by tentering.
11. A phase retarder as claimed in claim 8 wherein said thermoplastic resin film has an .alpha.-value, as defined by equation (1) shown below, of 1.00 or more (1) .alpha. = wherein RF represents an R value determined using F-line of sodium (486.1 nm); and RD represents an R value determined by using D-line of sodium (589.3 nm).
12. A liquid crystal display comprising a liquid crystal cell containing liquid crystals, said liquid crystal cell being sandwiched between a pair of parallel polarizing sheets, and a phase retarder provided between a polarizing sheet and the liquid crystal cell in such a manner that the optical axis thereof makes an angle of from 30° to 60° with respect to the planes of polarization of the parallel polarizing sheets, said phase retarder being obtained by uniaxially stretching a polycarbonate film, whose retardation value ranges from about 200 nm to about 625 nm and whose color difference .DELTA.E* is not more than 20 as measured under cross nicols with the phase retarder being set in such a manner that the main optic axis thereof makes an angle of 45° with the crossed nicols.
13. A liquid crystal display comprising a liquid crystal cell containing liquid crystals, said liquid crystal cell being sandwiched between an upper and a lower parallel polarizing sheet, and a phase retarder provided between the upper polarizing sheet and the liquid crystal cell in such a manner that the optical axis thereof makes an angle of from 30° to 60° with respect to the planes of polarization of the parallel polarizing sheets, said phase retarder being obtained by uniaxially stretching a polycarbonate film, whose retardation value ranges from about 200 nm to about 625 nm and whose color difference .DELTA. E* is not more than 20 as measured under cross nicols with the phase retarder being set in such a manner that the main optic axis thereof makes an angle of 45° with the cross nicols.
Applications Claiming Priority (12)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP16480187 | 1987-06-30 | ||
| JP164801/87 | 1987-06-30 | ||
| JP182849/87 | 1987-07-21 | ||
| JP18284987 | 1987-07-21 | ||
| JP24197987 | 1987-09-24 | ||
| JP241979/87 | 1987-09-24 | ||
| JP278080/87 | 1987-11-02 | ||
| JP62278080A JPH0677084B2 (en) | 1987-11-02 | 1987-11-02 | Retarder |
| JP89478/88 | 1988-04-11 | ||
| JP8947888 | 1988-04-11 | ||
| JP162114/88 | 1988-06-28 | ||
| JP63162114A JPH0713683B2 (en) | 1987-06-30 | 1988-06-28 | Retardation plate, composite polarizing plate using the same, and liquid crystal display device |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1312759C true CA1312759C (en) | 1993-01-19 |
Family
ID=27551770
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA000570770A Expired - Fee Related CA1312759C (en) | 1987-06-30 | 1988-06-29 | Phase retarder and liquid crystal display using the same |
Country Status (1)
| Country | Link |
|---|---|
| CA (1) | CA1312759C (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN117392919A (en) * | 2022-07-01 | 2024-01-12 | 北京小米移动软件有限公司 | Film detection methods, electronic equipment, devices and media |
-
1988
- 1988-06-29 CA CA000570770A patent/CA1312759C/en not_active Expired - Fee Related
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN117392919A (en) * | 2022-07-01 | 2024-01-12 | 北京小米移动软件有限公司 | Film detection methods, electronic equipment, devices and media |
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