CA1312114C - Ir-radiation source and method for producing same - Google Patents
Ir-radiation source and method for producing sameInfo
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- CA1312114C CA1312114C CA000582820A CA582820A CA1312114C CA 1312114 C CA1312114 C CA 1312114C CA 000582820 A CA000582820 A CA 000582820A CA 582820 A CA582820 A CA 582820A CA 1312114 C CA1312114 C CA 1312114C
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J61/00—Gas-discharge or vapour-discharge lamps
- H01J61/02—Details
- H01J61/12—Selection of substances for gas fillings; Specified operating pressure or temperature
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J61/00—Gas-discharge or vapour-discharge lamps
- H01J61/02—Details
- H01J61/12—Selection of substances for gas fillings; Specified operating pressure or temperature
- H01J61/14—Selection of substances for gas fillings; Specified operating pressure or temperature having one or more carbon compounds as the principal constituents
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J61/00—Gas-discharge or vapour-discharge lamps
- H01J61/02—Details
- H01J61/30—Vessels; Containers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J61/00—Gas-discharge or vapour-discharge lamps
- H01J61/02—Details
- H01J61/30—Vessels; Containers
- H01J61/35—Vessels; Containers provided with coatings on the walls thereof; Selection of materials for the coatings
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J65/00—Lamps without any electrode inside the vessel; Lamps with at least one main electrode outside the vessel
- H01J65/04—Lamps in which a gas filling is excited to luminesce by an external electromagnetic field or by external corpuscular radiation, e.g. for indicating plasma display panels
- H01J65/042—Lamps in which a gas filling is excited to luminesce by an external electromagnetic field or by external corpuscular radiation, e.g. for indicating plasma display panels by an external electromagnetic field
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J9/00—Apparatus or processes specially adapted for the manufacture, installation, removal, maintenance of electric discharge tubes, discharge lamps, or parts thereof; Recovery of material from discharge tubes or lamps
- H01J9/24—Manufacture or joining of vessels, leading-in conductors or bases
- H01J9/245—Manufacture or joining of vessels, leading-in conductors or bases specially adapted for gas discharge tubes or lamps
- H01J9/247—Manufacture or joining of vessels, leading-in conductors or bases specially adapted for gas discharge tubes or lamps specially adapted for gas-discharge lamps
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- Physics & Mathematics (AREA)
- Electromagnetism (AREA)
- Plasma & Fusion (AREA)
- Manufacturing & Machinery (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
- Crystals, And After-Treatments Of Crystals (AREA)
- Heating, Cooling, Or Curing Plastics Or The Like In General (AREA)
- Chemical Vapour Deposition (AREA)
- Manufacture Of Electron Tubes, Discharge Lamp Vessels, Lead-In Wires, And The Like (AREA)
- Discharge Lamps And Accessories Thereof (AREA)
Abstract
IR-RADIATION SOURCE AND METHOD FOR PRODUCING SAME
ABSTRACT OF THE DISCLOSURE
A source of IR-radiation, having an enclosure defining between its walls a sealed-off, electrode-less chamber, the walls having at least one portion transparent to IR-radiation, and the chamber containing a gas mixture of at least one, molecular, IR-active gas, of at least one buffer gas and of at least one noble gas. A method for producing a source of IR-radiation is also described and claimed.
ABSTRACT OF THE DISCLOSURE
A source of IR-radiation, having an enclosure defining between its walls a sealed-off, electrode-less chamber, the walls having at least one portion transparent to IR-radiation, and the chamber containing a gas mixture of at least one, molecular, IR-active gas, of at least one buffer gas and of at least one noble gas. A method for producing a source of IR-radiation is also described and claimed.
Description
~3~2~1~
, The present invention relates to sealed-off, molecular sas-discharge sources, without internal electrodes, radiating at discrete, non-coherent and spontaneous emission frequencies in the infra-red (IR) spectrum, and to a method of producing such sources.
Sealed-off, as opposed to non-sealed continuous flow, molecular gas-discharge IR sources are known in the art. These sources are, however, in general of short life span due to dissociation and/or depletion of the IR emitting gas during operation and are weak due to non-radiative relaxation of the excited molecules. Also, the ratio of the IR output to the input power of these known sources, is low. In order to overcome some of these shortcomings, solutions were suggested which include rather complicated structures, such as the device described in Robert A. Young's U.S~ Patent number 3,984,727 and the device described in the U.K. patent number 1,591,709, to R.S. Webley.
It is therefore an object of the present invention to ameliorate the disadvantages of the prior art devices and to provide IR-radiating sources of simple structure capable of emitting narrow spectral lines at discrete spontaneous emission frequencies characteristic of the molecular rotation - vibration transition band of one or several gas species.
It is a further object of the present invention to provide IR-sources which operate continuously for at least several months, have a 3~2~1~
power output, at selected frequencies of at least several milliwatts, and a power efficiency which is such that the specific IR output power at these frequencies is in the order of several percent or even tens of percent, of the total power needed to operate these sources.
These and other objects are achieved by providing a source of IR-radiation, comprising an encl~sure defining between its walls a sealed-off, electrodeless chamber, said walls having at least one portion transparent to IR-radiation, and said chamber containing a gas mixture of at least one, molecular, IR-active gas, of at least one buffer gas and of at least one noble gas, said source of IR-radiation emitting discrete, solely non-coherent, spontaneous emission frec~uencies in the IR-spectrum characteristic of the molecular rotation-vibration transition band of said at least one molecular IR-active gas.
The invention also provides a method for producing a source of IR-radiation, comprising: provid;ng an enclosure made of a dielectric material defining between its walls a chamber, soaking said chamber in a cleaning agent, thoroughly rinsing said chamber with distilled de-ionized waterl drying said chamber, baking said chamber at a temperature of about between 200-300C, introducing in the chamber at least one noble gas, effecting a discharge in the chamber for a period of time and emptying said gas, filling said chamber with a gas mixture containing at least one, molecular, IR-active gas, of at least one buffer gas and of at least one noble gas, and hermetically sealing-off said chamber.
"; ~, ~3~
The invention will now be described in connection with certain preferred embodiments with reference to the following illustrati~/e figures so that it may be more fully understood.
With specific reference now to the figures in detail, it is stressed that the particulars shown are by way of example and for purposes of illustrative discussion of the pre~erred embodiments of the present invention only and are presented in the cause of providing what is believed to be the most useful and readily understood description of the principles and conceptual aspects of the invention.
In this regard, no attempt is made to show structural details of the invention in more detail than is necessary for a fundamental under-standing of the invention, the description taken with the drawings making apparent to those skilled in the art how the several forms of the invention may be embodied in practice~
In the drawings:
Fig, 1 is a schematic representation, partly in cross-section, of an IR-radiation source according to the present invention;
Fig. 2 is a graph showing discrete emission spectrum of an IR-radiation source;
Fig. 3 is a schematic representation of an embodiment of an IR-radiation source according to the invention, and Fig. 4 is a schematic representation of a two compartment IR-radiation source.
1~2~
Referring to Fig. 1, there is illustrated an IR-radiation source 2 constituted by an enclosure 4 defining between its walls a sealed-off chamber 6. The enclosure 4 is made of a dielectric material such as Pyrex ~ glass or quartz and has at least one wall 8 transparent to IR-radiation, which radiation, during operation, can be em;tted there-from in the direction of arrows A. In order to excite gas molecules contained inside the chamber 69 the enclosure 4 may, however, be fitted on the outside thereof, with a pair of electrodes 10 and 12 connectable via a cable 14 to an RF driver (not shown) for powering and controlling the source 2.
In accordance with the present invention, the interior oF theenclosure 4 is filled with a gas mixture containing:
a) at least one, molecular, IR-active gas capable of emitting IR-radiation of a known discrete spectral distribution when suitably excited;
b) at least one buffer gas having relatively long-living state of excited energy levels, capable of storing the absorbed exciting energy for increasing the rate of excitation and emission of the IR-active gas by the V-V (vibration-vibration) collisional process, and c) at least one noble gas for assisting the initiation of the gas mixture discharge and for increasing the concentration of free electrons in the chamber.
Experiments carried out with such mixtures have shown that in order to achieve an IR-radiation source exhibiting a prolonged life span, an enhanced emission, and/or a suitable modulation of the emitted IR-radiation, several inter-related parameters should be taken into account:
i) the mixture of the above-described three types of gases;
ii) the pressure of the mixture inside the chamber, and iii) the configuration of the chamber.
Considering these interdependent parameters, it can be stated that during the natural decay time of the excited IR-active molecules, e.g., in the order of several milliseconds, the molecules are prone to quenching by three different processes: wall quenching, collisional quenching and self quenching. The wall quenching is caused by the diffusion of excited molecules from a location in the bulk of the gaseous medium to the walls of the enclosure where it is rapidly quenched and the excitation is lost. The average diffusion time for an average size of a source operating at gas pressures which are lower than optimal pressures for high output, is several times faster than the radiative life time. This obviously results in a substantial reduction of the IR intensity of the conversion efficiency of discharge energy compared with the corresponding situation in atomic sources in the visible or U.V, regions of the spectrum. The colli-sional quenching occurs between the IR-active molecules and other constituents of the mixture, including impurities. Premature quenching of the excited states by collision of excited molecules with other atoms or molecules present in the gas mixtures, results in a decrease of the intensity of the IR-emission and of the efficiency of IR-source.
The nature of a particular quenching agent depends on the specific emitting molecule and on the excited state. For example the 4.27 emission from the (001) state to the (000) state of a C02 molecule is particularly susceptible to quenching by collision with water or hydrogen molecules.
Finally, molecules in their excited state, emitting character-istic IR-radiation are often quenched by collision with unexcited molecules of the same species. This is called self quenchins and it drastically limits the overall pressure of active species permissible in the IR-emitting source. It follows that IR-active molecular species in the source, as well as atomic or molecular buffer species should be maintained at bound pressures not exceeding predetermined values. Since diffusion to the walls of the enclosure is faster at reduced pressure, ~all quenching and collisional quenching are inter-~ 3 ~
dependent. Thus, only relative large size sources can maintain highemission intensities at considerable power conversion efficiencies.
Examples of IR-radiation sources built and operated, in accordance with the present invention, are as follows:
EXAMPLE NO. GAS MIXTURE RELATIVE PRESSURES
l. C02,N2,He 1:4:7 2~ Co2~N2~Helxe 1:2:2:3 3, C02,N2,Xe 1:2:8 4~ CO,N2,Xe 1:1:8 _ _ _ _ . .......... . _ The total pressure inside the chamber can vary from 1 to 100 torr.
Fig. 2 illustrates the emission intensity of an IR-radiation source comprising C02, N2, Xe, and He, having relative partial pres-sures of 1,2,3,3, and a total pressure in the range of 6 - 25 torr.
The source has been excited by an RF oscillator operating at a frequency range of 4-7 MHz at an average output power of hundreds of milliwatts. The output from the radiation source is in the order of tens of milliwatts.
Referring now, with reference to Figs. 3 and 4, to the aspect of the configuration of the IR-radiation sources, this term as used here-in is meant to encompass~ both, the overall size and shape of an enclosure defining a chamber 6 containing the mixture of the gas.
~3~2'~
g In a gas mixture of example No. 2, for instance, the lifetime at the (001) vibrational state of a carbon dioxide (C02) molecule which produces the 4,27 micron emission is approximately 5 milliseconds, It follows that in order to maximize the IR output, the chamber dimen-sions in the region of the discharge and the gas mixture total and partial pressures should be chosen so as to avoid the possibility that diffusion to the wall could take much less than this time and, that the different collisional relaxing processes will occur at a higher rate than 1/5 milliseconds = 200 sec 1 If, however, it is desired to obtain faster modulation rates of the emitted IR-radiationi the size of the chamber should be small enough so that the diffusion of the molecules to the walls of the chamber will take less than the decay time of the molecule. While for the C02 molecule the decay time is approximately 5 milliseconds, the decay time for C0 (see example No.
4) is about 30 milliseconds.
As seen in Fig. 3, the enclosure 4, is composed of two portions:
a first portion of a greater diameter D (about 40 mm) and of a length L (about 50 mm) called the reservoir and of a second portion of a lesser diameter d, (about 15 mm) and of a length 1 (about 30mm), called the discharge portion or zone. The two electrodes 10 and 12 are coupled onto the discharge zone. Upon excitation, the desired gas emission exits the chamber 6 in the direction of arrow A. Hence~ as can be appreciated, the major volume of the chamber 6 is utilized as a reservoir for constantly replenishing the discharge zone with the same mixture of gas molecules. This type of source configura'cion increases the life span and stability of the output power o~ a source.
Experiments made with an IR-radiation source having a config-uration of Fig. 3 and filled with a gas mixture of example 2 above, have shown that a duration of a life-span exceeding over 10,000 hours of continuous operation can be achieved. Experiments made with a source containing a gas mixture of Example No. 4, achieved continuous operation exceeding 5000 hours.
Other experimental results which were carried out are summarized in the following tables:
TABLE I: Pressure Dependence on IR-radiation Decay_Time Source configuration of Fig. 1; D=15mm; gas mixture of Example No. 3.
Total pressure in Decay Time Comparative IR-the chamber (msec) radiation Output TABLE II: Gas Mixture Dependence on IR-radiation Decay Time Source conFiguration of Fig. 1; D=15mm; total pressure 10 torr~
. _ _ . _ . .
Gas Mixture Decay Time Comparative IR-C2'N2'Xe (msec) radiation Output ~ . . . _ . . _ _ _ 10:20: 30 4 100 10: 1: 30 2 45 10: 1:100 3 60 10: 1:300 2.5 40 TABLE III: Gas Chamber Configuration Dependence on IR-Radiation Decay Time Gas mixture of Example No~ 3; total pressure 10 torr.
-Gas Chamber Diameter Decay TimeComparative IR-(in mm) (msec)radiation Output 3.5 70 -Turning to Fig, 4, there is illustrated a modified source 2, having two compartments 14 and 16. In the compartment 14 there is introduced a gas mixture according to the invention having a certain active gas, (e~g., C02). In the compartment 16 there is sealed a gas m;xture, however, with an additional active gas, (e.g., N20 or any other molecule having a dissociation tendency similar to N?0). When discharge occurs in compartment 14, radiation in direction A from the molecule of said certain active gas enters into the compartment 16 with the additional active gas. In the second compartmènt 16, the first active molecule will absorb the characteristic radiation emanating from the compartment 14 and by the collisional V-V process, will excite the second active molecule to its vibrational state. Hence a radiation in direction B of the second active gas will be emitted from the compartment 16, without inducing a gas discharge in it.
As it has been hereinbefore described, an essential feature of the present invention is the self-controlled long-life continuous emission IR-radiation source, which is achieved, inter alia, by avoiding, as far as possible, different quenching processes and other 3L L~
-causes depleting the IR-active gas in the mixture. In this endeavour, it is proposed to pretreat the interior of the enclosure 4 prior to the introduction of the gas mixture therein as follows:
a) soaking the gas chamber 6 in chemicals. For example, overnight soaking with 30% Nitric Acid in water or Sulphuric Acid + 1%
Sodium persulphate, or sulpho-chromic Acid, or other similar cleaning agents such as AlconoxR, MicroR or NochromixR;
b) thoroughly rinsing with double-distilled de-ionized water;
c) drying the chamber with e.g., ethanol;
d) baking at 280C in a vacuum oven;
e) introducing in the chamber a noble gas, e.g., Xe, effecting a discharge in the chamber for a short period of time and emptying the gas; and f) introducing a gas mixture in the chamber substantially equal to the gas mixture to be used in the source, effecting a discharge for a short period of time, e.g~, several minutes, and emptying the gas.
Having baked out and evacuated the chamber, and having eFfected discharges with gases of the final mixture used, the selected gases, as described hereinbefore, are introduced into the chamber at the calculated ratios and pressures, the chamber is then hermetically sealed-off.
Optionally, the enclosure materials which normally have high relaxing tendency to the IR-active molecules, can be coated with substances which reduce this tendency, for example, Barium Fluoride or Sapphire.
Alternatively, it is proposed to produce the enclosure wall material with a radioactive substance, that while radiating into the chamber, assists in pre-conditioning the gas mixture inside the enclosure for easy ignition~ The same effect can be achieved by adding traces of radioactive gas such as 85Kr.
Also, in order to maintain a preferred level of IR-active gas molecules, it is suggested in some cases7 to add to the mixture gas molecules which will maintain the concentration of the IR-active gas molecules at the desired level. Such an addition may be constituted by e.g., H2 molecules when the IR-active molecules are CH4.
While in the above description there have been given limited examples of IR-active molecules, experiments have shown that many other IR-active molecules are also very useful. Among these there should be mentioned the following gas molecules including rare isotopes:
-`` 13~211~
HF H2o16 HDS so218 N15~13 DF H2o1~ D2S SeO2 PH3 HCl HDo16 H2Se Cl2o2 PD3 D37Cl D2ol6 HDSe cl302 AsH3 D35Cl D2o18 D2Se cl402 AsD3 HB2 TH0 3 CS2 SbH3 DB2 TD0 N1402 CSe2 SbD3 DI H2S So16018 ND3 It will be evident to those skilled in the art that the invention is not limited to the details of the foregoing illustrative embodi-ments and that the present invention may be embodied in other specific forms without departing from the spirit or essential attributes thereof. The present embodiments are therefore to be considered in all respects as illustrative and not restrictive, the scope of the invention being indicated by the appended claims rather than by the foregoing description, and all changes which come within the meaning and range of equivalency of the claims are therefore intended to be embraced therein.
, The present invention relates to sealed-off, molecular sas-discharge sources, without internal electrodes, radiating at discrete, non-coherent and spontaneous emission frequencies in the infra-red (IR) spectrum, and to a method of producing such sources.
Sealed-off, as opposed to non-sealed continuous flow, molecular gas-discharge IR sources are known in the art. These sources are, however, in general of short life span due to dissociation and/or depletion of the IR emitting gas during operation and are weak due to non-radiative relaxation of the excited molecules. Also, the ratio of the IR output to the input power of these known sources, is low. In order to overcome some of these shortcomings, solutions were suggested which include rather complicated structures, such as the device described in Robert A. Young's U.S~ Patent number 3,984,727 and the device described in the U.K. patent number 1,591,709, to R.S. Webley.
It is therefore an object of the present invention to ameliorate the disadvantages of the prior art devices and to provide IR-radiating sources of simple structure capable of emitting narrow spectral lines at discrete spontaneous emission frequencies characteristic of the molecular rotation - vibration transition band of one or several gas species.
It is a further object of the present invention to provide IR-sources which operate continuously for at least several months, have a 3~2~1~
power output, at selected frequencies of at least several milliwatts, and a power efficiency which is such that the specific IR output power at these frequencies is in the order of several percent or even tens of percent, of the total power needed to operate these sources.
These and other objects are achieved by providing a source of IR-radiation, comprising an encl~sure defining between its walls a sealed-off, electrodeless chamber, said walls having at least one portion transparent to IR-radiation, and said chamber containing a gas mixture of at least one, molecular, IR-active gas, of at least one buffer gas and of at least one noble gas, said source of IR-radiation emitting discrete, solely non-coherent, spontaneous emission frec~uencies in the IR-spectrum characteristic of the molecular rotation-vibration transition band of said at least one molecular IR-active gas.
The invention also provides a method for producing a source of IR-radiation, comprising: provid;ng an enclosure made of a dielectric material defining between its walls a chamber, soaking said chamber in a cleaning agent, thoroughly rinsing said chamber with distilled de-ionized waterl drying said chamber, baking said chamber at a temperature of about between 200-300C, introducing in the chamber at least one noble gas, effecting a discharge in the chamber for a period of time and emptying said gas, filling said chamber with a gas mixture containing at least one, molecular, IR-active gas, of at least one buffer gas and of at least one noble gas, and hermetically sealing-off said chamber.
"; ~, ~3~
The invention will now be described in connection with certain preferred embodiments with reference to the following illustrati~/e figures so that it may be more fully understood.
With specific reference now to the figures in detail, it is stressed that the particulars shown are by way of example and for purposes of illustrative discussion of the pre~erred embodiments of the present invention only and are presented in the cause of providing what is believed to be the most useful and readily understood description of the principles and conceptual aspects of the invention.
In this regard, no attempt is made to show structural details of the invention in more detail than is necessary for a fundamental under-standing of the invention, the description taken with the drawings making apparent to those skilled in the art how the several forms of the invention may be embodied in practice~
In the drawings:
Fig, 1 is a schematic representation, partly in cross-section, of an IR-radiation source according to the present invention;
Fig. 2 is a graph showing discrete emission spectrum of an IR-radiation source;
Fig. 3 is a schematic representation of an embodiment of an IR-radiation source according to the invention, and Fig. 4 is a schematic representation of a two compartment IR-radiation source.
1~2~
Referring to Fig. 1, there is illustrated an IR-radiation source 2 constituted by an enclosure 4 defining between its walls a sealed-off chamber 6. The enclosure 4 is made of a dielectric material such as Pyrex ~ glass or quartz and has at least one wall 8 transparent to IR-radiation, which radiation, during operation, can be em;tted there-from in the direction of arrows A. In order to excite gas molecules contained inside the chamber 69 the enclosure 4 may, however, be fitted on the outside thereof, with a pair of electrodes 10 and 12 connectable via a cable 14 to an RF driver (not shown) for powering and controlling the source 2.
In accordance with the present invention, the interior oF theenclosure 4 is filled with a gas mixture containing:
a) at least one, molecular, IR-active gas capable of emitting IR-radiation of a known discrete spectral distribution when suitably excited;
b) at least one buffer gas having relatively long-living state of excited energy levels, capable of storing the absorbed exciting energy for increasing the rate of excitation and emission of the IR-active gas by the V-V (vibration-vibration) collisional process, and c) at least one noble gas for assisting the initiation of the gas mixture discharge and for increasing the concentration of free electrons in the chamber.
Experiments carried out with such mixtures have shown that in order to achieve an IR-radiation source exhibiting a prolonged life span, an enhanced emission, and/or a suitable modulation of the emitted IR-radiation, several inter-related parameters should be taken into account:
i) the mixture of the above-described three types of gases;
ii) the pressure of the mixture inside the chamber, and iii) the configuration of the chamber.
Considering these interdependent parameters, it can be stated that during the natural decay time of the excited IR-active molecules, e.g., in the order of several milliseconds, the molecules are prone to quenching by three different processes: wall quenching, collisional quenching and self quenching. The wall quenching is caused by the diffusion of excited molecules from a location in the bulk of the gaseous medium to the walls of the enclosure where it is rapidly quenched and the excitation is lost. The average diffusion time for an average size of a source operating at gas pressures which are lower than optimal pressures for high output, is several times faster than the radiative life time. This obviously results in a substantial reduction of the IR intensity of the conversion efficiency of discharge energy compared with the corresponding situation in atomic sources in the visible or U.V, regions of the spectrum. The colli-sional quenching occurs between the IR-active molecules and other constituents of the mixture, including impurities. Premature quenching of the excited states by collision of excited molecules with other atoms or molecules present in the gas mixtures, results in a decrease of the intensity of the IR-emission and of the efficiency of IR-source.
The nature of a particular quenching agent depends on the specific emitting molecule and on the excited state. For example the 4.27 emission from the (001) state to the (000) state of a C02 molecule is particularly susceptible to quenching by collision with water or hydrogen molecules.
Finally, molecules in their excited state, emitting character-istic IR-radiation are often quenched by collision with unexcited molecules of the same species. This is called self quenchins and it drastically limits the overall pressure of active species permissible in the IR-emitting source. It follows that IR-active molecular species in the source, as well as atomic or molecular buffer species should be maintained at bound pressures not exceeding predetermined values. Since diffusion to the walls of the enclosure is faster at reduced pressure, ~all quenching and collisional quenching are inter-~ 3 ~
dependent. Thus, only relative large size sources can maintain highemission intensities at considerable power conversion efficiencies.
Examples of IR-radiation sources built and operated, in accordance with the present invention, are as follows:
EXAMPLE NO. GAS MIXTURE RELATIVE PRESSURES
l. C02,N2,He 1:4:7 2~ Co2~N2~Helxe 1:2:2:3 3, C02,N2,Xe 1:2:8 4~ CO,N2,Xe 1:1:8 _ _ _ _ . .......... . _ The total pressure inside the chamber can vary from 1 to 100 torr.
Fig. 2 illustrates the emission intensity of an IR-radiation source comprising C02, N2, Xe, and He, having relative partial pres-sures of 1,2,3,3, and a total pressure in the range of 6 - 25 torr.
The source has been excited by an RF oscillator operating at a frequency range of 4-7 MHz at an average output power of hundreds of milliwatts. The output from the radiation source is in the order of tens of milliwatts.
Referring now, with reference to Figs. 3 and 4, to the aspect of the configuration of the IR-radiation sources, this term as used here-in is meant to encompass~ both, the overall size and shape of an enclosure defining a chamber 6 containing the mixture of the gas.
~3~2'~
g In a gas mixture of example No. 2, for instance, the lifetime at the (001) vibrational state of a carbon dioxide (C02) molecule which produces the 4,27 micron emission is approximately 5 milliseconds, It follows that in order to maximize the IR output, the chamber dimen-sions in the region of the discharge and the gas mixture total and partial pressures should be chosen so as to avoid the possibility that diffusion to the wall could take much less than this time and, that the different collisional relaxing processes will occur at a higher rate than 1/5 milliseconds = 200 sec 1 If, however, it is desired to obtain faster modulation rates of the emitted IR-radiationi the size of the chamber should be small enough so that the diffusion of the molecules to the walls of the chamber will take less than the decay time of the molecule. While for the C02 molecule the decay time is approximately 5 milliseconds, the decay time for C0 (see example No.
4) is about 30 milliseconds.
As seen in Fig. 3, the enclosure 4, is composed of two portions:
a first portion of a greater diameter D (about 40 mm) and of a length L (about 50 mm) called the reservoir and of a second portion of a lesser diameter d, (about 15 mm) and of a length 1 (about 30mm), called the discharge portion or zone. The two electrodes 10 and 12 are coupled onto the discharge zone. Upon excitation, the desired gas emission exits the chamber 6 in the direction of arrow A. Hence~ as can be appreciated, the major volume of the chamber 6 is utilized as a reservoir for constantly replenishing the discharge zone with the same mixture of gas molecules. This type of source configura'cion increases the life span and stability of the output power o~ a source.
Experiments made with an IR-radiation source having a config-uration of Fig. 3 and filled with a gas mixture of example 2 above, have shown that a duration of a life-span exceeding over 10,000 hours of continuous operation can be achieved. Experiments made with a source containing a gas mixture of Example No. 4, achieved continuous operation exceeding 5000 hours.
Other experimental results which were carried out are summarized in the following tables:
TABLE I: Pressure Dependence on IR-radiation Decay_Time Source configuration of Fig. 1; D=15mm; gas mixture of Example No. 3.
Total pressure in Decay Time Comparative IR-the chamber (msec) radiation Output TABLE II: Gas Mixture Dependence on IR-radiation Decay Time Source conFiguration of Fig. 1; D=15mm; total pressure 10 torr~
. _ _ . _ . .
Gas Mixture Decay Time Comparative IR-C2'N2'Xe (msec) radiation Output ~ . . . _ . . _ _ _ 10:20: 30 4 100 10: 1: 30 2 45 10: 1:100 3 60 10: 1:300 2.5 40 TABLE III: Gas Chamber Configuration Dependence on IR-Radiation Decay Time Gas mixture of Example No~ 3; total pressure 10 torr.
-Gas Chamber Diameter Decay TimeComparative IR-(in mm) (msec)radiation Output 3.5 70 -Turning to Fig, 4, there is illustrated a modified source 2, having two compartments 14 and 16. In the compartment 14 there is introduced a gas mixture according to the invention having a certain active gas, (e~g., C02). In the compartment 16 there is sealed a gas m;xture, however, with an additional active gas, (e.g., N20 or any other molecule having a dissociation tendency similar to N?0). When discharge occurs in compartment 14, radiation in direction A from the molecule of said certain active gas enters into the compartment 16 with the additional active gas. In the second compartmènt 16, the first active molecule will absorb the characteristic radiation emanating from the compartment 14 and by the collisional V-V process, will excite the second active molecule to its vibrational state. Hence a radiation in direction B of the second active gas will be emitted from the compartment 16, without inducing a gas discharge in it.
As it has been hereinbefore described, an essential feature of the present invention is the self-controlled long-life continuous emission IR-radiation source, which is achieved, inter alia, by avoiding, as far as possible, different quenching processes and other 3L L~
-causes depleting the IR-active gas in the mixture. In this endeavour, it is proposed to pretreat the interior of the enclosure 4 prior to the introduction of the gas mixture therein as follows:
a) soaking the gas chamber 6 in chemicals. For example, overnight soaking with 30% Nitric Acid in water or Sulphuric Acid + 1%
Sodium persulphate, or sulpho-chromic Acid, or other similar cleaning agents such as AlconoxR, MicroR or NochromixR;
b) thoroughly rinsing with double-distilled de-ionized water;
c) drying the chamber with e.g., ethanol;
d) baking at 280C in a vacuum oven;
e) introducing in the chamber a noble gas, e.g., Xe, effecting a discharge in the chamber for a short period of time and emptying the gas; and f) introducing a gas mixture in the chamber substantially equal to the gas mixture to be used in the source, effecting a discharge for a short period of time, e.g~, several minutes, and emptying the gas.
Having baked out and evacuated the chamber, and having eFfected discharges with gases of the final mixture used, the selected gases, as described hereinbefore, are introduced into the chamber at the calculated ratios and pressures, the chamber is then hermetically sealed-off.
Optionally, the enclosure materials which normally have high relaxing tendency to the IR-active molecules, can be coated with substances which reduce this tendency, for example, Barium Fluoride or Sapphire.
Alternatively, it is proposed to produce the enclosure wall material with a radioactive substance, that while radiating into the chamber, assists in pre-conditioning the gas mixture inside the enclosure for easy ignition~ The same effect can be achieved by adding traces of radioactive gas such as 85Kr.
Also, in order to maintain a preferred level of IR-active gas molecules, it is suggested in some cases7 to add to the mixture gas molecules which will maintain the concentration of the IR-active gas molecules at the desired level. Such an addition may be constituted by e.g., H2 molecules when the IR-active molecules are CH4.
While in the above description there have been given limited examples of IR-active molecules, experiments have shown that many other IR-active molecules are also very useful. Among these there should be mentioned the following gas molecules including rare isotopes:
-`` 13~211~
HF H2o16 HDS so218 N15~13 DF H2o1~ D2S SeO2 PH3 HCl HDo16 H2Se Cl2o2 PD3 D37Cl D2ol6 HDSe cl302 AsH3 D35Cl D2o18 D2Se cl402 AsD3 HB2 TH0 3 CS2 SbH3 DB2 TD0 N1402 CSe2 SbD3 DI H2S So16018 ND3 It will be evident to those skilled in the art that the invention is not limited to the details of the foregoing illustrative embodi-ments and that the present invention may be embodied in other specific forms without departing from the spirit or essential attributes thereof. The present embodiments are therefore to be considered in all respects as illustrative and not restrictive, the scope of the invention being indicated by the appended claims rather than by the foregoing description, and all changes which come within the meaning and range of equivalency of the claims are therefore intended to be embraced therein.
Claims (15)
1. A source of IR-radiation, comprising:
an enclosure defining between its walls a sealed-off, electrodeless chamber, said walls having at least one portion transparent to IR-radiation, and said chamber containing a gas mixture of at least one, molecular, IR-active gas, of at least one buffer gas and of at least one noble gas, said source of IR-radiation emitting discrete, solely non-coherent, spontaneous emission frequencies in the IR-spectrum characteristic of the molecular rotation-vibration transition band of said at least one molecular IR-active gas.
an enclosure defining between its walls a sealed-off, electrodeless chamber, said walls having at least one portion transparent to IR-radiation, and said chamber containing a gas mixture of at least one, molecular, IR-active gas, of at least one buffer gas and of at least one noble gas, said source of IR-radiation emitting discrete, solely non-coherent, spontaneous emission frequencies in the IR-spectrum characteristic of the molecular rotation-vibration transition band of said at least one molecular IR-active gas.
2. The source as claimed in claim 1 wherein said IR-active gas is selected from the group of CO2 and CO,
3. The source as claimed in claim 1 wherein said IR-active gas molecule contains at least one rare isotope.
4. The source as claimed in claim 1 wherein said buffer gas is selected from the group containing N2, CO or a mixture thereof,
5. The source as claimed in claim 1 wherein said noble gas is He or Xe.
6. The source as claimed in claim 1 wherein said gas mixture, inside a given volume and configuration of said chamber, provides a total pressure at which the average random propelling time to a wall of said chamber exceeds about 5 milliseconds, for maximizing the radiation output power.
7. The source as claimed in claim 1 wherein, for a given volume and configuration of said chamber, the partial pressure of quenching gas particles inside said chamber is such that the collisional quenching rate does not exceed about 200 sec-1, for maximizing the radiation output power.
8. The source as claimed in claim 1 wherein said gas mixture, inside a given volume and configuration of said chamber, is less than about 5 milliseconds for obtaining faster radiation modulation rate.
9. The source as claimed in claim 1 wherein, for a given volume and configuration of said chamber, the partial pressure of quenching gas particles inside said chamber is such that the collisional quenching rate exceed about 200 sec-1, for obtaining a faster output radiation modulation rate.
10. The source as claimed in claim 1 wherein said enclosure is pro-vided with two portions, a first larger portion defining a reservoir and a second portion of a smaller size, defining a discharge zone.
11. The source as claimed in claim 1 wherein said enclosure is divided into two compartments, by a partition, said partition being transparent to IR-radiation.
12. The source as claimed in claim 11 wherein a first of said two compartments is filled with said gas mixture and a second of said two compartments is filled with said gas mixture and an additional active gas molecule having a tendency for dissociation similar to that of an N2O molecule.
13. The source as claimed in claim 1 wherein the walls of said chamber are coated with a material which reduces the tendency of relaxing colliding excited IR-active molecules.
14. A method for producing a source of IR-radiation, comprising:
a) providing an enclosure made of a dielectric material defining between its walls a chamber;
b) soaking said chamber in a cleaning agent;
c) thoroughly rinsing said chamber with distilled de-ionized water;
d) drying said chamber;
e) baking said chamber at a temperature of about between 200-300°C;
f) introducing in the chamber at least one noble gas, effecting a discharge in the chamber for a period of time and emptying said gas;
g) filling said chamber with a gas mixture containing at least one, molecular, IR-active gas, of at least one buffer gas and of at least one noble gas, and h) hermetically sealing-off said chamber.
a) providing an enclosure made of a dielectric material defining between its walls a chamber;
b) soaking said chamber in a cleaning agent;
c) thoroughly rinsing said chamber with distilled de-ionized water;
d) drying said chamber;
e) baking said chamber at a temperature of about between 200-300°C;
f) introducing in the chamber at least one noble gas, effecting a discharge in the chamber for a period of time and emptying said gas;
g) filling said chamber with a gas mixture containing at least one, molecular, IR-active gas, of at least one buffer gas and of at least one noble gas, and h) hermetically sealing-off said chamber.
15. The method as claimed in claim 14 further comprising the step of introducing into the chamber a gas mixture of step g), effecting a discharge in said chamber for a period of time and emptying said gas, prior to said filling of said chamber with a gas mixture and sealing same off.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IL84463A IL84463A (en) | 1987-11-12 | 1987-11-12 | Ir-radiation source and method for producing same |
| IL84463 | 1987-11-12 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1312114C true CA1312114C (en) | 1992-12-29 |
Family
ID=11058319
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA000582820A Expired - Lifetime CA1312114C (en) | 1987-11-12 | 1988-11-10 | Ir-radiation source and method for producing same |
Country Status (6)
| Country | Link |
|---|---|
| EP (1) | EP0316189B1 (en) |
| JP (1) | JPH01161661A (en) |
| AT (1) | ATE117462T1 (en) |
| CA (1) | CA1312114C (en) |
| DE (1) | DE3852813T2 (en) |
| IL (1) | IL84463A (en) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB8914722D0 (en) * | 1989-06-27 | 1989-08-16 | Emi Plc Thorn | A discharge tube arrangement |
| GB8920051D0 (en) * | 1989-09-05 | 1989-10-18 | Emi Plc Thorn | A discharge tube arrangement |
| GB8922862D0 (en) * | 1989-10-11 | 1989-11-29 | Emi Plc Thorn | A discharge tube arrangement |
| DE4120730C2 (en) * | 1991-06-24 | 1995-11-23 | Heraeus Noblelight Gmbh | Electrodeless low-pressure discharge lamp |
| DE10128915A1 (en) | 2001-06-15 | 2002-12-19 | Philips Corp Intellectual Pty | Low pressure gas discharge lamp with mercury-free gas filling |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3617110A1 (en) * | 1986-05-21 | 1987-11-26 | Leybold Heraeus Gmbh & Co Kg | Lamp for producing resonant gas radiation |
-
1987
- 1987-11-12 IL IL84463A patent/IL84463A/en not_active IP Right Cessation
-
1988
- 1988-11-10 CA CA000582820A patent/CA1312114C/en not_active Expired - Lifetime
- 1988-11-11 DE DE3852813T patent/DE3852813T2/en not_active Expired - Lifetime
- 1988-11-11 AT AT88310636T patent/ATE117462T1/en not_active IP Right Cessation
- 1988-11-11 EP EP88310636A patent/EP0316189B1/en not_active Expired - Lifetime
- 1988-11-11 JP JP63286619A patent/JPH01161661A/en active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| ATE117462T1 (en) | 1995-02-15 |
| DE3852813T2 (en) | 1995-08-31 |
| EP0316189A2 (en) | 1989-05-17 |
| EP0316189A3 (en) | 1990-08-22 |
| IL84463A0 (en) | 1988-04-29 |
| JPH01161661A (en) | 1989-06-26 |
| EP0316189B1 (en) | 1995-01-18 |
| IL84463A (en) | 1992-06-21 |
| DE3852813D1 (en) | 1995-03-02 |
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