CA1305846C

CA1305846C - Method of catalytic cleaning of exhaust gases

Info

Publication number: CA1305846C
Application number: CA 549900
Authority: CA
Inventors: Jury Shaevich Matros; Viktor Anatolievich Chumachenko; Ljudmila Jurievna Zudilina; Alexandr Stepanovich Noskov; Evgeny Stepanovich Bogdan
Original assignee: Boreskov Institute of Catalysis Siberian Branch of Russian Academy of Sciences; SPETSIALNOE KONSTRUKTORSKO-TEKHNOLOGICHESKOE BJURO KATALIZATOROV S OPYTNYM ZAVODOM (SKTB KATALIZATOROV)
Current assignee: Boreskov Institute of Catalysis Siberian Branch of Russian Academy of Sciences; SPETSIALNOE KONSTRUKTORSKO-TEKHNOLOGICHESKOE BJURO KATALIZATOROV S OPYTNYM ZAVODOM (SKTB KATALIZATOROV)
Priority date: 1987-10-21
Filing date: 1987-10-21
Publication date: 1992-08-04

Abstract

ABSTRACT

The present invention relates to methods of catalytic cleaning Or exhaust gases.
According to the invention, the method of catalytic cleaning of exhaust gases from organics and carbon mono-xide consists in that an exhaust gas is passed through a bed of deep oxidation catalyst. The process is carried out with a temperature of 250-700°C. The catalist is made up of two parts. The exhaust gas is passed through a first part of the catalyst bed, stirred and passed through a second part of the catalyst bed. The stirring is continued until the temperature drop in the stream of the gas which is being cleaned is not over 50°C at the entrance into the second part of the catalyst bed, and the flow of the gas is reversed at regular intervals during the cleaning.

Claims

1. A method of catalytic cleaning of exhaust gases from organics and carbon monoxide, consisting in that an exhaust gas is passed through a bed of deep oxidation catalyst made up of two parts, whereby the exhaust gas is passed through a first part of the catalyst bed, stirred and passed through a second part of the catalyst bed, emerging wherefrom is the cleaned gas; said stirring lasting until the temperature drop in the stream of the gas which is being cleaned is not over 50°C at the entrance into the second part of the catalyst bed; the direction of the gas flow through the catalyst bed being reversed at regular intervals; wherein the operating temperature is from 250 to 700°C.

2. A method as claimed in Claim 1, according to which a gas containing air pollutants in an amount lees than 1 g/m3 is cleaned by being passed through the deep oxidation catalyst bed in the presence of a hydrocarbon fuel which is added periodically to the incoming exhaust gas in an amount of 0.5-5 g/m3.

3. A method for the reversible flow catalytic oxidation of a gas stream containing organic compositions, carbon monoxide or a mixture thereof, which comprises:

(1) passing the gas stream through a first bed of oxidation catalyst to oxidize at least a portion of the organic composition, carbon monoxide or mixture thereof; (2) mixing the gas stream passing from the first bed of oxidation catalyst so that the difference in temperature between the coldest portion of the gas stream and the hottest portion of the gas stream is not more than 50° C; (3) passing the mixed gas stream through a second bed of oxidation catalyst to further oxidize the oxidizable materials in the gas stream;
and (4) reversing the direction of flow of the gas stream wherein the second bed of oxidation catalyst becomes the first bed of oxidation catalyst and wherein the temperature of the catalyst beds is maintained in the range of 350° to 750° C.

4. A method as claimed in claim 3, wherein a gas containing air pollutants in an amount less than 1 g/m3 is cleaned by being passed through the catalyst bed in the presence of a hydrocarbon fuel which is added periodically to the incoming exhaust gas in an amount of 0.5-5 g/m3.