CA1295283C - Electroplating system with rinse tank and evaporator for contaminated effluent - Google Patents
Electroplating system with rinse tank and evaporator for contaminated effluentInfo
- Publication number
- CA1295283C CA1295283C CA000499261A CA499261A CA1295283C CA 1295283 C CA1295283 C CA 1295283C CA 000499261 A CA000499261 A CA 000499261A CA 499261 A CA499261 A CA 499261A CA 1295283 C CA1295283 C CA 1295283C
- Authority
- CA
- Canada
- Prior art keywords
- tank
- water
- rinse
- plating
- electroplating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000009713 electroplating Methods 0.000 title claims abstract description 29
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 102
- 238000007747 plating Methods 0.000 claims abstract description 75
- 238000000034 method Methods 0.000 claims abstract description 51
- 239000007921 spray Substances 0.000 claims abstract description 43
- 239000002351 wastewater Substances 0.000 claims abstract description 28
- 238000001704 evaporation Methods 0.000 claims abstract description 14
- 238000004065 wastewater treatment Methods 0.000 claims abstract description 9
- 229910052751 metal Inorganic materials 0.000 claims description 22
- 239000002184 metal Substances 0.000 claims description 22
- 238000011109 contamination Methods 0.000 claims description 9
- 239000002699 waste material Substances 0.000 claims description 9
- 239000000463 material Substances 0.000 claims description 7
- 230000003247 decreasing effect Effects 0.000 claims description 3
- 239000007787 solid Substances 0.000 claims description 3
- 239000012530 fluid Substances 0.000 claims description 2
- 239000002910 solid waste Substances 0.000 claims 3
- 238000010438 heat treatment Methods 0.000 claims 1
- 230000003472 neutralizing effect Effects 0.000 claims 1
- 230000008569 process Effects 0.000 abstract description 41
- 230000008020 evaporation Effects 0.000 abstract description 12
- 238000011282 treatment Methods 0.000 abstract description 8
- 239000000356 contaminant Substances 0.000 description 16
- 229910001369 Brass Inorganic materials 0.000 description 15
- 239000010951 brass Substances 0.000 description 15
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 14
- 239000000243 solution Substances 0.000 description 12
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 9
- 239000003643 water by type Substances 0.000 description 9
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 7
- 229910052802 copper Inorganic materials 0.000 description 7
- 239000010949 copper Substances 0.000 description 7
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 7
- 229910052737 gold Inorganic materials 0.000 description 7
- 239000010931 gold Substances 0.000 description 7
- 238000006386 neutralization reaction Methods 0.000 description 7
- 229910052759 nickel Inorganic materials 0.000 description 7
- 238000007792 addition Methods 0.000 description 6
- 238000004140 cleaning Methods 0.000 description 6
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 description 5
- 239000002253 acid Substances 0.000 description 5
- 238000010586 diagram Methods 0.000 description 5
- 239000012535 impurity Substances 0.000 description 5
- 239000010802 sludge Substances 0.000 description 5
- 239000000470 constituent Substances 0.000 description 4
- 230000006378 damage Effects 0.000 description 4
- 229910001385 heavy metal Inorganic materials 0.000 description 4
- 150000004677 hydrates Chemical class 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 3
- 230000000737 periodic effect Effects 0.000 description 3
- 239000010865 sewage Substances 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 2
- 235000011941 Tilia x europaea Nutrition 0.000 description 2
- 238000013019 agitation Methods 0.000 description 2
- 238000000889 atomisation Methods 0.000 description 2
- 239000003518 caustics Substances 0.000 description 2
- 229910052804 chromium Inorganic materials 0.000 description 2
- 239000011651 chromium Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 239000013505 freshwater Substances 0.000 description 2
- WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Chemical compound Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 description 2
- 239000004571 lime Substances 0.000 description 2
- 239000000314 lubricant Substances 0.000 description 2
- 229910044991 metal oxide Inorganic materials 0.000 description 2
- 150000004706 metal oxides Chemical class 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 238000005554 pickling Methods 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- 238000000746 purification Methods 0.000 description 2
- 150000004760 silicates Chemical class 0.000 description 2
- 229910052709 silver Inorganic materials 0.000 description 2
- 239000004332 silver Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 241000232971 Passer domesticus Species 0.000 description 1
- 239000005708 Sodium hypochlorite Substances 0.000 description 1
- 230000000712 assembly Effects 0.000 description 1
- 238000000429 assembly Methods 0.000 description 1
- 230000005465 channeling Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000011284 combination treatment Methods 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000000498 cooling water Substances 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- JEGUKCSWCFPDGT-UHFFFAOYSA-N h2o hydrate Chemical class O.O JEGUKCSWCFPDGT-UHFFFAOYSA-N 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 241000238565 lobster Species 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- 238000009428 plumbing Methods 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 239000008213 purified water Substances 0.000 description 1
- 238000011536 re-plating Methods 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25F—PROCESSES FOR THE ELECTROLYTIC REMOVAL OF MATERIALS FROM OBJECTS; APPARATUS THEREFOR
- C25F7/00—Constructional parts, or assemblies thereof, of cells for electrolytic removal of material from objects; Servicing or operating
- C25F7/02—Regeneration of process liquids
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/02—Treatment of water, waste water, or sewage by heating
- C02F1/04—Treatment of water, waste water, or sewage by heating by distillation or evaporation
- C02F1/048—Purification of waste water by evaporation
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D21/00—Processes for servicing or operating cells for electrolytic coating
- C25D21/16—Regeneration of process solutions
- C25D21/20—Regeneration of process solutions of rinse-solutions
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/16—Nitrogen compounds, e.g. ammonia
- C02F2101/18—Cyanides
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/20—Heavy metals or heavy metal compounds
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/20—Heavy metals or heavy metal compounds
- C02F2101/22—Chromium or chromium compounds, e.g. chromates
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/16—Nature of the water, waste water, sewage or sludge to be treated from metallurgical processes, i.e. from the production, refining or treatment of metals, e.g. galvanic wastes
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Heat Treatment Of Water, Waste Water Or Sewage (AREA)
- Crystals, And After-Treatments Of Crystals (AREA)
Abstract
AN IMPROVED ELECTROPLATING SYSTEM
ABSTRACT
An electroplating system with improved water use efficiency and unique waste water treatment which enables operation without access to public sewers thereby permitting compliance with governmental regulations regarding disposal of waste water. Water use efficiency is achieved by means of limited use governmental water sprays, multiple rinse tank backflow to the prior processs tank and water evaporation from said process tanks. In addition, all waste water not returned to the prior process tank locally at each plating subassembly is transferred to an inplant sump for common evaporative treatment.
ABSTRACT
An electroplating system with improved water use efficiency and unique waste water treatment which enables operation without access to public sewers thereby permitting compliance with governmental regulations regarding disposal of waste water. Water use efficiency is achieved by means of limited use governmental water sprays, multiple rinse tank backflow to the prior processs tank and water evaporation from said process tanks. In addition, all waste water not returned to the prior process tank locally at each plating subassembly is transferred to an inplant sump for common evaporative treatment.
Description
5~3 BACKGROUND OF THE INVENTION
FIELD OF THE INVENTION
The present invention relates generally to the field of electroplating systems and more specifically, to an electro-plating system designed to operate without access to public sewers.
PRI~R ART
With the plethora of state and federal regulations on control of toxic materials in waste water, it has become incumbent on plating enterprises to control the level of materials such as cyanide, heavy metals and the like in waste water leaving a plant. The source of the vast majority of this ~aste water is the rinse water used between the various steps in the plating procedure. Typically, the simplest plating cycles require three steps. These include cleaning to remove such soiling materials as buffing compounds, stamping or cutting lubricants and the like; an acîd dip to remove metal oxides, often called pickling; and finally, electroplating with one or ~ore metals. Upon withdrawal of parts from each of the ~0 processing tanks used in the aforementioned plating steps, the p~rts to be plated are covered with a film of the processing solution commonly referred to as dragout. This material is invariably a contaminant to the following process tank and must be removed by water rinsing before the parts enter the following process tank. These rinses must be constantly overflowed with clean or cleaner water to prevent buildup in the levels of process tank constituents , ~5~83 so that contamination of the Eollowing process tank does not result. Therefore, a major problem in controlling plant effluen-t is the control of quantity and content of the rinse waters that are generated in the plating sequence.
The present invention solves this problem by improving rinsing efficiency while minimizing water requirements.
Rinsing efEiciency is improved by providing air agitation in the rinse tank to ensure that the dragout is diluted to 1~ the maximum extent consistent with the rinse volume and the amount of dragin. In addition, the invention provides sprays over each tank which are active during withdrawal of the part or workpiece. This further dilutes the dragout and provides fresh water to prevent excessive buildup of the contaminants in the rinse water. Typically, the volume of water through a single rinse tank has to be rather high to keep the contaminants in the rinse water at a sufficiently low level to be tolerated in the following p~ocess tank. The present invention significantly reduces ~n the amount of water by multiple rinses. For example, it can be seen in a series of three consecutive rinses that e~ch rinse would be cleaner than the rinse ahead of it.
This makes it feasible to "backflow" the water from the third to the second to the first rinse in each tank. As a result, the incoming water is significantly cleaner than the contaminant level in the tank. The contaminants in the rinse waters are the constituents of the previous process tank. It is therefore feasible to return water to a previous process tank.
. ~ .
~ . ~ ~ .
1 ~Z9~i~83 The use of multiple rinses is one means for reducing the volume of rinse water, but ordinarily in most cases, the rinse water volume is still more than that which can be returned to the process tank. The present invention makes room in the process tank for these rinse waters by using an evaporator consisting of a device for pumping the solution continuously through a chamber designed to provide maximum surface area for liquid. At the same time a blower provides maximum air flow through the chamber which results in a significant amount of 1~ evaporation and makes room in the tank for the return o backflow rinse water from the sequence of tanks.
Although there are prior art patents which disclose some of the individual features of the present invention, no patents have been found which disclose the specific combination of ~eatures which permit operation of a plating system without access to public sewers.
United States Patent No. 2,984,081 to Hahn is directed to tha cooling of chromium plating solution and provides for a plating solution tank in which fluid is passed through a conduit into an evaporator.
United States Patent No. 3,616,437 to Yagishita is directed to a system for reclaiming plating wastes wherein a liquid rinse water is brought into a tower where it is heated by steam in order to partially vaporlze it. ~he vapor is then passed to an ejector where it is introduced into cooling water to be condensed and then brought to a reservoir.
~2~ 33 United States Patent No. 3,637,467 to Spatz is directed to a metal reclamation process and system which uses a primary rinse tank and a secondary rinse tank. Liquid is drawn off through a conduit and passed to a pump where it is brought into a reverse !
osmosis unit, the concentrate of which passes back to the plating tank and wherein permeate is brought through a conduit back to the primary rinse tank.
United States Patent No. 4,197,167 to Wright ~r. is directed to a process for recovery and reuse of metal electroplating baths. The system includes a reservoir which is supplied with a portion of the rinse mixture from a tank. Acid is added to the rinse mixture in the reservoir and the rinse and acid mixture is then recirculated through filters and back to the reservoir.
United States Patent No. 3,146,195 to Berardi is directed to purification of water in a lobster tank wh~xein the force of water coming out of the tube provides an aspirating action and draws air through the air tube and mixes the air with purified water issuing ~rom the tube. The mixture of water and air is projected out of the end of the submerged tube.
United States Patent No. 2,773,029 to Sebald is directed to a water treating system in which water is led to a primary water softener through a water conduit which is connected to spray valves disposed at the upper end of the softener.
None o~ these patents discloses a system which may operated e~ficiently without any access at all to public sewers for the disposal of the waste produced by an electroplating system.
Il ~Z~5~3 SUMMAR~ OF T~E INVENTION
-3 The present invention comprises a plating system which can be 4 operated without acce~s to public sewers. It comprises four principal subsystems including a nickel-chrome plating 6 subsystem, a copper-brass plating subsystem, a strip line 7 subsystem and a waste water treatment subsystemO In the 8 nickel-chrome subsystem, the only waste water produced is the 9 rlnse after an acid dip which is disposed of in an inplant sump. Three backflow rinse cycles are provided, one for the 1 cleaning operation, one for the nickel ~latmg operat~on ~ld one for the chrome plating operation. The number of rinses in each 3 cycle varies as the tolerance for the dragover into the 1~ following process tank varies in each case. Clean water i8 13 added to each of the last rinses from an overhead spray on a 1~ hoist which operates only on the withdrawal of parts from the 1~ - last rinse. The second subassembly, namely, the copper-brass 13 line is typically used for work limited to small parts on an 19 intermittent basis. In order to minimize rinse water carry-~0 over, thereby keeping rinse water requirements to minimum, a 21 hang-up bar is provided over each plating tank and each rinse 12 tank This hang-up bar allows parts to drain thoroughly and 13 reduces the carry-over to the following tank. Backflow water ~ generated by two rinses progresses through a separate tank for .~ destruction of the cyanide content of the solution by chemical ~6 oxidation accomplished by controlled addition of sodium '7 hypochlorite. An air-water spray wand is used over the second ,~ rinse tank. The backflow water is then transferred to an 9 inplant sump for waste water evaporation after treatment in a neutralization sump.
3~
~ i283 I The strip line assembly employs tanks which are used 2 intermittently for stripping plated metal from parts that are 3 to be replated. ~ang-up bars are provided over each strip tank 4 and each rinse tank to assure good drainage of parts. A wand consisting of a water spray with air atomization is provided 6 for rinsing with clean water over the rinse tank. The rinses 7 are also overflowed to the water evaporation tank.
9 The waste water treatment subassembly is connected by means lo of an inplant sump to the other suba~semblies from which waste ll water is received. The waste water from the three other 12 subassemblies enters the inplant sump and is eventually 13 transferred to a neutralizer ~ump. ~he waste water pH level is 1~ adjusted to 7.0 to 8.0 and then it progresses through a sump Is pump to an evaporator tank. The amount of rinse water is held 1~ to an absolute minimum in each subsystem. The contaminants in 17 the waste waters are primarily heavy metals which after cyanide 18 destruction to break the copper and brass complex, precipitate 1~ as metal hydrates. The waste water treatment 6ubsystem employs ~o a continuously operating sludge filter to remove these metal 21 hydrates along with silicates precipitated from spent cleaners 21 during neutraliza~ion. Sulfates are precipitated by the 23 addition of calculated amounts of lime. An evaporator tank is 24 maintained at a sufficiently high temperature to promote 2~ evaporation and is run continuously. The sludge is 26 accummulated as a dewatered cake and is oven dried to further reduce water content. This cake can then be accummulated and ;O roved to a Cla~s A landf'll at periodic intervals.
,~' ','' ' ,. ~ ;
~ ;2~3 l OBJE~TS OF THE INVENTIO~
4 It is therefore a principal object of the present invention to provide a plating system capable of nickel-chrome plating, 6 copper-brass plating and plate stripping without requiring ~ access to public sewers.
9 It is an additional object of the present invention to provide an apparatus for accomplishing the typical plating ll processes in which the quantity and content of rinse waters 12 used in the plating sequence are carefully controlled to 13 preclude a necessity for access to public sewers for disposing 14 of the waste waters.
1~
16 It is still an additional object of the present invention to 17 provide a novel electroplating facility and waste water 18 treatment combination which permits normal plating and 19 stripping operations in such a facility without generating 2~ waste rinse water which must be otherwise disposed o~ in a ~1 public sewage system~
~3 It is an additional object of the present invention to 2~ provide an apparatus for accomplishing typical metal plating 2~ processes in which the quantity and content of rinse waters in 26 the plating sequence are carefully controlled to preclude a 27 necessity for having access to public sewers for disposing of 28 the waste rinse waters used between the various steps in the 79 plating procedure.
3~
"
' ;;,; ~
It is still an additional object of the present invention to , provide a metal plating facility comprising subassemblies for 3 nickel-chrome plating, copper-brass plating and plate stripping 4 while at the same time recovering waste waters used for rinsing in the various subassemblies in a common waste water treatment 6 subassembly which permits treatment and disposal of waste water 7 effluents without requiring sewage disposal which might fall S outside of the disposal regulations of federal, state and local 9 agencies.
In a preferred embodiment the present invention is directed 11 to an improved electroplating system comprising: at least one 1. electroplating tank for plating parts; at least one water 13 rinse tank, said plated parts being transferred from said 1~ electroplating tank to said water rinse tank; means for pro-1~ viding a source of uncontaminated water positioned adjacent 1~ said rinse tank for (1) rinsing plated parts during a removal 1~ of said plated parts from said rinse tank and (2) inserting 1~ substantially uncontaminated water into said rinse tank for Ig reducing the contamination level of said rinse tank; means ~0 ~ox transferring overflow water from said rinse tank to a ,1 spray positioned above said plating tank for decreasing the contamination level of said rinse tank while removing dragout ~3 from said plated parts while they are being removed from said .~ plating tank; and an evaporator connected to said plating ~5 tank for receiving contaminated effluent from said plating ~6 tank for disposal of said plating tank effluent without ~7 cess to puùlic sewers.
.'",`~f' ~ ; ' t~
~ !
BPIEF DESCRIP~l!IOli OE Tlll: DP~WINGS
3 The aforementioned objects and advantages of the present ~ invention, as well as additional objects and advantages thereof, will be more full~ understood hereinafter as a result 6 of a detailed description of a preferred embodiment when taken 7 in conjunction with the following drawings:
9 FIG~ l is a block diagram representation of the nickel-chrome plating subassembly of the present invention;
ll 1~ FIG. ~ is a block diagram representation of the copper-brass 3 plating subassembly of the present invention;
1~ FIG. 3 is a block diagram representation of the strip line 1~ subassembly of the present invention;
1~
13 FIG. 4 is a block diagram representation of the waste water 19 treatment subassembly of the present invention; and 21 FIG. 5 is a block diagram representation of a typical ~ ckilow sequence utilized in the pre~ent invention.
\
3~
~2~ 3 l DETAILED DESCRIPTION OF A PREFERRED EMBODIMENT
~ Reference will first be made to FIG~ 1 which illustrates the 5 nickel-chrome pla~ing æubassembly of the pxesent invention.
FIELD OF THE INVENTION
The present invention relates generally to the field of electroplating systems and more specifically, to an electro-plating system designed to operate without access to public sewers.
PRI~R ART
With the plethora of state and federal regulations on control of toxic materials in waste water, it has become incumbent on plating enterprises to control the level of materials such as cyanide, heavy metals and the like in waste water leaving a plant. The source of the vast majority of this ~aste water is the rinse water used between the various steps in the plating procedure. Typically, the simplest plating cycles require three steps. These include cleaning to remove such soiling materials as buffing compounds, stamping or cutting lubricants and the like; an acîd dip to remove metal oxides, often called pickling; and finally, electroplating with one or ~ore metals. Upon withdrawal of parts from each of the ~0 processing tanks used in the aforementioned plating steps, the p~rts to be plated are covered with a film of the processing solution commonly referred to as dragout. This material is invariably a contaminant to the following process tank and must be removed by water rinsing before the parts enter the following process tank. These rinses must be constantly overflowed with clean or cleaner water to prevent buildup in the levels of process tank constituents , ~5~83 so that contamination of the Eollowing process tank does not result. Therefore, a major problem in controlling plant effluen-t is the control of quantity and content of the rinse waters that are generated in the plating sequence.
The present invention solves this problem by improving rinsing efficiency while minimizing water requirements.
Rinsing efEiciency is improved by providing air agitation in the rinse tank to ensure that the dragout is diluted to 1~ the maximum extent consistent with the rinse volume and the amount of dragin. In addition, the invention provides sprays over each tank which are active during withdrawal of the part or workpiece. This further dilutes the dragout and provides fresh water to prevent excessive buildup of the contaminants in the rinse water. Typically, the volume of water through a single rinse tank has to be rather high to keep the contaminants in the rinse water at a sufficiently low level to be tolerated in the following p~ocess tank. The present invention significantly reduces ~n the amount of water by multiple rinses. For example, it can be seen in a series of three consecutive rinses that e~ch rinse would be cleaner than the rinse ahead of it.
This makes it feasible to "backflow" the water from the third to the second to the first rinse in each tank. As a result, the incoming water is significantly cleaner than the contaminant level in the tank. The contaminants in the rinse waters are the constituents of the previous process tank. It is therefore feasible to return water to a previous process tank.
. ~ .
~ . ~ ~ .
1 ~Z9~i~83 The use of multiple rinses is one means for reducing the volume of rinse water, but ordinarily in most cases, the rinse water volume is still more than that which can be returned to the process tank. The present invention makes room in the process tank for these rinse waters by using an evaporator consisting of a device for pumping the solution continuously through a chamber designed to provide maximum surface area for liquid. At the same time a blower provides maximum air flow through the chamber which results in a significant amount of 1~ evaporation and makes room in the tank for the return o backflow rinse water from the sequence of tanks.
Although there are prior art patents which disclose some of the individual features of the present invention, no patents have been found which disclose the specific combination of ~eatures which permit operation of a plating system without access to public sewers.
United States Patent No. 2,984,081 to Hahn is directed to tha cooling of chromium plating solution and provides for a plating solution tank in which fluid is passed through a conduit into an evaporator.
United States Patent No. 3,616,437 to Yagishita is directed to a system for reclaiming plating wastes wherein a liquid rinse water is brought into a tower where it is heated by steam in order to partially vaporlze it. ~he vapor is then passed to an ejector where it is introduced into cooling water to be condensed and then brought to a reservoir.
~2~ 33 United States Patent No. 3,637,467 to Spatz is directed to a metal reclamation process and system which uses a primary rinse tank and a secondary rinse tank. Liquid is drawn off through a conduit and passed to a pump where it is brought into a reverse !
osmosis unit, the concentrate of which passes back to the plating tank and wherein permeate is brought through a conduit back to the primary rinse tank.
United States Patent No. 4,197,167 to Wright ~r. is directed to a process for recovery and reuse of metal electroplating baths. The system includes a reservoir which is supplied with a portion of the rinse mixture from a tank. Acid is added to the rinse mixture in the reservoir and the rinse and acid mixture is then recirculated through filters and back to the reservoir.
United States Patent No. 3,146,195 to Berardi is directed to purification of water in a lobster tank wh~xein the force of water coming out of the tube provides an aspirating action and draws air through the air tube and mixes the air with purified water issuing ~rom the tube. The mixture of water and air is projected out of the end of the submerged tube.
United States Patent No. 2,773,029 to Sebald is directed to a water treating system in which water is led to a primary water softener through a water conduit which is connected to spray valves disposed at the upper end of the softener.
None o~ these patents discloses a system which may operated e~ficiently without any access at all to public sewers for the disposal of the waste produced by an electroplating system.
Il ~Z~5~3 SUMMAR~ OF T~E INVENTION
-3 The present invention comprises a plating system which can be 4 operated without acce~s to public sewers. It comprises four principal subsystems including a nickel-chrome plating 6 subsystem, a copper-brass plating subsystem, a strip line 7 subsystem and a waste water treatment subsystemO In the 8 nickel-chrome subsystem, the only waste water produced is the 9 rlnse after an acid dip which is disposed of in an inplant sump. Three backflow rinse cycles are provided, one for the 1 cleaning operation, one for the nickel ~latmg operat~on ~ld one for the chrome plating operation. The number of rinses in each 3 cycle varies as the tolerance for the dragover into the 1~ following process tank varies in each case. Clean water i8 13 added to each of the last rinses from an overhead spray on a 1~ hoist which operates only on the withdrawal of parts from the 1~ - last rinse. The second subassembly, namely, the copper-brass 13 line is typically used for work limited to small parts on an 19 intermittent basis. In order to minimize rinse water carry-~0 over, thereby keeping rinse water requirements to minimum, a 21 hang-up bar is provided over each plating tank and each rinse 12 tank This hang-up bar allows parts to drain thoroughly and 13 reduces the carry-over to the following tank. Backflow water ~ generated by two rinses progresses through a separate tank for .~ destruction of the cyanide content of the solution by chemical ~6 oxidation accomplished by controlled addition of sodium '7 hypochlorite. An air-water spray wand is used over the second ,~ rinse tank. The backflow water is then transferred to an 9 inplant sump for waste water evaporation after treatment in a neutralization sump.
3~
~ i283 I The strip line assembly employs tanks which are used 2 intermittently for stripping plated metal from parts that are 3 to be replated. ~ang-up bars are provided over each strip tank 4 and each rinse tank to assure good drainage of parts. A wand consisting of a water spray with air atomization is provided 6 for rinsing with clean water over the rinse tank. The rinses 7 are also overflowed to the water evaporation tank.
9 The waste water treatment subassembly is connected by means lo of an inplant sump to the other suba~semblies from which waste ll water is received. The waste water from the three other 12 subassemblies enters the inplant sump and is eventually 13 transferred to a neutralizer ~ump. ~he waste water pH level is 1~ adjusted to 7.0 to 8.0 and then it progresses through a sump Is pump to an evaporator tank. The amount of rinse water is held 1~ to an absolute minimum in each subsystem. The contaminants in 17 the waste waters are primarily heavy metals which after cyanide 18 destruction to break the copper and brass complex, precipitate 1~ as metal hydrates. The waste water treatment 6ubsystem employs ~o a continuously operating sludge filter to remove these metal 21 hydrates along with silicates precipitated from spent cleaners 21 during neutraliza~ion. Sulfates are precipitated by the 23 addition of calculated amounts of lime. An evaporator tank is 24 maintained at a sufficiently high temperature to promote 2~ evaporation and is run continuously. The sludge is 26 accummulated as a dewatered cake and is oven dried to further reduce water content. This cake can then be accummulated and ;O roved to a Cla~s A landf'll at periodic intervals.
,~' ','' ' ,. ~ ;
~ ;2~3 l OBJE~TS OF THE INVENTIO~
4 It is therefore a principal object of the present invention to provide a plating system capable of nickel-chrome plating, 6 copper-brass plating and plate stripping without requiring ~ access to public sewers.
9 It is an additional object of the present invention to provide an apparatus for accomplishing the typical plating ll processes in which the quantity and content of rinse waters 12 used in the plating sequence are carefully controlled to 13 preclude a necessity for access to public sewers for disposing 14 of the waste waters.
1~
16 It is still an additional object of the present invention to 17 provide a novel electroplating facility and waste water 18 treatment combination which permits normal plating and 19 stripping operations in such a facility without generating 2~ waste rinse water which must be otherwise disposed o~ in a ~1 public sewage system~
~3 It is an additional object of the present invention to 2~ provide an apparatus for accomplishing typical metal plating 2~ processes in which the quantity and content of rinse waters in 26 the plating sequence are carefully controlled to preclude a 27 necessity for having access to public sewers for disposing of 28 the waste rinse waters used between the various steps in the 79 plating procedure.
3~
"
' ;;,; ~
It is still an additional object of the present invention to , provide a metal plating facility comprising subassemblies for 3 nickel-chrome plating, copper-brass plating and plate stripping 4 while at the same time recovering waste waters used for rinsing in the various subassemblies in a common waste water treatment 6 subassembly which permits treatment and disposal of waste water 7 effluents without requiring sewage disposal which might fall S outside of the disposal regulations of federal, state and local 9 agencies.
In a preferred embodiment the present invention is directed 11 to an improved electroplating system comprising: at least one 1. electroplating tank for plating parts; at least one water 13 rinse tank, said plated parts being transferred from said 1~ electroplating tank to said water rinse tank; means for pro-1~ viding a source of uncontaminated water positioned adjacent 1~ said rinse tank for (1) rinsing plated parts during a removal 1~ of said plated parts from said rinse tank and (2) inserting 1~ substantially uncontaminated water into said rinse tank for Ig reducing the contamination level of said rinse tank; means ~0 ~ox transferring overflow water from said rinse tank to a ,1 spray positioned above said plating tank for decreasing the contamination level of said rinse tank while removing dragout ~3 from said plated parts while they are being removed from said .~ plating tank; and an evaporator connected to said plating ~5 tank for receiving contaminated effluent from said plating ~6 tank for disposal of said plating tank effluent without ~7 cess to puùlic sewers.
.'",`~f' ~ ; ' t~
~ !
BPIEF DESCRIP~l!IOli OE Tlll: DP~WINGS
3 The aforementioned objects and advantages of the present ~ invention, as well as additional objects and advantages thereof, will be more full~ understood hereinafter as a result 6 of a detailed description of a preferred embodiment when taken 7 in conjunction with the following drawings:
9 FIG~ l is a block diagram representation of the nickel-chrome plating subassembly of the present invention;
ll 1~ FIG. ~ is a block diagram representation of the copper-brass 3 plating subassembly of the present invention;
1~ FIG. 3 is a block diagram representation of the strip line 1~ subassembly of the present invention;
1~
13 FIG. 4 is a block diagram representation of the waste water 19 treatment subassembly of the present invention; and 21 FIG. 5 is a block diagram representation of a typical ~ ckilow sequence utilized in the pre~ent invention.
\
3~
~2~ 3 l DETAILED DESCRIPTION OF A PREFERRED EMBODIMENT
~ Reference will first be made to FIG~ 1 which illustrates the 5 nickel-chrome pla~ing æubassembly of the pxesent invention.
6 Each separa~e rectangle represents a functional operation of 7 the nickel-chrome plating sequence used in the present i invention and also represents a tank which constitutes a g portion of the subassembly apparatus for accomplishing the lo method of ~he present invention. Metal parts to be plated are loaded on the left side of the subassembly and placed in the 12 first tank 12 which compri~es a soak cleaner for removing 13 caked-on dirt from the parts to be plated as well as such soils 14 as buffing compound~, stamping or cutting lubricants and the l~ like. The parts are subsequently placed in an electrocleaner l6 14 for further removal of organic materials. Generally l7 speaking, the purpose o~ the soak cleaning and electrocleaning l8 tanks 12 and 14 is to dislodge all foreign materials on the l9 parts to be electroplated.
~o ~l The next two tanks in the sequence of nickel-chrome 22 subassembly 10 are rinse and spray tanks 16 and 18. Upon the ~3 withdrawal of parts from each of the processing tanks, the ,~ parts to be plated are covered with a film of the processing solution, commonly referred to as dragout. This material is 26 invariably a contaminant to the following process tank and must 27 be removed by water rinsing before the parts enter the ~8 following process tank. ~hese rinses must be constantly ~9 overflowed with clean or cleaner water to prevent buildup in the levels of process tank constituents, otherwise 3l contamination of the following process tank will result. In 3~ order to make the rinsing efficiency high while reducing the :; . .
,.,~ '; ~,:
i~ . ,.,~ i ~52~3 l water requirements, each rinse tank is provided with a source 2 of air agitation to engure that the dragout film is diluted to 3 the maximum consis~ent with the rinse volume and the amount of 4 dragin. ~urthermore, overhead sprays are provided in some s cases and these sprays are active over the tank during 6 withdrawal o~ the part. This further dilutes the dragout film ~ and provides fresh water to prevent excessive buildup of 8 contaminants in ~he rinse wa~er. In the present invention the g amount of water used ~or rinses is greatly reduced by utilizing multiple rinses. By way of exxmple, it can be seen that in a series of three rinses, each rinse would be cleaner than the 12 rinse ahead of it~ This makes it feasible to backflow the 13 water for example, from a third rinse to a preceding second 14 rinse and in turn to a preceding first rinse, in a series of three rinse tanks As a result, the incoming water in each 16 tank is si~nificantly cleaner than the contaminant level in 17 that particular tank. To illustrate, in a rinse sequence which 18 would normally reguire 27 gallons of water an hour in a single 19 rinse to keep contaminants at an acceptable level, a double rinse would require only 9 gallons per hour and a triple rinse 21 would require only 3 gallons per hour.
2~
23 It can be understood from the above discussion that the so 24 called acontaminants" in the rinse waters are the necessary constituents of the previous process tank. It is therefore 26 feasible to return that water to the previous process tank, and 27 reducing the volume of rinse water by using multiple rinses is 28 one of the features of the present invention that renders it 2g possible to preclude the need for access to public sewers.
This multiple rinsing and backflow technique i~ utilized in the 31 nickel-chrome subassembly of FIG. l. More specifically, as 32 seen in FIG. l, the cleaner rinse water of tank 18 is ,i '"", ?, i ., . !
~ Z~%83 l back~lowed to the more contaminated rinse water of tank 16 2 which is in turn backflowed to the even more contaminated 3 solution of electrocleaner tank 14. ~n order to permit the 4 backflow process and ~till leave room in the process tank for these rinse waters, an evaporator is used at critical points in the process of each subassembly. For example, in the 7 subassembly of FIG. 1 an 80 gallon per hour evaporator unit 20 8 is connected to electrocleaner 14. Evaporator 20 comprises a ~ device for pumpiny the solution of electrocleaner tank 14 lo continuously through a chamber designed to provide maximum area 1l for the liquid. At the same time a blower provides maximum air l~ flow through the chamber and combined with the surface area of t3 the chamber, provides the level of evaporation required for J4 that particular processing tank. The back water flow from 1~ rinse tank 18 is replenished by rinse water from an overhead l6 hoist spray which remains active during withdrawal of the work.
l7 The hoist spray dilutes the dragout film and provides fresh l8 water to prevent excessive buildup of the contaminants in the l~ rinse water.
~0 ~l After the part to be plated is removed from electrocleaner 2~ 14, it is placed in rinse tank 16 and subsequen~ly in rinse ~3 tank 18. Thereafter it is placed in an acid dip tank 22. The ~ acld dip process, often called pickling, is designed to remove .~ metal oxides from the part. It also removes rust, scale and 26 other inorganic coatings that still adhere to the metal after 27 the soak and electrocleaning proce~es are completed. After ~8 the part is removed from the acid dip tank 22 it is transferred ~9 to the rinse and spray tank 24. Rinse and spray tank 24 is the only tank in the nickel-chrome æubassembly which produces waste 3l water in the form of an overflow which is transferred to the 3~ waste sump of the waste water treatment subassembly to be ` #~ J~ i l discussed hereinafter in conjunction with FIG. 4. The water in 2 rinse and spray tank 24 is replenished by the overhead rinse 3 water from the hoi~t spray above the tank which also keeps the 4 level of contaminants in rinse and spray tank 24 to a minimum.
s 6 Rinse and spray tank 24 completes the portion of the nickel-7 chrome subassembly 10 which is devoted to cleaning the part to 8 be plated. The part is next transferred to the nickel-plate 9 tank 26. The backflow process previously described in lo conjunction with rinse and spray tanks 16 and 18 and electrQcleaner tank 14 is again employed in the nickel plating 12 portion of the nickel-chrome subassembly. More specifically,13 as seen in FIG. 1, the nickel plating tank 26 is followed bythree water cleaning tanks, namely, rinse and spray tank 28, rinse and spray tank 30 and rinse tank 32. Rinse tank 32, l6 which has the lowest level of contaminants of the three rinse 17 tanks ollowing the nickel plate tank 26, has its water 18 constantly replenished by rinse water applied from the overhead Is hoist spray. The overflow from rinse tank 32 is backflowed ~o into rinse and spray tank 30 and the overflow from rinse and~l spray tank 30 is backflowed into rinse and spray tank 28.
~2 Finally, the overflow from rin~e and spray tank 28 is back-~3 10wed into the nickel plating tank 26 which is connected to an evaporator 34 which operates in the same manner as previously 2i described for evaporator 20. In this particular embodiment, 26 the evaporator 34 has a 60 gallon per hour capacity. The 27 number of rinses in each cycle varies as the tolerance for the 28 dragover to the following proce~s tank varies in each case.
29 The clean water added to each of the last rinses comes from a spray on the hoist which operates only on the withdrawal of the 3l parts from the last rinse. This relates the rinse water volume 32 directly to the number of parts being processed.
' ',''' /, , ' !
~2~ 33 When the nickel plating process i8 used as an undercoating ~ for chromium plating, the parts that are removed from rinse 3 tank 32 are thereaf~er placed in the chrome plating tank 36 which employs a two-stage rinsing process represented by rinse and spray tank 38 and rinse tank 40. The rinse water in rinse 6 tank 40 is replenished by the overhead hoist spray and the 7 overflow is channeled to the rinse and spray tank 38. The 8 overflow from rinse and spray tank 38 is channeled back to the ~ chrome plate tank 36 and the overflow ~rom chrome plate tank 36 is disposed of in evaporator 42 which in the particular ~I embodiment illustrated, has a 16 gallon per hour capacity.
1~
13 In the case of tubular or other hollow parts, the spray l~ rinses are effective only on the outside surfaces of the work.
l~ Therefore, it is preferable to double dip these parts in rinses l6 with sufficient time between these dips to allow complete l7 drainage. This ensures maximum possible dilution of the dragin l8 of the process solution which is carried by the parts. Return l~ of the dragout to each of the process tanks can result in the ~0 buildup of impurities in the process tanks. However, methods ~1 are available to control the level of these impurities in the ~2 process tanks. For example, organic impurities in the nickel ~3 plating tank are controlled b~ continuous activated carbon 2~ filtration and metallic impurities can be controlled by high pH
2~ filtration or by low current density electrolytic ~6 purifications. Similar steps are employed to control the level ~7 of impurities in the trivalent chrome solution of chrome .~ plating tank 36. The cleaning portion of subassembly 10 '9 accummulates soil6 which fall into two cla~se , solids which settle into the bottom of the tank and oils and greases which 3l float on the surface of the tank. Surface contaminan~s are 3~ removed by periodic skimming of the tank and solids are removed , ' . , : .
:.
~ 3 when the spent solution is removed to the sump tank for ~ disposal as hereina~ter described.
4 Reference will now be made to FIG. 2 which illustrates the , copper-brass subassembly of the present invention. Plating in 6 the copper-brass subassembly is typically limited to small 7 parts on an intermittent basis. Therefore the cost of ~ evaporating the brass tank and the copper tank and providing 9 separate rinse cycles is not generally justified. These rinses lo therefore are run continuously while work is in process. In Il order to minimize carry-over thereby keeping rinse water l~ requirements to a minimum, a hang-up bar is provided over each l3 plating tank and each rinse tank. This allows the parts to l~ drain thoroughly and reduces the carry-over into the following l~ tanks. Parts to be copper or brass plated or gold and silver 1~ plated are transferred to the copper-brass subassembly, l7 typically from the rinse and spray tank 24 of the nickel-chrome l~ subassembly. Thus, for example, a part which is to be copper 1~ plated either a an external plating layer or as an ~0 undercoating for other metal platingt is transferred to copper .1 plate tank 44. After the copper plating process has been completed, the part is transferred to the rinse tank 46 and en ~lnRe tank 48.
~8 3_ `,` '`; ~ ' -~ ~z~ 3 The backflow process for reducing contaminants is provided in ~ the copper-brass subassembly between rinse tank 48 and rinse 3 tank 46. After backflowinq through two rinses, the water ~ progresses through a separate tank 50 for destruction of the 5 cyanide content of the solution~ This chemical oxidation is 6 accomplished by controlled addition of sodium hypochlorite.
7 The overflow water is ~hen trans~erred to the was~e water 8 treatment subassembly through the inplant sump ~o be described 9 hereinafter in conjunction with FIG. 4. Brass plating may also lo be accomplished by means of brass plate tank 52, silver plating is accomplished in silver plate tank 54 and gold plating is accomplished in gold plate tank 56~ Because of the value of 3 the metal involved in the gold plating process, the gold plated parts are transferred first to a gold rinse tank 58 from which l~ dissolved gold can be recovered prior to transferring the parts l6 to rinse tank 46 and rinse tank 48 as previously described. An l7 air-water spray wand is used over the second rinse tank.
l8 19 The strip line subassembly of the present invention is shown in FIG. 3. The tanks in this line are used intermittently for ~1 stripping plated metal from rejects or from worn parts that are 22 to be replated. Therefore, it iB not usually economically ~3 feasible to provide evaporators or multiple rinses for each 24 tank in this subassembly. Accordingly, hang-up bars are 2~ provided over each tank and each rinse tank to ensure good 26 drainage of the parts. A wand consisting of a water spra~ with ~7 air atomization is provided for rinsing with clean water over 28 the rinse tank. The methods for stripping previously plated 29 parts for replating vary with the metal to be stripped. Some methods involve purely chemical reactions and some involve 31 making the part anodic in a proce~ that i8 substantially the 32 reverse of the electroplating process. Thus, strip line ~ 83 l subassembly 60 of FIG. 3 is provided with a muriatic strip tank 2 62, a pair of reverse sulfuric strip ~anks 64 and 66 and a 3 reverse caustic strip tank 68. In addition, three rinse tanks are provided including rinse tank 70, rinse tank 72 and rinse tank 74. Rinse tank 70 is used primarily for rinsing the part 6 after muriatic strip treatment and rinse tanks 72 and 74 are 7 employed to rinse the part after reverse treatment in either reverse sulfuric strip tanks 64 and 66 or reverse caustic tank ~ 68. Rinse tank 72 and 74 employ the previously described lo backflow process similar to that employed in nickel-chrome subassembly 10 of FIG. 1. Each rinse tank is connected to 1~ appropriate plumbing for channeling the waste water to the 13 inplant waste sump of the waste water treatment subassembly of 1~ FIG. 4 which will now be described.
1~
18 Waste water treatment subassembly 80 comprises an inplant 17 sump 82, a neutralization sump 84 and a waste water evaporation 18 tank 86 to which is connected a sludge filter 88 and an 19 evaporator 89 and a spent cleaner dump 90. All o~ the various ~o rinses described in conjunction with the subassemblies of ~1 FIGs. 1, 2 and 3 are overflowed through the inplant sump 82 and 22 neutralization sump 84 to water evaporation tank 86. Inplant 23 sump 82 collects the waste water from all of the subassemblies ~ and pumps it to the neutralization sump 84. ~eutralization 2~ sump 84 adjusts the pH level of the waste water so that it is 26 within the range of 7.0 to 7.5. Then a pump transfers the 27 neutralized waste water to waste water evaporation tank 86.
28 The amount of rinse water i8 held to an absolute minimum by the ~9 methods described above in conjunction with FIGs. 1, 2 and 3.
The contaminants in these waters will typically be primarily 31 heavy metals while the output of cyanide destruction tank 50 of 3~ subassembly 43 of FIG. 2, which breaks the copper and brass ~ !
2 ~3 l complex, precipitates contaminants as metal hydrates. Spent 2 cleaner dump 90 is u~ilized to collect ~he spent cleaners 3 during neutralization. A continuously operational sludge 4 filter 88 removes the heavy metals, metal hydrates along with silicates precipitated from spent cleaners during 6 neutralization. Sulfates are precipitated by the addition of 7 calculated amounts of lime. Evaporation tank 86 is maintained at a temperature of 160 degrees Fahrenheit with evaporator 89 running continuously at a capacity in the preferred embodiment o hereof of 80 gallons per hour. Sludge is accu~mulated as a dewatered cake and is oven dried to further reduce water l content. This cake is accummulated and removed to a Class A
13 landfill at periodic interval~.
1~
FIG. 5 represents in generalized form, one of the features of l6 the present invention. More specifically, FIG. 5 illustrates a l7 typical backflow sequence which enables the electroplating 8 system of the present invention to operate without the need for s access to public sewers. As shown in FIG. 5, there is ~o typically a tank devoted to the plating operation followed by a .1 plurality of tanks devoted to rinsing operations. Thus, shown 22 in FIG. 5 is a plating tank 100, a first rinse tank 102 and a ~3 second rinse tank 104. Second rinse tank 104 receives fresh 24 water replenishment from a suitable source such as an overhead 2~ spray line 106 as shown in FIG. 5. The water from second rinse 26 tank 104 is backflowed to first rinse tank 102, the water in 27 which is backflowed into the plating tank 100. The overflow 28 from plating tank 100 is pumped into an evaporator 108 which is 29 designed to provide a minimum required level of evaporation of the overflow water from the plating tank as a means for 31 disposal thereof. Except for the second rinse tank 104 which 32 receives a pure water hois~ spray from source 106, ~he backflow '''' ' .` .', :
;' - , .
~ ~2~83 1 to the two preceding tanks 102 and 100 i8 typically provided in 2 the form of an overhead spray of aerated water from a 3 stationary tank source that is less contaminated than the water 4 contained within the tank over which the spray is situated as shown in FIG. 5. In this manner, the part and the accompanying 6 dragout adhering to each part as it is removed from a tank, are 7 subjected to a spray rinse of water which is purer than the 8 water in which the part has been sitting while residing in the g tank.
ll It will now be understood that what has been disclosed herein 12 comprises a novel and highly advantageous electroplating system 13 which does not require access to public sewage systems for 1~ disposal of waste water. Two unique features of this system l~ make it possible to process metal parts for electroplating 16 through the present invention without that requirement. More 1~ specifically, one such feature involves the care~ul control and 18 high efficiency use of input water by use of overhead sprays, 19 backflows and evaporator units. The other such feature is employed in the form of a water water treatment subassembly 21 wherein waste water for whicb it would not be economically 22 feasible to provide an evaporator to dispose thereof with 23 respect to each individual source in the plating process, is 2~ directed to an inplant sump, a neutralization sump and as eventually to a unitary waste water evaporation tank which 26 utilizes its own evaporator unit for disposing of the common 27 nte water.
~LZ~35~83 Those having skill in the art to which the present invention ~ pertains will now perceive of various modifications and 3 additions which can be made to the invention. By way of 4 examplet the general features disclosed herein may be used advantageously in other forms of elec~roplating assemblies for 6 plating metals other than those specifically shown as examples 7 herein. However, it will be understood that all such modifications and additions are deemed to be within ~he scope ~ of the present invention which is to be limited only by the lo claims appended hereto.
Il ¦ We claim:
.~
j,i _ ~ ' ,"~ .
;' ` ''','1' '' '
~o ~l The next two tanks in the sequence of nickel-chrome 22 subassembly 10 are rinse and spray tanks 16 and 18. Upon the ~3 withdrawal of parts from each of the processing tanks, the ,~ parts to be plated are covered with a film of the processing solution, commonly referred to as dragout. This material is 26 invariably a contaminant to the following process tank and must 27 be removed by water rinsing before the parts enter the ~8 following process tank. ~hese rinses must be constantly ~9 overflowed with clean or cleaner water to prevent buildup in the levels of process tank constituents, otherwise 3l contamination of the following process tank will result. In 3~ order to make the rinsing efficiency high while reducing the :; . .
,.,~ '; ~,:
i~ . ,.,~ i ~52~3 l water requirements, each rinse tank is provided with a source 2 of air agitation to engure that the dragout film is diluted to 3 the maximum consis~ent with the rinse volume and the amount of 4 dragin. ~urthermore, overhead sprays are provided in some s cases and these sprays are active over the tank during 6 withdrawal o~ the part. This further dilutes the dragout film ~ and provides fresh water to prevent excessive buildup of 8 contaminants in ~he rinse wa~er. In the present invention the g amount of water used ~or rinses is greatly reduced by utilizing multiple rinses. By way of exxmple, it can be seen that in a series of three rinses, each rinse would be cleaner than the 12 rinse ahead of it~ This makes it feasible to backflow the 13 water for example, from a third rinse to a preceding second 14 rinse and in turn to a preceding first rinse, in a series of three rinse tanks As a result, the incoming water in each 16 tank is si~nificantly cleaner than the contaminant level in 17 that particular tank. To illustrate, in a rinse sequence which 18 would normally reguire 27 gallons of water an hour in a single 19 rinse to keep contaminants at an acceptable level, a double rinse would require only 9 gallons per hour and a triple rinse 21 would require only 3 gallons per hour.
2~
23 It can be understood from the above discussion that the so 24 called acontaminants" in the rinse waters are the necessary constituents of the previous process tank. It is therefore 26 feasible to return that water to the previous process tank, and 27 reducing the volume of rinse water by using multiple rinses is 28 one of the features of the present invention that renders it 2g possible to preclude the need for access to public sewers.
This multiple rinsing and backflow technique i~ utilized in the 31 nickel-chrome subassembly of FIG. l. More specifically, as 32 seen in FIG. l, the cleaner rinse water of tank 18 is ,i '"", ?, i ., . !
~ Z~%83 l back~lowed to the more contaminated rinse water of tank 16 2 which is in turn backflowed to the even more contaminated 3 solution of electrocleaner tank 14. ~n order to permit the 4 backflow process and ~till leave room in the process tank for these rinse waters, an evaporator is used at critical points in the process of each subassembly. For example, in the 7 subassembly of FIG. 1 an 80 gallon per hour evaporator unit 20 8 is connected to electrocleaner 14. Evaporator 20 comprises a ~ device for pumpiny the solution of electrocleaner tank 14 lo continuously through a chamber designed to provide maximum area 1l for the liquid. At the same time a blower provides maximum air l~ flow through the chamber and combined with the surface area of t3 the chamber, provides the level of evaporation required for J4 that particular processing tank. The back water flow from 1~ rinse tank 18 is replenished by rinse water from an overhead l6 hoist spray which remains active during withdrawal of the work.
l7 The hoist spray dilutes the dragout film and provides fresh l8 water to prevent excessive buildup of the contaminants in the l~ rinse water.
~0 ~l After the part to be plated is removed from electrocleaner 2~ 14, it is placed in rinse tank 16 and subsequen~ly in rinse ~3 tank 18. Thereafter it is placed in an acid dip tank 22. The ~ acld dip process, often called pickling, is designed to remove .~ metal oxides from the part. It also removes rust, scale and 26 other inorganic coatings that still adhere to the metal after 27 the soak and electrocleaning proce~es are completed. After ~8 the part is removed from the acid dip tank 22 it is transferred ~9 to the rinse and spray tank 24. Rinse and spray tank 24 is the only tank in the nickel-chrome æubassembly which produces waste 3l water in the form of an overflow which is transferred to the 3~ waste sump of the waste water treatment subassembly to be ` #~ J~ i l discussed hereinafter in conjunction with FIG. 4. The water in 2 rinse and spray tank 24 is replenished by the overhead rinse 3 water from the hoi~t spray above the tank which also keeps the 4 level of contaminants in rinse and spray tank 24 to a minimum.
s 6 Rinse and spray tank 24 completes the portion of the nickel-7 chrome subassembly 10 which is devoted to cleaning the part to 8 be plated. The part is next transferred to the nickel-plate 9 tank 26. The backflow process previously described in lo conjunction with rinse and spray tanks 16 and 18 and electrQcleaner tank 14 is again employed in the nickel plating 12 portion of the nickel-chrome subassembly. More specifically,13 as seen in FIG. 1, the nickel plating tank 26 is followed bythree water cleaning tanks, namely, rinse and spray tank 28, rinse and spray tank 30 and rinse tank 32. Rinse tank 32, l6 which has the lowest level of contaminants of the three rinse 17 tanks ollowing the nickel plate tank 26, has its water 18 constantly replenished by rinse water applied from the overhead Is hoist spray. The overflow from rinse tank 32 is backflowed ~o into rinse and spray tank 30 and the overflow from rinse and~l spray tank 30 is backflowed into rinse and spray tank 28.
~2 Finally, the overflow from rin~e and spray tank 28 is back-~3 10wed into the nickel plating tank 26 which is connected to an evaporator 34 which operates in the same manner as previously 2i described for evaporator 20. In this particular embodiment, 26 the evaporator 34 has a 60 gallon per hour capacity. The 27 number of rinses in each cycle varies as the tolerance for the 28 dragover to the following proce~s tank varies in each case.
29 The clean water added to each of the last rinses comes from a spray on the hoist which operates only on the withdrawal of the 3l parts from the last rinse. This relates the rinse water volume 32 directly to the number of parts being processed.
' ',''' /, , ' !
~2~ 33 When the nickel plating process i8 used as an undercoating ~ for chromium plating, the parts that are removed from rinse 3 tank 32 are thereaf~er placed in the chrome plating tank 36 which employs a two-stage rinsing process represented by rinse and spray tank 38 and rinse tank 40. The rinse water in rinse 6 tank 40 is replenished by the overhead hoist spray and the 7 overflow is channeled to the rinse and spray tank 38. The 8 overflow from rinse and spray tank 38 is channeled back to the ~ chrome plate tank 36 and the overflow ~rom chrome plate tank 36 is disposed of in evaporator 42 which in the particular ~I embodiment illustrated, has a 16 gallon per hour capacity.
1~
13 In the case of tubular or other hollow parts, the spray l~ rinses are effective only on the outside surfaces of the work.
l~ Therefore, it is preferable to double dip these parts in rinses l6 with sufficient time between these dips to allow complete l7 drainage. This ensures maximum possible dilution of the dragin l8 of the process solution which is carried by the parts. Return l~ of the dragout to each of the process tanks can result in the ~0 buildup of impurities in the process tanks. However, methods ~1 are available to control the level of these impurities in the ~2 process tanks. For example, organic impurities in the nickel ~3 plating tank are controlled b~ continuous activated carbon 2~ filtration and metallic impurities can be controlled by high pH
2~ filtration or by low current density electrolytic ~6 purifications. Similar steps are employed to control the level ~7 of impurities in the trivalent chrome solution of chrome .~ plating tank 36. The cleaning portion of subassembly 10 '9 accummulates soil6 which fall into two cla~se , solids which settle into the bottom of the tank and oils and greases which 3l float on the surface of the tank. Surface contaminan~s are 3~ removed by periodic skimming of the tank and solids are removed , ' . , : .
:.
~ 3 when the spent solution is removed to the sump tank for ~ disposal as hereina~ter described.
4 Reference will now be made to FIG. 2 which illustrates the , copper-brass subassembly of the present invention. Plating in 6 the copper-brass subassembly is typically limited to small 7 parts on an intermittent basis. Therefore the cost of ~ evaporating the brass tank and the copper tank and providing 9 separate rinse cycles is not generally justified. These rinses lo therefore are run continuously while work is in process. In Il order to minimize carry-over thereby keeping rinse water l~ requirements to a minimum, a hang-up bar is provided over each l3 plating tank and each rinse tank. This allows the parts to l~ drain thoroughly and reduces the carry-over into the following l~ tanks. Parts to be copper or brass plated or gold and silver 1~ plated are transferred to the copper-brass subassembly, l7 typically from the rinse and spray tank 24 of the nickel-chrome l~ subassembly. Thus, for example, a part which is to be copper 1~ plated either a an external plating layer or as an ~0 undercoating for other metal platingt is transferred to copper .1 plate tank 44. After the copper plating process has been completed, the part is transferred to the rinse tank 46 and en ~lnRe tank 48.
~8 3_ `,` '`; ~ ' -~ ~z~ 3 The backflow process for reducing contaminants is provided in ~ the copper-brass subassembly between rinse tank 48 and rinse 3 tank 46. After backflowinq through two rinses, the water ~ progresses through a separate tank 50 for destruction of the 5 cyanide content of the solution~ This chemical oxidation is 6 accomplished by controlled addition of sodium hypochlorite.
7 The overflow water is ~hen trans~erred to the was~e water 8 treatment subassembly through the inplant sump ~o be described 9 hereinafter in conjunction with FIG. 4. Brass plating may also lo be accomplished by means of brass plate tank 52, silver plating is accomplished in silver plate tank 54 and gold plating is accomplished in gold plate tank 56~ Because of the value of 3 the metal involved in the gold plating process, the gold plated parts are transferred first to a gold rinse tank 58 from which l~ dissolved gold can be recovered prior to transferring the parts l6 to rinse tank 46 and rinse tank 48 as previously described. An l7 air-water spray wand is used over the second rinse tank.
l8 19 The strip line subassembly of the present invention is shown in FIG. 3. The tanks in this line are used intermittently for ~1 stripping plated metal from rejects or from worn parts that are 22 to be replated. Therefore, it iB not usually economically ~3 feasible to provide evaporators or multiple rinses for each 24 tank in this subassembly. Accordingly, hang-up bars are 2~ provided over each tank and each rinse tank to ensure good 26 drainage of the parts. A wand consisting of a water spra~ with ~7 air atomization is provided for rinsing with clean water over 28 the rinse tank. The methods for stripping previously plated 29 parts for replating vary with the metal to be stripped. Some methods involve purely chemical reactions and some involve 31 making the part anodic in a proce~ that i8 substantially the 32 reverse of the electroplating process. Thus, strip line ~ 83 l subassembly 60 of FIG. 3 is provided with a muriatic strip tank 2 62, a pair of reverse sulfuric strip ~anks 64 and 66 and a 3 reverse caustic strip tank 68. In addition, three rinse tanks are provided including rinse tank 70, rinse tank 72 and rinse tank 74. Rinse tank 70 is used primarily for rinsing the part 6 after muriatic strip treatment and rinse tanks 72 and 74 are 7 employed to rinse the part after reverse treatment in either reverse sulfuric strip tanks 64 and 66 or reverse caustic tank ~ 68. Rinse tank 72 and 74 employ the previously described lo backflow process similar to that employed in nickel-chrome subassembly 10 of FIG. 1. Each rinse tank is connected to 1~ appropriate plumbing for channeling the waste water to the 13 inplant waste sump of the waste water treatment subassembly of 1~ FIG. 4 which will now be described.
1~
18 Waste water treatment subassembly 80 comprises an inplant 17 sump 82, a neutralization sump 84 and a waste water evaporation 18 tank 86 to which is connected a sludge filter 88 and an 19 evaporator 89 and a spent cleaner dump 90. All o~ the various ~o rinses described in conjunction with the subassemblies of ~1 FIGs. 1, 2 and 3 are overflowed through the inplant sump 82 and 22 neutralization sump 84 to water evaporation tank 86. Inplant 23 sump 82 collects the waste water from all of the subassemblies ~ and pumps it to the neutralization sump 84. ~eutralization 2~ sump 84 adjusts the pH level of the waste water so that it is 26 within the range of 7.0 to 7.5. Then a pump transfers the 27 neutralized waste water to waste water evaporation tank 86.
28 The amount of rinse water i8 held to an absolute minimum by the ~9 methods described above in conjunction with FIGs. 1, 2 and 3.
The contaminants in these waters will typically be primarily 31 heavy metals while the output of cyanide destruction tank 50 of 3~ subassembly 43 of FIG. 2, which breaks the copper and brass ~ !
2 ~3 l complex, precipitates contaminants as metal hydrates. Spent 2 cleaner dump 90 is u~ilized to collect ~he spent cleaners 3 during neutralization. A continuously operational sludge 4 filter 88 removes the heavy metals, metal hydrates along with silicates precipitated from spent cleaners during 6 neutralization. Sulfates are precipitated by the addition of 7 calculated amounts of lime. Evaporation tank 86 is maintained at a temperature of 160 degrees Fahrenheit with evaporator 89 running continuously at a capacity in the preferred embodiment o hereof of 80 gallons per hour. Sludge is accu~mulated as a dewatered cake and is oven dried to further reduce water l content. This cake is accummulated and removed to a Class A
13 landfill at periodic interval~.
1~
FIG. 5 represents in generalized form, one of the features of l6 the present invention. More specifically, FIG. 5 illustrates a l7 typical backflow sequence which enables the electroplating 8 system of the present invention to operate without the need for s access to public sewers. As shown in FIG. 5, there is ~o typically a tank devoted to the plating operation followed by a .1 plurality of tanks devoted to rinsing operations. Thus, shown 22 in FIG. 5 is a plating tank 100, a first rinse tank 102 and a ~3 second rinse tank 104. Second rinse tank 104 receives fresh 24 water replenishment from a suitable source such as an overhead 2~ spray line 106 as shown in FIG. 5. The water from second rinse 26 tank 104 is backflowed to first rinse tank 102, the water in 27 which is backflowed into the plating tank 100. The overflow 28 from plating tank 100 is pumped into an evaporator 108 which is 29 designed to provide a minimum required level of evaporation of the overflow water from the plating tank as a means for 31 disposal thereof. Except for the second rinse tank 104 which 32 receives a pure water hois~ spray from source 106, ~he backflow '''' ' .` .', :
;' - , .
~ ~2~83 1 to the two preceding tanks 102 and 100 i8 typically provided in 2 the form of an overhead spray of aerated water from a 3 stationary tank source that is less contaminated than the water 4 contained within the tank over which the spray is situated as shown in FIG. 5. In this manner, the part and the accompanying 6 dragout adhering to each part as it is removed from a tank, are 7 subjected to a spray rinse of water which is purer than the 8 water in which the part has been sitting while residing in the g tank.
ll It will now be understood that what has been disclosed herein 12 comprises a novel and highly advantageous electroplating system 13 which does not require access to public sewage systems for 1~ disposal of waste water. Two unique features of this system l~ make it possible to process metal parts for electroplating 16 through the present invention without that requirement. More 1~ specifically, one such feature involves the care~ul control and 18 high efficiency use of input water by use of overhead sprays, 19 backflows and evaporator units. The other such feature is employed in the form of a water water treatment subassembly 21 wherein waste water for whicb it would not be economically 22 feasible to provide an evaporator to dispose thereof with 23 respect to each individual source in the plating process, is 2~ directed to an inplant sump, a neutralization sump and as eventually to a unitary waste water evaporation tank which 26 utilizes its own evaporator unit for disposing of the common 27 nte water.
~LZ~35~83 Those having skill in the art to which the present invention ~ pertains will now perceive of various modifications and 3 additions which can be made to the invention. By way of 4 examplet the general features disclosed herein may be used advantageously in other forms of elec~roplating assemblies for 6 plating metals other than those specifically shown as examples 7 herein. However, it will be understood that all such modifications and additions are deemed to be within ~he scope ~ of the present invention which is to be limited only by the lo claims appended hereto.
Il ¦ We claim:
.~
j,i _ ~ ' ,"~ .
;' ` ''','1' '' '
Claims (5)
1. An improved electroplating system comprising:
at least one electroplating tank for plating parts;
at least one water rinse tank;
means for transferring said plated parts from said electroplating tank to said water rinse tank;
means for providing a source of uncontaminated water positioned adjacent said rinse tank for (1) rinsing plated parts during a removal of said plated parts from said rinse tank and (2) inserting substantially uncontaminated water into said rinse tank for reducing the contamination level of said rinse tank;
means for transferring overflow water from said rinse tank to a spray positioned above said plating tank for decreasing the contamination level of said rinse tank while removing dragout from said plated parts while they are being removed from said plating tank; and an evaporator connected to said plating tank for receiving contaminated effluent from said plating tank for disposal of said plating tank effluent without resorting to public sewers.
at least one electroplating tank for plating parts;
at least one water rinse tank;
means for transferring said plated parts from said electroplating tank to said water rinse tank;
means for providing a source of uncontaminated water positioned adjacent said rinse tank for (1) rinsing plated parts during a removal of said plated parts from said rinse tank and (2) inserting substantially uncontaminated water into said rinse tank for reducing the contamination level of said rinse tank;
means for transferring overflow water from said rinse tank to a spray positioned above said plating tank for decreasing the contamination level of said rinse tank while removing dragout from said plated parts while they are being removed from said plating tank; and an evaporator connected to said plating tank for receiving contaminated effluent from said plating tank for disposal of said plating tank effluent without resorting to public sewers.
2. An improved electroplating system of the type having a plurality of plating subsystems, each such subsystem being adapted for plating metal parts with at least one plating material, the improvement comprising:
a waste water treatment subassembly connected to each of said plating subsystems for receiving contaminated waste water therefrom, said subassembly having an evaporator for evaporating said waste water and at least one solid waste filter for removing solid wastes from said waste water, said plating subsystems including at least one plating tank, at least one rinse tank, means for providing a source of uncontaminated water for rinsing said metal parts when said metal parts are being withdrawn from said rinse tank of at least one of said plating subsystems and means for transferring overflow water from said rinse tank to a spray positioned above said plating tank for removing dragout from said metal parts and reducing the contamination level of said rinse tank, whereby no access to public sewers is needed for waste disposal.
a waste water treatment subassembly connected to each of said plating subsystems for receiving contaminated waste water therefrom, said subassembly having an evaporator for evaporating said waste water and at least one solid waste filter for removing solid wastes from said waste water, said plating subsystems including at least one plating tank, at least one rinse tank, means for providing a source of uncontaminated water for rinsing said metal parts when said metal parts are being withdrawn from said rinse tank of at least one of said plating subsystems and means for transferring overflow water from said rinse tank to a spray positioned above said plating tank for removing dragout from said metal parts and reducing the contamination level of said rinse tank, whereby no access to public sewers is needed for waste disposal.
3. The improvement recited in claim 2 further comprising:
means for neutralizing said waste water to a pH level in the range of 7.0 to 7.5 before said waste water is applied to said evaporator.
means for neutralizing said waste water to a pH level in the range of 7.0 to 7.5 before said waste water is applied to said evaporator.
4. The improvement recited in claim 2 further comprising:
means for heating said solid waste for accumulating a solid cake thereof.
means for heating said solid waste for accumulating a solid cake thereof.
5. An improved method for electroplating, the method comprising the following steps:
a) providing at least one electroplating tank for plating parts;
b) immersing said parts in said tank for electroplating;
c) providing at least one water rinse tank in the vicinity of said electroplating tank;
d) transferring plated parts from said electroplating tank to said rinse tank;
e) providing a source of uncontaminated water positioned adjacent said rinse tank;
f) rinsing said plated parts while removing said plated parts from said rinse tank;
g) inserting substantially uncontaminated water into said rinse tank for reducing the contamination level of said rinse tank;
h) transferring overflow water from said rinse tank to a spray above said electroplating tank for decreasing the contamination level of said rinse tank while removing dragout from said plated parts;
i) providing an evaporator in fluid communication with said electroplating tank; and j) transferring contaminated effluent from said electroplating tank to said evaporator for disposal of said electroplating tank effluent without access to public sewers.
a) providing at least one electroplating tank for plating parts;
b) immersing said parts in said tank for electroplating;
c) providing at least one water rinse tank in the vicinity of said electroplating tank;
d) transferring plated parts from said electroplating tank to said rinse tank;
e) providing a source of uncontaminated water positioned adjacent said rinse tank;
f) rinsing said plated parts while removing said plated parts from said rinse tank;
g) inserting substantially uncontaminated water into said rinse tank for reducing the contamination level of said rinse tank;
h) transferring overflow water from said rinse tank to a spray above said electroplating tank for decreasing the contamination level of said rinse tank while removing dragout from said plated parts;
i) providing an evaporator in fluid communication with said electroplating tank; and j) transferring contaminated effluent from said electroplating tank to said evaporator for disposal of said electroplating tank effluent without access to public sewers.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US78647285A | 1985-10-11 | 1985-10-11 | |
US786,472 | 1985-10-11 |
Publications (1)
Publication Number | Publication Date |
---|---|
CA1295283C true CA1295283C (en) | 1992-02-04 |
Family
ID=25138695
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA000499261A Expired - Lifetime CA1295283C (en) | 1985-10-11 | 1986-01-09 | Electroplating system with rinse tank and evaporator for contaminated effluent |
Country Status (4)
Country | Link |
---|---|
JP (1) | JPS6293400A (en) |
CA (1) | CA1295283C (en) |
DE (1) | DE3634634A1 (en) |
GB (1) | GB2182058B (en) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1062933A (en) * | 1990-12-26 | 1992-07-22 | 胡德忠 | Micro-discharge technology and equipment for rinsing water in industrial production |
Family Cites Families (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2984081A (en) * | 1958-03-17 | 1961-05-16 | Lyon Inc | Cooling of chromium plating solution |
US3616437A (en) * | 1966-10-18 | 1971-10-26 | Aisaburo Yagishita | Plating apparatus with recovery of plating chemicals from rinse waters |
US3658470A (en) * | 1969-06-16 | 1972-04-25 | Industrial Filter Pump Mfg Co | Metal ion recovery system |
US3637467A (en) * | 1970-05-07 | 1972-01-25 | Osmonics Inc | Metal reclamation process and apparatus |
US3661732A (en) * | 1970-06-01 | 1972-05-09 | Production Machinery Corp | Method and apparatus for electroplating |
JPS4927016A (en) * | 1972-07-10 | 1974-03-11 | ||
JPS5536078B2 (en) * | 1974-03-08 | 1980-09-18 | ||
JPS539237A (en) * | 1976-07-13 | 1978-01-27 | Ebara Udylite Kk | Treatment method of metal surface treating solution and water for washing said solution |
NL7805266A (en) * | 1977-05-23 | 1978-11-27 | Uss Eng & Consult | METHOD AND DEVICE FOR GALVANIC TINER. |
DE2729270B2 (en) * | 1977-06-29 | 1980-06-12 | Stolle, Hans, Ing.(Grad.), 7129 Brackenheim | Method for recovering carried-over electrolyte |
FR2421849A1 (en) * | 1978-04-05 | 1979-11-02 | Wajc Samuel | INTEGRATED PROCESS FOR THE TREATMENT OF RESIDUAL WATER FROM ANODIZATION WORKSHOPS AND INSTALLATION USED FOR THIS PROCESS |
JPS56108884A (en) * | 1980-01-31 | 1981-08-28 | Tanaka Kikinzoku Kogyo Kk | Washing method with water |
JPS57152478A (en) * | 1981-03-14 | 1982-09-20 | Kubota Ltd | Treatment for washing water in metallic surface treatment |
JPS5932599U (en) * | 1982-08-26 | 1984-02-29 | 三井造船株式会社 | launcher lifeboat |
-
1986
- 1986-01-09 CA CA000499261A patent/CA1295283C/en not_active Expired - Lifetime
- 1986-02-21 JP JP61038133A patent/JPS6293400A/en active Pending
- 1986-10-10 DE DE19863634634 patent/DE3634634A1/en not_active Ceased
- 1986-10-13 GB GB8624491A patent/GB2182058B/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
JPS6293400A (en) | 1987-04-28 |
GB2182058B (en) | 1990-02-21 |
DE3634634A1 (en) | 1987-04-16 |
GB8624491D0 (en) | 1986-11-19 |
GB2182058A (en) | 1987-05-07 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US4781806A (en) | Electroplating system | |
US3973987A (en) | Water recycle treatment system for use in metal processing | |
US5207917A (en) | Recycling and recovery of aqueous cleaner solutions | |
US4157942A (en) | Method for recovery of metals from metal plating baths and neutralizing toxic effluents therefrom | |
CN105776670A (en) | Wastewater split-flow separation and quality-based treatment utilization process method | |
JPH05195298A (en) | Method and system for recovering metal from electroplating waste | |
Janson et al. | Treatment of heavy metals in wastewaters. What wastewater‐treatment method is most cost‐effective for electroplating and finishing operations? Here are the alternatives | |
US4171255A (en) | Apparatus for recovery of metals from metal plating baths and neutralizing toxic effluents therefrom | |
US4952290A (en) | Waste water treatment and recovery system | |
EP0507006B1 (en) | Method of treating salt bath liquid | |
CA1295283C (en) | Electroplating system with rinse tank and evaporator for contaminated effluent | |
US4812240A (en) | Process for treating waste water contaminated with manganese | |
US5076885A (en) | Process for etching workpieces | |
Chang et al. | Alternative waste minimization analyses for the printed circuit board industry: Examples for small and large manufacturers | |
JPH10151466A (en) | Waste water purifying method and washing waste water treatment apparatus | |
JPH10273793A (en) | Method for removing harmful heavy metal from liquid absorbent containing harmful heavy metal | |
JP3558392B2 (en) | Electrodeposition wastewater recycling system | |
Ciancia | Pollution abatement in the metal finishing industry | |
US2725314A (en) | In line treatment of toxic carry-over of work pieces | |
DE3822953A1 (en) | Process for regenerating an iron- and/or zinc-containing hydrochloric acid bath | |
CN1149086A (en) | Process for regeneration of electrolytes, in particular of Na2SO4 from waste pickles for stainless steel, in particular, stainless steel strips | |
KR960013927B1 (en) | Apparatus and system for treating skimmed liquids using a ultrafilter and a separator for water and fats | |
KR100366726B1 (en) | Continuous Type Wastewater treatement Plant using Electrolysis | |
KR940006939Y1 (en) | Apparatus for treatment of waste water in gilding process of semiconductor factory | |
RU2143503C1 (en) | Production line for galvanochemical treatment of parts |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
MKLA | Lapsed |