CA1271634A

CA1271634A - Low inlet gas velocity high throughput biomass gasifier

Info

Publication number: CA1271634A
Application number: CA000518454A
Authority: CA
Inventors: Herman F. Feldmann; Mark A. Paisley
Original assignee: Battelle Development Corp
Current assignee: Future Energy Resources Corp
Priority date: 1985-09-20
Filing date: 1986-09-18
Publication date: 1990-07-17
Also published as: EP0239589B1; JPH0794669B2; AU591714B2; DE3670507D1; EP0239589A1; WO1987001719A1; JPS63501511A; AU6400286A

Abstract

LOW INLET GAS VELOCITY HIGH THROUGHPUT BIOMASS GASIFIER

Abstract The present invention discloses a novel method of operating a gasifier for production of fuel gas from carbonaceous fuels. The process disclosed enables op-erating in an entrained mode using inlet gas velocities of less than 7 feet per second and extraordinary feedstock throughputs exceeding 4000 lbs/ft2-hr.

Description

7~L~34 LOW INLET GAS VELOCITY HIGH TIIROUGHPUT BIOMASS GASIFIER

Background of Invention This invention relates to gasifiers for en-trained bed combustors particularly as applied to biomass 05 gasification for the production of a medium Btu grade fuel gas from a variety of biomass forms including shredded bark, wood chips, sawdust, sludges and other carbonaceous fuels or feedstocks.
The process system according to this invention relates to production of gas by use of a high throughput gasifier employing hot sand circulation for process heat.
As is known in the art, the exothermic combustion reactions càn be separated from the endothermic gasification reac-tion~. The exothermic combustion reactions can take place in or near the combustor while the endothermic gasifi-cation reactions take place in the gasifier. This separ-ation of endothermic and exothermic processes results in a high energy density product gas without the nitrogen dilution present in conventional air blown gasification systems.
The present invention relates to a novel method of operating a gasifier preferably for a parallel en-trained bed pyrolysis unit, i.e., a system comprising an endothermic reaction zone distinct from the exothermic reaction zone of the combustor wherein the heat from the exothermic zone is transferred to the endothermic reaction zone by circulation of an inert particulate solid such as sand. To be able to operate a gasifier in an entrained mode while using only low inlet gas velocities and at very high fuel feed rates would be an advance in the art and of commercial significance. The process disclosed by the present invention enables operating at inlet ~elocities -typical of fluidized beds but operating in an entrained f 7~

mode and with extraordinary throughputs with fuel feed rates for above those contemplated as possible based on existing art.
The novelty and unexpectedness of the present 05 invention can be readily ascertained by an examination of existing fluidization design equations and published lit-erature information on the rates of biomass conversion to gas, particularly as regards the prediction of the design of a conceptual biomass gasifier operating at the con-10 ditions taught by the present invention.
Incorporated herein by specific reference isChan, R. and Rrieger, B. B., "Modeling of Physical and Chemical Processes During Pyrolysis of a Large Biomass Pellet with Experimental Verificationn, American Chemical 15 Society, Division of Fuel Chemi9try Preprints Volu~e 28, No. 5, August 1983, pp. 330-337 and in particulax figures

2 and 3 set forth therein.
The data on the rate of conversion of biomass to gas published by Chan and Rrieger is used to estimate the 20 residence time required to convert a substantial fraction of biomass to gas. The gas generation rate depends on the time the particle is exposed to approximately the same heat flux as used in a constant 1500 to 1600 F fluid bed.
According to the published data of Chan and 25 Xrieger, to gasify wood chips should require, to dry, heat up, and pyrolize the wood, on the order of 2 to 3 minutes residence time in the gasifier. Heat balance calculations indicate that to provide the heat for gasification approx-imately 1~ pounds of sand must be circulated per pound of 30 wood gasified.
With this information, estimation can be made of the dimensions of a fluid-bed reactor to gasify wood.
Sizing of a fluid bed using the prior art to predict the dimensions a fluid bed would have to have to operate at the

3~

high biomass throughputs taught by this invention will make all the more apparent the novelty and unobviousness of this invention.
Since wood and sand are constantly fed to the 05 gasifier with sand and char withdrawn also at a constant rate, the residence time of wood and sand are equal.
Because the sand does not react or change in weight, the sand f 1GW and sand inventory in the reactor provide the design basis.
The residence time of wood and sand in the fluid bed is given by Sand Inventory lbs t Sand Feed Rate lbs/min ~he sand inventory in the bed is given by PBhB~B
where Pg ~ sand density at fluidization conditions, lbs~ft3 hB = fluid bed height, ft AB = cross sectional area of the fluid bed, ft2.
The sand feed rate is given by ~S ~lbs/hr) = WSO (lbs/ft2-hr) AB (ft2) .
WSO is the specific sand throughput and de-termines the fluid-bed cross sectional area required to 25 achieve the total sand feed rate which in turn is related to the wood rate by the heat balance. As mentioned, the heat balance requires approximately 15 pounds of sand per pound of wood. If one selects a wood throughput demonstra-ted to be feasible by this invention, for example, WWO =
30 2000 lbs/ft2-hr where WWO is the specific wood throughput, it is possible to estimate the fluid-bed height required to provide the necessary 2 to 3 minutes residence time. The expression for the residence time in terms of the-above parameters is given by '~ ' P BhBAB P BhB
t WSoAB W$o Since WSO = 15 WWO = 15 (2000 lbs/ft2-hr x 1 h;
WSO = 500 lbs/ft2-min 05 A reasonable value for the bulk density of a well fluidized bed of sand is common knowledge in the art and given by several fluidization texts at approximately 30 lbs/ft3.
Substituting in the above equation 30 lbs/ft3 x hB (ft) 3 mlnutes = - -500 lb~/ft2-min indica~es a bed h~ight of approximately 3 min x 500 lbs/ft2-min h8 = = 50 ft 30 lbs/ft3 would be required to provide the needed residence time at the high biomass throughputs taught by this invention. It is, however, well known by anyone familiar with fluidiza-20 tion technology that "slugging~ occurs with long skinnyfluid beds. The maximum fluid bed height to diameter ratio to avoid slugging is h/D = 5 and pxeferably a ratio h/D <2 is recommended for good fluidization.
Unlike the teachings of the prior art, the pres~
25 ent invention is able to gasify 2000 lbs/ft2-hr and even exceed 4500 lb/ft2-hr through a unit of 10 inch ~0.83 ft) diameter and length of 22 feet. Further, the operation is smooth and without any evidence of slugging.

~7~34 The present invention is a radical departure from tAe teachings and conventional wi~dom of the prior art.

Description of Related Art 05 Bailie, U.S. Patent 3,853,49~ describes a pro-cess involving separate gasification and combustion zones.
In the Bailie process, both zones are conventional fluid-bed reactors. Published wood throughput values for the Bailie process typically do not exceed 120 lbs/ft2-hr.
10 Fluidization would occur typically with inlet gas veloci~
ties of 1-3 ft/sec to provide good fluidization. Since the Bailie process employs conventional fluid-beds, transfer of circulating sand is by direct flow from fluid-bed to fluid-bed rather than by entrainment and exit out the top 15 of the reaction vessel.
Squires U.S. Patent 4,032,305 discloses another circulating bed gasifier for coal and coke gasification known as a n fast fluid-bed~. The fast fluid-bed can operate in a two-zone configuration of an exothermic 20 combustion zone and an endothermic gasification zone.
Squires states that the minimum velocity to achieve a circulating fast fluid-bed is a little more than 6 ftjsec with particles having an average diameter of 60 microns.
Squires prefers operating with particles no larger than 25 250 microns.
The present invention uses particles typically of 20-1000 and preferably 300-800 microns. Scaling the 6 ft/sec minimum velocity reco~mended by Squires based on finer particles to the coarser particles of this in-30 vention, one would estimate a minimum velocity of 30 ft/secwould be required to achieve fast fluid-bed conditions.
Both entrained and fluidiæed gasification pres-ents a variety of advantages incluaing low capit-al-equip=
ment costs, low maintenance, flexibility, ease of control 71~i34 and high conversion efficiency. There are few moving parts thus design and assembly are greatly simplified.
It is an object of the present invention to disclose a gasifier operating in the entrained mode but 05 using inlet velocities characteristic typically only of fluidized beds and capable of operating at fuel feedrates much higher than contemplated possible by the existing art. It is an object of the present invention to disclose such a gasifier having throughputs that can approach or 10 exceed from 500-4400 lb/ft2-hr.
The gasifier according to the present invention operates in the entrained mode but at inlet gas velocities below and wood throughputs that are well beyond what would be expected based on a knowledge of the prior ar~. In ~pite 15 of the fact that th~ system operates at inlet velocities typical of fluid-beds, the reactor operates in the en-trained mode.

Brief Description of the Drawings Figs. lA, lB, and lC are sketches of gasifier 20 systems according to the prior art.
Fig. 2 is a sketch of a gasifier system according to this invention depicted coupled with a typical parallel entrained bed pyrolysis unit.
Fig. 3 is a graph of biomass throughput via inlet 25 gas velocity. The graph highlights the present inven-tion's unique capability of operating in the region termed "Region IV" corresponding to high biomass throughput and low inlet gas velocity.
Fig. 4 is a sketch of a gasifier useful in the 30 process according to this invention. The depicted cyclone separator can inertially remove entrained solids, thus the gasifier optionally can be coupled to various made combustors incl~ding~ fast fluid, bubbling fluidized, multi-solid fluidized and entrained solid.

.

~7.~ia~

Summarv of the Invention This invention comprises the unexpected discovery that it is possible to gasify biomass at very high wood throughputs but in an entrained gasifier operating at low inlet gas velocities.
Entrainment rates in order to operate in an entrained mode, it had been believed, depended to lesser or greater degrees on a large number of complexly interrelated variables including particle size, density, uniformity of particles, column diameter, baffling, bed depth, but primarily it was believed on high inlet . gas velocity.
Though the .East :Eluidized bed is r~cognized as having much higher processing capacitios than a bubbling .El~lidized b~d~
this type of b~d typic~l:ly r~uired ai:r inlet exce~din~ 30 .Et/sec.
What makes this invention all the remarkable is that applicant has achieved entrainment of inert solids, not merely bubbling fluidization, in a parallel entrained bed pyrolysis process at an inlet velocity of as low as 0.5 ft/sec but with a wood throughput from 500 to 4400 lbs/ft2-hr. The lbs/ft2-hr relates to the gasifier diameter by referring to the cross-sectional area of the gasifier.
The improvement or combination which is claimed as the invention herein comprises a method of operating a gasiEier, which comprises introducing inlet gas at a gas velocity not exceeding 7 ft/sec to fluidize a bed in a gasifier vessel; forming the bed into a fluidized bed in a first space region by means of the inlet gas, the fluidized bed containing a circulating hot relatively fine and inert solid bed particle component; inputting carbonaceous material into the first space region with fluidized ' ~,;

~7~

- 7a - 26494-106 bed at a rate from 500-4400 lbs/ft2-hr; endothermally pyrolyzing the carbonaceous material by means of the circulating hot inert particle component so as to form a product gas; forming contiguous to and above the fluidized bed a lower average density entrained space region containing an entrained mixture oE inert solid particles, char, and carbonaceous material and the product gas;
gradually and continuously removing portions of the entrained mixture and the product gas from the entrained space region of the gasifier to a separator; separating the entrained mixture from the product gas; passing the inert solid particles through an exothermic reactLon zone to add heat; returning at least the inert solid particles to the ~Lr~t space r~ion. Further and ~or~
particular embodiments of the invention are de~ined in the claims forming part of this specification, which define the scope oE the exclusive rights claimed by the applicant.
Detailed Description The gasifier according to our invention is basically a reactor with a fluid-bed of sand at the reactor base operated at wood feed rates sufficiently high to genera-te enough product gas ~0 to circulate sand and gasified char by entrainment.
The gasifier is essentially a hybrid with an entrained zone above a fluidized bed gasifier.
This gasifier would have the features illustrated in Figure 4~ In Figure 4, the annular shaped gasifier vessel has a conventional gas distribution plate near the bottom and there at has openings for biomass feedstock entry, inert material circulation or recirculation, and fluidizing gas inletting. The reaction vessel has an exit at or near the to~ leading t~ a separator from which product 05gas is discharged and solids are recycled to the bottom of the gasifier or prefera~ly recycled via an exothermic combustor to reheat the inert material.
The biomass gasifier operates with a recir-culating particulate phase and at inlet gas velocities in 0 the range required to fluidize the sand or other re-circulating particulate phase. For example, a velocity of 0.8 to 2 ft/sec with a 20 x 50 mesh sand has allowed smooth stable operation. Velocities of 0.5 to 7 ft/sec can be used.
The biomass gasi~ier operates at woo~ eed xates that exceed 3000 lbs/hr of dry biomass per square oot of reactor cross sectional area. Throughputs of 4400 lbs--ft2/hr are achievable and possibly even higher. The inlet for wood feed and recirculating sand is located at the base 20 of the reactor in the neighborhood of the gas distributor.
The gasifier additionally has provision for removal of the circulating particulate phase and char by entrainment.
For example, separation of the particulate phase, such as sand and char from the product gas, can be accomplished by 25 conventional cyclone(s).
; I,ooking now at Fig. 3, the low inletgas velocity high throughput biomass gasifier of the present invention operates with biomass throughputs of from 200 and prefer-ably 500-4400 lb/ft2-hr but with inlet gas velocities of 30 0.5-7 ft/sec. This operating range corresponds approxi-mately with Region IV of the graph.
~ egion I visuali~es the operating parameters known to the art for conventional fluidized and entrained beds. Such beds in practice are bounded by a bioMass ~2~6;~

throughput of 2000 lb/ft2-hr and a minimum inlet velocity of 10-12 ft/sec up to approximately 30 ft/sec.
Region II illustrates the operating region of "fast fluid-bedsn. To achieve the bed density necessary 05 for a fast fluid-bed a minimum solids circulation rate is usually required. Region II includes the transport veloc-ities commonly used in vertical pneumatic conveying of particulate material. This is the typical operating re-gion of entrained systems regardless of the wood through-10 put.
Region III illustrates the operating region ofconventional fluid-beds. Such beds do not operate in the entrained mode. Experience at throughputs above 200 lb/-ft2-hr is unavailable to date for conventional fluid beds.
The method o~ operating a gasifier according to this invention comprises introducing inlet gas at a gas velocity not exceeding 7 ft/sec to fluidize a high average density bed in a gasifier vessel. The high average density bed is formed into a dense fluidi~ed bed in a first space region by means of the inlet gas. The dense fluidized bed contains a circulating first heated relatively fine and inert solid bed particle component. Carbonaceous material is inputted into the first space region with dense fluid-ized bed at a rate from 200 and preferably 500-4400 lbs/-~5 ft2-hr and endothermal pyrolysis of the carbonaceous ma-terial is accomplis~ed by means of the circulating heated inert material so as to form a product gas. Contiguous to and above the dense fluidized bed a lower a~erage density entrained space region is formed containing an entrained 30 mixture of inert solid particles/ char and carbonaceous material and the product gas. The entrained mixture is then removed from the entrained space region of the gasi-fier to a separator such as a cyclone wherein the entrained mixture of inert solid particles, char and carbonaceous 35 material is separated from the product gas. Finally, at il`6;~

least the inert solid particles are returned to the first space region after passage through an exothermic reaction zone such as a combustor to first heat the inert particles.
To facilitate the exothermic reaction, it can be advaa-05 tageous to route ~he entire entrained mixture absent prod-uct gas through the combustor.
In this invQntion a fluidized bed of heated sand or other relatively inert material at the lower end of the gasifier vessel forms a region of relatively high density.
10 Inputted wood or other carbonaceous material, being light-er than the sand, floats on the fluidized sand. As the wood is gasified by the hot sand, an entrained region of sand, char and carbonaceous particles forms in the upper end of the gasifier vessel.
The highest concentration of entrained wood and char would be found at the top of the densely fluidized zone within the gasifier vessel. Entrained hot sand circulates through the entrained wood and char. As the carbonaceous particles pyrolyze, they generate gas forming a high velo-20 city region above the fluidized bed. Despite a low gas inlet velocity below the bed the gas velocity above the fluidized bed becomes high enough to actually remove par-ticles from the bed.
By operating at low inlet gas velocity, high residence time in the reaction vessel can be achieved while surprisingly still having high throughputs of carbonaceous material generating gas to form the entrained region above the fluidized region.
In this system, unlike the prior art, material from the top of the vessel is removed from the system only by entrainment despite the low inlet gas velocities belo~
the bed. This is possible by the design of using a fluidized region above which is an entrained region from which particles are removed. Entrainment occurs in part 7~L~3~

because of the gas generated in situ contributin~ signifi-cantly to the volume of gas moving through the reaction vessel, while avoidin~ the destructive slugging predicted by the prior art for conventional flu~dized beds if oper-05 ated under the invention's parameters.
The carbonaceous material fed to the gasifierhas upwards of 6~ of the available carbon converted upon a single pass through the gasifier system. The remainder of the carbon is burned in the combustor to generate heat for the pyrolyses reaction. If other fuel is used in the combustor, then additional carbon can be converted in the gasifier.
The inlet air fed to the gasifier typically can be steam, combustion by-product gas, recycled product gas, nitrogen, air or other gas known in the art for yielding specific products~ An assoclated oxygen plant i~ not required for the gasifier unit operated according to this invention.
In the design of a conventional fluidized bed, entrainment of particles to the cyclone is considered deleterious to performance of the system. Loss by en-trainment is sought to be avoided or, if unavoidable, minimized as much as possible. Thus, a typical fluidized bed is designed such that enough space above the bed is provided to allow lifted particles to settle in the vessel.
This space must be provided for in the height of the gasifier vessel and is referred to as transport dis-engagement height or free board space.
~he present invention teaches how to use en-trainment to beneficial advantage to obtain high carbon-aceous feedstoc~ throughput. Commercial advantage of this invention becomes immediately apparent as more throughput means higher production levels through the same or smaller - sized equipment, thus a significant reduction in capital costs results from this technology.

.

.~71634 In this invention entrained material exits the vessel near the top of the gasifier to a cyclone or other inertial settling device for separating the product gas from the char, carbonaceous material and inert material.
05 The system of the present invention is versatile and could be combined with any type of combustor, fluid-ized, entrained, or non-fluidized, for heating the inert material. The inert material can be heated by passage through an exothermic reaction z~ne of a combustor to add heat. The inert material is understooa to mean relatively inert as compared to the carbonaceous material ancl could include sand, limestone, and other calcites or oxides such as iron oxide. Some of these "relatively inert materi-als" actually could participate as reactants or catalytic agents, thus "relatively inert" i8 used as a comparison to the carbonaceous materials and is not used herein in a strict or pure qualitative chemical sense as commonly applied to the noble gases. For example, in coal gasifi-cation, limestone is useful as a means for capturing sulfur to reduce sulfate emissions. Limestone might also be useful in catalytic cracking of tar in the gasifier.
The unexpectedness of this invention is re-flected from the realization that the invention cannot be arrived at by mere high input of carbonaceous material to a fluidized bed. The prior art theoretical limits as to slugging teaches that operating at fluidization velocity, the addition or throughput of more and more carbonaceous materials eventually results in an L/D ratio in excess of 2-5 giving rise to slugging, vibration and ultimately self destruction of the containment vessel. The prior art teaches completely away from the present invention.
In this invention, we have discovered that an unexpected operating relationship can exist between wood 'feed rate or throughput and inlet gas veiocity. ~ Thi-s relationship indicates the higher the wood feed rate, the ` ~716~4 lower the inlet gas velocity that can be tolerated. We have been successful in combining both extremely high wood throughputs with low inlet gas velocities. The combina-tion of low inlet gas velocity and high wood feed rates 05 provide the basis for the design of a biomass gasifier that is not only completely unanticipated based on existing ~ informativn but also could not be arrived at through - assembling of various combinations of available data.
Our experimental work has demonstrated that bio-10 mass con~ersion results in sufficient gas generation to transport the sand/char suspension through the reactor and to maintain a sufficiently low suspension density at the gasifier base to allow the hot sand from the aombustor to continually flow into the gasifier from the combustor.
That the sygtem would behave in this fashion is completely unpredictable based on existing knowledge as has been demonstrated in the previous calculations illustrating the application of available fluid-bed design criteria and biomass gasification data. As was demonstrated, assuming 20 the system is operating in the conventional fluid-bed mode in the manner of Bailie, then, to transfer the hot sand into the fluid-bed requires that the sand overcome a head of Pfbhfb where Pfb is the fluid-bed density and hfb is the fluid-bed height. Assuming that a wood residence time on 25 the order of 3 minutes is required to dry, heat up, and pyrolyze the wood, and with the sand/wood ratio necessary to provide the heat for gasification, a simple calcutati~n predicts that it would be impossible to maintain sand flow against the static pressure in the gasifier at wood feed 30 rates far lower than those covered by our present inven-tion. For example, at a wood throughput of 2000 lbs/-ft2-hr, and assuming a typical fluid-bed density of 30 lbs/ft3, h~b would be 50 ft (the experimental gasifier has a total height of only 22 ft). In addition, these high 35 wood throughputs would require fluid-beds with L/D (bed length to diameter) ratios far exceeding those at which fluid-beds can be smoothly operated. For example, fluidi-zation tests predict the onset of slugging, which causes severe vibration in fluid-beds, when the fluid-bed L/D
exceeds a value of 2 to 5 depending on particle size. Thus, 05 one "skilled in the art~ of both biomass gasification and fluid-beds would predict that the proposed invention would not work.
Since the system described in this invention has been successfully reduced to practice and does work, it is interesting to speculate on what is actually occurring in the gasifier when it is operated at inlet velocities insufficient to entrain the sand but at high throughputs.
At low inlet gas velocities, it is probably reasonable to speculate that A short fluid-bed exists at the base of the ga~ifier. Fresh wood and hot sand from the com~u~tor enter below the surface of the fluidized zone of the reactor.
Because of the low density of the wood and char, it is reasonable to expect a much higher concentration of wood and char to be floating on thesurface of the fluid-bed than is randomly circulating within the bed. Sand however circulates randomly in the fluidized zone thereby trans-ferring heat to the ~floating" wood. Since the con-centration of wood and char is highest at the top of the fluid-bed, most of the gas will be generated there. This means that entrainment will occur from the top of the fluid-bed zone because of the high local gas velocities.
The discovery that it is possible to operate ; using a low inlet gas velocity and high biomass throughput and maintain a steady-state inventory in the reactor ~ith removal of sand and char by entrainment allows a very substantial improvement over the existing art.

7~63~

~xamples 1. Gasifier Cou~led to Fluid Bed Combustor A process research unit (PRU) was assembled.
The system consisted of a 10 inch I.D. gasifier coupled to 05 a 40 inch I.D. combustor. The gasifier and all connecting piping was constructed without refrac~ ory linings to re-duce start-up and cool down time as well as the time required to reach steady state. All the components of a commercial-scale system are included in the P~U allowing 10 the system to be operated in a completely integrated fashion. The PRU combustor is oversized to ensure that the gasifier, which receives all its heat from the circulating entrained solids phase, can be maintained at a temperature ~ufficient to achieve the desired gasification conver-15 ~ions. Natural gas i5 added to help balance the large heatlosses inherent in a small-scale system.
~ he gasifier reactor is designed to operate up to 1600 F and 5 psig. Entrained sand and char are separated from the product gas in a disengager and returned to the 20 combustor. Char produced in the gasifier is consumed in the combustor to heat the sand phase. The combustor is a conventional fluid bed designed to operate at 1900 F.
Typically as-received or partially dried wood chips are charged to a feed hopper. A bed o~ silica sand 25 is placed in the conventional fluid bed combustor and fluidized with air at a linear velocity of about 1.5 ft/-sec. After smooth fluidization is established, a startup natural gas burner is ignited. This burner ~erves as an air heater and is used to preheat the bed to a temperature 3~ sufficient to combust char. The startup burner has a total heat input of 1 million Btu/hr. The wood feed rate is controlled by four metering screws located below the wood feed hopper. These screws empty into another larger horizontal conveying screw which, in turn, empties into a `:
;

~ ~ 7 vertical conveying screw. The wood chips then fall into the gasifier.
Adjustments to gas flows or system pressure (nominally 5 psig~ are made remotely from the control room.
05 The PRU system can be operated at wood feed rates from 50 to in excess of 2500 lb/hr. Larger commercial systems readily achieve significantly higher wood feed rates. ~xpressed as lb/ft2-hr 2500 lb/hr through a circu-lar lO" I.D. gasifier, is the same as 2500 lb/hr through an area [~ ~r2~ i.e., ~(5/12)2~ of 0.545 sq. ft.
2500 x 0.545 = 1 x = 4584 lb/ft2-hr Design specifications for the PRV system are:

lS Gasifier Size: lO in. I.D. x 22 ft long Temperature 1600 F
Pressure 20 psia Combustor Type: Fluidized bed Fuel: Natural gas in addition to wood char Temperature: 1900 F
Size: 40 in. I.D. x 11 ft long Feed Rate Wood: 50-2500 lb/hr i.e., (90-46~0 lbs/ft2-hr) Heating Value of Product: 475 Btu/SCF (dry) Heat Carrier: silica sand Gasifying Medium: steam or inert gas ~t Fuels Utilized Thus Far:
(without pretreatment or size reduction) O coarsly shredded bark ~ wood chips 05 . sawdust . hog fuel 2. Additional Demonstrations of the Feasibility of Oper-ating at Low inlet Gas Velocities and ~iqh Biomass Throughput 9 27163~

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~`~7~ 4 It will be evident to those skilled in the art that start-up of the gasifier for example coupled to a combustor would involve the staqes of heat-up and initi-ation of gasification. These stages could be comprised as 05 follows:

A. Start-Up Natural qas or some other fuel, which could be ; wood, is ignited in the combustor and burned at a rate sufficient to increase the combustor temperature at a rate which will not induce spalling of the ceramic lining.
Circulation of sand is then initiated between the gasifier and combustor to heat-up the gasifier. During the heat-up stage, air can be used as the transport gas in both gasifier and combustor. Gas velocities and wood throughputs in both the gasifier and combu~tor must be sufficient to entr~in the sand to allow for its circulation between gasifier and combustor. This would require a gas velocity on the order of 15 ft/sec with the sand particle size range that we employ. The combustion of an auxiliary fuel and circula-tion of the hot sand is continued until the gasifierreaches the desired temperature (about 1700 to 18Q0 F).

B. Initiation of Gasification After the gasifier reaches the desired 1700 to ~800 F, at this time the feed gas to the ~asifier is switched from air to steam and then, if desired, to recycle product gas. Wood feed is initiated and the wood feed rate gradually increased. As the wood gasifies, char is pro-duced which is transported to the combustor where it is burned to replace the start-up fuel. As the wood feed rate is increased, the feed gas ~steam or recycle product gas) to the gasifier is gradual~y reduced until the system is operating in the range of gas velocities not exceeding 7 ft/sec.

.

While particular embodiments of the invention have been shown and described, it will be obvious to those s~illed in the art that various changes and modifications may be made without departing from the essential features 05 of the present invention and, therefore, the aim in the appended claims is to cover all such changes and modifi-cations as fall wi~hin the true spirit and scope of the invention.

Claims

1. A method of operating a gasifier which comprises:
introducing inlet gas at a gas velocity not exceeding 7 ft/sec to fluidize a bed in a gasifier vessel, forming the bed into a fluidized bed in a first space region by means of the inlet gas, the fluidized bed containing a circulating hot relatively fine and inert solid bed particle component, inputting carbonaceous material into the first space region with fluidized bed at a rate from 500-4400 lbs/ft2-hr, endothermally pyrolyzing the carbonaceous ma-terial by means of the circulating hot inert particle component so as to form a product gas, forming contiguous to and above the fluidized bed a lower average density entrained space region containing an entrained mixture of inert solid parti-cles, char, and carbonaceous material and the product gas, gradually and continuously removing portions of the entrained mixture and the product gas from the entrained space region of the gasifier to a separa-tor, separating the entrained mixture from the prod-uct gas, passing the inert solid particles through an exothermic reaction zone to add heat, returning at least the inert solid particles to the first space region.

2. The method according to Claim 1 wherein the inert solid bed particle component is comprised of parti-cles of 300 to 800 microns average diameter.

3. The method according to Claim 1 wherein the carbonaceous material is inputted into the first space region with dense fluid bed at a rate exceeding 3000 lb/ft2-hr.

4. The method according to Claim 1 wherein the relatively inert solid bed particle component is selected from the group consisting of sand, limestone, metal ox-ides, and calcite.

5. The method according to Claim 4 wherein the inert solid bed particle component is comprised of parti-cles of 20-1000 microns average diameter.

6. The method according to Claim 1 wherein after separating the entrained mixture from the product gas, the entrained mixture is passed through an exothermic reaction zone of a combustor.

7. The method according to Claim 1 wherein separating the entrained mixture from the product gas is accomplished using a cyclone separator.

8. A method of operating a gasifier which comprises:
a. introducing inlet gas at a gas velocity of about 0.5 to 7 ft/sec to fluidize a bed in a gasifier vessel;
b. forming the bed into a fluidized bed in a first space region by means of the inlet gas, the fluidized bed containing a circulating hot relatively fine and inert solid bed particle component;
c. inputting and throughputting carbonaceous material into and through the first space region with fluidized bed at a rate from 500-4400 lbs/ft2-hr;
d. endothermally pyrolyzing the carbonaceous material by means of the circulating hot inert particle component so as to form a product gas;
e. forming contiguous to and above the fluidized bed a lower average density entrained space region containing an entrained mixture of inert solid particles, char, and carbonaceous material and the product gas;
f. gradually and continuously removing the entrained mixture and the product gas from the lower average density entrained space region of the gasifier to a separator, residence time of the carbonaceous material in the gasifier not exceeding 3 minutes on average;
g. separating the entrained mixture from the product gas;
h. passing the entrained mixture containing inert solid particles, char, and carbonaceous material through an exothermic reaction zone to add heat;
i. returning at least the inert solid particles to the first space region; and wherein the gasifier is operated at a pressure between atmospheric and 100 psia and wherein the inlet gas velocity in step (a) has an inverse relationship to the rate of inputting carbonaceous material in step (c).

9. The method according to claim 8 wherein the carbonaceous material is inputted into the first space region with dense fluid bed at a rate exceeding 3000 lb/ft2-hr.

10. The method according to claim 8 wherein the relatively inert solid bed particle component is selected from the group consisting of sand, limestone, metal oxides, and calcite.

11. The method according to claim 8 wherein after separating the entrained mixture from the product gas, the entrained mixture is passed through an exothermic reaction zone of a combustor.

12. The method according to claim 8 wherein separating the entrained mixture from the product gas is accomplished using a cyclone separator.

13. The method according to claim 8 wherein the gasifier vessel has an L/D ratio above 6.

14. The method according to claim 8 wherein the inlet gas introduced is selected from the group consisting of steam, recycled product gas, and mixtures thereof.

15. The method according to claim 8 wherein the gasifier is operated at a pressure between atmospheric pressure and 30 psia.