CA1262886A - Tensioning mechanism and cathode rollers for fiber plating - Google Patents

Abstract

ABSTRACT

A process and apparatus for individually electroplating metal onto filaments in which an array of tensioning rollers and contact rollers ensures a direct tight path for current carrying filaments from the contact point to the electrolyte in the tank and facilitates rapid replacement of the contact rollers when necessary.

Description

Z~21~G 110-0~4 ~,4/~ 1 ' 'B,~C~CGROU~D OF THE 'JNVENTIOI~ -1. Field of the Invention - This invention relates to metal coated filaments and to a process and an apparatus for their continuous production.

2. Description of the Prior Art.
Filaments comprising non-~etals and semi-metals, such as carbon, boron, silicon carbide, polyester, n~lon, aramid, cotton, rayon, and the li~e, in the form of monofilaments, yarns, tows, mats, cloths and chopped strands are known to be use~ul in reinforcing metals and organic polymeric materials. Articles comprising metals or plastics rein-forced with such fibers find wide-spread use in replacing heavier components made up of lower strength conventional materials such as aluminum, steel, titanium, vinyl poly-mers, nylons, polyester, etc., in aircraft, automobiles, office equipment~ sporting goods, and in many other fields.

A common problem in the use of such filamënts, and also glass, asbestos and others r is a seeming lacX of ability to translate the properties of the high strength filaments to the material to which ultimate and intimate contact is to be made~ In essence, even though a high strength filament is empIoyed, the filaments are merely mechanically entrapped, and the resulting composite pulls apart or breaks at disappointingly low applied forces.
The problems have been overcome in part by depositing - a layer or layers of metals on the individual filaments prior to incorporating them into the bonding material, e.g., metal or plastic. Metal deposition has been accomplished by vacuum deposition, e.s., the nicXel on fibers as des cribed in U.S. 4, 132,828; and by electroless deposition from chemical baths, e.g., nicXel on graphite filaments as described in ~.S.3,894,677; and by electrodeposition, .

~2e~ 6 e.g., the nickel electroplating on carbon fibers as des-cribed in Sara, U.S. 3,622,283 and in Sara, U.SO 3,807.996.
~en the metal coated filaments of such procedures are twisted or sharply bent, a very substantial quantity of the metal flakes off or falls off as a powder. When such metal coated filamentsare used to reinforce either metals or polymers, the ability to resist compressive stress and tensile stress is much less than what would be expected from the rule of mixtures, and this is strongly suggestive that failure to efficiently reinforce is due to poor bond-ing between the filament and the metal coating.
It has now been discovered that if electroplating is selected and if an amount of voltage is selected and used in excess of that which is required to merely dissociate lS (reduce) the electrodepositable metal ion on the filament surface, a superior bond between filament and metal layer is produced. The strength is such that when the metal coated filament is sharply bent, the coating may fracture, but it will not peel away. Moreover, continuous lengths of such metal coated filaments can be knotted and twisted without substantial loss of the metal to flakes or powder.
High voltage is believed important to provide or facilitate uniform nucleation of the electrodepositable metal on the filament, and to overcome any screening or inhibiting effect of materials absorbed on the filament sur~ace.
Although a quantity of electricity is required to electrodeposit metal on the filament surface, an increase in voltage to increase the amperes may cause the filaments to burn, which would interrupt a continuous process. The aforesaid Sara patent No. 3,807,966, uses a continuous process to nickel plate graphite yarn, but employs a plating current of only 2.5 amperes, and long residence times, e.g. 14 minutes, and therefore low, and conventional,voltages. In another continuous process, described in U.K. Patent No. 1,272,777, the individual ~ ~ 2~ ~

fi~ers in a bundle of fibers are electroplated without burning them up by passing the bundle through a jet of electrolyte carrying the platinq material, the bundle being maintained at a negative potential relative to the electrolyte, in the case of silver on graphite, the poten-tial between the anode and the fibers being a conventlonal

3 volts.
The present invention provides an efficient apparatus to facilitate increasing the potential between anode and the continuous filament cathode, since it is a key aspect of the present process to increase the vol-tage to obtain superior metal coated fibers. In addition, since it permits extra electrical energy to be introduced into the system without burning up the filaments, residence time is shortened, and production r~tes are vastly in-creased over those provided by the prior art. As will beclearfrom the detailed description which follo~s, novel means are used to provide high voltage plating, strategic cooling, efficient electrolyte-filament contact and high speed filament transport in various combinations, all of which result in enhancing the production rate and quality of metal coated filaments. Such filaments find substantial utility, for example, when incorporated into thermoplastic and thermoset molding compounds for aircraft lightning pro-tection, EMI/RFI shielding and other applications requiring electrical/thermal conductivity. They are also useful inhigh surface electrodes for electrolytic cells. Composites in which such filaments are aligned in a substantially parallel manner dispersed in a matrix of metal, e.gO, nic~el coated graphite in a lead or zinc matrix are characterized by light weight and superior resistance to compressive a~nd tensile stress. The apparatus of this invention can also be employed to enhance the production rate and product quality when e:Lectroplating normally non-conductive con-tinuous filaments, e.g., polyaramids or cotton, etc., if first 21~3~6 o an adherent electrically conductive inner layer is deposited,e.g., ~y chemical means,on the non-conductive filament.

28a6 S~MMARY OF T~E INVENTION
The present invention seeks to provide fibers formed of a conductive semi-me-tallic core with metallic coatings.
The present invention also seeks to provide a process in which the electroplating of -the fibers is effected under high voltage electroplating conditions.
Further, the present invention seeks to provide a pro-cess and apparatus which will efficiently and rapidly coat fibers with metallic coatings and facilitate the cleaning and collecting of the finished product.
According to the present invention, there is provided an apparatus for metal plating fiber, comprising:
(a) a D.C. rectifier;
(b) an electrolyte tank to which the rectifier delivers current;
(c) electrolyte in the electrolyte tank;
(d) a metal anode in the electrolyte;
(e) an electrolyte sprayed contact roller adapted to trans-mit high current immediately above the electrolyte surface;
(f) means for continuously passing fiber through the electro-lyte;
(g) means for delivering D.C. current from the rectifier through the fiber to the electrolyte; and (h) means for maintaining tension on the fiber to insure a direct tight path from the fiber at the contact point to the elect-rolyte in the tank, said means for maintaining tension on the fiber is an array of tensioning rollers located upstream of the contact member over which the fiber passes to reverse direction, and ~2~

- 5a - 61109-7291 further comprising means to drive the array of rollers simultane-ously at -the same speed in the direction of the fiber at a speed equal to or less than the speed of the fiber.
~ ccording to another aspect of the invention, -there is also provided a process for electroplating fiber comprising:
(a) continuously passing the fiber over a contact roller adapted to transmit high current into an electrolyte solution in a tank in which a metal anode is immersed;
(b) passing D.C. current at a minimum voltage of 10 volts through the fiber to the anode; and (c) imposing a tension on -the fiber upstream of the contact roller by passing the fiber over an array of tension rollers in a path that reverses -the direction of the fiber and rotatlng the ten~ion rollers in the direction of the fiber at a speed equal to or less than the speed of the fiber to insure a direct tight path from the fiber at the contact roller to the electrolyte in the tank, whereby metal from the anode migrates to the fiber and is bonded thereto.
The apparatus is a continuous line provided generally with a pay-out assembly adapted to deliver a multiplicity of fibers to an electrolytic plating bath. The line includes a pre-treatment process, after which the metal-plating is performed in a continuous process by the passage of the clean fibers -through an electrolyte under high voltage conditions. Means are provided to cool the fibers during the passage from the contact roll associa-ted with the electrolytic tank and the electrolyte bath.
Further, the fibers pass over contact rollers into ~L2~Z~

_ 6 _ 1109-7297 the electrolyte. The line includes an assembly of ten-sioning rollers that serve to insure a tight direct line of the fiber from the contact roller to the electrolyte.

The tensioniny rollers are comprised of a plurality of driven rollers over which the fibers pass, and the path of the fibers is reverse!d to create tension. The tensioning rollers are driven independently of the dri~e for the processing apparatus and at a speed equal to or less than the speed of the fiber. The speed is determin-ed by visual inspection.

The contact rollers are located in close proximity to the surface of the electrolyte, and by virtue of the processing conditions require frequent change. As a result the contact rollers are mounte~ on fixed aligned mounts. The mounts both carry support bushings having an outside diameter equal to the inside diameter of the contact roller.

, ~

DESCRIPTION OF THE DR~WI GS

The invention will be more readily understood when viewed in association wi-t:h the following drawings wherein:

FIGURE 1 is a schematic view of the overall process of the subject continuous electrolytic plating process except for the pay-out assembly.

FIGURE 2 is an elevational view of the pay-out section arranged specifically to simultaneously deliver a multiplicity of fibers to the electrolytic plating operation.

FIGURE 3 iS a plan view of the pay-out assembly of FIGURE 2.

FIGURE 4 iS an isometric view of the wetting and tensioning rollers between the pay-out and electrolytic bath.

FIGURE 5 iS an elevational view of one electro-lytic tank.

FIGURE 6 is a plan view of the tank of FIGURE 5.

FIGURE 7 is a sectional elevational view through line 10-10 of FIGURE 5.

FIGURE 8 is an isometric view of the commutation f ingers.

FIGURE 9 lS an isometric view of one contact roller in association with the means for providing coolant to the fihers and a current carrying medium from the contact roller to the bath.

~ 6 FIGURE 10 is an elevational view of a section of the electrolytic tank depicting an anode basket.

FIGURE 11 is a schematic of the electrolytic coolant conductor and a contact roller.

FIGURE lZ is a sectiona:L elevational view of a contact roller of the process assembly.

0 FIGURE 13 is a detail of the end cap of the roller of FIGURE 12.

FIGURE 14 is a partial detail of the opposite end of the roller of FIGURE 12.
FIGURE 15 is a view of the electrical system of the present invention.

FIGURE 16 is a drawing of the mechanism for synchronously driving the apparatus of the subject invention.

FIGURE 17 is a plan view through line 28-28 of the section of FIGURE 16.
FIGURE 18 is a side elevational view of the roller assembly in the drying section of the system.

~Z~;28B6 DESCRIPTION OF THE PREFERRED EMBODI~:NT
The process and apparatus of the present invention are directed to providing an eEficient and complete means 5 for metal-plating non-metallic and semi-metallic fibers.
The process of the invention relies on the use of very high voltage and current to effect satisfactory plating. As a result of the high voltage and current, an apparatus has been developed that can produce high volumes of plated material under high voltaqe conditions.
The process of the present invention and the apparatus particularly suitable for practicing the process of the invention are descr~bed in the pre-ferred embodiment in which the specified fiber to be plated is a carbon or graphite fiber and the plating metal is nickel. However, the process and apparatus of the present invention are suitable for virtually the entire spectrum of metal-plating of non-metallic and semi-metallic fibersO
The overall process and schematic of the apparatus except for the pay-out assembly are generally shown in FIGURE 1. The operative process includes in essence, a pay-out assembly for dispensing multiple fibers in parallel, tensioning rollers 6, a pre-treatment section 8, a plating facility 10, a rinsing station 12, a drying section 14 and take-up reels 16.

~Z~38~i More particularly, the pre-treatment section 8 shown generally in FIGURE 1 includes a tri~sodium phosphate cleaning section 26 and an associated washing-tee 28, rinse section 30 and associated washing-tees 32 and 32A, a hydrochloric acid section 34 and associated tee 36, and rinse section 38 with associated washing-tees 40 and 40A. The plating facility 10 is comprised of a plurality of series arranged electrolyte tanks shown illustratively in FIGURE 1 as tanks 18, 20, 22 and 24, each o which is charged with current by a separate rectifier, ~etter seen in FIGURES S and 15.
The rinsing section 12, sho~n generally in FIGURE 1 is com-prised of tank and tee assemblies similar to the pre-treat-m~nt apparatus. An arrangement of cascading tanks 42 and tees 44, 44A and 44B cycle rinse solution of water and electroly~e over the fibers 2. Thereafter, clean water - is passed over the fibers 2 in the rinse section 46 provided with tanks and washing-tees 48 and 48A.
The rinsed fiber 2 is then passed through section 50 wherein it is first air blasted in chamber 53 and then steam treated in section 55 to produce an oxide surface on the metal plate. ~hc ~rocess i5 completed by passage of the metal plated fiber 2 through the drying unit 14 and reeling of the finished fibers on take-up reels 17 in the reeling section 16.
As seen generally in FIGURE 1, the apparatus is 35 provided with means to convey the fibers 2 through the ~26~

system rapidly without abrading the fibers 2. The com-bination of strategically located guide rollers 51, tension rollers 6, force imposing rollers in the drying section 14 and a synchronous drive assembly shown in FIGURE 16 rapidly conveys the fibers 2 through the apparatus without abrasion of the fibers 2.
The operation begins with the pay-out assembly

4 shown in FIGURES 2 and 3. Functionally, the fibers 2 from the pay-out assembly 4 are delivered over a guide roller 5 through the tensioning rollers 6 to the pre-treatment section 8.

As best seen in FIGURES 2 and 3, the pay-out assembly 4 is comprised of a frame 52 on which the pay-out rollers 54 are mounted. The pay-out rollers 54 are mounted on the frame 52 on a rail 56 and a rail 58. The rollers 54 on rail 56 are arranged to pay-out the fibers 2 to the electroplating system while the rail 58 is an auxiliary rail adapted to mount the spare rollers 54 available to provide alternate duty.
A rail 60 mounts guide rollers 62 over which the fibers 2 from the pay-out rollers 54 travel to reach the tensioning rollers 6.

:~2~2~

o As best seen in ~IGURE 2, the fibers 2 extend from the respective rollers 54 over individual guide roller 62 associated with a particular roller 54 to the cc~mmon guide roller 5 and into the tensioning roller assembly 6. Guide bars 59 are provided ~o guide fibers 2 from the pay-out rollers 54 to the associated guide rollers 62.
As seen in FIGURE 3, the guide rollers 62 are .... .
aligned adjacent to each other to avoid interference between the fibers 2 as a plurality of fibers 2 are simultaneously delivered to the system to be treated and plated.

The pay-out assemhly 4 delivers the fibers ~ over a guide roller 5 to a wetting roller 80 and then to the tensioning rollers 6. A wetting tub 84 is provided with water which wets the fibers 2 and enables suitable and more efficient cleaning and rinsing of the fibers 2 during pre-treatment. The tensioning rollers 6 seen in FIGURE 1 ara shown in more detail in FIGURE 4.
The tensloning rollers 6 comprise an assembly of five rollers 90, all of which are driven through a single continuous chain 87 by a common source such as a variable speed motor 92. Each roller 90 is mounted on a shaft 89 which also mounts a fixed gear 91 around which the chain 87 is arranged. Idler rollers 97 are also arranged to engage the chain 87. A gear 93 extending from the shat 95 of the variable speed motor 92 drives the continuous chain 87 through a chain 101 and a gear 103 fixed to the shaft Z9 of a roller 90. It is n~ecessary that tension be provided to the fibers 2 at a location in the line upstream of the first plating contact roller. The plating contact roller and the fibers 2 must be in tight contact tb facilitate the operation at the high voltage and high current levels necessary for the process.
With tight contact, low resistance is provided between the fibers 2 and the contact rollers, thus the high current passing through the system circuit will not overload the fibers 2 causing destruction of the fibers.
As a result, the tension roller assembly 6 is located upstream of the electroplating tanks 18, 20, 22, 24 (FIG~RE 1) to provide that tension. On the other hand, the fibers should be subjected to as little drag as possible.

Inherent in the fibers 2 is the tendency to separate at the surface and accumulate fuzz. The variable drive motor 92 is coupled to all five of the rollers 90 to provide variable speed for the rollers at some speed equal to or less than the speed of the fibers 2. At carefully co;ntrolled speeds the necessary tension is provided without causing fuzz to accumulate on the ~ibers. The apparatus and procFss are designed to 8~

_14 _ afford a tension roller assembly 6 in which the tension rollers 90 travel at a slower speed than the fibers 2.
The tension on the fibers 2 is maintained by varying the speed of the tension roller 90 in rPsponse to visual determination of the tension.
The pre-treated fibers 2 are next electroplated.

As seen in FIGURE 1, a plurality of electroplating tanks 18, 20, 22 and 24 are provided in series. Under the high voltage-high current conditions of the process, the series arrangement of electroplating tank 18, 20, 22 and 24 afford means for providing discrete voltage and current to the fibers 2 as a function of the accumulation of metal-plating on the fibers 2. Thus, depending on the amount of metal-plating on the fibers 2, the plating voltage and current can be set to levels most suitable for the particular resistance developed by the fiber and metal.
The electrolytic plating tank 18 is shown in FIGURES 5,6 and 7 and is identical in structure to the plating tanks 20, 22 and 24 shown in FIGURE 1. The tank 18 is arranged to hold a bath of electrolyte. The tank 18 has mounted therewith contact rollers 100 and anode support bars 102 which are arranged in the circuit. The - contact rollers 100 receive current from the bus bar 10~ and the anode support bars 102 are connected directly to a bus bar 106. Each of the pIating tan~s 18, 20, 22 and _15 _ 24 are provided with similar but separate independent circuitry as seen in FIGURE 15. The anode support bars 102 have mounted thereon anode baskets 110 arranged to hold and transfer current to nickel or other metal-plating chips.
Each tank 18, 20, 22 and 24 is also provide~ with heat exchangers 114 to heat the electrolyte bath to reach the desirable initial temperature at start-up and to cool the electrolyte during the high intensity current operation~
The tank 18 is provided with a well 103 defined b~ a solid wall lQS in which a level control 107 is mounted and with a recirculation line 109. The recirculation line 109 includes a pump 111 and a filter 113 and functions to continuously recirculate electrolyte from the well 103 to the tank 18. Under normal operating conditions recirculat-: ed electrolyte.will enter the tank 18 and cause the elect-rolyte in the tank to r~se to a level abo~e the wall 105 and flow into the well 103. When electrolyte has evaporated frcm the tan~ the level in ~he well will drop and call for make-up from the downstream rinse section 12.
: 30 The tank 18 is also provided with a line 132 and pump 134 through which electrolyte is pumped to a manifold 128 that delivers the electrolyte to the spray noz~le 130 ~ ~2~86 o above the contact rollers 100.
As shown in more d0tail in FIGURE 10, the fibers 2 pass over the contact rollers 100 and around idler rollers 112 located in proximity to the bottom of the tank. The idler rollers 112 are ~rovided in pairs around which the fibers 2 pass to move into contact with the succeeding contact roller 100 The rollers 100 in the tank 18 com~unicate with the bus bar 104 through contact member 118. The detail of the contact member 118 seen in FIGURE 8 shows that the contact members 118 are formed of a bar 120 and a plural array of fingers 122 and 124 that together provide the positive contac~ over a sufficiently large area on the contact roller 100 to avoid creating a high xesistance condition at the point of contact. The fingers 122 and 124 are resiliently mounted on the bar 120 and by the nature of the material, are urged into contact with the contact roller 100 at all times.
Thus, a high strength positive electrical contact assembly is provided for an en~ironment wherein conven-tional brush contacts cannot serve well.

The high voltage-high current process of the present invention is further facilitated by means for protecting the fibers 2 during the passage between the electrolyte bath and the various contact rollersO The system includes the recirculating s~ray system 126 shown -17 ~ 1109-7297 generally n FIGURES 5 and 6 through which electrolyte i~
recycled from the platin~ tanks and sprayed through the spray nozzles 130 o~ the fibers 2 at contact points on the contact rollers 100.
The spray nozzles 130 are. arranged with two parallel tubular arms 136 and 138 having noz~le openings 139 located on the lower s~-fac~s thereof.
One tubular arm 136 of the spra~ no~zle 130, is arranged to direct electrolyte tangentially on the fibers 2 at the point at which the fibers 2 leave the contact roller 100. The other tubular arm 138 of the spray nozzle 130 is arranged to deliver electrolyte directly on the top of the contact roller 100 at the point at which the fiber 2 engages the contact roller 100. As previously indicated, it is vital that sufficient tension be applied on the fibers 2 to insure.that the fibers 2 are maintained in a tight direct line between ; the contact rollers 100 and the idler rollers 112. The need for a tight line is to assure that the low contact resistance suitable f~r current travel is available with high conductivity through the fibers 2 from the contact rollers 100 to the electrolyte bath. The electrolyte which is recirculated over the contact rollers 100 and the fibers 2provides;a parallel resistor in the circuit and servesto cool the fibers 2.
It is known that the fibers 2 heing plated have ~ 61109-7297 a low fusing currenk, such as 10 amps for 12K tow of about 7 microns in diameter. However, the process o-f the present inven-tion requires about 25 amps between contacts or about 125 amps per strand in each tank.
Furthermore, both contact resistance and anisotropic resistance must be overcome. The contact resistance of a 12K tow of about 7 microns on pure clean copper is about 2 ohms, thus at 45 volts twenty-two and one-half amps are required before any plating can occur. The anisotropic resistance is 1,000 times the long axis. Thus, the total contact tow length must be 1,000 times the tow diameter, which for 7 microns. Practice has taught that one-half inch of contact will properly serve the electric requirement of the system when plating 7 micron tow, hence two inch contact rollers 100 are used. It is also vital that the contact rollers 100 be located at a specified distance above the electrolyte bath to enable the system to operate at the high volt-ages necessary to achieve khe plating of the process. In practice, it has been found that the contact rollers 100 should be located 5 cm from the electrolyte bath when voltages of 16 to 25 volts are applied. Further, it has been found that recirculation of about 9 litres per minute per contact roller traveling at about 0.45 to 7.5 m/min. will properly cool the fiber ~,2~ 36 and provide a suitable parallel resistor when above 5,000 amps are passed ~hrough the system.

The electrolyte in the process is a solution constituted of eight to ten ounces of metal, preferably in the form of NiC12 and NiSo4 per gallon of solution.
The pH of the solution is set at 4 to 4.5 and the temperature maintained between 145 and 150 F. Recir-culation of ths electrolyte through the spray nozzles 130 at the desired rate requires that the nozzle openings be 3/32 inches in diameter on 1/8" centers over the length of each tubular arm 136 and 138. The presence of e~ectrolyte on the fibers is vital, but care is taken to avoid ; excessive electrolyte otherwise the contact rollers will 20 become subjecte~ to the plating occurring in the : electrolyte.

The contact r~lIers 1~0 are shown in detail in : 25 FIGURES 12-14. Each contact roller 100 is located in close pro~imity to the electrolyte in the plating tanks and each is adapted to transmit high current through the system in a high intensity voltage environment. The 30 contact roller 100 thus is designed for continual replace-ment. The contact roller 100 is pro~ided with fixed end .

~ ~2~86 o mounting sectîons 170 and 172 which hold a cylindrical copper tube 174. The cylindrical copper tube 174 is arranged to contact the commutator fingers 122-124 and deliver current through both the fibers 2 and recycled electrolyte to the electrolyte bath. The copper tube 174 is formed of conventional type L copper which must be able to carry 350 amperes. The diameter of the tubing is critical in that the diameter dictates the contact surface for the fibers 2 and the distance that the cohtact roller 100 will be from the electrolyte surface. As a result, the mounts 170 and 172 are fixedly arranged in alignment with each other to releasably support the tube 174 of the contact roller 100. The mount 170 is provided with a bearing support 176 through which a screw mount 178 passes. The screw mount 178 rotatably supports the copper tube 174 on a bushing support 180 and has the capacity to release the copper tube 174 upon retraction of the ~ushing support 180 by withdrawing the screw 178. The mount 172 includes a bushing suppor~ 182 on which a detent 184 is formed. Each copper tube 174 is provided with a notched mating slot 186 to fit around the detent 184 and effect positive attachment of the copper tube 174 to the bushing support 182 thereby obviating any uncer-tainty i~ alignment and facilitating dispatch in replacingeach copper tube section 174.

O
The overall electrical system 188 of the process and apparatus is shown schematically in FIGURE 15 wherein the capacity for discrete applica-tion of voltage and current to each electrolytic tank 18, 20, 22, 24 can be seen. Con~en~ional rectifiers 189, 191, 193 and 195 are arranged as a D.C. power source to deliver current to the respect:ive contact rollers 100 on each electrolytic tank. Bus bars 104, 194/ 196, 198 are shown for illustration extending respectively from the rectifiers 189, 191, 193 and l9S to one of ~he six contact rollers 100 on the electrolytic tanks 18, 20, 22 and 24. However, all six contact rollers 100 on each electrolytic tank are directly connected to the same bus bar. Bus bars 106, 202, 204 and 206 are shown extending respectively from the same rectifiers 189, 191, 193 and 195 through cables 208 to one anode support bar 102 mounted on the electrolytic tanks 18, 20, 22 and 24.
Again the respective anode bus bars contact each anode support bar 102 mounted on each electrolytic tank connected to the bus bar.
As a result of the arrangement, discrete high voltage can be delivered to each electrolytic tank 18, 20, 22, 24 as a function of the metal plating on the ~i~ers in each electrolytic tank.
Practice has taught that the voltage in the first electrolyte tank 18 should not be below 16 volts and seldom be below 24 volts. ~he voltage in the second tank 20 should ~. ~Ei2~3~36 not be below 14 volts and the voltage in the third electro-light tank Z2 should not be below 12 volts.
Illustrative~y, fibers 2 have been coated in a system of three ~ectifier-electrolyte tank assemblies, rather than the four shown in FIGURES 1 and ~ under the following conditions whereln excellent coating has re-sulted:

AMPS 1,400 1,400 1,400 The nickel metal coated fibers 2 produced unde~
these conditions have the following properties and characteristics:
Filament Shape Round (but dependent on graphite fiber) Diameter 8 microns Metal Coa~ing Approximately 0.5 microns thic~, about 50% of the tot~l fiber weight.
Density 2.50-3.00 grams/cm.

- Tensile Strength Up to 450,000 psi Tensile Modulus 34 M psi r ~S.S,~"c~
~: J ~ Electrical~ 0O008 ohms/cm. (12R tow) Conductivity 0~10 ohms/1000 strands/cm.

After the nickel plating has occurred, the fully plated fibers 2 are delivered to the rinsing section ~ 12 seen in FIGUXE 1.

The drag-out section 42 and rinse section 46 are arranged with tanks to accumulate the discharge from the tees 44, 44A, 44B, 48 and 48A and both neutralize the discharge for waste disposal and provide a repository for accumulation of make-up fox the electrolyte tanks 18, 20, 22 and 24.

The apparatus of the present invention is arranged for synchronous operation as shown in FIGURES
16-18. A motor 222 is provided to insure that the contact rollers 100 and the guide rollers 51 rotate at the same speed to avoid abrading the fibers 2.

The motor 222 directly drives an assembly of rollers 223 arranged to effect a capstan. The rollers 223 are located in the dryer 14 and as best seen in FIGURE 17 cause the fiber to reverse direction six times.
The reversal in direction is sufficient to impose a force on the fibers 2 that will pull the fibers through the apparatus without allow~ng slack.

In addition, the motor 222 is connected by a gear and chain assembly to drive each contact roller 100 and each guide roller 51 at the same.speed.

In essence, the gear and chain assembly is com-prised of guide drive assemblies 225, best seen ln FIGURE 17 and contact roller drive assemblies 227.... Each guide drive assembly 225 includes drive transmission gear 230 mounted on shafts 231, a gear 224 fixedly secur-ed to the guide roller 51 and a chain 233 that engages the gears 230 and 224.

The contact roller drive assembly i~cludes drive transmission gear 239 mo~mted on the shafts 231 common to the gears 230, a gear 241 fixedly secured to each contact roller 100 and a chain 243 that engages both gears 239 and each of the gears 241 on the six contact rollers 100 associated with each electrolyte tank.

The location of the capstan rollers 223, seen in FIGURE 18, in the dryer 14 enhances drying. The flat surface and force applied to the fibers 2 spreads the fibers and thereby accelerates drying.

The system also includes a variable speed clutch override drive motor 219 for the take-up reels 17.
The force generated by the variable torque motor 219 pro-vides the force to draw the fiber 2 through the system.
However, the capstan rollers 223 provide a means to isolate the direct force imposed on the fibers 2 at the take-up reels 17 from the fibers 2 upstream of the capstan rollers.

Claims (7)

THE EMBODIMENTS OF THE INVENTION IN WHICH AN EXCLUSIVE
PROPERTY OR PRIVILEGE IS CLAIMED ARE DEFINED AS FOLLOWS:

1. A process for electroplating fiber comprising:
(a) continuously passing the fiber over a contact roller adapted to transmit high current into an electrolyte solution in a tank in which a metal anode is immersed;
(b) passing D.C. current at a minimum voltage of 10 volts through the fiber to the anode; and (c) imposing a tension on the fiber upstream of the contact roller by passing the fiber over an array of tension rollers in a path that reverses the direction of the fiber and rotating the tension rollers in the direction of the fiber at a speed equal to or less than the speed of the fiber to insure a direct tight path from the fiber at the contact roller to the electrolyte in the tank, whereby metal from the anode migrates to the fiber and is bonded thereto.

2. A process as in Claim 1 wherein the speed of the tension rollers is regulated as a function of the tension of the fiber.

3. A process as in Claim 1 further comprising the step of driving the contact roller in the same direction in which the fiber is travelling.

4. An apparatus for metal plating fiber, comprising:
(a) a D.C. rectifier;

- 25a - 611090-7297 (b) an electrolyte tank to which the rectifier delivers current;
(c) electrolyte in the electrolyte tank;
(d) a metal anode in the electrolyte;

(e) an electrolyte sprayed contact roller adapted to transmit high current immediately above the electrolyte surface;
(f) means for continuously passing fiber through the electro-lyte;
(g) means for delivering D.C. current from the rectifier through the fiber to the electrolyte; and (h) means for maintaining tension on the fiber to insure a direct tight path from the fiber at the contact point to the electrolyte in the tank, said means for maintaining tension on the fiber being an array of tensioning rollers located upstream of the contact member over which the fiber passes to reverse direction, and further comprising means to drive the array of rollers simult-aneously at the same speed in the direction of the fiber at a speed equal to or less than the speed of the fiber.

5. An apparatus as in Claim 4 wherein the means to drive the rollers is comprised of a gear on the shaft of each tensioning roller, a continuous chain passing over each gear, and a variable speed motor coupled to the continuos chain to drive the chain.

6. An apparatus as in Claim 5 wherein the contact member is a contact roller and further comprising means to rotate the contact roller in the direction of the fiber at the speed of the fiber.

7. An apparatus as in Claim 6 wherein the array of tension-ing rollers is comprised of five rollers.