CA1258370A - Heat-resisting supporting member - Google Patents
Heat-resisting supporting memberInfo
- Publication number
- CA1258370A CA1258370A CA000527417A CA527417A CA1258370A CA 1258370 A CA1258370 A CA 1258370A CA 000527417 A CA000527417 A CA 000527417A CA 527417 A CA527417 A CA 527417A CA 1258370 A CA1258370 A CA 1258370A
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- heat
- resisting
- ceramics
- supporting member
- alloys
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Abstract
ABSTRACT OF THE DISCLOSURE
The present invention relates to a heat-resisting sup-porting member, such as a skid button, for supporting a heated material, such as a steel plate, in a high-tempera-ture atmosphere within a heating furnace and the like and provides a heat-resisting supporting member in which a pe-ripheral surface of a lower corner portion of a supporting aggregate formed of heat-resisting alloys with single ceram-ics, ceramic particles or ceramic bars dispersed therein or heat-resisting alloy-impregnated ceramics formed by impreg-nating air-pores of porous ceramics with heat-resisting al-loys is coated with heat-resisting alloys so as to be capa-ble of being welded to other members while the remaining pe-ripheral surface of the supporting aggregate is coated with a shock-resisting substance formed of heat-resisting alloys, heat-resisting alloys with ceramic particles dispersed therein or heat-resisting alloy-impregnated ceramics. A
heat-resisting supporting member according to the present invention is superior in insulating property and high-temperature compression resistance.
The present invention relates to a heat-resisting sup-porting member, such as a skid button, for supporting a heated material, such as a steel plate, in a high-tempera-ture atmosphere within a heating furnace and the like and provides a heat-resisting supporting member in which a pe-ripheral surface of a lower corner portion of a supporting aggregate formed of heat-resisting alloys with single ceram-ics, ceramic particles or ceramic bars dispersed therein or heat-resisting alloy-impregnated ceramics formed by impreg-nating air-pores of porous ceramics with heat-resisting al-loys is coated with heat-resisting alloys so as to be capa-ble of being welded to other members while the remaining pe-ripheral surface of the supporting aggregate is coated with a shock-resisting substance formed of heat-resisting alloys, heat-resisting alloys with ceramic particles dispersed therein or heat-resisting alloy-impregnated ceramics. A
heat-resisting supporting member according to the present invention is superior in insulating property and high-temperature compression resistance.
Description
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TITLE OF THE INVENTION
HEAT-RESISTING SUPPORTING MEMBER
BACKGROUND OF THE INVENTION
Field of the Invention The present invention relates to a heat-resisting supporting member, such as a skid button, provided on an upper surface of a skid in a heating furnace for directlY
supporting a heated material such as a steel material.
Description of the Prior Art A steel material is transferred through an inside of a heating furnace to be heated at an appointed temperature.
A skid supports the steel material during the transportation of the steel material. The skid has such a construction that a skid pipe for passing a cooling water therethrough is provided with a skid button fixedlY mounted there on for di-rectly supporting the steel material and it is coated with an insulating material arranged along its periphery. And, this skid button must support the weight of .the steel mate-rial in an atmosphere of high temperature, so that it is necessary for the skid button to have a great compression-creep strength at higher temperature.
Accordingly, the skid button has been formed of heat-.
7~3 resisting steels or Co-base or Ni-Cr-base heat-resisting a]-loys or ceramics or composites comprising ceramics and metals.
It is necessarY for the skid button formed of heat-re-sisting steels or alloys to be frequently renewed since a creep-deformation is generated on an upper surface of the skid button after using it for a long time in an atmosphere of high temperature, whereby a useful life time of the skid button is shortened. And, in order to reduce such a creep-deformation, a cooling water has been passed through said skid pipe but a problem has occurred in that a temperature of a portion brought into contact with the steel material is lowered, whereby generating skid mark on the steel material.
In order to solve the above described problem, a skid button formed of ceramics has been proposed. However, the conventional skid button of this type has a construction that all of a surface brought into contact with a heated steel material is exposed to ceramics, so that a disadvan-tage has occurred in that a reaction makes proceed between the ceramics and oxidized scales or the atmosphere within the furnace to wear the ceramics. In addition, when the wear causes difference of elevation on the skid button, or when the steel material has a warping, a problem has occurred in that a shock load acts upon the skid button = ~
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during the transportation of the steel material, whereby the ceramics are broken and scattered. Besides7 the skid button formed of ceramics can not use the welding as a means of fixedly mounting it on the skid pipe, so that it has re-quired a special construction for fixedly mounting it on the skid pipe and has been expensive.
SUMMARY OF THE INVENTION
The present invention was achieved in view of the above described circumstances and thus it is a first object of the present invention to provide a heat-resisting suppor-ting member to which a superior insulating property, a superior high-temperature compression-creep strength and a long use-ful life time are imparted by coating at least a part o~ a peripheral surface of a lower corner portion of a supporting aggregate which is a core comprising ceramics with a heat-resisting alloy and by coating the remaining portion of said peripheral surface with a shock-resisting substance.
It is a second object of the present invention to pro-vide a heat-resisting member which can eliminate such disad-vantages of ceramics as the inferior shock-resistance and the wear due to the reaction between them and oxidized scales of a heated material or an atmosphere within a furnace by coating the peripheral surface of the supporting ~L258~
aggregate mainly comprising ceramics with a shock-resisting substance.
It is a third object of the present invention to pro-vide a heat-resisting supporting member which can be easilY
fixedly mounted on another member by coating at least a part of the peripheral surface of the lower corner portion of the supporting aggregate with a heat-resisling alloy.
It is a forth object of the present invention to pro-vide a heat~resisting supporting member to which a high-tem-perature compression-creep strength more superior to the heat-resisting alloy is imparted by using the heat-resisting alloy with ceramic particles dispersed therein or the mate-rial formed by impregnating porous ceramics having continu-ous air-pores with heat resisting alloys as the shock-resisting subs~ance.
It is a fifth object of the present invention to pro-vide a heat-resisting supporting member of which cost can be reduced by using a composite comprising ceramics and heat-resisting alloys as the supporting aggregate.
The above and further objects and features of the in-vention will more fully be apparent from the following detailed description with accompanying drawings.
BRIEF DESCRIPTION OF T~IE DRAWINGS
3'76D
Fig. 1 is a front longitudinal sectional view showing a first preferred embodiment of the presen~ invention;
Fig. 2 is a transverse sectional view showing a shape of ceramics as a supporting aggregate;
Fig. 3 is a longitudinal sectional view showing a shape of ceramics as a supporting aggregate;
Fig. 4 is a diagram showing a method of producing a skid button according to a first preferred embodiment of the present invention;
Figs. 5, 7, 8 are front longitudinal sectional views showing a second preferred embodiment of the present inven-tion;
Fig. 6 is a sectional view of the embodiment shown in Fig. S taken along a line vi-vi thereof;
Figs. 9, 11, 12, 13 are front longitudinal sectional views showing a third preferred embodiment of the present invention;
Fig. 10 is a sectional view of the embodiment shown in Fig. 9 taken along-a line x-x thereof;
Figs. 14, 15, 16, 1~ are front longitudinal sectional views showing a fourth preferred embodiment of the present invention; and Fig. 18 is a transverse sectional view of the embodi-ment shown in Fig. 17.
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DETAILED DESCRIPTION OF THE PREFERRED EMBO~]MENTS
The preferred embodiments of a skid button as a heat-resisting supporting member according to the present inven-tion will be described below with reference to the drawings.
At first, a skid button according to the first preferred em-bodiment o~ the present invention, in short a skid button, in which a supporting aggregate is formed of merely ceram-ics, is described. Referring now to Fig. 1 which is a front longitudina] sectional view showing a skid button according to the first preferred embodiment of the present invention, reference numeral 1 designates ceramics forming a supporting aggregate 10. All of a peripheral surface of a lower corner portion of the ceramics 1 is coated with a heat-resisting alloy 2 while the remaining peripheral surface is coated with a shock-resisting substance 3. In this preferred embo-diment, of the shock-resisting substance 3 portion position-ed at an upper portion and a lower portion of the skid but-ton are coated with heat-resisting alloy-impregnated ceram-ics 3a while the remaining portions are coated with a heat resisting alloy 3b. That is to say, in this preferred embo-diment the heat-resisting alloy-impregnated ceramics 3a serves to hold the ceramics 1 in the production of the skid button or to reinforce the shock-resisting substance 3 posi-tioned on the upper surface and the lower surface of the ce--. . ~
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ramics 1. In addition, reference numeral 4 designates a bedseat, 5 designating an insulating material, and 6 desiKnat-ing a skid pipe.
Now, the ceramics 1 are not limited at all in shape.
They may have a solid circular section as shown in Fig. 2 (a), a hollow circular section as shown in Fig. 2(b~, a po-lygonal section as shown in Fig. 2(c) and Fig. 2(d) and an oval section as shown in Fig. 2(e). Also the longitudinal section may be uniform in the direction of height as shown in Fig. 3(a), in the form in which the lower portion requir-ing the weldability is an inversed frustum of cone as shown in Fig. 3(b), barrel-shaped as shown in Fig. 3(c), trape-zoidal as shown in Fig. 3(d) and in the form in which the lower portion is partially hollowed, as shown in Fig. 3(e).
The shape of the longitudinal section of the ceramics 1 as shown in Fig. 3(e~ compensates the reduction of the strength against a horizontal force resulting from an in-crease of an area occupied by the ceramics 1 by the shock-resisting substance 3 existing in a hollow portion 17 of the lower portion and may be used together with the forms as shown in Fig. 3(a) to (d).
Next, the shock-resisting substance 3 is described.
The shock-resisting substance 3 is not limited at all in material but heat-resisting alloys, heat-resisting allo~s ~2~3~1 with ceramic particles dispersed therein or heat-resisting alloy-impregnated ceramics are PreferablY used. Besides, the shock-resisting substance 3 may be uniform all over the area to be coated or partially different. For example, an upper portion or both the upper portion and a lower portion of the skid button exhibiting a particularly remarkable high-temperature compression-creep deformation are coated with heat-resisting alloy-impregnated ceramics while the remaining portions are coated with heat-resisting alloys.
The heat-resisting alloy-impregnated ceramics have a three-dimensional frame structure, that is to say a struc-ture in which heat-resisting alloys are impregnated in air-pores of a ceramic foam as the porous ceramics having conti-nuous air-pores by the casting method. Since the heat-re-sisting alloy-impregnated ceramics are composites comprising ceramics and metals, they are superior to heat-resisting al-loys and the like in high-temperature compression-creep strength and the wear of ceramics resulting from the reac-tion between them and oxidized scales or an atmosphere with-in a furnace is remarkably reduced in comparison with heat-resisting alloys and the like.
The heat-resisting alloY-impregnated ceramics is pref-erable to contain air-pores at a ratio of 60 to ~0 %. 1{
the air-pores are contained at a ratio less than 60 %, the 837~
shoek-resistanee is redueed while the air-pores are contain-ed at a ratio larger than 80 %, the compression-resistance is deteriorated.
The heat-resisting alloys wiLh ceramic par~icles dis-persed therein are, for example, insulating alloys with ce-ramic particles having grain sizes of 1 to 5 mm eontained therein. The content of ceramic particles is preferable to be about 50 to 80 % bY volume. The reason of the above de-seribed is same as that of said porosity in the ceramic foam.
In addition, a thickness of the shock-resisting sub-stance 3 on the upper surface of the skid button is prefera-ble to be in a range from O.S cm to 2.0 cm. It is a reason of this that if the thickness of the shock-resisting sub-stance 3 is larger than 2.0 em, the high-temperature com-pression-ereep deformation oeeurs in the shoek-resisting substanee laYer of the upper surface of the skid button to bring about disadvantages similar to those in the conven-tional skid button formed of heat-resisting alloys while if it is less than 0.5 cm, the effect of coating the ceramics with the shock-resisting substance can not be exhibited.
In addition, in view of the coating property of the shock-resisting substance 3, the corner portions of the eeramics 1 as the supporting aggregate are preferably faced.
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Besides, in order to make the welding of the skid but-ton to the skid pipe 6 possible, it is desired that the same shape as that of the conventional skid button formed of heat-resisting alloys is imparted to the lower portion of the skid button and the shortest distance between the welded portion and the ceramics 1 is 15mm or more.
Next, a method of producing the skid button according to this first preferred embodiment will be described.
As shown in Fig. 4, the heat-resisting alloy-impre~-nated ceramic 3a and the ceramics l are installed within, for example, an aluminous mold 21. And, a gate portion 22 and a riser portion 23 are provided on said heat-resisting alloy-impregnated ceramic 3a. In addition, said gate portion 22 and said riser portion 23 are sealed at a circumference thereof so that a molten metal may not leak out.
The mold 21 under such a condition is placed in an electric furnace 24, which can be preheated up to tempera-ture of 1,300C or more, and heated at a temperature-rise ratio of sufficiently preventing said ceramics 1 from being worn by a thermal shock (200C/hr or less). After remaining at 1,300C for 2 hours, a Co-base heat-resisting alloy, for example, which has been molten in a separa-te furnace, is di-rectly poured into the mold 21 at temperature of 1,500C
from the upper portion of the electric furnace 24. After ii83~
cooling, the mold 21 is dismantled and the upPer and lower surfaces of the skid button are mechanicallY processed to some extent to obtain a finished skid button.
Next, the skid button according to the second preferred embodiment of the present invention, in short, the skid but-ton whose supporting aggregate is formed of a composite com-prising ceramics and heat-resisting alloys, will be describ-ed. The composite comprising ceramics and heat-resisting alloys is a ceramic bar assembly coated with heat-resisting alloys by molding, heat-resisting alloys with ceramic parti-cles dispersed therein or heat-resisting alloy-impregnated ceramics. Fig. 5 is a front longitudinal sectional view showing one example of a skid button according to the second preferred embodiment and Fig. 6 is a sectional view of Fig.
5 taken along a line vi-vi thereof. In this example, a sup-porting aggregate 10 is obtained by tying up a large number of ceramic bars 11 in a bundle and coating the bundle with heat-resisting alloys by molding, all peripheral surface of the lower corner portion of said supporting aggregate 10 be-ing coated with the heat-resisting alloy 2 while all of the remaining peripheral surface of said supporting aggregate 10 is coated with the shock-resisting substance 3.
In the example as shown in Fig. 5, although the shock-resisting substance 3 is coated on merely the side surface of the peripheral portion and not coated on the upper sur-face of the supporting aggregate, it goes without saying that also the upper surface of the supporting aggregate had better be coated with the shock-resisting substance 3.
Besides, although it is thought that the ceramic bars 11 exposed on the upper surface of the supporting aggregate have a problem in shock-resisting strength and the wear re-sulting from the reaction between ceramics and an atmosphere within a furnace in this example, since the heat-resisting alloys surrounding these ceramic bars 11 cover the upper end of said ceramic bars 11 by the use of the skid button in the case where the upper end of the ceramic bars 11 is broken or worn, thereafter the breakage bY a shock and the wear by the reaction of ceramics can be prevented leaving no problem in use.
The heat-resisting alloys with ceramic bars dispersed therein include, for example, heat-resisting alloys with ce-ramic bars having diameters of 5 to 10 mm and formed of high-strength compact A1203 standing therein. ln this case, an area ratio of the ceramic bars is preferable to be about 25 to 75 ~. That is to say, provided that a load of about 1 ton is applied to each skid button and at worst one piece of ceramic bars receives this load of 1 ton, a diameter of at least 5 mm is required. In addition, in view of the wear by ~ ~58~7~
a shock, the allowable maximum diameter is about 10 mm. Be-sides, it is the reason why said range of area ratio is de-sirable that in order to disperse a shock a~s far as possible to suppress the wear by a shock, an area ratio of at least 25 ~ is required while in order to meet the requirements of an effective thermal insulation and the existence of the heat-resisting alloy layer to some extent among the ceramic bars for sufficiently restraining the ceramic bars by dint of the shock-resisting substance surrounding the ceramic bars, the area ratio of the ceramic bars must not exceed 75 .
The production of the skid button shown in Fig. 5 is performed as follows:
A large number of ceramic bars are tied in a bundle and the resulting bundle is set in the mold. The mold is placed in the electric furnace which can be preheated up to 1,300C, and lhen heated at a temperature-rise ratio of preventing the ceramic bars from being worn by a thermal shock (200C/hr or less). After remaining at 1,300C for 2 hours, a Co-base heat-resisting alloy, for example, which has been molten in a separate furnace, is Poured into the mold at a temperature of 1,500C from the upper portion of the electric furnace. After cooling, the mold is dismantled to obtain the supporting aggregate.
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Subse~uently9 the resulting supporting aggregate is set within the mold and the heat-resisting alloy is molded in the same order as described in the first preferred embodi-ment, and then after cooling, the mold is dismantled and the upper and lower surfaces of the skid button are subjected to a mechanical processing to some extent to obtain a finished skid button.
Figs. 7, 8 are front longitudinal sectional views show-ing another example of the skid button according to the sec-ond preferred embodiment. In these examples heat-resisting alloys with ceramic particles dispersed therein are used as the supporting aggregate 10 and the remaining structure is same as shown in the preferred embodiment shown in Fig. 5.
In addition, in the preferred embodiment shown in Fig. 8, the upper surface of the supporting aggregate 10 is coated with, for example, the heat-resisting alloy-impregnated ce-ramic 3a.
Besides, it is desired that an incorporation ratio of ceramics in the supporting aggregate is 50 ~ or more in av-erage in the direction of height in a transverse section of the skid button in area-occupation ratio. This value of 60 % is obtained on the basis of the strength and insulating property of the skid button. If this value is less than 50 %, the desired strength and insulating propertY can not be 37~
obtained and an effective reduction of skid rnarks can not be achieved. In addition, the shock-resisting substance used for this second preferred embodiment of the skid button is same as that used for the first preferred embodiment.
In this second preferred embodiment, since the support-ing aggregate is formed of a composite comprising ceramics and heat-resisting alloys, the cost can be reduced in compa-rison with the first preferred embodiment in which the sup-porting aggregate is formed of merely ceramics.
Next, the skid button according to the third preferred embodiment of the present invention, in short, the skid but-ton, in which the supporting aggregate is formed of a compo-site comprising a plurality of plates cylindrical or bar ce-ramics and heat-resisting alloys interposed among the ceram-ics, will be described. Fig. 9 is a front longitudinal sec-tional view showing one example of the skid button according to this third preferred embodiment and Fig. 10 is a section-al view of Fig. 9 taken along a line x-x thereof. Referring to ~igs. 9, lO, reference numeral 12 designates a corrugated sheet-like ceramic. The supporting aggregate 10 is con-structed from a plurality of said corrugated sheet-like ce-ramics 12 disposed at suitable intervals and coated with a heat-resisting alloy 13 by molding. And, in the skid button according to this example, although all of the peripheral ~:~5~33~
surface of the lower corner portion of the supporting aggre-gate 10 is coated with a heat-resis~ing alloy while all of the remaining peripheral surface of the supporting aggregate 10 is coated with a shock-resisting substance, in this exam-ple shown in Fig. 9, the heat-resisting alloy 13 construct-ing ~he supporting aggregate 10 is used as both the heat-re-sisting alloy coating all of the peripheral surface of the lower corner portion of the supporting aggregate 10 and the shock-resisting substance coating all of the remaining pe-ripheral surface of the supporting aggregate 10.
It is desired that the incorporation ratio of ceramics as the main ingredient in the supporting aggregate is in av-erage 30 to 80 % in the direction of height in area-occupa-tion ratio of ceram~cs in a transverse section of the skid button. These values of 30 % and 80 % are determined on the basis of the strength and insulating property of the skid button and the incorporation ratio of ceramics less than 30 % leads to the insufficient strength and insulating property of the skid button, whereby the effective reduction of skid marks can not be achieved. In addition, the incorpo-ration ratio of ceramics in the supporting aggregate larger than 80 % leads to the reduction of the restriction for ce~
ramics, whereby the strength of the skid button is reduced.
Figs. 11, 12, 13 are transverse sectional views showing ~583~7~
other examples of the skid button according to the third preferred embodiment. Referring to Fig. 11, cylindrical ce-ramics 14 having different diameters concentrically arranged and coated with the heat-resisting alloy 13 by molding are used as the supporting ag~regate 10.
Referring to Fig. 12, the cylindrical ceramics 14 with a plurality of corrugated sheet-like ceramics 12 arranged therein at suitable intervals and coated with the heat-re-sisting alloy 13 are used as the supporting aggregate lO.
Referring ~o Fig. 13, ceramic bars 11 are arranged at a central portion of the supporting aggregate lO as shown in Fig. ll.
In addition, flat plate-like ceramics (not shown~ may be used in place of the corrugated sheet~like ceramics shown in Figs. 9(10), 12.
Besides, although all of the peripheral surface is coated with the heat-resisting alloy in the above described preferred embodiments, only the side surface of the periph-eral portion may be coated with the heat-resisting alloy without coating the upper surface.
It goes without saying that the shock-resisting sub stance may be formed of a material different from lhe heat-resisting alloy 13, as described in the first or second pre-ferred embodiment, without using the heat-resisting allo~ 13 ~2S~337~
as both the heat-resisting alloy coating all of the periph-eral surface of t~le lower corner portion and the shock-re-sisting substance coating the remaining portion.
Next, a method of producing the skid button according to the third preferred embodiment (Fig. 9) will be describ-ed.
The ceramics are arranged in a mold and a heating gas is supplied in the mold through a gate to preheat the ceram-ics up to about 1,200~C. It goes without saying that the ceramics are heated at a temperature-rise rate of preventing the ceramics from being worn by a thermal shock (200C/hr or less). After remaining at such a temperature for 2 hours, a Co-base heat-resisting alloy, for example, which has been molten in a separate furnace, is poured into the mold.
After cooling, .the mold is dismantled to obtain the support-ing aggregate. In this preferred embodiment, since the heat-resisting alloy constructing the supporting aggregate is used as both the shock-resisting substance and the heat-resisting alloy for coating the peripheral surface of the supporting aggregate, it is necessary only to form the sup-porting aggregate in a size of the skid button.
Next, the skid button according to the fourth preferred embodiment of the present invention, in short, the skid but-ton, in which the supporting aggrega~e is integrated with 1~
~25~37~P
the shock-resisting substance and they are formed of the same material, will be described. Ceramic particles, heat-resisting alloys with ceramic bars dispersed therein or heat-resisting alloy-impregnated ceramics are used as mate-rials for forming the supporting aggregate and the shock-resisting substance.
In Fig. 14, the heat-resisting alloy 2 is provided in the central portion and the lower end portion below the vi-cinity of the central portion in the direction of height, whereby improving the shock resistance even though the insu-lating property is sacrificed to some extent. In addition, in Fig. 15, the heat-resisting alloy 2 is provided only in the lower end portion to aim at only the improvement of the weldability. And, since the supporting aggregate can be produced by integrally molding the heat-resisting alloy 2 and the heat-resisting alloy 15 with ceramic particles dis-persed therein in these preferred embodiments shown in Figs.
14, 15, the reduction of the strength does not occur in the boundary portion of both heat-resisting alloys 2, 15.
Furthermore, in Fig. 16, the boundary portion of said heat-resisting alloys ~, 15 is formed so as to be engageable with each other and the supporting aggregate is produced by coating the heat-resisting alloy 15 with ceramic particles dispersed therein previously molded in the appointed shape ~25~3~
with the heat-resisting alloy 2 by molding, whereby prevent-ing the heat-resisting alloy 15 with ceramic particles dis-persed therein from escaping and improving the weldability of the skid button.
In Figs, 17, 18, the peripheral side surface nf a heat-resisting alloy 16 with the ceramic bars 11 dispersed there-in is coated with the heat-resisting alloy 2.
Also in this preferred embodiment, since the ceramic particles or the ceramic bars are exposed on the upper sur-face, a problem seems to occur in points of the shock re-sistance and the wear of ceramics by the reaction but in face no problem occurs on account of the reason being same as described in the second preferred embodiment.
The production of the skid button according to the pre-ferred embodiment shown in Fig. 17 is carried out as fol-lows:
At first, the ceramic bars are arranged in a dispersedmanner in a mold at the desired intervals, and then the mold is placed within an electric furnace, which can be preheated up to 1,300C or more, for example, and heated at a tempera-ture-rise rate of preventing the ceramic bars from being worn by the thermal shock (200C/hr or less). After remain-ing at such a temperature for 2 hours, a Co-base heat-re-sisting alloy, for example, which has been molten in a sepa-~:~5~3'7C~
rate furnace, i5 poured into the mold at a temperature of1,500C from the upper portion of the electric furnace.
After cooling, the mold is dismantled and the upper and low-er surfaces of the skid button are subjected to the mecha-nical processing to some extent to produce the skid button.
And, in this preferred embodiment, since the supporting aggregate, the shock-resisting substance and the heat-re-sisting alloy on the corner portion are integrallY molded, they are easy to produce.
Besides, although in the above described four kinds of preferred embodiment, all of the peripheral surface of the lower corner portion of the supporting aggregate is coated with the heat-resisting alloy, a part of the peripheral sur-face of -the corner portion may be coated with the heat-re-sisting alloy if the welding is possible.
Next, the characteristics of the skid button according to the present invention are described.
(1) Insulating property Since ceramics superior to metals in insulating proper-ty are used as the main ingredient of the supporting aggre-gate, the skid button according to the present invention ex-hibits a superior insulating property. Although a less heat conductivity of the ceramics used is more desirable, the ex-periments by the present inventor have shown that a highly 3L2~33~
effective reduction o:f skid marks can be achieved in the case where the ceramics having a heat conductivity of at least 1/3 time that of metals or less are used.
TITLE OF THE INVENTION
HEAT-RESISTING SUPPORTING MEMBER
BACKGROUND OF THE INVENTION
Field of the Invention The present invention relates to a heat-resisting supporting member, such as a skid button, provided on an upper surface of a skid in a heating furnace for directlY
supporting a heated material such as a steel material.
Description of the Prior Art A steel material is transferred through an inside of a heating furnace to be heated at an appointed temperature.
A skid supports the steel material during the transportation of the steel material. The skid has such a construction that a skid pipe for passing a cooling water therethrough is provided with a skid button fixedlY mounted there on for di-rectly supporting the steel material and it is coated with an insulating material arranged along its periphery. And, this skid button must support the weight of .the steel mate-rial in an atmosphere of high temperature, so that it is necessary for the skid button to have a great compression-creep strength at higher temperature.
Accordingly, the skid button has been formed of heat-.
7~3 resisting steels or Co-base or Ni-Cr-base heat-resisting a]-loys or ceramics or composites comprising ceramics and metals.
It is necessarY for the skid button formed of heat-re-sisting steels or alloys to be frequently renewed since a creep-deformation is generated on an upper surface of the skid button after using it for a long time in an atmosphere of high temperature, whereby a useful life time of the skid button is shortened. And, in order to reduce such a creep-deformation, a cooling water has been passed through said skid pipe but a problem has occurred in that a temperature of a portion brought into contact with the steel material is lowered, whereby generating skid mark on the steel material.
In order to solve the above described problem, a skid button formed of ceramics has been proposed. However, the conventional skid button of this type has a construction that all of a surface brought into contact with a heated steel material is exposed to ceramics, so that a disadvan-tage has occurred in that a reaction makes proceed between the ceramics and oxidized scales or the atmosphere within the furnace to wear the ceramics. In addition, when the wear causes difference of elevation on the skid button, or when the steel material has a warping, a problem has occurred in that a shock load acts upon the skid button = ~
~ 25i~3~7~
during the transportation of the steel material, whereby the ceramics are broken and scattered. Besides7 the skid button formed of ceramics can not use the welding as a means of fixedly mounting it on the skid pipe, so that it has re-quired a special construction for fixedly mounting it on the skid pipe and has been expensive.
SUMMARY OF THE INVENTION
The present invention was achieved in view of the above described circumstances and thus it is a first object of the present invention to provide a heat-resisting suppor-ting member to which a superior insulating property, a superior high-temperature compression-creep strength and a long use-ful life time are imparted by coating at least a part o~ a peripheral surface of a lower corner portion of a supporting aggregate which is a core comprising ceramics with a heat-resisting alloy and by coating the remaining portion of said peripheral surface with a shock-resisting substance.
It is a second object of the present invention to pro-vide a heat-resisting member which can eliminate such disad-vantages of ceramics as the inferior shock-resistance and the wear due to the reaction between them and oxidized scales of a heated material or an atmosphere within a furnace by coating the peripheral surface of the supporting ~L258~
aggregate mainly comprising ceramics with a shock-resisting substance.
It is a third object of the present invention to pro-vide a heat-resisting supporting member which can be easilY
fixedly mounted on another member by coating at least a part of the peripheral surface of the lower corner portion of the supporting aggregate with a heat-resisling alloy.
It is a forth object of the present invention to pro-vide a heat~resisting supporting member to which a high-tem-perature compression-creep strength more superior to the heat-resisting alloy is imparted by using the heat-resisting alloy with ceramic particles dispersed therein or the mate-rial formed by impregnating porous ceramics having continu-ous air-pores with heat resisting alloys as the shock-resisting subs~ance.
It is a fifth object of the present invention to pro-vide a heat-resisting supporting member of which cost can be reduced by using a composite comprising ceramics and heat-resisting alloys as the supporting aggregate.
The above and further objects and features of the in-vention will more fully be apparent from the following detailed description with accompanying drawings.
BRIEF DESCRIPTION OF T~IE DRAWINGS
3'76D
Fig. 1 is a front longitudinal sectional view showing a first preferred embodiment of the presen~ invention;
Fig. 2 is a transverse sectional view showing a shape of ceramics as a supporting aggregate;
Fig. 3 is a longitudinal sectional view showing a shape of ceramics as a supporting aggregate;
Fig. 4 is a diagram showing a method of producing a skid button according to a first preferred embodiment of the present invention;
Figs. 5, 7, 8 are front longitudinal sectional views showing a second preferred embodiment of the present inven-tion;
Fig. 6 is a sectional view of the embodiment shown in Fig. S taken along a line vi-vi thereof;
Figs. 9, 11, 12, 13 are front longitudinal sectional views showing a third preferred embodiment of the present invention;
Fig. 10 is a sectional view of the embodiment shown in Fig. 9 taken along-a line x-x thereof;
Figs. 14, 15, 16, 1~ are front longitudinal sectional views showing a fourth preferred embodiment of the present invention; and Fig. 18 is a transverse sectional view of the embodi-ment shown in Fig. 17.
~25~37~
DETAILED DESCRIPTION OF THE PREFERRED EMBO~]MENTS
The preferred embodiments of a skid button as a heat-resisting supporting member according to the present inven-tion will be described below with reference to the drawings.
At first, a skid button according to the first preferred em-bodiment o~ the present invention, in short a skid button, in which a supporting aggregate is formed of merely ceram-ics, is described. Referring now to Fig. 1 which is a front longitudina] sectional view showing a skid button according to the first preferred embodiment of the present invention, reference numeral 1 designates ceramics forming a supporting aggregate 10. All of a peripheral surface of a lower corner portion of the ceramics 1 is coated with a heat-resisting alloy 2 while the remaining peripheral surface is coated with a shock-resisting substance 3. In this preferred embo-diment, of the shock-resisting substance 3 portion position-ed at an upper portion and a lower portion of the skid but-ton are coated with heat-resisting alloy-impregnated ceram-ics 3a while the remaining portions are coated with a heat resisting alloy 3b. That is to say, in this preferred embo-diment the heat-resisting alloy-impregnated ceramics 3a serves to hold the ceramics 1 in the production of the skid button or to reinforce the shock-resisting substance 3 posi-tioned on the upper surface and the lower surface of the ce--. . ~
~2~37~
ramics 1. In addition, reference numeral 4 designates a bedseat, 5 designating an insulating material, and 6 desiKnat-ing a skid pipe.
Now, the ceramics 1 are not limited at all in shape.
They may have a solid circular section as shown in Fig. 2 (a), a hollow circular section as shown in Fig. 2(b~, a po-lygonal section as shown in Fig. 2(c) and Fig. 2(d) and an oval section as shown in Fig. 2(e). Also the longitudinal section may be uniform in the direction of height as shown in Fig. 3(a), in the form in which the lower portion requir-ing the weldability is an inversed frustum of cone as shown in Fig. 3(b), barrel-shaped as shown in Fig. 3(c), trape-zoidal as shown in Fig. 3(d) and in the form in which the lower portion is partially hollowed, as shown in Fig. 3(e).
The shape of the longitudinal section of the ceramics 1 as shown in Fig. 3(e~ compensates the reduction of the strength against a horizontal force resulting from an in-crease of an area occupied by the ceramics 1 by the shock-resisting substance 3 existing in a hollow portion 17 of the lower portion and may be used together with the forms as shown in Fig. 3(a) to (d).
Next, the shock-resisting substance 3 is described.
The shock-resisting substance 3 is not limited at all in material but heat-resisting alloys, heat-resisting allo~s ~2~3~1 with ceramic particles dispersed therein or heat-resisting alloy-impregnated ceramics are PreferablY used. Besides, the shock-resisting substance 3 may be uniform all over the area to be coated or partially different. For example, an upper portion or both the upper portion and a lower portion of the skid button exhibiting a particularly remarkable high-temperature compression-creep deformation are coated with heat-resisting alloy-impregnated ceramics while the remaining portions are coated with heat-resisting alloys.
The heat-resisting alloy-impregnated ceramics have a three-dimensional frame structure, that is to say a struc-ture in which heat-resisting alloys are impregnated in air-pores of a ceramic foam as the porous ceramics having conti-nuous air-pores by the casting method. Since the heat-re-sisting alloy-impregnated ceramics are composites comprising ceramics and metals, they are superior to heat-resisting al-loys and the like in high-temperature compression-creep strength and the wear of ceramics resulting from the reac-tion between them and oxidized scales or an atmosphere with-in a furnace is remarkably reduced in comparison with heat-resisting alloys and the like.
The heat-resisting alloY-impregnated ceramics is pref-erable to contain air-pores at a ratio of 60 to ~0 %. 1{
the air-pores are contained at a ratio less than 60 %, the 837~
shoek-resistanee is redueed while the air-pores are contain-ed at a ratio larger than 80 %, the compression-resistance is deteriorated.
The heat-resisting alloys wiLh ceramic par~icles dis-persed therein are, for example, insulating alloys with ce-ramic particles having grain sizes of 1 to 5 mm eontained therein. The content of ceramic particles is preferable to be about 50 to 80 % bY volume. The reason of the above de-seribed is same as that of said porosity in the ceramic foam.
In addition, a thickness of the shock-resisting sub-stance 3 on the upper surface of the skid button is prefera-ble to be in a range from O.S cm to 2.0 cm. It is a reason of this that if the thickness of the shock-resisting sub-stance 3 is larger than 2.0 em, the high-temperature com-pression-ereep deformation oeeurs in the shoek-resisting substanee laYer of the upper surface of the skid button to bring about disadvantages similar to those in the conven-tional skid button formed of heat-resisting alloys while if it is less than 0.5 cm, the effect of coating the ceramics with the shock-resisting substance can not be exhibited.
In addition, in view of the coating property of the shock-resisting substance 3, the corner portions of the eeramics 1 as the supporting aggregate are preferably faced.
3~
Besides, in order to make the welding of the skid but-ton to the skid pipe 6 possible, it is desired that the same shape as that of the conventional skid button formed of heat-resisting alloys is imparted to the lower portion of the skid button and the shortest distance between the welded portion and the ceramics 1 is 15mm or more.
Next, a method of producing the skid button according to this first preferred embodiment will be described.
As shown in Fig. 4, the heat-resisting alloy-impre~-nated ceramic 3a and the ceramics l are installed within, for example, an aluminous mold 21. And, a gate portion 22 and a riser portion 23 are provided on said heat-resisting alloy-impregnated ceramic 3a. In addition, said gate portion 22 and said riser portion 23 are sealed at a circumference thereof so that a molten metal may not leak out.
The mold 21 under such a condition is placed in an electric furnace 24, which can be preheated up to tempera-ture of 1,300C or more, and heated at a temperature-rise ratio of sufficiently preventing said ceramics 1 from being worn by a thermal shock (200C/hr or less). After remaining at 1,300C for 2 hours, a Co-base heat-resisting alloy, for example, which has been molten in a separa-te furnace, is di-rectly poured into the mold 21 at temperature of 1,500C
from the upper portion of the electric furnace 24. After ii83~
cooling, the mold 21 is dismantled and the upPer and lower surfaces of the skid button are mechanicallY processed to some extent to obtain a finished skid button.
Next, the skid button according to the second preferred embodiment of the present invention, in short, the skid but-ton whose supporting aggregate is formed of a composite com-prising ceramics and heat-resisting alloys, will be describ-ed. The composite comprising ceramics and heat-resisting alloys is a ceramic bar assembly coated with heat-resisting alloys by molding, heat-resisting alloys with ceramic parti-cles dispersed therein or heat-resisting alloy-impregnated ceramics. Fig. 5 is a front longitudinal sectional view showing one example of a skid button according to the second preferred embodiment and Fig. 6 is a sectional view of Fig.
5 taken along a line vi-vi thereof. In this example, a sup-porting aggregate 10 is obtained by tying up a large number of ceramic bars 11 in a bundle and coating the bundle with heat-resisting alloys by molding, all peripheral surface of the lower corner portion of said supporting aggregate 10 be-ing coated with the heat-resisting alloy 2 while all of the remaining peripheral surface of said supporting aggregate 10 is coated with the shock-resisting substance 3.
In the example as shown in Fig. 5, although the shock-resisting substance 3 is coated on merely the side surface of the peripheral portion and not coated on the upper sur-face of the supporting aggregate, it goes without saying that also the upper surface of the supporting aggregate had better be coated with the shock-resisting substance 3.
Besides, although it is thought that the ceramic bars 11 exposed on the upper surface of the supporting aggregate have a problem in shock-resisting strength and the wear re-sulting from the reaction between ceramics and an atmosphere within a furnace in this example, since the heat-resisting alloys surrounding these ceramic bars 11 cover the upper end of said ceramic bars 11 by the use of the skid button in the case where the upper end of the ceramic bars 11 is broken or worn, thereafter the breakage bY a shock and the wear by the reaction of ceramics can be prevented leaving no problem in use.
The heat-resisting alloys with ceramic bars dispersed therein include, for example, heat-resisting alloys with ce-ramic bars having diameters of 5 to 10 mm and formed of high-strength compact A1203 standing therein. ln this case, an area ratio of the ceramic bars is preferable to be about 25 to 75 ~. That is to say, provided that a load of about 1 ton is applied to each skid button and at worst one piece of ceramic bars receives this load of 1 ton, a diameter of at least 5 mm is required. In addition, in view of the wear by ~ ~58~7~
a shock, the allowable maximum diameter is about 10 mm. Be-sides, it is the reason why said range of area ratio is de-sirable that in order to disperse a shock a~s far as possible to suppress the wear by a shock, an area ratio of at least 25 ~ is required while in order to meet the requirements of an effective thermal insulation and the existence of the heat-resisting alloy layer to some extent among the ceramic bars for sufficiently restraining the ceramic bars by dint of the shock-resisting substance surrounding the ceramic bars, the area ratio of the ceramic bars must not exceed 75 .
The production of the skid button shown in Fig. 5 is performed as follows:
A large number of ceramic bars are tied in a bundle and the resulting bundle is set in the mold. The mold is placed in the electric furnace which can be preheated up to 1,300C, and lhen heated at a temperature-rise ratio of preventing the ceramic bars from being worn by a thermal shock (200C/hr or less). After remaining at 1,300C for 2 hours, a Co-base heat-resisting alloy, for example, which has been molten in a separate furnace, is Poured into the mold at a temperature of 1,500C from the upper portion of the electric furnace. After cooling, the mold is dismantled to obtain the supporting aggregate.
37~
Subse~uently9 the resulting supporting aggregate is set within the mold and the heat-resisting alloy is molded in the same order as described in the first preferred embodi-ment, and then after cooling, the mold is dismantled and the upper and lower surfaces of the skid button are subjected to a mechanical processing to some extent to obtain a finished skid button.
Figs. 7, 8 are front longitudinal sectional views show-ing another example of the skid button according to the sec-ond preferred embodiment. In these examples heat-resisting alloys with ceramic particles dispersed therein are used as the supporting aggregate 10 and the remaining structure is same as shown in the preferred embodiment shown in Fig. 5.
In addition, in the preferred embodiment shown in Fig. 8, the upper surface of the supporting aggregate 10 is coated with, for example, the heat-resisting alloy-impregnated ce-ramic 3a.
Besides, it is desired that an incorporation ratio of ceramics in the supporting aggregate is 50 ~ or more in av-erage in the direction of height in a transverse section of the skid button in area-occupation ratio. This value of 60 % is obtained on the basis of the strength and insulating property of the skid button. If this value is less than 50 %, the desired strength and insulating propertY can not be 37~
obtained and an effective reduction of skid rnarks can not be achieved. In addition, the shock-resisting substance used for this second preferred embodiment of the skid button is same as that used for the first preferred embodiment.
In this second preferred embodiment, since the support-ing aggregate is formed of a composite comprising ceramics and heat-resisting alloys, the cost can be reduced in compa-rison with the first preferred embodiment in which the sup-porting aggregate is formed of merely ceramics.
Next, the skid button according to the third preferred embodiment of the present invention, in short, the skid but-ton, in which the supporting aggregate is formed of a compo-site comprising a plurality of plates cylindrical or bar ce-ramics and heat-resisting alloys interposed among the ceram-ics, will be described. Fig. 9 is a front longitudinal sec-tional view showing one example of the skid button according to this third preferred embodiment and Fig. 10 is a section-al view of Fig. 9 taken along a line x-x thereof. Referring to ~igs. 9, lO, reference numeral 12 designates a corrugated sheet-like ceramic. The supporting aggregate 10 is con-structed from a plurality of said corrugated sheet-like ce-ramics 12 disposed at suitable intervals and coated with a heat-resisting alloy 13 by molding. And, in the skid button according to this example, although all of the peripheral ~:~5~33~
surface of the lower corner portion of the supporting aggre-gate 10 is coated with a heat-resis~ing alloy while all of the remaining peripheral surface of the supporting aggregate 10 is coated with a shock-resisting substance, in this exam-ple shown in Fig. 9, the heat-resisting alloy 13 construct-ing ~he supporting aggregate 10 is used as both the heat-re-sisting alloy coating all of the peripheral surface of the lower corner portion of the supporting aggregate 10 and the shock-resisting substance coating all of the remaining pe-ripheral surface of the supporting aggregate 10.
It is desired that the incorporation ratio of ceramics as the main ingredient in the supporting aggregate is in av-erage 30 to 80 % in the direction of height in area-occupa-tion ratio of ceram~cs in a transverse section of the skid button. These values of 30 % and 80 % are determined on the basis of the strength and insulating property of the skid button and the incorporation ratio of ceramics less than 30 % leads to the insufficient strength and insulating property of the skid button, whereby the effective reduction of skid marks can not be achieved. In addition, the incorpo-ration ratio of ceramics in the supporting aggregate larger than 80 % leads to the reduction of the restriction for ce~
ramics, whereby the strength of the skid button is reduced.
Figs. 11, 12, 13 are transverse sectional views showing ~583~7~
other examples of the skid button according to the third preferred embodiment. Referring to Fig. 11, cylindrical ce-ramics 14 having different diameters concentrically arranged and coated with the heat-resisting alloy 13 by molding are used as the supporting ag~regate 10.
Referring to Fig. 12, the cylindrical ceramics 14 with a plurality of corrugated sheet-like ceramics 12 arranged therein at suitable intervals and coated with the heat-re-sisting alloy 13 are used as the supporting aggregate lO.
Referring ~o Fig. 13, ceramic bars 11 are arranged at a central portion of the supporting aggregate lO as shown in Fig. ll.
In addition, flat plate-like ceramics (not shown~ may be used in place of the corrugated sheet~like ceramics shown in Figs. 9(10), 12.
Besides, although all of the peripheral surface is coated with the heat-resisting alloy in the above described preferred embodiments, only the side surface of the periph-eral portion may be coated with the heat-resisting alloy without coating the upper surface.
It goes without saying that the shock-resisting sub stance may be formed of a material different from lhe heat-resisting alloy 13, as described in the first or second pre-ferred embodiment, without using the heat-resisting allo~ 13 ~2S~337~
as both the heat-resisting alloy coating all of the periph-eral surface of t~le lower corner portion and the shock-re-sisting substance coating the remaining portion.
Next, a method of producing the skid button according to the third preferred embodiment (Fig. 9) will be describ-ed.
The ceramics are arranged in a mold and a heating gas is supplied in the mold through a gate to preheat the ceram-ics up to about 1,200~C. It goes without saying that the ceramics are heated at a temperature-rise rate of preventing the ceramics from being worn by a thermal shock (200C/hr or less). After remaining at such a temperature for 2 hours, a Co-base heat-resisting alloy, for example, which has been molten in a separate furnace, is poured into the mold.
After cooling, .the mold is dismantled to obtain the support-ing aggregate. In this preferred embodiment, since the heat-resisting alloy constructing the supporting aggregate is used as both the shock-resisting substance and the heat-resisting alloy for coating the peripheral surface of the supporting aggregate, it is necessary only to form the sup-porting aggregate in a size of the skid button.
Next, the skid button according to the fourth preferred embodiment of the present invention, in short, the skid but-ton, in which the supporting aggrega~e is integrated with 1~
~25~37~P
the shock-resisting substance and they are formed of the same material, will be described. Ceramic particles, heat-resisting alloys with ceramic bars dispersed therein or heat-resisting alloy-impregnated ceramics are used as mate-rials for forming the supporting aggregate and the shock-resisting substance.
In Fig. 14, the heat-resisting alloy 2 is provided in the central portion and the lower end portion below the vi-cinity of the central portion in the direction of height, whereby improving the shock resistance even though the insu-lating property is sacrificed to some extent. In addition, in Fig. 15, the heat-resisting alloy 2 is provided only in the lower end portion to aim at only the improvement of the weldability. And, since the supporting aggregate can be produced by integrally molding the heat-resisting alloy 2 and the heat-resisting alloy 15 with ceramic particles dis-persed therein in these preferred embodiments shown in Figs.
14, 15, the reduction of the strength does not occur in the boundary portion of both heat-resisting alloys 2, 15.
Furthermore, in Fig. 16, the boundary portion of said heat-resisting alloys ~, 15 is formed so as to be engageable with each other and the supporting aggregate is produced by coating the heat-resisting alloy 15 with ceramic particles dispersed therein previously molded in the appointed shape ~25~3~
with the heat-resisting alloy 2 by molding, whereby prevent-ing the heat-resisting alloy 15 with ceramic particles dis-persed therein from escaping and improving the weldability of the skid button.
In Figs, 17, 18, the peripheral side surface nf a heat-resisting alloy 16 with the ceramic bars 11 dispersed there-in is coated with the heat-resisting alloy 2.
Also in this preferred embodiment, since the ceramic particles or the ceramic bars are exposed on the upper sur-face, a problem seems to occur in points of the shock re-sistance and the wear of ceramics by the reaction but in face no problem occurs on account of the reason being same as described in the second preferred embodiment.
The production of the skid button according to the pre-ferred embodiment shown in Fig. 17 is carried out as fol-lows:
At first, the ceramic bars are arranged in a dispersedmanner in a mold at the desired intervals, and then the mold is placed within an electric furnace, which can be preheated up to 1,300C or more, for example, and heated at a tempera-ture-rise rate of preventing the ceramic bars from being worn by the thermal shock (200C/hr or less). After remain-ing at such a temperature for 2 hours, a Co-base heat-re-sisting alloy, for example, which has been molten in a sepa-~:~5~3'7C~
rate furnace, i5 poured into the mold at a temperature of1,500C from the upper portion of the electric furnace.
After cooling, the mold is dismantled and the upper and low-er surfaces of the skid button are subjected to the mecha-nical processing to some extent to produce the skid button.
And, in this preferred embodiment, since the supporting aggregate, the shock-resisting substance and the heat-re-sisting alloy on the corner portion are integrallY molded, they are easy to produce.
Besides, although in the above described four kinds of preferred embodiment, all of the peripheral surface of the lower corner portion of the supporting aggregate is coated with the heat-resisting alloy, a part of the peripheral sur-face of -the corner portion may be coated with the heat-re-sisting alloy if the welding is possible.
Next, the characteristics of the skid button according to the present invention are described.
(1) Insulating property Since ceramics superior to metals in insulating proper-ty are used as the main ingredient of the supporting aggre-gate, the skid button according to the present invention ex-hibits a superior insulating property. Although a less heat conductivity of the ceramics used is more desirable, the ex-periments by the present inventor have shown that a highly 3L2~33~
effective reduction o:f skid marks can be achieved in the case where the ceramics having a heat conductivity of at least 1/3 time that of metals or less are used.
(2) High-temperature compression-creep strength Since ceramics superior to the usual insulating materi-als in high-temperature compression resistance are used as the main ingredient of the supporting aggregate, the useful life time of the skid button can be prolonged. According to the inventor's experiments, the useful life time of the con-ventional skid buttons, such as the skid button formed of heat-resisting steels and the skid button formed of ceramics is a half year or less while that of the skid button accord-ing to every preferred embodiment of the present invention is two years or more.
(3) Shock-resistance and the prevention of the wear of ceramics due to the reaction Although ceramics exhibit superior results in insulat-ing property and high-temperature compression-creep strength, they have disadvantages in, for example, that they are inferior in shock-resistance and they are worn by the reaction between them and oxidized scales of the heated ma-terial or an atmosphere within a furnace. In the skid but-ton according to the present invention, all of the peripher-al surface of the lower corner portion of ceramics as the ~51~37~3 supporting aggregate is coated with heat-resisting alloys while all of the remaining peripheral surface is coated with shock-resisting substances, whereby the disadvantages inci-dental to ceramics can be eliminated.
As this invention may be embodied in several forms without departing from the spirit of essential characteris-tics thereof, the present embodiment is therefore illustra-tive and not restrictive, since the scope of the invention is defined by the appended claims rather than by the de-scription preceding them, and all changes that fall within the meets and bounds of the claims, or equivalence of such meets and bounds thereof are therefore intended to be em-braced by the claims.
As this invention may be embodied in several forms without departing from the spirit of essential characteris-tics thereof, the present embodiment is therefore illustra-tive and not restrictive, since the scope of the invention is defined by the appended claims rather than by the de-scription preceding them, and all changes that fall within the meets and bounds of the claims, or equivalence of such meets and bounds thereof are therefore intended to be em-braced by the claims.
Claims (20)
1. A heat-resisting supporting member, characterized by that at least a part of a peripheral surface of a lower corner portion of a supporting aggregate as a core material with ceramics contained therein is coated with a heat-resisting alloy while the remaining peripheral surface Is coated with a shock-resisting substance.
2. A heat-resisting supporting member as set forth in Claim 1, in which said supporting aggregate is formed of only ceramics.
3. A heat-resisting supporting member as set forth in Claim 1, in which said supporting aggregate is formed of a composite comprising ceramics and heat-resisting alloys.
4. A heat-resisting supporting member as set forth in Claim 3, in which said composite comprising ceramics and heat-resisting alloys is a heat-resisting alloy with ceramic particles dispersed therein.
5. A heat-resisting supporting member as set forth in Claim 4, in which said ceramics particles are contained at a ratio of 50 to 80 % by volume.
6. A heat-resisting supporting member as set forth in Claim 3, in which said composite comprising ceramics and heat-resisting alloys is an assembly of ceramic bars coated with heat-resisting alloys by molding.
7. A heat-resisting supporting member as set forth in Claim 6, in which an area-occupation ratio of said ceramic bars is 25 to 75 %.
8. A heat-resisting supporting member as set forth in Claim 3, in which said composite comprising ceramics and heat-resisting alloys is a material formed by impregnating porous ceramics having continuous air-pores with heat-resisting alloys.
9. A heat-resisting supporting member as set forth in Claim 3, in which said composite comprising ceramics and heat-resisting alloys is either a plurality of plate, cylindrical or bar-like ceramics with heat-resisting alloys interposed thereamong.
10. A heat-resisting supporting member as set forth in Claim 9, in which said ceramics are contained at a ratio of 30 to 80 % by volume.
11. A heat-resisting supporting member as set forth in Claim 1, in which said shock-resisting substance is formed of heat-resisting alloys.
12. A heat-resisting supporting member as set forth in Claim 1, in which said shock-resisting substance is formed of a material formed by impregnating ceramic porous ceramics having continuous air-pores with heat-resisting alloys.
13. A heat-resisting supporting member as set forth in Claim 12, in which the porosity of said porous ceramic is 60 to 80 %.
14. A heat-resisting supporting member as set forth in Claim 1, in which said shock-resisting substance is a mix-ture comprising heat-resisting alloys and a material formed by impregnating porous ceramics having continuous air-pores with heat-resisting alloys.
15. A heat-resisting supporting member as set forth in Claim 1, in which said shock-resisting substance is formed of heat-resisting alloys with ceramic particles dispersed therein.
16. A heat-resisting supporting member as set forth in Claim 15, in which said ceramic particles are contained at a ratio of 50 to 80 % by volume.
17. A heat-resisting supporting member as set forth in Claim 1, in which an area-occupation ratio of said ceramics in a section at right angles to the direction in which a load to be supported acts is 50 % or more.
18. A heat-resisting supporting member as set forth in Claim 1, in which said supporting aggregate is integrally formed with said shock-resisting substance and they are formed of the same material.
19. A heat-resisting supporting member as set forth in Claim 18, in which said same material is heat-resisting alloys with ceramic particles or bars dispersed therein.
20. A heat-resisting supporting member as set forth in Claim 18, in which said same material is a material formed by impregnating porous ceramics having continuous air-pores with heat-resisting alloys.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CA000527417A CA1258370A (en) | 1987-01-15 | 1987-01-15 | Heat-resisting supporting member |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CA000527417A CA1258370A (en) | 1987-01-15 | 1987-01-15 | Heat-resisting supporting member |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1258370A true CA1258370A (en) | 1989-08-15 |
Family
ID=4134766
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA000527417A Expired CA1258370A (en) | 1987-01-15 | 1987-01-15 | Heat-resisting supporting member |
Country Status (1)
| Country | Link |
|---|---|
| CA (1) | CA1258370A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN117324596A (en) * | 2023-11-09 | 2024-01-02 | 苏州兴业材料科技股份有限公司 | Composite high-strength heat-insulating riser and preparation method thereof |
-
1987
- 1987-01-15 CA CA000527417A patent/CA1258370A/en not_active Expired
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN117324596A (en) * | 2023-11-09 | 2024-01-02 | 苏州兴业材料科技股份有限公司 | Composite high-strength heat-insulating riser and preparation method thereof |
| CN117324596B (en) * | 2023-11-09 | 2024-03-26 | 苏州兴业材料科技股份有限公司 | Composite high-strength heat-insulating riser and preparation method thereof |
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