CA1248120A - Process for preparing alkylene carbonates from alkylene oxides - Google Patents
Process for preparing alkylene carbonates from alkylene oxidesInfo
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- CA1248120A CA1248120A CA000557781A CA557781A CA1248120A CA 1248120 A CA1248120 A CA 1248120A CA 000557781 A CA000557781 A CA 000557781A CA 557781 A CA557781 A CA 557781A CA 1248120 A CA1248120 A CA 1248120A
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- alkylene
- arsonium
- carbonates
- carbonate
- ethylene
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Abstract
Process for Preparing Alkylene Oxides from Alklene Carbonates Inventor Robert M. Weinstein Abstract of the Disclosure An alkylene oxide, e.g. ethylene oxide, is prepared from the corresponding alkylene carbonate, e.g. ethylene carbonate, in the presence of an effective amount of a qua-ternary arsonium halide. The quaternary arsonium halides are also effective catalysts for the reverse reaction, that is, to form alkylene carbonates from the corresponding epox-ide and carbon dioxide.
Description
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Process for Preparing Alkylene Oxides from Alkylene Carbonates Prior Art This invention relates to the preparation of alkylene oxides. Such compounds may be formed by reacting hydro-carbons with oxygen by processes well known in the art.
However, there are advantages to forming alkylene oxides by decomposing the corresponding alkylene carbonates, which are generally easier and less hazardous to handle and transport.
The present invention relates to such a process and a new class of catalysts, which may be used to decompose alkylene carbonates, particularly ethylene carbonate, to the corre-sponding epoxide or, alternatively, to prepare alkylene carbonates by the reverse reaction.
While the formation of alkylene oxides from the corre-sponding olefins has been extensively discussed in the art, the decomposition of alkylene carbonates to form the corre-sponding epoxides has not.
In U. S. patent 2,851,469 it is suggested that ethylene carbonate can be decomposed by heating, although large amounts of polymeraresaid to be formed. Certain catalysts are said to have been suggested, but found unsatisfactory. Using poly-halogenated hydrocarbons is disclosed to give better results.
In U. S. patent 4,069,234 (and the related U.S. 4,111,965;
4,192,810; 4,257,966; and 4,276,223) vicinal epoxides are shown to be formed by decomposing the corresponding carbonates in the presence of various catalysts, including phosphonium halides, sulfonium halides, sulfoxonium halides, and salts of iron, tin, manganese, and ~inc.
The alkali metal halides are used as catalysts for de composing al~yl-substituted ethylene carbonates in U. S. pat-ent 4,371,704. A distinction was made between the reactivity o~ ethylene carbonate`and substituted ethylene carbonates.
Also, U.S. 4,374,259 discloses tin catalysts for decomposing substituted carbonates, while U.S. 4,265,821 shows the use of lanthanum iodides.
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Process for Preparing Alkylene Oxides from Alkylene Carbonates Prior Art This invention relates to the preparation of alkylene oxides. Such compounds may be formed by reacting hydro-carbons with oxygen by processes well known in the art.
However, there are advantages to forming alkylene oxides by decomposing the corresponding alkylene carbonates, which are generally easier and less hazardous to handle and transport.
The present invention relates to such a process and a new class of catalysts, which may be used to decompose alkylene carbonates, particularly ethylene carbonate, to the corre-sponding epoxide or, alternatively, to prepare alkylene carbonates by the reverse reaction.
While the formation of alkylene oxides from the corre-sponding olefins has been extensively discussed in the art, the decomposition of alkylene carbonates to form the corre-sponding epoxides has not.
In U. S. patent 2,851,469 it is suggested that ethylene carbonate can be decomposed by heating, although large amounts of polymeraresaid to be formed. Certain catalysts are said to have been suggested, but found unsatisfactory. Using poly-halogenated hydrocarbons is disclosed to give better results.
In U. S. patent 4,069,234 (and the related U.S. 4,111,965;
4,192,810; 4,257,966; and 4,276,223) vicinal epoxides are shown to be formed by decomposing the corresponding carbonates in the presence of various catalysts, including phosphonium halides, sulfonium halides, sulfoxonium halides, and salts of iron, tin, manganese, and ~inc.
The alkali metal halides are used as catalysts for de composing al~yl-substituted ethylene carbonates in U. S. pat-ent 4,371,704. A distinction was made between the reactivity o~ ethylene carbonate`and substituted ethylene carbonates.
Also, U.S. 4,374,259 discloses tin catalysts for decomposing substituted carbonates, while U.S. 4,265,821 shows the use of lanthanum iodides.
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In European Patent Application 47,474, a stream of inert gas was used to strip the epoxides formed, while in a related application, EP 47,473, a vacuum was used. No new catalysts were disclosed, but phosphonium halides or alkali metal ha-lides were mentioned as being suitable.
Arsonium compounds have been suggested as catalysts for polycarbonate preparation and in heterogeneous reactions (phase transfer catalysis). They have been included in a list of quaternary --onium bicarbonates in the U. S. patent 4,226,778, which are reported ~o be useful for making alkyl-ene carbonates from the corresponding halohydrins.
It has now been found that quaternary arsonium compounds may be used to prepare alkylene oxides from the corresponding carbonates or, alternatively, to prepare alkylene carbonates from the corresponding epoxides, as will be seen from the follo~ing discussion.
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Summary of the Invention A process for the preparation of alkylene oxides, e.g., ethylene oxide, from the corresponding alkylene carbonate, which employs as a catalyst an effec~ive amount of a quater-nary arsonium halide. Such compounds may be generally de-fined by the formula RlR2R3R4AsX, where RlR~R3R~ may be hydrogen, alkyl, cycloalkyl, aryl, alkenyl, cycloalkenyl, and may be the same or different. X is either chlorine, bromine, or iodine.- A particularly preferred species is tetraphenyl arsonium iodide. In general, the catalyst will be present as about 0.001 to 0.1 mol for each mol of alkylene carbonate. The reaction will be carried out at a temperature of about 100 to 250C and a pressure of aboutO.005 to2.0 bar.
Where ethylene carbonate is being decomposed, the temperature will be about 150 to 225~C, and the pressure about 0.005 to 2.0 bar.
-he organic arsonium halides are also effective as cata-lysts for the reverse reaction, that is, preparing alkylene carbonates from the corresponding epoxide and carbon dioxide.
2~ Thus in the present divisional specification, there is provided a process for the preparation of an alkylene carbonate comprising reacting the corresponding alkylene oxide with carbon dioxide~in the presence of an effective amount of a quarternary arsonium halide.
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Description of the Preferred Embodiments Alkylene carbonates generally may be characterized as high boiling liquids o~ low toxicity. Of particular impor-tance are ethylene carbonate and propylene carbonate since they may be used as liquid sources of the corresponding ox-ides, which are quite volatile at ambient conditions. Effi-cient decomposition of alkylene carbonates to their oxides would be necessary for commercial applications. In the fol-lowing discussion most attention will be given to the prepa-ration of ethylene oxide from its carbonate, but withoutintending to limit the scope of the invention~
Decomposition of an alkylene carbonate may be carried out at temperatures generally in the range of 100 to 250C.
For ethylene carbonate, temperatures of 150 to 225~C are preferred. The pressures should be relatively low in order to favor the decomposition reaction, which produces carbon dioxide. However, pressures in the range ofO.005 to 2.0 bar are feasible. For ethylene carbonate, a pressure between 0.005and 2.0bar is preferred. The decomposition reaction may be carried out batchwiseorcontinuously in suitable equipment familiar to those skilled in the art. It may be advantageous to employ a high-boiling solvent, such as sulfolane, or a substituted alkylbenzene (e.g., 1,2,3,4 tetramethyl benzene).
An important aspect of the process is the selection and use of a catalyst from the quaternary arsonium halide group.
Broadly, the group includes compounds having the formula R1R2R3R4AsX, where RlR2R3R4 may be hydrogen, alkyl, cyclo-alkyl, aryl, alkenyl, or cycloalkenyl, and may be the same or different. X is either chlorine, bromine, or iodine.
Examples of ~uch compounds are tetrabutyl arsonium iodide, triphenyl methyl arsonium bromide, triphenyl methyl arsonium iodide, triphenyl heptyl arsonium iodide, tetraphenyl arsonium ~hloride, tetraphenyl arsonium bromide, or tetraphenyl arson-
In European Patent Application 47,474, a stream of inert gas was used to strip the epoxides formed, while in a related application, EP 47,473, a vacuum was used. No new catalysts were disclosed, but phosphonium halides or alkali metal ha-lides were mentioned as being suitable.
Arsonium compounds have been suggested as catalysts for polycarbonate preparation and in heterogeneous reactions (phase transfer catalysis). They have been included in a list of quaternary --onium bicarbonates in the U. S. patent 4,226,778, which are reported ~o be useful for making alkyl-ene carbonates from the corresponding halohydrins.
It has now been found that quaternary arsonium compounds may be used to prepare alkylene oxides from the corresponding carbonates or, alternatively, to prepare alkylene carbonates from the corresponding epoxides, as will be seen from the follo~ing discussion.
12~4 ~2~
Summary of the Invention A process for the preparation of alkylene oxides, e.g., ethylene oxide, from the corresponding alkylene carbonate, which employs as a catalyst an effec~ive amount of a quater-nary arsonium halide. Such compounds may be generally de-fined by the formula RlR2R3R4AsX, where RlR~R3R~ may be hydrogen, alkyl, cycloalkyl, aryl, alkenyl, cycloalkenyl, and may be the same or different. X is either chlorine, bromine, or iodine.- A particularly preferred species is tetraphenyl arsonium iodide. In general, the catalyst will be present as about 0.001 to 0.1 mol for each mol of alkylene carbonate. The reaction will be carried out at a temperature of about 100 to 250C and a pressure of aboutO.005 to2.0 bar.
Where ethylene carbonate is being decomposed, the temperature will be about 150 to 225~C, and the pressure about 0.005 to 2.0 bar.
-he organic arsonium halides are also effective as cata-lysts for the reverse reaction, that is, preparing alkylene carbonates from the corresponding epoxide and carbon dioxide.
2~ Thus in the present divisional specification, there is provided a process for the preparation of an alkylene carbonate comprising reacting the corresponding alkylene oxide with carbon dioxide~in the presence of an effective amount of a quarternary arsonium halide.
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Description of the Preferred Embodiments Alkylene carbonates generally may be characterized as high boiling liquids o~ low toxicity. Of particular impor-tance are ethylene carbonate and propylene carbonate since they may be used as liquid sources of the corresponding ox-ides, which are quite volatile at ambient conditions. Effi-cient decomposition of alkylene carbonates to their oxides would be necessary for commercial applications. In the fol-lowing discussion most attention will be given to the prepa-ration of ethylene oxide from its carbonate, but withoutintending to limit the scope of the invention~
Decomposition of an alkylene carbonate may be carried out at temperatures generally in the range of 100 to 250C.
For ethylene carbonate, temperatures of 150 to 225~C are preferred. The pressures should be relatively low in order to favor the decomposition reaction, which produces carbon dioxide. However, pressures in the range ofO.005 to 2.0 bar are feasible. For ethylene carbonate, a pressure between 0.005and 2.0bar is preferred. The decomposition reaction may be carried out batchwiseorcontinuously in suitable equipment familiar to those skilled in the art. It may be advantageous to employ a high-boiling solvent, such as sulfolane, or a substituted alkylbenzene (e.g., 1,2,3,4 tetramethyl benzene).
An important aspect of the process is the selection and use of a catalyst from the quaternary arsonium halide group.
Broadly, the group includes compounds having the formula R1R2R3R4AsX, where RlR2R3R4 may be hydrogen, alkyl, cyclo-alkyl, aryl, alkenyl, or cycloalkenyl, and may be the same or different. X is either chlorine, bromine, or iodine.
Examples of ~uch compounds are tetrabutyl arsonium iodide, triphenyl methyl arsonium bromide, triphenyl methyl arsonium iodide, triphenyl heptyl arsonium iodide, tetraphenyl arsonium ~hloride, tetraphenyl arsonium bromide, or tetraphenyl arson-
3~ ium iodide. As will be seen, tetraphenyl arsonium iodide(Ph4AsI) has been found particularly useful.
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The amount of the quaternary arsonium halide will be chosen to provide the optimum catalytic effect. Generally, this will be between about 0.1 and 10 mol percent relative to the alkylene carbonate. For ethylene carbonate, 0.2 to 5 mol percent is preferred.
The following examples will illustrate the general use-fulness of the process and by comparative examples demonstrate the advantages to be obtained.
Example 1 Several quaternary arsonium halides were compared by de-composing ethylene carbonate in a 50-ml round-bottomed ~lask.
Ethylene carbonate was placed in the flask, along with about 0.84 mol percent of the arsonium halide to be tested. Nitro-~5 gen was introduced above the decomposing liquid to the flaskat a low rate to facilitate removal of the ethylene oxide.
Two methods of analyzing the gaseous reaction products ¦~
were employed. In Method A, ethylene oxide was measured by passing the gases through a standardized MgC12/HCl solution, ;
and back-titrating the unreacted HCl with standard NaOH to obtain a measurement of the amount of HCl which was used.
This number of moles of reacted HCl is equal to the amount of ethylene oxide produced. Acetaldehyde was measured by gas chromatography via gas sampling of the reaction products priox to entering the MgC12/HCl scrubber solution.
In Method B, the gaseous reaction products were scrubbed into methanol which was chilled to 0~C. The methanolic solu-tion of ethylene oxide and acetaldehyde so obtained was weighed and analy~ed by gas chromatography.
Carbon dioxide could be measured by adsorption on Ascarite (trademark of the Arthur H.~ Thomas Co.), and the reaction bot-toms were also analyzed by gas chromatography.
As the reaction proceeded, ethylene carbonate was added periodically to approximate a continuous reaction in which the ratio of ethylene carbonate to catalyst remains constant.
The results of the test are given in Table I following.
Table I
Reaction Yield of EO(f) CatalYst Temp, CTime, hrs ~ ~e) S (a) Ph4 A~Cl.H2O 163 167 13 26 (b) Ph4AsC1 162-167 6.75 29 (c) Ph4A~I 163-166 l9 98 Id) Ph4A~Br 165-170 12 43 (a) Tetraphenyl arsonium chloride monohydrate (b) Tetraphenyl arsonium chloride (anhydrous) ~c) Tetraphenyl arsoniu~ iodide (d) Tetraphenyl arsonium bromide (e) Low yields of EO reflect significant production of polymers (~ Yield of EO was based on mol EC charged Since the hydrocarbon moieties are the same, the supe-lS rior performance of the iodide over the other halide~ is evident, although they all act a~ cataly~t~ for the reaction.
An advantage for using arsonium halide catalysts of the invention is the relatively low make of acetaldehyde, as shown in the following example.
Example 2 Experiments following the procedures of Example 1 were carried out to compare quaternary phosphonium halide catalysts with quaternary arsoni~m halide catalysts. The results are ~5 shown in Table II.
Table II
Catalvst _ Acetaldehyde Type _ _ Mol ~ Tem~, C ppm td) (a) Ph3MePI 2.5 164-168 avg 34,000 30 (b) Ph3MeAsI 2.5 164-167 avg 20,000 (c) Ph4AsI 0.85 163-165 4,800 (c) Ph4AsI 0.83 178-181 S,000 (c) Ph4AsI 205 179-181 7,000 (a) Triphenyl methyl phosphonium iodide (b~ Triphenyl methyl arsonium iodide (c) Tetraphenyl arsonium iodide (d) Based on ethylene oxide ~wt.AcH/wt.ECx10 It can be seen that arsonium halides produce significantly less of the undesirable acetaldehyde; also, that tetraphenyl arsonium halides reduce the acetaldehyde production substan-tially compared to the triphenyl methyl arsonium halides.
Accordingly, tetraphenyl arsonium iodide is a particularly preferred catalyst for the decomposition of ethylene carbon-ate. It has additional practical advantages which make it particularly suitable for commercial applications. It is thermally stable and can be easily isolated from any heavy reaction products or the alkylene carbonate for reuse, since it is insoluble in water.
Organic antimony halides have been suggested as cata-lysts for the formation of ethylene carbonate from ethylene oxide and carbon dioxide. However, such compounds appear to be inferior for the decomposition of ethylene carbonate, as will be seen in the following example.
Example 3 ComParative Two organic antimony halides were tested following the procedures of Example 1, except that ethylene carbonate was not added to replace that already consumed; that is, the reaction was carried out batchwise and the relative concen-tration of the catalyst ~herefore increased as the ethylene carbonate was decomposed. When 2.5 mol % triphenyl antimony dichloride was used, after 2 hours at 170C the ethylene car-bonate was found to have been completely polymerized. How-ever, the same amount of tetraphenyl antimony bromide, after 2.25 hours at 173-8C, decomposed 94% of the ethylene carbon-ate, but with a selectivity to ethylene oxide of only 42%.At a lower temperature, 125-9C, after 3 hours the same amount of tetraphenyl antimony bromide had only converted 7% of the ethylene carbonate, again with only a low selectivity to ethyl-ene oxide, 53~. A 40% selectivity to acetaldehyde was measured in both cases when tetraphenyI antimony bromide was used.
Example 4 An experiment following the procedure of Example 1 was carried out to demonstrate the use of tetraphenyl arsonium iodide (Ph4A~I) to catalyze the decomposition of substituted alkylene carbonates to suh~tituted alkylene oxides.
Propylene carbonate (83.3 g, 0.816 mol) and tetraphenyl arsonium iodide (10.0 g, 0.0196 mol) were placed in a 250-cc, round~bottomed flask. A reaction temperature of 195+3C was employed to decompose propylene ~arbonate. After 2.75 hours, }0 24.7% of the propylene carbonate charged was found to have decomposed to a mixture of propylene oxide, allylalcohol, ace-tone, and propionaldehyde, with selectivities of 87.3%, 0.1%, 1.0~ and 1.1%, respectively.
ExamPle 5 Arsonium halides will also catalyze the formation of alkylene carbonates. Two experiments were performed, one in the presence of 22 mol ~ H2O, the other in an anhydrous system.
These experiments were conducted in a l-liter autoclave to which enough tetraphenyl arsonium iodide had been added to equ 1 0.25 mol 3 of the ethylene oxide charged. Ethylene ox-ide was charged to a 250-cc stainless steel bomb and attached to the autoclave. It was forced into the autoclave by apply-ing a carbon dioxide overpressure, thus adding carbon dioxide and ~thylene oxide to the autoclave together. At room tem-perature, carbon dioxide was added to bring the initial pres-sure to 28.6 bar, and the reaction was begun by heating to 150~3C. A maximum reactor pres--ure at 150C of 52.7 bar was obtained, and after 45 minutes, this pressure was 42.4 bar.
Carbon dioxide was then continually added to the autoclave to maintain this pressure. After a 2-hour reaction period, the reactor was cooled and vented through MgC12/HC1 scrubbers in order to trap any unreacted ethylene oxide.
The following table summarizes the results of these experlments.
Table III
Tetraphenyl Arsonium Iodide Catalyzed Carbonation of Ethylene Oxide _ ~ EO (a) % EC (b) % MEG (c) 5 E~p. _ arqe Conv~rsion Selectivity SelectivitY
1 2.31 mol EO/0.5 mol H20 74.80 88.10 5.19 2 2.22 mDl EO 84.80 91.40 0.70 (a) Ethylene oxide ~) Ethylene ~arbonate ~c) Mbnoethylene glycol The reaction of alkylene oxides with carbon dioxide to form alkylene carbonates over quaternary arsonium halide cata-lysts may be carried out at temperatures above about 20C, particularly above 90C, preferably in the range of 90 to 200C. The pressure will be in the range of about 10 - 200 bar, preferably 30 - 80 bar. The molar ratio of carbon diox-ide to alkylene oxide should be at least 1/1 and the partial pressure of carbon dioxide should be sufficient to provide the desired selectivity to alkylene carbonate. The amount of catalyst used may be up to about 0.1 mol per mol of alkylene oxide, preferably about 0.001 to 0.02. As the data indicate, the reaction may be carried out with or without water being present, while maintaining a high selectivity to the carbonate.
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The amount of the quaternary arsonium halide will be chosen to provide the optimum catalytic effect. Generally, this will be between about 0.1 and 10 mol percent relative to the alkylene carbonate. For ethylene carbonate, 0.2 to 5 mol percent is preferred.
The following examples will illustrate the general use-fulness of the process and by comparative examples demonstrate the advantages to be obtained.
Example 1 Several quaternary arsonium halides were compared by de-composing ethylene carbonate in a 50-ml round-bottomed ~lask.
Ethylene carbonate was placed in the flask, along with about 0.84 mol percent of the arsonium halide to be tested. Nitro-~5 gen was introduced above the decomposing liquid to the flaskat a low rate to facilitate removal of the ethylene oxide.
Two methods of analyzing the gaseous reaction products ¦~
were employed. In Method A, ethylene oxide was measured by passing the gases through a standardized MgC12/HCl solution, ;
and back-titrating the unreacted HCl with standard NaOH to obtain a measurement of the amount of HCl which was used.
This number of moles of reacted HCl is equal to the amount of ethylene oxide produced. Acetaldehyde was measured by gas chromatography via gas sampling of the reaction products priox to entering the MgC12/HCl scrubber solution.
In Method B, the gaseous reaction products were scrubbed into methanol which was chilled to 0~C. The methanolic solu-tion of ethylene oxide and acetaldehyde so obtained was weighed and analy~ed by gas chromatography.
Carbon dioxide could be measured by adsorption on Ascarite (trademark of the Arthur H.~ Thomas Co.), and the reaction bot-toms were also analyzed by gas chromatography.
As the reaction proceeded, ethylene carbonate was added periodically to approximate a continuous reaction in which the ratio of ethylene carbonate to catalyst remains constant.
The results of the test are given in Table I following.
Table I
Reaction Yield of EO(f) CatalYst Temp, CTime, hrs ~ ~e) S (a) Ph4 A~Cl.H2O 163 167 13 26 (b) Ph4AsC1 162-167 6.75 29 (c) Ph4A~I 163-166 l9 98 Id) Ph4A~Br 165-170 12 43 (a) Tetraphenyl arsonium chloride monohydrate (b) Tetraphenyl arsonium chloride (anhydrous) ~c) Tetraphenyl arsoniu~ iodide (d) Tetraphenyl arsonium bromide (e) Low yields of EO reflect significant production of polymers (~ Yield of EO was based on mol EC charged Since the hydrocarbon moieties are the same, the supe-lS rior performance of the iodide over the other halide~ is evident, although they all act a~ cataly~t~ for the reaction.
An advantage for using arsonium halide catalysts of the invention is the relatively low make of acetaldehyde, as shown in the following example.
Example 2 Experiments following the procedures of Example 1 were carried out to compare quaternary phosphonium halide catalysts with quaternary arsoni~m halide catalysts. The results are ~5 shown in Table II.
Table II
Catalvst _ Acetaldehyde Type _ _ Mol ~ Tem~, C ppm td) (a) Ph3MePI 2.5 164-168 avg 34,000 30 (b) Ph3MeAsI 2.5 164-167 avg 20,000 (c) Ph4AsI 0.85 163-165 4,800 (c) Ph4AsI 0.83 178-181 S,000 (c) Ph4AsI 205 179-181 7,000 (a) Triphenyl methyl phosphonium iodide (b~ Triphenyl methyl arsonium iodide (c) Tetraphenyl arsonium iodide (d) Based on ethylene oxide ~wt.AcH/wt.ECx10 It can be seen that arsonium halides produce significantly less of the undesirable acetaldehyde; also, that tetraphenyl arsonium halides reduce the acetaldehyde production substan-tially compared to the triphenyl methyl arsonium halides.
Accordingly, tetraphenyl arsonium iodide is a particularly preferred catalyst for the decomposition of ethylene carbon-ate. It has additional practical advantages which make it particularly suitable for commercial applications. It is thermally stable and can be easily isolated from any heavy reaction products or the alkylene carbonate for reuse, since it is insoluble in water.
Organic antimony halides have been suggested as cata-lysts for the formation of ethylene carbonate from ethylene oxide and carbon dioxide. However, such compounds appear to be inferior for the decomposition of ethylene carbonate, as will be seen in the following example.
Example 3 ComParative Two organic antimony halides were tested following the procedures of Example 1, except that ethylene carbonate was not added to replace that already consumed; that is, the reaction was carried out batchwise and the relative concen-tration of the catalyst ~herefore increased as the ethylene carbonate was decomposed. When 2.5 mol % triphenyl antimony dichloride was used, after 2 hours at 170C the ethylene car-bonate was found to have been completely polymerized. How-ever, the same amount of tetraphenyl antimony bromide, after 2.25 hours at 173-8C, decomposed 94% of the ethylene carbon-ate, but with a selectivity to ethylene oxide of only 42%.At a lower temperature, 125-9C, after 3 hours the same amount of tetraphenyl antimony bromide had only converted 7% of the ethylene carbonate, again with only a low selectivity to ethyl-ene oxide, 53~. A 40% selectivity to acetaldehyde was measured in both cases when tetraphenyI antimony bromide was used.
Example 4 An experiment following the procedure of Example 1 was carried out to demonstrate the use of tetraphenyl arsonium iodide (Ph4A~I) to catalyze the decomposition of substituted alkylene carbonates to suh~tituted alkylene oxides.
Propylene carbonate (83.3 g, 0.816 mol) and tetraphenyl arsonium iodide (10.0 g, 0.0196 mol) were placed in a 250-cc, round~bottomed flask. A reaction temperature of 195+3C was employed to decompose propylene ~arbonate. After 2.75 hours, }0 24.7% of the propylene carbonate charged was found to have decomposed to a mixture of propylene oxide, allylalcohol, ace-tone, and propionaldehyde, with selectivities of 87.3%, 0.1%, 1.0~ and 1.1%, respectively.
ExamPle 5 Arsonium halides will also catalyze the formation of alkylene carbonates. Two experiments were performed, one in the presence of 22 mol ~ H2O, the other in an anhydrous system.
These experiments were conducted in a l-liter autoclave to which enough tetraphenyl arsonium iodide had been added to equ 1 0.25 mol 3 of the ethylene oxide charged. Ethylene ox-ide was charged to a 250-cc stainless steel bomb and attached to the autoclave. It was forced into the autoclave by apply-ing a carbon dioxide overpressure, thus adding carbon dioxide and ~thylene oxide to the autoclave together. At room tem-perature, carbon dioxide was added to bring the initial pres-sure to 28.6 bar, and the reaction was begun by heating to 150~3C. A maximum reactor pres--ure at 150C of 52.7 bar was obtained, and after 45 minutes, this pressure was 42.4 bar.
Carbon dioxide was then continually added to the autoclave to maintain this pressure. After a 2-hour reaction period, the reactor was cooled and vented through MgC12/HC1 scrubbers in order to trap any unreacted ethylene oxide.
The following table summarizes the results of these experlments.
Table III
Tetraphenyl Arsonium Iodide Catalyzed Carbonation of Ethylene Oxide _ ~ EO (a) % EC (b) % MEG (c) 5 E~p. _ arqe Conv~rsion Selectivity SelectivitY
1 2.31 mol EO/0.5 mol H20 74.80 88.10 5.19 2 2.22 mDl EO 84.80 91.40 0.70 (a) Ethylene oxide ~) Ethylene ~arbonate ~c) Mbnoethylene glycol The reaction of alkylene oxides with carbon dioxide to form alkylene carbonates over quaternary arsonium halide cata-lysts may be carried out at temperatures above about 20C, particularly above 90C, preferably in the range of 90 to 200C. The pressure will be in the range of about 10 - 200 bar, preferably 30 - 80 bar. The molar ratio of carbon diox-ide to alkylene oxide should be at least 1/1 and the partial pressure of carbon dioxide should be sufficient to provide the desired selectivity to alkylene carbonate. The amount of catalyst used may be up to about 0.1 mol per mol of alkylene oxide, preferably about 0.001 to 0.02. As the data indicate, the reaction may be carried out with or without water being present, while maintaining a high selectivity to the carbonate.
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Claims (3)
PROPERTY OR PRIVILEGE IS CLAIMED ARE DEFINED AS FOLLOWS:
1. A process for the preparation of an alkylene carbonate comprising reacting the corresponding alkylene oxide with carbon dioxide in the presence of an effective amount of a quarternary arsonium halide.
2. The process of claim 1 wherein said quarternary arsonium halide is expressed as RlR2R3R4AsX, where R is a member of the group consisting of hydrogen, alkyl, cycloalkyl, aryl, alkenyl, and cycloalkenyl, and may be the same or different; and where X is a member of the group consisting of chlorine, bromine, and iodine.
3. The process of claim 1 wherein said quaternary arsonium halide is tetraphenyl arsonium iodide.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CA000557781A CA1248120A (en) | 1984-10-25 | 1988-01-29 | Process for preparing alkylene carbonates from alkylene oxides |
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US664,728 | 1984-10-25 | ||
| US06/664,728 US4851555A (en) | 1984-10-25 | 1984-10-25 | Process for preparing alkylene oxides from alkylene carbonates |
| CA000491058A CA1238643A (en) | 1984-10-25 | 1985-09-18 | Process for preparing alkylene oxides from alkylene carbonates |
| CA000557781A CA1248120A (en) | 1984-10-25 | 1988-01-29 | Process for preparing alkylene carbonates from alkylene oxides |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA000491058A Division CA1238643A (en) | 1984-10-25 | 1985-09-18 | Process for preparing alkylene oxides from alkylene carbonates |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1248120A true CA1248120A (en) | 1989-01-03 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA000557781A Expired CA1248120A (en) | 1984-10-25 | 1988-01-29 | Process for preparing alkylene carbonates from alkylene oxides |
Country Status (1)
| Country | Link |
|---|---|
| CA (1) | CA1248120A (en) |
-
1988
- 1988-01-29 CA CA000557781A patent/CA1248120A/en not_active Expired
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