CA1240463A - Method and apparatus for making improved laminating film and improved film - Google Patents

Abstract

ABSTRACT
A method and apparatus for manufacturing a film suitable for use in lamination under heat and pressure.
A plurality of resins is co-extruded into concentric annuli, the inner annulus being a polyester type resin, and at least one of the outer annuli consisting of a polyolefin based resin. The co-extrusion is carried out as the extruding die is rotated about its axis.
After quenching to form a multi-layer seamless tube, the tube is collapsed and heated to a temperature suit-able for biaxial orientation. An air bubble is intro-duced into the heated tube to expand the diameter there-of and simultaneously orient the tube biaxially by molecular orientation. The biaxially oriented tube is cooled sufficiently to retain its molecular orientation, and is then collapsed. The tube is then heated to a shrinking temperature while under controlled restrain to achieve a predetermined dimen-sion in amount of shrinkage in the film. Finally, the edges of the shrunk tube are slit to form a pair of flat films.
Additional improvements are achieved by including irradiation of the films by ultraviolet light, and by treating one of the film surfaces with a corona discharge.

Description

SPECIFICP.TION
.
The present invention is in the field of manufacturing film suitable for use as laminating Eilm and involves co-extrusion of a plurality of films of S different chemical compositi~n, biaxially orienting the same, subjecting the hiaxially oriented tube to controlled sizing conditions, and then forming a pair of flat films from the tube.
Various types of heat-activated lamination systems have been used commercially for many years.
Such systems are usually used for encapsulating and sealing of documents between two plastic films to protect documents and to enhance the visual appearance.
Such post-lamination is usually performed in offices, schools, or graphic art shops. In the case of laminating identification cards, licenses, and the like, there are often stringent specifications and consist~nt high quality results are required.
The laminating films used in this type of lamination procedure usually consist of one layer of unoriented polyethylene or a copolymer thereof/ a~d another layer of orientedand heat-set polyethylene terephthalate (PET). ~ypically, these materials are prepared by an extrusion coating of polyethylene or its copolymers onto an oriented PET film wPb.
The extrusion processes com~only used to produce pac]caging films, although producing usable laminating films, provide several inherent drawbacks~
For one, hazy streaks and bubbles occasionally will occur as a result of contact with the hot shoes.
~hese streaks and bubbles are caused by air bubbles which are trapped a~ the interface between the tw~
layers during the coating operation. Such bubbles 1 are usually microscopic in size but they expand into larger bubbles and cause visual defects such as streaks when subjected to certain heating conditions in the lamination step. This phenomenon only occurs from time to time. It has been known that it is influenced by process conditions, but it has not been known ho~ to predictably cuxe it.
Heated roll laminators also have their own disadvantages, particularly the creation of wrinkles 1~ and the presence of uneven heating. For post-lamination applications, it is desirable that the film should shrink minutely in the transverse direction when heated so as to smooth out the film which, in turn insures uniform heating. Laminating film produced by existing extrusion coating operations occasionally will exhibit positive dimensional change in the transverse direction of the film when heated. Although the amount of change is very small, it is very undesirable since it causes the film to wrinkle and to be heated unevenly.
The reasons for this ~ransverse growth are believed to be twofold. In the extrusion coating operation, the PET is usually heated to drive off the solvent or water from the primers. At the same time, the film is necessarily under tension in the machine direction (MD) to avoid wrinkles and the like. This combination of conditions tends to cause tensile stress in the PET
film in the machine direction, and, due to the poisson's ratio of the material, a certain amount of compres-sion stress is also effected in the transverse direction of the film. The stresses are frozen-in when film is cooled under tension. When the film is re-heated in the post-lamination step r the stresses are relieved to cause MD shrinkage and transverse growth.
Moreover, the PET film when produced by 3~ conventional flat cast procedures tends to have low 3_ transverse shrinkage which contributes to the aforementioned transverse growth problem.
Another drawback existing in conventional laminating ~ilm is inadequate interfacial adhe.sion for certain applications. In the manufacture of identification cards, outdoor signs, and the like, the resulting laminates m~st possess excellent inter-facial adhesion in laminating films but must also be resistant to environmental influences such as high humidity, rain, and the like. This requirement is not met by existing laminating film technology. Although many water-resistant primers are available, they all contain residual low molecular weight fractions which, upon heating in the lamination step, tend to migrate through the polyethylene layer to the surface, causing a weakening effect on the adhesion of the laminate to the underlying document.
Another defect results from the fact that in post-laminating, the film is always contact heated ~o either by means of heated rollers or by heated shoes.
Uniform heating therefore depends on uniform contact.
The presence of gauge hands which are inherent in flat die-casting and coating processes cause uneven contact, and thus cause uneven heating. Although good quality control on existing processes can reduce this problem, it cannot be eliminated completelyO
There are numerous examples of multi-ply laminating films in the patented prior art of which the following are believed to be typical examples.
Bornstein et al U.S. Patent No. 4,064,296 describes a heat shrinkable, multi layer film including a layer of a hydrolyzed ethylene-vinyl acetate copolymer formed by co-extruding the hydrolyzed ethylene-vinyl acetate copolymer layer between two other polymeric layers which themselves may be ethylene-vinyl acetate 1 copolymers. The resulting laminated structure is thereafter irradiated and oriented to produce a film which is heat shrinkable and is said to have very low oxygen permeability.
Schirmer V.S. Patent No. 4,095,~12 describes a process for producing oriented films and laminates from nylo~ 66 and blends thereof wherein a nylon layer is co-extruded between layers of polymeric materials such as polyoleins and their copolymers to form a laminate. A~ter quenching of the laminate, the laminated structure is oriented biaxially.
In U.S~ Patent No, 4,151,328 to Kight thexe is described a packaging material film including a self-adhering layer composed of a terpolymer of ethy-lene, a vinyl ester, and an alkenoic acid. This layer is aoplied onto a plasticized saran.
Mueller et al in U.~. Patent No. 4,188,443 describe a multi-layer polyester/polyolefin shrink film consisting preferably of five layers in which the middle 2d layer is a polyester or copolyester, the two inner ~ayers adjacent the mi~dle layer are both ethylene-vinyl acetate co~olymers, and ~he skins or outer layers are ethylene-propylene copolymers. This patent describes biaxial stretching of the two by means of internal air pressure to form a bubble.
U.S. Patent No, 4,197,326 to Wakamatsu et al describes a packaging tube composed of an oriented laminated film formed by stretching a composite film having an inner layer composed of an oxygen barrier thermoplastic resin confined between outer layers of a thermoplastic resin having a smaller water absorption capability than the inner layer. The oxygen barrier layer may be materials such as nolyamides, PET, hydrolyzed ethylene-vinyl acetate copolymers (EV~) and polyvinyl alcohol whereas the thermoplastic resin 1 outer films are composes of materials such as poly-ethvlene, ~VA, or pol~butene.
Andrews et al U.S. Patent No. 4,198,256 descri.bes a heat-sealable oriented plast:ic film con-sisting of an oriented polypropylene film covered witha heat-seala~le layer consisting of a ~redominantly linear random copolymer of ethylene with an additional alpha-olefin having at least three carbo:n atoms per molecule.
In U.S. Patent to Mitsuishi et al there is described a stretch-oriented laminate polyester film consisting of two or three layers of polyester films of different intrinsic viscosities. The preferred embodi-ment of the invention consists of a stretch-oriented laminated film and a magnetic layer coated on an ex-ternal surface thereof to provide a maynetic recording medium.
U.S. Patent No. 4,274,900 to Mueller et al describes a multi-layer polyester/polyolefin shrink film preferably having five layers in which the middle layer is a polyester or copolyester, the two inner adjacent layers are EVA copolymers, and the s~in or outer layers comprise ethylene-propylene copolymers.
The present invention provides a method of manufacturing a film suitable for use in lamination under heat and pressure which eliminates many of the ob-jectionable features of laminating films of the prior art. Speciically, the method of the present invention in its broader aspects involves co-extruding concentric annuli Gf a polyester such as PET as the inner annulus and a polyolefin-based resin as the outer annulus while rotat.ing the annul.i about their common axis during extrusion. The extrusion is carried out in the absence of air at the interace between the two annuli. In 1 the next step, the extrudate is quenched to ~orm a multi-layer seamless tube which is thereupon collapsed and heated to a temperature in excess of ~he glass transl-tion temperature, which is suitable for biaxial orien-tation. In the next step, an air bubble is introduce~into the heated tube to expand the diameter thereof to a diameter greatex than that of the original extrudate to thereby orient the tube biaxially by molecular orientation. This biaxially oriented tube is cooled sufficiently to retain its molecular orienta-tion and then collapsed. The tube is then heated to a relatively high heatset shrinking temperature while restraining shrinkage thereof to a predetermined, sized, dimension and finally the thus shrunk film is slit at the edges to form a pair of flat films. Additional benefits are achieved by irradiating the films by ultraViletlight during and~or after the controlled shrinkage step to enhance the interfacial adhPsion.
In addition, the slitting of the tube into flat films is advantageously followed by a treatment of the film surfaces in a texturizing process which roughens the surface of the film, and in turn, is followed by treatment with a corona discharge.
The paxticularly preferred form of the pre-sent invention involves co-extrusion of three annuli, the PET resin constituting the inner annulus, and dif-ferent EVA resins constituting the middle and outer annu~i.
The present invention also provides an improved laminating film as an end product and also an improved film tube spreader and support which provides the controlled amount of shrinkage in the tube prior to slitting.
The laminating fllm of the present invention has no entrapped air bubbles at the interface of the i3 1 layers because the layers are co~-extruded and the inter-face is never in contact with air. This eliminates visual defects such as streaks caused by entrapped bubbles.
The improved film has desirable transverse shrinkage and never exhibits undesired transverse growth because of the novel co extrusion and co-orientation process. In accordance with this process, solvent or water drying is ~liminated, and the machine direction stress under heat is also eliminated. Furthermore, it was found tha~ the process of the present invention produces films with increased amount of transverse shrink to start with. This combination eliminates the transverse growth and the wrinkles and uneven heating caused by it.
Delamination problems are also eliminated and interfacial adhesion whieh is insensitive to the environment is provided between the film layers.
The oscillation or rotation of the extrusion dies and other hardware in t.h~ manu~acture of the film virtually eliminates the gauge band problem, and thus eliminates the uneven heating and wrinkling problems associated with it.
The drawings illustrate a preferred form of ~5 apparatus or use in the process of the present invention and are identified as follows:
FIG. 1 is a somewhat schematic showing o an overall production line embodying the improvements of the present invention;
FIG. 2 is a cross-sectional view of an en-larged scale illustrating a portion of one embodiment of the co-extrusion mechanism in accordance with the presen~ invention;
FIG. 3 is a cross-section21 view taken sub-stantially along the line III-III of FIG~ 2;

1 FIG. 4 is a cross-sectional view taken sub-stantially along the line IV-IV of FIG. 2;
FIG. 5 is a view ~aken substan1:ially along the line v-V of FIG. 1;
FIG. 6 is a view taken substanl:ially along the line VI-VI of FIG. 5;
FIG. 7 is a view taken substantially along the line VII-VII of FIG. 5; and FIG. 8 is a broken-a~ay view illustrating the three~ply laminating film of the present invention.
In FIG. 1, reference numeral lO indicates generally a coextrusion appara~us for use in accordance with the principles of the present invention. It includes a distribution ring ll which is fed by three l~ nozzles, a centrally disposed nozzle 12 which injects thP PE~ resin, and side nozzles 13 and l4 which are used to inject the materials which are ~o be laminated to the central annulus of PET. For example, the material injected through the nozzle 13 which forms themiddle annulus of the three-ply structure may be EVA containing about 8% by weight vinyl acetate. The resin injec~ed through the nozzle 14 may, for example, be E~A having a 4~ vinyl acetate concentration. The outside layer serves to bond itself more securely to the underlying substrate, while the material of the middle layer serves to bind the outer EVA layer to the inner PET layer.
The PET function as an ultra~iolet absorbing layer, while the EVA layers are ultraviolet transmitting layers. In place of the PET~ other high temperature resisting materials such as polycarbonate resins, poly-butene terephthalate resins, and the iike, can be employed.
In place o~ the EVA, other olefinic resins such as ethylenic copolymers including ionomers can be employed.

1 One embodi.ment of the die arrangemen-t is illustrated in FIG. 2. There, the distributing head 11 is fixedly mounted on a support 15. It is also pro-~Jided with an air inlet pipe 16 for for~!ing the ~o-extrudates into the form of a tube 17 during co-extrusion. The air inlet pipe 16 communicates with a centrally disposed passage 18 in a centrally disposed rotatable extrusion head 19. The extrusion head 19 may be rotated during extrusion by various means. As illustrated7 a drive gear 20 engages teeth 21 formed in the exterior of the extrusion head 19. A bearing 22 permits relative xotation between the extrusion head 19 and the distributor head 11.
As best seen in FIG. 3, the three resinous compositions are delivered to arcuate segments 12a, 13a, and 14a, respectively, at the top of the rotating ex-trusion head 19. These arcuate slots ~erge into con-tinuous annular rings 12b, 13b, and 14b, respectively, at the base of the rotatable extrusion head 19~ so that upon extrusion, continuous annuli 12c, 13c and 14c are co-extruded as best seen in FIG. 4. Since the extruding surfaces come together in the ahsence of air, there is no possibility of entrapping air bubbles which could lead ~o s~reaks.
Returning to FIG. 1, the extruded tube 17 while still hot is passed through a water ring 25 to ~uench ~he external surface of the extruded tube 17, The water is sufficiently cold to fast-quench the tube and reduce crystallinity in the PET s~ that the PET
either stays amorphous or has low crystallinity ~less than 25%). Additional water quenching is effected by a plurality of water spray devices 26 as the tube is collapsed between a pair of nip rollers 27 and 28.
During passage between the rollers 27 and 28, water i5 str.ipped Erom the exterior surface of the extruded 1 tube and falls into a pan 29. Additional amounts of water are stripped from the tube by training the same over a roller 30 and co~tacting the tube with air jets 3~ which blow the remaining surface water down into a collecting pan 3~.
The dried extruded tube is then guided by means of rollers 33, 34, and 35 into an extrusion tower generally indicated at reference numeral 36. Within the tower, the flattened tube passes between a pair of nip rollers 37 and 38 which further flatten the same and then thr~ugh an iris 39. The interior of the tube is reopened at this point, by air inside the tube.
As it is reopened, the tube passes through a heater 40 in which it is heated to a temperakure suitable for biaxial orientation. Such temperature is usually in excess of the glass transition temperature of P T.
If necessary, an air ring 41 can be provided to adjust the neck of the tube tn a temperature most suitable for biaxial orientation.
Air trapped within the tube serves to form a bubble within the tube which causes the tube to ex-pand to a diameter about three to four times the diameter of the original extruded tube 17, forming an enlarged diameter tuhe 42 which is biaxially oriented. The tube then passes through a cooling air ring 43 which reduces the temperature on the tube, befor~ it is again collapsed by passing through a collapsing frame 44 and then into the nip between a pair of rollers 45 and 46.
After passing between rollers 47, the ~lattened tube is then subjected to controlled heat-set and ultra-violet irradiatisn. The heat-set is accomplished by means o~ a heater-sPreader generally indicated at reference numeral ~8 and shown in detail at FXGS. 5 to 7, inclusive.

1 The s~reader consis~s of a pair Gf conduits 49 and 50 in spaced canvilevered relation as seen in FIG~ 7. The spacing between the two conduits 49 and 50 is controlled by a pair of frame members 51 and 52, respectively, connected ~o the two conduits.
The spacing between the frame members is controlled by means of adjusting means 53 and 54 extending between the two frame members. The ends o the frame members 51 and 52 are received in sliding relation along a pair of rods 55 and 56.
A coolant such as water is circulated through each of the conduits 49 and 50. A water inlet pipe 57 serves ~o introduce the eirculating water into ~he conduit 49, and discharge line 58 is provided to return the coolant to the source. Similarly, a water inlet line 59 and a discharge line 60 are provided for circulating cooling water through the conduit 50.
The flattened tube is fitted over the spreader 48 and may be opened by the introduction of air through air lines 61 and 62. The tube is thus slightly dis-tended in being pulled over the spreader which prevents it from shrinking beyond a controlled amount.
The tube as it enters the spreader 48 has a room temperature but is heated to a heat-set tempera-tuxe of about 400F, above the highest temoeraturesused in expected subsequent lamination processes in which the film will be used. All ~he time the tube is on the spreader, it is under longitudinal tension provided by take-up rollers 63 and 64 ~FIG. 1).
A pair of arcuate guides 65 and 66 is provided beyond the end of the spreader to provide guide means for directing the tube for the slitting operation.
Slitting knives 67 and 6~ are fixedly secured to slides 69 and 70, respectively, which slides are adjus-tably positionable by being slidably mounted on the rods 55 1 and 56 as shown in FIG. 5. Relative position of the slides 69 and 70 dictates the positionin which the slitting knives 67 and 68 sever the elongated tube into a pair of flat face-to-face films.
Before the flat films are cooled down below 230 F, they are subjected to irradiation by banks 72 and 73 of ultraviolet lights. These lights serve to improve the adhesion betwPen the layers making up the films.
After trea~ment with th~ ultraviol~t light, the films may be texturized on their outwardly acing surfaces by passing the same into ~ontact with rollers 74 for one of the surfaces and rollers 75 for the other.
These texturizing rollers are used to create a rough surface on the EVA side of the film. The rough surface is desirable for eliminating air bubbles and the like and helps winding up the same on the rolls.
Following the tex~uriæing, the films may be subjected to treatment in a zone 76 in which a corona discharge device is located. This technique provides enhancement of adhesion to the substrate in post-lamination operations.
The final product is illustrated in FIG. 8 of the drawings. The interior laminate 81 comes in contact with the substrate and consists of a roughened, corona treated EVA film. ~ightly secured to the film 81 is the intermediate binder film 82 consisting of an EVA polymer having a higher content o~ ~inyl acetate than the film 81. Finally, the outer film 83 consists of oriented, heat-set PET of good optical clarity.
The present invention provides a film which still retains some transverse shrinkage proper~y making it ideally suited for use in post-lamination procedures.
In most other applications for oriented, heat-set 1 PET films, it is usually desirable to minimize the shrinkage, not to encouraye it.
Although co-extrusion has been known in svme cases to provide a film of good clarity, such co-S extrusion is used in the present instanc~e to eliminatethe heat-activated bubbling problem which has been very troublesome.
Moreover, although ultra~ioletlight at elevated temperatures is known to enhance adhesion between certain layers of plastic materials, it is found that in this case, the ultraviolet light has to be used after the orientation step to be ~ffectiv~.
When ultraviolet light is used before orientation, the adhesion achieved is almost comple~ely lost after orientation.
It should be evidentthat various modifications can be made to the described embodiments without depart-ing from the scope of the present invention.

Claims (6)

The embodiments of the invention in which an exclusive property or privilege is claimed are defined as follows:

1. An improved laminating film having one outer film having a surface composed of an optically clear, biaxially oriented polyester resin, a second outer film having a surface composed of an ethylene vinyl acetate copolymer, and an intermediate film interposed between said first and second films and bonding the same together, said intermediate film comprising an ethylene-vinyl acetate copolymer having a higher content of vinyl acetate than said second outer film, and second outer film being embossed to create a textured surface, said laminating film having a residual shrinkage not greater than 2%.

2. A film according to claim 1 in which said one outer film is composed of polyethylene terephthalate.

3. A film according to claim 1 in which: said one outer film is composed of polyethylene terephthalate and both said second and intermediate films are composed of an ethylene-vinyl acetate copolymer, said second outer film having a lower vinyl acetate content than said intermediate film .

4. A film according to claim 1 wherein ultraviolet irradiation has been applied to the interfaces between the intermediate film and the outer films via the second outer film.

5. An improved multi-layer laminating film of a biaxially oriented layer and at least one heatsealable layer adhered thereto, wherein a very small residual transverse shrinkage occurs under lamination temperature conditions.

6. The film of claim 5 wherein the residual shrinkage is no greater than 2%.