CA1234503A - Meter for measuring the concentration of water in a water-ink mixture - Google Patents

Meter for measuring the concentration of water in a water-ink mixture

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Publication number
CA1234503A
CA1234503A CA000488871A CA488871A CA1234503A CA 1234503 A CA1234503 A CA 1234503A CA 000488871 A CA000488871 A CA 000488871A CA 488871 A CA488871 A CA 488871A CA 1234503 A CA1234503 A CA 1234503A
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CA
Canada
Prior art keywords
water
frequency
output
amplifier
voltage
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
CA000488871A
Other languages
French (fr)
Inventor
Thomas A. Fadner
Kwang E. Chung
Ira B. Goldberg
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Boeing North American Inc
Original Assignee
Rockwell International Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rockwell International Corp filed Critical Rockwell International Corp
Priority to CA000488871A priority Critical patent/CA1234503A/en
Application granted granted Critical
Publication of CA1234503A publication Critical patent/CA1234503A/en
Expired legal-status Critical Current

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Abstract

ABSTRACT OF THE DISCLOSURE

A meter is provided which can continuously measure the amount of water in a flowing mixture of water and lithographic ink. The mixture flows between the plates of a capacitor cell. This cell provides capacitance for an audio frequency oscillator. The output frequency of the oscillator is converted to a voltage which is proportional to the output frequency of the oscillator. This voltage is converted to a second voltage which is proportional to the logarithm of the first mentioned voltage and is also proportional to the concentration of water in the mixture. This second voltage is read out in a display device which can be set to read the water content of the mixture of water and ink.

Description

~3~5~3 A METER FOR MEASURING THE CONCENTRATION
OF WATER IN A WATER-INK MIXTURE

Ira ~. Goldberg Kwang E. Chung Thomas A. Fadner BACKGROUND OF THE INVENTION
This invention relates to the field of meters and part-icularly to the field of meters for measuring the concentration of water in a water-ink mixture.
Lithographic printing presses use a mixture of ink and aqueous dampening solution. The dampening solution is water with small amounts of proprietary additives to enhance water wetting of the printing plate. A continuous flow of ink and of dampening solution are furnished to the press. These can be supplied as a mixture of ink and dampening solutionj or as sep-arate streams of ink and dampening solution depending upon press configuration. In any case, the useful printing mixture on press contains both ink and water. In keyless inking systems, for economical~operation, the ink-water mixture should be~recirculated, since only a fraction of the ink mixture is being consumed by the printing~process at any given time.
In order to obtain the best printing results, the proper amounts of water and of ink in the mixture must be maintained.
This can be done at start-up when a fresh water-ink mixture is added by ...

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~23~5~33 using the proper proportions for making the mixture. However, over a period o~ time during printing the proportions of ink and water can change in the recirculating mixture. At present, the printer attending the press has no means of automatically and con-tinuously monitoring the concentration of water in a recirculating water-ink mixture. He must rely upon his experience and the print-ing results to estimate the concentration of the water in the mixture.
Meters are known which measure the dielectric constant of a mixture to determine the moisture content of materials or the density of a mixture. Some of these prior art meters use a Wheatstone bridge-type circuit to measure dielectric properties (e.g., U.S. Patent 3,696,299, dated October 3, 1972 to J. Pullman and W. Weidlich). Others use two oscillators to obtain a frequency differential which is related to the dielectric properties of the material being tested (e.g., U.S. Patent 4,048,844, dated September 20, 1977 to A. Dunikowski et al). Still other meters use an oscillator with peak detectors (e.g., U.S. Patent 4,399,404, dated August 16, 1983 to R. Resh) or a logic circuit (e.g., U.S. Patent 4,130,796, dated December 19, 1978 to L. Shum). However, what the printer needs is a simple meter which will automatically provide a direct reading of the concentration of water in the ink.
SUMMARY OF THE INVENTION
It is an object of the invention to provide a meter for conveniently measuring the concentration of wat~r in a mixture of water and ink.
According to the invention, the mixture to be measured forms the dielectric between the plates of a capacitor in a special capac-itor cell. This cell provides capacitance for an audio frequency
-2-... . .
- :.. ' - , : ., , ~LZ3~ 3 oscillator. When the dielectric constant of the mixture changes due to changes in the water content of the mixture, the output frequency of the oscillator changes. The output frequency of the oscillator is converted to a voltage which is proportional to the output frequency of the oscillator. This voltage is then con-verted to a second voltage which is proportional to the logarithm of the first mentioned voltage. This second voltage is read out in a display device. Because the concentration of water in water-ink mixtures is proportional to the logarithm of the mixtures' dielectric constant, the display device can be set to provide a direct reading of the ratio of water in the water-ink mixture.
In a preferred embodiment, the special capacitor has an inlet and an outlet and is coupled in series by appropriate tubing to a recirculating water-ink mixture system at the press. ~he meter can then provide a continuous reading of the water in the mixture.
These and other objects and features of the invention will be apparent from the following detailed description taken together with reference to the accompanying drawings.

BRIEF DESCRIPTION OF THE DRAWINGS
Figure 1 is a graph showing the relationship between the water concentration ton a linear scale) and the dielectric constant (on a logarithmic scale) for water-ink mixtures of three di~ferent types of inks;~
Figure 2 is a block diagram of the ink meter circuit ; according to the invention;

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~;~3~ 3 Figure 3 is a schematic diagram of the ink meter circuit according to the invention; and Figure 4 is a preferred embodiment of a capacitor cell for use in the invention.

DESCRIPTION OF THE PREFERRED EMBODIMENT
A microwave cavity was used to study the dielectric pro-perties and the microwave absorption of water and lithographic ink mixtures. During these studies it was discovered that the logarithm of the real component, ~', of the dielectric constant, ~= ~1 + iE", iS linear with the concentration of water in the water-ink mixture. This relationship is defined by the following equation:
log = log~O'+ KC, where ~1 is the real part of the com-plex dielectric constant ~(shown above), Eol iS its value for ink without added water, C is the concentration by weight of water (or water with dampening solution), and k is a proportionality con~tant.
Additional testing showed that this relationship was re-prcducible, and that it applied to many different types of lith-ographic ink. Figure 1 shows this logarithmic relationship for three different newspaper inks supplied by the Flint Ink Co., Detroit, MI, namely a blank ink, curve 2, a yellow ink, curve 4, and a magenta ink, curve ~. These curves were obtained on mixtures tested at 23 degrees C. Testing at temperatures ranging from 10 degrees C to 40 degrees C showed that the ink-water mixtures had an anomalously small temperature dependence. These results were surprising because water itself shows a large temperature depend-ence. Apparently, this...

~:

~ 3a~3 anomalous behavior is related to the microstructure of the water-ink emulsion. In any event, the small temperature de-pendence and the reproducible phenomenological behavior (Fig-ure 1) provides a theoretical basis for a meter to measure the water concentration of water-ink mixtures as described below.
Figure 2 is a block diagram of a capacitance type meter according to the invention for obtaining a linear readout of khe concentration, C, of water (or dampening solution) in an ink-water mixture. In this meter, the mixture acts as a dielectric material for a capacitor 8. The capacitance of capacitor 8 depends upon the dielectric constant E ' of the mixture and (as discussed above and as shown in Figure 1) this in turn depends upon the concentration, C, of water in the mixture.
Capacitor cell 8 is a part of the circuit of an audio-frequency oscillator 10. Oscillator 10 provides a square wave frequency, f, which is inversely proportional to the dielectric constant of the mixture in capacitor 8. This is expressed by the equation~

f = 2RfC E ~ n[(l~ )] , where Rf is the feed-back resistor defined by the type of ink being measured, ~ is the value of the resistance of the positive feedback loop of the os-cillator, and C is the capacitance of cell 8 in the absence of the mixture.
Once the square wave signal, f, is generated, a frequency-to-voltage converter 12 is used to convert the signal to A voltage, E, whlch is proportional to -~-T- . As shown in Figure 1, the o logarlthm of the dielectric constant, is linear with the ~: ~ 5 `` ~
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concentration of fountain solution, C. Therefore, El is con-verted to base 10 logarithm by logarithmic amplifier 14. Be-cause a limited logarithmic range is required, unit 14 can be constructed from an inexpensive operational amPlifier and an appropriate NPN transistor, or can be purchased as a modular unit as shown later in the schematic diagram. In fact, at low concentration of water (e.g., 0-20% water), the relationship between water concentration and dielectric constant E ~ iS suff-iciently linear to provide an accuracy of + 1% without a logar-ithmic amplifier. Consequently, for meters used only for measur-ing concentrations less than about 20% water, logarithmic ampli-fier 14 can be eliminated. The output voltage, E2, is propor-tional to the concentration of water, C, offset by some arbitrary voltage as shown by the relationship: E2 ~ KC + log EoI . Log ~O' is a constant for the particular type of ink being tested.

The final stage of the water-ink mixture meter is an amplifier 16 for conditioning the signal from logarithmic ampli-fier 14 and a display device 18 for reading out the signal.
Amplifier 16 has an adjustable offset voltage and an adjustable gain from 0.95 to 20 in order to provide a voltage output of 0 volts when the concentration of water in the water-ink mixture is 0 (C = 0) and 5 volts when its concentration is 50% (C - 50%).

A functional schematic diagram of the meter is shown in Figure 3. The unit consists of an oscillator (multivibrator) which uses amplifier Al shown at the upper left hand corner. A
three position switch is used to select the appropriate feedback capacitors to set the frequency based on some reference point (e.g., empty cell or known ,.

~23~ 3 ink-water system). The output from the oscillator is amplified (Amplifier A2) by an amount determined by the positive ~ain setting, (50 ~ 2)/x where x is the resistance between the wiper of the 50 k~ potentiometer and ground (in k~ ). This is a non-critical setting and is needed only to ensure that there is a proper signal amplitude to trigger the frequency-to-voltage con-verter (Burr-Brown VF32) shown in the lower right corner of the figure. This integrated circuit provides a voltage directly pro-portional to the frequency. A reference voltage to input 1 pro-vides a reference voltage for the logarithmic zero point.
This constant voltage is then fed into a logarithmic amplifier (surr-Brown Log 100 module) shown at the bottom center of Figure 3. This is connected such that a 3-decade span per 10 V
is maintained. A reference current to pin 14 is supplied by a simple current regulated circuit shown below the log-amplifier.
The output of the unit is positive above a 1 V input (log 1 = 0), and is inverted with the 0 to -1 gain amplifier A4. The gain settings are switched with the appropriate feedback resistors for the multivibrator circuit as shown by the dotted line. This amp-lifier serves two functions. The first is to establish the pro-portionality constant k using the appropriate gain settings as described in the previous section, and the second is to establish the zero point voltage to correct for log ~O'.
The output of A4 is fed into A3 which acts as a buffer for the digital panel meter DM 3100L set for a 0 to 5 volt output.
The unit can be adjusted, for instance, to read 1 volt for 10%
water concentration. The four amplifiers (Al to A4) shown in Figure 3 can ~.r ~- ' ~' .

~:~3~ 3 be combined into a "~uad op-amp" integrated circuit such as National Semiconductor LF 457.
With nominal modification the circuit can be adjusted to operate at any frequency which responds linearly to the dielectric constant of the ink. Frequencies which have been used for various inks range from less than 4 kHz to over 300 kHz. However, care should be taken in constructing the meter to minimize stray capacitance and to use an amplifier with a sufficient gain-bandwidth product and a negligible phase shift belo~ 3 MHz.
Figure 4 shows the design of a capacitor cell 8 for use in the meter of the invention. This cell may be designed so that it can be placed in series with, for instance, a 3/4 inch diameter pipe 19 carrying the water-ink mixture of a large printing press.
The inner member 20 is supported within an outer member 22 and electrically isolated from it by, for instance, nylon screws 24 and nylon spacers 26. Inner member 20 is a tube with closed ends, and it serves as one of the plates of capacitor 8. Oscillator 10 is connected to inner member 20 by metal screw 28 and connector 30. It is insulated from outer member 22 by spacer 26 and insulating bushing 32.
Outer member 22 serves as the other plate of capacitor cell 8. It is electrically connected to oscillator 10 through connector 34. In this design a space of about 0.2 inch i9 pro-vided for the flowing water ink mixture which, as such, becomes the dielectric of the capacitor cell.
The facing surfaces of members 22 and 20 are coated with a thin (0.005 - 0.010 inch) non-conducting polymeric layer (e.g., teflon* . . . . . . . . . . . . . . . . . . . . .

* trade mark I
'.

~ ~3~ } ~lSC~5 cr poly~inyl chloride) to eliminate electrolYtic conductance and to prever,t corrosion.
Numerous variation5 and modification5 can ~e made without departing from the invention. For example, the capacitor cell 8 can be designed as a pair of flat parallel plates rather than the concentric tube desi~n illustrated in Figure 4. The mixture being measured can include ir,~s other than lithographic in~ if the relation between the dielectric constant and the water concentration of the mixture is c-imilar to that for mixtures containing lithographic in~c.
The measurements c~n be made of a flowing stream or simplY of a batch of mixture. ~ccordingly~ it should ~e undenstood that the specific form of the invention described above is illustrative only and is not intended to limit the ~.cope of the invention.

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Claims (7)

THE EMBODIMENTS OF THE INVENTION IN WHICH AN EXCLUSIVE
PROPERTY OR PRIVILEGE IS CLAIMED ARE DEFINED AS FOLLOWS:
1. A meter for measuring the concentration of water in a fluid mixture of ink and water, said meter comprising:
a capacitor cell for containing a fluid mixture;
an audio-frequency oscillator circuit which utilizes said capacitor cell for providing capacitance in said oscillator circuit so that said oscillator circuit provides an output frequency which is inversely proportional to the di-electric constant of said fluid;
a frequency to voltage converter which receives said output frequency of said oscillator circuit and converts it to a first voltage output which is directly propor-tional to said output frequency;
a logarithmic amplifier which receives said first voltage output of said frequency-voltage converter and converts it to a second voltage output which is proportional to the logarithm of said first voltage output and is directly proportional to said concentration of water in said fluid mixture in said capacitor cell; and a display means which receives said second voltage output of said logarithmic amplifier and displays it, whereby said concentration of water in said fluid mixture in said capacitor cell can be measured.
2. The meter as claimed in Claim 1, wherein said fluid mixture is a flowing fluid mixture and said capacitor cell has an inlet and an outlet for receiving and discharging said flowing fluid mixture.
3. The meter as claimed in Claim 1 including a first amplifier between said oscillator circuit and said frequency to voltage converter to provide a signal of proper amplitude for said frequency to voltage converter.
4. The meter as claimed in Claim 1 including a second amplifier to receive the output from said logarithmic amplifier and establish the proper zero point voltage for the mixture being measured and a third amplifier to receive the output of said second amplifier and serve as a buffer for said display means.
5. The meter as claimed in Claim 1, wherein said oscillator circuit includes selectable resistance and capacitance means to select an appropriate feedback to set the frequency for specific mixtures.
6. The meter as claimed in Claim 2, wherein said capacitor cell comprises an inner close-ended cylinder spaced concentrically within an outer open-ended cylinder, and separate electrical connectors to said inner and to said outer cylinders, the space between said concentrically spaced cylinders being provided to contain said flowing fluid mixture.
7. A meter for measuring the concentration of water in a flowing fluid mixture of ink and water, said meter comprising:
a capacitor cell having an inlet and an outlet for receiving and discharging a fluid mixture;
an audio-frequency oscillator circuit which utilizes said capacitor cell for providing capacitance in said oscillator circuit so that said oscillator circuit provides an output frequency which is inversely proportional to the dielectric constant of said fluid, said oscillator circuit having selectable resistance and capacitance means to select an appropriate feedback to set the frequency for specific mixtures;
a first amplifier for amplifying the output of said oscillator circuit;
a frequency to voltage converter which receives said amplified output frequency of said oscillator circuit and converts it to a first voltage output which is directly pro-portional to said output frequency;
a logarithmic amplifier which receives said first voltage output of said frequency-voltage converter and converts it to a second voltage output which is proportional to the logarithm of said first voltage output and is directly proportional to said concentration of water in said fluid mixture in said capacitor cell;

a second amplifier which receives the output from said logarithmic amplifier and establishes the proper zero point voltage for the mixture being measured;
a buffer amplifier which receives the output of said second amplifier; and a display means which receives the output of said buffer amplifier and displays it, whereby said concentration of water in said fluid mixture in said capacitor cell can be measured.
CA000488871A 1985-08-16 1985-08-16 Meter for measuring the concentration of water in a water-ink mixture Expired CA1234503A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CA000488871A CA1234503A (en) 1985-08-16 1985-08-16 Meter for measuring the concentration of water in a water-ink mixture

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CA000488871A CA1234503A (en) 1985-08-16 1985-08-16 Meter for measuring the concentration of water in a water-ink mixture

Publications (1)

Publication Number Publication Date
CA1234503A true CA1234503A (en) 1988-03-29

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Family Applications (1)

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Country Status (1)

Country Link
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2024074812A1 (en) * 2022-10-04 2024-04-11 P.E.S. Technologies Limited Sensor including measurement circuits for determining resistance and capacitance of an environmental condition and a method of operating such a sensor

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2024074812A1 (en) * 2022-10-04 2024-04-11 P.E.S. Technologies Limited Sensor including measurement circuits for determining resistance and capacitance of an environmental condition and a method of operating such a sensor

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