CA1220974A - Acid preservation systems for food products - Google Patents
Acid preservation systems for food productsInfo
- Publication number
- CA1220974A CA1220974A CA000459811A CA459811A CA1220974A CA 1220974 A CA1220974 A CA 1220974A CA 000459811 A CA000459811 A CA 000459811A CA 459811 A CA459811 A CA 459811A CA 1220974 A CA1220974 A CA 1220974A
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- Canada
- Prior art keywords
- percent
- weight
- moisture content
- salad dressing
- fumaric acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A40/00—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
- Y02A40/90—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in food processing or handling, e.g. food conservation
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Abstract
ABSTRACT OF THE DISCLOSURE
.
Fumaric acid is used alone or in combination with acetic acid to preserve acid containing food products from microbiological spoilage in the absence of or at reduced levels of chemical preservative.
.
Fumaric acid is used alone or in combination with acetic acid to preserve acid containing food products from microbiological spoilage in the absence of or at reduced levels of chemical preservative.
Description
~Z(~9~
This invention relates to a method of preserving food products against microbiological spoilage and to the preserved food products obtained thereby.
BACKGROUND OF THE INVENTION
-Growing popularity of health foods and natural foods has greatly increased the need for a method of preventing food spoilage without use of the chemical food preservatives which are usually used. Even when used, it is desired to employ chemical food preservatives at reduced levels. Additionally, certain organoleptic properties which are desirable in some foods are only obtainable in the absence of chemical preser-vatives or when the quantity of chemical preservatives is substantially reduced.
.~
~22~3~'7,f~
Most common food spoilage problems are caused by unwanted growth of bacteria, yeasts and molds. In those foods wherein acid is present, the pH is generally suffi-ciently low that growth of bacteria which are harmful to man or animals is inhibited. Certain bacteria, molds and yeasts, however, may grow under these p~ conditions to cause spoilage.
A recent attempt to solve this problem in low acid foods has been described in ~.S. Patent No. 4,145,451 to - ~les, wherein microbiological spoilage is prevented by use of phosphoric acid in synergistic combination with acetic acid, and in the absence of the usual chemical food pre-servativesO The prior art usage of sugar and organic acids for the preservation of food products including salad dress-ings, mayonnaise, and condiments as well as reference to the well-known relationship between the requirements for sugar ana acid as used in the preservation of foods is also dis-cussed in the Oles patent.
SUMMARY OF T~E INVEMTION
f In accordance with the present invention, storage stable acid containing food products may be prepared by add-ing thereto for preservatiDn purposes fumaric acid or fumaric acid in combination with acetic acid at a level sufficient to prevent spoilage.
Food products including salad dressinys and mayon-naise containing acid may thus be produced wherein micro-biological spoilage is prevented without the use of chemical preservatives. In one preferred embodiment a salad dressing is produced comprising edible oil, sweetener, salt, emul-sifier, water, nonfat dry milk solids, starch, gum, spices and flavors, acetic acid and fumaric acid. In another pre-ferred embodiment a salad dressing is produced comprising edible oil, water, acetic acid and ~umaric acid.
Thus, in accordance wi~h the present invention, a method is provided for preparing low acid food products which are stable against spoilage without the presence of chemical preservatives or with reduced levels of chemical preservatives~
An advantage of the present invention is that the need ~or chemical preservatives can be eliminated and pre-servation of acid containing food products can be achieved without increasing the total titratable acid content of the f~od product.
Another advantage of the present invention is that food pro~ucts having reduced levels of acetic acid are pro-vided at given sugar contents which are preserved against spoilage without the use o chemical perserva~ives.
An additional advantage of the present invention is that food products are produced which have a lower level o~ perceived tzrtness and which thus may be more organolep-tically desirable.
The food compositions of the present invention comprise between 0 and about 60 percent by weisht edible oil, between about 20 an~ about 96 percent by weight moisture, between about 0 znd about 30 percent by weight sweetener, and the balance is food solids an~ a preserving system containing fumaric acid alone or in combination with acetic acid. The food compositions contain about O percent to 1.8 percent acetic acid and about 0.1 percent to 1.5 percent fumaric acid, the percent acetic and fumaric acids being expressed as weight percent based on total moisture present.
All other percents are calculated as wei~ht percent of the total composition.
Generally, consistent with producing ~ palatable food composition acetic acid is added until the desired level of tartness is attained and then fumaric acid is added until effective preservation is achieved. The relative amounts of acetic and fumarir acid added to the product are chosen ~o pxovide effective preservation of the food product against microbiological spoilage in the absence of chemical preservatives. Alternatively, the relative amounts of acid are chosen to allow the amount of chemical preservative needed t~ prevent microbiolo~ical spoila~e to be reduced.
( Microbiological spoilage, as used herein, is that spoilage caused by ~rowth of yeast, mold and/or bacteria, including lactobacilli. Effective Preservation, as used herein, is die off of lactobacilli, yeast and/or mold at both high and low contamination levels in f~ur weeks. Die off for high level inoculations is at least a 3 log drop in contaminants. Die off for low level inoculations is at least a 1 log drop in contaminants.
In those food products wherein acetic acid is not normally an ingredient or is not re~uired for flavor, fumaric acid may be used with or without acetic acid as a ~2~g~
preservative to prevent microbiological spoilage in the absence of chemical preservatives. Alternatively, the fumaric acid may be added in quantities sufficient to reduce the amoun~ o chemical preservative required to prevent microbiological spoilage.
Optional ingredients used in producing the food products of this invention include, but are not limited to, egg yolk, buttermilk, buttermilk solids, dehydr ted sour Y cream, nonfat dxy milk solids, food particulates, such as i~ 10 bacon, cheese and minced ~nions, salt, gums, such as xanthan and algin derivatives, emulsifiers, starch, spices and flavors, ethylenediaminetetraacetic acid (hereinafter EDTA), and a low level of chemical preservatives, such as potassium sorbate and sodium benzoate.
1~ The ingredients utilized in the food pro~ucts of this invention are well known. Any of the well known triglyceride oils or mixtures thereof derived from oil seeds may be used, for example cottonseed, soybean, corn or saf-flower. Sweeteners including sucrose, dextrose, fructose and corn syrup solids may be used. Sucrose is the preferred sweetener. The level of use of sweetener is determined based on its sweetening power as compared with sucrose as the standard (hereinafter sucrose equivalent). Artifical sweeteners also may be used.
The acetic acid is typically incorporated in the formulations of this invention as vinegar of about 100 grain strength, i.e., abou lC~ acetic acid.
The source of egg yolk may be whole eggs or dry or liquid egg yolk and may be fresh or frozen. The egg yolk ~ L~Z~ 4 content is expressed in terms of egg yolk solid in the examples provided herein. The gums, starches, spices and flavors that are utilized in this invention are well known to those in the food industry and are conventionally em-ployed for food uses. While a gum and a starch may beutilized together, generally if a starch is added the gum is omitted and vice versa. Moisture, as used herein, includes moisture in water, bu~termilk and lactic acid.
The food products of this invention may be pour-able or semisolid, emulsified or nonemulsified, they maycontain oil ~r be oilless as that term is generally under-stood in food technology. The food products of this inven-tion include, but are not limited to, saiad dressings as that term is broadly understood, ~hat is a salad dressing is any savory li~uid or semisolid cooked or uncooked food which may be used as a dressing for salad. Salad dressing as used herein is understood to include but not be limited to:
mayonnaise, two-phase Italian dressing, oil-free dressing, French dressing, cucumber dressing, Blue cheese dressing, creamy Italian dressing, sour cream and bacon dressing and imitations thereof, including those for which federal stan~ards have and have not been adopted. Salad dressin~ as used herein is also understood to include that food product similar in appearance to mayonnaise but which is stiffened by an addition of a cooked starch paste. Sandwich spreads - u~ilizing a mayonnaise or salad dressing base are also within the scope of the present invention.
In those food products which normally include acetic acid as an ingre~ient an improved effect is observed ,~2~q~
when the amo~nt of acetic acid is reduced and fumaric acid is substituted therefor in an amoun~ such tha~ the total amount of titratable acid is the same as it would be if only acetic acid had been used.
The inventors have discovered that if the quantity of acetic acid is selected so that the desired degree of tartness is achieved, and then fumaric acid is added so that the ~otal ~i~ra~able acid available is equal to that amount ., availab~e in the previously formulated food product con-i~ 10 taining only acetic acid, the need for chemical preserva-tives to prevent microbioloyical spoilage is eliminated.
Alternatively, the amount of chemical preservative which is necessary to prevent spoilage is greatly reduced when fumaric acid is added but the total titratable acid is less than the a~ount of titratable acid present in the ori~inal formulation.
Only small amounts of fumaric acid need be used alone or in combination with acetic acid. Generally, about 0.1 percent to about 1.5 percent fumaric acid based on total moisture is (. necessary. Any food grade fumaric acid is suitable.
Generally, consistent with the aim of producin~ a palatable food composition for the purpose intended, the food prod~cts of this invention may have any of the ingre~
dients lis~ed below at the indicated levels. All percents are based on wei~ht percent of the total composition except that the percent fumaric acid and acetic acid are expressed as weight percent base~ on total moisture presen~.
7'~
INGREDIENT WEIGHT PERCENT
Oi~ 0-60 Moisture 20-96 Sweetener 0-30 Egg Yolk 0-8 Food particulates 0-20 Nonfat Milk Solids 0~10 S~lt 0-5 Gums 0-5 Emulsifiers 0-1 Spices and Flavors 0-10 7 Starch . 0-20 Acetic Acid 0-1.~
Fumaric Acid 0.1-1,5 ~5 A typical hiyh oil containing dressing for salad, which may be either semisolid or pourable, might have ~he following composition:
INGREDIENT W - .c~r ~rRc~$
Ranqe SPecific Exam Oil 30-60 ~0.0 Moisture 20-50 32.97 Sweetener 0-20 8.0 ; E~ Yolk 0-8 2.0 ~ood Particulates 0-25 Nonfat Milk Solids 0-10 2 Salt 0-5 1.~
Gums 0-2 0.75 Starch 0-20 0 Spices and ~lavors 0-5 2.0 Acetic Acid 0-1.8 1.1 Fumaric Acid 0.1-1.50 1.28 ~L~21~ '74 A typical low-oil containing dressin~ for ~salad, which may be either pourable or semi.solid, might have the following composition:
INGREDIENT WEIG~T PERCENT
RangeSpecific Example Oil 1.5-2.0 15.0 Moisture 25-90 67.22 Sweetener 0-25 10.0 Egg Yolk 0-8 0.0 .
10 Emulsifiers 0-1 0.3 Nonfat Milk Solids 0-10 0.0 Salt 0-5 2.0 Gums 0-5 1 5 Starch 0-20 0.0 Spices and Flavors 0-10 2~5 Food Particulates 0-25 0.0 Acetic Acid 0-1.8 0.89 Fumaric Acid 0.1-1.5 1.31 A typical oilless dressing might have the following composition:
INGREDIENT WEIGHT PERCENT
_ Range Specific Example Oil <1.5 .75 Moisture 50-96 73.02 Sweetener 0-30 15.0 Food Particulates 0-25 2.0 Nonfat Milk Solids 0-10 0.0 Salt 0-5 2.0 Gums 0-5 2.5 Starch 0-20 0.0 Spices and Flavors 0-10 3.0 Acetic Acid 0-1.8 0.96 Fumaric Acid 0.1-1.50 1.41 ~Z~
These formulations are presented by way of example only and other formulations for dressings for salads are well kn~wn in the art. Similarly, techniques for the manu-facture of dressing products of the types described herein are well known and within the skill of the art.
EXAMPLES
The following procedure was used to produce the formulations illustrated by Examples 1-5 in ~ABLE I except that in Examples 4 and 5 fumaric acid was not added. All numbers in TABLE I xepresent weight percent of the total composition except that the percent fumaric and acetic acid are expressed as weight percent based on total moisture.
Spices and flavors were mixed together in an 80%
vinegar and 20~ water solution.
~umaric acid was added to the water to form a main mix. The main mix was heated until the fumaric acid dis-~ solved lapproximately 60~C~.
The main mix was then cooled to approximately 30~C
`~ and the following ingredients were added: vineyar, salt, sugar, hydrolyzed yeast, EDTA, nonfat dry milk solids, spices and flavors and dehyrated sour cream. The resultant mix was agitated at room temperature.
The emulsifier and gum were mixed with a quantity of oil sufficient to form a slurry which W2S then trans-ferred to the mai~ mix. The rest of the oil was then addedto the main mix which was agitated until the oil was ade-quately dispersed. The product was then emulsif ied. There-after, the salad dressing was bottled. It was stored at refrigeration temperature, (approximately 4C) until microbiological testing was begun.
TABLE I
_.
INGREDIENT EXAMPLE
. . _ . .
__ _ Soybean Oil 31.9 31.9 31.9 31.931.9 Moisture 52.0 51.6 50.8 51.351.8 Dehydrated Sour Cream 1.9 1.9 1.9 1.9 1.9 Nonfat Dr~ Milk Solids 0.9 0.9 0O9 0.9 0.9 Sugar 5~7 5.7 5.7 5.7 5.7 Salt 2.9 2~9 2.9 2.9 2.9 Hydrolyzed Yeast 1~3 1.3 1.3 1.3 1.3 Gum 1.3 1.3 1.3 1.3 1.3 Spices and Flavors 1.0 1.0 1.0 1.0 1.0 Emulsifier 0.3 0.3 0.3 0~3 0.3 EDTA o.oog o.oog o.oog o.oog o.oog Acetic Acid 0.96 0.97 0.98 2.9 1.91 Fumaric Acid 0.47 1.47 2.85 0.0 0.0 Resistance to spoilage was determined by inoculating duplicate samples o each salad dressing formulation with 10 to 102 (low level) and 104 to 105 (high level) mixed lactobacilli strains measured as number of organisms/ml of substance and by inoculating samples of each salad dressing formulation with 1 ol to 102 and 104 to 105 mixed yeast strains measured as number of organisms/ml oE substance. Incubation was at 27C and standard microbiological procedures were used to make initial plate counts and plate counts after 4 weeks.
Tests wherein spoilage occurred are indicated by the letter S
in TABLE II. The weight percent of fumaric and acetic acid as shown in TABLE II is based on total moisture present.
g~
Effective preservation, as used herein, means die ofE oE contaminant at both high and low contamination levels in Eour weeks. Die off for high level inoculations is at least 3 log drop in contaminants. Die off for low level inoculation is at least a 1 log drop in contaminants.
Borderline preservation, as defined herein, means no increase in contaminant at either the high or low level of inoculation in four weeks. In those cases where growth occurred at either the high or low level, there was no effective preservation as that term has been defined herein.
The results of the microbiological testing on formulations shown in Examples 1 5 are summarized in TABLE
II~ The preservation system contained in ~he formulation of Example 2 demonstrated preservative effectiveness against both high and low lactobacilli growth and was borderline with respect to yeast growth. The preservation system contained in the formulation of Examples 1 and 3 demonstrated preservative effectiveness against both high and low level lactobacilli~
but was not effective as a preservative against yeast growth.
The formulation illustrated by Example 4, which contained no fumaric acid, was ineffective as a preservative against yeast at both high and low inoculation levels and was borderline against lactobacilli growth. The formulation illustrated by Example 5, which contained no fumaric acid~ was ineffective as a preservative against high and low level lactobacilli and also ineffective against high and low level yeast.
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~ 2; . ' ~ tn ~ 13 -Examples ~9 are illustrative of salad dressings having reduced levels of chemical preservatives. The following procedure was used to produce the formulations illustrated by Examples 6-10 in TABLE III except that fumaric acid was not added in Example 10. All numbers used in TABLE III represent weight percent of the total composi-tion except that the percent ~umaric acid and acetic acid are expressed as weight percent based on total moisture present.
Spices and flavors were mixed together in an 80~
vinegar and 20% water solution. Sodium benzoate and potas-sium sorbate were dissolved in water. Fumaric acid was added to water to form a main mix. The main mix was heated until the fumaric acid dissolved! (approximately 60C).
The main mix was then cooled and the following ingredients were added. vinegar, lactic acid, sodium benzoate, potassium sorbate, sucrose, salt, nonfat dry milk solids, buttermilk solids, buttermilk, dehydrated sour cream, and EDTA.
The emulsifier and gums were mixed with a portion of the soybean oil, sufficient to form a slurry which was added ~o the main mix with agitation. The rest of soybean oil was added and mixed until the oil was adequately dis-persed. The salad dressing was bottled and stored at about4C until microbiological testing was begun. The formula-tions of Examples 5-10 were inoculated and tested for microbiological spoilage in the same manner as Examples 1-5 above.
:1 2~V~7~
The results of the microbiological tests on forrnu-lations shown in ~xamples 6-10 are summarized ir~ TAsLE I~. It has been observed that the preservat.ion systems containe~ in the formulation of Examples 6-9 are effective preservatives against lactobacilli at high and low inoculation levels and against yeast at high and low inoculation levels. The formulation illustrated by Example 10, which contained no fumaric acid, was effective as a preservative against yeast but was borderline as a preservative against lactobacilli.
TABLE III
INGREDIENT EXAMPLE
6 ? 8 9 10 Soybean Oil 46.9 38.8 50.0 39.2 49.9 Moisture 27.6 31.1 21.5 31.7 20.4 Dehydrated Sour Cream10.3 15.4 14.8 15.2 15.2 Buttermilk 2.4 2.6 2.2 2.5 2.5 Sucrose 4.2 4.3 4.3 4.3 4.3 Salt 1.4 1.6 1.6 1.6 1.6 Lactic Acid 0.90 0.86 1.0 0.8 0.8 Gum 0.32 0.35 0.25 0.35 0.35 Spices and Flavors 0,09 0.1 0.37 0.29 0.25 Food Particulates2.45 0.9 0.2 0.0 0.0 Sodium Benzoate 0.1 0.1 0.1 0.1 0.1 Potassium Sorbate0.2 0.2 0.1 0.1 0.2 Nonfat Dry Milk Solids2.0 2.0 2.0 2.0 2.5 Emulsifier 0.2 0.2 0.2 0.2 0.2 EDTA 0.0070.007 0.007 0.007 0.007 Acetic Acid 0.93 1.31 1.42 1.25 1.95 Fumaric Acid 0.32 0O32 0.47 0.32 0.0 While there have been described what are believed to be the preferred embodiments of the present invention, those ~2~7~
skilled in the art will recognize that other and further modifications may be made thereto without departiny rom the spirit of the invention and it is intended to claim all such changes as fall within the true scope of the invention.
This invention relates to a method of preserving food products against microbiological spoilage and to the preserved food products obtained thereby.
BACKGROUND OF THE INVENTION
-Growing popularity of health foods and natural foods has greatly increased the need for a method of preventing food spoilage without use of the chemical food preservatives which are usually used. Even when used, it is desired to employ chemical food preservatives at reduced levels. Additionally, certain organoleptic properties which are desirable in some foods are only obtainable in the absence of chemical preser-vatives or when the quantity of chemical preservatives is substantially reduced.
.~
~22~3~'7,f~
Most common food spoilage problems are caused by unwanted growth of bacteria, yeasts and molds. In those foods wherein acid is present, the pH is generally suffi-ciently low that growth of bacteria which are harmful to man or animals is inhibited. Certain bacteria, molds and yeasts, however, may grow under these p~ conditions to cause spoilage.
A recent attempt to solve this problem in low acid foods has been described in ~.S. Patent No. 4,145,451 to - ~les, wherein microbiological spoilage is prevented by use of phosphoric acid in synergistic combination with acetic acid, and in the absence of the usual chemical food pre-servativesO The prior art usage of sugar and organic acids for the preservation of food products including salad dress-ings, mayonnaise, and condiments as well as reference to the well-known relationship between the requirements for sugar ana acid as used in the preservation of foods is also dis-cussed in the Oles patent.
SUMMARY OF T~E INVEMTION
f In accordance with the present invention, storage stable acid containing food products may be prepared by add-ing thereto for preservatiDn purposes fumaric acid or fumaric acid in combination with acetic acid at a level sufficient to prevent spoilage.
Food products including salad dressinys and mayon-naise containing acid may thus be produced wherein micro-biological spoilage is prevented without the use of chemical preservatives. In one preferred embodiment a salad dressing is produced comprising edible oil, sweetener, salt, emul-sifier, water, nonfat dry milk solids, starch, gum, spices and flavors, acetic acid and fumaric acid. In another pre-ferred embodiment a salad dressing is produced comprising edible oil, water, acetic acid and ~umaric acid.
Thus, in accordance wi~h the present invention, a method is provided for preparing low acid food products which are stable against spoilage without the presence of chemical preservatives or with reduced levels of chemical preservatives~
An advantage of the present invention is that the need ~or chemical preservatives can be eliminated and pre-servation of acid containing food products can be achieved without increasing the total titratable acid content of the f~od product.
Another advantage of the present invention is that food pro~ucts having reduced levels of acetic acid are pro-vided at given sugar contents which are preserved against spoilage without the use o chemical perserva~ives.
An additional advantage of the present invention is that food products are produced which have a lower level o~ perceived tzrtness and which thus may be more organolep-tically desirable.
The food compositions of the present invention comprise between 0 and about 60 percent by weisht edible oil, between about 20 an~ about 96 percent by weight moisture, between about 0 znd about 30 percent by weight sweetener, and the balance is food solids an~ a preserving system containing fumaric acid alone or in combination with acetic acid. The food compositions contain about O percent to 1.8 percent acetic acid and about 0.1 percent to 1.5 percent fumaric acid, the percent acetic and fumaric acids being expressed as weight percent based on total moisture present.
All other percents are calculated as wei~ht percent of the total composition.
Generally, consistent with producing ~ palatable food composition acetic acid is added until the desired level of tartness is attained and then fumaric acid is added until effective preservation is achieved. The relative amounts of acetic and fumarir acid added to the product are chosen ~o pxovide effective preservation of the food product against microbiological spoilage in the absence of chemical preservatives. Alternatively, the relative amounts of acid are chosen to allow the amount of chemical preservative needed t~ prevent microbiolo~ical spoila~e to be reduced.
( Microbiological spoilage, as used herein, is that spoilage caused by ~rowth of yeast, mold and/or bacteria, including lactobacilli. Effective Preservation, as used herein, is die off of lactobacilli, yeast and/or mold at both high and low contamination levels in f~ur weeks. Die off for high level inoculations is at least a 3 log drop in contaminants. Die off for low level inoculations is at least a 1 log drop in contaminants.
In those food products wherein acetic acid is not normally an ingredient or is not re~uired for flavor, fumaric acid may be used with or without acetic acid as a ~2~g~
preservative to prevent microbiological spoilage in the absence of chemical preservatives. Alternatively, the fumaric acid may be added in quantities sufficient to reduce the amoun~ o chemical preservative required to prevent microbiological spoilage.
Optional ingredients used in producing the food products of this invention include, but are not limited to, egg yolk, buttermilk, buttermilk solids, dehydr ted sour Y cream, nonfat dxy milk solids, food particulates, such as i~ 10 bacon, cheese and minced ~nions, salt, gums, such as xanthan and algin derivatives, emulsifiers, starch, spices and flavors, ethylenediaminetetraacetic acid (hereinafter EDTA), and a low level of chemical preservatives, such as potassium sorbate and sodium benzoate.
1~ The ingredients utilized in the food pro~ucts of this invention are well known. Any of the well known triglyceride oils or mixtures thereof derived from oil seeds may be used, for example cottonseed, soybean, corn or saf-flower. Sweeteners including sucrose, dextrose, fructose and corn syrup solids may be used. Sucrose is the preferred sweetener. The level of use of sweetener is determined based on its sweetening power as compared with sucrose as the standard (hereinafter sucrose equivalent). Artifical sweeteners also may be used.
The acetic acid is typically incorporated in the formulations of this invention as vinegar of about 100 grain strength, i.e., abou lC~ acetic acid.
The source of egg yolk may be whole eggs or dry or liquid egg yolk and may be fresh or frozen. The egg yolk ~ L~Z~ 4 content is expressed in terms of egg yolk solid in the examples provided herein. The gums, starches, spices and flavors that are utilized in this invention are well known to those in the food industry and are conventionally em-ployed for food uses. While a gum and a starch may beutilized together, generally if a starch is added the gum is omitted and vice versa. Moisture, as used herein, includes moisture in water, bu~termilk and lactic acid.
The food products of this invention may be pour-able or semisolid, emulsified or nonemulsified, they maycontain oil ~r be oilless as that term is generally under-stood in food technology. The food products of this inven-tion include, but are not limited to, saiad dressings as that term is broadly understood, ~hat is a salad dressing is any savory li~uid or semisolid cooked or uncooked food which may be used as a dressing for salad. Salad dressing as used herein is understood to include but not be limited to:
mayonnaise, two-phase Italian dressing, oil-free dressing, French dressing, cucumber dressing, Blue cheese dressing, creamy Italian dressing, sour cream and bacon dressing and imitations thereof, including those for which federal stan~ards have and have not been adopted. Salad dressin~ as used herein is also understood to include that food product similar in appearance to mayonnaise but which is stiffened by an addition of a cooked starch paste. Sandwich spreads - u~ilizing a mayonnaise or salad dressing base are also within the scope of the present invention.
In those food products which normally include acetic acid as an ingre~ient an improved effect is observed ,~2~q~
when the amo~nt of acetic acid is reduced and fumaric acid is substituted therefor in an amoun~ such tha~ the total amount of titratable acid is the same as it would be if only acetic acid had been used.
The inventors have discovered that if the quantity of acetic acid is selected so that the desired degree of tartness is achieved, and then fumaric acid is added so that the ~otal ~i~ra~able acid available is equal to that amount ., availab~e in the previously formulated food product con-i~ 10 taining only acetic acid, the need for chemical preserva-tives to prevent microbioloyical spoilage is eliminated.
Alternatively, the amount of chemical preservative which is necessary to prevent spoilage is greatly reduced when fumaric acid is added but the total titratable acid is less than the a~ount of titratable acid present in the ori~inal formulation.
Only small amounts of fumaric acid need be used alone or in combination with acetic acid. Generally, about 0.1 percent to about 1.5 percent fumaric acid based on total moisture is (. necessary. Any food grade fumaric acid is suitable.
Generally, consistent with the aim of producin~ a palatable food composition for the purpose intended, the food prod~cts of this invention may have any of the ingre~
dients lis~ed below at the indicated levels. All percents are based on wei~ht percent of the total composition except that the percent fumaric acid and acetic acid are expressed as weight percent base~ on total moisture presen~.
7'~
INGREDIENT WEIGHT PERCENT
Oi~ 0-60 Moisture 20-96 Sweetener 0-30 Egg Yolk 0-8 Food particulates 0-20 Nonfat Milk Solids 0~10 S~lt 0-5 Gums 0-5 Emulsifiers 0-1 Spices and Flavors 0-10 7 Starch . 0-20 Acetic Acid 0-1.~
Fumaric Acid 0.1-1,5 ~5 A typical hiyh oil containing dressing for salad, which may be either semisolid or pourable, might have ~he following composition:
INGREDIENT W - .c~r ~rRc~$
Ranqe SPecific Exam Oil 30-60 ~0.0 Moisture 20-50 32.97 Sweetener 0-20 8.0 ; E~ Yolk 0-8 2.0 ~ood Particulates 0-25 Nonfat Milk Solids 0-10 2 Salt 0-5 1.~
Gums 0-2 0.75 Starch 0-20 0 Spices and ~lavors 0-5 2.0 Acetic Acid 0-1.8 1.1 Fumaric Acid 0.1-1.50 1.28 ~L~21~ '74 A typical low-oil containing dressin~ for ~salad, which may be either pourable or semi.solid, might have the following composition:
INGREDIENT WEIG~T PERCENT
RangeSpecific Example Oil 1.5-2.0 15.0 Moisture 25-90 67.22 Sweetener 0-25 10.0 Egg Yolk 0-8 0.0 .
10 Emulsifiers 0-1 0.3 Nonfat Milk Solids 0-10 0.0 Salt 0-5 2.0 Gums 0-5 1 5 Starch 0-20 0.0 Spices and Flavors 0-10 2~5 Food Particulates 0-25 0.0 Acetic Acid 0-1.8 0.89 Fumaric Acid 0.1-1.5 1.31 A typical oilless dressing might have the following composition:
INGREDIENT WEIGHT PERCENT
_ Range Specific Example Oil <1.5 .75 Moisture 50-96 73.02 Sweetener 0-30 15.0 Food Particulates 0-25 2.0 Nonfat Milk Solids 0-10 0.0 Salt 0-5 2.0 Gums 0-5 2.5 Starch 0-20 0.0 Spices and Flavors 0-10 3.0 Acetic Acid 0-1.8 0.96 Fumaric Acid 0.1-1.50 1.41 ~Z~
These formulations are presented by way of example only and other formulations for dressings for salads are well kn~wn in the art. Similarly, techniques for the manu-facture of dressing products of the types described herein are well known and within the skill of the art.
EXAMPLES
The following procedure was used to produce the formulations illustrated by Examples 1-5 in ~ABLE I except that in Examples 4 and 5 fumaric acid was not added. All numbers in TABLE I xepresent weight percent of the total composition except that the percent fumaric and acetic acid are expressed as weight percent based on total moisture.
Spices and flavors were mixed together in an 80%
vinegar and 20~ water solution.
~umaric acid was added to the water to form a main mix. The main mix was heated until the fumaric acid dis-~ solved lapproximately 60~C~.
The main mix was then cooled to approximately 30~C
`~ and the following ingredients were added: vineyar, salt, sugar, hydrolyzed yeast, EDTA, nonfat dry milk solids, spices and flavors and dehyrated sour cream. The resultant mix was agitated at room temperature.
The emulsifier and gum were mixed with a quantity of oil sufficient to form a slurry which W2S then trans-ferred to the mai~ mix. The rest of the oil was then addedto the main mix which was agitated until the oil was ade-quately dispersed. The product was then emulsif ied. There-after, the salad dressing was bottled. It was stored at refrigeration temperature, (approximately 4C) until microbiological testing was begun.
TABLE I
_.
INGREDIENT EXAMPLE
. . _ . .
__ _ Soybean Oil 31.9 31.9 31.9 31.931.9 Moisture 52.0 51.6 50.8 51.351.8 Dehydrated Sour Cream 1.9 1.9 1.9 1.9 1.9 Nonfat Dr~ Milk Solids 0.9 0.9 0O9 0.9 0.9 Sugar 5~7 5.7 5.7 5.7 5.7 Salt 2.9 2~9 2.9 2.9 2.9 Hydrolyzed Yeast 1~3 1.3 1.3 1.3 1.3 Gum 1.3 1.3 1.3 1.3 1.3 Spices and Flavors 1.0 1.0 1.0 1.0 1.0 Emulsifier 0.3 0.3 0.3 0~3 0.3 EDTA o.oog o.oog o.oog o.oog o.oog Acetic Acid 0.96 0.97 0.98 2.9 1.91 Fumaric Acid 0.47 1.47 2.85 0.0 0.0 Resistance to spoilage was determined by inoculating duplicate samples o each salad dressing formulation with 10 to 102 (low level) and 104 to 105 (high level) mixed lactobacilli strains measured as number of organisms/ml of substance and by inoculating samples of each salad dressing formulation with 1 ol to 102 and 104 to 105 mixed yeast strains measured as number of organisms/ml oE substance. Incubation was at 27C and standard microbiological procedures were used to make initial plate counts and plate counts after 4 weeks.
Tests wherein spoilage occurred are indicated by the letter S
in TABLE II. The weight percent of fumaric and acetic acid as shown in TABLE II is based on total moisture present.
g~
Effective preservation, as used herein, means die ofE oE contaminant at both high and low contamination levels in Eour weeks. Die off for high level inoculations is at least 3 log drop in contaminants. Die off for low level inoculation is at least a 1 log drop in contaminants.
Borderline preservation, as defined herein, means no increase in contaminant at either the high or low level of inoculation in four weeks. In those cases where growth occurred at either the high or low level, there was no effective preservation as that term has been defined herein.
The results of the microbiological testing on formulations shown in Examples 1 5 are summarized in TABLE
II~ The preservation system contained in ~he formulation of Example 2 demonstrated preservative effectiveness against both high and low lactobacilli growth and was borderline with respect to yeast growth. The preservation system contained in the formulation of Examples 1 and 3 demonstrated preservative effectiveness against both high and low level lactobacilli~
but was not effective as a preservative against yeast growth.
The formulation illustrated by Example 4, which contained no fumaric acid, was ineffective as a preservative against yeast at both high and low inoculation levels and was borderline against lactobacilli growth. The formulation illustrated by Example 5, which contained no fumaric acid~ was ineffective as a preservative against high and low level lactobacilli and also ineffective against high and low level yeast.
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~ 2; . ' ~ tn ~ 13 -Examples ~9 are illustrative of salad dressings having reduced levels of chemical preservatives. The following procedure was used to produce the formulations illustrated by Examples 6-10 in TABLE III except that fumaric acid was not added in Example 10. All numbers used in TABLE III represent weight percent of the total composi-tion except that the percent ~umaric acid and acetic acid are expressed as weight percent based on total moisture present.
Spices and flavors were mixed together in an 80~
vinegar and 20% water solution. Sodium benzoate and potas-sium sorbate were dissolved in water. Fumaric acid was added to water to form a main mix. The main mix was heated until the fumaric acid dissolved! (approximately 60C).
The main mix was then cooled and the following ingredients were added. vinegar, lactic acid, sodium benzoate, potassium sorbate, sucrose, salt, nonfat dry milk solids, buttermilk solids, buttermilk, dehydrated sour cream, and EDTA.
The emulsifier and gums were mixed with a portion of the soybean oil, sufficient to form a slurry which was added ~o the main mix with agitation. The rest of soybean oil was added and mixed until the oil was adequately dis-persed. The salad dressing was bottled and stored at about4C until microbiological testing was begun. The formula-tions of Examples 5-10 were inoculated and tested for microbiological spoilage in the same manner as Examples 1-5 above.
:1 2~V~7~
The results of the microbiological tests on forrnu-lations shown in ~xamples 6-10 are summarized ir~ TAsLE I~. It has been observed that the preservat.ion systems containe~ in the formulation of Examples 6-9 are effective preservatives against lactobacilli at high and low inoculation levels and against yeast at high and low inoculation levels. The formulation illustrated by Example 10, which contained no fumaric acid, was effective as a preservative against yeast but was borderline as a preservative against lactobacilli.
TABLE III
INGREDIENT EXAMPLE
6 ? 8 9 10 Soybean Oil 46.9 38.8 50.0 39.2 49.9 Moisture 27.6 31.1 21.5 31.7 20.4 Dehydrated Sour Cream10.3 15.4 14.8 15.2 15.2 Buttermilk 2.4 2.6 2.2 2.5 2.5 Sucrose 4.2 4.3 4.3 4.3 4.3 Salt 1.4 1.6 1.6 1.6 1.6 Lactic Acid 0.90 0.86 1.0 0.8 0.8 Gum 0.32 0.35 0.25 0.35 0.35 Spices and Flavors 0,09 0.1 0.37 0.29 0.25 Food Particulates2.45 0.9 0.2 0.0 0.0 Sodium Benzoate 0.1 0.1 0.1 0.1 0.1 Potassium Sorbate0.2 0.2 0.1 0.1 0.2 Nonfat Dry Milk Solids2.0 2.0 2.0 2.0 2.5 Emulsifier 0.2 0.2 0.2 0.2 0.2 EDTA 0.0070.007 0.007 0.007 0.007 Acetic Acid 0.93 1.31 1.42 1.25 1.95 Fumaric Acid 0.32 0O32 0.47 0.32 0.0 While there have been described what are believed to be the preferred embodiments of the present invention, those ~2~7~
skilled in the art will recognize that other and further modifications may be made thereto without departiny rom the spirit of the invention and it is intended to claim all such changes as fall within the true scope of the invention.
Claims (21)
PROPERTY OR PRIVILEGE IS CLAIMED ARE DEFINED AS FOLLOWS:
1. A preserved salad dressing comprising up to about 60 percent by weight edible oil, between about 20 and about 96 percent by weight moisture, up to about 30 percent by weight sweetener, as sucrose equivalent, up to about 1.8 percent by weight acetic acid, based on the total moisture content of the food composition, and between about 0.1 and about 1.5 percent by weight fumaric acid, based on the total moisture content of the food composition, the amount of fum-aric acid or the combined amounts of fumaric acid and acetic acid being sufficient to preserve the food composition against microbiological spoilage.
2. A salad dressing comprising between about 30 and about 60 percent by weight edible oil, between about 20 and about 50 percent by weight moisture, between 0 and about 8 percent by weight egg yolk solids, up to about 20 percent by weight sweetener, as sucrose equivalent, between 0 and 5 percent by weight salt, between 0 and about 10 percent by weight nonfat dry milk solids, between 0 and about 20 percent by weight starch, between 0 and about 2 percent gum, between 0 and about 1 percent by weight emulsifiers, between 0 and about 5 percent by weight spices and flavours, between 0 and about 25 percent by weight food particulates, up to about 1.8 percent by weight acetic acid, based on total moisture content of the food composition, and between about 0.1 and about 1.5 percent by weight fumaric acid, based on total moisture content of the food composition, the amount of fumaric acid or the combined amounts of fumaric acid and acetic acid being effective to preserve the salad dressing against microbiological spoilage.
3. A salad dressing according to claim 2, further comprising a chemical preservative.
4. A salad dressing comprising between about 1.5 and about 30 percent by weight edible oil, between about 25 and about 90 percent by weight moisture, between 0 and 3 percent by weight egg yolk solids, up to about 25 percent by weight sweetener, as sucrose equivalent, between 0 and about 5 percent by weight salt, between 0 and about 10 per-cent by weight nonfat dry milk solids, between 0 and about 20 percent by weight starch, between 0 and about 5 percent gum, between 0 and about 1 percent by weight emulsifiers, between 0 and about 10 percent by weight spices and flav-ours, between 0 and about 25 percent by weight food partic-ulates, up to about 1.8 percent by weight acetic acid, based on total moisture content of the food composition, and be-tween about 0.1 and about 1.5 percent by weight fumaric acid, based on total moisture content of the food composit-ion, the amount of fumaric acid or the combined amounts of fumaric acid and acetic acid being effective to preserve the salad dressing against microbiological spoilage.
5. A salad dressing according to claim 4 further comprising a chemical preservative.
6. A salad dressing comprising up to about 1.5 per-cent by weight edible oil, between about 50 and about 96 percent by weight moisture, between 0 and about 8 percent by weight egg yolk, between 0 and about 10 percent by weight milk solids nonfat, up to about 30 percent by weight sweet-ener, as sucrose equivalent, between 0 and about 5 percent by weight salt, between 0 and about 25 percent by weight food particulates, between 0 and about 5 percent by weight gum, between 0 and about 20 percent by weight starch, be-tween 0 and about 10 percent by weight spices and flavours, between up to about 1.8 percent by weight acetic acid, based on total moisture content of the food composition, and be-tween 0.1 and 1.5 percent by weight fumaric acid, based on the total moisture content of the food composition, the amount of fumaric acid or the combined amounts of fumaric and acetic acid being effective to preserve the salad dress-ing against microbiological spoilage.
7. A salad dressing according to claim 6, further comprising a chemical preservative.
8. A salad dressing comprising about 50 percent by weight edible oil, about 33 percent moisture, about 2 percent by weight egg yolk, about 2 percent by weight nonfat milk solids, about 8 percent by weight sweetener, calculated as sucrose, about 1.5 percent by weight salt, about .75 percent by weight gum, about 0.1 percent emulsi-fiers, about 2.0 percent by weight spices and flavors, about 1.10 percent by weight acetic acid, based on total moisture content of the food composition, and about 1.3 percent by weight fumaric acid, based on moisture.
9. A salad dressing comprising about 15 percent by weight edible oil, about 67 percent by weight moisture, about 10 percent by weight sweetener, calculated as sucrose, about 2 percent by weight salt, about 0.3 percent emulsi-fiers, about 1.5 percent by weight gum, about 2.5 percent by weight spices and flavors, about 0.9 percent by weight acetic acid, based on total moisture content of the food composition, and about 1.3 percent by weight fumaric acid, based on moisture.
10. A salad dressing comprising about 0.75 percent by weight edible oil, about 73 percent by weight moisture, about 15 percent by weight sweetener, calculated as sucrose, about 2 percent by weight salt, about 2.5 percent by weight gum, about 2 percent by weight food particulates, about 3.0 percent by weight spices and fla-vors, about 0.96 percent by weight acetic acid, based on total moisture content of the food composition, and about 1.4 percent by weight fumaric acid, based on moisture.
11. A salad dressing comprising about 31.9 percent by weight edible oil, about 52 percent moisture, about 0.9 percent by weight nonfat milk solids, about 5.7 percent by weight sucrose, about 2.9 percent by weight salt, about 1.9 percent by weight dehydrated sour cream, about 1.3 percent by weight gum, about 1.0 percent by weight spices and flavors, about 0.96 percent by weight acetic acid, based on total moisture content of the food composition and about 0.47 percent by weight fumaric acid, based on moisture.
12. A salad dressing comprising about 31.9 percent by weight edible oil, about 51.6 percent by weight moisture, about 0.9 percent by weight nonfat milk solids, about 5.7 percent by weight sucrose, about 2.9 percent by weight salt, about 1.9 percent dehydrated sour cream, about 1.3 percent by weight gum, about 0.3 percent by weight emulsifier, about 0.009 percent by weight flavor preserva-tive, about 1.3 percent by weight flavor enhancer, about 1 percent by weight spices and flavors, about 0.97 percent by weight acetic acid, based on total moisture content of the food composition, about 1.41 percent by weight fumaric acid, based on moisture.
13. A salad dressing comprising about 31.9 percent by weight edible oil, about 51 percent moisture, about 1.9 percent dehydrated sourcream, about 0.9 percent by weight nonfat dry milk solids, about 5.7 percent by weight sucrose, about 2.9 percent by weight salt, about 1.3 percent by weight hydrolyzed yeast, about 1.3 percent by weight gum about 1.0 percent by weight spices and flavors, about 0.3 percent by weight emulsifiers, about 0.009 percent by weight EDTA, about 0.98 percent by weight acetic acid based on total moisture content of the food composition and about 2.85 percent by weight fumaric acid based on total moisture content of the food composition.
14. A salad dressing comprising about 47 percent by weight edible oil, about 27.6 percent by weight moisture, about 10 percent by weight dehydrated sour cream, about 9 percent by weight buttermilk, about 2 percent buttermilk solids, about 4 percent by weight sucrose, about 1 percent by weight salt, about 2 percent food particulates, about 0.3 percent by weight gum, about 2 percent by weight nonfat dry milk solids, about 0.1 percent by weight spices and flavors, about 0.2 percent by weight emulsifier, about 0.007 percent EDTA, about 0.9 percent by weight lactic acid, about 0.1 percent sodium benzoate, about 0.2 percent by weight potassium sorbate, about 1.31 percent by weight acetic acid, based on total moisture content of the food composition about 0.32 percent by weight fumaric acid, based on total moisture content of the food composition.
15. A salad dressing comprising about 39 percent by weight edible oil, about 31 percent moisture, about 3 percent by weight buttermilk solids, about 0.9 percent by weight food particulates, about 4 percent by weight sucrose, about 2 percent by weight salt, about 2 percent by weight nonfat dry milk solids, about 15 percent by weight dehy-drated sour cream, about 13 percent by weight buttermilk, about 0.4 percent by weight gums, about 0.2 percent by weight emulsifier, about 0.8 percent by weight lactic acid, about 0.007 percent by weight EDTA, about 0.1 percent by weight spices and flavors, about 0.1 percent sodium benzoate, about 0.2 percent by weight potassium sorbate, about 1.31 percent by weight acetic acid, based on total moisture con-tent of the food composition and about 0.32 percent by weight fumaric acid, based on total moisture content of the food composition.
16. A salad dressing comprising about 50 percent by weight edible oil, about 21.5 percent by weight moisture, about 12 percent by weight buttermilk, about 2 percent by weight buttermilk solids, about 2.0 percent by weight nonfat dry milk solids, about 4 percent by weight sucrose, about 2 percent by weight salt, about 0.007 percent by weight EDTA, about 15 percent dehydrated sour cream, about 0.25 percent by weight gums, about 0.2 percent by weight emulsi-fier, about 0.37 percent by weight spices and flavors, about 1.0 percent by weight lactic acid, about 0.2 percent by weight food particulates, about 0.1 percent by weight sodium benzoate, about 0.1 percent by weight potassium sorbate, about 1.42 percent by weight acetic acid, based on total moisture content of the food composition and about 0.47 percent by weight fumaric acid, based on total moisture content of the food composition.
17. A salad dressing comprising about 39 percent by weight edible oil, about 31.7 percent by weight moisture, about 14.5 percent by weight buttermilk, about 2.5 percent by weight buttermilk solids, about 4 percent by weight sucrose, about 2 percent by weight salt, about 15 percent dehydrated sour cream, about 0.35 percent by weight gums, about 0.2 percent by weight emulsifier, about 0.3 percent by weight spices and flavors, about 0.8 percent by weight lac-tic acid, about 2.0 percent by weight nonfat dry milk so-lids, about 0.007 percent by weight EDTA, about 0.1 percent by weight sodium benzoate, about 0.1 percent by weight pot-assium sorbate, about 1.25 percent by weight acetic acid, based on total moisture content of the food composition and about 0.32 percent by weight fumaric acid, based on total moisture content of the food composition.
18. A method of preserving a salad dressing com-prising the step of providing for the presence therein of up to about 1.8 percent by weight acetic acid, and between about 0.1 and about 1.5 percent by weight fumaric acid, said percentages being based on total moisture content of the food composition.
19. In a method of preserving a salad dressing comprising up to 60% by weight of edible oil between about 20% and about 96% by weight of moisture and up to about 30%
by weight of sweetener as sucrose equivalent, the step of providing for the presence therein of up to about 1.8%
acidic acid and from about 0.1 to about 1.5% fumaric acid, said percentages being weight based on total moisture content of the salad dressing.
by weight of sweetener as sucrose equivalent, the step of providing for the presence therein of up to about 1.8%
acidic acid and from about 0.1 to about 1.5% fumaric acid, said percentages being weight based on total moisture content of the salad dressing.
20. A method of preserving a salad dressing according to claim 19 further comprising the step of in-corporating a chemical preservative in the composition.
21. In a method of preserving a salad dressing comprising about 32 percent by weight edible oil, about 51.6 percent by weight moisture, about 5.7 percent by weight sucrose, the step of providing for the presence therein of about 0.97 percent acetic acid, and about 1.4 percent fumaric acid, said percentages being weight based on the total moisture content of the salad dressing.
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CA000459811A CA1220974A (en) | 1984-07-26 | 1984-07-26 | Acid preservation systems for food products |
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CA000459811A CA1220974A (en) | 1984-07-26 | 1984-07-26 | Acid preservation systems for food products |
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1984
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