CA1212309A - Method for compressing a low temperature high density liquid gas - Google Patents

Abstract

ABSTRACT OF THE DISCLOSURE

This invention provides a method for compressing a low tem-perature high density liquid gas, for example, helium. The method comprises the steps of: withdrawing and transferring the fluid from a storage receptacle to the accumulator of the first inlet of a two stage compressor; compressing the fluid in the first stage to a pressure intermediate that of the storage receptacle and the final pressure at the point of delivery of the fluid; transferring the pressurized fluid from the first stage to a second stage permitting warming of the fluid during transfer and compressing the fluid to the pressure required at the point of delivery; and heat exchanging and warming the fluid exiting the second stage against ambient atmosphere and discharging the warmed fluid to a point of use. The prior art methods of compressing usually require a large capacity heat exchanger and a source of heat, together with a compressor con-taining usually 4 or 5 stages and inter and after stage cooling requiring a driver, a cooling source and devices to remove entrained contaminants, namely, oil in the form of vapors used to lubricate the compressor.

Description

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The present invention relates to a method for compressing a low temperature high density liquid gas. In particular, the method is useful for the compression of liquid helium.

This application is a divisional of copendin~ Canadian 5Application Serial Number 421,814, filed February 17, 1983.

Transportation of large quantities of a liquid cryogen, e.g. helium, from the production plant to a distant location is usually accomplished by liquefying the gas, transferring the 10 liquid into an insulated tank, transporting the tank to a dis- -tant location where, depending on the final usage, the liquid is either stored as liquid, transferred into another insulated liquid container, or converted to gas, warmed to near ambient temperaturel and compressed to high pressure for storage in cylinders. In the case of compression, the process of warming the gas to ambient temperature and then compressing it to high pressure requires a large capacity heat exchanger and a source of heat tapproximately 6700 BTU/thousand standard cubic feet or 1508 Joules/gram), and a compressor containing usually 4 or 5 stages with inter and after stage cooling requiring a driver (approximately 25,500 BTU/thousand standard cubic feet or 5740 3Oules/gram), a cooling source (approximately 25,500 BTU/million cubic feet or 5740 Joules/gram), and devices to remove entrained contaminants namely, oil in the form of vapors used to lubricate the compressor.
Capital cost of this equipment is large. Usually incom-plete oil removal is not only objectionable but often hazardous since the helium may be used in the diving industry as a breath-ing gas carrier. Equipment of this size usually is noisy, gen-erally not transportable and requires, inter alia, constantsupervision while in operation, continual analysis of com-pxessed helium and frequent maintenance.

U.S. Patent 4,156,584 is one example of a helium pump used to compress and transfer liquefied gas but one that will not in and of itselE be able to accomplish the foregoing objectives.

BRIEF SUMMARY OF THE INVENTION
In accordance with one embodiment of the present inven-tion, there is provided a method for compressing a low tempera-ture high density fluid gas comprising the steps of:
withdrawing and transferring the fluid from a storage recepta-cle to the accumulator of the first inlet of a two stage com-pressor; compressing the fluid in the first stage to a pres-sure intermediate that of the storage receptacle and the final pressure at which the fluid gas is to be compressed; trans-ferring the pressurized fluid from the first stage to a second stage permitting warming of the fluid during transfer and com-pressing the Eluid to the pressure required a-t the point oE
delivery; and heat exchanging and warming the fluid exiting the second stage against ambient atmosphere and discharging the warmed fluid to a point of use.
In the above method, a pump for compressing and transfer-ring a cryogenic liquid from a storage receptacle may be uti-lized. The pump may be of the type which comprises a piston mounted for reciprocal movement inside a tubular housing com-municating with the liquid, means to move the piston, means to permit movement of liquid from the receptacle to a variable pumping chamber in the tubular member during a portion of the stroke of the piston of the pump and means to discharge liquid from the pumping chamber through an outlet valve during the reverse portion of the stroke of the piston. The pump may fur-ther comprise a base plate mounted on a support frame for posi-tioning the tubular housing containing a piston rod, one end of which projects from the housing, the projecting end positioned relative to a motor driven fly wheel containing thereon an _.

3~3 eccentric and a four bar linkage disposed between the eccen-tric and the projecting end of the piston rod, the four bar linkage includes as its prime element a beam having at least three mounting points having centers disposed relative to each other at the apecies of a right triangle, the beam positioned by fixing the mounting point at the 90 apex to the frame by means of a rocker arm, and the mounting point at the other apecies to the eccentric and the piston rGd respectively, the connection to the piston rod including a yoke; and a piston of a hollow elongated structure extending substantially the length of the piston rod and mounted for reciprocation through a suitable aperture in the base plate, the piston being sealed to the rod by means of a rigid boot; whereby rotation of the fly wheel causes the linkage to translate rotating motion of the fly wheel to nearly true straight line reciprocating motion of the piston rod so that the piston assembly travels through both the warm zone and cold zone packing with deviations from straight line motion being accommodated by elastic deformation of the piston rod.
In the above pump for compressing and transferring lique-fied gas, e.g., helium, the piston is driven by a motor, the drive mechanism being based upon a four bar linkage wherein rotary motion of the motor or motor driven fly wheel is con-verted to reciprocating motion to drive the piston in a nearly straight line. The piston is driven with negligible losses due to nonlinearity of the drive, the nonlinearity being almost negligible. The pump may further include an improved piston ring assembly to minimize leakage of the cryogen past the pis-ton, a boot assembly to vent air entrained in the cylinder above the piston head and a cushioned discharge valve to pre-vent leakage of fluid past the discharge orifice. A two-stage pump in combination with the associated valving and heat exchan-gers provides means and methods for removing liquefied helium ~Z~23~9 from a storaqe receptacle and vaporizing the liquefied helium with pressurization to approximately 3,000 psi t205 atmos-pheres). The specific energy requirement to perform this com-pression is approximately 1020 BTU/thousand standard cubic feet ~230 Joules/gram).

BRIEF DESCRIPTION OF THE DRAWINGS
Figure 1 is a front elevational view of a pump assembly which may be utilized with the present invention;
Figure 2 is a schematic representation of the four bar drive linkage for the pump;
Figure 3 is an enlarged longitudinal section of the pump of Figure l;
Figure 4 is an enlarged fragmentary view of the pump of Figure 3 illustrating the boot stop.
Figure 5 is a fragmentary section of the pump of Figure 3 illustrating the piston seal.
Figure 6 is an enlarged fragmentary view of the cushioned discharge valve of the pump of Figure 3.
Figure 7 is a schematic representation of a pump together with associated equipment used to pump liquid helium.

DETAILED DESCRIPTION OF THE INVENTION
eferring to Figure 1, the pump assembly 10 includes the pump 12 mounted on a base plate 14 which in turn is affixed to a frame I6 constructed of structural members such as channels which may be arranged and secured together by conventional tech-niques and in a manner to accommodate all the accessory equip-ment as is well known in the art. A motor 18 is mounted on frame 16. Motor 18 drives fly wheel 20 by means of a flexible belt 22 as is well known in the art, the fly wheel 20 being held to the frame 16 in a conventional manner for rotation.
Fly wheel 20 includes an eccentric 2~ which 3~

in turn has mounted thereon a beam 26 having a general-i2ed shape in the form of a L. The assembly of linkages can resemble a letter J giving rise to calling the drive mechanism a "J-drive". Beam 26 has two points 28, 30, positioned so that the center of eccentric 24, points 28 and 30 define a right triangle with the centers at the apices of the right triangle. Point 28 includes a pivot 29 fixed to rocker arm 32 which is in turn journaled to a pivot 34 fixed to a suitable struc-tural member 36 which in turn is fixed to base plate 14and frame 16. Point 30 has a pivot 38 which receives yoke assembly 40 which is in turn fixed to the pump shaft (not shown) via a threaded connector 42. The drive mechanism operates so that when the motor rotates, rotary motion ox the fly-wheel 20 is translated into reciprocating motion of the pump shalt so that the piston inside the pump is driven in a linear reciprocating motion.
The drive mechanism for the piston transmits rotating power from ale motor 18 via a pulley 19 and belt 22 to the fly wheel 20. Fly wheel 20 is keyed to crank shaft eccentric 24. Crank shaft eccentric ~4 drives the beam 26 through tapered roller bearings (not shown). Zero clearance can be maintained.on tapered roller bearings by means of "O" rings (not shown) used .as springs. The "C" rings also seal the crank shaft to the seal ring and prevent loss of grease from the bearing cavity. The drive mechanism consists of the beam 26, coupled to the rocker arm 32, pivot support 36 fixed to base plate 14, and the eccentric 24 of the fly wheel crank shaft to form the four bar linkage. Thus, the coupler point curve of the beau 26 at the piston drive end 38 is nearly a straight line.
Referring to Figure 2, the four bar linkage is schematically shown which produces nearly true straight line reciprocating motion from continuous rotary motion.
The slight deviation from true stlaight line motion is ~Z~

accommodated by a flexible link which is sized to permit trans-mission of both compressive and tensile forces. The linkage transmits continuous rotary motion of the crank AB to bar BC of the four bar linkage AB, BC, CD, AD. Bar BC is moved in such fashion by the crank AB and the constraint of bar CD that a point E extended from bar BC exhibits nearly perfect straight line motion. The deviation from a straight line is accommo-dated by Elexure of bar EF, the length of bar EF is not criti-cal to the drive arrangement if a bearing is employed in the piston. The length of EF is made sufficient for flexure when there is no bearing in the piston and flexure of the bar EF is used to accommodate movement perpendicular to its direction of motion. Thus, it can be demonstrated that the coupler point curve of extension E in the linkage AB, BC, CD, AD has a devia-tion from a straightline of plus or minus .002075 parts (inchesjinch or centimeters/centimeter, etc.) and that an extremely small force perpendicular to the direction of motion of bar EF is imposed on the piston guide even if a rather large force is imposed on bar EF in the direction of its motion.
Prior to the four bar linkage diagrammed in Figure 2 with the dimensions or proportions shown in Table I the closest cata-logued approximation to straight line using a four bar linkage was shown to have a deviation of approximately plus or minus 0.0171 parts (inches per inch or centimeters per centimeter, etc.l as illustrated by John A. Hrones and George L. Nelson in their publication entitled "Analysis of the Four-Bar Linkage its application to the Synthesis of Mechanisms", 1951 published jointly by the Technology Press of the Massachusetts Institute of Technology and Wiley Press, N.Y., N.Y.

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Table I
AB = 1 L

2~
BC = 2.0 L
CD = 2.0 L
2 . 8173 L
CE = 2.0 L
EF æ L

Specific proportions of the four bar linkage shown in Table I
are key to making possible the combination of the four bar link-age and the flexible bar disclosed herein. The combination, in this case, can conveniently handle a load of 8,000 pounds ~3,632 kg) applied in the direction of motion of the bar E with-out buckling the bar, while developing a negligibly small -Eorce or movement perpendicular to the direction of motion. In pre-vious reciprocating drives using a four bar linkage and lever a force of 3,000 pounds (1362 kg) was permissible and the drive was not compact. To achieve similar results with such a drive mechanism a beam length of 30 times the stroke (L) would be required. The drive mechanism disclosed herein accomplishes the same end with a beam length 2 times the stroke and a summed length (DC plus CE) of 4 times the stroke Referring now to Figure 3, the pump 12 is affixed to base plate 14 by a support column 50 which in turn is fixed to cylin-der 52. Disposed within cylinder 52 is piston 54 comprising asolid head 56 machined from a bar of chromium nickel stainless steel affixed to an elongated tubular extension 58 also fabricated from chromium nickel stainless steel. Piston 54 reciprocates inside of cylinder 52 and is positioned by a piston rider 60 and sealed by a piston seal or ring assembly 62 which-is detailed in Figure 5 and will be described ~z~

more particularly hereinafter. Piston 54 is slideably mounted in base plate 14 by means of a rod seal assembly 64 and suitable guiding means 66 as is well known in the axt. Disposed within the piston is a piston rod 68 which is affixed to yoke assembly 40 by means of a threaded bolt connection and nut 70 as is well known in the art. The piston is sealed to the piston rod at the drive end by means of a rigid boot 72 and a pair of o rings 74, 76. Between boot 72 and nut 70 is a boot stop 78 illustrated in Figure 4 and described more fully hereinafter.
Coupled to the cylinder is an inlet valve seat 80 which includes an inlet valve 82 and an attendant inlet valve stem 84. Inlet valve seat 80 has mounted thereon an inlet conduit 86 and nozzle 88 which have affixed thereon a vacuum jacketed accumulator 90. The vacuum jacketed accumulator 90 includes an outer vacuum jacket 92 and an im~er product accumulator (surge vessel) 94 and an inlet conduit 96. A pumpout port 98 is included to achieve the required vacuum for the acc-~ulator 90.
A discharge valve 100 having a poppet 102 is shown generally in Figure 3 and detailed in Figure 6.
Referring to Figure 4, the boot stop 78 of Figure

3 is shown in greater detail. The boot stop 78 includes a groove or recess 79 which forms an indentation on the surface which mates with "O" ring 74 which seals the boot 72 to the piston rod 68. If gas accumulat`es between the piston rod 68 and the inner surface of piston 54 due to either helium leaking past the threaded joint connecting the piston rod ~8 to piston head 56 or air leaking into the space via the boot seals while the apparatus is cold and subsequently expands when warm, "O" ring 74 will deform as shown in Figure 4, thus creating a passage for the gas to pass outwardly of the boot 72. "O" ring 74 popping out of its cavity acts as a relief valve as shown. As the apparatus cools `'O"

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rung 74 will resume its original shape and provide an effective seal. Boot stop 7~ prevents axial motion of the boot relative to the piston rod and piston while permitting torsional motion (wobbling3 of boot 72.
Referring to Figure 5, the piston seal 62 consists of 8 separate assemblies. The first (111), third (113)1 fifth (115) and seventh (117) assemblies are gas block assemblies comprising an unsplit cylinder ring (a which reduces the pressure fluctuations on the succeeding rings. Due to the differential thermal contractions of the rings and piston materials the ring becomes tighter on the piston at lower temperatures.
The rings (a) are made of compounds of polytetrofluoro-ethylene and filler materials sold under the trade designations Rulon LD and FOF-30 which exhibit low wear and frictional behavior in unlubricated sliding contact with chromium nickel stainless steel which is used for the piston material. Retainers (b) for the gas block rings are machined from a metal alloy having low expansion characteristics such as sold under the trade designation Invar 36. The retainer is sealed to the cylinder wall by means of static sealing rings (c) which are an unsplit cylindrical ring of polytetrofluoroethylene sold under the trade designation Teflon. Since the cylinder is fabricated from a chromium nickel austenitic stainless steel as the cylinder cools it contracts inwardly in a radial direction. The retainer ring (b) does not undergo as much inward contraction as the cylinder thus compressing the seal rings (a) and pre-venting leakage past the cylinder wall and retainer.The second (112) and fourth ~114) assemblies consist of a beveled upper ring (d) which is unsplit and a split beveled lower ring (e). The function of the split in ring (e) is to allow for wear of the lower ring (e) while the unsplit upper ring (d) seals the area created by the split. The rings are held together by means of springs (f) which exert axial force on a pusher plate (g) and on the rings themselves. The sixth (116) and eighth (118) assemblies are bevelled rings (h) in a beveled retainer (i) and are split in a direction which limits leakage past the split. These rings (h) are split to allow for wear and have proven to have relatively long life with very low leakage. Assemblies six and eight are mechanically the weakest assemblies in the composite piston seal and are, therefore, near the end opposite the pumping chamber where pressure pulsations are the least.
Figuxe 6 details the energy dissipating valve cushion or cushioned discharye valve 100. Valve 100 is fixed to pump 12 so that poppet 102 closes a discharge orifice seat 120. Valve 100 includes a valve body 121 comprising a cylindrical bore 122, a cylindrical jacket wall 124, aperture 126 for relieving gas pressure and sealing gasket 128, the valve body 121 being removable from the valve receiver 125 in cylinder 52 by suitable 2Q threads as shown. Poppet 102 is guided by a pair of bushings 130, 132 fixed to the body 121. Cushion elements 134, 136 are affixed respectively to the poppet 102 and valve body 121 and have disposed there-between a spring 138. Cushion members 134, 136 are fabricated in such a manner that they have thin elastic sections which will contact each other on excursion of the poppet valve to the open position. Elastic compres-sion of the thin section of the cushion elements 134, 136 cushions the opening of the poppet valve. Normally - 30 when a check valve is subject to rapid dynamic) changes in flow (direction or magnitude) the poppet 102 and spring 138 acquire kinetic energy. If the flow increases in magnitude the direction of motion of the poppet will be called opening If the flow decreases in magnitude sr reverses, the poppets direction of motion will be called closiny. During periods of steady flow the -- ~z~
ll puppet will (eventually) acquire an equilibrium position where, in the absence of other effects, the fluid resistance forces against its face are balanced by the forces exerted by the spring 138. Check valves used in reciprocating pumps and compressors (Doth for the inlet and discharge of each cylinder) are subjected to dynamic flow within each cycle. Therefore, the poppet element 120 is in motion during at least part of each cycle.
The accelerations and velocities of the poppet are not negligible. Unless the dimensions of the valve are sufficient to provide no limit to the poppet motion, the poppet will, when opening strike the stop 136.
When closing the poppet will eventually strike seat 120. The problem is that when the poppet strikes either the stop or the seat it may rebound, and will generally produce forces and stresses on the seat, stop and faces of the poppet. Rebounds from the seat result in a lag between the time at which the valve should close and the time at which the poppet comes to rest in the closed position. This delay results in reverse flow in the reciprocating compression equipment.
Should the impact stresses induced in the seat stop, or the poppet be o sufficient magnitude, yielding, deform-ation and finally fxacture of the valve component can result. Thus, the valve disclosed herein comprises a cushion with no 1uid damping requirements, the cushion relying on the elasticity of the cushion materials. It is only active when the valve is nearly fully opened, thus providing for minimized rebound of the poppet valve during the opening portion of the cycle.
Referring back to figure 3, the piston rod 68 is a slender beam o sufficient cross-section to prevent buckling of the rod, but relatively weak in bending so that the plus or minus ~0083 inch (.22 millimeter) deviation from linear motion develops an insignificantly small bending moment on the piston 54. Piston 54 is 3~

guided by guiding means 60, 61 and 66 and moves in reciprocating fashion within cylinder 52. The hollow piston 54 is sealed to the piston rod by means of the rigid boot 72 flexibly sealed to the rod by means of an "0" ring 74 and flexibly sealed to the piston by means of an "0" ring 76. These "O" rings provide low torsional restraint to the boot while preventing entrance of air into the annular space between the piston rod and the boot. As described in connection with Figure 4, should air enter the annular space it will be vented on warming by the action of "O" ring 74 moving into the groove 79 in boot stop 78.
In operation the vacuum jacketed inlet accumulator 90 is connected to a liquid helium tanker containing product (either liguid or cold supercritical gas) at a pressure of 1 to 125 psig (1.07 to 9.5 atmospheres) by means of a vacuum jacketed conduit or transfer line (not shown). Fluid is admitted through valve 82 which opens when sufficient difference in pressure exists across the valve 82 to balance the valve spring which otherwise holds the valve closed, When opening, the moving elements of the valve acquire kinetic energy which is largely absorbed by the valve spring and partially absorbed by compression of fluid within the valve guide. Energy absorbed by compression of the fluid is partially dissipated by leakage of fluid past the valve stem guide ring and the valve guide bearings.
This damping effect is useful in slowing the valve both as it opens and as it closes. Undamped valves tend to bounce away from the seat more than damped valves, thus delaying the final closing of the valve. The seat of the valve is flat reducing the guidance requirement to achieve a seal thus allowing some further damping kinetic energy in a hydrodynamic sgueeze film.
The discharge valve 100 is as shown in Figure 6, a flat seat valve which is open when pressure forces ~Z~

across the valve face exceed the force is exerted by the spring 138 and pressure forces across the back ace of the valve. Some of the discharge valve kinetic energy is stored in the spring 138 but the remainder is stored in the cushion elements 134 and 136. Part of the cushion stored energy is dissipated as internal friction, the remainder forces the valve to rebound from the fully open position. The damping affect relies primarily on the energy lost to internal friction within the cushion. Some of the closing energy of the valve is dissipated by the hydrodynamic sgueeze film formed at thy flat seat area, some is dissipated in internal friction in the valve face material and seat material, and the remaining undissipated energy causes the valve to bounce or rebound after closing.
Except for the provision for damping valve kinetic energy, both the inlet and discharge valves are conven-tional spring loaded, stem guided, pressure actuated flat faced check valves.
In order to take liquid, liguid and saturated gas or supercritical helium and raise it to a pressure of 3,000 psig (205 atmospheres) at a flow rate of 30,000 to 60,000 standard cubic feet per hour (39 to 78 g/sec) a two-stage pump is utilized. Both stages of the pump 2~ are constructed in an identical manner to the pump shown in the drawing, the system being shown diagramat-ically in Figure 7. Of course, the stages are different in that the first stage would be as shown in Figure 3 and the second stage would be without the vacuum jacketed inlet accumulator (90). A heat exchanger utilizing ambient air fan driven against tubes containing high pressure helium may be used to warm the helium to near ambient temperature. The warmed high pressure helium may be stored in cylinders.
As shown in Figure 7, fluid which may consist of helium gas at supercritical temperature and pressure but high density, or liguid and saturated gas mi~,tures enters the vacuum jacketed accumulator 190. As the piston head 256 of the first stage 200 moves away from the inlet valve (top dead center), the pressure of residual fluid in the pumping chamber drops. when the pressure difference across the inlet valve face exceeds the inlet spring force, -the inlet valve opens admitting fluid to the pumping chamber from the accumulator 190 through a vacuum insulated conduit 286. At top dead center, the pumping chamber is filled with fluid and the inlet valve closes. As the piston descends the fluid trapped in the pumping chamber is compressed until pressure within the pumping chamber exceeds the pressure of the first stage discharge. The discharge valve now opens admitting compressed fluid to the annular chamber 97 (figure 3) surrounding the cylinder.
Despite efforts to thermally isolate this cold chamber, some heat addition to the compressed fluid is anticipated which will reduce the density of the discharge fluid.
This fluid is then compressed in the second stage 300 which is vertually identical in construction and operation to the first stage 200, the fluid entering the second stage 300 now being supercritical gas. The discharye valve of the first stage is oriented to permit the expulsion of any liquid in the first stage cylinder during its downward stroke. The discharge valve of the second stage is oriented vertically to facilitate assembly of the discharge valve, the result being that first and second stage valves are located at the bottom side of their respective cylinders.
To limit the interstage pressure of the first stage discharge both the first and second stage bores and strokes are made identical. The first stage is then a booster for the second stage and interstage pressure i5 developed solely from the heat gained to the first stage fluid. Both stages are identical in ~Z~

volumetric capacity however, if only low density super-critical gas i5 to be compressed, the first stage may be made volumetrically larger than the second stage.
Typically, liguid, liguid and saturated gas or supercritical dense gas enter the accumulator at a composite density of 0.125 to 0.06 grams per cubic centimeter. In one embodiment of the invention the inlet pressure is limited to 125 psig ~9.5 atmospheres) or less mechanically. The fluid is compressed in the first stage and heated, partially during the admission to the cylinder, partially during compression, and partially after expulsion from the cylinder. Conditions ox the fluid just prior to entering the second stage include an estimated 1,0~0 watt heat gain from all sources which increase the fluid temperature from about 5.8Kelvin to about 8.34GKelvin. Density of the fluid entering the second stage will be equal to the composite density entering the first stage, and interstage pressure will adjust itself according to the amount of heat unavoidably entering the pump fluid in the first stage 200. Fluid enteriny the second stage may be compressed to a maximume of 3,000 psig (205 atmospheres), depending upon the cylinder back pressure, and expelled to a first heat exchanger 400, and at assumed temperature of 21.1~Kelvin. The first heat exchanger 400 is used to re-cool piston ring, leakage (blow-by~ gas from the second stage. This cool blow by gas may be used to maintain pressure on the ullage of liquid containing vessel 500 from which the pump is removiny fluid. The pressure of this blow-by gas stream will slightly exceed that of the vessel, but will not exceed 150 psig (11.2 atmospheres).
The mass flow rate of the piston leakage gas is not usually known but generally increases with increasing discharge pressure, and may increase as the piston rings are worn through operation. The objects are to:

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(a not throw away the leakage gas to atmo-sphere;
(b) maintain or to some extent make up for liquid level declining in the cryogen vessel (500);
(c) not inject impure gas into the cryogen vessel. this leakage gas is expected to be substantially less contarninated than commercial trade A cylinder gas (nominally 99.995% pure);
(d) reduce heat transfer to the liquid surface in the cryogen vessel, or general-ly, to limit the thermal energy returned to the vessel, and (e) reduce the volume-of blow-by gas so that most or preferably all) of it can be returned to the cryogen vessel (500).
After about 50 hours of operation, the blow-by mass rate appears to be about 1 SCUM (60 SCFH) when the pump discharge pressure is on the order of 2500 psig (171 atm).
The first stage blow-~y is negligibly small (much less than 1/2 SCFM) and this gas is simply vented to atomsphere by a primary and secondary (if required) relief valve.
The discharge gas now enters a second hPat exchanger 402 called a fan-ambient vaporizer, where it will receive heat from the atmosphere until it is nearly as warm as a~ient temperature. The gas may be stored in cylinders gas storage) whose back pressure at any time in the filling process will determine the pump discharge pressure. Cooled blow-by gas will drive remaining liguid out of the vessel connected to the pump inlet and, when the proc ss of emptying this vessel has been completed, the residual gas in the vessel will already be warmed to at least 22K, thus dense vapor recovery 3~
]7 techniques will not be necessary prior to returning the vessel for refilling.
The use of a discharge gas thermal shield surrounding each stage (in the annulus surrounding the cylinder) is thermodyna-mically sound and eliminates the need for a vacuum jacketaround the cylinder and a separate accumulator tsurge vessel) for the discharge streams of each stage. This is not thermody-namically appropriate for ambient compressor cylinders where the cylinder operates at a higher temperature than ambient.
This feature has not been observed on commercial cryogen pumps.
A pump for compressing and transferring liquid, liquid and gaseous and supercritical helium as contemplated herein will compress 30,000 to 60,000 standard cubic feet per hour (39 to 78 grams/secO) of helium to a maximum pressure of 3,000 psig (205 atmospheres). The maximum power consumption for such a unit is 25 horsepower including the 5 horsepower fan for the fan ambient vaporizer. Typically, the method according to the invention using the above described apparatus thus yields a maximum compression requirement of 1,700 BTUs per thousand stan-dard cubic feet (383 Joule/gram) and a heating power require-ment of 425 BTU per thousand standard cubic meet (196 Joules/-gram). Total maximum power consumption is 2,125 BTU per thou-sand standard cubic feet (478 Joules/gram). The method accord-ing to the present invention requires no heat exchanger cool-ing, no oil vapor removal equipment, and maintenance should beappreciably reduced due to the small size and reduced number of stages used. The above-described unit may prove comparable to warm compression systems in noise and supervision but should not require continuous analysis of the compressed gas. The above-described unit can be mounted on a skid and is readily transportable requiring only connection to a 25 kilowatt source of electric power to the liquid containing vessel and to the cylinders to be filled.

Claims (5)

The embodiments of the invention in which an exclu-sive property or privilege is claimed are defined as follows:

1. A method for compressing a low temperature high den-sity fluid gas comprising the steps of:
withdrawing and transferring said fluid from a stor-age receptacle to an accumulator of a first inlet of a two stage compressor;
compressing the fluid in the first stage to a pres-sure intermediate that of the storage receptacle and the final pressure at which said fluid gas is to be compressed;
transferring the pressurized fluid from the first stage to a second stage permitting warming of the fluid during transfer and compressing said fluid to the pressure required at the point of delivery; and heat exchanging and warming the fluid exiting the second stage against ambient atmosphere and discharging said warmed fluid to a point of use.

2. A method according to claim 1 wherein leakage gas from a second stage piston of said second stage of said two stage compressor exchanges heat with compressed fluid exiting said second stage.

3. A method according to claim 1 wherein discharge gas is used to thermally shield said first and second compression stages.

4. A method as defined in claim 1, 2 or 3, wherein said low temperature high density fluid gas is selected from the group consisting of liquid gas, liquid and saturated gas, liquid helium and helium gas at supercritical temperature and pressure but high density.
.

5. A method according to claim 1, 2 or 3 wherein said low temperature high density gas is liquid helium.