CA1210234A - Spraying apparatus - Google Patents

Spraying apparatus

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Publication number
CA1210234A
CA1210234A CA000454753A CA454753A CA1210234A CA 1210234 A CA1210234 A CA 1210234A CA 000454753 A CA000454753 A CA 000454753A CA 454753 A CA454753 A CA 454753A CA 1210234 A CA1210234 A CA 1210234A
Authority
CA
Canada
Prior art keywords
nozzle
liquid
body member
generator
cartridge
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
CA000454753A
Other languages
French (fr)
Inventor
David J. Owen
Colin G. Maclaine
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Procter and Gamble Co
Original Assignee
Imperial Chemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from GB838313959A external-priority patent/GB8313959D0/en
Priority claimed from GB838322308A external-priority patent/GB8322308D0/en
Priority claimed from GB838326666A external-priority patent/GB8326666D0/en
Application filed by Imperial Chemical Industries Ltd filed Critical Imperial Chemical Industries Ltd
Application granted granted Critical
Publication of CA1210234A publication Critical patent/CA1210234A/en
Expired legal-status Critical Current

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  • Electrostatic Spraying Apparatus (AREA)

Abstract

Abstract Spraying apparatus Electrostatic spraying apparatus e.g. for graphic works having a hand or finger held body carrying a nozzle to which the atomising potential is applied from a high voltage generator.
the nozzle is of the non-drip type, e.g. a capillary bore or a felt- or fibre- tip so that no liquid is dispensed therefrom in the absence of the atomising potential. The nozzle and liquid reservoir may be a cartridge, e.g. a felt-tip graphic marker.
the generator may be with n the body so as to provide a self contained unit which can be "earthed" via the user's hand.

Description

~2~23~

1 ~ 32649 This invention relates to spraying apparatus, and in particular to spraying apparatus that ca~. be held in the human hand preferably between the digits thereof, for applications such as graphic work where it is desired that the area to which the spray i~ applied oan be precisely controlledO
One form of digit held spray applicator that has been used heretofore ~or graphic work is the so-called ~air brush" -~herein an applicator having a body member de~igned to be held between the digits o~ the humRn hand is provided with a nozzle through which the liquid may be dispe~sed from a reservoir as a spray. The applicator is connected, generally via a flexible tube, to a source of propellant for atomising the liquid as a spra~ from the nozzleO The propellant source is typically an air compressor or a canister of liquified, compressed, gasO
Suita~le air compressors tend to be relatively bulk~, noisy and e~pensive while canisters o~ propellant become exhausted relatively quickly thereby presenting con~iderable operating expense. Such air-brushes, although somewhat cumbe~some, are however widely used by tho~e engaged in graphic work, e.gO
designers, artists, eignwriters, model makers, and decorative coach worke~s~
In graphic work, eOg. drawing or writing, marking implements employing liquid inks have a nozzle, and ink supply thereto, of the type that, whe~ the nozzle is in contact with a ~urface beneath the nozzle that is receptive to the ink and is 3 ~
2 ~ 32649 moved relative to, but in contact with the surface, ;nk i5 trans-ferred from the nozzle on to the surface, but ~hen the nozzle is disposed abo~e, and out of contact with, a surface, no ink is dispensed from the nozzle.
Such marking impliments include fountain and ball point pens, and markers employing a porous wick-type nib comprising a felt, or plastic, pad, or fibre bundle7 e.g. felt- or fibre- tip pens and graphic markers for example of the type described in ~X
patent specification 628350.
We have found that liquids can be caused to spray from nozzles of this type of construction.
In the apparatus of the present invention, the spray is effected electrostatically by applying a sufficiently large electrical potential, relative to earth, to the nozzle.
It is known, for example from ~S Patent 4356528, that a liquid can be electrostatically sprayed by applying a high potential to a nozzle from which the liquid is to be sprayed so as to cause the liquid to atomise as a spray of electrically charged dropletsO ~owe~er in the arrangement described in that ~S patent, the applied potential effects atomisation of liquid that is flowing, eOg. dripping, from the nozzle, eOg~ by gravity flowO
It has also been suggested in "~aturwissenschaften" 40 (1953) page 337 that the application of a sufficient potential can effect atomisation of a liquid supported by surface tension in an upwardly directed nozzle of capillary dimensions.
The present invention is based on an appreciation that a combination of these teachi~gs can provide a useful precision spraying apparatus.
~ccordingly the present invention provides apparatus for spraying a liquid comprising (i) an elongated body member, sui-table for holding in the human hand, provided with a nozzle at one end, (ii) means for delivering the liquid to said nozzle, (iii) a high voltage generator, and ~2~23~L
3 ~ 3264g (iv) means for applying a sufficiently large electrical potential, relative to earth,from said generator to said nozzle that, when said body member is held in the human hand with the nozzle at a distance of 2 cm above an earthed surface, sufficient electrical gradient is provided at said nozzle to atomise said liquid as a spray of electrically charged droplets, said nozzle and said means for delivering the liquid thereto being of the type that, when said nozzle is in contact with a surface beneath the nozzle that is receptive to said liquid and mo~ed relative to, but Ln contact with, said surface9 liquid is trans-ferred from said nozzle o~ to said surface, but when said nozzle is disposed a~ove, but out of contact with, a surface and no atomising electrical potential is applied to said nozzle, no liquid is dispensed from said nozzle.
~ he nozzle has one or more orifices from which the liquid is dispensed on application of the high potentialO Ihe orifices may be irregular, circular, or annular, for example as provided by a needle or wixe disposed substantially concentric-ally within a circular opening. Iypically, in such cases, theorifi¢e cm ss-sectional area is in the range 0.01 to 1 mm2~
~ nother form of nozzle member comprises a porous wick material protruding from a support. ~he types of porous felt or plastic pads or fibre bundles widely used in graphic implements such ~s felt- or porous plastic- tip markers or felt- or fibre-tip pens a~e eminently suitable as the wick material. In such cases the cross-sectional area of the porous wick can be con-siderably larger than aforesaid, for example up to 1 cm square.
~he noz le configuration is determined by the require-ment that the liquid does not flow, e.g. drip, therefrom in theabsence of an applied high potential and in the absence of a contacting surface. ~his requirement is affected by the nozzle cross-sectional area, the nature of any porous wick, the nature of the liquid, e~g. its surface tension and the pressure to which the liquid is subject, e.gO the head of liquid in the liquid 3 ~
4 3 32649 deliver~ means.
~ he nozzle co~iguration may have some effect on ~he nature of the electrical field at the nozzle and hence on the shape of the spray produced: in the case of a porous pad or fibre bundle nozzle construction, it may be preferable to employ a pad or bundle having a point, h~m-spherical, or "bullet head"
configuration.
~ o obtain satisfacto~y spraying it is preferred that the nozzle configuration is such that the air-liquid interface at the nozzle has at least one radius of curvature below 5 mm~
particularly below 2 mmO
~ he nozzle co~figuration may affect the volumetric flow of liquid through the nozzle when the potential is applied and hence the volumetric spraying rateO ~o vary the flow rate the nozzle may be demountable from the body member so that it can be exchanged for another nozzle of differing configuration.
The viscosity of the liquid will also affect the volumetric flow rate. If desired, provision may be made for va~ying the volu-metric flow rate of liquid thr~ugh the nozzle by means of a suitable v~lve, e~g. a needle valve, controlled e.g. by rotation of a portion of the body member or by a slider thereon~ Such a valve need not dify the size of the nozæle orifice but may be positioned to form a variable flow restriction upstream of the nozzle.
Some form3 of graphic implements, eOg. ball-point pens, rely upon movement of a component, e.g. a ball, relative to a housing therefor to "pump" the ink through the orifice between the component and its housing to t~ansfer the ink on to that sur~ace of the compone~t that contacts the ;nk-receptive surface on which it is desired to make a markO ~he relative movement occurs when the component is moved across the ink-receptive surface~ In the present invention when using this fo~m of nozzle construction, since, during ~praying, there is no contact with the surface to be sprayed, movement of the nozzle relative to the surface being sprayed does not effect that movement of the 2 ~ ~

3 32~49 component relative to its housing and hence the ~Ipump~ action does not occur~ ~herefore to enable such nozzles to be employed, the nature of the liquid should be such that it would flo~l through the orifice formed by the space between the component and its housing, upon contact, and relative movement, of that orifice, rather than the surface of said component, with an ink receptive surface beneath the orifice without relative movement between said component and its housing.
~he body member is shaped so that it is suitable for holding in the human handO ~o this end the bod~ member is elongated and preferably has at least one cross-sectional di-mension below lO cm. Preferably the maæimum cross-sectional dimension is below 10 cmO For fine scale work the body member is preferably shaped so that it may be held between the digits of the human hand. ~hus it may be held between the thumb and one or more fingers or between adjacent fingers depending on the userrs preference. To this end the body member preferably has at least one cross~sectional dimension below 4 cm7 particularly within the range 0~5 to 3 cmO ~he total length of the body member is prefera~ly between 4 and 25 cm, particularl~
between 5 and 20 cm~ It is preferred that the total length of the body member plus nozzle member is below 25 cmO
~ he body member is preferably constructed from an electrically insulating material, e.gO a suitable plastics mater~al but, as mentioned hereinafter, its surface preferably has an electrically conductive portionO
The means for supplying the liquid to be sprayed to the nozzle will generally comprise a reservoir for the liquid and a fluid connection from the rese~oir to the nozzle.
The reservoir may be within the body member or may be mounted on the surface thereof. ~he reservoir may comprise a cartridge, which may be refillable, which can be disconnected from the body member so that the reservoir can be replacedr ~lternatively the reservoir may be remote from the body member and connected thereto by a flexible tubeO Where the 3 ~
6 ~ 32649 reservoir is mounted in, or on, the body member, feed of liquid to the nozzle is preferably effected by capillary action, e.g. 'Dy a wick of porous material e~tending from the nozzle to the reser-voir. ~he reservoir may be a wad of absorbent material, eOg. felt or wadding impregnated with the liquid, within a suitable casing.
l~here the reservoir is remote from the body member, the reservoir may be pressurised to supply the liquia to the nozzle. ~lter~-atively a pump may be used to supply the liquid to the nozzle~
It will be appreciated however that, if the supply of liquid is pressurised, or a pump is employed~ the pressure on the liquid must be insufficient to overcome the forces, e.g~
surface tension forces, preventing flow of liquid from the nozzle when the high potential is nat applied to the nozzle and the nozzle is not in contact with a liquid receptive surfaceO
There may be provision for the simultaneous connection of a plurality of reservoirs to the body member in which case, one or more valves may be provided to regulate the flow from the reservoirs. Where there are two reservoirs, a single valve is preferably provided to vary the relative proportions of liquid flowing from each reservoir: the use of such a valve enables gradual colour ch nges to be obtained in graphic work on a work-pieoe by gradually changing from liquid of one colour from one reservoir to liquia of a^nother colour from a second reservoir as spraying is co~ducted~
In common with 'lair-brushes", the apparatus described hereinbefore presents some cleaning problems: although it can be cleaned by changing the spray liquid to a suitable cleaning solvent, and continuing spr~ying, this is waste~ul of cleaning ~olvent and also is time oonsuming~ Except where, as is des cribed hereinbefore, the bod~ member is provided with a pluIality of reservoirs with valve means to control the flow of liquid there-from and to permit gradual change from one reservoir to another, changing from spraying one liquid to another ma~ also necessitate an inte~mediate cleaning operationO ~hese problems can however be avoided in one preferred fo~m of the invention wherein the 3L2~34 7 ~ ~649 reservoir and nozzle constitute a single cartridge unit which can be removed from the body member and exchanged for ansther cartridge. m e cartridge in such cases is conveniently a felt-or fibre- tip applicator, for example a felt- or fibre- tip marker of the type widely used in graphic workO
In this form of the invention it is necessa~ that the body member is provided with a contact to apply the high potential from the high voltage generator (~hich may be within the body member or remote therefrom) to the cartridge. If the cartridge is of an electrically conductive material, then the high potential is conducted either directly to the nozzle or through the cartridge walls to the liquid therein and thence~ by co~duction through the liquid, to the nozzle~ ~ven where the cartridge is manufactured from a poor conductor, in many cases a sufficiently high potential can be applied to the nozzle via conduction over the cartridge surface. ~owever it is preferred in such a case to provide an electrical connection directly to -the nozzle or to the liquid within the cartridge. Where the liquid reservoir is liquid absorbed on a suitable wad within the cartridge, such a connec-tion can be effected by inserting a suitable conductive stud,e.g. a metal drawing pin, thIough the wall of the cartridge so that the stud contacts the liquid impregnated wad, ~ herefore in accorda~ce with a further aspect of the invention, there i~ provided apparatus for use in the spraying of a liquid from a cartridge ha~ing a casing enclosing a reservoir of the liquid and a nozzle of the type that, when said nozzle is in contact with a surface beneath the nozzle that is receptive to said liquid and is moved relative to, but in contact with, said æurface, liquid is transferred from said nozzle on to said surface, but when said nozzle is disposed above, but-out of contact with, a surface and no atomising electrical potential is applied to said nozzle, no liquid is dispensed fro~ said nozzle, comprising (i) an elongated body member, suitable for holding in the human--hand, and adapted to receive said cartridge with the nozzle thereof projecting from one end of 2 3 ~
8 ~ 32649 said body mem~er, (ii) a high voltage generator, and (iii) mea~s to apply a sufficiently large electrical pote~tial, relative to earth9 from said generator to ~aid cartridge, when said cartridge is fitted to said body member9 that, when said body member is held in the huma~ hand with the nozzle of a cartridge, at a distance of 2 cm above an earthed surface, sufficient elec-trical gradient i8 provided at saia nozzle to atomise aid liquid a~ a spray of electrically charged dropletsO
In a preferred form of the inYention, the body member is adapted to receive cartridges of more than one shape and/or size. ~o enable such cartridges to be employed, there may be provided one or more adaptor components which are fitted as necessa~y to the body member to locate and/or hold diffexent cartridge~ in position and/or to enahle adequate electrical con-nection to the differing cartridges to be made.
~le apparatus of the invention includes mean~ for applying a high pote~tial, relative to earth, to the nozzle or to a co~tact which, when a cartridge containing the nozzle is connected to the body member, enables a high potential to be applied to the nozzleO
~he high potential is provided by a suita~le high voltage gene~ator which may be a piezo-electric generator operated by movement of a suitable component9 e.g 9 a push button or trigger, or a mains, or, particularly, battery p~wered generator~
The ge~erator may be mounted in or on the body member, or may be remote therefrom~ Where a battery powered generator is mounted in the body member, it is preferred that the body member also accomodate6 -the necessary batteries.
Where the generator is remote from the body member or is powere~ from a source remote from the body member, an electrical ~5 connection9 e.g. a M exible lead, is required from the remote 9 ~ 32649 generator, or power source, to the body member. Where the liquid reservoir is also remote from the body member, the high voltage from a remote generator may be applied to the liquid in the reservoir and the potential applied to the nozzle from the liquid in the reservoir via conduction through the liquid in the fluid connection from the reservoir to the body memberO
~ he generator is conveniently of the type employing a transformer to produce high voltage pulses at a frequency of fxom 1 Hz to 20 k~z. Such a generator should be provided with a rectifiex to avoid pulses of opposite polarity7 e.g. as obtained as a result of "ringing", from being applied to the nozzle. Preferably the high voltage circuit has sufficient capacitance that, during use, ths desired electrical gradient at the nozzle is maintained between pulses but on the other hand should have a low stored energy, preferably less lO mJ, SQ
that no safety hazard is presented to the user for example by accidental contact of the user with the nozzle or on contact of the nozzle with an earthed sur~ace~
~he appropriate capacitance may in some cases be provided by the capacitance between the liquid reservoir and/or its casing and an eaI~hed member, e.g. the uæer, rather than by a discrete capacitor component.
It is necessary that the high voltage generator is capable of applying a sufficient potential, relative to earth, to the nozzle that, when the nozzle is held spaced 2 cm above an earthed surface, the liquid is atomised ~rom the nozzle as a spray of electrically charged droplets. It will be appreciated that the applied potential will generally be such as to enable spraying to occur over a range of diætances-of the nozzle ~rom an earthed surface. The potential required at the nozzle to effect such spraying will depend on the nature of the liquid, eOgO
its resistivity and the nozzle con~iguration but will generally be within the range l to 25 kV, in particular between 5 and 20 kV, and may be negative, or, preferably, positive with respect to earth.

~3 ~ 3 ~
~ 3264g lhe field strength at the nozzle is preferably such that the liquid is drawn from the nozzle as one or more charged ligame~ts which then break up into the spray of charged droplets.
When a nozzle with a high potential applied thereto is brought close to an earthed surface7 spark discharges from the nozzle to the earthed surface may occur instead of sprayingq It is preferred that the field strength at the nozzle is such that the maximNm distance of the nozzle from an earthed ~urface at which spark discharges occur is less than 5 mmO At greater dis-tances the field strength is insufficient to cause spark dischargesbut is sufficient to atomise the liquid as it leaves the nozzle as a spray of fine, electrically charged, dropletsO As the nozzle is moved further away from the earthed surface, eventually the field between the nozzle and that surface will drop below that necessar~ to cause atomisation. We prefer that the field strength at the nozzle is such that the distance at which spraying ceases is not more than 30 cm, particularly not more than 15 cm.
It is seen that, for a given applied poten-tial, spray-ing can be caused to stop by moving the nozzle a sufficient dis-tance away from the earthed surface: also, when the nozzle is in contact with the earthed surface, liquid can be deposited thereon by moving the nozzle, in contact with the surface, relative there-to; i.e. in the manner of a conventional marking or writing implement.
Provision ma~ be made for va~ying the pote~tial applied to the nozzle, for example b~ var~ving the generator ou-tput, e.g.
the frequency of production of high voltage pulses and/or their magnitude. mi~ is advantageous since it enables fine, narrow, sprays to be produced, by using relatively low voltages, e.g.
1 - 5 kV, when the nozzle is close to the earthed surface~ by increasing the nozzle potential7 eOg. to 8 - 15 kVl a broader sprag can be obtained with the nozzle at greater distances from the earthed surface. If the higher potential were to be applied with the nozzle close to the earthed sur~ace, a fine enough spray might not be obtainable because of the occurrence of spark discharges.

3 ~
11 ~ 32~4g ~ or applications such as graphic work, the nozzle will generally be held at a distance within-the range 0.5 .o 10 cm from a workpiece9 ~he latter should have sufficient surface and/or volume conductivity that there is rapid dis-sipation to earth of the charge transferred -thereto by the charged droplets alighting thereon.
Paper, thin card, and metal~ are suitable work pieces, even if they already have a layer of paint of lacquer thereonO
~hus the appara-tus may be used for applications such as coach-lining, touch-up painting, workpieces such as automobiles as well as normal graphic art work, ~or many applications the wor~piece will be supported on a work-top, eOg. a drawing board, on which graphic work is performed and providing this work-top is not an insulator, sufficient cllarge dissipation to earth can take place. Preferably -the support is wood, metal, graphite filled plastics _aterial, or a non-conductive ma-terial support provided with a conductive surface layer e.g. al7~m;n;um foil or metallised plastics film fastened, e.g. lami nated, to the supportO
An electrical connection, to form a return path, is re~uired between the generator and the woxkpiece~ Where the generator and/or its power source, is remote from the body member this connection will normally be provided by a direct con-nection, or via the earth, Where the generator is mounted with;n the body member, sufficient electrical continuity to earth can no~mally be provided by conauction through the user!-s hand ~ol~ng the body member thus obviating the need for an electrical lead from the generator to-earthO Conduction from the generator to earth via the user can be facilitated by providing a conductive portion on the body member surface, which por*ion is connected to the gener3tor and to which contact is normally made by the user's hand during spraying.
A switch will normally be provided to switch the high potential applied to the nozzle on and off. mis switch may be, for example, an electronically operated touch sensor switch or a push button or slide switch, provided on the body mem~er or may be a switch, eOg~ foot operated, remote from the body member.

3 ~
12 ~ 32649 In general the high voltage generator will be powered by a relatively low voltage source e.g. the mains or batteries and it is preferred that the switch is located in the low voltage circuit.
Where the switch is hand operated the portion of the switch contacted by the user during spraying may be elec~rically conductive and connected to the generator in order to facilitate the earth connection of the generator.
It will be appreciated that when spraying is taking place7 there will be a re~uction in the potential difference between the nozzle and earth from that potential difference be-tween the nozzle and earth -that exists when no spray m g is taking place, i.e. ~Ihen the electrical gradient at the nozzle is insuf-ficient to cause ato~isationO Ihis reduction results from a number of factors:
(i) the impedance of the return path from the earth to the generatorO Where this impedance is low the effect on the potential difference between the nozzle and the substrate may be insignificant.
However where the return path has a sigaificant impedance9 eOg. where the workpiece has a relatively low conductance and/or the return path includes conduction through the user, the potential differenoe across the retuxn path, and hence the reduction in pot~ntial difference be-tween the nozzle and workpiece may be significant.
(ii) the impedance between the high voltage generator and the nozzle. A significant potential difference re-duction betwee~ the nozzle and workpience may occur 3D if this impedance is high, for example where the high voltage is applied to the nozzle from the generator via conduction over the surface or through a cartridge made of a poor conductor.
(iii) the impedanoe of the leakage return path from the nozzle to the gener~torO This impedance acts as a 2 ~ 4 13 ~ 32649 shunt to the spra~ current and so may result in a significant potential difference reduction between the nozzle and substrate, particularly if the "for-ward" impedance from the generator to the nozzle is high.
It is preferred that generator output voltage and the aforementioned impedances are such that this reduced potential difference between the nozzle and earth is sufficient, prefer-ably above 1 kV, and in particular above 5 kV, to permit spray-ing to continue so that spraying is continuous rather than inte~mittentO
~ he spray current, i.e. the current flowing as a result of the trans~er of the charged atomised liquid droplets from the nozzle, will generally be with;n the range 1 to 5000, and usually below 1000 nAO
~ Masking of the workpiece can be achieved by means of an insulating material~ e~gO a plastics film, disposed over those parts of the workpiece that it is desired not to sprayO Where the mask is placed over the workpiece it will usually be held fixmly in place by the electrostatic charges induced when the applicator i8 brought near to the maskO Masking can also be achieved by the use of an earthed electric~lly conductive material placed over the workpiece~ if the mask is insulated from a work-pie¢e of relatively poor conductivity, eOg. paper or cardg altho~gh the mask m~y become contaminated by the spray, the spray will be repelled in the vicinity of the edges of the mask leaving an unsprayed portion of the workpiece not only under the mask but also around the mask edges~ Also, with a workpiece of relatively poor conductivity, textured effects can be achieved by positioning an earthed, suitably textured, conductive mem~er under the workpiece.
The apparatus of the present invention is of particular utility for graphic work, particularly using a system wherein a conventional graphic marker, e.g. a felt or fibre-tip applicator i3 uæed aæ a cartridge in a body member which is preferably self cont~ined in the sense that the body member contains the high 3 ~ 3 ~
14 ~ 32649 voltage generator and, if the la-tter is electrically po-"ered, rather than of the piezo-electric type, batteries to power the generator~ The liquid that may be used include any liquids that may be dispensed by such markers eOg. inks, which are preferably spirit based, lacquers and varnishes. Where the nozzle is of a type wherein solid particles in the liquid will not be filtered out during passage through the nozzle, e~g. where the nozzle is merely a bore of small cross-sectional dimensions, other liquids such as suspensions, e.g. paints and enamels can be used for graphic applications. ~Jhile aqueous inks, e.g. indian ink can be used, it is prefexred to employ non~aqueous liquids having a resistivity above 104, and in particular between 107 and ohm-cm.
~he liquid typically has a viscosity within the range 10 4 to 10 1 PaDs and a surface tension of 10 2 to 10 1 ~tm.
While of prima~y application to graphic work, the apparatus of the invention may also be used for the localised spray application of other products, for example pesticides e.gO
on to houseplants; anaesthetics; antiseptics and other pharm, aceutical preparations, eOg. for the treatments of wounds or skin blemishes; personal hygiene products; cosmetics; perfumes;
demisting liquids; lubricating oils; a &esives; and d~y clean-ing fluids e.g. grease spot removers.
While the apparatus is capable of spraying when held at 3 om above an earthed surface, in some cases it may be desired to spray the liquid simply into the atmosphere7 eOg. where the liquid is an insecticide, such as a fl~killer, or a perfume or air freshener rather than on to a workpiece~ For such applications it is necessary that an earthed member, which may in some cases be the user's hand, is sufficiently near to the nozzle to act as a field intensifying electrode as described in aforesaid ~S Patent 4356528. However for such cases it is preferred that an electrode is poeitioned adjacent to, but spaced from the nozzle, preferably ! upstream thereof, with an earth connection from said electrode, e.g. via the user. If desired provision may be made for va~Lng 3 ~
~ ~2649 the position of this electrodeO
~ he provision of a field intensifying electrode may, in some cases, also be desirable in a graphic implement as it will enable spraying to continue when the nozzle is a consider-able distance from the workpiece: this is of benefit if it isdesired to apply the liquid to relatively large workpiece areas, e.gO to colour background areas. m e field intensifying electrode may also have an effect on the shape of the spray.-It may be desirable to provide a switch, e.g. a push button or slide switch, on the body whereby the electrical con-nection to the field intensifying electrode to earth may be made or broken. Where connection of the field intensifying electrode to earth is made via the user~ the body member may be provided with an electrically conductive portion on its surface connected to the field intensifying electrode connection of the field lntensifying electrode to earth via the user will then be made when the user con-tacts the electrically conductive portion of the body member surface and will be broken when there iB no such contact.
Hence by making or breaking the electrical connection between the field intensifying electrode and earth, the field intensifying electrode can be rendered operative or inoperative as desiredO
~he invention is illustrated by reference to the accompanying drawings Ln which Figure 1 is a perspective view of one form of the apparatus in accordance with the invention in use~
Figure 2 is a circuit diagram of the high voltage generator used in the apparatus of Figure 1, Figure 3 is a longitudinal section of the applicator used in the apparatus of Figure 1.
Figure 4 is a lo~gitudinal section of an alternative applicator.
Figure 5 is a plan view oP an alteDaative embodiment wherein the liquid reservoir and nozzle comprise a demountable cartridge unit, Figure 6 is a section along the lLne ~-A of Figure 5, 2 3 ~
16 ~ 32649 ~igure 7 is a section along the line ~-~ of ~igure 5 with the cartridge removed, ~igure 8 is a section along the line C-C of ~igure 5, ~igure 9 is a section corresponding to Figure 6 ~,lith an alte~native cartridge fitted, together with a suitable adaptor.
In Figure 1 there is shown a flat drawing board 1 having a metallised surface layer 2 on which the workpiece 3, e.gO a sheet of paper, is resting~ ~t the right hand side of board 1 is a housing 4 containing batteries and a battery powered high volt-age gene~atorO ~he generator circuit is shown in ~igure 2 and consists of a solid state s~itching device 5 powered by batteries 6 via an on/off switch 7 mounted on housing 4. ~he switch;ng device 5 produces pulses which are fed to the prima~y 8 of a trans-former. High voltage pulses are thus produced in the secondarJwinding 9 of the transformer and are rectified by rectifier 10 and fed to capacitor 11. (Capacitor 11 can in some cases be omitted as descxibed hereinafter). One te~minal, Vo, of the gensrator is connected to the metallised surface 2 of board 1 while the other telminal, V~, is connected -to an output socket 12 on housing 40 ~ypically the generato~ is arranged to give an output voltage ranging between 5 and 20 kV at load currents up to 200 n~.
and a maximum power output of less than 10 mW
~he applicator 1~ consis-ts of an elongated cyllndrical pen-shaped impleme~t ha~ing a metal nozzle 14 at one end a~d an imsulated fle~ible electrical lead 15 con~ected to the opposite endO In use lead 15 is plugged into socket 12. Provided the capacitance given by lead 15 is su~icient, capacitor 11 can be omitted from the high voltage generator~
~ he applicator has a body 16 formed from an insulating plastics material which is hollow thus providi~g a reservoir for the liquia to be sprayed. To the end of body 16 the metal nozzle 14 is screw mounted. ~ozzle 14 has a tapered entry region 17, ~5 forming a valve seat, connected to a small diameter bore 18.

~2~ 34 17 ~ 32649 ~ypically the bore diameter will range between Ool and 1.0 mmO
Since nozzle 14 is screw fitted to body 16, it can readily be removed for cleaning or replacement by a nozzle having e.gO a different ent~y region configuration, and/or different bore dimensions.
Surrounding the outer end of body 16 is a metal sleeve 19 which i~ insulated from nozzle 14. The lower end 20 of sleeve 19 acts as a field intenæifying electrode7 when connected to the surface 2 Of board 1 through the user's body.
The other end of body 16 is provided with a screw threaded cap 21 of insulating material to which a needle 22 is fitted extending down the length of the body 16 -to provide a needle valve seating with the entry region 17 of nozzle 14~ The flexible lead 15 is connected through cap 21 to the needle 22~
Even though the needle 22 is not necessarily in contact with the seating 17~ the high voltage will be conducted from needle 22 through the liquid to the nozzle 14~
A sm~ll hole 23 is provided in cap 21 to ast as an air bleed into the reservoir space within the body 16.
~y rotating cap 21 with respect to the body 16, the restriction to ~low of the liquid from the reservoir to the nozzle outlet can be varied thus enabling the rate of spraying to be adjusted.
In an alternative form of applicator shown in Figure 4 25 the bddy 16 has no sepa~ate cap but the flexible wire 15 is fastened to a stud 24 passing through the closed end 25 of the body 16~ Inside body 16 the stud 24 is connected to a wire 26 extending along the body 16 towards, but ending short of, the other end thereof so that the wire 26 contacts the liquid in the 30 reservoir formed by the hollow interior of the body 16. An air vent 23 is provided in the closed end 25 of body 16~ In this embodiment the nozzle assembly comprises a metal tube 27 attached to a moulding 28 of an insulating plastics material screwed on to the lower end of body 160 Screwed on to the ;nner end of moul~ing 35 28 is a cap 29 provided with an orifice 30 to permit flow of liquid 23~
18 ~ 32~49 from the hollow interior of body 160 Mounted inside moulding 28, and retained by cap 29, is a fluted slide member 31 into which a wire 32 is mounted so that it extends axially along tube 27. The flutes 33 of slide member 31 enable the liquid to flow past member 31 to tube 27.
~ he passage between wire 32 which typically has a diameter of 0~2 mm, and the tube 27, which typically has an interior diameter of 0~3 mm, thus form~ an a~nular passage for liquid to be sprayed. Since wire 32 is capable of longitudinal movement, cleaning of this passage is facilitated by engagement of the end of tube 27 with a scrap of material, eOgO paper, to depres~ wire 32.
In an example, an applicator of the type shown in Figure 4 was charged with Indian ink and connected as shown in Figure 1 to a high voltage generator giving a max;lm~m voltage of 8 kV~ Ink sprayed from the nozzle when the latter was 5 to 20 mm from a sheet of paper lying on the metal suxfaced boardO At the maximum current drawn from the generator during spraying, the generator output voltage fell to about 7 k~ between pulses.
When a mask consisting of a piece of non-conducting plastics film was placed over part of the wor~piece9 spraying ceased when the nozzle was over the masked areas, ~he mask was held firmly in place by electrostatic attraction.
In ~he embodiment of ~igures 5 to 9, the apparatuæ is self contained and employs a cartridge unit for the liquid reservoir and nozzle. The cartridge is co~veni~ntly a felt-tipped marker. ~he apparatus of this embodiment is designed to accomodate, with the use of an adaptor, cartridges of different shapes and/or siæes.
The apparatus comprises a body 34-construoted from two shell mouldings 35, 36 formed from an electrically insulating plastics material~ ~hese moul~;ngs may be held together by any suitable means, for example adhesive along the mating surfaces.
Within the shell formed by mouldings 35, 36, interior partitions define housings for a switch assembly 37, batteries 38, 3L~3 2~

a high voltage generator 39 and a high voltage lead 40 there-from. Also mounted within the shell is a cartridge housing 41.
~ he generator 39 is powered, via switch assembly 37, from two 1.5 v dry batteries 38 located within a housing 42.
5 ~he top and bottom of housing 42 are formed by partitions 43, 44 and 45, 46 integral with mouldings 35 and 36 respectively. ~he front end of the housing is likewise formed by partitions 47, 48 integral with mouldings 35~ 360 Adjacent the front end of the batte~y housing 42 are a 19 pair of spring metal contact strips which project through slots 49 in the partions 43, 45 forming the top of the battery housing 4~. Cne of these contact strips is designated by the reference numeral 50 in Fig~re 6.
~he batteries are held in place, and connected in 15 series, by a spring metal contact strip 51 at the ~ear of the batte~y housing 42. ~his contact strip 51 is mounted on a cover plate 52 moulded from an electrically insulating plastics material~
Gover plate 52 is provided with lugs 53~ 54 at its upper and lower ends. ~hese lugs engage, through upper and lower 20 slots 55~ 56 in the shell mouldings, with the shell mouldings to hold cover plate 52 in position. The shell mouldings 35, 36 are provided with ribs 57, 58 adjacent the lower edge of the lower slot 56~ A recess 59 in the lower lug 5~ of the cover plate 52 engages with ribs 57, 58.
Cover plate 52 can be removed, for changing the batteries 387 by pressing inwards against the spring pressure of c~nt~ct 51~ to disengage recess 59 of lug 54 from the ribs 57, 58 and then sliding the cover plate 52 up~ards to disengage lug 53 from the upper slot 55O
~he generator 39 is of the type shown in Figure 2 and is located within an enclosure 60 between the top of shells 35 36 and the partitions 43~ 45 thereof fo~ming the top of the batte~r enclosure 42~ ~he rear of the generator enclosure 60 is fo~med by the ends 61~ 62 of the shell mouldings 35~ 36 35 respectively while the front is formed by partions 63, 64 integral 3~

with moul~;ngs 35, 36 respectively.
Slots 65 are provided in partitions 63, 64 to allow -two rigid leads 66 from the generator 39 to pass throu~h the partitions 63, 64 to the switch enclosure 67.
~he batter~ spring contact 50 is connected directly thl~ugh slot 49 to generator 39 while the other battery qpring contact (not shown) at the front of the batte~y housing 42 con-nects with one of the rigid leads 66 projecting through slots 65.
~he switch enclosure 67 is fo~med by partitions 43,45 and 63, 64, and the front upper portion of shell mould;ngs 357 36.
An opening 68 is provided in mould;ngs 35, 36 into which projects a button 69 moulded from an electrically conductive plastics material. 3utton 69 is pivotally mounted, by means of an integral lug 707 in bosses 71, 72 in-tegral with mouldings 35, 36. The front end of button 69 bears a lug 73 which is urged against the underaide of the front upper portion of mouldin~s 35, 36 adjacent opening 68 by a spring metal contact strip 74. Button 69 also ca~ries on its underside an integrally fo~med projection 75 which bears against a non-latching push-to-make switch 760 Switch 76 is supported by ~igid leads 66. One of these leads also con~ects to contact 74. On closing switch 76 by pressing button 699 the electrical connection from batteries 38 to generator 39 is completed, thus providing power to the generator.
~ounted withîn the shell mouldings 35, 36 is a cartridge housing 41 moulded from an electrically insulating plastics material. ~ousing 41 comprises a first hollow cylindrical portion 77 provided at its front end with a flange 78 which abuts the interior front end of shell mouldings 35, 36, and a second hollow cylindrical portion 79 of reauced diameter fo~ming a rearward extension of the first cylindrical portion 77. The first cylindrical portion 77 is of such internal dimensions -that it can receive a cylindrical oartridge 80, of short, squat, configur-ation with one end of the cartridge projecting from the front of the shell mouldings 35, 36.

12~L~323~

As is shown in ~igure 9, the second cylindrical portio~
79 is of such internal dimensions that it can receive a longer cartridge 81 of reduced cross-section.
Housing 41 al~o has an integrally formed sleeve 82 in 5 which a spring metal contact strip 83 is mounted, soldered to the end of the high voltage lead 40 from generator 39. ~he con-tact strip 83 projects through a slot 84 in the base of -the first cylindrical portion 77 of housing 41 to contact the casing of the cartridge 80 inserted therein.
High voltage lead 40 is led, from contact strip 83, behind the rear of the first cylindrical portion 77 of housing 41, round the outside of the second cylindrical portion 79 o housing 41, betweerl partitions 85, 86 integrally fo~ed in shell moulding 35, in-to the generator enclosure 60 through a slot 87 in 15 partition 43. ~he high voltage lead 40 connects to the high voltage generator at the high voltage output te~ninal 88 on the top of generator 39O Part of the path of lead 40 is shown dotted in Fig~re 7.
In the arrangement shown in ~igures 5 and 6 the cart-20 ridge 80 has a metal casing~ In the embodiment of ~igure 9 how-ever the cartridge 81 has a casing of a non-conducting plastics materialO In order to make electrical contact with the liquid in cartridge 81, a metal drawing pin 89 is pressed through the cartridge walls at such a position that the head OI pin 89 will 25 contact the contact strip 83.
When using the longer, thinner, cartridge 81, in order to hold it in positiorl an adaptor 9~ is employedO (~his adaptor is shown dotted in ~igure 7)O ~he adaptor 90 has an upper surface 91 shaped to fit within the first cylindrical portion 77 of 30 housing 41, a lower surface 92 corresponding to that of the second cylindrical portion 79 of housing 41, and a flange 93 at the front to abut against the front of shell moul~;ngs 357 360 ~ he ca~tridges 80, 81 are of the type having a felt- or fibre- tip 94 projecting from a support 95 at one end of the 35 cartridge. ~ormally the casing of the cartridge encloses a wad or strip of porous material impregnated with liquid.
In use, a cartridge conta;n;ng the liquid to be spra~Jed in inserted in housing 41, if necessary with an adaptor and/or a contact through the cartridge casing, and then button 69 is de-pressed. ~his causes a high potential to be applied fromgenerator 39, via high voltage lead 40 to contact strip 83 and hence to the nozzle 94 via conduction through or over the cart-ridge casing.
When positioned sufficiently close to an earthed surface, the liquid in the cartridge is atomised from the felt-or fibre- tip nozzle 94 as a spray of fine, electrically charged droplets. ~he retu~n path to the ge~erator is formed by con-densation through the u~er contacting button 69) which, being electrically conductive, provides a connection from earth~ via the user, to spring contact 74 and hence, via switch 76, to the generator.
In the following Examples, apparatus of the type shown in Figures 5 - 9 was employed~ The body member, which could be held between the thumb and forefinger, with the latter resting on button 69,had a total length of about 14 cm, a maximum height of 63 mm and a m~ximum width of 39 mm.

A standard "Magic Marker" (R~M) felt-tip marker from the'Studio Colours range (colour A 310 cadmium red) was fitted into the body member as shown in Figure 6~ ~he marker had a metal cap which contacted contact strip 83. The felt-tip on the marker as supplied had a chisel config~ration 3 mm thick and 6 mm deep. ~he generator, which produced high voltage pulses at a frequency of about 20 - 25 Hz, provided a voltage of about 12 kV
at the tip when the button 69 was depressed.
With the tip held at distances 2, 3 and 4 cm above a piece of paper resting on a wooden desk, ink sprayed from the nozzle.
~XINEI~ 2 ~xample 1 was repeated but replacing the standard 12~L~)23~
23 ~ 32649 felt-tip by a cylindrical polyester fibre-bundle tip of 3.7 mm diameter with its end shaped to the bullet-head configuration shown in Figures 5, 6 and 29. When held with the tip 2, 3 and 4 cm above the paper, on pressing button 69 a more intense spray 5 was obtained than in Example 1.
EXA~Iæ 3 Example 2 was repeated with the addition of 1 ml of xylene to the wadding inside the marker to dilute the ink therein. This ink dilution increased the flow rate and the spray intensity.
a~
Example 2 was repeated with similar results, using the following Studio Colour range "Magic Markers" fitted with the bullet head tips:
Fuschia A ~48 Forest Green A 600 Cobalt ~lue A 455 Africano A 262 Cadmium Yellow A 704 ~XA~LB~
~o assess the effect of varying the voltageg and to measure the spray current, the generator in the applicator was disconnected and a high voltage applied to contact strip 83 via a flexible high voltage lead from a remote variable voltage 25 generator. The other terminal of the generator was earthed. To measure the current, the tip was positioned above a metal plate connected to earth via a digital meterO
~ xample 3 was repeated with the tip at 3.5 cm from the plate. At an applied voltage of 12 kV the current was 19 nA
while at 15 kV the current was 60 nA. With 15 kV applied voltage the tip was gradually mo~ed away from -the plate. A spray was still obtained with the tip 9 cm from the plateO With an applied voltage of 9.5 kV good sprays were obtained with the tip between 1 and 7 cm from the plateO

24 ~ 32649 Example 1 was repeated using a standard "Pantone"
(R~M) felt-tip pen type "Warm Red M" in place of the '~agic Marker": in this case adaptor 90 was employed. The pen had a plastic body and a chisel-edge felt-tip of 6 mm widtho Using a generator applying 11~8 kV to strip 83, the voltage at the tip was only 6.2 kV. Only a ve~y faint spra~
was found with the tip held at 2 cm from the paper but the intensity increased as the tip was brought closer (to within 1 cm) of the paper.

Example 6 was repeated but, to improve the conduction of the high voltage from strip 83 to the felt-tip, a metal draw-ing pin was pressed through the pen casing at the position of contact 83. In this case the voltage at the tip was 11.5 kVo ~he spra~ intensity was greater than in ~xample 6.
E3AMP1~ 8 Example 7 was repeated but with the felt-tip replaced by a polyester fibre bundle bullet-head tip of diameter 4.8 mm and using a generator producing 14 kV at strip 83 (13.9 kV at the felt-tip)O A more intense spray was obtained than in Example 7.

Bxample 6 was repeated using the felt-tip used in ~xample 8 and ad~ing 1~5 ml of xylene to the cartridge contents.
Good spraying was obtained at distances up to 7 cm from the paperO
~XA~Iæ 10 Example 1 was repeated using a standard "~extmark"
(RIM) 700 blue ink marker. As in Example 6 an adaptor was employed to hold the marker in position. The marker had a metal casing and a bullet-head configuration tip formed of an ac~ylic fibre bundle oP about 4 mm diameter.
With an applied voltage of 14 kY, satisfactory spraying was obtained at distances of 2, 3 and 4 cm from the paper.

Z~

~ ~2649 E~qPL~ 11 Example 5 was repeated using the marker of Example 10 with the tip at va~ying distances from the plateO ~ne measured current was as follows:
5Distance from VoltageCurrent paper (cml (kV) (nA) Fnder all the conditions quoted, satisfacto~y spraying occurredO
15 All the markers employed in Examples 1 to 11 could be used conventio~ally by moving the tip in contact with paperO
EX~Moel~ 12 An empty '~agic Marker" type 79 in which the tip supplied has been sharpened to a poi~t was charged with an alcohol based af-tershave. When f.itted to the applicator body provided with a generator producing high voltage pulses at a frequency of about 20~25.~z, giving a voltage of about 12 kV at the tip7 a spray could be dispe~sed Lnto the a-tmosphere. ~he user's finger on button 69 acted as a field intensifying electrode to per~it spraying even though ~o other earthed surface was within 50 cm of the tip.
~ tersha~e could also be deposited on the user's chin by holdi~g the tip a few cm from the chin, or b~ moving the tip over the skin while in contact therewithO
~
An empty "Magic Ma~ker" of the type used in ExamPle 12 was charged with a vegetable oil based pesticide~ When fitted to the applicator bod~ as in Example 127 a pesticide spray could be di~pensed on to housepla~ts when held within 10 cm of the plant.
The pesticide could also be dispensed by wiping the tip on the 26 ~ ~2649 houseplant leaves.
All the cartria~es of Examples 1 to 13 ware such that no liquid was dispensed when no high potential was applied and the tip was not in contact with a receptive surface such as paperO

PA/~G ~
20 Feb~uary 1984

Claims (17)

CLAIMS:
1. Apparatus for spraying a liquid comprising (i) an elongated body member, suitable for holding in the human hand, provided with a nozzle at one end, (ii) means for delivering the liquid to said nozzle, (iii) a high voltage generator, (iv) means for applying a sufficiently large electrical potential, relative to earth, from said generator to said nozzle that, when said body member is held in the human hand with the nozzle at a distance of 2 cm above an earthed surface, sufficient electrical gradient is provided at said nozzle to atomise said liquid as a spray of electrically charged droplets, said nozzle and said means for delivering the liquid thereto being of the type that, when said nozzle is in contact with a surface beneath the nozzle that is receptive to said liquid and is moved relative to, but in contact with, said surface, liquid is trans-ferred from said nozzle onto said surface, but when said nozzle is disposed above, but out of contact with, a surface and no atomis-ing electrical potential is applied to said nozzle, no liquid is dispensed from said nozzle.
2. Apparatus according to claim 1 wherein said nozzle com-prises a wick of porous material protruding from a support.
3. Apparatus according to claim 1 wherein said nozzle is demountable from said body member.
4. Apparatus according to claim 1 wherein the means for delivering the liquid to the nozzle comprises a reservoir of said liquid within said body member, said reservoir being demountable from said body member.
5. Apparatus according to claim 4 wherein the reservoir and nozzle comprise a single cartridge unit which can be removed from the body member.
6. Apparatus according to claim 5 wherein said cartridge unit is a graphic marking implement.
7. Apparatus according to claim 5 wherein said body member is adapted to receive cartridges of more than one shape and/or size.
8. Apparatus according to claim 1 wherein the high volt-age generator is mounted within the body member.
9. Apparatus according to claim 8 wherein the outer surface of said body member is provided with an electrically conductive portion electrically connected to the high voltage generator thereby providing an earth return to said generator when said electrically conductive portion is contacted by the hand of the user.
10. Apparatus according to claim 9 wherein the high volt-age generator is powered by at least one battery provided within said body member.
11. Apparatus according to claim 9 wherein said electrically conductive portion comprises a push button which, when depressed, causes a high potential, relative to earth, to be generated by said generator.
12. Apparatus for use in the spraying of a liquid from a cartridge having a casing enclosing a reservoir of the liquid and a nozzle of the type that, when said nozzle is in contact with a surface beneath the nozzle that is receptive to said liquid and is moved relative to, but in contact with, said surface, liquid is transferred from said nozzle on to said surface, but, when said nozzle is disposed above, but out of contact with, a surface and no atomising potential is applied to said nozzle, no liquid is dispensed from said nozzle, comprising (i) an elongated body member, suitable for holding in the human hand, and adapted to receive said cartridge with the nozzle thereof projecting from one end of said body member, (ii) a high voltage generator, and (iii) means to apply a sufficiently large electrical potential, relative to earth, from said generator to said cart-ridge, when said cartridge is fitted to said body member, that, when said body member is held in the human hand with the nozzle of the cartridge at a distance of 2 cm above an earthed surface, sufficient electrical gradient is provided at the nozzle to atomise said liquid as a spray of electrically charged droplets.
13. Apparatus according to claim 12 wherein said body member is adapted to receive cartridges of more than one shape and/or size.
14. Apparatus according to claim 12 wherein the high volt-age generator is mounted within the body member.
15. Apparatus according to claim 14 wherein the outer surface of said body member is provided with an electrically conductive portion electrically connected to the high voltage generator thereby providing an earth return to said generator when said electrically conductive portion is contacted by the hand of the user.
16. Apparatus according to claim 15 wherein the high volt-age generator is powered by at least one battery provided within said body member.
17. Apparatus according to claim 15 wherein said electrically conductive portion comprises a push button which, when depressed, causes a high potential, relative to earth, to be generated by said generator.
CA000454753A 1983-05-20 1984-05-18 Spraying apparatus Expired CA1210234A (en)

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
GB8313959 1983-05-20
GB838313959A GB8313959D0 (en) 1983-05-20 1983-05-20 Graphic implements
GB8322308 1983-08-18
GB838322308A GB8322308D0 (en) 1983-08-18 1983-08-18 Graphic implements
GB8326666 1983-10-05
GB838326666A GB8326666D0 (en) 1983-10-05 1983-10-05 Graphic implements

Publications (1)

Publication Number Publication Date
CA1210234A true CA1210234A (en) 1986-08-26

Family

ID=27262106

Family Applications (1)

Application Number Title Priority Date Filing Date
CA000454753A Expired CA1210234A (en) 1983-05-20 1984-05-18 Spraying apparatus

Country Status (1)

Country Link
CA (1) CA1210234A (en)

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