CA1209565A - Metal fluoborate catalyzed hindered aromatic amine curing agents for polyepoxide resins - Google Patents

Metal fluoborate catalyzed hindered aromatic amine curing agents for polyepoxide resins

Info

Publication number
CA1209565A
CA1209565A CA000450473A CA450473A CA1209565A CA 1209565 A CA1209565 A CA 1209565A CA 000450473 A CA000450473 A CA 000450473A CA 450473 A CA450473 A CA 450473A CA 1209565 A CA1209565 A CA 1209565A
Authority
CA
Canada
Prior art keywords
amine
hindered aromatic
fluoborate
copper fluoborate
hindered
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
CA000450473A
Other languages
English (en)
French (fr)
Inventor
David A. Shimp
Original Assignee
Celanese Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Celanese Corp filed Critical Celanese Corp
Application granted granted Critical
Publication of CA1209565A publication Critical patent/CA1209565A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/68—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the catalysts used
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/50—Amines
    • C08G59/5033—Amines aromatic

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Epoxy Resins (AREA)
CA000450473A 1983-04-11 1984-03-26 Metal fluoborate catalyzed hindered aromatic amine curing agents for polyepoxide resins Expired CA1209565A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US06/483,981 US4447586A (en) 1983-04-11 1983-04-11 Metal fluoborate catalyzed hindered aromatic amine curing agents for polyepoxide resins
US483,981 1983-04-11

Publications (1)

Publication Number Publication Date
CA1209565A true CA1209565A (en) 1986-08-12

Family

ID=23922251

Family Applications (1)

Application Number Title Priority Date Filing Date
CA000450473A Expired CA1209565A (en) 1983-04-11 1984-03-26 Metal fluoborate catalyzed hindered aromatic amine curing agents for polyepoxide resins

Country Status (5)

Country Link
US (1) US4447586A (enExample)
EP (1) EP0122149B1 (enExample)
JP (1) JPS59197420A (enExample)
CA (1) CA1209565A (enExample)
DE (1) DE3472563D1 (enExample)

Families Citing this family (34)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4540750A (en) * 1984-09-24 1985-09-10 Ciba-Geigy Corporation Diethyl toluene diamine hardener systems
US4668758A (en) * 1985-09-30 1987-05-26 Shell Oil Company Cure rate control in epoxy resin compositions
US4775736A (en) * 1985-12-27 1988-10-04 Ethyl Corporation Epoxy curing agent composition
US4756787A (en) * 1986-01-22 1988-07-12 Loctite Corporation Compositions curable by in situ generation of cations
US4717440A (en) * 1986-01-22 1988-01-05 Loctite Corporation Compositions curable by in situ generation of cations
FR2608613B1 (fr) * 1986-12-17 1989-03-31 Rhone Poulenc Chimie Polymeres a groupements imides faits a partir de diamines encombrees et leurs procedes de preparation
US4874833A (en) * 1988-08-22 1989-10-17 Shell Oil Company Composition containing epoxy resin and alkyl hindered polyaromatic diamine and monoaromatic amine curing agents
US4946925A (en) * 1989-01-25 1990-08-07 Air Products And Chemicals, Inc. Bridge bis(cyclohexylamine) curing agents for epoxy resins
CA2008089A1 (en) * 1989-01-25 1990-07-25 Herbert F. Strohmayer Bridged bis(cyclohexylamine) curing agents for epoxy resins
JP2754230B2 (ja) * 1989-03-23 1998-05-20 株式会社スリーボンド セルフロッキング剤及び締め具
US4933421A (en) * 1989-03-30 1990-06-12 Shell Oil Company Epoxy resin composition containing metal tetrafluoroborate and boron ester
US5011721A (en) * 1989-10-16 1991-04-30 Thiokol Corporation Chemorheologically tailored matrix resin formulations and their use in making pre-impregnated fibers and in fabricating composite parts
CA2028414C (en) * 1989-10-25 2000-02-08 Owen H. Decker Method for increasing fiber strength translation in composite pressure vessels using matrix resin formulations containing surface-active agents
US5593770A (en) * 1989-10-25 1997-01-14 Thiokol Corporation Chemorheologically tailored matrix resin formulations containing anhydride curing agents
US5545278A (en) * 1989-10-25 1996-08-13 Thiokol Corporation Method for increasing fiber strength translation in composition pressure vessels using matrix resin formulations containing anhydride curing agents and surface-active agents
US5025078A (en) * 1990-02-02 1991-06-18 Air Products And Chemicals, Inc. Epoxy resin systems containing methyl-2,6,-cyclohexanediamine
US5091574A (en) * 1990-02-06 1992-02-25 Texaco Chemical Company Polyoxyethylene diamine derivatives of diglycidyl ethers
ES2074686T3 (es) * 1990-04-10 1995-09-16 Ciba Geigy Ag Mezclas de materiales con resina epoxi que contienen complejos areno de hierro y determinadas aminas.
US5128433A (en) * 1991-06-04 1992-07-07 Polytek Development Corp. Thixotropic polymer compositions and process for use thereof
US5264501A (en) * 1991-08-09 1993-11-23 Air Products And Chemicals, Inc. Alkyl substituted bi(cyclohexylamines)
US5393806A (en) * 1991-12-26 1995-02-28 Albemarle Corporation Epoxide system curing agents
US5280091A (en) * 1992-02-07 1994-01-18 Air Products And Chemicals, Inc. Epoxy resins cured with mixed methylene bridged poly(cyclohexyl-aromatic)amine curing agents
US5565499A (en) * 1993-03-24 1996-10-15 Loctite Corporation Filament-winding compositions for fiber/resin composites
US5539012A (en) * 1993-08-18 1996-07-23 Loctite Corporation Fiber/resin composites and method of preparation
US5679719A (en) * 1993-03-24 1997-10-21 Loctite Corporation Method of preparing fiber/resin composites
US5541000A (en) * 1993-08-17 1996-07-30 Minnesota Mining And Manufacturing Company Latent, thermal cure accelerators for epoxy-aromatic amine resins having lowered peak exotherms
FR2753978B1 (fr) 1996-09-30 1999-05-14 Inst Francais Du Petrole Composition thermodurcissable, ses utilisations et preforme souple depliable comprenant cette composition
US6590011B1 (en) * 2000-05-01 2003-07-08 Polymeright, Inc. Radiation initiated epoxy-amine systems
US6379799B1 (en) * 2000-06-29 2002-04-30 Cytec Technology Corp. Low moisture absorption epoxy resin systems with alkylated diamine hardeners
US6962964B2 (en) * 2003-02-06 2005-11-08 Air Products And Chemicals, Inc. Hydrogenation of methylenedianiline homologs and epoxy resins cured with same
WO2013010788A2 (de) 2011-07-15 2013-01-24 Basf Se Polyetheramine als beschleuniger in epoxid-systemen
WO2013113587A1 (de) 2012-02-03 2013-08-08 Basf Se Hyperverzweigte polymere zur modifikation der zähigkeit von gehärteten epoxidharz-systemen
CN107148436B (zh) 2014-11-20 2019-11-08 陶氏环球技术有限责任公司 加速剂组合物
TWI762938B (zh) * 2020-05-29 2022-05-01 台光電子材料股份有限公司 樹脂組合物及其製品

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2951822A (en) 1956-11-23 1960-09-06 Union Carbide Corp Preparation of polyglycidyl aromatic amines and resinous compositions made therefrom
US3018262A (en) * 1957-05-01 1962-01-23 Shell Oil Co Curing polyepoxides with certain metal salts of inorganic acids
US2951825A (en) 1958-02-03 1960-09-06 Union Carbide Corp Glycidyl derivatives of amino phenols
US3033803A (en) 1958-10-03 1962-05-08 Devoe & Raynolds Co Production of glycidyl ethers
NL120445C (enExample) * 1959-02-05
GB987015A (en) 1962-07-12 1965-03-24 Ciba Ltd Improvements in or relating to epoxide resins, processes for their production and their use
ES305034A1 (es) * 1963-10-18 1965-04-01 Ciba Geigy Procedimiento para endurecer compuestos poliepoxidos cicloalifaticos
US3432440A (en) * 1965-02-11 1969-03-11 Celanese Coatings Co Epoxy curing agents comprising a fluoborate salt and a hydrolyzable ester
US3859314A (en) 1967-06-29 1975-01-07 Celanese Coatings Co Process for preparing glycidyl esters of polycarboxylic acids
US4321351A (en) * 1979-11-05 1982-03-23 Ciba-Geigy Corporation Process for the production of epoxy resin castings
US4366108A (en) * 1980-07-25 1982-12-28 Ciba-Geigy Corporation Liquid matrix system based on a mixture of epoxide resin and an amine curing agent for producing fibre-reinforced plastics components

Also Published As

Publication number Publication date
EP0122149A3 (en) 1985-12-27
US4447586A (en) 1984-05-08
EP0122149B1 (en) 1988-07-06
JPS59197420A (ja) 1984-11-09
JPH0365809B2 (enExample) 1991-10-15
DE3472563D1 (en) 1988-08-11
EP0122149A2 (en) 1984-10-17

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Legal Events

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