CA1196111A - Ingaas field effect transistor - Google Patents

Ingaas field effect transistor

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Publication number
CA1196111A
CA1196111A CA000421665A CA421665A CA1196111A CA 1196111 A CA1196111 A CA 1196111A CA 000421665 A CA000421665 A CA 000421665A CA 421665 A CA421665 A CA 421665A CA 1196111 A CA1196111 A CA 1196111A
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CA
Canada
Prior art keywords
transistor
further characterized
channel region
source
channel
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
CA000421665A
Other languages
French (fr)
Inventor
Alfred Y. Cho
Thomas P. Pearsall
Paul O'connor
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AT&T Corp
Original Assignee
Western Electric Co Inc
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Publication date
Application filed by Western Electric Co Inc filed Critical Western Electric Co Inc
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Publication of CA1196111A publication Critical patent/CA1196111A/en
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Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
    • H01L29/66Types of semiconductor device ; Multistep manufacturing processes therefor
    • H01L29/68Types of semiconductor device ; Multistep manufacturing processes therefor controllable by only the electric current supplied, or only the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched
    • H01L29/76Unipolar devices, e.g. field effect transistors
    • H01L29/772Field effect transistors
    • H01L29/78Field effect transistors with field effect produced by an insulated gate
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
    • H01L29/02Semiconductor bodies ; Multistep manufacturing processes therefor
    • H01L29/12Semiconductor bodies ; Multistep manufacturing processes therefor characterised by the materials of which they are formed
    • H01L29/20Semiconductor bodies ; Multistep manufacturing processes therefor characterised by the materials of which they are formed including, apart from doping materials or other impurities, only AIIIBV compounds
    • H01L29/201Semiconductor bodies ; Multistep manufacturing processes therefor characterised by the materials of which they are formed including, apart from doping materials or other impurities, only AIIIBV compounds including two or more compounds, e.g. alloys
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
    • H01L29/40Electrodes ; Multistep manufacturing processes therefor
    • H01L29/43Electrodes ; Multistep manufacturing processes therefor characterised by the materials of which they are formed
    • H01L29/49Metal-insulator-semiconductor electrodes, e.g. gates of MOSFET
    • H01L29/51Insulating materials associated therewith
    • H01L29/518Insulating materials associated therewith the insulating material containing nitrogen, e.g. nitride, oxynitride, nitrogen-doped material

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  • Engineering & Computer Science (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Ceramic Engineering (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Computer Hardware Design (AREA)
  • Junction Field-Effect Transistors (AREA)

Abstract

InGaAs FIELD EFFECT TRANSISTOR

Abstract InGaAs FETs using a silicon nitride layer, between the metal and the channel layer reduce the gate leakage current and yield desirable FET characteristics, particularly high transconductance.

Description

-- 1 ~

InGaAs FIELD EFFECT TRANSISTOR

This invention relates to a field effect transistor comprising semlconductor source, drain and channel regions all of the same conductivity type, the channel region having an InGaAs composition, source and drain electrodes contacting the source and drain regions~
and a gate electrode overlying the channel regionO
Many modern technological applications, such as memories or si~nal processing using in-tegrated circuits and microwave transmis~ion using discrete devices such as field effect transistors, require higher speed operation than i5 currently available. Many approaches have been taken in attempts to obtain such higher speed operation. ~or example, one approach uses superconducting Josephson junction devices to obtain high speed operation. Another approach uses semiconductor materials other than the commonly-used silicon to obtain higher speed opexation.
The first such semiconductor material extensively investigated was undoubtedly GaAs, which is o interest because of its high room temperature electron mobility which is higher than that of Si. Another semiconductor material currently of interest, although it has not been investigated as extensively as GaAs, is In 53Ga ~7As which may be grown lattice matched to semi-insulating InP
substrates. This semiconductor material is of device interest, especially for field effect transistor (FET) applications, because of parameters such as its high electron mobility, which is approximately 50 percent greater than that of GaAs. It is also of device interest because of its low effective electron mass, and the large energy separation between the central and satellite conduction band minima. These features suggest that electrons move faster in InGaAs than in GaAs or Si.
However attractive these parameters make InGaAs appear as a material for devices, construction of field ,, . .,, --.,. ".

effect transistors whose performance actually benefits from these favorable parameters has been difficult because of the low Schottky barriex height for metals on n-type materials. The Schottky barrier height is only 0.2 eV and conventional metal semiconductor field effect transistor (MESFET) gates cannot be fabricated because of the large gate channel leakage current. As a result, workers in the field have investigated various schemes for obtaining an effective low leakage gate structure which could modulate the electron flow in the InGaAs channel region. One approach used diffused junction FETs and is described in Electronics Letters, 16, pp. 353-355, May 8, 1980. The second approach uses grown Schottky-assisted gate field effect transistors and is described in Electron Device Letters, EDL-l, pp. 15~-155, August 1980. Both of these approaches su~fer the drawback at the present time of presently requiring custom growth and processing techniques to achieve a working device and the prospects for large area uniformity in device characteristics are relatively small. Yet another approach uses inversion mode metal-insulator-semiconductor (MIS) structures. Such s-tructures are advantageous because they offer greater ease in FET
fabrication. A structure using this approach is described in Electron Device Letters, EDL-2, pp. 73-7~, March 1981.
While fabrication difficulties are somewhat alleviated with this approach, the device performance, as measured by the transconductance, obtained has so far been disappointing.
The problems are overcome in accordance with the invention in a InGaAs field effect transistor in which the gate electrode is separated from the channel region by a thin insulator o~ SiN.
Thus, according to the invention there is provided a field effect transistor comprising semi-conductor source, drain and channel regions all of -the same conductivity type, the channel region having an InGaAs composition, source and drain electrodes contac-ting the source and drain regions, and a gate electrode ~96~
- 2a -overlying the channel region, characteri~ed in that the gate electrode is separated from the channel region by a thin layer of SiN.
Other structural features cooperate to give improved device characteristics as will be described below.
In the drawing:
FIG. 1 is a sectional view of one embodiment of a device according to this invention;

..

FIG. 2 is a top view of one embodiment of a device of this invention; FIG. 3 shows the deplection mode drain characteristics of a device according to this invention; and FIG. 4 plots the square root of the effective gate voltage, horizontally, versus the drain currentt vertically.
It has been found that ield effect transistors fabricated on n-type InGaAs and having an insulator assisted gate electrode with an interfacial insulating layer between the metal and the channel layers have desirable device characteristics such as a reduced gate leakage curren~ and high transconduc-tance. The semiconductor material of the channel layer comprises InxGal_xAsyPl_y. Embodiments in which y is approxîmately equal to one are preferred because oE the higher electron mobility for these compositions. The insulating layer comprises silicon nitride in a preferred embodiment. In a further preferred embodiment, the device has an In 53Ga 47As channel layer disposed on a high resistivity buffer layer comprising Al ~8In 52As, source and drain electrodes electrically contacting said InGaAs channel layer and a gate electrode having a metal and a layer of silicon nitride between the metal and the In 53Ga 47As layer. Devices having a 1.2 ~im gate length and a net donor doping concentration in the channel of approximately 5xlO16cm~3 showed a dc transconductance of 130 mS/mm. Both depletion and enhancement mode operation were observed.
The layers are conveniently grown by ~olecular beam epitaxy (characterized by crystal lattice matching) on semi-insulating InP substrates. The silicon nitride layer is conveniently grown by plasma-enhanced chemical vapor deposition. The insulator-assisted gate technology of the invention has significant advantages in fabrication flexibility and control as compared to other approachesO
For reasons of clarity, the Figures are not drawn to scale. A device of this invention, indicated generally as 1, is shown in cross-section in FIG. 1. The device comprises substrate 10, buffer layer 13, a channel layer 16, a source-drain contact layer 19, source and drain electrodes 22 and 25, respectively, insulator layer 28, and contact 31. The substrate is typically semi-insulating Fe-doped InP.
The channel layer comprises n-type GaxInl_ ~AsyPl y having a net donor concentration within the range from 2X1016 to 8xlO16cm~3 and a thickness that is typically between 0~35 and 1.8 ~m. The channel electrical thickness, which depends on the channel doping, should be equal to the maximum calculated depletion width. Lower donor concentrations are generally undesirable because the channel will not conduct sufficient current and higher concentrations are undasirable because the electron mobility begins to dropO The doping concentration and thickness are determined by the requirement, for depletion mode operation, that the channel be depleted at the expected gate operating voltage~ This condition also depends on the thickness of the insulator layer 28 as well as the dielectric constants of the insulator and the semiconductor.
The buffer layer, which should also be high resistivity, typically comprises nominally undoped Al 4~In 52As, although other compositions that have high resistivities and lattice match to InP may be used. The resistivity of this layer should generally be greater than 106 ~cm~ The buffer layer is typically between 0.2 and 0.5~ m thick, and although nominally undoped, it is generally n~type Al 4~In 52As with a donor concentration of approximately 2xlO15cm 3. If sufficiently high quality substrate surfaces can be obtained, the channel layer may be grown directly on the semi-insulating substrate~ i.e., the high resistivity buffer layer may be omitted.
The contact layer for forming the source and draing region 19 is highly dopedy typically n-type with a donor concentration o approxirnately 8xl018cm~3, and reduces the source and drain parasitic resistances. The source and drain electrodes 22,25 are typically ohmic contacts formed by, for example, a Ge/Au metallization and alloying.
The insulator 28 is a thin, (yenerally between approximately 150 and 1000 ~ngstroms) layer of silicon nitride. The insulator layer should be as thin as possible and the minimum thickness is determined by the maximum acceptable leakage current under reverse bias. The insulator layer should also be thin enough or an extended depletion region without ;nversion. For depletion mode operation, the holes tunnel into the metal and there is no accumulation of holes next -to the insulator semiconductor interface. There is no absolute upper limit to the insulator layer ~hickness but thicknesses greater than approximately 250 Angstroms may degrade device characteristics. Other insulator materials may be used but silicon nitride has the virtues of being easily controlled and apparently reducing the surface states. For enhancement mode operation, a very small leakage current is desired. Silicon nitride apparently does not undergo any deleterious chemical reactions with the semiconductor materials and it creases a minimum of surface energy states at the interface with the semiconductor. The insulator material should have as high a dielectric constant and be thermally compatible with the semiconductor material.
Contact 31 is a metal such as aluminum and forms the gate electrode.
The advantages of the device are best obtained in depletion mode operation and the device is not designed for inversion mode operation.
In a preferred embodiment, y is approximately equal to 1.0 and x is approximately equal to 0.~7 because this combination of parameters defines the composition having the highest electron mobility that can be lattice matched to InP.

~ 6 -Device fabrication conveniently begins with the growth of epitaxial layers comprising, for the embodiment d~ Al.48In.52AS~ Ga~47In s3As and highly doped Ga 47In 53AS and which are grown on semi-insulating InP substrate. These layers are conveniently grown by molecular beam epitaxy (MBE) although other methods may be used. It has been found that covering the back surface of the substrate, i.e., wafer, with silicon nitride prevents substrate decomposition which is caused by reaction of the wafer with the indium that is used to mount the wafer for the growth process. Device fabrication then proceeds with mesa isolation which begins with pa~tern delineation of a resist coated wafer that defines the mesas. Isolation is conveniently accomplished by ion milling at an angle of 45~ Ion milling proceeds until the substrate is reached.
An angle of approximately 45 is preferred because the shape of the mesa wall facilitates formation of good source, drain, and gate contacts~ The substrate may now be conducting and if so, the conducting portion may be removed by an etchant such as 10 percent HCl in H2O or a 5:1:1 mixture of H2S04, H2O2 and H2O. The source and drain contacts may not contact the substrate in some embodiments.
In these embodiments, the conducting portion of the wafer need not be removedO Alternatively, the mesa could be defined by chem;cal etching.
Source and drain electrodes are then formed by opening windows for the contacts and evaporating a AuGe/Ag~Au metallization. This is followed by lift off and alloylng at a temperature hetween 400C and 460C for a time of approximately 10-20 seconds. This procedure gives very low contact resistances on In 53Ga 47As having n+-doped contact layers. Using the transmission line method, the specific contact resistance was estimated to be approximately 5xlO 3~-cm2 which corresponds to 0.01 ~-mm of device width. Width refers to the dimension perpendicular to current flow and length to the dimension parallel to current flow~ The length should be as short as possible for high speed operation. Other metallizations may, of course, be used, and for some, no alloying with the n~ contact layer may be neededO
The channel region is then pattern delineated and etched using an etching solution such as 5:1 citric acid/H202, and a photoresist mask. The etching is conveniently monitored by measuring the current between source and drain electrodes 22 and 25 and terminating the etching when the saturated channel current reaches a predetermined value, usually 80 120 mA per mm of device width. The etching proceeds through the n+-layer into the channel layer. This etching procedure permits abrication of a channel having the desired -thickness. The photoresist material is then removed and the semiconductor material cleaned. A thin layer of silicon nitride is then deposited by plasma-enhanced chemical vapor deposition from silane (SiH4) and ammonia (NH3) at a substrate temperature that is typically approximately 300C. This process provides a low temperature deposition process having an in situ cleaning capacity. The gate metallization, typically having lengths between 1.2 and 1.8 ~m, is then ~ormed by aluminum evaporation and lift off. The gate metallization appears to contact the channel layer but this does not adversely affect device performance as the dielectric has been deposited everywhere and the area covering ~he active layer is very small. Any metal can be used but aluminum is well suited for use with lift offO Devices actually tested had gate widths of approximately 250 ~m.
A top view of a device abricated according to this processing sequence is shown generally as 11 in FIG. 2. Shown are substrate 100, mesa 110, source electrode 220, drain electrode 250 and gate electrode 311.
FIG. 3 shows the drain current-voltage characteristics of a device having a gate length of approximately 1.2 ~m and a channel doping of approximately 6xl016cm 3. The channel doping was estimated from gate capacitance versus voltage measurements and Hall effect characterization of samples which were grown under similar conditions. The dc transconductance at a drain bias of 4.5 volts was 130 mS/mmO The unit used is milli-siemenS
per mm of gate width. Both depletion mode, that is, VGs less than zero, and enhancement mode, that is, VGs greater than zero, operations were observed with negligible gate current. With this device, the intrinsic transconductance, gm, was approximately 150 to 170 mS/mm. The gate source capacitance was 4~2 pP/mm at zero bias and 1.3 pF/mm at VGs of zero and a VDs of 4 volts.
The inerred effective velocity of the electrons in the channel was determined by employing the relationship:

IDS5 = q VS ND ~a - [2F ~ VG)/q ND] }, (1) where VS is the electron velocity, a is the channel thickness, ND is the bulk donor concentration, ~ is the semiconductor dielectric constant, ~ is the diffusion potential due to the band bending at the interface, and VG
is the effective gate channel voltage including self-biasing effects. Differentiating with respect to VG
yields:

dIDSs/d(VG 1/2) = v5 ~ 2~qND (2) IDSs is plotted as the function of VG1/2 in FIG. 4 where the source resistance of 4Q-mm and a critical field of 3xlO3V/cm were used. As can be seen, this curve departs from the linear relationship predicted by Equation (2) and is probably due to the neglected effects of the built-in potential ~ and the reductions of insulator voltage at low gate voltages as well as to the velocity degradation near the buffer interface at high absolute values of VG. Using the central portion of FIG. 4, an effective electron velocity of 2.0+005xlO7cm/sec was found. This is approximately 50 to 70 percent higher than the values :~L~
g commonly observed in GaAs MESFETs at room temper~ture and is somewhat lower than the peak electron velocity predicted theoretically for this particular composition. The electrons in the devices are within a few thousand Angstroms of a heterointerface and this may result in a decrease in velocity relative to that of bulk material.
Although the invention has been described by reference to a particular embodimentl modifications of this embodiment will be readily thought of by those skilled in the art. For example, devices may be fabricated with a gate electrode having two fingers for increased current-carrying capacityO Additionally, the device may be constructed in planar embodimentsO In these embodiments, electrîcal isolation between devices is provided by, for example, ion implantation which renders the volume between individual devices nonconducting. Other methods may, of course, be used.
It is also contemplated that a plurality of devices may be present on a single substrate. Devices of this invention may also be integrated on a sinyle substrate with light sources or photodetectors. Light detection may also occur in devices of this invention.

Claims (11)

Claims
1. A field effect transistor comprising semiconductor source, drain and channel regions all of the same conductivity type, the channel region having an InGaAs composition, source and drain electrodes contacting the source and drain regions, and a gate electrode overlying the channel region, CHARACTERIZED IN THAT
the gate electrode is separated from the channel region by a thin layer of SiN.
2. The transistor of claim 1 FURTHER CHARACTERIZED IN THAT
the source and drain regions are more highly doped than the channel region.
3. The transistor of claim 2 FURTHER CHARACTERIZED IN THAT
the semiconductor channel region is lattice-matched to a semiconductor layer having a significantly higher resistivity than the channel region.
4. The transistor of claim 3 FURTHER CHARACTERIZED IN THAT
the high resistivity layer is lattice matched to a semi-insulating substrate.
5. The transistor of claim 1 FURTHER CHARACTERIZED IN THAT
the thickness of the SiN insulator layer is 150-1000 µm.
6. The transistor of claim 5 FURTHER CHARACTERIZED IN THAT
the structural parameters of the device are designed to give operation in a mode other than an inversion mode of operation.
7. The transistor of claim 6 FURTHER CHARACTERIZED IN THAT
the source drain and channel layers comprise doped In1-xGaxAsyP1-y.
8. A transistor as recited in claim 7 FURTHER CHARACTERIZED IN THAT
y is approximately equal to 1.0 and x is approximately equal to 0.47.
9. A transistor as recited in claim 8 FURTHER CHARACTERIZED IN THAT
said high resistivity layer comprises A1.48In.52As.
10. A transistor as recited in claim 8 FURTHER CHARACTERIZED IN THAT
said channel region has a doping concentration between 2x1016/cm3 and 8x1016/cm3.
11. A transistor as recited in claim 10 FURTHER CHARACTERIZED IN THAT
said channel region has a thickness between 0.35 µm and 1.8 µm.
CA000421665A 1982-02-26 1983-02-15 Ingaas field effect transistor Expired CA1196111A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US35251882A 1982-02-26 1982-02-26
US352,518 1989-05-15

Publications (1)

Publication Number Publication Date
CA1196111A true CA1196111A (en) 1985-10-29

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JP (1) JPS58158975A (en)
CA (1) CA1196111A (en)
FR (1) FR2522442A1 (en)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2187432B1 (en) * 2008-11-13 2013-01-09 Epcos AG P-type field-effect transistor and method of production

Also Published As

Publication number Publication date
FR2522442A1 (en) 1983-09-02
FR2522442B1 (en) 1984-12-28
JPS58158975A (en) 1983-09-21

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