CA1154730A - Dust control apparatus and method of transferring dust laden discrete solid particles - Google Patents

Abstract

ABSTRACT OF THE DISCLOSURE
A dust control apparatus in the form of a hood is disclosed for minimizing or eliminating the evolution of dust when loading dust laden solid discrete particles from a large container to a series of small containers. The appara-tus is designed specifically for unloading spent catalysts from catalytic vessels into a series of drums without evolu-tion of voluminous clouds of dust. The apparatus and method are designed to be portable so that expensive and sophisti-cated installations are not required in instances where the vessels are infrequently unloaded. The dust control hood makes use of the angle of repose of the solid discrete par-ticles to be transferred in such manner that the drums do not overfill. Simultaneously, air is drawn across the hood and the dust is collected in a suitable filter at a distance away from the loading area. Provision is also made for separa-tion and collection of dust from pyrophoric materials utilizing an inert gas rather than air as the carrier medium.

Description

~ '7~
The present invention relates to fluent material handllng apparatus. More particularly, the present invention relates to dru~ loading devices for use in loading of vessels which are on].y infrequently loaded. More specifically, this invention rela~es to the minimization and elimination of evolved dust when loading discrete solid particles from one vessel to a series of drums or other vessels.
Transfer of dust containing materials into containers has always presented problems due to the evolution of dus~.
In many instances, the dust can have adverse health e~fects on the personnel, a~d in all instances, the dust cloud pre-sents unsafe and aesthetically unpleasing problems. Dust control can be implemented by the use of fairly sophisticated equipment. However, the use of such equipment is not readily applicable to "on site" operation in which vessels are only infrequent].y unloaded. Furthermore, even wi~h equipment used for temporary operations, there is a serious disadvantage in determining when the receiving container is full. Therefore, if the dust control device has to be periodically removed to observe the level of filling, intermittent dust evolution occurs or the drum or receiving container overflows which can distrupt ~he entire operation.
The present invention overcomes the problems pre-viously associated with the prior art by providing a dust control hood through which a current of air selectively entrains the dust evolved during the loading operation and removes it to a dust collector. The pro~lem of determining when the drums or other containers are filled, so as to elim-inate the periodic removal of the dust control hood, is qui~e simply solved by the use of a normally limp transfer hose feeding into the apparatus. A dip pipe, connected to the ~ 3~
normally limp transfer hose extends from the top of the hood down into the container being filled so that when the level of the discrete solid reaches the level of the discharge end of the dip pipe, the normally limp transfer hose becomes rigid, and therefore observable to the operator. The operator then, by merely manually squeezing off the hose, or by utilizing a quick disconnect clamp of some sort, can easily stop the flow of materials. Since the dip pipe extends down into the drum to about the level of the rim, or slightly above or below same, the angle of repose of the loaded material allows for addi-tional room for more materials to be added. Thus, when the dust control hood is lifted, the materials past the point of constriction in the transfer hose and/or in the dip pipe fall into the drum, filling the area provided through the natural angle of repose of the filled materials, without overfilling the drum. The lid can be quickly placed on~o the filled drum. The operator then merely moves the dust control hood with the connected hoses to a waiting drum, releases the constricting pressure on the hose and allows the operation to continue. Alterna~ely, the transfer hose can be loosely inserted into the dip pipe opening and after the drum is filled and the hose squeezed off, the hose itself can be reinserted in the dip pipe of a second hood on an adjacent drum and the loading can be renewed. This allows for faster transfer from drum to drum and only requires one or more additional dust hoods. The use of this apparatus allows for fast loading of the various drums in a conveyerized operation or allows for the use of various commercially available switching devices.
Fig. 1 is a semidiagrammatical view o the apparatus of this invention being used in unloading used catalyst from 7 '~

a catalytic vessel.
Fig. 2 is a side elevation of one embodiment of the device of this invention with a portion broken away for purposes of illustration.
Fig. 3 is a plan view illustrating the device of this invention and particularly illustrating the use of an adjustable air inlet flap.
Figs. 4 through 9 are fragmentary diagrammatic views illustrating step by step the use of the system and apparatus of this invention.
Fig. 10 is a schema~ic view of the use of the system and apparatus of this invention in unloading pyrophoric materials under a blanket of an inert gas.
Fig. 11 is a diagrammatic view of the use of the process and apparatus in this invention in handling highly pyrophoric dust while minimizing the dangerof a fire in the bag house.
Fig. 12 is a fragmentary view of the apparatus of this invention used in conjunction with a vacuuming process whereby dust is preferentially separated from discrete solid particles.
Referring now to Fig. 1, the apparatus and method of this invention is illustrated specifically in unloading used catalyst from a catalytic.vessel 1 into a drum 40 or series of drums or other containers. While the dust control equipment has been described for use in un~oading spent catalysts from catalytic vessels it may also be employed in founderies, mineral processing plants, coal processing plants, oil refineries, chemical plants and other industries in which dust containing discrete solids require transfer from one vessel or container to another. Further, while the invention ~ 3~

has been described primarily as a portable method, it can be installed as a permanent unit for continuous or semi- -continuous operation. However, one of the major advantages of the equipment and of the method is that they lend them-selves readily for transportation from one area to another for intermittent or infrequent usage.
Referring, now to Fig. 1, a catalyst vessel 1 is shown having a dump chute 2 and a dump chute valve 3. A
normally limp transfer hose 4 is connected to the dump chute

2 by use of a clamp (not shown) and the discharge end of the hose is operatively connected to the dust control hood 6.
The dust control hood 6, as shown best in Figs. 2 and 3, has a top 7, a wall portion ~ and a rim 9. Rim ~ contains a depending skirt 10 which in the embodiment shown in Fig. 2 contains a sealing ring 21.
At the top 7 of the dust control hood -there is a dip pipe 11 having an opening 12 and a discharge end 13 which terminates at about the level of the depending skirt 10. The dip pipe can terminate at a point slightly above or below this level depending upon the natural angle of repose 27 of the materials being loaded. As illustrated, the transfer hose 4 can be fitted over the opening 12 of dip pipe 11, or merely inserted into the opening.
In the embodiment illustrated i~ Figs. 2 and 3 there is a gas inlet 14 which has an adjustable cover 15 in the form of a rubber flap which is pivotabl~ attached at point 16 with a rivet for manipulation to either side. How-ever, in the devices shown in Figs. 1 and 10, the gas inlet is in the form of an inlet tube 17 which may be connected 0 to a recycle line 30 for purposes to be described hereinafter.
Furthermore, as illustrated in Figs. 4 through ~, ~ 7 ~

the gas inlet opening 14 can be completely eliminated by the elimination o~ the sealing ring 21 which allows for air to flow between the depending skirt 10 and the upper rim 41 of the drum 40. In any event, all that is required is that air or other gases be allowed to enter into the h,ood area while the dus~ laden materials are being loàded. As will be appar-ent, the dust which evolves from the discrete dust laden pieces being loaded into the drum 40 is entrained into the air stream flowing across plenum 23 between t'he hood 6 and the drum and which escapes via outlet 18 through outlet tube 19 into the outlet line 22. This air is puiled by means of fan 26 through the dust collector 25, preferably in the form of a bag filter, and the exhaust air thereafter is discharged to the atmosphere (or recycled in the case of insert gases).
Referring now to drawings 4 through 9, the air is shown by the arrows entering between the depending skirt 10 and the upper rim 41 of the drum 40 and sweeping across the plenum 23 of the hood through the outlet tube 19 into outlet line 22 to the ~iltering apparatus (not shown). The transfer hose 4 is shown in limp condition as the pulverulent solids and dust are loaded into the bottom of the drum. However, as is shown in Fig. 5, once the solids 28 have reached the discharge end 13 of the dip pipe 11, the normally limp transfer hose 4 becomes rigid and is readily observable by the operator. Thereafter, as is shown in Fig. 4, the operator can manually squeeze off or,c'lose' off the transfer hose 4 thus stopping the flow of materials 28 into the drum 40. The natural angle of repose of the loaded ma~erials (indicated at 27) allows for additional material to be loaded into the drum without overfilling and this is accomplished when the operator pulls the hood 6 and attached hoses 4 and 22 away from the drum. This is shown in Fig. 7 as allowing the materials in the dip pipe 13 and in the transfer hose past the point of constriction to fall into the drum 40.
Thereafter, the lid 42 can be easily placed onto the drum as is shown in Fig. 8 and the hood 6 and attached hoses are immediately transferred to a waiting container as is shown in Fig. 9. Handles have been provided for this purpose.
As has previously been mentioned, the transfer hose 4 need not be physically attached ~o the dip pipe 11 but can merely be inserted therein. Thus, in this case, the operator will provide two or more dust control hoods 6 for two or more drums 40 and merely lift the transfer hose upwardly after applying constricting pressure and thus allow the residual materials to flow into the drum through the open dip pipe 11.
Thereafter, the hose is inserted into the dip pipe 11 of a waiting hood 6 on an adjacent drum 40 and the pressure re-leased so as to allow the flow to again resume to the new drum. As will be obvious to artisans in this art, slide valves can be used rather than manually squeezing off the transfer hose or other methods can be devised for stopping the flow when the transfer hose shows, through its rigidity, that the drum is filled. Furthermore, the outlet line 22 may be through a manifold, with closure valves in the case of multiple hoods for multiple drums. Since all of this is within the skill of the art, further description is not deemed necessary.
In some instances, as havepreviously been alluded to, the materials being transferred are pyrophoric and will burst into flame upon exposure to air. In these instances, a method such as that disclosed in Fig. 10, may be used wherein an inert gas is used to blanket the materials being ~ '7~

loaded to the container. The inert gas, as for example nitrogen or carbon dioxide, can be fed through the inlet tube 17 to purge the drum 40. The inert gas is then fed through exhaust tube 19 through exhaust line 22 to the dust collector 25. In this instance, however, the fan 26 rather than exhausting to the atmosphere propels the gases back through recycle line 30 which is connected to the inlet tube 17. A make up of nitrogen or CO2 can be fed from cylinder 33 via line 34 to the recycle line through a T arrangement, (not shown). Thus it is possible, with the use of the method and apparatus of this invention, to safely and successfully trans-fer dangerous pyrophoric materials containing pyrophoric dust to drums without danger of conflagration.
In some instances, in the transfer of extremely highly pyrophoric materials, such as RANEY ~ICKEL and the CATALYTIC RICH GAS (CRG) CATALYSTS, the dust is so highly pyrophoric, that there is a danger of a fire in the filter bags in the "bag house". This would occur, when the hood, is lifted from the drum a~d oxygen in the area would be with-~0 drawn through the outlet line 22 to the filter. This catalystdust, holding absorbed hydrogen atoms, in an extremely active state, readily combines with oxygen or other oxidizing mater-ials at atmospheric temperatures.
Thus, in order to avoid this possibility we have devised the device and system shown in Fig. 11. Essentially, the principle is the same in that the transfer hose 4 feeds the pyrophoric material from its source to the drum 40 through the dip pipe 11 o~ hood 6. However, there has been added an additional member in the form of a conical member 60 contain-ing an outer wall 61 and a depending flange 62. The inletpipe 17, is welded through weldments 63 to the outer wall '73~

portion 61 and at 63 to the inner wall portion 8 so as to space the conical member 60 in spaced relation to the inner wall 8 of ~he original hood 6. In the same manner, outlet tube 19 is welded both to the inner wall 8 and the outer wall 61 by weldments 64. Other suitable spacers may be utilized. The conical top piece 60 terminates into a neck portion 65 which is connected to an annular disc 66 which closes the conical piece hermetically around the neck of the original hood 6. The neck portion contains an outlet pipe 67 which allows air to run from the annular space or plenum 68 between the inner wall 8 and the outer wall 61.
Thus, the plenum 68 is in communication with the atmosphere surrounding the drum 40 and with the neck portion and with the outlet pipe 67 of the conical piece 60.
` The outlet line 69 goes to a second filter 70 which is connected in series with fan 71 which is then exhausted through line 22 and through line 30 to the inlet 14 of the hood 6 passes through plenum 23 through outlet 19 back through the outlet line 22 to the filter 25. The fan 26 connected ~0 in series pulls the nitrogen through the recirculating line 30 and make up nitrogen is added at point 33. A positive pressure of nitrogen is maintained through the system so that ~hen the hood 6 is lifted from the top of the drum 40, any residual dust around the rim 41 is drawn into the annular space 68 of the conical top piece 60. Therefore, any residual pyrophoric dust is picked up throu~h the plenum 68 afforded by the conical top piece 60 and is pulled with the surrounding air through a outlet pipe 67 and through the outlet line 69 to the filter system 70. This dust will oxidize. However, due to the small amount of the dust and the high volume flow of air through the plenum, the heat will be sufficiently absorbed so that fire is not a problem in ~he filter system 70. It will be appreciated, of course, that the majority of the pyrophoric dust is collected in the filter 25 which is constantly blanketed with an inert gas nitrogen sc, as to prevent any oxidation or any fear of conflagration.
In the event tha~ a vacuuming technique is utilized to unload the container rather than a gravity feed system, it is still possible to utilize the dust control apparatus as is shown in the illustration in Fig. 11. In this instance, the dust containing solids 28 are fed ~hrough inlet 51 into a cyclone 50, whereby the solid particles 28 for the most part are separated from the pulverulent dust containing materials. The dust, entrained in the low pressure gases, is fed through outlet 52 back to the vacuum truck for collec-tion in the bag filter located therein,whereas the solid materials 28 are fed through a vacuum break 55, in the form of a rotary air lock or gate valve and into the normally limp transfer hose ~+ to the dust control hood 6. This operation illustrates again the outlet line 22 leading to the dust col-lector apparatus and the fan not shown so that any dust notseparated in the cyclone is eliminated from evolution at the point of transfer.
It will be apparent, that many modifications will occur to those skilled in the art from the detailed descrip-tion herein given. As previously mentioned, the use of this apparatus and method is not limited to unloading spent cata-lysts from catalytic reactors, but may find wide use in foundry operations, chemical plant operations, coal process-ing plants, feed and grain operations, and other industries in which the transfer of dust laden solids from one point to another offers safety, health and aesthetic problems. For _g_ '7~

these reasons, the det~iled description, herein given, should be construed as being exemplary in nature and non-limiting except so as to be commensurate in scope with the appended clalms .

Claims (4)

THE EMBODIMENTS OF THE INVENTION IN WHICH AN EXCLUSIVE
PROPERTY OR PRIVILEGE IS CLAIMED ARE DEFINED AS FOLLOWS:
1. Dust control apparatus for minimizing dust evolution in transferring dust laden solid discrete particles from a first source to a series of receiving containers which comprises, in combination:
A. a normally limp transfer hose in communication with a first source, B. a hood for covering the outer rim of a receiving con-tainer including, 1. a top portion, , 2. a depending wall portion, 3. a rim portion for registry over the open top of a receiving container, 4. a dip pipe opening into the top portion of said hood and extending downwardly to a discharge end near the top of said receiving container, 5. a gas inlet and 6. a gas outlet C. exhaust means including:
1. a gas outlet connected to said gas outlet and 2. a fan in communication with said gas outlet line D. dust collecting means in operative relation with said gas outlet line and said fan.

2. Dust control apparatus as defined in Claim 1, the further combination therewith of closure means for use in closing off said transfer hose.

3. Dust control apparatus as defined in Claim 1, in which said hood contains a handle for lifting said hood from said receiving container for transfer to a second receiving container.

4. Dust control apparatus as defined in Claim 1, in which said hood contains an adjustable gas inlet opening for controlling the amount of gas directed across the top of said hood to said gas outlet.

5. Dust control apparatus, as defined in Claim 1, in which said hood contains a gas inlet port.

6. Dust control apparatus, as defined in Claim 4, in which said gas inlet port has a flap which may be adjustably opened or closed for controlling the volume of air drawn across the hood.

7. Dust control apparatus, as defined in Claim 1, in which said hood contains an inspection port.

8. Dust control apparatus, as defined in Claim 1, the further combination with said transfer hose of a quick release clamp.

9. Dust control apparatus, as defined in Claim 1, the further combination therewith, of a gasket surrounding said depend-ing rim portion of said hood for forming a gas tight seal with the rim of said receiving container.

10. A dust control apparatus as defined in Claim 9, the fur-ther combination therewith of an inert gas return line, connected at one end to said gas outlet and at the other end to said gas inlet for forming a continuous gas loop.

11. A dust control apparatus, as defined in Claim 10, the further combination therewith of a source of make-up inert gas for said gas loop.

12. Dust control apparatus, as defined in Claim 1, in which said hood comprises:
A. an outer wall portion in spaced relation with said depending wall portion;
B. an annular space between the two wall portions, defining an annual gas plenum;
C. a gas inlet at the bottom of said plenum in communi-cation with said annular gas passage;
D. an upper neck portion surrounding said dip pipe;
E. an annular disc hermetically sealing said upper neck portion to said inner wall portion and joined to the top part of said upper neck portion;
F. a gas outlet pipe in communication with said plenum and said gas inlet;
G. a second filter in communication with said gas outlet and a fan for pulling gas through said annular gas passage and thereafter through said second filter.

13. Dust control apparatus, as defined in Claim 12, which comprises further:
A. a gas inlet tube opening into the inner of the wall portions extending outside of the outer wall portions;
B. a gas outlet tube, opening into the inner of the wall portions and extending outside of the other wall portion;
C. a continuous gas loop comprising;
1. a recycle line connected to said gas inlet tube and said gas outlet tube and in communication with said dust collector and first fan;
2. a source of make up inert gas for recirculation through said continuous gas loop.

14. A method of transferring dust laden discrete solid par-ticles from a first source to a series of smaller containers through a normally limp transfer hose in operative rela-tion to said first source, the improvement of minimizing the evolution of dust within the transfer area and of transferring evolved dust via an outlet hose and fan to a dust collector away from said transfer area, which com-prises, the steps of:
A. placing a hood over the open top of the first of a series of smaller containers, said hood comprising:
1. a top portion, wall portions and a rim portion, in which:
a. said wall portion depends from said top por-tion and terminates in a rim portion, b. said rim portion fits over the top rim of the smaller container;
c. a dip pipe opening in the top portion of said hood and connected to said normally limp trans-fer hose and extending downwardly to terminate as a discharge end;
d. a gas inlet, e. a gas outlet for connection to said outlet hose and fan;
B. loading said discrete particles from said first source into smaller containers through said limp transfer hose and said dip pipe, C. drawing a gas stream through said gas inlet and across said hood to selectively entrain dust i said gas stream, D. drawing gas and entrained dust from said hood and from said receiving container through said outlet hose to said dust collector and collecting dust in said dust collector, E. constricting said normally limp transfer hose at a point above the dip pipe as said transfer hose becomes rigid from the transferred solid discrete particles contained therein;
F. lifting the entire hood and connected hoses and allow-ing the collected solid discrete particles in the dip pipe and in the transfer hose past the point of clamp-ing constriction to fall into the filled container without overfilling said container;
G. placing the hood onto a waiting empty container and fitting the depending skirt over the upper rim thereof;
H. releasing the constriction pressure from the transfer hose to resume the transfer operation.

15. A method of transferring dust laden discrete solid particles from a first source to a series of smaller containers through a normally limp transfer hose in operative rela-tion to said first source, the improvement of minimizing the evolution of dust within the transfer area and of transferring evolved dust via an outlet hose and fan to a dust collector away from said transfer area, which comprises, the steps of:
A. placing a hood over the open top of two or more of a series of smaller containers, each of said hoods comprising:
1. a top portion, wall portions and a rim portion, in which:
a. said wall portion depends from said top portion and terminates in a rim portion, b. said rim portion fitting over the top rim of a smaller container;
c. a dip pipe opening in the top portion of said hood and extending downwardly to terminate as a discharge end;
d. a gas inlet, e. a gas exhaust for connection to said exhaust hose and fan;
B. placing said transfer hose into the dip pipe of the first of said hoods;
C. loading said discrete particles from said first source into smaller containers through said limp transfer hose and said dip pipe;
D. drawing a gas stream through said gas inlet and across said hood to selectively entrain dust in said gas stream, E. drawing gas and entrained dust from said hood and from said receiving container through said exhaust hose to said dust collector and collecting dust in said dust collector.
F. constricting said normally limp transfer hose at a point above the dip pipe as said transfer hose becomes rigid from the transferred solid discrete particles contained therein;
G. lifting the transfer hose out of said dip pipe and allowing the collected solid discrete particles in the transfer hose past the point of constriction to fall into the filled container without overfilling said container;
H. placing the transfer hose into the dip pipe of a hood on a waiting empty container.

I. releasing the constricting pressure on the transfer hose to resume the transfer operation.

16. A method of transferring dust laden discrete solid par-ticles, as defined in Claim 14 in which said dust laden discrete solid particles are pyrophoric when exposed to air, the improvement which comprises:
A. sparging an inert gas through said hood and into said empty container prior to the transfer operation;
B. continuing said sparging operation through said hood during the filling operation; , C. selectively entraining said pyrophoric dust into said inert gas;
D. collecting said pyrophoric dust in a dust collector;
E. thereafter, discharging said inert gas from said dust collector.

17. A method of transferring dust laden discrete particles, as defined in Claim 15, the further improvement of re-cycling said inert gas from said filter apparatus back to the sparging operation and adding makeup inert gas for the gas lost in the process.

18. A method of transferring dust laden discrete particles of highly pyrophoric materials, which comprises the steps of:
A. loading said pyrophoric material through a transfer hose to a container closed with a dust control hood;
B. establishing a plenum chamber between said hood and said container;
C. circulating an inert gas through plenum, out of said hood to a closed gas loop comprising in a series;

1. a filter;

2. a fan;

3. a source of make up gas;

4. and thence back to said hood.
D. collecting said pyrophoric dust in said filter beneath a blanket of inert gas;
E. providing a second plenum outside said dust control hood;
F. drawing ambient air through said plenum to an exhaust line;
G. drawing said air from said plenum through a second filter;
H. lifting said hood from said container when filled;
I. entraining any excess pyrophoric dust in said stream of ambient air drawn into said plenum;
J. oxidizing said excess pyrophoric dust in said second plenum and in said filter system;
K. disipating excess heat of oxidation through the use if excess volumes of air throughout the plenum and filtration system.