CA1153321B - Laminated tube for collapsible containers and method of making same - Google Patents

Abstract

LAMINATED TUBE FOR COLLAPSIBLE
CONTAINERS AND METHOD OF MAKING
SAME
Abstract of the Disclosure A laminated tube adapted to be used as the body of a collapsible dispensing container includes an inner layer of an epoxy resin, an intermediate layer of aluminum foil and an outer layer of thermoplastic material. The tube is made by forming a foil and epoxy resin laminate into tubular form having longitudinally extending circumferentially over-lapped edges, and extruding thermoplastic material about the foil.

Description

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Background of the Invention This invention relates to the art of collapsible dis-pensing containers and, more particularly, to a laminated tube structure for the body of such a container and a method of making the tube.
Collapsible tubular containers are prov~ded for dispensing a wide variety of products including, ~or example, cosmetics, shampoos, foods, dentifrices and the like. Problems encountered in connection with oxygen absorption and product contamination and permeation have led to considerable ef~orts to provide laminated constructions for the body po~tions of the dispensing containers to overcome the problems. Such laminated construc-tions generally include a barrier layer of metal foil to elimi-nate oxygen absorption and water vapor transmission and inner and outer layers of a thermoplastic material such as polyethylene.
The inner layer of polyethylene protects the product from con-tamination by the metal foil but, while such inner layer can be made relatively thin, an undesirable degree of product permeation still takes place causing deterioration of the product ~n the ~ container. Heretofore, the tubular body portions of such con-tainers have been produced by forming a flat laminate into tubular form with overlapping edges and then heat sealing the edges to provide a tube having a longitudinal ~eam. Such a heat sealed construction necessitates heat sealing compatibility of the inner and outer layers of the laminate and thus requires both layers to be thermoplastic. Accordingly, such previous methods of cor,struction limit selectivity of materials and thus limit the use of containers employing such body constructions.
Moreover, the compatibility requirements for heat sealing have made it impossible to employ thermosetting plastic materials for the inner surface of the tubular body so as to minimize the product permeation ~roblem for the inner layer of a container.
With further regard to such previous container body con-structions, the longitudinal seam produced by heat sealing the .. .. .~ , .
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laminate edges creates problems with respect to providing indicia on the outer surface of the tubular body. In this respect, such a longitudinal seam makes it necessary to pre~print the plastic film defining the outer layer of the laminate by rotogravure printing methods. More particularly, the presence of a longi-tudinal heat sealed seam in the tubular body portion provides an interruption in the otherwise circular outer surface contour of the tube, whereby the tube cannot be printed upon after for-mation thereof by less expensive techniques such as roll print-ing. Still further, such a longitudinal heat sealed seam isvisible and, accordingly, is undesirable from the standpoint of aesthetics.
Definitions .
Mechanical bond, or mechanically bonded, as used herein means a bond in which two films or layers of material are ad-hered to one another such that they can be peeled apart.
Thermal bond, or thermally bonded, as used herein means a bond in which two films or Iayers of material are fused or otherwise adhered to one another such that they cannot be peeled apart without rupturing or tearing one of the films, or layers.
Heat sealed, or heat sealing, as used herein means a thermal bond.
Bond, or bonded, as used herein without reference to either a mechanical or a thermal bond means a bond in which two films or layers of material are adhered either by a mechan-ical bond or by a thermal bond.
Sum~ary of the Invention The disadvantages of collapsible dispensing container bodies heretofore provided, and the disadvantages of the methods of construction thereof are minimized or overcome in accordance with the present invention. In this respect, the present in-vention enables the production of a tubular dispensing-container body having an inner surface which is less permeable than those of laminated structures heretofore provided, enables the pro-duction of a collapsible container body having an outer surfaceuninterrupted by a longitudinal heat sealed seam, and enables the use of a wide variety of materials in producing a tubular dispensing container body by avoiding the necessity for compatible thermoplastic materials to enable heat sealing. In accordance with one aspect of the present in~ention, the inner surface of .. .. . . ..

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a laminated tube for use as a collapsible container body is defined by a thermosetting plastic material which, preferably, is an epoxy resin. In accordance with another aspect of the invention, a laminated tube for use as a dispensing container body includes a tubular core having circumferentially over-lapping marginal side edges, the core being enclosed in a seamless sheath of plastic material in a manner which provides structural integrity for the longitudinal seam without the presence of a heat sealed seam along the tube.
In accordance with a preferred embodiment of the invention, a dispensing container body tube is produced by forming a sheet or laminate of core material into a tubular configuration having circumferentially overlapping marginal-side edges and then en-capsulating the tubular core in a seamless sheath of flowable plastic material, such as by extrusion of the plastic about the core. This advantageously enables the use of thermally incompatible materials for the inner and outer layers of the tube, and enables the use of a thermosetting plastic for the inner layer of the tube- In this respect, the plastic sheath is bonded to the core and thus maintains the core in tubular form, advantageously avoiding the necessity for a heat sealing compatibility between the material of the sheath and a layer of the core defining the inner surface of the tube. Additionally, by avoiding a heat sealed seam the tube can be roll printed after it is produced.
Further, in accordance with a preferred embodiment of the invention, the overlapped marginal side edges of the core are interlocked with the sheath material in a manner which optimizes the structural integrity of the seam when the core is encapsulated and stabilizes the radially inner one of the marginal side edges against displacement inwardly of the tubular body. Such an interlocked relationship preferably is achieved by providing a thin bead of the sheath material along and about the longi-tudinal edge of the radially inner one of the overlapped marginal side edges prior to extrusion of the sheath material about the core. During the extrusion operation the material of the bead fuses and becomes integral with the material of the ; extruded sheath. The heating of the bead material during the extrusion process provides for the overlapped marginal 4~ edges to be mechanically bonded to one another by the interposed . . .

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~;3321 layer of the bead material, and fusing of the bead material with the sheath provides continuity of the sheath material be-tween the overlapped marginal edges and about the longitudinal side edge of the radially inner one of the marginal edges. This mechanical bonding is sufficient to prevent displacement of the radially inner one of the overlapped marginal edges inwardly of the tubular b~dy relative to the outer one of the edges and which displacement would leave only the sheath material along the longi-tudinal seam to hold the core in tubular form. Additionally, the continuity of the sheath material about the side edge of the radially inner one of the marginal edges, locks the overlapped edges against circumferential displacement in the direction of overlap. Thus the structural integrity of the seam is opti-mized and, if the core includes a barrier layer of metal foil, the bead advantageously covers the otherwise exposed edge thereof along the seam.
It is accordingly an outstanding object of the present in-vention to pro~ide an improved laminated tube construction for use as a body of a collapsible dispensing container.
Another object is the provision of a laminated tube con-struction of the foregoing character having an inner surface which provides improved resistance to product permeation.
Yet another object is the provision of a laminated tube construction of the foregoing character having inner and outer layers of thermally incompatible plastic materials.
Still another object is the provision of a laminated tube construction of the foregoing character which is free of any heat sealed seams.
A further object is the provision of a laminated tube con-struction of the foregoing character having an inner layer ofthermosetting plastic material, a barrier layer and an outer layer of plastic material.
Still a further object is the provision of a laminated tube construction of the foregoing character including a tubular core having longitudinally extending circumferentially overlapped marginal side edges encased in a seamless sheath of plastic material in a manner whereby the marginal side edges are inter-locked with the sheath material against relative circumferential displacement of the overlapped edges and radially inward displace-ment of the inner one of the marginal side edges.

~5332~ j Yet a further object is the provision of a laminatedtube construction of the foregoing character which includes a tubular core laminate of metal foil and thermosetting plastic encapsulated in a seamless sheath of plastic material.
Another object is the provision of an improved method for making a laminated tube for use as the body portion of a collapsible dispensing container.
Yet another object is the provision of a method of the foregoing character which enables a wider selectivity with res-pect to plastic materials included in the layers of the laminatedtube.
Still another object is the provision of a method of the foregoing character which enables the tube to have an outer surface free of any visible longitudinal seams.
A further object is the provision of a method of the foregoing character which enables the tube to have inner and outer layers of plastic material which are incompatible for heat sealing.
Yet a further object is the provision of a method of ,20 the foregoing character which enables overlapping edges of a tubular core of the laminated tube to be interlocked with the material of a sheath enclosing the core in a manner which optimizes structural integrity of the longitudinal seam of the completed tube.
In accordance with one broad aspect, the present inven-tion relates to a laminated tube having radially inner and outer surfaces and adapted to be used as the body of a collapsible dis-pensing container comprising, a tubular core including a layer of material providing said inner surface of said tube, said core having longitudinally extending circumferentially overlapped marginal side edges including said layer of material and terminat-ing in circumferentially opposite directions, and a seamless ~53321 - 5a -sheath of plastic material surrounding and bonded to said core and providing said outer surface of said tube, said plastic material of said sheath being thermally incompatible with said core layer providing said inner surface of said tube.
In accordance with another aspect, the present inven-tion relates to a method of making a seamless laminated tube adapted to be used as the body of a collapsible disp~nsing con-tainer comprising, forming a sheet of core material to a tubular configuration having longitudinally extending circumferentially overlapping marginal side edges, said core material having thermally incompatible radially inner and outer surfaces in said tubular configuration, and encapsulating said tubular core in a seamless sheath of plastic thermally incompatible with the core material providing said radially inner surface, and curing said plastic material.
BRIEF DESCRIPTION OF THE DRAWINGS
The foregoing objects, and others, will in part be obvious and in part pointed out more fully hereinafter in con-junction with the written description of preferred embodiments of the invention shown in the accompanying drawings in which:
FIGURE 1 is a perspective view of a core laminate for a laminated tube constructed in accordance with the present invention;
FIGURE 2 is a cross-sectional view showing the core laminate when initially fGrmed into a tube;
FIGURE 3 is a cross-sectional view showing the core just prior to extrusion of the sheath material thereabout;
FIGURE 4 is a cross-sectional view showing the completed tube, and, FIGURE 5 is a plan view schematically illustrating apparatus by which a laminated tube is made in accordance with the present invention.

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~--~Ll~, 1 ~33zl Description of Preferred Embodiments Referring now in greater detail to the drawings wherein the showings are for the purpose of illustrating preferred em-bodiments of the invention only and not for the purpose of limiting the invention, FIGURE 1 illustrates a core laminate 10 comprised of a barrier layer 12 preferably of metallic foil and a layer of thermosetting plastic material 14 suitably bonded to one side of the barrier layer. Laminate 10 has longitudinally extending opposite marginal side edges 16 and 18 and, as set forth more fully hereinafter, marginal edge 16 is provided with a thin bead or film of plastic material 20 after which the laminate is formed about a mandrel 22 to a tubular configuration as shown in FIGURE 2. More particularly, it will be seen that film 20 is longitudinally coextensive with marginal edge 16 lS and includes a portion 20a extending laterally inwardly over barrier layer 12, a portion 20b extending laterally inwardly over thermosetting plastic layer 14, and a portion 20c extend-ing across the vertical side edge of the laminate. When core laminate 10 is formed to the tubular configuration, marginal side edges 16 and 18 are disposed in circumferentially over-lapping relationship with thermosetting plastic layer 14 dis-posed inwardly of the tube Accordingly, marginal edge 16 becomes the radially inner one of the overlapped edges, and portion 20a of film 20 is disposed between marginal edges 16 and 18 and more particularly between the.foil of marginal edge 16 and the thermosetting plastic of marginal edge 18.
As seen in FIGURE 3, overlapping edges 16 and 18 are then displaced radially against a flat 24 on mandrel 22, As ex-plained hereinafter, this enhances achieving a more uniform radial thickness of the sheath material in which the core is subsequently encapsulated, As seen in ~IGURE 4, the tubular core is then encapsulated in a seamless sheath of plastic material 26 which is bonded to the outer surface of barrier layer 12 so as to maintain the core in tubulàr form. Film 20 and sheath material 26 are of the same plastic material and during encapsulation, portion 20a of film 20 fuses with and becomes integral with sheath material 26. Film portion 20a mechanically bonds with the thermosetting plastic on marginal edge 18 to hold marginal edge 16 against displacement radially inwardly of the encapsulated core relative to marginal edge 18.

33~1 This advantageously avoids a longitudinal line of potential weakness which would result from such displacement of marginal edge 16 in that the tube seam would then be defined only by the thickness of the sheath material in area 26a thereof.
Further, the fusing of sheath material 26 with bead portion 20a provides a thermal bond therebetween, whereby bead 20 becomes an integral extension of the sheath which locks around the longitudinal inner edge of the core and thus ad-vantageously resists any relative circumferential displacement of marginal edges 16 and 18 in the direction of overlap thereof.
Thus, overlapped edges 16 and 18 are stabilized by the mechanical bond and the locking relationship, and the structural integrity of the longitudinal seam along the co~pleted container body is optimized.
Encapsulation enables the outer surface 28 of the tube to be circular ;n cross-sectional contour and free of any longi-tudinal seams. Moreover, encapsulation avoids the necessity for heat sealing compatibility between the plastic materials of inner and outer layers 14 and 26 of the tube as is required to achieve a thermally bonded seam in tube constructions hereto-fore provided. At the same time, it will be appreciated that the materials of the inner and outer layers can be compatible if desired. Thus, inner and outer layers 14 and 26 in the embodiment described can be like or different thermosetting materials, or a combination of a thermosetting inner layer and a thermoplastic outer layer. Ther~fore, it will be appreci-ated that the inner and outer layers can be selected from a wide variety of materials depending on the particular product to be stored and dispensed from a collapsible container having a body portion made from the tube.
In the preferred embodiment, the thermosetting material of inner layer 14 is a high temperature setting epoxy resin, and outer layer 26 is a thermoplastic material, preferably a low density polyethylene. Barrier layer 12 is aluminum foil having a thickness of about 0.002 inch. Epoxy layer L4 has a thickness of about 0.0005 inch, a suitable epoxy resin being that sold by Hanna Chemical Company of Columbus, Ohio unde_ product designation H-ll or H-23, which has a curing tempera-ture of about 550F and a curing time of about eight minutes.
Polyethylene layer 26 has a thickness of about 0.003 inch and, . . . .. .. . . . .. . . .

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with regard thereto, it will be appreciated that the thickness in the area 26a thereof will vary from the latter dimension.
Bead 20 is also polyethylene, and portions 20a, 20b and 20c thereof each have a thickness of about 0.003 inch. Further, marginal edges 16 and 1~ have a circumferential overlap of about 0.090 inch and bead portions 20a and 20b have a lateral width corresponding to the dimension of overlap.
The laminated tube is preferably produced continuously, and the tubular core is preferably encapsulated in sheath 26 by extruding the sheath thereabout. FIGURE 5 of the drawing schema-tically illustrates production of the tube in this manner. In this respect, a roll 30 of the laminated core material 10 is supported at one end of the forming apparatus to provide an indeterminate length of the core material. The forming apparatus includes circular mandrel 22 referred to hereinabove and which has an upstream end 22a thereof attached by welding or the like to a rigid support member 32. Mandrel 22 extends the full length of the apparatus and has a downstream terminal end 22b. Core material 10 is continuously fed from roll 30 to a forming plow 34 which, in a well known manner, operates to bend material 10 into tubular form about mandrel 22 as the core material moves through the plow. Bead 20 is applied in the form of molten thermoplastic material to edge 16 of the core material upstream from plow 34. The bead can for ex-ample be applied by means of a pump P having a nozzle struc-tured and positioned to apply the bead as shown in FIGURE 1.
The plastic material of bead 20 can be supplied to pump P
from any suitable source and, for example, can be supplied from the source of molten plastic for the sheath extruder referred to hereinafter.
It will be appreciated that plow 34 and mandrel 22 co-operate to form core material 10 substantially to the tubular configuration shown in FIGURE 2 of the drawing. By the time bead 20 engages the mandrel surface it has cooled sufficiently to avoid any problems of adherence of bead portion 20b there-with. The tubular core material then passes along mandrel 2~
through a sizing ring device 36 which, as is well known, serves to bring the tubular core to a desired cross-sectional dimen-sion. Depending on the materials of the core laminate, it may be desirable to warm the material to enhance the sizing operation ... . - - .. , :

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- -~3321 g and, for this purpose, sizing member 36 preferably includes a circumferentially closed housing having inlet and outlet pass-ages 38 and 40 for circulating hot air therethrough. From sizing member 36, the tubular core passes along mandrel 22 through an extrusion cross head die 42 by which outer layer 26 of plastic material is extruded onto the exterior surface of the tubular core. Preferably, to obtain a generally uniform radial thickness of extruded layer 26, roller R is provided at the entrance end of extrusion die 42 in cooperable relationship with flat 24 on mandrel 22 to form the radial step in overlapped marginal ~ide edges 16 and 18 of laminate 10 as shown in FIGURE 3.
The material extruded onto the tubular core can either be a thermoplastic or thermosetting plastic material and is fed to cross head die 42 through an inlet 44 leading from a plastic extruder, not shown. As mentioned hereinabove, pump P for applying head 20 to the core material can also be connected to the extruder to receive the molten plastic for the bead there-from. In the preferred embodiment, outer layer 26 is a thermo-plastic material and, accordingly, the sheathed tube exiting from cross head die 42 passes through a cooling jacket 46 to at least partially cure the extruded plastic layer. For this purpose, it will be appreciated that jacket 46 is provided with inlet and outlet passages 48 and 50, respectively, to facilitate the circulation of a suitable cooling medium therethrough. It will be further appreciated of course that a heating jacket would be employed if layer 26 was a thermosetting plastic. A
suitable drive arrangement such as endless belts 52 and 54 is provided adjacent the outlet of cooling Jacket 46 to facilitate driving the completed tube from the downstream end 22b of mandrel 22, and it will be appreciated that a suitable cut-off mechanism, not shown, is preferably provided beyond the down-stream end of the mandrel to cut the finished tube into desired lengths.
While the preferred tube structure has an inner layer of a thermosetting plastic material, a layer of metal foil to which the thermosetting plastic layer is bonded and an outer layer of plastic bonded to the metal foil and providing the outer surface of the tube, it will be appreciated that layers of material could be interposed between the thermosetting plastic inner layer and metal foil and between the metal foLl and outer x- 6118 -. .

plastic layer. It will be further appreciated that the barrier layer could be defined by a material other than a metal foil as herein described. In this respect, the laminate materials will be determined at least in part by the product with which the tube is to be used. Still further, if the tube were to be used for the body of a dispensing container in which the metal foil would not contaminate the product or be corroded therehy, the metal foil alone could define the core, or could define the inner layer of a laminate core. The method of the present invention advantageously enables a tube to be formed without thermally bonding the overlapping marginal edges of the core, thus avoiding the e~pense of equipment for this pur-pose, eliminating the need for and the expense of providing thermoplastic layers on opposite sides of the core laminate for heat sealing, and thus increasing the selection of core materials and combinations thereof in a laminated core structure.
Accordingly, it will be appreciated that many embodiments of the present invention can be made and many changes can be made in the embodiments herein illustrated and described, whereby it is to be distinctly understood that the foregoing descrip-tive matter is to be interpreted merely as illustrative of the invention and not as a limitation.

Claims (30)

1. A laminated tube having radially inner and outer surfaces and adapted to be used as the body of a collapsible dispensing container, comprising:
(a) a tubular core, including a layer of material providing said inner surface of said tube, said core having longitudinally extending circumferentially overlapped marginal side edges including said layer of material and terminating in circumferentially opposite directions;
(b) a seamless sheath of plastic material surrounding and bonded to said core and providing said outer surface of said tube, said plastic material of said sheath being thermally incompatible with said core layer providing said inner surface of said tube; and, (c) a film of plastic material compatible with the material of said sheath and extending therefrom between said overlapped marginal side edges to provide a mechanical bond therebetween.

2. The laminated tube according to claim 1, wherein said core has radially inner and barrier layers, said inner layer providing said inner surface of said tube and being a thermosetting plastic material, and said barrier layer being a metal foil.

3. The laminated tube according to claim 2, wherein said thermosetting plastic material is an epoxy resin.

4. The laminated tube according to claim 3, wherein said metal foil is aluminum.

5. The laminated tube according to claim 4, wherein said plastic material of said outer surface is a thermoplastic material.

6. The laminated tube according to claim 3, wherein said thermosetting plastic material is on one side of said metal foil and said plastic material of said sheath is on the opposite side of said metal foil.

7. The laminated tube according to claim 6, wherein said thermosetting plastic material is an epoxy resin.

8. The laminated tube according to claim 6, wherein said thermosetting plastic material is an epoxy resin and said metal foil is aluminum.

9. The laminated tube according to claim 6, wherein said thermosetting plastic material is an epoxy resin and said material of said sheath is a thermoplastic material.

10. The laminated tube according to claim 9, wherein said metal foil is aluminum.

11. The laminated tube according to claim 6, wherein said metal foil is aluminum and said material of said sheath is a thermoplastic material.

12. The laminated tube of claim 1, wherein the film of plastic material is a bead extending from the sheath between said overlapped marginal edges and about the free edge of the radially inner one of said overlapped edges.

13. The laminated tube according to claim 12, wherein said core is a laminate including a barrier layer and a film of thermosetting plastic material bonded thereto, said thermosetting plastic film providing said inner surface of said tube.

14. The laminated tube according to claim 13, wherein said barrier layer is a metal foil.

15. The laminated tube according to claim 13, wherein said thermosetting plastic film is an epoxy resin.

16. The laminated tube according to claim 13, wherein said sheath is a thermoplastic material.

17. The laminated tube according to claim 13, wherein said barrier layer is a metal foil and said thermosetting plastic film is an epoxy resin.

18. The laminated tube according to claim 17, wherein said sheath is a thermoplastic material.

19. The laminated tube according to claim 18, wherein said metal foil provides the outer surface of said core and said sheath is bonded to said foil.

20. A method of making a seamless laminated tube adapted to be used as the body of a collapsible dispensing container, comprising the steps of:
(a) forming a sheet of core material to a tubular configuration having longitudinally extending circumferentially overlapping marginal side edges, said core material having thermally incompatible radially inner and outer surfaces in said tubular configuration;
(b) encapsulating said tubular core in a seamless sheath of plastic thermally incompatible with the core material providing said radially inner surface;
(c) providing a film of plastic material thermally compatible with the material of said sheath to extend from the sheath between said overlapped marginal side edges; and (d) curing said plastic material.

21. The method according to claim 20, wherein said sheet of core material is of indeterminate length, wherein the sheet of core material is continuously formed to said tubular configuration, and wherein the tubular core is continuously encapsulated by extruding said plastic material thereabout.

22. The method according to claim 20, wherein the film is continuously provided in the form of a bead along and about the edge of said sheet defining the radially inner one of said overlapping marginal side edges.

23. The method according to claim 20, wherein said core is a laminate including a layer of barrier material and a layer of thermosetting plastic formed with said thermosetting plastic layer disposed inwardly and providing said radially inner surface, and said film is a bead of plastic material applied along and about the free edge of the radially inner one of said marginal side edges.

24. The method according to claim 23, wherein the sheath is extruded to have a circular outer surface contour in cross-section.

25. The method according to claim 20, wherein said core is a laminate including adjacent layers of metal foil and thermosetting plastic, said core being continuously formed with said thermosetting plastic disposed inwardly, said film being a bead of plastic material continuously flowed onto the marginal edge of said laminate defining the radially inner one of said overlapped edges, and said core being encapsulated by continuously advancing said tubular core through an extrusion die and extruding a sheath of plastic material about said tubular core.

26. The method according to claim 25, wherein said material of said sheath is thermoplastic, and wherein said encapsulating includes cooling said sheath downstream from said extrusion die.

27. The method according to claim 25, wherein said metal foil of said laminate defines the outer surface of said tubular core, and wherein said encapsulating includes extruding said plastic sheath onto said metal foil.

28. The method according to claim 27, wherein said thermosetting plastic of said laminate is an epoxy resin.

29. The method according to claim 28, and wherein said encapsulating includes extruding said sheath to have a circular outer surface contour in cross-section.

30. The method according to claim 25, wherein said thermosetting plastic of said laminate is an epoxy resin.