CA1130782A - Decontamination method - Google Patents

Decontamination method

Info

Publication number
CA1130782A
CA1130782A CA360,892A CA360892A CA1130782A CA 1130782 A CA1130782 A CA 1130782A CA 360892 A CA360892 A CA 360892A CA 1130782 A CA1130782 A CA 1130782A
Authority
CA
Canada
Prior art keywords
hone
tube
fluid
tubes
rotatable
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
CA360,892A
Other languages
French (fr)
Inventor
Thomas H. Dent
Edward H. Smith
Robert T. Marchese
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
CBS Corp
Original Assignee
Westinghouse Electric Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Westinghouse Electric Corp filed Critical Westinghouse Electric Corp
Application granted granted Critical
Publication of CA1130782A publication Critical patent/CA1130782A/en
Expired legal-status Critical Current

Links

Classifications

    • GPHYSICS
    • G21NUCLEAR PHYSICS; NUCLEAR ENGINEERING
    • G21FPROTECTION AGAINST X-RADIATION, GAMMA RADIATION, CORPUSCULAR RADIATION OR PARTICLE BOMBARDMENT; TREATING RADIOACTIVELY CONTAMINATED MATERIAL; DECONTAMINATION ARRANGEMENTS THEREFOR
    • G21F9/00Treating radioactively contaminated material; Decontamination arrangements therefor
    • G21F9/001Decontamination of contaminated objects, apparatus, clothes, food; Preventing contamination thereof
    • G21F9/005Decontamination of the surface of objects by ablation
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F22STEAM GENERATION
    • F22BMETHODS OF STEAM GENERATION; STEAM BOILERS
    • F22B37/00Component parts or details of steam boilers
    • F22B37/002Component parts or details of steam boilers specially adapted for nuclear steam generators, e.g. maintenance, repairing or inspecting equipment not otherwise provided for
    • F22B37/003Maintenance, repairing or inspecting equipment positioned in or via the headers
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28GCLEANING OF INTERNAL OR EXTERNAL SURFACES OF HEAT-EXCHANGE OR HEAT-TRANSFER CONDUITS, e.g. WATER TUBES OR BOILERS
    • F28G3/00Rotary appliances
    • F28G3/08Rotary appliances having coiled wire tools, i.e. basket type
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28GCLEANING OF INTERNAL OR EXTERNAL SURFACES OF HEAT-EXCHANGE OR HEAT-TRANSFER CONDUITS, e.g. WATER TUBES OR BOILERS
    • F28G3/00Rotary appliances
    • F28G3/16Rotary appliances using jets of fluid for removing debris
    • F28G3/163Rotary appliances using jets of fluid for removing debris from internal surfaces of heat exchange conduits

Landscapes

  • Engineering & Computer Science (AREA)
  • General Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • High Energy & Nuclear Physics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Food Science & Technology (AREA)
  • Thermal Sciences (AREA)
  • Cleaning In General (AREA)

Abstract

14 48,631 ABSTRACT OF THE DISCLOSURE
The decontamination method comprises inserting a rotatable hone into a tube while rotating and moving the hone through the tube at a rate of approximately 6-12 revolutions of the hone per inch of tube.

Description

.3 ~ ~ S %

1 48,631 DECONTAMINATION METHOD
CROSS-REFERENCE TO RELATED APPLICATION
This application is related to ~ Appli-cation Serial No. ~co,~.3 , entitled "Decontamination Apparatus" filed~ n the name of E. H. Smith et al. and assigned to the same assignee.
BACKGROUND OF THE INVENTION
This invention relates to decontamination methods and more particularly to a method for decontam-inating heat exchange tubes in a nuclear steam generator.
A typical nuclear steam generator comprises a vertically oriented shell, a plurality of U-shaped tubes disposed in the shell so as to form a tube bundle, a tubesheet for supporting the tubes at the ends opposite the U-like curvature, and a dividing plate that cooperates with the tubesheet orming a primary fluid inlet plenum at one end of the tube bundle and a primary fluid outlet plenum at the other end of the tube bundle. The primary fluid having been heated by circulation through the nu-clear reactor core enters the steam generator through the primary fluid inlet plenum. From the primary fluid inlet plenum, the primary fluid flows upwardly through first openings in the IJ-tubes near the tubesheet which supports the tubes, through the U-tube curvature, downwardly through second openings in the U-tubes near the tubesheet, and into the primary fluid outlet plenum. At the same time, a secondary fluid known as feedwater, is circulated around the U-tubes in heat transfer relationship there-with, thereby transferring heat from the primary fluid in ~ 2
2 48,631 t:he tubes to the secondary fluid surrounding the tubes causlng a portion of the secondary fluid to be converted to steam. Since the primary fluid contains radioactive particles and is isolated from the secondary fluid by the U-tube walls and the tubesheet, it is important that the U-tubes and tubesheet be maintained defect-free so that no breaks will occur in the U-tubes or in the welds between the U-tubes and the tubesheet, thus preventing contamina-tion of the secondary fluid by the primary fluid.
Occasionally, it is necessary to inspect or repair the U-tubes or the tubesheet welds by way of access through the primary fluid inlet and outlet plena. For this purpose, manways are provided in the vertical shell so that working personnel may enter the inlet and outlet 1~ plena to perform operations on the U-tubes and tubesheet.
Ilowever, since the primary fluid which is generally water contains radioactive particles, the inlet and outlet plena become radioactive, which thereby limits the time that working personnel may be present therein. In addition, since the primary fluid is conducted through the U-tubes, the U-tubes also become contaminated. Accordingly, it would be advantageous to be able to perform operations on the U-tubes and tubesheet without being exposed to high levels of radiation. Consequently, it is important to decontaminate lhe inlet and outlet plena together with a portion of the U-tubes so that working personnel may enter the inlet and outlet plena o~ the nuclear steam generator to perform operat:ions thereon.
Therefore, what is needed is a method that i.s capable of decontaminating the U-tubes so as to reduce the radiation level in the inlet and outlet plena of the nllclear steam generator so that work may be performed thereon.
SUMMARY OF THE INVENTION
The decontamination method comprises inserting a rotatable hone into a tube while rotating and moving the hone through the tube at a rate of approximately 6-12 revolutions of the hone per inch of tube.

~.3~7~3;2
3 48~31 RIEF DESCRIPTION OF THE ~RAWINGS
While the specification concludes with claims particularly pointing out and distinctly claiming the subject matter of the invention it is believed the inven-tion will be better understood from the following descrip-tion taken in conjunction with the accompanying drawings wherein:
Figure 1 is a partial cross-sectional view in elevation of a typical steam generator;
Figure 2 is a diagram of the decontamination apparatus shown in relation to a typical steam generator, Figure 3 is a partial cross-sectional view of the rotatable hone disposed within a heat exchange tube of a nuclear steam generator;
Figure 4 is an enlargement of the rotatable hone;
Figure 5 is a detailed cross-sectional view of the rotatable hone apparatus;
Figure 6 is a partial cross-sectional view in elevation of the cleaning apparatus and drive mechanism;
Figure 7 is a view along line VII-VII of Figure 6;
Figure 8 is a view along line VIII-VIII of Figure 6; and Figure 9 is a view along line IX-IX of Figure 6.
DESCRIPTION OF THE PREFERRED FMBODIMENT
In a tube-type steam generator, a tubesheet supports a bundle of heat transfer tubes. The invention described herein provides a method that is capable of remotely decontaminating the heat transfer tubes in a nuclear steam generator.
Referring to Figure 1, a nuclear steam generator referred to generally as 20, comprises an outer shell 22 with a primary fluid inlet nozzle 24 and a primary fluid outlet nozzle 26 attached thereto near its lower end. A
generally cylindrical tubesheet 28 having tube holes 30 therein is also attached to outer shell 22 near its lower end. A dividing plate 32 attached to both tubesheet 28 ~L~3~
4 4$,631 and outer shell 22 defines a primary fluid inlet plenum 34 and a primary fluid outlet plenum 36 in the lower end of the stea~ generator as is well understood in the art.
Tubes 38 which are heat transfer tubes shaped in a U-like curvature are disposed within outer shell 22 and attached to tubesheet 28 by means of tube holes 30. Tubes 38, which may number about 3,500 form a tube bundle 40. In addition, a secondary inlet nozzle 42 is disposed on outer shell 22 for providing secondary fluid such as water while steam outlet nozzle 44 is attached to the top of outer shell 22. In operation, the primary fluid which may be water having been heated by circulation through the nu-clear reactor core enters steam generator 20 through primary fluid inlet nozzle 24 and flows into primary fluid 15 inlet plenum 34. From primary fluid inlet plenum 34, the primary fluid flows upwardly through tubes 38, through tubesheet 28, up through the U-shaped curvature of tubes 38, down through tubes 38 and into the primary fluid outlet plenum 36, where the primary fluid exits the steam generator through primary fluid outlet nozzle 26. While flowing through tubes 38, heat is transferred from the primary fluid to the secondary fluid which surrounds the tubes 3~, causing the secondary fluid to vaporize. The resulting steam then exits the steam generator through steam outlet nozæle 44. On occasion, it is necessary to inspect or repair tubes 38 or the welds between the tubes 38 and the tubesheet 28 to assure that the primary fluid, which may contain radioactive particles, remains isolated from the secondary flu-id. Therefore, manways 46 are provided in outer shell 22 to provide access to both primary fluid inlet plenum 34 and primary fluid outlet plenum 36 so that access may be had to the entire tube-sheet 28.
Referring now to Figure 2, the decontamination apparatus is referred to generally as 50 and comprises a rotatable hone 52 capable of being disposed within tubes 38. Rotatable hone 52 has an attachment mechanism 54 disposed around it for guiding the rotatable hone in rela-48,631 ~ionship to tubesheet 28. Attachment mechanism 54 has aplurality of camlocks 56 attached thereto for being dis-posed in tubes 38 so as to support attachment mechanism 54 from tubesheet 28. Camlocks 56 may be chosen from those well known in the art. As an alternative to the use of attachment mechanism 54, rotatable hone 52 may be sup-ported and by guided remote handling devices (not shown).
Decontamination apparatus 50 also comprises a first flexi-ble conduit 58 attached to attachment mechanism 54 and n capable of being extended through manway 46 to cleaning mechanism 60. Cleaning mechanism 60 is provided for removing contamination from rotatable hone 52 as rotatable hone 52 is removed from steam generator ~0. Decontamina-tion apparatus 50 also comprises advancement mechanism 62 for advancing and withdrawing rotatable hone 52. Advance-ment mechanism 62 may comprise a tandem set of motorized rubber belts in contact with rotatable hone 52 for moving rotatable hone 52 in a desired direction. In addition decontamination apparatus 50 comprises drive mechanism 64 and cable holding apparatus 66. Drive mechanism 64 serves as the mechanism to rotate rotatable hone 52 while cable holding apparatus 66 provides a mechanism for winding and unwinding the cable of decontamination apparatus 50.
Referring now to Figures 3, 4, and 5, rotatable hone 52 comprises helical wound tubing 68 capable of conducting a f:Luid therethrough. ~ nozxle 70 is attached to one end of helical wound tubing 68 while a screw fit-ting 72 is connected to the other end thereof. A spirally wound brush 74 is disposed on helical wound tubing 68 between screw fittings 72 and nozzle 70 for contacting the inside of tubes 38 and removing contaminants therefrom when rotatable hone 52 is rotated. Brush 74 may be chosen from those well known in the art of honing. Brush 74 is chosen such that it is capable of removing a thin layer of contaminated me~al from the insides of tubes 38 to thereby reduce the contamination of the tubes 38. Nozzle 70 has a plurality of channels 76 disposed therein for conducting the fluid from nozzle plenum 78 and directing the fluid _ ~ ~ 3 toward the inside of tubes 38 to thus lubricate brush 74 and to flush the contaminated particles that have been removed by brush 74. Channel 76 may have a diameter of approximately 1/32 inch and may be arranged at approxi-mately between 20 to 40 angle with respect to the longi-tudinal axis of nozzle 70 and preferably at approximately 30. As rotatable hone 52 is rotated and as brush 74 contacts the inside of tubes 38 a fluid such as water is conducted through helical wound tubing 68, into nozzle plenum 78, and out through channel 76 into contact with the inside of tube 38 and brush 74. In this manner a thin layer of metal is removed from the inside of tubes 38 and flushed through first flexible conduit 58 to cleaning mechanism 60. The fl.uid conducted through helical wound tubing 68 serves to not only flush away the contaminated particles, but it also serves to lubricate and cool brush 7~
Stil.l referring to Figures 3, 4, and 5, rotat-able hone 52 also comprises an outer member 80 that is attached to second flexible conduit 82 in a fluid-tight manner and is capable of being disposed in first flexible conduit 58. A bushing 84 is disposed in outer member 80 and has inner member 86 rotatably disposed therein. Inner member 86 has a bore 88 therethrough for conducting a fluid. Screw fitting 72 is capable of being attached to inner member 86 by means of threads 90 in inner member 86.
Inner member 86 also has a plurality of passages 92 in its lower end for a allowing the fluid to enter inner member 86 and to flow through bore 88 into helical wound tubing 68. At its lower end, inner member 86 is firmly attached to cable 94 which is attached to drive mechanism 64 lo-cated outside the steam generator for rotating inner member 86 and helical wound tubing 68 thus rotating brush 74 of rotatable hone 52. Cable 94 is disposed in second flexible conduit 82 so as to allow a fluid such as water to be conducted through second flexible conduit 82 and into the annulus between inner member 86 and outer member 80 so as to force the fluid through passages 92 and :

~3~;37~
; .,`;, l~;, through bore 8~. lhe fluid is condu~ d ~ hrou~h ~<:)r~
through helical wound tubing 68, and into nozzle plenum 78. From nozzle plenum 78, the fluid is forced through channel.s 76 of nozzle 70 and into contact with brush 74 and the inner surface of tubes 38. The fluid entrains the contaminants that are removed by brush 74 and carries the contaminants to the bottom of tube 38 where they are carried away through first flexible conduit 58 to cleaning mechanism 60.
Referring now to Figures 6-9, cleaning mechanism 60 comprises a housing 96 with flexible conduit 58 at-tached thereto at one end. Second flexible conduit 82 and cable 94 are arranged to slide through first flexible conduit 58, through a central passage in housing 96, and into attachment with drive mechanism 64. A first fluid return chamber 98 is defi.ned in housing 96 and in fluid communication with first flexible conduit 58 so that the fl.uid that is being returned by first flexible conduit 58 flows int.o first fluid return chamber 98 and into drain ~n piping 100. From drain piping 100, the fluid is conducted to ei~.her a waste disposal treatment facility or to a recircu:l.ation facil:ity chosen from those well known in the art. A spray chamber 102 is also defined within housing 96 for spraying a se~ond fluid which may also be water onto second flexible conduit 82 for removing contamination from second flexible conduit 82. Spray chamber 102 com-prises an outer sleeve 104 which may be a substantially cylindr:ical member and an inner sleeve 106 disposed within outer sleeve 104. Inne~ sleeve 106 has holes disposed therein for conducting the second fluid therethrough. An inlet. port 108 i.s attached to the outside of outer s:leeve 104 for conducting the second ~luid illtO the annulus defined between outer sleeve 104 and inner sleeve 106.
From the annulus defined between inner sleeve 106 and outer sleeve 104, the second fluid is conducted there-through and out of the holes in inner sleeve 106. In this manner, the second fluid is sprayed against second flexi-ble cond~lit 82 for removing the contamination therefrom.

~3f~.-q7~2 8 48,631 A spray water return chamber 110 is also disposed within housing 96 and connected to drain piping 100. Spray water returll <~h~lmber 110 serves to collect the spray of the secon{l fLuid ~Ind conduc~ the second fluid into drain piping 100 thereby removing contaminants from second flexible conduit 82. A wiper section 112 is attached to the end of housing 96 such that second flexible conduit 82 passes therethrough. Wiper section 112 comprises a plur-ality of buffing cloths 114 which are disposed within wiper section 112 and in contact with second flexible conduit 82 for removing fluid and contaminants from second flexible conduit 82. The excess fluid that is collected by buffing cloths 114 is allowed to drip into drip pan 116 and from there allowed to flow into drain piping 100.
Therefore, it can be seen that cleaning mechanism 60 serves to conduct the first fluid from first flexible conduit 5~ to drain piping 100 and serves to clean second f'lexible conduit 82.
Referring now to Figure 6, drive mechanism 64 comprises a chuck 118 having an opening 120 therein.
Cable 94 is rotatably disposed within chuck 118 and at-tached to motor 122 by means of a rotatable connector 124.
Motor 122 may be a 0.5 horsepower motor chosen from those well kr.own in the art and is provided for ro~ating cable 94 and rotatable hone 52. I`he second flexible conduit 82 is also attached to chuck 118. Opening 120 is provided for conducting a ~'luid into chuck 118 and into second ~lexible conduit 82 while cable 94 is bei.ng rotated by n~otor 122. Thus, chuck 118 provides a mechan.ism whereby 3 cable 94 can be rotated without second f'lexible conduit 82 being rot.ated thereby allowing a fluid to be conducted through second flexible conduit 82 and around cable 94.
Motor 122 serves to rotate cable 94 which in turn rotates rotatable hone 52 thus removing the contaminatlon from the i.nside of tubes 38. Drive mechanism 64 is supported on cable holding apparatus 66. Cable holding apparatus 66 may be a rotatable platform or a take-up wheel capable of rotating so as to accommodate the excess cable 94 and ~34.~7~2 ,`.,(~;l excess second f,lexible conduiL 82 under the influence ot advancement mechanism 62. Thus, drive mechanism 64, the excess o~f cable 94, and the excess of second flexible (onduit 82 are stored on cable holding apparatus 66 such rj that when advancement mechanism 62 advances cable 94 and second f:l,exible conduit 82, cable holding apparatus 66 rotates to allow such advancement. On the other hand, when advancement mechanism 62 retracts second flexible conduit 82 and cable 94, cable holding apparatus 66 ro-tates in the opposite direction, thus storing the excesscable and conduit.
OPERAI'ION
When it becomes necessary to inspect or repair st.eam generator 20, steam generator 20 is deactivated and :l.5 drainecl of its primary fluicl. Next, personnel enter steam generator 20 through manways 46 ~.o position decontamina-~ion app~rclt-us 50 in relationship thereto so as to decon-tamin.l~e t.he steam generatoL. A~tachment mechani.sm 54 i.s at-r;lnged near tubesheet. 28 so that camlocks 56 are in-,?~) serted i.nl:o t.ubes ~8. Camlocks 56 are then activatedthereby support:i.ng attachment mechanism 54 from tubesheet 28. In ~his manner first ~lexible conduit 58 is attached to a particular tube 38 i.n a fluid-tight manner.
Once first flexible condui~ 58 has been con-nected to the sel.ected tube 38, rotatable hone 52 is theninserted i.nto f;.rst ~lexib'l.e conduit 58 and advanced therethrouKh by means o~' advancement mechanism 62. When rotatable honc 52 has reached the desired location within t:ube 38~ drive mechan;sm 64 is activated which results in 3(~ motor 122 rotaling cable 9l~ and rotatable hone 52 a~ the desired angular speed. ~t the same time, a first fluid which may be wa~er is conducted under a pressure o~ be-tween apl~roximately 1800 psi to 2,000 psi through opening 120 and illtO chuc~k 118. From chuck 118, the first fluid ~'j is collducLed through second flexible conduit 82 and into :i.nner n~ember 86~ From inner member 86 the first fluid is then collducted through helical wound tubing 68 and out through channels 76 of nozzle 70. The first fluid co~n-!

3'~
48,631 ~-~ct~; brush 74 and the inside of tubes 38 as brush 74 rotates in contact with the inside ~f tul>e 3~. I`hc .
of brush 74 remo~,7es d thin lclyt~L ~ t~ ~n~ lin~
from the inside of tube 38 which thereby lowers the radia-tion level of tube 38. The first fluid entrains the contaminated metal that has been removed and carries it to the bottom of tube 38 where the first fluid enters first flexible conduit 58. First flexible conduit 58 carries the first fluid with contaminants entrained therein to ]() cleaning mechanism 60 and into drain piping 100.
Advancement mechanism 62 moves rotatable hone 52 through tube 38 at a linear rate slow enough to ensure proper decontamination but at a fast enough rate to pre-vent degradation of tube 38. The rate at which rotatable hone 52 is moved through tube 38 is chosen so as to achieve a sufficient decontamination factor (DF) where:

DF - Initial Activity Fina Activity It has been found that it is important for rotatable hone 52 to rotate at between approximately 6-12 revolutions per inch of tube 38. At approximately 6-12 revolutions per inch of tube, a decontamination factor of between approxi-mately 20-25 may be achieved. Thus, a decontamination factor o between 20-25 can be attained for various com-binations of rotational speed and linear speed of rotat-able hone 52. The following table illustrates some of thecombinations that will yield approximately 6-12 revolu-tions per inch and thus yield decontaminations factors of between 20-25.
Rotational Speed Linear SpeedRevolutions 3(~of hone (rpm) of ho~ 5~ inch of tube 13.3'.'~i7~
11 48,631 I'h~re~or-~, d~contaminations factors of approximately 20-25 can be achi~ved ~or rotational speeds of between 800-3500 rpm and for linear speeds of between 5 ft/min to 50 ~t/min. The actual choice of rotational speeds and linear speeds may depend upon the time available to complete the operation.
Once a sufficient portion of tube 38 has thus been decontaminated, advancement mechanism 62 is reversed which causes rotatable hone 52 to be withdrawn from tube 38. As second flexible conduit 82 is withdrawn under the action of advancement mechanism 82, a second fluid which may also be water is introduced into spray chamber 102 through inlet port 108. The second fluid is sprayed against second flexible conduit 82 thereby washing contam-inants therefrom and into spray water return chamber 110.
From spray water return chamber 110, the second fluid is conducted through drain piping 100. As second flexible conduit is withdrawn, it also contacts buffing cloths 114 which wipe residual fluids and contaminants therefrom.
2n When rotatable hone 52 has thus been withdrawn from the selected tube 38, the same process may then be performed on another tube. Of course, several rotatable hones 52 may be arranged on a sing:le attachment mechanism
5~ so that several tubes 38 may be decontaminated at once.
In this manner, tubes 38 are decontaminated thereby reduc-ing the radiation level in primary fluid inlet plenum 34 and primary flu:id outlet plenum 36 so that working person-nel may enter and perform opera~ions in steam generator 20. There~ore, it can be seen that the invention provides 3 a decontamination method capable of decontaminating tubes in a nuclear steam generator.

Claims (6)

12 48,631 We claim as our invention:
1. A method for decontaminating tubes com-prising:
inserting a rotatable hone into a tube;
rotating said hone while said hone is disposed in said tube; and moving said hone through said tube so that said hone rotates at a rate of approximately 6-12 revolutions of said hone per inch of said tube.
2. The method according to claim 1 wherein said method further comprises spraying a fluid from said hone while said hone is rotating.
3. The method according to claim 2 wherein said fluid is water.
4. The method according to claim 3 wherein said method further comprises rotating said hone at between approximately 800 rpm to 3500 rpm.
5. The method according to claim 4 wherein said method further comprises moving said hone through said tube at a rate of approximately 5-50 ft/min.
6. A method for decontaminating tubes compris-ing:
inserting a rotatable hone into a tube;
rotating said hone at between approximately 800-3500 rpm while spraying water from said hone; and moving said hone through said tube at between approximately 5-50 ft/min resulting in approximately 6-12 revolutions of said hone per inch of said tube and thus removing contamination from the inside surface of 13 48,631 said tube and carrying the contaminants away in said water.
CA360,892A 1979-10-16 1980-09-23 Decontamination method Expired CA1130782A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US8544579A 1979-10-16 1979-10-16
US085,445 1979-10-16

Publications (1)

Publication Number Publication Date
CA1130782A true CA1130782A (en) 1982-08-31

Family

ID=22191643

Family Applications (1)

Application Number Title Priority Date Filing Date
CA360,892A Expired CA1130782A (en) 1979-10-16 1980-09-23 Decontamination method

Country Status (2)

Country Link
KR (1) KR830001010B1 (en)
CA (1) CA1130782A (en)

Also Published As

Publication number Publication date
KR830001010B1 (en) 1983-05-24

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