CA1127385A - Fluorescent material - Google Patents

Abstract

ABSTRACT OF THE DISCLOSURE
A fluorescent material is an alkaline earth metal boron phosphate activated by a divalent europium compound having the formula m(Sr1-x-y-pBaxCayEupO).(l-n)P2O5-nB2O3 wherein parameters x,y,p,m and n are respectively in the ranges:
0 ? x ? 0.5 0 ? y ? 0.2 0.001 ? p ? 0.15 1.75 ? m ? 2.30 0.05 ? n ? 0.23 BACKGROUND OF THE INVENTION:
The present invention relates to novel bluish green emitting fluorescent materials of alkaline earth metal boron phosphates acti-vated by a divalent europium compound.
In the specification, the fluorescent material means "phosphor"
and the boron phosphate means "borate phosphate".
Heretofore, it has been well ksown that strontium-magnesium phosphate activated with copper (Sr,Hg)3(PO4)2 : Cu and calcium halophosphate activated by antimony Ca10(PO4)6(F,C1)2 : Sb are used as typical fluorescent material emitting in bluish green wavelength region under exciting it by ultraviolet radiation or cathode radiation.

Description

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48,570 However, these known fluorescent materials have dis-advantages to be unsatisfactory from the practical viewpoints.
When the fluorescent material of a phosphate activated by copper is used for a low pressure or high pressure mercury discharge lamp, it is difficult to avoid a trouble of a serious decrease of lumi-nous output because the activator of copper is oxidized by heating (such as 600C) in a baking step (lehring) for the fluorescent material in the preparation of a fluorescent lamp.
The fluorescent material of a halophosphate activated by antimony has wide luminous region so as to emit an emission energy even in near-ultraviolet wavelength region as invisible region.
Accordingly, it is difficult to obtain satisfactory luminous efficiency by using it in a discharge lamp for lightening.

SUMMARY OF THE INVENTION:

It is an object of the present invention to overcome the above-mentioned disadvantages and to provide novel bluish green emitting fluorescent materials which are not inactivated in a baking step for a preparation of a fluorescent lamp and whose luminous efficiency is high.
The foregoing and other objects of the present invention have been attained by providing a novel fluorescent material of an alkaline earth metal boron phosphate activated by a divalen-t europium com-pound having the formula m(Sr1 x y pBaxCayEupO)-(l-n)P205~nB203 wherein parameters x,y,p,m and n are respectively in the ranges:
O _ x ~ 0.5 O ~ y < 0.2 `' `' ?3~
~8,570 0.001 _ p < 0.15 ^ 1.75 _ m < 2.30 ~; 0.05 _ n < 0.23 ,:, DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS:

The fluorescent material of the present invention can be obtained by blending raw materials having suitable element for the for-mula such as CaC03, SrC03, BaC03, CaHPO4, SrHPO4, BaHPO4, H3BO3, Eu2O3 etc, at ratios for forming the formula.
~;~ The mixture is charged in a heat resistant vessel such as a silica crucible, and it is calcined at about 1,000 to 1,200C for suitable time in a reducing atmosphere such as a mixed gas of nitrogen and ` hydrogen.
The raw materials can be compounds of each element which can be converted to the corresponding oxide by a thermal decomposi-tion. That is, hydroxides, nitrates, oxalates of each element can be used as raw materials.
; The phosphate source and the boron oxide source should be used.
As described below, the fluorescent materials of the present invention emits bluish green light under exciting it by ultraviolet rays having short or long wavelength, blue visible radiation or cathode radiation.
The fluorescent material having the formula wherein x = O
and y = O, is strontium boron phosphate having the formula m(Srl_pEupO~ ~l-n)P203. nB203.
This flourescent material emits bluish green light under the emission peak at 480 nm.

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48,570 When barium component is added to the strontium component to be parameter x = about 0.5 as maximum content, the wavelength for the emission peak is shifted to longer wavelength side to be about 490 nm.
When calcium component is added to the strontium component, in said range of y, the emission spectrum is not substantially changed.
The maximum parameters x and y are defined to be 0.5 and 0.2, because the luminous ou-tpu-t is remarkably decreased and blue light having the emission peak at about 410 to 430 nm is emitted if these values are higher.
The blue light has low luminous OlltpUt to be low practical value.
The parameters of m and n in the formula can be selected as desired in said ranges. It is most preferably to be in the ranges of 1.9 _ m _ 2.1 and 0.14 _ n _ 0.18~ since the maximum luminous out-put can be obtained by selecting the parameters of m and n in said ranges.
The europium content as the parameter p is defined in said range, because an absorption of excited radiation is not enough and effec-tive luminous output cannot be obtained when the parameter p is smaller whereas a quantum efficiency is too low to use in a practical purpose when the parameter p is higher.
It is most preferable to be in the range of 0.005 _ p < 0.05 because the fluorescent material having remarkably high luminous output can be obtained.
As described above, the fluorescent material of the present invention can be used for a fluorescent layer in a low pressure or high pressure mercury discharge lamp or a cathode-ray tube.

73i~i - 48,570 It is most preferable to use in a low pressure mercury discharge lamp from the viewpoints of degree of luminous output and position of emission spectrum.
In the preparation of the fluorescent layer for the mercury discharge lamp, the fluorescent material is dispersed in an organic solvent (such as butyl acetate) or water containing a binder for prelimi-nary forming a coated film such as nitrocellulose.
The fluorescent material of the present invention is chemical-ly stable in these solvents without deterioration for a long time.
In the baking process for removing the binder by heating (about 600C), the fluorescent material is highly stable and the luminous efficiency is not substantially decreased.
The luminous efficiency of the strontium-magnesium phos-phate activated by copper as the known fluorescen-t material is usually decreased to about 50 to 80% by the baking process at about 600C where-as that of the fluorescent material of the present invention is only about

2 to 5%.
That is, the fluorescent material of the present invention has substantially no trouble in comparison with those of the known fluores-cent materials.
The most important advantages of the fluorescent ma-terial of the present invention is to be excited by visible blue radiation as well as ultraviolet radiation.
The blue color mercury line spectrum at 405 nm and 436 nm emitted from a mercury discharge lamp does not substantially contri-bute for luminous efficiency because such blue light is quite less sensitive as visible light.
The fluorescent material of the present invention absorbs such blue light to convert it to bluish green light which is highly sen-sitive as visible light.

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4~,570 When the fluorescent material of the present invention is used for the low pressure mercury discharge lamp (fluorescent lamp), the luminous efficiency (lm/W) is at least the same or about 50% higher than that of the calcium halophoshate activated by antimony, because the fluorescent material oE the present invention gives high quantum efEiciency and it is excited even by the blue mercury line spectrum to concentra-te luminous energy in the range of wavelength of about 440 to 570 nm and to emit substantially no energy in short wavelength region shorter than 440 nm.
The fluorescent material of the present invention has said excellent luminous characteristics and various advantageous character-istics and the industrial advantages are significant.
The present invention will be further illustrated by certain examples.

EXAMPLES 1 to 7 and REFEREN~E:

The raw materials were blended at ratios shown in Table 1 to obtain mixtures.
Each mixture was charged in a silica crucible and was fired at the temperature shown in Table 1 in an atmosphere of a mixed gas of nitrogen and hydrogen, for 3 hours.
The volumetric ratio of nitrogen to hydrogen was about 20 : 1 though it can be varied to a desired ratio. The trivalent europium was reduced to the divalent europium.
Each fired product obtained by the firing was quenched and pulverized as sieved to obtain each fluorescent material having the formula shown in Table 1.

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48,570 In the emission spectrum of each fluorescent material, the wavelength for the emission peak is shown in unit of nanometer (nm).
The fluorescent materials emi-t bluish green light having the emission peak at wavelength of about 480 to 490 nm.
A luminous output of each fluorescent material under exciting by ultraviolet radiation having wavelength of 254 nm was measured and compared with a luminous output of the known calcium halophosphate activated by antimony. A luminous output ratio (energy ratio) of each fluorescent material to the known calcium halophosphate activated by antimony as 100 is shown in Table 1.
The luminous output ra-tios of the fluorescent materials of the present invention were higher than lO0.

2~3~i 48,570 .1 ~0 ~ O
p; ~ o _ _ J~ o a~ O O O O O
a ~, 4~ ~ O O O O O
. '~ '~' ~ ~ U~ ~ ~O
~ ~ ~ ~ ~ ~, E~

00 0~ 0~ 0~ ~ ~ C~ ~ C~
~1 ~ ~ ~ O ~ C~l ~ O ~ ~ ~ O ~ ~ ~ ~ O O~ 1- C`l ~ O
'~ ~ ~ O O O ~ O O O ~ O O O ~, O O O O O O O O O
J~ `-E3 O o ~ ~ ~ o ~ ~ ~ o ~ ~ ~ o o ~ ~ ~ o o ~ ~ ~

3 `~ ~ ~ ~ O ~ O~ ~ P l C~ ~ g P~ C~ P~ g lq ~l S l 5~ ~ ~ ) h n~
~i P:; ~ V~ Cq ~ L~ u7 p:~ ~ ~ C~ ~ ~ C~ l u~
~ _ 0~ 0~ 0~ 0 p: ~ P~
C~I O O O oo ~C~ p~c~l U~ ou~
0,~
C~ . . O O
O ~ O C~I CO~i o~

4~ O O O O O
a~ 0~ ~ ~1 ~1 .~ O ~1 ~ ~
~ ~ ~ ~ ~0 ~ ~ ~ C~ Fq p:
o~ ~ ~ ~
O O O O O
~ ~J ~1 ~ ~-i C~J C`l ~ ~`3 , a ~ c~ ~ ~ ~
~ _ ~Zt73~5 P~ _ ~8,570 ~rl O ~ 00 ~ O
C`J ~ O
:q~ _ C) ~ O O O
P ~ ~ ~
o ~ _ ~o o o ., . .,, C_~ ~ ~ l a~ ,, _ ~ ~ oo o ~ c~ ~o o ~
~ ~ U~ ~ o C~ ~ o ,~ ~ o ,_ 's~ ~ ~ o o o o o ~ o o o o o _ a~ ~ ~ O o ~ Cf) ~7 ~ O O O
o ~ ~ o o o o ~ P~ ~ o o o ~-1 ~, ~

.. ~ '~
o ~o ~ o C`l rd C~ P: ~CO
r- S~ ;U
. ~ _ a~
_ W

,, , ~ ~ . ~ '' .

, :', 3~35 48,570 Figure 1 shows emission spectra of -the fluorescent mate-rials of Examples 1,3,5 and 7 under exciting by ultraviolet radiation 254 nm.
As it is clear from Figure 1, the Eluorescent materials of the present invention emit most of the luminous energy in relatively narrow bluish green wavelength region and do not substantially emit the luminous energy in wavelength region shorter than about 440 nm.
In Figure 1, the broken line shows the emission spectrum of calcium halophosphate activa-ted by antimony, and the peaks height of the spectrum is given as 100.
The emission spectra of Examples 2,4 and 6 are not shown in Figure 1 and they are respectively similar to those of Examples 1, 5 and 1.
Figure 2 shows an exci-tation spectrum of the fluorescent material of Example 1. In Figure 2, the relative luminous output ratio is shown as function of wavelength of excited radiation under the consider-a-tion of the maximum luminous output as 100.
As it is clear from Figure 2, the fluorescent material of the invention is satisfactorily excited even by ultraviolet radiation having short wavelength or long wavelength and also by visible blue radiation.
The excitation spectra of the fluorescent materials of Exam-ples 2 to 7 are substantially the same with that of Example 1.
Each straight tube type fluorescent lamp (40W) was prepared by using the fluorescent material of Example 1 and 3 and the known calcium halophosphate activated by antimony and the characteristics of each lamp were tested. The results are shown in Table 2.

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27;385 48,570 ; TABLE 2 Luminous effi- Luminous effi-ciency at zero ciency at 500 Maintenance factor Fluorescent material hour of lighten- hours of light- (%) ing (lm/W) ening (lm/W) A B 100 x (B/A) Example 1 68.2 66.9 98.1 : Example 3 47.0 46.2 98.3 Calcium halo-phosphate activated 45.0 42.4 94.2 with antimony It is clear from Table 2 that the fluorescent lamps using the fluorescent materials of the present invention have excellent superior characteristics on the luminous efficiency and the maintenance factor to those of the reference.
Various fluorescent materials were prepared by varying parameters m,n and p in the formula of Example 1 and the luminous outputs of the fluorescent materials were measured. ~he results are shown in Figures 3,4 and S.

Figure 3 shows a relation of the relative luminous outputs ; to the value m of the fluorescent materials having the formula m(SrO 89Euo 02) o.84P205 0.16B203 (egcited by ultraviolet radiation having wavelength of 254 nm).
It is clear from Figure 3, that effective luminous output is obtained in the range of m = 1.75 to 2.30 especially m = 1.90 to 2.10.
Figure 4 shows a relation of the relative luminous outputs to the value n of the fluorescent materials having the formula (SrO 98Euo 02o) (l-n)p2os nB25 v, , , ~ 3~2~3~5 48,570 It is clear from Figure 4, the specific lumination according to the present invention can be given in a range of n = 0.05 to 0.23, and high luminous outpu-t can be given in a range of n=0.14 to 0.18.
; Figure 5 shows a relation of the relative luminous outputs to the value p of the fluorescent materials having the formula (Srl pEupO) 0.84P205-0.16B203.
It is clear from Figure 5, effective luminous output is obtained in a range of p = 0.001 to 0.15 and especially in a range of p = 0.005 to 0.05.
; In these figures, strontiwn was used as the alkaline earth metal. Thus, it was confirmed that the substantially same tendency is given in the case of barium or calcium when the content is in said range.
As it is clear from these examples and description, the fluore-scent materials of the present invention are alkaline earth boron phos-phates activated by divalent europium compound.
According to various analyses such as X-ray diffraction analysis, chemical elementary analysis and luminous characteristic analysis, it was found that these fluorescent materials are in a form of single compound though a crystalline structure is not clearly found.
In the X ray diffraction analysis, -the fluorescent materials of the present invention impart the specific X-ray diffraction data.
When the parameter m or n of the fluorescent material is out of said range, a different compound is partially formed together with the fluorescent material of the present invention.
That is, in the latter case, the different diffraction fringe which is different from the specific diffraction fringe of the fluorescent material of the present invention is found and the luminous output is lowered, as practical disadvantageous problems.
Figure 6 shows X-ray diffraction spectrum of the fluorescent material of Example 1. - 12 -. ~, ,.
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~8,570 EXAMPLE 8 (Preparation) The fluorescent material of Example 1 was prepared as follows.
SrHP04308.4g (1.68 mole) SrC0341.33g (0.28 mole) H3B0319.74g (0.32 mole) Eu2037.04g (0.02 mole) The raw materials were charged in a ball mill made of alumina, and mixed and pulverized to prepare a mixture. The mixture was charged in a silica crucible and fired at 1140C for 3 hours in an electric furnace in an atmosphere of a mixed gas of nitrogen and hydrogen (volumetric ratio of N:H = 20:1). The fired product was quenched and pulverized and sieved. The resulting fluorescent material emitted bluish green light under exciting it by ultraviolet radiation or cathode radia-tion.
According to a chemical analysis, the result was substantially confirmed with that of the compound 2SrO 98Euo 020Ø84P205 0.16B203.
According to X ray diffraction analysis of the flourescent material, the X ray diffraction spectrum being substantially the same with Figure 6 was ob~ained.

EXAMPLE 9 (Preparation) SrHP04308.4g (1.68 mole) Sr(N03)259.26g (0.28 mole) H3B0319.79g (0.32 mole) Eu2037.04g (0.02 mole) , 7~5 48,570 The raw materials were mixed with 500 cc of water and they were thoroughly stirred and dried on an evaporating dish in a drier heated at 150C. The dried mixture was charged in a silica crucible and fired at 1130C for 2 hours in a mixed gas of nitrogen and hydro-gen (volumetric ratio of N:~l = 20:1) containing 1.5 vol % of steam.
The product was quenched and pulverized and sieved to obtain the fluore-scent material having the same formula with -that of Example 1. The fluorescent material can be used without any treatment.

EXAMPLE 10 (Preparation) The raw materials of Example 8 were charged and mixed in a ball mill. The mixture was charged in a silica crucible and fired at 1000C for 1 hour in air. The product was quenched and pulverized and sieved and then, the product was further fired at 1150C for 1.5 hours in a mixed gas of Example 9 containing 1.5 vol % of steam.
The product was ~uenched and pulverized and sieved to obtain the fluore-scent material of the present invention.
The fluorescent material emitted bright bluish green light under exciting it by ultraviolet radiation or cathode radiation.

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Claims (3)

48,570 WHAT IS CLAIMED IS:

1) An alkaline earth metal boron phosphate fluorescent activated by material divalent europium having the formula m(Sr1-x-y-pBaxCayEupO).(1-n)P2O5.nB2O3 wherein parameters x,y,p,m and n are respectively in the ranges:
0?x?0.5 0?y?0.2 0.001?p? 0.15

1.75?m?2.30 and 0.05?n?0.23.

2) A fluorescent material according to Claim 1 wherein the parameters m and n are in the ranges:
1.9?m?2.1 and 0.14?n?0.18

3) A fluorescent material according to Claim 1 wherein the parameter p is in the range:
0.005?p?0.05.