CA1127379A - Process for the removal of acid gases from a gas mixture - Google Patents
Process for the removal of acid gases from a gas mixtureInfo
- Publication number
- CA1127379A CA1127379A CA321,520A CA321520A CA1127379A CA 1127379 A CA1127379 A CA 1127379A CA 321520 A CA321520 A CA 321520A CA 1127379 A CA1127379 A CA 1127379A
- Authority
- CA
- Canada
- Prior art keywords
- aqueous solution
- mono
- gas
- gas mixture
- removal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000007789 gas Substances 0.000 title claims abstract description 52
- 238000000034 method Methods 0.000 title claims abstract description 18
- 239000000203 mixture Substances 0.000 title claims abstract description 16
- 239000002253 acid Substances 0.000 title claims abstract description 13
- 239000007864 aqueous solution Substances 0.000 claims abstract description 18
- BFSVOASYOCHEOV-UHFFFAOYSA-N 2-diethylaminoethanol Chemical compound CCN(CC)CCO BFSVOASYOCHEOV-UHFFFAOYSA-N 0.000 claims abstract description 10
- 150000001412 amines Chemical class 0.000 claims abstract description 10
- 239000002904 solvent Substances 0.000 claims abstract description 8
- HXJUTPCZVOIRIF-UHFFFAOYSA-N sulfolane Chemical compound O=S1(=O)CCCC1 HXJUTPCZVOIRIF-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 21
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 claims description 20
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 8
- 229910052799 carbon Inorganic materials 0.000 claims description 4
- 125000004432 carbon atom Chemical group C* 0.000 claims description 4
- 239000001569 carbon dioxide Substances 0.000 claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- 239000007833 carbon precursor Substances 0.000 claims description 2
- 229940031098 ethanolamine Drugs 0.000 claims description 2
- 150000003141 primary amines Chemical group 0.000 claims description 2
- 125000000467 secondary amino group Chemical group [H]N([*:1])[*:2] 0.000 claims 1
- 239000002250 absorbent Substances 0.000 description 26
- 230000002745 absorbent Effects 0.000 description 26
- 239000000243 solution Substances 0.000 description 9
- LVTYICIALWPMFW-UHFFFAOYSA-N diisopropanolamine Chemical compound CC(O)CNCC(C)O LVTYICIALWPMFW-UHFFFAOYSA-N 0.000 description 8
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 7
- 238000010521 absorption reaction Methods 0.000 description 6
- 230000008929 regeneration Effects 0.000 description 5
- 238000011069 regeneration method Methods 0.000 description 5
- CRVGTESFCCXCTH-UHFFFAOYSA-N methyl diethanolamine Chemical compound OCCN(C)CCO CRVGTESFCCXCTH-UHFFFAOYSA-N 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 description 2
- 239000003245 coal Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000000356 contaminant Substances 0.000 description 2
- 238000002309 gasification Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000003345 natural gas Substances 0.000 description 2
- 239000002594 sorbent Substances 0.000 description 2
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
- VNMOWKHAHQJUJI-UHFFFAOYSA-N 9-[3-(tert-butylamino)propyl]-8-(2-iodo-5-methoxyphenyl)sulfanylpurin-6-amine Chemical group COC1=CC=C(I)C(SC=2N(C3=NC=NC(N)=C3N=2)CCCNC(C)(C)C)=C1 VNMOWKHAHQJUJI-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical group CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 1
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 1
- IJCVBMSXIPFVLH-UHFFFAOYSA-N [C].S=O Chemical compound [C].S=O IJCVBMSXIPFVLH-UHFFFAOYSA-N 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 description 1
- 150000003335 secondary amines Chemical group 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
- B01D53/1493—Selection of liquid materials for use as absorbents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
- B01D53/1456—Removing acid components
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C7/00—Purification; Separation; Use of additives
- C07C7/11—Purification; Separation; Use of additives by absorption, i.e. purification or separation of gaseous hydrocarbons with the aid of liquids
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
- Y02C20/00—Capture or disposal of greenhouse gases
- Y02C20/40—Capture or disposal of greenhouse gases of CO2
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/151—Reduction of greenhouse gas [GHG] emissions, e.g. CO2
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Analytical Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Water Supply & Treatment (AREA)
- Gas Separation By Absorption (AREA)
- Treating Waste Gases (AREA)
- Industrial Gases (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NL7803075 | 1978-03-22 | ||
| NLAANVRAGE7803075,A NL190316C (nl) | 1978-03-22 | 1978-03-22 | Werkwijze voor het verwijderen van zure gassen uit een gasmengsel. |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1127379A true CA1127379A (en) | 1982-07-13 |
Family
ID=19830538
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA321,520A Expired CA1127379A (en) | 1978-03-22 | 1979-02-14 | Process for the removal of acid gases from a gas mixture |
Country Status (11)
Families Citing this family (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4405585A (en) | 1982-01-18 | 1983-09-20 | Exxon Research And Engineering Co. | Process for the selective removal of hydrogen sulfide from gaseous mixtures with severely sterically hindered secondary aminoether alcohols |
| US4405580A (en) | 1982-01-18 | 1983-09-20 | Exxon Research And Engineering Co. | Process for selective removal of H2 S from mixtures containing H22 with tertiary amino azabicyclic alcohols |
| US4508692A (en) * | 1982-01-18 | 1985-04-02 | Exxon Research & Engineering Co. | Process for the selective removal of hydrogen sulfide from gaseous mixtures with strongly basic tertiary amino compounds |
| US4417075A (en) * | 1982-01-18 | 1983-11-22 | Exxon Research And Engineering Co. | Di-(Secondary and tertiaryalkylaminoalkoxy)alkanes |
| US4405582A (en) * | 1982-01-18 | 1983-09-20 | Exxon Research And Engineering Co. | Process for selective removal of H2 S from mixtures containing H22 using diaminoether solutions |
| US4483833A (en) * | 1982-01-18 | 1984-11-20 | Exxon Research & Engineering Co. | Process for selective removal of H2 S from mixtures containing H22 with heterocyclic tertiary aminoalkanols |
| US4405811A (en) * | 1982-01-18 | 1983-09-20 | Exxon Research And Engineering Co. | Severely sterically hindered tertiary amino compounds |
| US4405581A (en) | 1982-01-18 | 1983-09-20 | Exxon Research And Engineering Co. | Process for the selective removal of hydrogen sulfide from gaseous mixtures with severely sterically hindered secondary amino compounds |
| US4405583A (en) | 1982-01-18 | 1983-09-20 | Exxon Research And Engineering Co. | Process for selective removal of H2 S from mixtures containing H22 using di-severely sterically hindered secondary aminoethers |
| US4471138A (en) * | 1982-01-18 | 1984-09-11 | Exxon Research And Engineering Co. | Severely sterically hindered secondary aminoether alcohols |
| US4892674A (en) * | 1987-10-13 | 1990-01-09 | Exxon Research And Engineering Company | Addition of severely-hindered amine salts and/or aminoacids to non-hindered amine solutions for the absorption of H2 S |
| US4895670A (en) * | 1987-10-13 | 1990-01-23 | Exxon Research And Engineering Company | Addition of severely-hindered aminoacids to severely-hindered amines for the absorption of H2 S |
| US4894179A (en) * | 1987-10-13 | 1990-01-16 | Exxon Research And Engineering Company | Absorbent composition containing a tertiary amino azabicyclic alcohol and an amine salt |
| US4894178A (en) * | 1987-10-13 | 1990-01-16 | Exxon Research And Engineering Company | Absorbent composition containing severely-hindered amine mixture for the absorption of H2 S |
| EP0672446B1 (en) * | 1994-03-18 | 2002-11-13 | The Kansai Electric Power Co., Inc. | Method for the removal of hydrogen sulfide present in gases |
| CN100379485C (zh) | 2002-01-14 | 2008-04-09 | 国际壳牌研究有限公司 | 从气体混合物中除去二氧化碳的方法 |
| US7524990B2 (en) | 2004-02-17 | 2009-04-28 | Exxonmobil Research And Engineering Company | Synthesis of sterically hindered secondary aminoether alcohols |
| EP1718598B1 (en) | 2004-02-17 | 2013-10-02 | ExxonMobil Research and Engineering Company | Synthesis of sterically hindered secondary aminoether alcohols from acid anhydride and/or acid halide and sulfur trioxide |
| WO2005082836A1 (en) | 2004-02-17 | 2005-09-09 | Exxonmobil Research And Engineering Company | Synthesis of severely sterically hindered secondary aminoether alcohols from a ketene and/or carboxylic acid halide and/or carboxylic acid anhydride |
| EP1716096B1 (en) | 2004-02-17 | 2012-05-02 | ExxonMobil Research and Engineering Company | Synthesis of sterically hindered secondary aminoether alcohols |
| US8480795B2 (en) | 2005-08-09 | 2013-07-09 | Exxonmobil Research And Engineering Company | Absorbent composition containing molecules with a hindered amine and a metal sulfonate, phosphonate or carboxylate structure for acid gas scrubbing process |
| JP5061108B2 (ja) | 2005-08-09 | 2012-10-31 | エクソンモービル リサーチ アンド エンジニアリング カンパニー | 酸性ガススクラビング法のためのポリアルキレンアクリルアミド塩 |
| CN101300223B (zh) | 2005-08-09 | 2013-07-03 | 埃克森美孚研究工程公司 | 用于酸气涤气工艺的烷基氨基烷氧基（醇）单烷基醚 |
| EP1922135B1 (en) | 2005-08-09 | 2011-01-19 | ExxonMobil Research and Engineering Company | Hindered cyclic polyamines and their salts for acid gas scrubbing process |
| ES2368762T3 (es) | 2007-01-30 | 2011-11-22 | Mt-Biomethan Gmbh | Procedimiento e instalación para el tratamiento de gases brutos con contenido de metano y dióxido de carbono, concretamente biogás, para la obtención de metano. |
| US9458367B2 (en) | 2012-03-14 | 2016-10-04 | Exxonmobil Research And Engineering Company | Low temperature transport and storage of amine gas treatment solutions |
| WO2015031484A1 (en) | 2013-08-29 | 2015-03-05 | Dow Global Technologies Llc | Gas sweetening solvents containing quaternary ammonium salts |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR685992A (fr) * | 1930-10-07 | 1930-07-21 | Girdler Corp | Perfectionnements à la séparation des gaz entre eux |
| GB1058304A (en) * | 1964-03-12 | 1967-02-08 | Shell Int Research | Process for the purification of fluids |
| GB1102943A (en) * | 1965-04-05 | 1968-02-14 | Allied Chem | Separation of acidic gas constituents from gaseous mixtures containing the same |
| US3598881A (en) * | 1968-10-17 | 1971-08-10 | Lummus Co | Process for removing acid gases from cracked gases containing diolefins |
| NL7109521A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1970-07-13 | 1972-01-17 | ||
| JPS472861A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1971-07-09 | 1972-02-12 | ||
| SE424815B (sv) * | 1975-10-30 | 1982-08-16 | Union Carbide Corp | Forfarande for kontinuerlig selektiv absorption av svavelvete fran ett gasramaterial |
-
1978
- 1978-03-22 NL NLAANVRAGE7803075,A patent/NL190316C/xx not_active IP Right Cessation
-
1979
- 1979-02-14 CA CA321,520A patent/CA1127379A/en not_active Expired
- 1979-03-13 BE BE1/9308A patent/BE874786A/xx not_active IP Right Cessation
- 1979-03-20 BR BR7901719A patent/BR7901719A/pt unknown
- 1979-03-20 AU AU45261/79A patent/AU524870B2/en not_active Ceased
- 1979-03-20 FR FR7906959A patent/FR2422432A1/fr active Granted
- 1979-03-20 DE DE19792910940 patent/DE2910940A1/de active Granted
- 1979-03-20 JP JP3185679A patent/JPS54131570A/ja active Pending
- 1979-03-20 ZA ZA791327A patent/ZA791327B/xx unknown
- 1979-03-20 GB GB7909712A patent/GB2017524B/en not_active Expired
-
1985
- 1985-12-30 MY MY915/85A patent/MY8500915A/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| MY8500915A (en) | 1985-12-31 |
| JPS54131570A (en) | 1979-10-12 |
| GB2017524A (en) | 1979-10-10 |
| AU4526179A (en) | 1979-09-27 |
| BR7901719A (pt) | 1979-10-16 |
| NL190316C (nl) | 1994-01-17 |
| FR2422432B1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1983-06-10 |
| DE2910940C2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1987-08-06 |
| NL7803075A (nl) | 1979-09-25 |
| FR2422432A1 (fr) | 1979-11-09 |
| AU524870B2 (en) | 1982-10-07 |
| NL190316B (nl) | 1993-08-16 |
| ZA791327B (en) | 1980-03-26 |
| GB2017524B (en) | 1982-09-15 |
| BE874786A (nl) | 1979-09-13 |
| DE2910940A1 (de) | 1979-10-11 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKEX | Expiry |