CA1126692A - Non-sacrificial anode and water heater construction - Google Patents

Non-sacrificial anode and water heater construction

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Publication number
CA1126692A
CA1126692A CA379,185A CA379185A CA1126692A CA 1126692 A CA1126692 A CA 1126692A CA 379185 A CA379185 A CA 379185A CA 1126692 A CA1126692 A CA 1126692A
Authority
CA
Canada
Prior art keywords
tank
interior
anode
improvement
electrically conductive
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
CA379,185A
Other languages
French (fr)
Inventor
Michio B. Nozaki
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Rheem International Inc
Original Assignee
Rheem International Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US05/839,006 external-priority patent/US4136001A/en
Application filed by Rheem International Inc filed Critical Rheem International Inc
Priority to CA379,185A priority Critical patent/CA1126692A/en
Application granted granted Critical
Publication of CA1126692A publication Critical patent/CA1126692A/en
Expired legal-status Critical Current

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Abstract

ABSTRACT OF THE DISCLOSURE
Non-sacrificial anode for use in a hot water heater has a single elongated electrically conductive wire extending within the interior of the water heater tank. Anode distribution points made of platinum coated tantalum are attached to the conductive wire at preselected locations. A catalyst of the type which permits hydrogen gas and oxygen gas at standard temperatures and pressures to form water molecules is suspended from the tank's interior.

Description

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This is a divisional of co-pendillg Canadian Patent application serial No. 301,747, filed April 21, 1978 in the name Theem International, Inc.
This invention relates generally to an improved construction for hot water heaters. These water heaters typically include a storage tank formed as an upright cylinder from steel or ferric metal plate and an anode used to protect the tank from galvanic corrosion. This invention pertains more specifically to a non-sacrificial anode for use in water heater construction which will protect the tank for effectively, efficiently and safely than prior non-sacrificial anodes.
Non-sacrificial anodes generally include one or more elongated fila-ments of electrically conductive metal impressed with a small electrically positive potential so as to produce direct current from the anode to the metal tank. The current counteracts the corrosive activity of the water and dissolved oxygen to protect the metal tank and fixtures from galvanic corrosion. The voltage of the impressed current is dependent upon, among other things, the quality and characteristics of the lining, the electrical conductivity of the water within the tank, and the configuration of the anode in relation to the tank walls and other metal elements.
Non-sacrificial anodes are deficient in at least two significant aspects. Since the protective current follows the path of least resistance, it will frequently flow directly from the anode to a nearby metal projection, such as the heating elements, leaving the tank walls and remaining fixtures unpro-tected. It is known to compensate for this limitation by utilizing a higher voltage so that the protective current is applied to all areas of the tank walls and fixtures notwithstanding a relatively greater current drain in some loca-lized area. However, the materials, methods of construction and operating conditions commonly associated with anode and tank are expensive and inherently 1~2~;69~

limited so as to make operation of the tank and non-sacrificial anode system dangerous, especially in certain conditions. The higher voltages associated with certain systems increase the danger.
Expense is related to materials and methods of construction. One conventional type of anode includes a filament of titanium coated with platinum.
Use of this type is limited to low voltage systems because the platinum/titanium interfaces break down at voltages above 13 volts. The construction of this type anode generally includes installing the anode as a plurality of short discreet filaments interspaced within the tank in order to avoid proximity between the anode and metal projections within the tank; this requires more materials and labor than single filament systems.
Single filament non-sacrificial anodes are high voltage types of con-ventional anodes and generally use a tantalum wire coated with platinum as the platinum/tantalum interface will withstand 85 to 100 volts. However, tantalum is more expensive than titanium and the higher voltage increases the dangers associated with non-sacrificial anodes.
The danger associated with non-sacrificial anodes results from an accumulation of hydrogen and oxygen gas generated through the electrolysis of water by the protective current flowing from the anode to the tank and fixtures.
The presence of hydrogen and oxygen gas in an enclosed space creates a very real threat of explosion. In normal operating conditions much of the hydrogen and oxygen gases are dissolved in the water flowing through and out of the tank.
But when the heater stands idle, as when a homeowner goes on vacation, the static conditions in the tank produce a serious explosion hazard - so serious tha~ no hot water heater, now commercially available and known to this appli-cant, has received the safety approval of either governmental or non-governmental consumer safety organizations. It can also be seen that the rate of accumulation of the gases clepends primarily upon the magnitude of the protective current.
Thus the larger the protective current, the more dangerous the explosion poten-tial.
It is an ohject of the present invention to provide a hot water heater and non-sacrificial anode which provides a protective current over the entire interior surface exposed to water. It is a further object of the inven-tion to provide a hot water heater and single filament platinum coated non-sacrificial anode which has a long life even when operating at voltage levels sufficient to protect the entire interior surface of the tank.
One further object of the invention is to provide a hot water heater and non-sacrificial anode having a more economic construction than conventional hot water heaters and non-sacrificial anodes.
Still another object of the invention is to provide a hot water heater and non-sacrificial anode having a safer and more economic operation than conven-tional hot water heaters and non-sacrificial anodes.
; According to a broad aspect of the present invention, there is provided in a hot water heater including a substantially hollow metal tank having at least one opening and an interior surface defining an interior therein, said - tank being formed at least in part of a galvanically active material, said ~O interior surface being substantially lined with an electrically non-conductive galvanically inert material, and a heating element, the improvement comprising:
a single elongated wire made of an electrically conductive material, said wire projecting within said interior and being connected to an external source of electricity, and a plurality of electrically conductive, chemically stable, gal-vanically inert, water insoluble, non-toxic, discrete anode distribution members connected to said electrically conductive material at preselected locations, said anode members cooperating with said tank to define means for directing a protective positive electrical current from within said interior to said intcrior surface.
In a preferred embodiment, the non-sacrificial anode further includes a catalyst element of the type which permits hydrogen gas and oxygen gas at standard atmospheric temperatures and pressures to form water molecules. The catalyst, which is disposed at the top of the tank, is chemically stable, inert, substantially water insoluble non-toxic and harmless in contact with food stuffs.
The invention andthatofcopending application serial No. 301,747 will now be described in greater detail with reference to the accompanying drawings, in which:
Figure 1 is a cross-sectional view of a hot water heater showing the preferred form of the improved non-sacrificial anode assembly described herein;
Figure 2 is a cross-sectional view of the non-sacrificial anode assem-bly described herein;
Figure 3 is a perspective view of a portion of the non-sacrificial anode assembly;
Figure 4 is a cross-sectional view of the non-sacrificial anode assembly at line 4-4 of Figure 2;
Figure 5 is a cross-sectional view of a first alternative embodiment of the catalyst and sacrificial anode assembly described herein; and Figure 6 is a cross-sectional view of a second alternative embodiment of the catalyst and sacrificial anode assembly described herein.
Referring to the figures, the hot water heater assembly, generally 10, includes an outer casing 12 and a tank 14. The outer casing 12 may be made of metal, ceramic coated metal or plastic, using conventional construction techniques so as to form a shell over the tank 14. The tank 14 is shaped as a cylindrical tube and is formed at least in part from a galvanically active metal 112~ Z

using convelltional construction techlliques. The casing 12 and tank 14 preferably have a drain valve opening ]6 near the lower portion of the tank 14 through which a drain valve 18 is affixed. The valve 18 generally has a handle 20 so that any water in the tank 14 can be manually drained. The tank interior 22 is enclosed by a top 24 having a filler pipe opening 26 advantageously positioned near the center thereof. A fixture 28 and filler pipe 30 are affixed to the tank 14 within the opening 26 so that water can be introduced into the tank 14.
A first and second heating element 32, 34 of substantially conventional construc-tion are also affixed to the tank 14 and project within interior 22.
As shown in Figure 2, the novel non-sacrificial anode 40 of this inven-tion is a single elongated wire 42 attached preferably to the top 24. The wire 42 projects within interior 22, generally extending from the top 24 towards the lower interior of the tank 14 The wire 42 also extends out of the heater assembly 10 for connection with an external source of positive direct current potential. A second post 44 projects from the anode 40 and is attached to a second wire 46 forming an electrical ground, As best shown in Figure 2, wire 42 preferably includes an electrically conductive core 50 and an electrically non-conductive, water impermeable covering 52. The material used to make core 50 is advantageously titanium. Tantalum or other electrically conductive materials which form electrically non-conductive, protective films in contact with water may be used. The covering 52 is preferably a conventional plastic material such as polyvinylchloride. The covering should be chemically stable, galvanically inert, substantially water insoluble, non-toxic and harmless when in contact with food stufs. The covering 52 preferably acts to protect the core material 50 particularly during the initial usage or break-in period of the hot water heater assembly 10.

1~2~ %

A plurality of anode distribution points 54 are attached to wire 42, generally by spot welding the anode distribution point directly to the core material 50 The covering 52 is generally removed from the point of attachment prior to welding. As shown in Figure 4, the anode distribution point includes a flat, rectangular shaped base member 56 covered with a thin coating 58 and spot welded to core 50 at location 60. The base member 56 is preferably made of tantalum or other electrically conductive material which forms an interface with the coating metal capable of withstanding relatively high voltages. The coating 58 is preferably platinum, but may also be any other electrically conductive material which is chemically stable, galvanically inert and which does not form an electrically non-conductive film in contact with water.
The elongated wire 42 preferably extends away from top 24 towards a lower central portion of interior 22. The anode distribution points 54 are generally located at pre-selected locations so that the sum of the electrical resistances between any given localized area of tank 14 and the plurality of anode distribution points 54 is substantially constant. That is, the anode distribution points 54 are located at positions which are spaced substantially equally between the heating elements 32,34 of the tank 14 and any other conduc-tive projections within interior 22. The protective current distribution from the points 54 are directed to each localized area of the tank 14 as well as to conductive projections such as heating elements 32,34. It is known through measurements with a calomel reference cell that the requisite d.c. potential ; of the protective current at the protective coating surface must be at least ~0.78 volts with respect to the tank. Applicant has found that the single fila-ment non-sacrificial anode of this invention will provide a protective current having the requisite potential at the coating or interior surface 62 while operating with a total current in the range of 8 to 40 milliampcres, preferably llZ6~9Z

8 to 16 milliamperes and a total voltage potential from about 1 to about 85 volts, preferably about 20 volts, depending upon the design of the water heater, the anode points, the resistivity of the water, and the placement of the anode distribution points.
A porous basket 70 suspended within interior 22 from the top 24 con-tains a catalyst 72 of the type which permits hydrogen gas and oxygen gas at standard atmospheric temperatures and pressures to form water molecules. The porous basket is preferably made of a water insoluble, non-corrosive, solid material. The catalyst should be chemically stable, inert, substantially water insoluble, non-toxic and harmless in contact with food stuffs. The catalyst is preferably a mixture of pulverized palladium or platinum and alumina or carbon.
The carbon is advantageously activated carbon. The basket 70 is suspended by attaching it to a steel cap 74 having a threaded surface which screws into the top 24. Wire 42 is projected through the center of steel cap 74 and basket 70 into interior 22. A plastic insert 76 and a rubber seal 78 are generally fitted within steel cap 74 to position and electrically insulate wire 42 with respect to steel cap 74 and basket 70. An insulating paper 80 is positioned around the wire 44 between steel cap 74 and the top 24.
The lower voltage requirements of this novel non-sacrificial anode produce a lower build-up of hydrogen and oxygen gas than conventional non-sacrificial anodes. The catalyst further inhibits the build-up of hydrogen and oxygen gas, thus further increasing the safety factor of this non-sacrificial anode and hot water heater design.
Figures 5 and 6 show alternative configurations for the arrangement of catalyst 72. Figure 5 shows the catalyst as cylindrical pellets with a central passageway. The pellets are strung on the elongated wire 42 near the steel cap 74. Figure 6 shows how the catalyst could be made in flat, planar 6~Z

memhers and mounted on wire 42 near the steel cap 74. The consideration for choosillg the configuration of thc catalyst include active surface area of the catalyst and diffusion paths for the oxygen and hydrogen gas as well as other characteristics conventionally known in the art.
The above description relates to a preferred embodiment of the invention. The preferred configuration is described and illustrated in the drawing. However, alternative configurations and modifications are possible within the scope of the invention. For example, the number of the distribution anode points 54 may be changed; the configuration of wire 42 may be altered although the wire may be retained as a single filament, The materials used in making the wire and the anode distribution points may be varied. The location of the catalyst may be isolated from the location of the wire 42; and the materials used to make the catalyst may be changed. Therefore, the subject matter of the invention is limited only by the following claims and their e~ui-valents.

Claims (8)

THE EMBODIMENTS OF THE INVENTION IN WHICH AN EXCLUSIVE
PROPERTY OR PRIVILEGE IS CLAIMED ARE DEFINED AS FOLLOWS:
1. In a hot water heater including a substantially hollow metal tank having at least one opening and an interior surface defining an interior therein, said tank being formed at least in part of a galvanically active material, said interior surface being substantially lined with an electrically non-conductive galvanically inert material, and a heating element, the improvement comprising:
a single elongated wire made of an electrically conductive material, said wire projecting within said interior and being connected to an external source of electricity, and a plurality of electrically conductive, chemically stable, galvanically inert, water insoluble, non-toxic, discrete anode distribution members connected to said electrically conductive material at preselected loca-tions, said anode members cooperating with said tank to define means for directing a protective positive electrical current from within said interior to said interior surface.
2. The improvement of claim 1 wherein said interior further comprises a plurality of localized areas, said preselected locations being positioned so that the sum of the electrical resistances between said plurality of anode points and said localized areas is substantially constant.
3. The improvement of claim 1 wherein said electrically conductive material is a metal selected from the group consisting of titanium and tantalum.
4. The improvement of claim 1 wherein said anode members comprise plati-num coated tantalum members.
5. The improvement of claim 1 wherein said anode members provide a protec-tive current from about 8 to about 40 milliamps at about 1 to about 85 volts.
6. The improvement of claim 1 wherein said anode members provide an electric current from about 8 volts to about 16 milliamps at about 20 volts.
7. The improvement of claim 1 wherein said wire further includes an electrically non-conductive water impermeable coating.
8. The improvement of claim 1 wherein said interior surface further comprises a plurality of localized areas in contact with water, said protective current being directed from within said interior to each said localized area and said protective current having a positive potential of at least 0.78 volts with respect to said tank surface at said localized area.
CA379,185A 1977-10-03 1981-06-05 Non-sacrificial anode and water heater construction Expired CA1126692A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CA379,185A CA1126692A (en) 1977-10-03 1981-06-05 Non-sacrificial anode and water heater construction

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US05/839,006 US4136001A (en) 1977-10-03 1977-10-03 Non-sacrificial anode and water heater construction
US839,006 1977-10-03
CA301,747A CA1103200A (en) 1977-10-03 1978-04-21 Non-sacrificial anode and water heater construction
CA379,185A CA1126692A (en) 1977-10-03 1981-06-05 Non-sacrificial anode and water heater construction

Publications (1)

Publication Number Publication Date
CA1126692A true CA1126692A (en) 1982-06-29

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
CA379,185A Expired CA1126692A (en) 1977-10-03 1981-06-05 Non-sacrificial anode and water heater construction

Country Status (1)

Country Link
CA (1) CA1126692A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112813435A (en) * 2021-01-07 2021-05-18 北京市第一0一中学 Sacrificial anode structure for high-insulation water heater

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112813435A (en) * 2021-01-07 2021-05-18 北京市第一0一中学 Sacrificial anode structure for high-insulation water heater

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