CA1121960A - Method and apparatus for making stress free plastic article - Google Patents

Abstract

ABSTRACT Disclosed is a method and apparatus for making stress free plastic articles from plastic particles such as powder utilizing heat and pressure in which a quantity of plastic particles is supplied to a first member, a flexible diaphragm is disposed in opposed relationship to said first member with said plastic particles therebetween, a microporous air release means is positioned between said plastic particles and said flexible diaphragm, a fluid-like pressure is applied to said diaphragm to cause said diaphragm to apply an even fluid-like pressure through said air release means to said plastic particles, heat is applied to said plastic particles while under said fluid-like pressure and any entrapped gases between the particles is vented by means of the air release means. The pressure and heat are controlled to effect a consolidation of the plastic particles into the article. A second diaphragm may be used on the opposite side of said first diaphragm and either one or both of said diaphragms may be a sealed envelope to which fluid pressure is applied. The plastic article produced by the method is substantially free of all stresses.

Description

STRESS FF~E.~` PLASTIC AP~TICLE, ~IETHOD O~ KI~G
T~IE SA~I~ AMD APPAP~T~S FOR PERFORMING SAID METHOD
TO MA~E SAID ~TICLE

_ ELD OF THE INVEMTION

This invention belongs to the field of forming plastic zrticles including sheets from plastic particles and to welding the same under heat and pressure also utilizing plastic powders. Previous known methods of forming plastic articles including sheets from plastic particles have experienced a variety of difficulties.
Many plastics are difficult or impossible to mold into articles or to form into sheets, particularly, thin sheets called films. Also, it is difficult to weld many plastic sheets by conventional electronic heating or other "thermowelding" techniques without having the joint exhibit a thickness greater than the thickness of the sheet. Further, such techniques for welding have generally been applicable only to certain rela-tively thin materials such as films. For example, the homopolymer chlorotrifluoroethylene may be thermo-welded only in very thin thicknesses. In such con-ventional welding techniques the resulting joints frequently exhibit varying strengths and degradation of the plastic along the weld due to excessive or unequal heating, or unequal pressure. Still further, such conventional welding techniques frequently result - in holes through ~he material at or adjacent the weld either during formation or subsequently during use which phenomenon is sometimes referred to as "holing through". When the sheet material to be welded has .., ~ ....

, -_ --2--variable thicknesses these difficulties in conven-tional welding techniques are compounded even when the thickness variation is slight. Nor do the conven-tional welding systems produce a weld over the entire width of the overlappecl edges. As a result, the unwelded portions of the edges are subject to movemen~
in use by wind or other air currents which deteriorate the weld, often to the point where the weld separates.
Previous efforts to overcome these problems with conventional welding by using wider welded areas (more overlap) greatly reduces the speed of joining which lS detrimental commercially.

~ luch of what has been said above with respect to welding also applies to the forming of shaped articles including sheets from plastic particles. Still further, when forming plastic articles or sheets from plastic particles by the use of conventional methods the articles or sheets produced have stresses or strains built into them by the method of formation except in those instances where the plastic being used is a monomer or a liquid-like material or are rormed by solvent or casting methods such as those methods using organosols or plastisols for the production of the article or the sheet. Solvent methods of forma-tion are expensive, generally slow, and are not applicable to a great many plastic resins. Polymers having millions molecular weight, for example, have proven very difficult to form into articles or sheets by many conventional techniques and, indeed, it is practically impossible to produce large thin sheets from such millions molecular weight polymers directly from the plastic particles. While certain plastics have been formed into articles, particularly sheets, that are nearly stress or strain free by the solvent _ -3-1 or liquid phase methods mentioned above, such products have not been widely used with solid polymers except with polymers such as polyvinyl chloride. Still further, such stress or strain free products (herein-after referred to as "stress free" products) have notheretofore been produced from polymers having millions molecular weight. In an effort to produce stress free plastic articles including sheets, attempts have heretofore been made to release the stresses built into the product during its formation by certain expensive after-treatments such as heating the product to a temperature suitable to relieve the stresses therein. Generally this involves heating the product to near and sometimes into the melt phase for extended periods. Such treatments (especially if the product is not restrained during treatment) can induce dimensional changes in the product which render it useless. The present invention eliminates stress as a problem. Prior to the present invention the best quality of sheet (including film) plastics produced from pelletized or ground plastic powder has been made by the compression method; however, due to its large capital investment and costly operation such sheets produced by such compression method have priced themselves out of the market place except for very special applications. In the compression method the pressures required may reach many thousands of pounds per square inch with the recommended pressures for polystyrene homopolymer sheets, for example, being from l,000 to lO,000 p.s.i. (70.3 - 703 kg/cm2) and those for acrylics being on the order of 2,000 -5,000 p.s.i. ~140 - 352 kg/cm2).

~1 2 ~30 I~ is known from U.S. patent no. 3,383,265 ~hat two plastic sheets can be welded together by placing them in a chamber having at least one flexible wall and heating with inrared or other heat while the flexible wall is pressed against the joint until it melts into the weld. Such process and method are, howevez, not disclosed as being useful for forming products from 0 particulate material, much less stress free products.

DISCLOSURE OF T~E INVENTION

The present invention proposes to overcome the defi-ciencies of the prior art by producing plastic arti-cles which are stress free directly from plastic particles by supporting said particles upon a suitable support such as a mold or platen, heating the plastic particles while applying to said plastic particles fluid pressure including applying said fluid pressure substantially uniformly to said supported plastic particles while the same are heated to a temperature sufficient to cause said particles to melt and form said article, and venting any air or gasses contained in the plastic powders du{ing said heating and pres-sing. The apparatus for performing the method util-izes a flexible rnember which may be a diaphragm alone or a diaphragm that is one face of a closed envelope.
The apparatus also includes an air release means which is, preferably, in two parts although a single element air release means is also contemplated. When the air release means is of two parts, one is a wire cloth or screen and the other is a microporous parting sheet.
The microporous parting sheet may advantayeously be 1~ ~5~

comprised of a fiberglass fabric coated with poly-tetrafluroethylene, thus providing a sheet with a myriad of minute openings therethrough.

In using the apparatus of this invention in carrying out the method to produce stress free articles such as sheets, the pressures required are often as low as 50 p.s.i. (3.52 kg/cm2) and less including use of only that force generated by the differential between atmospheric pressure and a readily obtainable partial vacuum.

The articles including sheets produced by this inven-tion are stress free and degradation is greatly reduced or eliminated. The articles may be made of such diverse plastics as polyethylene, polyvinyl chloride, polystyrene, polypropylene~ the acrylics, and others, including, particularly, polymers of millions molecular weight such as millions molecular weight polyethylene, which are otherwise very dif-ficult to process. Dissimilar plastics even such widely dissimilar materials such as the polystyrenes and polyvinyl chlorides may be superimposed in one or more layers and produced as one solid sheet.

Still further, the product produced by this invention exhibits the characteristics on its surface of the mold or platen support. In one specific example the product is produced having a mirror surface of extremely high quality which exhibits high smooth-ness or polish comparable to that of polished glass by having been formed on a platen having a surface with an extreme polish. Such a surface may be glass or highly polished metal and may, if desired, have :3'12196~
__ -6-1 ?atterns _ngraved or otherwise produced therein for reproduction in the final plastic article.

In carrying out the ~ethod to produce such a sheet suitable for use as a mirror the plastic material in comminuted state is disposed on a suitable mold or platen in a layer of desired thickness. Over this layer of comminuted plastic particles or powder is placed the above-mentioned microporous parting sheet and over this is placed the wire screen. The plastic is then heated to at least its fusion or melt temp-erature and while so heated there is applied across the gas release means (comprised of the microporous parting sheet and the wire screen) a fluid-like pressure sufficient to cause the plastic material to fuse to a coherent sheet. The fluid pressure applied to this sandwich may be exerted through a flexible diaphragm or by means of two separate diaphragms one of which is placed beneath the platen and the other of which is placed above the wire screen. Fluid pressure is then applied to the diaphragm to cause the same to press evenly in a fluid like manner over the entire surface of the layer of plastic particles.

The diapnragm may be either a single flexible member placed against one or both sides of the sandwich (comprising the mixture, plastic particles, micro-porous parting sheet, and wire screen) or the dia~
phragm may be one face of a sealed envelope in which case either a single envelope pressing-against the air release means or a pair of opposed sealed envelopes (with the sandwich therebetween) may be utilized.

The pressure may be either liquid such as water or hydraulic fluid under pressure or gas such as ~Z196~
-7- !

1 air or ar inert gas under pressure. In either event, the fluic pressure may be applied to the outer sur-faces o~ tne diaphragm or diaphragms which tr2nsmits the same ~o the plastic particles. Alternatively, and particularly when two diaphragms are used which are not the taces of sealed envelopes, the periphery of the dia~hragms may be sealed together and the air between ~he two evacuated whereby the pressure is ambient Dressure and the amount thereof is determined by the aifferential between ambient pressure and the degree o vacuum applied between the peripherally sealed diaphragms. ~hen one or two envelopes are used, the fluid pressure is applied by placing the fluid within the envelope under pressure which pres-sure the flexible diaphragm face of the envelope transmits fluidly to the plastic articles.

During the step of applying fluid pressure (by any of the ~escribed mechanisms or methods) to the heated plastic material, all areas of the plastics material are cont~cted with a pressure that is even and sub-stantially uniform throughout. Any gas (including air or mois~ure) present in the plastics material is exhauste~ under the heat and pressure and the same is vented by means of the air release means comprised of the wire cloth or screen and the microporous parting sheet. It should also be noted that a porous or multiperforated thin flexible metal sheet may be used in place of the wire screen. Alternatively, a polytetr~fluoroethylene (PTFE) coated wire screen or minutely perforated or porous flexible metal sheets coated with PTFE may be used to replace both the wire screen and the microporous parting sheet.

As the plastics material melts and consolidates, the 8- !

1 significant movement is that towards solidification .hus avoiding the gross lateral flow that in other ?rocesses causes the introduction of various stresses into the product upon cooling. If the sheet is produced on a glass plate master the fluid pressures applied are so even that the product is produced without any damage or breakage occurring to the glass master. The glass master is preferably tempered or heat resistant glass.

When producing a mirror, as one specific embodiment, there is then applied to that face of the finished sheet which exhibits the polish of the master (i.e.
that face which was against the master) a layer of reflective metal. The reflective metal may be sprayed silver and in order to protect the same there is applied thereover a transparent abrasion resistant coating. This abrasion resistent coating may advan-tageously be a solution of glass resin polymer applied evenly over the metal layer which resin is then cured by means of radiant heat. In one specific example the plastic sheet may be a polystyrene homo-polymer of ap2roximately .09" (2.29mm) in thickness with a layer of silver sprayed onto its polished surface and the silver layer coated with a film of 40%
glass resin and 5% catalyst in solution in butanol.
.

When welding sheets of plastics together previous disadvantages mentioned above including "holing through" are eliminated while producing a weld with little or no thickness variation being apparent in the final product not even in the weld and also having a mirror or other smooth surface as desired. Further, the invention permits the welding of dissimilar plastics, even those as diverse as polyethylene and 9~0 g 1 polyvinyl chloride.

~nen the invention is used to join two sheets or pieces of plastic material, they may be placed in juxtaposed edge to edge relationship or in overlapped relationship with powdered plastic between the meeting or overlapped edges. A fluid-like pressure is then applied to the joint while heating the same into or close to the melting temperature. As in the case of producing an article, the fluid pressure is applied by either one diaphragm or by two opposed diaphragms either or both of which may be one face of a sealed envelope. Under the applied heat and pressure the weld is formed and the particles lose their discreet identities and assume the ultimate desired shape.

Where the materials to be joined are different plastic polymers the use of correspondingly different plastic powders has been found particularly advantageous. For e~ample, different plastic powders have been used in which the plastic of one powder corresponds to the plastic of one of said polymers and the plastic of the other powder corresponds to the plastic of the other of said polymers. At the joint or junction between the two materials the plastic powders may advan-tageously be arranged in a graded manner. That is tosay that the powder adjacent the first of said mater-ials is comprised of the same plastic as the first of said materials while the plastic powder adjacent the second of said materials is the same polymer as the second plastic polymer. Between these extremes the concentration of one of said powders increases and the other decreases in a gradual manner until midway between the two materials to be joined the powder comprises a mixture of substantially equal amounts ~2~

oi- the two different polymers. The entire assembly ia then subjected to a uniform fluid pressure with applied heat to affect a welding of the joint and a melting and fusion of the powders wi_h each other and with the adjacent (ju~taposed or overlapped) edges of the materials being joined. Alternatively, in many applications the powders may be supplied at the joint without such gradation toward the center.

After the applicaton of the plastic powders to one of the platens the platens are moved toward each other until a light pressure is applied to the layer of plastic particles. Thereafter the pressure is applied to tne diaphragm or the envelope as described above.
The diaphragm contacts the plastic powder with an even fluid pressure while heat is applied. The fluid pressure is substantially uniform over all of the plastic particles while the applied heat is sufficient to melt and consolidate the particles of the powder.
It will be seen that the same basic method is used whether an article, a sheet, a weld or other joint is being produced.

The time required to form the article including a sheet or to make suitable welds will in part depend upon the particular plastic or plastics being worked, the thickness of the final product and like considera-tions. After applying heat and pressure as described above for a sufficient length of time to produce the article the pressure is released from the dia-phragm (or envelope) and the platens are separated permitting the removal of the product.

There is far less or practically no degradation of the ~.f~ 3~1 1 piastic whether in for,ming an article or making a weld since the diaphragm or dia?h~agms effectively exclucle virtuallv all air from contact with the plastic.
The air release means such as the PTFE coated glass fiber fa~ric having many minute pinholes and tne wire cloth or screen described above also helps tne escape of air so that the plastic is formed or welded in the absence of air with the result that degradation is greatly reduced or eliminated.
The apparatus used in carrying out the method com-prises a frame having mounted thereon upper and lower platens at least one of which is covered with a flexible impermeable diaphragm or envelope. The diaphragm or envelope may be of any suitable material which will withstand the pressure and heat of opera-tion including suitably selected metal sheets, plastic sheets, plastic and fabric combinations or the like.
I~etal alloys having extremely low coefficients of expansion are particularly useful for the diaphragm or the diaphragm wall of the envelope. When the dia-phragm or diaphragm face of the envelope is of metal thicknesses from about 0.002" (0.05mm) to 0.0075"
(0.19mm) have been found adequate. However, thicker diaphragms may be used as well with up to about 0.06"
(1.5mm) being contemplated. Thicknesses of 0.020"
(0.51mm) to 0.035" (0.89mm) are generally sufficient.

The heat may be supplied to one or both platens in a number of ways. Common heat bars or heat elements of the electrical resistance type are satisfactory in many applications although a more versatile means of supplying heat is by using infrared radiation in wave lengths from 7,500A to 6 microns or more.
Since such infrared radiation lends itself readily to 1~2 ~360 1 concentra~ion, absor?~ion, transmission, and refrac-tion over th~ areas to be hea~ed by use of known optical and physical means such infrared radiation heatins is more versatile than ordinary electrical resistance heating elements~ In either event with either s~stem quite accurate temperature control is possible from less than about 200F (9~C~ to an excess of about 2,000F (1093C) which latter tempera-ture far exceeds any normal temperature re~uirement when wo.king with plastics.

~TAILED DESCRIPTION OF THE D~WINGS

The in~ention will be fully understood by those skilled in the art from the following description and dra~ ngs in which:

FIG. 1 illustrates schematically the production of a wide she~e~ by use of plastic powders;
FIG. 2 illustrates a mixture of different plastic powders graded progressively when joining two dis-similar ~astic sheets;

FIG. 3 is a schematic vertical section of another emoodimen~ of the apparatus of the invention;

FIG. 4 is a schematic vertical section of yet another embodiment of the apparatus of the invention; and FIG. 5 is a schematic side elevation illustrating the curing or an abrasion resistant coating applied to the silverea face of a plastic sheet when producing a mirror in accordance with the invention.

~19~

Di:T~ILl~D DE~iCP~IPTIO-;I OE` THE I~VENTION

In FIG. 1, there is shown an apparatus 100 com~rising a lower platen 80 esuipped with heating elements 81.
The heating elements 81 rnay be electrical resistance heaters or, alternatively, may be tubes through which a heatins fluid is pul.nped. A second platen 88 is positioned in opposed relationship to the platen 80.
The platen 88 also incorporates heating elements 89 either by way of resistance heaters or tubes through which ,he heating fluid is pumped. Any of a number of suitable heat sources may be used in place of or in addition to the heating cores 81,89. For example, infrared radiation from any suitable source such as electrical bars, quartz tube heaters or tne like are particularly versatile because of the ease of control-ling, concentrating, transmitting and absorbing the same on the material to be heated by use of known optical and physical techni~ues. Eowever, any source of heat can be adapted for use in this invention.

The platens 80 and 88 are mounted for relative move-ment toward and from one another by movement of one or both thereof. Secured to one of the platens 80,88, preferably the upper platen 88 as shown, is a flexible envelope 86 containing a fluid 87. The envelope 86 includes a front face or diaphragm 90. The diaphragm 90 and the entire envelope 86 may be of any suitable material which will withstand the pressure and heat of operation including suitably selected metal sheets, plastic sheets, plastic and fabric combinations or the like. In some instances, metal alloys having ex-tremely low coefficients of expansion are particularly useful for the diaphragm and for the entire envelope.
~owever, in most applications it has been found that 1 high coefficient OL^ e~?ansion materials, particularly cop?er and some stainless steels are very suitable.
~hen a metal is used it has been found that thicknes-ses from abou- 0.0 0" (0.51 mm) to 0.035" (0.89 mm) are adeauate. However, thicknesses of up to about 0.06" (1.5 mm) are also useful. The interior of the envelope con.aining the fluid 87 communicates through a suitable conduit 91 with a source of fluid under pressure (not shown). The fluid may be a liquid such as water, hydraulic fluid, heat transfer fluid or tne like or, alternatively, the fluid may be gaseous in which event air, or an inert gas such as nitrogen are suitable. The pressure source is selected depending upon the type of fluid (liquid or gaseous) which is to be utilized. A polished plate 82 is placed upon the platen 80 for the formation of a sheet of plastic. It will be appreciated that with suitable mold release agents the polished plate 82 ma~ oe dispensed with and the sheet formed directly upon the platen 80; however, 20 the polished plate 82 is preferred. Members 102 and 104 on the plate 82 confine the plastic particles 83 which preferably comprise a finely ground powder. As will be apparent to those skilled in the art, in a batch type operation where a single sheet is to be 25 formed the members 102 and 104 extend around the periphery of the platen 80 and the plate 82 to confine the plastic particles 83 on all sides. However, when a continuous or substantially continuous sheet is to be formed the platens 80 and 88 can be elongated and comprise the adjacent converging runs of two conveyor-like structures so that the platens 80 and 88 not only move toward and from each other but also move longi-tudinally alony with each other at the same rate. In the latter event, the members 102 and 104 are posi-tioned only at the lateral side edges of the platen 80 as shown.

~l~Z1i''3~
- -]5-I The a-~?aratus also includes a breathable microporous sheet S' wilich is laced immediately above the plastic particles 83. The sheet 84 comprises a fabric mater-ial made of fiberglaas and coated with PTFE in such a manner that the sheet has a myriad of minute pin holes substantially invisible to the naked eye extending therethrough throughout substantially the entire extent of the sheet. Positioned over the microporous parting sheet 84 is a fine woven wire cloth or screen 85. Alternatively, the element 85 may be a thin, flexible, porous or minutely perforated metal sheet.
As will be apparent in the following description, the microporous parting sheet 84 and the wire screen 85 together comprise an air release means to release entrapped air from the layer of plastic particles 83 during formation of the sheet. The microporous parting sheet 84 and the wire screen 85 may be single sheets of material placed over the particle layer 83 in a batch operation or they may be a continuous track of material in the event the sheet is to be formed substantially continuously.

While the above description refers to a two part air release means, a one part air release means as above described is also contemplated. In such case the elements 84 and 85 are replaced by a single PTFE
coated sheet comprising a porous metal sheet or wire screen.

In operation, a layer of plastic particles 83 is spread substantially evenly in the area defined by the members 102 and 104 which layer is spread to a thick-ness substantially equal to or slightly greater than that of the members 102 and 104. The heating elements 81 or 89 or both are then energized to heat the ~Zll9~1 1 pla~ens 80 or 88 or both, and in the case of the platen 88 in order ~o heat the fluid 87 and the diaphragm 90 as well. While either platen 80 or 88 may be heated as described or both may be heated, it is sometimes sufficient that the lower platen 80 be heated whereby the heat is transferred through the polished plate 82 to the plastic particle layer 83.
The platens 80 and 88 are then brought toward each other with the microporous parting sheet 84 and the wire screen 85 positioned therebetween. It will be appreciated that the layer of particles 83 together with the polished sheet 82, microporous parting sheet 84, and wire screen 85 comprise a "sandwich" located between the two platens 80 and 88.

When the platens 80 and 88 have been brought together sufflciently so that the diaphragm 90 is applying a firm pressure on the layer 83 of plastic particles through the wire screen 85 and microporous parting sheet 84, then pressure is supplied through the conduit 91 to the envelope 86 and thus to the dia-phragm 90. Uhder the heat supplied by the platen 80 (or the platen 88 or both) and the pressure applied by the diaphram 90 under pressure from the fluid 87, the plastic particles melt and consolidate into the plastic sheet. There is no lateral flow of plastic, only movement together to consolidation thus elimina-ting flow lines that produce stress. During this operation the diaphragm 90 insures that all areas of the layer 83 of particulate plastic material are under uniform pressure. After a suitable time, the platen 80 and 88 are separated, and the sheet produced from the layer of particles 83 is removed from the appa~
ratus.

,, . .. _ . . . . . .. . . .. . . . . . . . . . .. . . .

~z~
_ -17-1 The particle size is ?referably below aoout 40 mesh, although, generally, the finer the powder used the better the results obtained, but, in any event, the powder should be free flowing so that there is an easy leveling of the ?lastic particle layer when the particles are applied initially. The pressures used will generally be below about 50 p.s.i. (3.52 kg/cm ), with 40 p.s.i. (2.81 kg~cm2) being typical though this will vary depending upon the material. The temperature best used is usually above the melt and will depend upon the particular plastic particles being utilized with 350F (177C) being useful for polyvinyl chloride (PVC) as polymerized (without additives) and commercially available.

This type of process produces a sheet that is vastly superior ~o previous products, which is stress free and has greatly improved physical and mechanical properties. Surprisingly, sheets of plastic made from the highest molecular weights such as millions molecu-lar weight polyethylene (MMwPE) are thermoformable when made by this process. Additionally, there is little or even no degredation even with materials in which high degradation is normally considered unavoid-able. For example, MMwPE produces a stress free sheetthat is completely undegraded and can be produced in any thickness ranging from very thin films to heavy weights. Among other attributes it is this freedom from stress that makes these MMwPE sheets thermo-formable whereas such sheets produced by other methods(if they can be produced at all) are very difficult or impossible to thermoform.

Pure polyvinylchloride (PVC) sheet or film produced from polymerized plastic particles exhibits previously ~L~2~ 0 unootaina~le propertiea. Among these are great impact strengths at far below freezing comparable to that at room temperature and the lack of the high degrada-tion in a sheet of pure PVC which it is otherwise not possible to produce except by adding expensive addi-tives. As another example, PTFE articles produced by this invention exnibit a much superior dielectric strength. sy this process and equipment practically the whole range of thermoplastic materials can be 0 processed.

Two or more dissimilar materials can be spread in layers to produce a cladding, laminating, or surfacing thus allowing different properties to be combined at lo-w cost or, alternatively, incorporating properties otherwise unattainable in one material. As one example, it is possi~le to produce a laminate in one step. The plastic particle layer 83 may include at the upper surface thereof a second layer 83' of a different plastic polymer in order that the completed product comprise a plastic sheet having one plastic on one side and a different plastic on the other side.
Still further, a wood, metal, or other like material may be place directly upon the polished plate 82 or the platen 80 and a layer of plastic particles 83 distributed thereover and then formed by this process such that the plastic particles are laminated directly to the wood, metal or other layer. Still further, one or more different polymeric materials can be spread in layers of the same or different thickness and simul-taneously formed into film or sheet in one step. For example, normal molecular weight polyethylene may be spread in a layer 83' over a layer 83 of MMwPE
placed on the polished sheet 82 in order to provide a cheap substrate (the upper layer 83') for facings ~z~

(the layer 83) having low coefficients of friction.
Various mixes of powders have been mixed with the plastic particles in layer 83 which have included graphite or molybdenum disulfide also for low coef-ficients of friction materials.

Still further, this invention permits the production of much wider sheets than those which are currently possible and at a lower cost, while also eliminating great problems in maintaining thickness tolerances.
And, as indicated, products with unusual properties may be produced. For example, very large building panels of pure PVC powder may be used in layer 83' to provide a low cost high strength backing with superior impact strength onto which a weather-side surface may be produced simultaneously in one step by providing the layer 83 with a suitable powdered plastic of an acrylic or the like which is ultra-violet light absorptive. Thls provides unparalleled resistance to the elements on the exposed surface. The outer surface can also be made highly chemically resistant by using fluorinated materials in the layer 83.

Due to the broad applicability of this invention plastic articles having a wide variety of unusual charac-teristics may be produced. Indeed, it is possible to "engineer" many of the properties of the final product not previously possible. For example, this invention includes the ability to lower the heat requirement when melting crystalline materials such as polyethylene by as much as 20-~5%. This results in a fast heating of the sheet when thermoforming with attendant savings in energy costs. Still further, the same sheet may be pellitized or ground for use as raw material for extrusion and injection processes and . " -- .

o - ~o -1 this raw ma erial will require less total heat input to melt the plastic, ~hus ma!~lng for a mo~e economical operation.

It has even beein found that some crystalline materials such as p~lye~hylene, cnlorotrifluorceth~lene, poly-propvlene and the like may be processed in ~he sheet at below the melt temperatu e. It is only necessary that the temperatures in the large crystal growth 0 range be neld long enough in the compacted fine particles so that the crystals will grow across boundaries of the sufficiently small particles and form into a solid mass.

During th~ formation of the sheet from the plastic material ~3 or 83 plus 83' any gases including air that surr~nd the particles escape through the micro-porous par-ting sheet 84 and the wire sc een 85 to the atmosphere. This is true also of any moisture that may be presen~ which is vaporized and escapes in the same manner. ~ccordingly, as the sheet is being for~ed, it is formed substantially in the absence of air, mois-ture and c2ygell and degradation is greatly lessened or avoided. Still further, there is no stress in the product since there is very little, if any, actual movement beyond that necessary to move from the particula~e form into the solidified mass of the sheet, as i~entioned above.

In produci~.g articles ~lith the e~uipment and method of this inven~ion, efficient results are often obtained from heating the bottom platen 80 only and using air pressure in the flexible envelope 86. As mentioned, however, the upper platen 88 may be heated by a suitable ~eans. Still another alternative is to provide steam or hot liquids as the pressurizing fluid 87 in order to heat the diaphragm 90.

In addition to the formation of articles, in particu-lar sheets of plastic from plastic particles, the invention is also applicable to the welding of pre-viously formed plastic sheets whether of the same or of different materials. For example, not only is it possible by this invention to make articles at far lower pressures (at 50 p.s.i. (3.52 kg/cm2) or less) than materials such as MMwPE have heretofore required, but by an adaptation of this process plastics which it has been difficult or impossible to weld may be welded with an excellence heretofore unknown.

FIG. 2 shows the manner of welding a butt joint between two sheets of previously formed plastic sheet material 200 and 202. As shown in FIG. 2 only the lower platen 80 and the polished metal plate 82 are shown for simplicity. It will be appreciated that the upper platen 88 with its associated envelope 86 and diaphragm 90 together with the microporous parting sheet 84 and the wire screen 85 are also utilized in FIG. 2. The two sheets 200, 202 of plastic material to he joined are positioned on the polished plate 82 with their edges in spaced relationship as shown. In the space between their edges there is provided the plastic particulate material 201 to a depth to provide sufficient material for the proper thickness in the finished product to avoid either too thin or too thick a quantity of material at the finished joint. The particulate material 201 is preferably of the same polymer as the sheets 200 and 202. After supplying the material 201 to the space between the adjacent o - -- ~ 2 2--1 edg;'â 0_ ~he shee~s 200, 202, the platens 80 and 88 aLe broug'lt together as described above to provide a firm pressuLe on the particles 201. At least one of the platens 80 or 88 (preferably the lower platen ~0) o. both are heated and are maintained at a suitable temperature generally at or above the melt tempera ure of the plastic particles 201. After the diaphragm 90 has been brought to bear through the wire screen 85 and the microporous parting sheet 84 on the layer of 0 plastic particles 201, pressure is supplied through conduit 91 to the fluid 87 and the diaphragm 90 to provide the requisite pressure for formation.
After the plastic particles 201 have melted and formed the joint between the sheets 200 and 202, the pressure - 15 in envelope 8~ is released and then the platens 80 and 88 are separated, and the polished plate 82 with the product thereon is removed from tne apparatus. If no plate 82 is used then the product formed on platen 80 is usually cooled before it can be removed. For -~ 20 certain plastics or for reinforced articles cooling is not necessary. It will be appreciated that this apparatus and process is essentially the same as that described above with respect to FIG. 1 for the forma-tion of a sheet excepting only that the elements 102 and 104 are not required and are instead replaced by the sheets 200, 202 of plastic material.
.

when the sheets 200 and 202 are of different plastic polymers it is preferred that the plastic particulate material 201 be composed of particles of the same two plastic polymers as the sheets 200 and 202. In many - instances it suffices to spread the two different plastic polymer particles and have them meet directly in the joint 201; however, it is sometimes preferred to use a gradual gradation from the plastic on one :

o 1 side to that of the other. For exam~sle, assumins that shee 200 is made of a first plastic polymer desis-nated A' and tne secoi~d sheet 202 is made o. a ci~-L rent 31a_tic polyme~ designated B', then a track o~
po~ders wouid be placed adjacent the sheet 200 ,which is entirely a powder of the A' polymer. Similarly a track of powder would be placed adjacent to the sheet 202 which is entirely of the B' polymer. Adjacent to the track of A' polymer would be placed a mixture of plastic particles comprised of, say, two-thirds of the A' polymer plus one-third of the Bl polymer and adjacent to the track of B' polymer powder would be placed a track of powder comprising a mixture of, say, two-thirds of the B' polymer plus one-third of the A' poly-~er. In the middle a mixture of one-half of the A' polymer and one-half of the B' polymer is provided. After supplying these tracks of plastic particles the sheets 200, 202 and the powder 201 are processed as above descri'oed for the joining of two sheets 200, 202 of the same polymer. while the ratios of two-thirds, one-third; one-half, one-half; and one-third, two-thirds have been mentioned by way of illustration, it will be appreciated that other proportions may be used and fewer or more tracks with lesser or sreater gradual increase an~ decrease of the respective polymers may be utilized.

While the above description of the use of th~ inven-tion for welding sheets of plastic material together has referred to the forming of butt type joints, and while a butt type joint is shown in FIG. 2, the invention is not so limited. It has been found equally as useful in forming overlapped joints in which the plastic particles are placed in one or more layers oetween the overlapped edges of tne sheets.

2:J 9~0 _ -2~-1 The la.-ers of plastic powders may be graded with var~inL~ proportions as above described for the graded trac'~s 3-- powders.

In the ~bov~ description of welding two like or unlike pre-exi,Ling sheets of plastic together, the plastic powders used would form the weld with the adjacent sheets using the present invention. However, it someti~es happens that a plastic powder will not form a weld -~ith a pre-e~isting sheet even when that sheet was pro~uced from the same plastic as the powder. In order t~ join two unlike sheets together in such instances, the joint is formed at the same time as the sheets ~hemselves using the present method and equip-ment.

The Examples below are illustrative of the applicationof the invention to the joining of unlike sheets at the same time that one or both of the sheets are formed.

EXAMPLE I

Pure p~lyvinyl chloride (PVC) was joined to millions molecu~ar weight polyethylene (MMwPE). Pure PVC
powder which was pure as polymerized (no additives) was spread to be formed into a sheet and pure finely powdere~ MMwPE powder was spread to become a sheet with t~e powders meeting at the middle. The two powders met directly without the use of any mixture or gradation of the powders therebetween other than what mixing may have resulted from the pressure subse-quently applied. The materials assembled as just describ~d were then treated as above described in an apparatus such as illustrated in FIGS. l and 2 and 9¢0 1 heated to a tem?era~ure above the melt of either plastic, in this case, at 392F (200C). Sheets of varying thic~nesses from 0.043" (1.09mm) to 0.051"
(1.3mm) were joined in this manner. In a tensile strength test to determine the strength of the joint, the joined sheet was placed in a test ap?aratus wi.h the joint line transverse to the direction of pull.
It was found that the MMwPE sheet parted at 23 pounds/
0.1875" (10.4 kg/4.76mmj width while the joint re-mained intact.

EXA~PLE II

.~ polyvinyi chloride (PVC~ sheet 0.033" (0.84mm) thick5 was joined to a millions molecular weight polyethylene (MMwPE) sh-eet 0.030" (0.76mm) thick in tne manner described a~ove for Example I, excepting only that the PVC powder contained 2~ of a tin stabilizer. The PVC powder met directly with the MMwPE powder with no gradation trlerebetween. The powders were then heated and processed in apparatus similar to that of FIGS. 1 and 2. In a tensile test of the joint it was found that the joint parted at 17 lbs/0.1875" (7.7 kg/
4.76mm) width which is approximately the tensile strength of MMwPE at that thic'~ness. Subsequent tests demonstrated that the joint line strength is increased by the use of a single mixture of 50% PVC powder and S0~ MMwPE powder. Still further improvement in the strength is achieved by use of the gradual increase of one and decrease of the other powder as above des-cribed with reference to the sheets 200, 20~ when made respectively of polymers A' and B'.

2~61) - -~6- !
-E~AMPr,E III

A PVC sheet was joined to a sheet of acrilonitrilebutadiQne styrene (ABS) while producing bot'n sneets from powders. The sheets were of 0,024" (O.olmm) in thickness. The PVC powder used contained 2~ tin stabilizer, A finely powdered A~S resin was spread to meet the edge of the PVC powder directly without gradation t'nerebetween. The assembly was then sub-jected to pressure and heat as described above inapparatus like that shown in FIGS, 1 and 2 to consoli-date and form a joint. In a strength test in a tensile apparatus it was found that the ABS sheet parted at 23 lbs./0.1875" (10.4 kg~4.76mm) width while the joint remained intact. The PVC sheet also re-mained intact.

EXAMPLE IV

A pre-existing commercially available PVC sheet was joined to a sheet ol MMwPE as the sheet of MMwPE was formed. Pure PVC (without additives~ powder was spread to meet the edge of the pre-existing sheet of PVC and MMwP~ powder which iwas to become the L~IL`~wPE
sheet was spread to meet the PVC powder directly and then processed as in Example I. Tests to separate the sheet were relatively crude and the tensile strength was not measured; however, the sheets did not part at the joint.

Accordingly, the present invention is applicaole to the joining of two unlike sheets when both sheets are being formed as in Examples I, II, and III above or where one sheet already exists and the other sheet is formed at the time the joint is made as in Example IV
above.

3~

1 In all instances the surface of the joint reflected the te~tu.e o- the metal sheet 82 and the ?arting sheet 84, and was not detectable as a joint exce?t as to color when color existed.

From the above examples, it is apparent that virtually any combina.ions of plastics may be welded or joined together with weld or joint strengths close to or equal to that of the sheet itsel~. In some cases the strength of the weld or joint is improved by a more gradual change of one plastic powder material to the other at the joint as previously described.

It has been noted that when pure PVC or MMwPE are used in this process either in the formation of sheets or in the formation of welds or joints, there is compara-tively little or no degradation of these materials and tney are substantially stress free even though these materials are not normally considered to be capable of formation into sheets, welds, or joints with less than a great amount of degradation unless the PVC is specially compounded or, in the case of MMwPE, a thickness greater than about one-half inch is used.
Even with the 392F (200C) process temperature generally used with these examples, the present invention consolidates the plastic material in an extremely short dwell period above normal tempera-tures.

The following table is a useful guide in making first estimates of welding or joining temperatures:

-2~-~Yelding Plastic Melt Point Temp. Degradation Pure Polyvinyl ) 335F 392F Very sliynt Cnloride as ) (168C) (200C) polymerized ) (about) Pure Polyethylene ) 280-290F 392F .lot measur-or polymerized ) (138-143C) (200C) a~le (too 0 millions molecular ) slight) weight Polyvinyl Chloride ) 330-335F 392F Very slight plus 2% tin ) (166-168C) (200C) 5 stabilizer Pure ABS as ) Below 300F 392F Not measur-polymerized ) (149C) (200C) able (Acrylonitrile-butadiene-styrene) ) The pressures necessary for welding or joining are the same as for making sheet and are very low and for some plastics may be only that obtainable from atrnosphere and a partial vacuum.

The process and apparatus of this invention are capable of producing a number of unique new products having improved or new properties as will be a?parent to those skilled in the art. Among these is the ability to produce wide thickness differences in the same sheet in which case more powder is used in the thicker areas and less in the thinner areas. Also different plastics may be used in different portions of the same sheet.

~~~ -29- !

~lost notably plas~ic articles lncluding sheQts pro-cluced by the method and ap?aratus of this in~ention are stress rree. Still further, it is possible by this method and apparatus to produce articles including sheets of various thicknesses from very thick to vQry thin films from materials which have not previously been considered capable of being formed into such sheets. Among these are plastic polymers having millions molecular weight including, particu-0 larly, MMwPE. ~lost importantly, articles includingsheets of millions molecular weight plastics such as polyethylene can not only be produced by this inven-tion which was not previously economically possible, but in addition, such sheets are stress free which also was not previously possible. A product that is free of stress is very important in a number of applications as will be appreciated by those skilled in the art since such products are dimensionally very stable under extremes of temperature and do not have the localized weaknesses often associated with pro-ducts having stresses built into them during forma-tion. Previous to this invention the use of plastic sheets was limited to those temperatures that would not excessively release the stresses built into the product- Sheets or other articles produced by this invention, however, can be used at any temperature the particular plastic will withstand.

While this invention has numerous applications in industry and can produce a very wide assortment of products including among others, sheet for use in the construction industry, in claddiny, glazing for windows, and the like, one e~ample described below is as a base or substrate for a mirror in place of the usual glass. This particular article is described ~ 3l2~

1 below with reference to a second and third embodiment of the apparatus of this invention as shown in FIGS. 3 and 4.

Essen~ially, the apparatus of FIGS. 3 and 4 differs from that of FIGS. 1 and 2 in having two diphragms one above and one below the sandwich. The diaphragms may be either single sheets of a heat resistant flexible material ( FIG. 3 ) or the front face of a sealed envelope ( FIG. 4). This arrangement permits the use of glass platens which has not heretofore been possible.

With reference to FIG. 3r there is shown an apparatus comprising support members Sl and S2 suitably mounted for relative movement. ~hat is to say that either one or both of the support members Sl, S2 may move toward and away from the other support member Sl, S2. The upper support member Sl carries an upper platen l while the lower support S2 carries a lower platen 2.
Each of the platens l and 2 incorporates heating cores 3 which may be electrical resistance heaters or tubes for carrying heated fluids, either gas or liquid. In place of heating cores 3 any of the heating mechanisms described above with re'feren'ce''~~to'~'the apparatus of 25 FIGS. 1 and 2 may be used.

As shown in FIG. 3 ~ there is a top diaphragm 4 and a lower diaphragm 5 carried respectively by pressure frames or members Pl and P2 which may advantageously form part of the jaws of a press also incorporating the supports Sl and S2. The diaphragms 4 and 5 are shown as having peripheral gaskets 6 of a suitable resiliently compressible sealing material such as rubber. The gaskets are preferably also resistent ~o 35 deterioration from heat and are preferably spaced a ~_,~.

~1~19~
_ -31-1 su~ficient distance from platens 1 and 2 as to reducQ
the heaL that im~inges on said gaskets o. The gaske,s ~ may be forced into sealing contact by the pressure members Pl and P2.

~s shown in FIG~ 3, a master sheet 7 is positioned between the diaphragms 4 and 5. When producing a mirror, tine sheet 7 is preferably of a high quality tempere~ or heat resistant glass highly poiished although highly polished metal master plates 7 may also be used.

The appa~atus also includes a microporous parting sheet 1~ ,and a wire screen 11 like elements 84 and 85 describe~ above with reference to FIG. 1.

In opera`_ion, a layer of powdered plastic material 8 is place~ upon the master sheet 7. If desired, a second 1ayer 9 of the same or a different plastic material and of the same or different color may be placed o-~r the layer 8. The apparatus ia then closed bringin~ frames Pl and P2 as well as the support frames ~L and S2 together with the gaskets 6 in gas sealing contact to provide a chamber. At the same time, the support frames Sl and S2 are firmly pressing upon the opposite sides of the sandwich comprised of the master sheet 7, the layer of plastic particles 8 (or layers of plastic particles 8, 9, etc.), the microporous parting sheet 10, and the wire screen 11.
Either or both of the platens 1, 2 is heated to a temperature sufficient to melt the plastic particles making up the layer 8 (or the layers 8, 9, etc.).
After sealing the gaskets o and bringing the platens 1 and 2 into firm pressing engagement with the sandwich 7, 8, 9, 10, 11, a partial vacuum is applied through the conduit 12 to the sealed space or chamber defined by the diaphragm 4 and 5 and the gaskets 6. In this way, a pressure is achieved on the outer side of the diaphragms 4 and 5 which is a function of the differ-ential between the atmospheric pressure and the residual pressure within the chamber 4, 5, 6 resulting from the applied partial vacuum. This pressure though relatively low, is sufficient for the formation of many plastic particles (depending on their molecular weight and their flow properties at the melt) into articles and sheets in accordance with the present invention. This pressure applies a fluid pressure evenly over the whole area of the powdered layer 8 (or layers 8, 9, etc.). Also, due to the evenness of the pressure no damage such as cracking, or breaking of the glass master sheet 7 is experiencea.

The gaskets 6 are kept sealed and the partial evacua-tion of the chamber 4, 5, 6 maintained long enough for the heat from platens 1 and 2 to penetrate into the plastic layer 8 (or layers 8, 9, etc.) to melt the plastic and to cause it to fuse under the applied heat and pressure into a coherent sheet. Thereafter the vacuum at conduit 12 is discontinued, the apparatus is opened, and the finished plastic sheet removed.

FIG. 4 shows an apparatus similar to that of FIG. 3 in which like elemen~s are numbered with the same refer-ence numerals. In F~G. 4, the pressure members Pl, P2 are not utilized nor are the gaskets 6. Also, in FIG.

4, the diaphragms 4 and 5 have been replaced by sealed pressure envelopes 14 and 15 respectively having flexible diaphragm faces 141, 151 respectively. These sealed pressure envelopes 14 and 15 are mounted to support members Sl and S2 respectively by any known suitable means (not shown). It will be appreciated ~2~
~ -33- !

1 th~ whil~ the pressure envelopes 14 and 15 are shown s~aced from th- platens 1, 2 for purposes of clarity, the same will oe in contact with the platens 1 and 2 and may be secured directly ~hereto as wi~h the envelope &6 shown in FIG. 1. Indeed, the apparatus of FIG. 4 is very similar to that of FIG. 1 accepting that the lower platen 2, unlike the lower platen 80 in FIG. 1, is also supplied with a sealed fluid envelope 15. Conduits 13 and 16 connect the interior of the fluid envelopes 14 and 15 respectively with a source of fluid under pressure. As with the apparatus of FIG. 1 the source of fluid pressure may be a hydraulic pump, an air compressor, or the like depending upon whether the fluid is a liquid such as water or hy-draulic fluid or a gas such as air or an inert gassuch as nitrosen.

In operation, the support members Sl, and S2 are brought together with the sandwich comprising the master sheet 7, the layer of plastic particles 8 (or layers 8, 9 etc.), the microporous parting sheet 10, and the woven wire screen 11 all positioned as shown between the sealed envelopes 14 and 15. One or both of the pla~ens 1 and 2 will have been previously heated to or above the melting point of the plastic particles to be molded. After the platens 1 and 2 are exerting a firm pressure upon the sandwich 7, 8, 9, 10, 11 through their respective envelopes 14 and 15, the fluid within envelopes 14 and 15 is pressurized by a suitable mechanism through the conduits 13 and 16 respectively. In this construction, it is essential that the platens 1 and 2 be supported by their support members Sl and S2 by a mechanism that not only applies the low pressure required but holds the pressure exerted by the platens 1 and 2. The fluid pressure in ... -3~-1 envelo?es 14 and 15 causes the diapnragm faces 141 and 151 to bear wi.n an even pressure over the entir-- area of the la~ier of particles to be formed into a sheet.
Tris pressure ia very even and adjusts automatically to insure evenr.ess over the enti.re area. The pressure is kep. ap?lied in the envelo?es 14 and 15 and the apparatus is kept closed to ~.aintain the platens 1 and 2 in position for a time sufficient to achieve melting of the powdered plastic material and its consolidation into a homogeneous sheet. AfteL forma-tion, the fluid pressure is relieved through conduits 13 and 16 and tnus from the envelopes 14 and 15 and then the apparatus is opened thus moving th platens 1 and 2 away from each other. The sandwich may then be removed and cooled sufficientl~ for the plastic to be removed from the master layer 7. In many applications it has been found that the fluid pressure a?plied to the envelopes 14 and 15 may be from below about 10 p.s.i. (0.73 kg/cm2) to about 50 p.s.i. (3.52 kg/cm2) depending upon such variables as the particular plastic beins formed, its molecular weight and its flow properties, the nature of any embossings or debossings to be imparted to the plastic sheet from the master 7 and the like.
An alternative method of operating the apparatus of FIG. 4 comprises first pressurizing the envelopes 1', 15 with fluid pressure while the apparatus is open and support members Sl, S2 separated wholly or ?artly.
This pressurizing of the envelopes 14, 15 causes them to balloon outwardly at a very low pressure such as about 1-5 ?.s.i. (0.073-0.365 kg/cm2). At this point, the conduits 13, 16 are turned off thus main-taining the fluid under pressure in the envelopes 14, 15. Thereupon, the apparatus is operated to cause the 9~() platens 1, 2 to close together with the necessary addi~ional pressure being supplied by the apparatus itself, for example, with the usual hydraulic or fluid rams such as used in presses.

In all cases, any air, gas, or moisture which might otherwise tend to become trapped within the final sheet (as the plastic powder melts and forms into the sheet) passes Ollt through the microporous parting sheet 10, the air ~scape wire screen 11 and then to the atmosphere with any moisture being converted to vapor and escaping in the same manner.

The diaphragms 4, 5, 141 and 151 as well as the entire envelopes 14 and 15 may be made of any suitable metal or plastic material as mentioned above that will stand the pressures and temperatures involved. A
copper sheet of 0.030" (0.76mm) in thickness and a stainless steel sheet of the 400 series of 0.020"
(0.51mm) in thickness have been used successfully.
Thicknesses of up to about 0.06" (1.5mm) are also very useful.

The coherent plastic sheet produced reflects the high polish of the master sheet 7 and equals the best that can be produced in glass. If desired the master sheet 7 may be etched or have other surface ornamenta-tion which will be reproduced in the final plastic sheet. Because of the very even fluid pressure applied by the diaphragms there is no cracking or breaking of the master sheet 7 even when it is made of glass.

Because of the extremely smooth and polished surfaces obtainable the sheet produced can be used in many ~2~ 0 _ -36-1 applications where glass is used. In one application it serves well as a mirror. Indeec reflective mater-ials bond ~ith greater strength to the plastic sheets produced by this invention than to glass. This is contrary to previous experience since heretofore polystyrene has been nearly impossible ~o silver plate directly without an intermediate coating or other treatment. Also, mirrors made from such sheets provide strikingly better reflectivity. ~hen pro-ducing sheets to be used as a mirror care must betaken to avoid any release agent on the surface and if release agents are used on the master sheet 7 they must be cleaned off thoroughly from the final ~lastic sheet. Gther than for this, no special treatment such as chemical etchings or corona discharge are neces-sary.

Silver spray plating has proved very efficient and economical in the production of mirrors from sheets produced in accordance with this invention. A pres-sently preferred procedure for the application of such a reflective coating is as follows:
(a) cleaning and water rinsing to obtain a release free and fingerprint free surface (b) a sensitizing spray is applied (c) a water rinse (d~ a silver solution is sprayed evenly overthe surface (e) a thorough water rinse is applied All of the above steps (a) throush (e) may be per-formed automatically on e~uipment conventionally used for glass mirrors. It is presently preferred to produce mirrors of the "first surface" type rather than of the "second surface" type as is usual with ~z~

1 glass. That is to say tha~ the reflective coating is placed upon the front surface of the sheet OL D1aStiC
ra~her than ~'ne rear surface as is common wi~h glass mirrors. In order to pro~ect the silver plating in such firs~ surface mirrors it must be covered with a suitable ~ransparent abrasion resistant coating for example an acrylic coating which is preferably sprayed on.

A preferred material for this abrasion resistant coating is the class of glass resin polymers des-cribed in U.~. patent no. 3,451,838. These polymers cure to an abrasion resistant glass-like hard thermo-set material that is insoluble in most common solvents non-yellowing and highly light transmitting above about 1930A. A 40% solution of such a glass resin in butanol with about 5% of a catalyst has proven successful. A thickness of .001" (0.025mm) has been found adequate.
~0 The recommended cure time by the manufacturer of the glass resin utilized was 16-24 hours at 275~ (135C).
This recom~lended cure temperature and time is unecon-omically long and the temperature excessive for the polystyrene homopolymer mirror sheet 0.09" (2.29mm) thick which was used to produce a mirror by this invention since the material melts at about 280~
(138C). The total of heat and curing time ~as reduced to six minutes or less by the use of radiant heat evenly applied from above. This radiation strikes the silver plating which reflects back well over 90%
of the radiation reaching it. The resin coating therefore heats very quickly while the other side of the shee' heats only very slowly. A temperature of 4G0F (2~4C) is reached very rapidly (about four minutes or less) and a cure of the glass resin is achieved at this temperature before there is damage to the underlying polystyrene sheet.

FIG. 5 shows an apparatus for curing in accordance with the just described procedure. As shown in FIG.

5 there is a highly reflective stainless steel panel 17 having a plurality of radiant heating coils 18 positioned therebelow. A polystyrene homopolymer sheet 19 produced by the present invention either by the apparatus of FIG. 3 or FIG. 4 and 0.09" (2.29mm) thick, having a molecularly thin silver layer 20 thereon, and having a film coating 21 of a glass resin as described above was cured as shown in the apparatus of FIG. 3. The complete operation was completed in about six minutes as above mentioned.

Mirrors produced in accordance with this process appear, to the lay observer, to have a greatly magnifying effect due to the fact that such a mirror does not experience the 10-15% light loss which is common to second surface glass mirrors.

In all of the above embodiments of the apparatus and method of this invention the heating of the platens may commence before or after the platens are brought together or before or after fluid pressure is applied to the plastic particles by the diaphragm or dia-phragms. The particular sequence will depend upon a number of variables including the particular equipment being used, time to heat the platens and the plastic, the temperature required, etc. In all instances, however, the plastic particles consolidate into the article while at or above their melt temperature and while they are at the same time being subjected to the fluid pressure applied by the diaphragm or diaphragms.

Claims (20)

The embodiments of the invention in which an exclusive property or privilege is claimed are defined as follows:-

1. In a method of making a plastic article from finely divided plastic particles utilizing heat and pressure the improvement comprising applying a quantity of said plastic particles to a first member; disposing a flexible diaphragm in opposed relationship to said first member with said plastic particles therebetween; disposing between said plastic particles and said diaphragm a microporous air release means;
positioning said diaphragm against said air release means with said air release means against said plastic particles; applying a fluid-like pressure to said diaphragm to cause said diaphragm to apply an even fluid-like pressure on said plastic particles through said air release means; heating said plastic particles to at least the melting temperature thereof while they are under said fluid-like pressure; venting entrapped gases through said air release means from between said particles while the latter are being heated and pressed with said fluid-like pressure; controlling the degree of pressure and heat applied to said plastic particles to achieve sufficient pressure and heat to cause the particles to consolidate and form a plastic article.

2. The method of Claim 1 in which said flexible diaphragm is one face of a sealed envelope.

3. The method of Claim 1 including a second flexible diaphragm positioned in opposition to said first flexible diaphragm with said microporous air release means and said plastic particles therebetween and in which fluid-like pressure is applied to both of said diaphragms.

4. The method of Claim 3 in which said diaphragms are sealed together and said fluid-like pressure is applied by applying a partial vacuum between said diaphragms.

5. The method of Claim 3 in which both of said diaphragms are the front face of sealed envelopes and in which said fluid-like pressure is applied by pressurizing a fluid in said envelopes.

6. The method of any of Claims 1 to 3 in which said microporous air release means comprises a polytetra-fluoroethylene coated fiberglass fabric positioned adjacent to said plastic particles and a wire screen positioned between said fabric and the first of said diaphragms.

7. The method of any of Claims 1 to 3 in which said air release means is a polytetrafluoroethylene coated wire screen.

8. The method of Claim 1 in which said method is used to weld two sheets or plastic together by placing said plastic particles between adjacent edges of said sheets and processing said sheet edges and plastic particles as in Claim 1.

9. The method of Claim 8 in which the adjacent edges of said sheets are separated apart with the plastic particles extending therebetween in a rela-tionship to produce a butt weld.

10. The method of Claim 8 in which the adjacent edges of said sheets overlap with the plastic parti-cles therebetween whereby an overlapped weld is produced.

11. The method of Claim 1 in which said plastic particles are of two different plastics, the plastic particles of one of said plastics being arranged to produce a sheet by said method, the plastic particles of the other of said plastics being arranged to produce a second sheet by said method simuiltaneously with the formation of said first mentioned sheet, and the plastic particles of said first and other plastics meeting each other whereby two sheets are produced simultaneously with joining said sheets together.

12. The method of Claim 1 including disposing a pre-existing sheet of plastic adjacent to said plastic particles to produce a second sheet from said plastic particles which second sheet is joined to said first mentioned sheet during formation of said second sheet by processing in accordance with the method of Claim 1.

13. The method of one of Claims 3, 4, or 5 in which said first member includes a polished glass sheet positioned between said diaphragms whereby one face of said article exhibits the polished surface of said glass sheet, applying a reflective silver layer to said polished surface of said article, applying a transparent plastic coating over said reflective layer, and curing said transparent plastic coating whereby a mirror is produced.

14. An apparatus for making a plastic article from finely divided plastic particles utilizing heat and pressure which apparatus includes a pair of members movable relative to each other characterized in that: one of said members includes a flexible diaphragm positioned in opposed relationship to the other of said members; a microporous air release means positioned between said diaphragm and said other member; means for applying a fluid-like pressure to said diaphragm to cause said diaphragm to apply an even fluid-like pressure through said air release means to plastic particles positioned on said other member; and means for heating at least one of said members.

15. The apparatus of Claim 14 in which said flexible diaphragm is one face of a sealed envelope.

16. The apparatus of Claim 14 in which said other member includes a second flexible diaphragm and means for applying fluid-like pressure to both of said diaphragms.

17. The apparatus of Claim 16 in which sealing means is provided at edges of at least one of said diaphragms whereby said diaphragms may be sealed together when said members are moved to a position adjacent each other; and said means for applying a fluid-like pressure applies a partial vacuum to the chamber defined by said sealing means and said diaphragms.

18. The apparatus of Claim 16 in which both of said diaphragms are the front face of sealed envelopes and in which said means for applying a fluid-like pressure applies pressure to both of said envelopes by pressurizing a fluid in said envelopes.

19. The apparatus of any one of Claims 14 through 16 in which said microporous air release means comprises a poly-tetrafluoroethylene coated fiberglass fabric and a wire screen positioned between said fabric and the first of said diaphragms.

20. The apparatus of any one of Claims 14 through 16 in which said air release means is a polytetrafluoroethylene coated wire screen.