CA1111219A - Biaxial film process and rotary apparatus therefor - Google Patents

Abstract

ABSTRACT OF THE DISCLOSURE
In a biaxial blown tube synthetic resin film making apparatus, the extruder die, mandrel, rehat ovens and hot air ring are caused to rotate and oscillate about a stalk moving coaxially therethrough to provide a flatter, more uniform film.

Description

~ 36 CA 3431 This invention relates to a blown tube process and apparatus for producing biaxially oriented synthetic thin gauge resin film such as polypropylene film, and more particularly to a blown tube apparatus where the extrucler die, rehea-t ovens, and hot air ring are caused to rotate and oscillate in unison to provide a flatter, more uniform polypropylene film~
In a ~ell-known biaxially oriented hlown tube apparatus and process, polypropylene resin is fed through an extruder die head to form a continuously moving cooled and solidified tubular section or stalk which then passes ~ ?
through a reheat furnace to bring it up to a predetermined ~; orientation temperature. At the predetermined orienting or softening temperaturel the stalk is insufflated or expanded into a very large thin gauge cylindrical structure -referred to as a blown tube or bubble. This cylindrical structure i6 closed at one end by having it pass through :~:: - -a pair of nip rolls, and thereafter the double lay flat biaxially oriented section emanating from the nip rolls is -~
slit and wound on storage or mill rolls.
One of the problems of such a process is that an irregular section or a gauge non uniformity causes a ; continuing build up in the film in a mi]1 roll because the non uniformity is continually wound on itself in each . ~
` turn. Large rolls so wound have differences in roll ; ;
diameters because of this cascading effect. These ;~
differences, because of the creep characteristics of the film degrade the basic flatness eveness and straightness of the film. When precision winding machines such as capacitor roll winding machines are utilized to wind capacitor rolls, this degradation causes skewering and . .
~ wrinkling in the winding film which are extremely :, - ' .... .
.,. . . : l undesirable factors.
It has now been discovered, that the extruder die and equipment utilized to increase or reduce the temperatures in the process lending up to the point of insufflation of the stalk must have their effects applied or directed against the stalk in a manner to have an effect on the uniformity of the gauge of polypropylene stalk circumferentially, in order to provide a film with optimum physical characteristics r particularly for electrical capacitor use. In one preferred form of this invention, the polypropylene stalk which only moves axially passes through a reheat oven which coaxially surround ths polypropylene stalk and i5 caused to rotate in unison with a combination rotating die and mandrel. At the same -time, ~ ~ .
a hot air ring which is positioned near the shoulder of -~
the insufflated tube is also caused to simultaneously rotate synchronously with the reheat ovens and the die head~ After a period of rotation, these rotating units are caused to reverse their rota~ion and a process is ~` 20 periodically repeated to provide a form of oscillation movement.
This invention will be better understood when taken in connection with the following description and the drawings in which:
Fig. 1 is a schematic illustration of a blown tube apparatus of this invention.
Fig. 2 is a schematic illustration of the rotating die of this invention.
Fig. 3 is an enlarged schematic and cross sectional view of the die- } t rotator of Fig. 2.
Fig. 4 is an enlarged schematic and cross sectional view of the die and mandrel of Fig. 2.

- 2 -~ 36 CA 3431 Fig. S is a partial schematic and cross sectional illustration of the rotating reheat oven, the rotating hot air ring of this invention, and a bubble support system.
Fig. 6 is a schematic representation of the bubble support system for a polypropylene bubble which does not ~ ;
have a rotating hot air ring.
Fig. 7 is a schematic and exaggerated illustration of a polypropylene strip o~ the prior art with a gauge non uniformity.
Fig. 8 is a schematic and exaggerated illustra~
tion of a polypropylene strip of this invention with a gauge non uniformity.
A schematic illustration of an apparatus utilized to provide polypropylene film by the blown tube process is shown in Fig. 1 as appara~us 10. In apparatus lQ, polypropy~
~ lene resin is fed into hopper 11 from where it passes into ; an extruder 12 where the temperature is elevated sufficiently to provide molten characteristics to the resin. The molten 2Q resin then passes upwardly through a feed duct 13 to a combined rotating die and ma~drel unit 14 of this invention. ;~
-~ The molten resin emanates from the die and mandrel unit as a thick walled tube section or stalk 15. In order to provide the proper travel or axial movement of stalk 15 through die unit 14, a palr of tube advancer rolls 16 ~,~
are employed to provide an upward pull on the stalk 15.
Rolls 16 neck the stalk 15 so as to close off the stalk volumes below and above the rolls 16 around a central air pipe (not shown).
Stalk 15 then passes from the advancer rolls 16 into a rotating ~t oven unit 17 which may be a combina-tion of one or more stacked ovens. In the oven 17 the -- 3 _ the temperature o-f the stalk 15 i5 raised to a predetermined level where the plasticity of the polypropylene is in the desired orientation range of the insufflation step.
Stalk 15, after passing through the oven 17 is caused to move through a rotating hot air unit 18. Hot air riny unit 18 provides currents of hot air to be directed against the stalk 15 to stabilize and equalize the temperature at a constant and predetermined orientation level above that in the reheat oven. At this point, air is introduced into stalk from the central air pipe (not shown) to expandthe 5talk into the bubble 19, as illustrated. `~
After the stalk 15 has been expanded to a bubble form 19, it passes through a cold air ring 20 which cools the bubble to provide a fixed level of ~ ;
solidification of the polypropylene. Bubble 19 then passes upwardly through a collapse frame roller assembly 21 which tapers the bubble towards a line section through a pair of nip rolls 21a. The nip rolls 21a pinch off the bubble 19 to retain a given amount of alr pressure there-withinn In this process the film is biaxially oriented.
It is oriented in the cross machine direction (CMD) because the expanding stalk or bubble provides lateral stretching. ;~
At the same time, the nip rolls provide an axial stretching of the bubble for orientation in the machine direction (MD).
The polypropylene which emanates from the nip rolls emanates as a dual lay flat biaxially oriented sheet joined . ! ~
at the edges. At this point the polypropylene film runs through a slitting and winding assembly 22 wherein the polypropylene strip is slit to provide a pair of strips each of which are then wound on supply rolls 23, as illustrated.
:

~ ~ 4 -.

~ 34 CA 3431 An important feature of -this invention is a rotating die mandrel unit 14, which is more particularly illus-trated in Figs. 2 and 3. Referring now to Fig. 2, the rotating die mandrel unit comprises a ro-tating assembly 24 which includes a motor and gear box unit 25, and a chain drive 26, which rotates the rotator 27. Rotator 27 is more particularly described with respect to Fig. 3.
;; Referring now to Fig. 3, rotator assembly 27 is illustrated as comprising a stationary apparatus 29 and a rotary apparatus 30. Rotary apparatus 30 with its , : . .
-~; sprocket drive 31 is mounted for rotation on stationary apparatus 29 by means of bearings 31, and is effectively sealed by means of seals 32. As the molten resin proceeds from the extruder 12 through duct 13, it enters the rotating die and mandrel assembly 28 as illustrated in Fig. 4.
Referring now to Fig. 4, a rotating die and mandrel assembly 28 comprises a die member 34 having a cylindrical orifice 35 therein through which the molten resin from duct 13 is caused to enter. The molten resin ;
~; which emanates from die member 34 passes over a cylindrical -~- quench mandrel 36~ Quench mandrel 36 contains a cooling - medium, as known in the art, for example in U. S. patent 4,008,022 Carrico dated February 15, 1977 assigned to the same assignee as the present invention, and reduces the temperature of the molten polymer emanating from the die 13 to cause it to solidify and to progressively , "
move upwardly as a tube. In the present invention the mandrel 36 is connected to the die member 34. By means of the chain drive 26, the die 34 and the mandrel 36 are caused to rotate in unison so that the polypropylene '.-,:~
stalk slips at the interface between the stalks and the '~
., .

~ 36 CA 3431 mandrel 36. sy this means, gauge irregularities are circumferentially distributed by the rotator of the die 39. Slippage of the stalk 15 permits the use of a stationary tube ad~ancer (roll assembly 16) thus reducing the complexity. It furthermore avoids the need for a rotating bubhle.
~` The rotating reheat oven uni~ 17 and hot air ring 18 are best described with respect to E'ig. 5.
Referring now to Fig. 5, there is illustrated a partial ~- 10 and schematic view of a combined hot air ring 18 and ~:'''A re~,ef,;~
e~a~ oven unit 17. Reheat oven unit 17 includes a motor ~; drive assembly 37 which rotates the furnace assembly through a ring gear 38. The internal su~face of the ovens (not shown), include appropriate electricallradiant heaters ;~ arranged peripherally about the interior surface which are connected by means of electrical cables 39 to a ;
, source of power 40 (not shown). These heaters operate in a temperature range of 700-1200F and provide heating circumferentially of the stalk. Coiled electrical cables . .
;~ 20 39 are sufficiently long to permit at least 360 of rotating `~
of the reheat oven 17 and are suspended on trolley means.
Reheat oven 17 may thus be defined as a circumferential :::
or ring oven. As the stalk 15 passes through the reheat oven, its temperature is raised to a predetermined level which is ordinarily in the range necessary for insufflation.
The temperature in the rehat ovens must be sufficiently high that all points of the stalk are brought up close to - the required temperature. The stalk temperature is then raised by a small increment to the orientation level, within the hot air ring structure 18.
The hot air ring structure 18 of this invention ;
is also best described with respect to Fig. 5. Referring .
- 6 - ~

~ain to Fig. 5, there is illustrated a partial and cross sectional view of a rotating hot ring structure 18.
Air ring structure 18 is supported on a frame or platforrn 41 separate from the reheat oveh 17 for independent rotation. ~Iot air for the air ring structure 18 is supplied from a source 42 (not shown) through conduit 43 into an annular chamber 44. Fitted into the annular chamber is a hot air lip assembly 45~ Lip assembly 45 forms a closure wall for chamber 44 and is rotationally mounted on chamber 44 through bearing means 46 and 47. The lip assembly 45 is driven by means of a chain drive 48 from a motor source of power 49 (Fig. 1). Air from annular chamber 44 passes through a series of flow distributors 50 and a specially shaped orifice 51 to be directed against stalk 15. ~he temperature of the air in the hot air ring 18 is from about 250F to ~50F and the flow rate is from ;~
70-130 cub. ft. per minute with a stalk speed of from 15 to 8~ ft. per minute.
In addition to the rotating die 14, reheat oven 17, and hot air ring 18, an improved bubble support system 52 is employed. This support system 52 is also fixed to -the rotating lip assembly 45 as is illustrated in Fig.
1. Referring again to Fig. 1, the bubble support system 52 is illustrated as being interposed between the hot air ring assembly 18 and the shoulder section 53 of the bubble 19. The function fo the bubble support system is not only to lend some stability and support to the bubble during the operation of the process and apparatus, but also to provide initial support during the start-up process when the bubble is first formed. A prior art support system is illustrated schematically in Fig. 6.
Referring now to Fig. 6, a section of the bubble ~ ~$ ~ 36-CA-3431 19 is shown as extending from the ho-t air ring 18 to the bub~le shoulder 52. Directly above the hot air rlng there is a series of cylindrical roll means 5~ in circumferential and -transverse relationship to bubble 19. These rollers are usually of a non-metallic or soft material such as TeflonTM which lightly engage the bubble and are ro-tated by frictional engagement with the bubble. Usually four such rolls 5~ are employed. It has been discovered that the optimum advantages gained by the rotary apparatuses of this invention were being detrimentally affected by the ~; channelling and localizing of hot air flow from hot air ring 18 around the rolls.
Channelling and localizing of this hot air has been significantly reduced by the ball arrangement illus~
trated in Fig. 5. Referring again to Fig. 5, a frame assembly 55 is shown as attached to the lip asser~ly ~5 of ~;~ hot air ring 18. A plurality of circumferentially mounted brackets 56 support a circular ring or axle 57 which ` surrounds the stalk 15. Mounted for rotation on the ring is a series of about 30 Teflon balls 58 of about 1.0 inch diameter. The balls 58 are rotated by being in frictional engagement with tube 19 and because of their number and shape, they provide better distribution and equalization of the hot air from the hot air ring 18.
An improvement in film gauge is obtained through the use of this rotating air ring.
The rotating systern of this invention comprises ;~
three units i.e., (1) die and mandrel unit, (2) reheat oven unit of one or more ovens, and a (3) hot air ring unit (including the bubble support) which are preferably operated in unison and are synchronized with respect to speed and origin. The rotational speed of each of ~r~
- ` 36 CA 3431 the three uni-ts is adjusted to the same value a-t a common point in their rotation. The units the rotate at the same ;~ speed for 360 oE travel. At that point a suitable control such as a microswitch for each unit is tripped and the unit is caused to move 360 in the reverse direction ~ -wherein a further microswitch is tripped and the rotational cycle is then repeated.
The electrical circuit which interconnects ~; the three units is designed so that in the vent one of the units trips its mocroswitch prior to the tripping of the other switches, there will be a delay in operation until the other microswitches are tripped. Then all -~ three units~ béi~ the reverse cycle simultaneously. This arrangement provides sufficient although not precise synchronization.
It has been discovered that operation, i.e., oscillation of the rotary units of this invention without synchronization unexpectedly actually reinforces film gauge irregularities at various positions about the periphery of the bubble 19. Howev~r, oscillation even without synchronization provides more uniformity than would be - the case if none of the units oscillated. There are, however, various combinations of oscillations which may be used in the practice of this invention. Preferably a 360 max travel is employed to obtain better results.
In one practice of this invention a rotational speed of the rotating units may fall in the range of 4 to ~- 15 minutes per revolution. A speed of 6 minutes per :' revolution gave good results with polypropylene film and approximates 5 revolutions of the entire bubble for one bubble.
The practice of this invention provides enhanced ~
;,, ' _ g _ ,; .

,', , ' : ~
. . . .

~ 36 CA 3431 control over the many variables in the bubble process of manufacturing bia~ially oriented polypropylene film and improves the final product, particularly with respect to roll uniformity and flatness of the film as well as with respect to bag and camber. Thick and thin spots in a film strip as a result of gauge variations are very dettri-mental to electrical grade films used in capacitors. The improved process steps of this invention are directed to the rotation or oscillation of the noted three units to perform their simultaneous heat treating and smoothing functions circumferential of the moving stalk. Initially the die and mandrel rotates while the stalk does not rotate, but ;
moves axially from the die. Then the reheat ovens apply a uniform exposure to heat because of the rotating reheat ovens. And finally, a hot air ring provides uniform drafts of hot air circumferentially of the axially moving stalk.
All units must be carefully coaxially aligned to prevent hot spots.
The practitioner has a choice of changing the . ~
many process variables such as flow rate, resin temperature, die opening, etc., to change the quality of the final fil~m.
owever at the point where this invention starts these variables have been controlled to a very precise degree, and yet the minor variations which occur and which are indeed ~- small when viewed alone, build up rapidly on a more or less standard roll which may weight about 500 to 1000 lbs., be 4 to 7 feet wide and contain at least 60,000 ft. of film.
In some bubble processes of the non biaxially oriented kind, it has been known to rotate a die head or even the nip rolls and other upper components. The marked improvements of the present invention are obtained by the rotation of the ~;
; temperature related components of the process, i.e., die and cooling mandrel, reheat oven and hot air riny, and ;
their rotation and oscillation at predetermined rates.
The practice of this invention also provides a trouble indicator in the film making process. For example, in the prior process the major if not solely mechanically adjustable item was the die which was adjusted to provide a thicker or more unifrom thickness final film. When an irregularity occurrred in -the final film the die was usually adjusted to accommodate the irregularity wherever else it occurred in the system, usually in an unknown location. If, fox example, the irregularity occurred in the reheat oven, oscillation of the oven units could very well magnify -the problem or create a more serious problem with the other variables in the system. By the same token, oscillation of one variable not contributing to the problem could also magnify the problem if it were occurring later in -the cycle. sy the present invention, ,. ~
the operation is provided with selection menas whereby he may change one or more variables to flnd the variabIe which .: :
is causing a problem.
Many variations of the mounting and drivi~g means . , of this invention will become apparent to those skilled in the art~ All units may be separately mounted or mounted ~
for integral rotation. Several intermediate combinations are possible. Drive mean~s may follow the same format.
In prior biaxial film processes where a gauge non uniformity appeared, it became rolled up on itself over thousands of feet of film in a roll until a signifi-cant diameter difference is noted. After storage for only - 30 a short period of time, the creep characteristics of the film cause a set in the film such that upon unrolling there is a distinct uneveness in the film. When such a ' ~'' : - 11 -~ 36 CA 3431 roll is placed in a winding machiner there are various detrimental results, notably wrinkling of the film in the winding machine because the irregularity causes variation in ra-te of feed of the film from the lonyer or smaller roll diameter embodying the non uniformity. Where the film has a camber, because for example of a ridge in the roll diameter at one end of a roll, the straight feed on a winding machine causes wrinkling of the film being taken off -the roll.
The present invention is a unique defect handling and distributor arrangement. To some degree, because of its temperature effects it tends to ameliorate some film irregularities. To a greater extent, it distributes the irregularities throughout the film strip -or bubble surface. It operates in one respect to remove ; the registration effect of film irregularities in a roll and to distribute them laterally over a roll.
This distribution becomes even more important in film metallizing processes where a film web is passed through an evaucated and heated chamber wherein aluminum is vacuum deposited on the film. Wrinkling and bagginess ~ in the film is exceedingly difficult ~o handle in such - a process. The film of the present invention lays flat under these extreme conditions because of its unique non uniformity distribution structure.
For example, referring now to Fig. 7, there is ~ ;
schematically illustrated a partly unrolled section 59 of the film of the prior art. In the film section 59, the line 61 denotes a line of a non uniformity, for example an area of a thicker film. This area 61 is axial, i.e., in the machine direction and is wound up on itself. In Fig. 8 illus-trating the film section 60 of this invention, the same non uniformity now numbered 62 is distributed .

~ 36 CA 3431 laterally or, in effect, in both the machine direction : and cross machine direc-tion first in one CMD and then in the opposite C~D. Other irregularities are distributed laterally depending on the rotation and oscillation.
Oscillation of 180 provides a dis-tribution in CMD over one half the film width. A metallized layer 63 on this film strip represents an improved electrode and dielectric ~ .
; for capacitor use. It is characterized by having linear or series irregularities, non uniformity, or defects foll.owing a bias distribution pattern which has significant ~; lateral or diagonal directions extending over about one ~-; half or more of the film width in one CMD before reversing to provide a diagonal path in an opposite CMD. This film strip i.s much more stable when passing through a vacuum metallizer due to its reduced bagginess and camber ~:~
while being unwound, passed through the vacuum chamber . in an unsupported state and then being rewound. ~ ~:
~; While this invention has been disclosed wit~
respect to particular embodiments thereof, numerous modifications may be made by those skilled in the art ;~ without departing from its true spirit and scope.
; Therefore, it is intended that the appended claims cover all such modifications and variations which come within the true spirit and scope of the present invention.
' ' .

,: :
,,:

~"'~'

Claims (7)

The embodiments of the invention in which an exclu-sive property or privilege is claimed are defined as follows:

1. In a bubble apparatus for producing biaxially oriented synthetic resin film comprising an extruder to extrude molten resin in the form of a stalk, means to insufflate said stalk, and means to slit the insufflated stalk, the improvement comprising:
(a) an annular die for extruding molten resin in the form of a stalk, (b) mounting means mounting said die for rotation about its vertical axis independently of said extruder whereby resin from said extruder is extruded from said annular die as a non-rotating stalk, (c) a cylindrical cooling mandrel mounted coaxially with said annular die for rotation therewith whereby said non-rotating stalk slides axially and circumferentially over the rotating mandrel, (d) drive means for rotating said die and mandrel, (e) control means to control said drive means to rotate said die and mandrel, (f) a reheat oven coaxially positioned in said apparatus with respect to said stalk to receive said stalk from said die, (g) heating means to raise the temperature in said oven, (h) oven mounting means adapting said oven for rotation about the vertical axis of said die, (i) oven drive means for rotating said oven, (j) advancing means to advance said stalk through the rotating oven, and (k) oven control means to control said oven drive means to rotate said oven.

2. The apparatus of claim 1, further comprising:
(a) a hot air ring coaxially positioned in said apparatus with respect to said stalk next adjacent the point of insufflation, (b) said ring consisting of an annular chamber defining a hot air inlet and radially inwardly directed hot air exits, (c) ring mounting means adapting said ring for rotation about the vertical axis of said die whereby hot air from said hot air exits is directed against said stalk which is moving axially through said ring, (d) ring drive means for rotating said hot air ring, and (e) ring control means to control said ring drive means to rotate said hot air ring,

3. The apparatus of claim 2, wherein each of said mounting means adapts its corresponding device for independent rotation.

4. The apparatus of claim 2, wherein each of said control means controls its corresponding drive means independently.

5. The apparatus of claim 2, wherein:
(a) said hot air ring includes a stationary outer annular chamber wall and a rotatable inner annular chamber wall defining said radially inwardly directed hot air exits and closing said annular chamber, and (b) said ring mounting means adapts said inner wall for coaxial rotation with respect to said outer wall.

6. The apparatus of claim 2, further comprising:
(a) an annular bubble support ring surrounding said stalk above said hot air ring, (b) a circumferential row of small balls mounted on said annular bubble support ring for polar rotation with said bubble support ring as their axis of rotation, (c) said stalk frictionally engaging said balls to rotate said balls on their axis as said balls support said stalk, and (d) means mounting said bubble support ring for coaxial rotation with respect to said stalk.

7. The apparatus of claim 6, wherein said mounting means is said hot air ring.