CA1101579A - Flame-retardant flexibilized polyphenylene ether compositions - Google Patents
Flame-retardant flexibilized polyphenylene ether compositionsInfo
- Publication number
- CA1101579A CA1101579A CA292,795A CA292795A CA1101579A CA 1101579 A CA1101579 A CA 1101579A CA 292795 A CA292795 A CA 292795A CA 1101579 A CA1101579 A CA 1101579A
- Authority
- CA
- Canada
- Prior art keywords
- composition
- flame retardant
- parts
- aromatic phosphate
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 60
- 239000003063 flame retardant Substances 0.000 title claims abstract description 20
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims abstract description 18
- 229920001955 polyphenylene ether Polymers 0.000 title claims abstract description 17
- 229910019142 PO4 Inorganic materials 0.000 claims abstract description 28
- 125000003118 aryl group Chemical group 0.000 claims abstract description 27
- 239000010452 phosphate Substances 0.000 claims abstract description 27
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims abstract description 26
- -1 vinyl aromatic compound Chemical class 0.000 claims abstract description 17
- 229920001400 block copolymer Polymers 0.000 claims abstract description 14
- 239000004014 plasticizer Substances 0.000 claims abstract description 14
- 229920005989 resin Polymers 0.000 claims abstract description 14
- 239000011347 resin Substances 0.000 claims abstract description 14
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims abstract description 9
- 229920001169 thermoplastic Polymers 0.000 claims abstract description 9
- 229920002725 thermoplastic elastomer Polymers 0.000 claims abstract description 9
- 239000004416 thermosoftening plastic Substances 0.000 claims abstract description 9
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 7
- 150000004684 trihydrates Chemical class 0.000 claims abstract description 7
- 150000001993 dienes Chemical class 0.000 claims abstract description 6
- 229920002554 vinyl polymer Polymers 0.000 claims abstract description 5
- 150000008282 halocarbons Chemical class 0.000 claims abstract description 4
- 238000000465 moulding Methods 0.000 claims abstract description 4
- 229910052736 halogen Inorganic materials 0.000 claims description 7
- 150000002367 halogens Chemical class 0.000 claims description 7
- 125000004432 carbon atom Chemical group C* 0.000 claims description 5
- 125000005843 halogen group Chemical group 0.000 claims description 4
- 229910052760 oxygen Inorganic materials 0.000 claims description 4
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 4
- 229920000642 polymer Polymers 0.000 claims description 4
- 150000001875 compounds Chemical class 0.000 claims description 3
- 239000001301 oxygen Substances 0.000 claims description 3
- 239000012188 paraffin wax Substances 0.000 claims description 3
- XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical group C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 claims description 3
- 239000004215 Carbon black (E152) Substances 0.000 claims description 2
- 150000001555 benzenes Chemical class 0.000 claims description 2
- 229910052799 carbon Inorganic materials 0.000 claims description 2
- 229930195733 hydrocarbon Natural products 0.000 claims description 2
- 229910052739 hydrogen Inorganic materials 0.000 claims description 2
- 239000001257 hydrogen Substances 0.000 claims description 2
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims description 2
- 239000000306 component Substances 0.000 claims 12
- 239000012757 flame retardant agent Substances 0.000 claims 2
- GVLZQVREHWQBJN-UHFFFAOYSA-N 3,5-dimethyl-7-oxabicyclo[2.2.1]hepta-1,3,5-triene Chemical compound CC1=C(O2)C(C)=CC2=C1 GVLZQVREHWQBJN-UHFFFAOYSA-N 0.000 claims 1
- RREGISFBPQOLTM-UHFFFAOYSA-N alumane;trihydrate Chemical compound O.O.O.[AlH3] RREGISFBPQOLTM-UHFFFAOYSA-N 0.000 claims 1
- 125000005027 hydroxyaryl group Chemical group 0.000 claims 1
- 229920000468 styrene butadiene styrene block copolymer Polymers 0.000 claims 1
- 125000001424 substituent group Chemical group 0.000 claims 1
- 239000000178 monomer Substances 0.000 abstract 1
- 235000021317 phosphate Nutrition 0.000 description 16
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 8
- HIXDQWDOVZUNNA-UHFFFAOYSA-N 2-(3,4-dimethoxyphenyl)-5-hydroxy-7-methoxychromen-4-one Chemical compound C=1C(OC)=CC(O)=C(C(C=2)=O)C=1OC=2C1=CC=C(OC)C(OC)=C1 HIXDQWDOVZUNNA-UHFFFAOYSA-N 0.000 description 7
- 238000000034 method Methods 0.000 description 6
- 239000004793 Polystyrene Substances 0.000 description 5
- 229920001971 elastomer Polymers 0.000 description 5
- 229920002223 polystyrene Polymers 0.000 description 5
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- 239000001202 beta-cyclodextrine Substances 0.000 description 4
- 239000000806 elastomer Substances 0.000 description 3
- LIAWCKFOFPPVGF-UHFFFAOYSA-N 2-ethyladamantane Chemical compound C1C(C2)CC3CC1C(CC)C2C3 LIAWCKFOFPPVGF-UHFFFAOYSA-N 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- 239000013032 Hydrocarbon resin Substances 0.000 description 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- 229920002633 Kraton (polymer) Polymers 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 229920006270 hydrocarbon resin Polymers 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- PMJHHCWVYXUKFD-SNAWJCMRSA-N (E)-1,3-pentadiene Chemical compound C\C=C\C=C PMJHHCWVYXUKFD-SNAWJCMRSA-N 0.000 description 1
- YJTKZCDBKVTVBY-UHFFFAOYSA-N 1,3-Diphenylbenzene Chemical group C1=CC=CC=C1C1=CC=CC(C=2C=CC=CC=2)=C1 YJTKZCDBKVTVBY-UHFFFAOYSA-N 0.000 description 1
- WAEOXIOXMKNFLQ-UHFFFAOYSA-N 1-methyl-4-prop-2-enylbenzene Chemical group CC1=CC=C(CC=C)C=C1 WAEOXIOXMKNFLQ-UHFFFAOYSA-N 0.000 description 1
- IGGDKDTUCAWDAN-UHFFFAOYSA-N 1-vinylnaphthalene Chemical compound C1=CC=C2C(C=C)=CC=CC2=C1 IGGDKDTUCAWDAN-UHFFFAOYSA-N 0.000 description 1
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 description 1
- 241000735495 Erica <angiosperm> Species 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000003490 calendering Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 125000002524 organometallic group Chemical group 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- SONNWYBIRXJNDC-VIFPVBQESA-N phenylephrine Chemical class CNC[C@H](O)C1=CC=CC(O)=C1 SONNWYBIRXJNDC-VIFPVBQESA-N 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- PMJHHCWVYXUKFD-UHFFFAOYSA-N piperylene Natural products CC=CC=C PMJHHCWVYXUKFD-UHFFFAOYSA-N 0.000 description 1
- 229920000582 polyisocyanurate Polymers 0.000 description 1
- 239000011495 polyisocyanurate Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000012815 thermoplastic material Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/52—Phosphorus bound to oxygen only
- C08K5/521—Esters of phosphoric acids, e.g. of H3PO4
- C08K5/523—Esters of phosphoric acids, e.g. of H3PO4 with hydroxyaryl compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
- C08L71/08—Polyethers derived from hydroxy compounds or from their metallic derivatives
- C08L71/10—Polyethers derived from hydroxy compounds or from their metallic derivatives from phenols
- C08L71/12—Polyphenylene oxides
- C08L71/123—Polyphenylene oxides not modified by chemical after-treatment
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US75273176A | 1976-12-21 | 1976-12-21 | |
| US752,731 | 1976-12-21 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1101579A true CA1101579A (en) | 1981-05-19 |
Family
ID=25027573
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA292,795A Expired CA1101579A (en) | 1976-12-21 | 1977-12-09 | Flame-retardant flexibilized polyphenylene ether compositions |
Country Status (11)
| Country | Link |
|---|---|
| JP (1) | JPS5379945A (OSRAM) |
| AU (1) | AU517478B2 (OSRAM) |
| BR (1) | BR7708512A (OSRAM) |
| CA (1) | CA1101579A (OSRAM) |
| DD (1) | DD134538A5 (OSRAM) |
| DE (1) | DE2751496C2 (OSRAM) |
| FR (1) | FR2375293A1 (OSRAM) |
| GB (1) | GB1575457A (OSRAM) |
| IT (1) | IT1088919B (OSRAM) |
| MX (1) | MX146037A (OSRAM) |
| NL (1) | NL7713133A (OSRAM) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2752383A1 (de) * | 1976-12-28 | 1978-06-29 | Gen Electric | Plastizierte verstaerkte zusammensetzungen aus einem polyphenylenaetherharz |
| JPS55500472A (OSRAM) * | 1978-06-02 | 1980-07-31 | ||
| BR8105866A (pt) * | 1980-01-14 | 1981-11-24 | Gen Electric | Misturas plastificantes de polifenileno aperfeicoadas |
| NL8301569A (nl) * | 1983-05-04 | 1984-12-03 | Gen Electric | Polymeermengsel met vlamwerende eigenschappen, geschikt voor draadmantelextrusie, op basis van polyfenyleenoxyde en elektrisch geleidende draad. |
| DE3628577A1 (de) * | 1986-08-22 | 1988-03-03 | Basf Ag | Halogenfreie, selbstverloeschende, schlagfeste, thermoplastische formmasse |
| EP0389837A1 (en) * | 1989-03-07 | 1990-10-03 | Mitsubishi Cable Industries, Ltd. | Phenylene oxide polymer composition |
| US5118748A (en) * | 1989-03-07 | 1992-06-02 | Mitsubishi Cable Industries Ltd. | Phenylene oxide polymer composition |
| GB9119795D0 (en) * | 1991-09-17 | 1991-10-30 | Albright & Wilson | Flame retardant plastics material |
| JPH08134346A (ja) * | 1994-11-14 | 1996-05-28 | Sumitomo Chem Co Ltd | ポリフェニレンエーテル系樹脂組成物 |
| US6797754B2 (en) | 2002-05-06 | 2004-09-28 | Cheil Industries Inc. | Flame retardant styrenic compositions containing oxaphospholane compound as flame retardant |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3663654A (en) * | 1969-02-24 | 1972-05-16 | Gen Electric | Flame retardant composition of polyphenylene ether,styrene resin and phosphorus |
| US3660531A (en) * | 1969-06-04 | 1972-05-02 | Uniroyal Inc | Thermoplastic resin blend of polyphenylene oxide with butadiene-containing polymers |
| IT969424B (it) * | 1971-09-09 | 1974-03-30 | Sumitomo Co Ltd | Composizione di ossido polifenile nico modificato in particolare a propagazione di fiamma ritardata |
| DE2434848C2 (de) * | 1973-08-13 | 1986-09-04 | General Electric Co., Schenectady, N.Y. | Thermoplastische Masse |
-
1977
- 1977-11-18 DE DE2751496A patent/DE2751496C2/de not_active Expired - Lifetime
- 1977-11-29 NL NL7713133A patent/NL7713133A/xx not_active Application Discontinuation
- 1977-12-08 FR FR7737039A patent/FR2375293A1/fr active Granted
- 1977-12-09 CA CA292,795A patent/CA1101579A/en not_active Expired
- 1977-12-14 GB GB51974/77A patent/GB1575457A/en not_active Expired
- 1977-12-15 IT IT30749/77A patent/IT1088919B/it active
- 1977-12-16 MX MX171785A patent/MX146037A/es unknown
- 1977-12-19 JP JP15281877A patent/JPS5379945A/ja active Pending
- 1977-12-19 DD DD77202763A patent/DD134538A5/xx unknown
- 1977-12-20 BR BR7708512A patent/BR7708512A/pt unknown
- 1977-12-20 AU AU31792/77A patent/AU517478B2/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| DD134538A5 (de) | 1979-03-07 |
| BR7708512A (pt) | 1978-08-22 |
| JPS5379945A (en) | 1978-07-14 |
| IT1088919B (it) | 1985-06-10 |
| DE2751496A1 (de) | 1978-06-22 |
| MX146037A (es) | 1982-05-04 |
| AU3179277A (en) | 1979-06-28 |
| FR2375293B1 (OSRAM) | 1984-09-07 |
| NL7713133A (nl) | 1978-06-23 |
| AU517478B2 (en) | 1981-08-06 |
| DE2751496C2 (de) | 1994-09-22 |
| GB1575457A (en) | 1980-09-24 |
| FR2375293A1 (fr) | 1978-07-21 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKEX | Expiry |