CA1100903A - Electrofiltration system for purifying organic liquids - Google Patents
Electrofiltration system for purifying organic liquidsInfo
- Publication number
- CA1100903A CA1100903A CA346,790A CA346790A CA1100903A CA 1100903 A CA1100903 A CA 1100903A CA 346790 A CA346790 A CA 346790A CA 1100903 A CA1100903 A CA 1100903A
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- solids
- edible oil
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- particles
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Abstract
ELECTROFILTRATION SYSTEM FOR PURIFYING ORGANIC LIQUIDS
ABSTRACT OF THE DISCLOSURE
Non-petroleum organic liquids (fats, animal and vegetable oils, etc.) containing solids (e.g., hydrogenation catalysts) are purified within a unique electrofiltration system wherein the organic liquids are passed through a selected bed material in which is established an intense electric field for removing the solids. Upon solids-fillup of the bed, selectively cleaning restores the bed for continued purifica-tion of the organic liquid stream. The purified organic liquid stream is monitored for indicating when the selective cleaning of the bed is required. The electrofiltration system, both in a novel electofilter and process, produces without aging a new organic liquid product having comparable properties to multistep processed prior art organic liquid.
ABSTRACT OF THE DISCLOSURE
Non-petroleum organic liquids (fats, animal and vegetable oils, etc.) containing solids (e.g., hydrogenation catalysts) are purified within a unique electrofiltration system wherein the organic liquids are passed through a selected bed material in which is established an intense electric field for removing the solids. Upon solids-fillup of the bed, selectively cleaning restores the bed for continued purifica-tion of the organic liquid stream. The purified organic liquid stream is monitored for indicating when the selective cleaning of the bed is required. The electrofiltration system, both in a novel electofilter and process, produces without aging a new organic liquid product having comparable properties to multistep processed prior art organic liquid.
Description
1~ )3 BACKGROUND OF THE INVENTION
1. Field of the ~nvention This invention related to the removal of solids from an organic liquid by using electrical fields. The invention more particularly rela-tes to the removal from organic liquids of solids by their induced adherence upon a particulate bed under the action oE d.c. electrical fields.
1. Field of the ~nvention This invention related to the removal of solids from an organic liquid by using electrical fields. The invention more particularly rela-tes to the removal from organic liquids of solids by their induced adherence upon a particulate bed under the action oE d.c. electrical fields.
2. Description oE the Prior Art Non--petroleum organic liquids include fats, vegetable and animal oils which may be used for human consumption~ but are no-t necessarily limited to such utilization. These organic li~uids can be purified by removing solids to improve chemical properties, color and ~.
visual appearance, and for other reasons. In one example, the hydrogenation of edible oils for preparing more suitable products.for human consumption has been known for nearly one hundred years. The modern hydrogenation process for edible oils originated in research work conducted at the turn of this century. In this process, the edible oils, such as cottonseed, soybean, and corn oil, are placed within a reaction vessel (commonly termed a "converter") and brought into contact with hydrogen at elevated temperature and pressure in the presence of a small amount of metal hydrogenation catalyst.
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, .. ..
~O~gO3 For example, the catalyst is usually present in s~all amounts which may range ~ro~l .01% to about 0.5% by wei~ht based upon the total weight of the edible oils subjected to h~drogenation.
Various types of hydrogenation catalysts, such as copper chromite, are known for providiny the reaction between hydrogen and the edible oil. For example, one commercial hydrogenation catalyst includes the metal nicke:l as the principal catalytic agent, but it also may have minor amounts of copper, alumina, or other materials. The metal hydrogenation catalysts are employed principally in a finely deEined divided form and are prepared by special methods. Commonly, the nickel me-tal is placed upon a finely divided, highly porous, inert refractory material, such as diatomaceous earth, or other highly siliceous material. The cat~lys-t is suspended in the edible oils during the hydrogenation process as oil-coated insert solids, which may adsorb soaps or other impurities found in the oil. After the hydrogenation reaction is completed to the desired degree, ~he hydrogenation reaction materials are removed from the converter. Then, these materials are passed through a filtration system for removing the inorganic solids from the hydrGgenated edible oil product.
Various inorganic materials are added to the hydrogenated edible oil product to enhance its filterability.
Filteraids usually are employed to promote the product filtration procedure. Various types of relatively so~histicated and expensive filtration equipment are employed. Generally, pressurized filter press assemblies are used, in parallel flow arrangements, to pass the product through a multitude of filter elements which may comprise screen supports carrying ~,~, ~ .
- .x bm:'~
1)9~3 paper, canvas or other types of filter medium. These filter elements may be precoa-ted with some type of diatomaceous earth or filteraid to improve oil ~ilterabili-ty. The hydrogenated edible oil pro~uct is passed through these filters to remove as much as possible of the hydrogenation catalyst material and other inorganic solids materials. However, the fllters canno-t remove substantially all of the inorganlc solids. ~dditionally~
the filters pass decreasin~ amounts of inorc~anic solids as the filtration procedure progresses to~ards an ultimate removal level.
~ he edible oil industry employs two basic tests to determine the effectiveness of filtration on a hydrogenated edible oil product. In one test, a pound of the edible oil is passed through a filter disc at regulated physical conditions of temperature and time. The filter disc retains impurities above a certain size magnitude leaving a "dark spot" which is compared to a standard set of filter discs The test is known as the 'IFilter Disc Impurities Test"~ The standard discs are numbered 1 through 10, with number 10 being that disc which shows no change in "color" over the unused filter disc. Another test is the analysis of the edible oil for nickel content. The filtration procedure produces an edible oil with from one to several parts per million (ppm) of nickel content For consumer acceptance and long term storage and other reasons, the nickel content is preferred to be iess than 1 ppm of nickel.
Mechanical filtra-tion equipment employed in the edible oil industry usually passes some solids during the filtration procedure. As an example, the edible oil product has a color of relatively low value, e.g., ~ at the beginning of filtration~
bm~
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,: ~ .. .
,, ~ : ., , .. ~:
- : , : . -9~3 but then its color test rapidly improves towards a filter disc color of 9 or better. For this reason, the fil-ter equipmen-t cannot produce throughout the edible oil filterecl product a ~ilter disc color of 9 or be-tter.
The filtered edible o:il, a-t eleva-ted -temperatures, is subjected to additional treating steps which may include treatment with bleaching earth, phosphoric or citric acid or other metal scavengersr with the addition oE fll-teraids, so that the finely divlded resldual inorganic catalyst and other solids are removed. The edlble oil accep-ted by consumers must have a color of ~ or better. Thus~ filtration or o-ther color improvement procedures are employed with each edible oil subjected to the hydrogenation. Substantial time elapses in these procedures and subjects the edible oils to aging. The procedures are practiced until the edible oil has a filter disc color of 9 or better~ and residual hydrogenation catalyst sblids, and possibly colloidal nickel metal, is at an acceptable low value Nearly forty years ago, it was purposed to purify edible oils by adding a small amount of a loader-type solids, such as "10% activated clay" in a finely divided admixture to the edible oil This mixture was then flowed horizon-tally in a zigzag path between closely spaced electrodes which were energized to elevated potentials~ The impurities and the loader solids were to migrate to one or the o-ther electrodes for -their removal from the edible oil Accumulated solids might "drop off"
after reaching a certain thickness on the electrodes or they could be removed by interrupting or reversing the current.
Mechanical removal of the solids from the electrodes could ~ I .
4 bm~
~o9v~
also be used. Unfortunately, the unpacked dielectric zone between the electrodes will not remove substantially all of the impurities from the edible oil. One reason for this result may be that the elec-tric field cannot be made o:E sufficient intensity even with closely spaced electrodes that substantially all of the inorganic solids could be removed from the edible oils, Some solids pass through the spaces between the electrodes without being attracted to them Eor removal from the edible oil, It has been proposed :Eor nearly as many years to employ electro~iltration systems for removing inorgan:ic and organic solids from dielectric natural and petroleum oils.
For this purpose, the dielectric oil carrying the solids is passed through a particulate material within an elevated d.c~
electric potential field. The d c. field can have potentials of between 5 to 200 kilovolts established across the bed. The bed might be composed of particles of materials such as furnace slag, sand, gravel, limestone, crushed glass, glass bead, ceramics palletized clay, and like solid materials. Various types of electroae arrangements have been advocated for providing the high voltage d.c electrical field for these electrofilter aevices~ The electrofilter devices, which have been known in the past, have been highly effective for removing inorganic :~
solids from dielectric liquids such as the hydrocarbon products of cruae oil refining~ Unfortunately, these electrofilters are very effective in attracting solids to the particulate bed materials. These removed solids adhere very strongly to the bed material even with the d.c. electric field remove~ from the electrofilter device. Once the bed is subject to a solids-fillup, substantial changes in electrical conductivity occur which induce -S-bm~
.: - .. ~ . .
. -, ~ . -~Q L)~3~)3 arcing in many instances, Arcing can produce a sudden releaseof solids into the dielectric liquid! Then, the bed must be cleaned before being reused.
The tenacious adherence of inorganic solids upon the particulate bed of electrofilters has required special techniques for regeneration, Example may be taken to U.S. Pa-ten-ts 3,39~067,
visual appearance, and for other reasons. In one example, the hydrogenation of edible oils for preparing more suitable products.for human consumption has been known for nearly one hundred years. The modern hydrogenation process for edible oils originated in research work conducted at the turn of this century. In this process, the edible oils, such as cottonseed, soybean, and corn oil, are placed within a reaction vessel (commonly termed a "converter") and brought into contact with hydrogen at elevated temperature and pressure in the presence of a small amount of metal hydrogenation catalyst.
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; . .; ,. ;, , :- , . : .~ :. - . ~, ., . : ~ .
, .. ..
~O~gO3 For example, the catalyst is usually present in s~all amounts which may range ~ro~l .01% to about 0.5% by wei~ht based upon the total weight of the edible oils subjected to h~drogenation.
Various types of hydrogenation catalysts, such as copper chromite, are known for providiny the reaction between hydrogen and the edible oil. For example, one commercial hydrogenation catalyst includes the metal nicke:l as the principal catalytic agent, but it also may have minor amounts of copper, alumina, or other materials. The metal hydrogenation catalysts are employed principally in a finely deEined divided form and are prepared by special methods. Commonly, the nickel me-tal is placed upon a finely divided, highly porous, inert refractory material, such as diatomaceous earth, or other highly siliceous material. The cat~lys-t is suspended in the edible oils during the hydrogenation process as oil-coated insert solids, which may adsorb soaps or other impurities found in the oil. After the hydrogenation reaction is completed to the desired degree, ~he hydrogenation reaction materials are removed from the converter. Then, these materials are passed through a filtration system for removing the inorganic solids from the hydrGgenated edible oil product.
Various inorganic materials are added to the hydrogenated edible oil product to enhance its filterability.
Filteraids usually are employed to promote the product filtration procedure. Various types of relatively so~histicated and expensive filtration equipment are employed. Generally, pressurized filter press assemblies are used, in parallel flow arrangements, to pass the product through a multitude of filter elements which may comprise screen supports carrying ~,~, ~ .
- .x bm:'~
1)9~3 paper, canvas or other types of filter medium. These filter elements may be precoa-ted with some type of diatomaceous earth or filteraid to improve oil ~ilterabili-ty. The hydrogenated edible oil pro~uct is passed through these filters to remove as much as possible of the hydrogenation catalyst material and other inorganic solids materials. However, the fllters canno-t remove substantially all of the inorganlc solids. ~dditionally~
the filters pass decreasin~ amounts of inorc~anic solids as the filtration procedure progresses to~ards an ultimate removal level.
~ he edible oil industry employs two basic tests to determine the effectiveness of filtration on a hydrogenated edible oil product. In one test, a pound of the edible oil is passed through a filter disc at regulated physical conditions of temperature and time. The filter disc retains impurities above a certain size magnitude leaving a "dark spot" which is compared to a standard set of filter discs The test is known as the 'IFilter Disc Impurities Test"~ The standard discs are numbered 1 through 10, with number 10 being that disc which shows no change in "color" over the unused filter disc. Another test is the analysis of the edible oil for nickel content. The filtration procedure produces an edible oil with from one to several parts per million (ppm) of nickel content For consumer acceptance and long term storage and other reasons, the nickel content is preferred to be iess than 1 ppm of nickel.
Mechanical filtra-tion equipment employed in the edible oil industry usually passes some solids during the filtration procedure. As an example, the edible oil product has a color of relatively low value, e.g., ~ at the beginning of filtration~
bm~
.- ~
,: ~ .. .
,, ~ : ., , .. ~:
- : , : . -9~3 but then its color test rapidly improves towards a filter disc color of 9 or better. For this reason, the fil-ter equipmen-t cannot produce throughout the edible oil filterecl product a ~ilter disc color of 9 or be-tter.
The filtered edible o:il, a-t eleva-ted -temperatures, is subjected to additional treating steps which may include treatment with bleaching earth, phosphoric or citric acid or other metal scavengersr with the addition oE fll-teraids, so that the finely divlded resldual inorganic catalyst and other solids are removed. The edlble oil accep-ted by consumers must have a color of ~ or better. Thus~ filtration or o-ther color improvement procedures are employed with each edible oil subjected to the hydrogenation. Substantial time elapses in these procedures and subjects the edible oils to aging. The procedures are practiced until the edible oil has a filter disc color of 9 or better~ and residual hydrogenation catalyst sblids, and possibly colloidal nickel metal, is at an acceptable low value Nearly forty years ago, it was purposed to purify edible oils by adding a small amount of a loader-type solids, such as "10% activated clay" in a finely divided admixture to the edible oil This mixture was then flowed horizon-tally in a zigzag path between closely spaced electrodes which were energized to elevated potentials~ The impurities and the loader solids were to migrate to one or the o-ther electrodes for -their removal from the edible oil Accumulated solids might "drop off"
after reaching a certain thickness on the electrodes or they could be removed by interrupting or reversing the current.
Mechanical removal of the solids from the electrodes could ~ I .
4 bm~
~o9v~
also be used. Unfortunately, the unpacked dielectric zone between the electrodes will not remove substantially all of the impurities from the edible oil. One reason for this result may be that the elec-tric field cannot be made o:E sufficient intensity even with closely spaced electrodes that substantially all of the inorganic solids could be removed from the edible oils, Some solids pass through the spaces between the electrodes without being attracted to them Eor removal from the edible oil, It has been proposed :Eor nearly as many years to employ electro~iltration systems for removing inorgan:ic and organic solids from dielectric natural and petroleum oils.
For this purpose, the dielectric oil carrying the solids is passed through a particulate material within an elevated d.c~
electric potential field. The d c. field can have potentials of between 5 to 200 kilovolts established across the bed. The bed might be composed of particles of materials such as furnace slag, sand, gravel, limestone, crushed glass, glass bead, ceramics palletized clay, and like solid materials. Various types of electroae arrangements have been advocated for providing the high voltage d.c electrical field for these electrofilter aevices~ The electrofilter devices, which have been known in the past, have been highly effective for removing inorganic :~
solids from dielectric liquids such as the hydrocarbon products of cruae oil refining~ Unfortunately, these electrofilters are very effective in attracting solids to the particulate bed materials. These removed solids adhere very strongly to the bed material even with the d.c. electric field remove~ from the electrofilter device. Once the bed is subject to a solids-fillup, substantial changes in electrical conductivity occur which induce -S-bm~
.: - .. ~ . .
. -, ~ . -~Q L)~3~)3 arcing in many instances, Arcing can produce a sudden releaseof solids into the dielectric liquid! Then, the bed must be cleaned before being reused.
The tenacious adherence of inorganic solids upon the particulate bed of electrofilters has required special techniques for regeneration, Example may be taken to U.S. Pa-ten-ts 3,39~067,
3,799,855, 3,799,856, and 3~799,~57 for illustrat:Lons of various types of practical and commercial bed cleanup systems. These patents describe cleanup procedures which produced a very hiyh mechanical agita-tion between the particles of the electrofilter bed for mechanically removing adhering inorganic solids.
Naturally, high levels of mechanical contact between these particles cause abrasion and could result in a small amount of abraded particle material being released from the bed, As a result, the bed would hav`e to be scrupulously cleaned of the small fragmented portions of the particulate material unless these residues were not critical to the dielec-tric liquid being treated. In the electrofiltration purification of hydrocarbon materials, such as distillates and residual streams or inorganic materials, a small amount of residue from abraded particulate bed material would not be a problem, However, these abraded materials are intolerable in edible oils, The prior art has included proposals to employ electrofiltration for purification of various types of dielectric organic liquids for about four decades~ However, no electrofilter device has produced the purfication of organic liquids which contain finely-divided inorganic and organic solids for several impor-tant reasons. In the first instance, the electrofilter equipment must eEfect complete removal from solids without either an unaccep-table pressure buildup or deleterious ~- I
bm~
~ . , . . . ~ . - . ;
)3 change in electrical characteristics inducing arcing, shor-ting and like problems. In the second instance, the electrofilter must be capable of h~ndlin~ effectively the organic liquid stream containlng widely varying amoun-ts of solids. In -the third instance, the electrofilter system must contain a particulate bed material of special characteris-tics so tha-t (1 the organic liquid product is produced with extremely low amount of residual solids, without undue pressure buildup or arcing, (2) the particula-te bed material is readily cleaned of adhering solids/ and ~3) no abrasion or loss of the particula-te bed material itself occurs to contaminate the organic liquid.
The foregoing reasons summarize the incapability of prior art electrofiltration system in being used in the purification of organic liquids containing finely divided solids, The present invention is an electrofiltration system for purifying organic liquids by removal of finely-divided solids without the foregoing recited problems of prior art electrofilters~-In particular, the present invention is a novel electrofilter, electrofiltration process, and organic liquid product. A
selected material in the bed of the electrofilter system produces a substantially complete removal of the solids, irrespective of the solids loading content, and without the electrofilter system having any appreciable pressure buildup or electrical arcing in the bed. The bed is chemically inert, and no contamination of the organic liquid stream occurs in use. The cleaning of the bed of accumulated soIids is not complicated and produces an environment for continuous and repeated elec~^ofiltration for producing a product organic liquid equal in physical and chemical charac-teristics to ccmmercial product prepQred by extended time! multistep p~ocedures Additional fea-tures -of the present invention will be appreciated from the-following description.
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39(~3 SUM~IARY OF THE INVENTION
In accordance with this invention, there is provided an electrofiltration system, including apparatus, process, and product, for the purification of an organic liquid stream of high resistivity. In particular, the organic liquid gtream~
at suitablP temperature, is passed through a chemically inert bed having multitudinous flow channels between rigid masses of a solid material having a dielectric constant not in excess of about 7. A d.c. electric field within the bed provides a sufficient intensity for removing solids from the organic liquid stream by the electrically induced adhesion oE the solids on the material to provide a purified organic liquid stream removed to a subsequent utilization. The bed material, at least in part, is selectively cleaned of adhering solids by interruption of the electrical field, passing a cleaning fluid through the material to remove adhering solids, and then removing the fluid with the removed solids from the material being cleaned.
In a preferred embodiment, the purified organic liquid stream is monitored to provide an indicating signal when to undertake the selective cleaning of the bed material. The purified organic liquid stream is a novel product, quickly prepared - without aging, and having comparable chemical and physical properties to conventional multistep treated commercial product.
In one particular aspect the present application, which is a division of copending Canadian Application No. 266,570, filed November 25, 1976, is concerned with the provision of an electrofiltration process for removing hydrogenation catalyst - and other undissolved solids from a stream of edible oil which ~ has been subjected to catalytic hydrogenation,-&~ process comprising:
j 1/ ~` `` --8-.: . : : . :: ~- -(a) providing the stream of so hydrogenat~d edible oil at a sufficient temperature that organic solids such as stearine are in solution and cannot plug an electrofilter bed adapted to remo~e the undissolved solids carried therein;
~b) passing said stream of oil through a chemically inert bed having multitudinous flow channels between rigid masses of a solid material having a dielectric constant not in excess of about 7;
(c) establishing a d.c. electrical Eield within said bed havlng an intensity sufEicient of removing the undissolved solids from said stream of oil by electrically induced adhesion of the solids in said bed material;
(d) removing the purified oil stream with reduced undissolved solids content from said bed; and (e) cleaning at selected intervals at least a portion of said material of adhering solids by interruption of said r o, u ~ ~ ~ h ~ J Q /
electrical field~ passing a cleaning fluid~to remove adhering solids from said material and removing the fluid with the removed solids from said material. ' In another particular aspect the present application, which is a division of copending Canadian Application No. 266,570, filed November 25, 1976, is concerned with the provision of an electrofiltration process for removing solids from an organic liquid stream comprising:
~a) passing said liquid stream through a bed of chemically inert, hard granular particles of a rigid, substantially incompressible material, said particles being non-spheroidal with a relatively discontinuous surface configuration and a dielectric constant not in excess of about 7;
~ 8a-- . :, . . .
09~3 (b) establishing a d.c. electrical field within said bed haviny an intensi,ty sufficient for removing the solids from the organic liquid stream by electrically incluced adhesion of t.he solids on said particles;
(c) removing the purifled'organic liquid stream with reduced solids content from saicl bed; and (d) cleaning at selected intervals at least a portion of said particles of adhe~ing solids by interruptincJ said electrical field, passing a cleaning fluid through the bed to remove adhe.rin~ solids from said particles and re~loving the fluid with the removed solids from.said particles being clearled.
In a further particular aspect the present application, which is a divisional of copending Canadian Application No.
266,570, filed November 25, 1976, is concerned with the provislon of an electrofi,ltration process for removing hydrogenation catalyst and other undissolved solids from a stream of edible oil which has been subjected to catalytic hydrogenation, said process comprising:
(a) providing the stream of so hydrogenated edible oil at a sufficient temperature that organic solids such as ~ 8b-bm~
. . : , :, , ~
,. : -. :; .: . .
~0~03 stearine are in solution and cannot plug an electrofilter bed adapted to remove the undissolved solids carried therein;
(b) passing said stream of oil through a chemically inert bed having multitudinous flow channels between rigid masses of a solid material having a dlelectric constant not in excess of about 7;
~ c) establishing a d.c~ electrical field within said bed having an intensity suficient for removing the undissolved solids from said stream oE oil by electrically induced adhesion of the solids in said bed material; and (d) xemoving the purified oil stream with reduced undissolved solids content from said bed.
DESCRIPTION OF THE DRAWINGS
Figure 1 is a diagrammatical illustration, in flow schematic, of the present electrofilter system applied to a prior art -8c-bm~
'~
~0()903 hydrogenation plant for producing edible oil as an exarnple of an organic liquid;
Figure 2 is a vertical cross-section illustrating the construction of the electrofilter sho~n in the system of Figure l; and jl/,'`l-, -8d-:.::., ., : .
. -: ~ , , ,;
: . :: .::
' :. :- ' :~' ' - :
)9~3 Figure 3 is a graphic comparison of several bed materials employea in the electrofilter of Figure 1 and a typical mechanical filtration relative to the Eilter disc impurities color of an edible oil puri.fied in the present electrofiltration system~
D~SCRIPTION OF SP~CIFIC EMBODIMENTS
The present electro~il-ter system will he described in the purification of one type oE organic liquid, namely, an edible oil. However, it will be apprecia-ted -that the invention is equally applicable and o:E utili-ty with other -types of organic liquids, e~g~, fa-ts, animal and veyetable ~A
oils. Referring now to Figure l, there is shown an embodiment of the present electrofilter system associated with an appropriate portion of a prior art hydrogenation plant, wherein edible oils are contacted with hydrogen at elevated tempera-ture and pressure in the presence of a finely-divided catalytic - material~ More particularly, the hydrogenation plant is enclosed within the chainline 12 with the designation of prior art being applied as an example o-f commercial operations~
An edible oil, such as soybean oil, is brought from storage through an inlet conduit 13 and a heat exchanger 14 directly into the hydrogenation converter 16. The hea-t exchanger 14 - raises the temperature of the edible oil to a suitable level, e.g., above 250 F. The converter 16 is a steel vessel usually with an upright axis which contains the charge of edible oil to be hydrogenated~ The edible oil in the converter is admixed with a suitable amount of metal catalyst.
In most instances, a dia-tomaceous earth or a filteraid material is intermixed with the catalyst iTI suitable bm~
.:
- . , ' :
.
:
~0~)9~3 proportions with an edible oil carrier in the catalyst mix tank 17. Then, this mixture is displaced by pump 18 through a control valve 19 into the converter 16. The converter 16 usually has an internal mixer arrangement for maintaining a suspension o:E the catalyst materials within the edible oil. Hydrogen is added to the converter 16. The hydrogenation reaction ta~es place over a suitable length of time, such as one hour, depending upon the mass of edible oil charge and the des:ired hydrogenation degree to be produced in t~e edible oil product, The converter 16 may be of any suitable size. For description, the converter 16 will receive an edible oil charge of about 40,000 pounds, and the hydrogenation catalyst material is of the nickel metal variety, which is introduced to a suitable concentration of between ~01 and ,5 percent by weight. The nickel catalyst is approximately 25% by weight of nickel with the remainder being Kieselguhr or other diatomaceous earth material, After the hydrogenation reaction is completed~ the contents of the converter 16 are moved through the valve 21 into a drop tank 22 where the hydrogenated edible oil product is held while being.processed for the removal of the finely-divided hydrogenation catalyst and other inorganic solids.
Presently, the contents of the drop tank 22 are moved through a control valve 23 by centrifugal pump 24~ an optional heat exchanger 26, and through a piping loop con-taining several control valves to the inlet 27 of the filter press 28.
The filter press is conventional with a plurality of filter elements, The filtered edible oil is removed from the filter bm:
, ~ ;. . -... .
~00903 press 2~ throu~h the outlets 29 or 31 dependlng upon whether the sections are operated in parallel or in separate sections. The outlets 2~ and 31 connect to a filtere* edible oil line 32 for directing this stream to subsequent processing for the removal of res.idual amounts of the hydrogenation catalyst and other inorganic solids.
For example, the filtered edible oil in the line 32 may contain about several parts per million of nickel metal (suspended and colloidal) so as to have a pronounced green-to-black colo.r, and several parts per million of lnorganic solids, such as filteraid, and a filter disc color of 6 or worse. Thus, the filter press 2~ cannot produce an acceptable edible oil product that could be used for human consumption The filtered edible oil in line 32 now usually is subjected to additional processing steps. One step is treatment with citric acid or phosphoric acid and a filteraid material, and filtration to remove the chelated hydrogenation catalyst.
Another step is a bleaching operation wherein a small amount of bleaching clay is added to the edible oil, and then filtered to provide the edible oil product. The edible oil product after one or more of these steps is an edible oil product directly suitable for consumer use Sometimes, this product is subjected also to a winterizing and/or deodorizing step to produce certain types of edible oils.
In the present invention, all mechanical filtration steps are avoided. The hydrogenated edible oil in the drop tank 22 is passed through the novel electrofilter system of the present invention . Referring specifically to that portion of Figure 1 outside the chainline 12, the edible oil from the bm:~
- : . -. ~
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. .
drop tank 22 is diverted through the block valve 33 in-to a raw oil line 34. The edible oil in the line 34, by use of the heat ex~hanger 26, is adjus-ted in temperature, usually above 150 F., so that organic solids, such as stearine, are in total solution in the edible oil stream and cannot plug the electrofilter. The line 34 connects in-to an inlet manifold 36 associated with the electroE~ ter 37. The manifold 36 h~s a plurality o~ motor control valves 35, 38, and 39, whose functions will be hereinafter described. With this arrangement o~ the inlet mani~old 36, the edible oil is passed upwardly through the electrofilter 37 and removed through the outlet manifold 42 which includes motor control valves 43 and 44. However~ it may be desired to have the edible oil passed downwardly through the electrofilter 37 and the-functions of the inlet and outlet manifolds would then be reversed. The piping for the present system is arranged for this purpose as will be appreciated by examination of the respective manifolds and their connections in-to the system shown in Figure 1, - The electrofilter 37 is arranged so that substantially all of the solids, including the hydrogenation catalyst, filteraid, dia-tomaceous earth, etc., and any insoluble organic solids, are removed from the edible oil stream The electrofilter 37 has a selected bed forming an inner electrode space subjected to a high intensity d.c. electric field for removing substantially all of these solids from the edible oil. The purified edible oil stream is removed through a product line 46 and a three-way control valve 47 into an edible oil product conduit 48 for removal to a subsequent bm:
- : . . .. :
.... , ,~ . , : - ~
, . ~ .; . . , ,:
~iO0~(~3 utilization~ Preferably, the edible oil product line ~6 includes a moni~or of the purified edible oil product ~rom the electrofilter 37 to detexmine the approach of a suddenly increased solids content which occurs on the approach of solids-fillup in the bed of the electrofilter 37.
The present invention involves the selection of a certain type of material :Eormin~ -the bed o~ the electro-filter 37. The bed is chemically inert and has multitudinou.s flow channels between rigid masses of a solid material. The bcd material should havc a dielec-tric constant no-t in excess of about 7. The bed material should have sufficient rigidity so that in operation it cannot be compressed in a degree to reduce the flow channels, thereby producing an unacceptable pressure drop across the bed.
One of the cha.racteristics of the electrofil-ter 37 with this selected bed is that substan-tially all of the solids, including even colloidal nickel and filteraid materials, are removed .rom all the edible oil passing into the product line ~6, and this purity is maintained until the bed has accumulated its capacit~ of removed solids as the solids-fillup condition :~
is approached. As this solids-fillup condition is approached - in the bed of the electrofilter 37~ no significant changes occur in the electrical parameters or measurable physical operation conditions concerning the electrofilter~ However, there is a sudden increase in the solids content of the trea~ed edible oil. More particulaxly, -the pressure drop across the eletrof.ilter 37 is small and does not change within -the measurement error of conventional pressure gauges. In addition, no significant change in electrical parame-ters, voltage or ~r 1 3 ! bm:~
. , : ' , ~ .
~1~0~(~3 current, occurs in the high vol~age el~c-tric field imposed upon the bed within the electrofilter 37~ These phenomena of the electrofil-ter 37 are more appar~nt from -the following discussion of the preferred design and operation of ~he elec-trofilter 37.
The edible oil treated in the electrofilter 37 enters the product line 46 in such a completely puriEied form, relatively free oE inor~anic solids, colloidal me-tals, etc~, that it has a unique appearance classified by experienced workers in the food indus-try as "br:ight and clear" in appearance. Edible oil of -this bri~ht and clear appearance has a filter disc impurity number generally of about 10~
The reason for this unexpected product result is not completely understood except that the electrofilter 37 produces substantially complete removal of nickel catalyst, colloidal nickel, and other solids from the edible oil, In addition, the electrofilter 37 maintains the production of outstanding edible oil product unitl the solids-fillup condition of the bed of the electrofilter 37 is reached. Only at this solids-fillup condition does the edible oil entering the outletmanifold 42 rapidly deteriorate towards the proper-ties of the raw edible oil flow in the line 34 from the drop tanic 22, As a result, the electrofilter 37 for maximum efficiency and best operation requires a mechanism to predict the onset of this rapid deterioration in edible oil quality when solids-fillup of the electrofiiter bed is reached. One means of accomplishing this result is by a fixed time cleaning cycle. Alternatively, the initial appearance of a small amount of inorganic solids in the edible oil within the product line =~ bm:~
... ..
9(93 46 can be detected as solids-fillup condition is approached, l~hen the electrofilter 37 is operating satisfactorily, the edible oil in product line 4~ is bright and clear in appearance and also shows no Tyndall effect~ At the very onset of solids-*illup in the bed of the electrofilter 37, a slight Tyndall effect occurs in the edible oil, If desired, a sight glass 49 is placed in the product line 46 to de-tect this Tyndall effect. A narrow beam, high intensity light, throu~h the sight glass 49 displays the occurrence of the Tyndall effect. At this t:ime~ the electrofilter 37 is "shu~ down" for a selective cleaning of the bed by the through removal of adhering inorganic solids.
If desired, the monitoring of the edible oil stream for the occurrence of increased solids content can be undertaken by a monitor 51, including an optical cell 52 in the product line 46, to provide an output signal 53, The - monitor 51 may be a nephalometer. The output signal can give a visual or arcual indication to an operator. Preferably, the output signal is adapted to adjust the various valves and other switching functions for cleaning the electrofilter 37 The controller 54 upon receipt of the output signal can provide a plurality of output signals 56 to operate the various control valves associated with the elec-trofilter 37t conduct the stepwise sequence of cleaning steps in the electrofilter 37, and control the operation of a high voltage power supply 40 which is associated with the electrofilter 37. The controller 54 may be convenient and employ either pneumatic or electrical control signals 56 in the necessary sequencing functions for the desired control of the various elements associated with ~ -15-- `' bm ',l .
V~
the electrofilter 37. The d.c. electrical field in the electrofil-ter 37 is removed from the bed material Eor the cleaning process.
The bed material in the electrofilter 37 is cleaned at least in par-t, but preferably in its entirety by use oE
a cleaning fluid. Also, the bed material may be cleaned in place, externally or in any manner whexein -the cleaning fluid flow removes solids Erom the material. If desired, the cleanillg Eluid rna~ be a portion of the raw edible oil in line 3~ -taken from the drop tank 22. In other instances, it may be desired to use other fluids -Eor cleaning -the bed material of the electrofilter, such as edible oil product taken from the conduit 48. The cleaning fluid can be used in a single pass mode but preferably is recirculated in the cleaning process. In one example, edible oil as a cleaning fluid is placed into the charge tank 57 wherein its temperature can be elevated as desired by use of a steam heating system 58.
Then, the pump 59 moves the edible oil through the cleaning line 61, and with the block valve 62 in a closed position, the edible oil flows into the inlet manifold 36 to pass upwardly through the electrofilter 37 into the outlet manifold 42. The circulating edible oil returns in the line 46 through the three-way valve 47, the return conduit 63 through block valve 64 and then into the charge tank 57.
However, the electrofil-ter may be also cleaned with downflowing edible oil. The circulating flow through the cleaning the line 61 of edible oil is adjusted in rate so that the bed of electrofilter 37 is only sllghtly expanded but no-t displaced or mechanically abraided in the absence of the d.c. electric field. The edible oil in the charge tank 57 containing the bm:~
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9qP3 removed solids can be passed through the filter press 28 -for recovery of the edible oil which may then be recycled throu~h line 34 and the electrofilter 37. Al~ernatively, this mixture of edible oil and solids inclu~ing catalyst may be recycled into the converter 16 Eor reuse.
Preferably, the cleaning process is carried out in the electrofilter 37 by first terminating the E:Low through the line 34 of the edible oil Erom the drop tank 22. Then, the valved manifolds are arranged so that a flow of nitorgen from the line 66 is passed clownwardly through the electrofil-ter 37 to displace the residual liquid volume of purified edible oil into the produc-t line 46 and through the valve 47 into the edible oil conduit ~8. In this manner, the amoun-t of "slippage" or recycle of purified edible oil is minimized in the use of the electrofilter 37. As long as the power supply 40 is energized and an electric field exists in the bed material of the electrofilter 37, the adhering solids will not be displaced from the bed by the flow of nitrogen.
Then, the flow of nitrogen through line 66 is terminated and the power supply 40 is de-energized. The cleaning fluid can now be circulated through the electrofilter 37 as previously described.
The volume of the circulating cleaning :cluid is not as critical as the flow rate through the bed of the electrofilter 37 which will usually be in the range of at least 16 inches per minute super-ficial velocity through the bed material. Under those condi-tions, -the volume of recirculating cleaning fluid may be as small as three times the liquid volumetric capacity of the electrofilter 37. The _ .,~ I
bm;i~
::- :, : - , ~0~99~3 optical properties of the cleaning fluicl and entxained solids flowing through th.e line 46 can be employed to determine when ultimate cleaning of the bed material has cccurred since solids amounts become constan-t. For example, the monitor 51 reaches a peak reading of opacity which indicates the encl of the eleaning eycle. At this time, the cleaning fluid is removed from the electrofilter 37 by switchin~ the necessary valves to be displaced by the ineoming edible oil in line 34.
Preferably, the cleaning fluid is cl.isplaced from -the eleetro-filter 37 by a small ~uantity oE the edible oil produc-t from the product line 46. Al.ternatively, nitrogen :is applied through line 66 (as previously deseribed) to displace the liquid eontents of the eleetrofilter 37 downwardly through the manifold 36 and into the various lines and conduits for its recovery. Now, the bed material of the eleetrofilter :~
37 is elean and ean be returned to purification of the raw edible oil in line 34. The power supply 40 is energized, the valves adjusted to reinstate the operation of electrofilter 37, and the flow of the edible oil through the eonduit 34 from the drop tank 22 is resumed. Thus, the eleetrofilter 37 employs a selected bed material whieh not only produees optimum cleaning of the edible oil, but also permits ready eleaning of adhering solids.
The electrofilter 37 has a suitable construetion whieh in one embodiment is illustrated in vertieal seetion in Figure 2. The eleetrofilter 37 comprises an upright vessel 71 having inlet connections 72 connected to the inlet manifold 36 and an outlet distributor 73 eonnected to the outlet manifold 42. Preferablyr the inlet 72 is provided by a . ~ , ~- bm~
9~)3 plurality of well screens 74 which are dimensioned so as to prevent the passage of the material 76 comprisiny the bed 77.
Energized electrodes are positioned within the bed 77 and may take any usual form. For example, an inlet bushing 78 extends upwardly into the vessel 71 and carries a spider 79 on which are mounted in a concentric arrangement an çnergized rod 81, and metal cylinders 82, 83 and 84. Th~ rod 81 is connected by a lead 86 to the power supply 40 so that the electrodes carried on spider 79 are energiæed to a d.c. potential relative to the grounded shell of the vessel 71. A similar system of grounded concentric electrodes is suspended from a spider 87 supported upon a mounting bracket 88 carried about the internal perimetry of the vessel 71. Suspended from the spider 87 in concentric relationship are a plurality of cylindrical electrodes 89, 91, and 92. It will be apparent that the concentric relationship of the energized and grounded cylindrical electrodes provide for establishing an electrical field within the bed 77. For example, the spacing between the energized and grounded electrodes can be one inch with a like spacing about the rod electrode 81 and to the internal cylindrical surface of the metal shell of the vessel 71. With this arrangement, the power supply 40 should provide at leas-t 20 kilovolts per inch d.c. electrical potential to lead 86.
Preferably, the power supply 40 provides a d.c. potential of at least 40 kilovolts per inch within the bed 77. Excessive high intensity potentials in the d.c. electric field within the bed 77 should be avoided. Excessively high d.c. potentials could lead to gas (hydrogen) ionization and arcing within the electrofilter 37. The finely-divided solids carried in the bm ~
~, .-.
edible oil into the bed 77 axe acted upon by the d.c. electric field which electrically induces the adhesion of these solids onto the surfaces of particles 76. For practical purposes, no solids can escape the bed 77 in the presence of the ~.c.
elec-tric field un-til the solids-fillup condition is reached.
The electrically in~uced adhesion of solids is so great a force that a flow of nitrogen gas e~ual in rate to cleaning fluid flows cannot remove them. However, removal of the d.c.
electxic field allows a simple washing of the bed to remove completely these solids. The electrofilter 37 is a system similar to known electrofilters haviny particulate materials in their inner electrode spaces. However, the particular selection of the particles ~6 forming the bed-77 of the present electrofilter 37 produces an electrofilter system unique in apparatus and process, and this system produces une~xcted purification of organic liquids, such as oil streams, into a bright and clear product equal to commercial products obtained by multistep filtration procedures.
More particularly, the bed 77 of the electrofilter 37 is preferably comprised of chemically inert, hard granular particles of a rigid, and substantially incompressible material. Furthermore, these particles are in the majority non-spheroidal with a relatively discontinuous surEace configuration and a dielectric constant not in excess of about 7 (at 1 kilohertz~. The term "non-spheroidal" is intended to include by definition particles other than true spheres, such as oval and other non-round shapes having minor to major axes in ratios exceeding 4 to 6. By the terminology "relatively discontinuous surface configuration" is meant a surface that is not planar or unbroken such as the surface ~ .
~, bm ~
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~0~03 of a glass be~cl, and p~rticularly included are multifaceted particles haviny meeting edges be-tween multitudes o-f s~all surfaces which may bé planar, concave, convex and combinations thereof, regular or ixregular in arrangement.
The exact reason for the novel functioning of the bed 77 in the electrofilter 37 cannot be determined with an exact scientific definition. Ilowever, it is helieved that the particularly selected particles 76 in conjunction with the electrical characteristics of the organic liquids (e.c3., edible oil) and the contaminating solids, such as the metal hydrogenation catalyst and filteraid, interrelate to prod~lce the novel results of the present invention. For example, edible oils have a dielectric constant of about 3.5.
The diatomaceous earth carrier (Kieselguhr), the metal hydrogenation catalyst, and filtera~d all have a dielectric constant of about 4. The metal hydrogenation catalyst and the filteraid materials have h~ghly developed pore surfaces which appear to be completely saturated wi-th edible oil.
The particles 76 which are selected for the purpose of the present invention also have a dielectric constant not greatly in excess of about 7, and preferably below about 5. Thus, all of the dielectric materials within the elec-trofilter 37 have very similar dielectric constantsr and all these materials have extremely high resistivity (e.g., 1 x 10 ohm-cm) and dielectric strength (e.g., above 10 kv, dc/mm). It is believed that these dielectric properties permit the bed 77 to function exceptionally within the high intensity d.c.
e]ectric field for electrically inducing the tenaceous adhesion of the solids, such as filteraid, to the par-ticles 76. However, .~ ~, 1 1 5. bm,"~
, .
)9Q3 terminating the d.c. electric field within the bed 77 allows the adhering s~lids to be easily removed by a relatively lo~
rate of flow of a cleaning fluid without disruption of th~
particles 76. For example, the elec-trofilter 37 will operate to remove solids with a flow o:E 12 inches per minute super-Eicial velocity of edible oil through the bed 77. However, the particles 76 in the bed 77 are cleaned thoxoughly (wi.th the d.c. electric field removed) at the flow rate of above abou-t 1~ inches per minute super:Eicial velocity w;.th ed;.ble oil as the cleanin~ flu~d. The bed 77 does not need to be made turbulent or suffer particle movement, but pre:Eerably, it merely expands slightly during the flow of cleaning fluid.
The particles 76 should be chemically inert and not contamina-te the edible oil. The particles 76 should have a relatively discontinuous surface configration in contrast to a highly polished smooth surface such as glass bead or marble.
In addition, the particles 76 should have a relatively high density or specific gravity and a substantial hardness co~.pared to the solids which are to ~e removed. Par-ticles ;
selected for use in the present electrofiltration sys-tem are preferably selected from materials in the group consisting of a mineral containing crystalline silicon dioxide such as flint, garnet, granite and fused quartz. These particles 76 selected from this mineral group have a hardness value of at least 7 on the Mohs scale of ha.rdness, a specific gravity between about 2.5 and about 2.9, a:dielectric constant of about 4, and a discontinuous surface configuration provided in nature. The particles 76 may range in size from about 1 mm to about 13 mm for good results. A crushed flint with an - -.
-~s bm~
'~ , :.. ,.' .. ..
' ~.' ,,: ' : , , ' 09~3 avera~e (50 percentile) particle size (smallest dimension) of 2.5 mm gives excellent results~ These particles in the electrofilter 37 will not contaminate the edible oil during either elec-troEi:Ltration or the cleaning cycle for removing adhering solids from the bed 77. In addition, these particles provide an unexpected ease in cleaning the adhering solids rom the bed 77 with a cleaning fluid.
An experimental electrofilter system was placed into a commercial edible oil refinery ancl -tested with several edible oils and bed ma-terials -to document the outstanding results. The experimen~al system was essentially similar to that illustrated in Figure 1 using the electrofilter 37 shown in Figure 2. The electrofi]ter was a cylindrical metal vessel having a 15 inch internal diameter with a 30 inch total vertical height. The vessel was placed on an upright axis and arranged with electrodes as is shown in Figure 2.
The concentric electrodes had an engagement length (taken in the vertical) of 14 inches. The interior of the vessel was substantially filled with selected particles according to the guidelines of the present invention. A one inch spacing of the electrodes existed over their engagement length. The electrodes electrically confined in the bed l.~ cubic feet of these particles. The power supply energized selectively these electrodes to be-tween 20 and 40 kilovolts. An edible oil stream of soybean oil was taken directly from the drop tank of the commercial operation. The drop tank held the hydrogenation edible oil which contained nickel metal in -the amount of several hundred parts per million and solids of several hundred parts per million. The experimental bm G;~-,~
- , .. , ~ : .
09(~3 electrofilter system was operated on this edible oil charge under pr~cise test procedures on three types of particle media, desi~nated as F~ M-l, and G-l. These media were commercial Flintabrise~M brane sandblasting materials which are commercially available from Clemtex Limited o~ ~anada at Ilouston, Texas, More particularly, the medium F-ll was a crushed flint roc~ with an average ~50 percen-ti:Le) particle size (least dimension) of 2.5 millimeters, The medium M-l was a commerci~l "No l marine sand" which had been screened 0 50 tha-t all particle sizes were between 8 and 20 mesh on Tyle.r s~andard screens. The medium G-l was a river gravel (grani-te) which had been screened to sizes between one-fourth and one-half inch. These media are all minerals.containing crystalline silicon dioxide, have specific gravities between abou-t 2.5 and about 2.9, dielectric constants less than about 5 and usually about 4, and high dielectric stengths, A11 media were scrupulously cleaned by carefully screening, water-washing, and air-drying so that no possible contamination of the edible oil stream could occur. ~ach medium was placed within the experimental electrofilter and subjected to test conditions of the samé nature as described for the electrofilter 37, The incoming raw edible oil stream was taken directly from the drop tank 22 and passed upwardly through the electrofilter at a rate of about 9 gallons per minute and at temperatures between 150 and 200 F. The product edible oil stream from the electrofilter was tested in accordance with the filter disc impurities test, analyzecl for nickel content, and visual appearance. The total throughput volume of the electrofilter was recorded until the onset of product edible oil degradation .
bm:~
, - , , ; ,: - .
, : :
: : : ,: ::. , 9~3 by increased solids content arising :Erom the onset of solids-fillup of the bed of the electrofilter as detected by the initial observance of a Tyndall ef f ec t, The data f.rorn these tests of the media are set forth in the following Tables 1, 2 and 3.
T~BIE 1 Medi~n F-ll Fil-tex Disc Ni./p~Vol/~a~ Ap~e 40 kv @ 0.13-0.30 an~ps 8-~ - 178 C].ear Rate 7.5 - 9 gFrn eclible oil 10 1.0 326 Very Clear @ 165 F. 10 .7 823 Cl~r Bed loading 6~4Lbs,/ft.3 10 ~ 1010 Clear - 1295 Clear 3 . 4 1416 Clear 9 - 1656 Clear
Naturally, high levels of mechanical contact between these particles cause abrasion and could result in a small amount of abraded particle material being released from the bed, As a result, the bed would hav`e to be scrupulously cleaned of the small fragmented portions of the particulate material unless these residues were not critical to the dielec-tric liquid being treated. In the electrofiltration purification of hydrocarbon materials, such as distillates and residual streams or inorganic materials, a small amount of residue from abraded particulate bed material would not be a problem, However, these abraded materials are intolerable in edible oils, The prior art has included proposals to employ electrofiltration for purification of various types of dielectric organic liquids for about four decades~ However, no electrofilter device has produced the purfication of organic liquids which contain finely-divided inorganic and organic solids for several impor-tant reasons. In the first instance, the electrofilter equipment must eEfect complete removal from solids without either an unaccep-table pressure buildup or deleterious ~- I
bm~
~ . , . . . ~ . - . ;
)3 change in electrical characteristics inducing arcing, shor-ting and like problems. In the second instance, the electrofilter must be capable of h~ndlin~ effectively the organic liquid stream containlng widely varying amoun-ts of solids. In -the third instance, the electrofilter system must contain a particulate bed material of special characteris-tics so tha-t (1 the organic liquid product is produced with extremely low amount of residual solids, without undue pressure buildup or arcing, (2) the particula-te bed material is readily cleaned of adhering solids/ and ~3) no abrasion or loss of the particula-te bed material itself occurs to contaminate the organic liquid.
The foregoing reasons summarize the incapability of prior art electrofiltration system in being used in the purification of organic liquids containing finely divided solids, The present invention is an electrofiltration system for purifying organic liquids by removal of finely-divided solids without the foregoing recited problems of prior art electrofilters~-In particular, the present invention is a novel electrofilter, electrofiltration process, and organic liquid product. A
selected material in the bed of the electrofilter system produces a substantially complete removal of the solids, irrespective of the solids loading content, and without the electrofilter system having any appreciable pressure buildup or electrical arcing in the bed. The bed is chemically inert, and no contamination of the organic liquid stream occurs in use. The cleaning of the bed of accumulated soIids is not complicated and produces an environment for continuous and repeated elec~^ofiltration for producing a product organic liquid equal in physical and chemical charac-teristics to ccmmercial product prepQred by extended time! multistep p~ocedures Additional fea-tures -of the present invention will be appreciated from the-following description.
~, - -~ 7--. , . . . - ~ , , : : - .
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39(~3 SUM~IARY OF THE INVENTION
In accordance with this invention, there is provided an electrofiltration system, including apparatus, process, and product, for the purification of an organic liquid stream of high resistivity. In particular, the organic liquid gtream~
at suitablP temperature, is passed through a chemically inert bed having multitudinous flow channels between rigid masses of a solid material having a dielectric constant not in excess of about 7. A d.c. electric field within the bed provides a sufficient intensity for removing solids from the organic liquid stream by the electrically induced adhesion oE the solids on the material to provide a purified organic liquid stream removed to a subsequent utilization. The bed material, at least in part, is selectively cleaned of adhering solids by interruption of the electrical field, passing a cleaning fluid through the material to remove adhering solids, and then removing the fluid with the removed solids from the material being cleaned.
In a preferred embodiment, the purified organic liquid stream is monitored to provide an indicating signal when to undertake the selective cleaning of the bed material. The purified organic liquid stream is a novel product, quickly prepared - without aging, and having comparable chemical and physical properties to conventional multistep treated commercial product.
In one particular aspect the present application, which is a division of copending Canadian Application No. 266,570, filed November 25, 1976, is concerned with the provision of an electrofiltration process for removing hydrogenation catalyst - and other undissolved solids from a stream of edible oil which ~ has been subjected to catalytic hydrogenation,-&~ process comprising:
j 1/ ~` `` --8-.: . : : . :: ~- -(a) providing the stream of so hydrogenat~d edible oil at a sufficient temperature that organic solids such as stearine are in solution and cannot plug an electrofilter bed adapted to remo~e the undissolved solids carried therein;
~b) passing said stream of oil through a chemically inert bed having multitudinous flow channels between rigid masses of a solid material having a dielectric constant not in excess of about 7;
(c) establishing a d.c. electrical Eield within said bed havlng an intensity sufEicient of removing the undissolved solids from said stream of oil by electrically induced adhesion of the solids in said bed material;
(d) removing the purified oil stream with reduced undissolved solids content from said bed; and (e) cleaning at selected intervals at least a portion of said material of adhering solids by interruption of said r o, u ~ ~ ~ h ~ J Q /
electrical field~ passing a cleaning fluid~to remove adhering solids from said material and removing the fluid with the removed solids from said material. ' In another particular aspect the present application, which is a division of copending Canadian Application No. 266,570, filed November 25, 1976, is concerned with the provision of an electrofiltration process for removing solids from an organic liquid stream comprising:
~a) passing said liquid stream through a bed of chemically inert, hard granular particles of a rigid, substantially incompressible material, said particles being non-spheroidal with a relatively discontinuous surface configuration and a dielectric constant not in excess of about 7;
~ 8a-- . :, . . .
09~3 (b) establishing a d.c. electrical field within said bed haviny an intensi,ty sufficient for removing the solids from the organic liquid stream by electrically incluced adhesion of t.he solids on said particles;
(c) removing the purifled'organic liquid stream with reduced solids content from saicl bed; and (d) cleaning at selected intervals at least a portion of said particles of adhe~ing solids by interruptincJ said electrical field, passing a cleaning fluid through the bed to remove adhe.rin~ solids from said particles and re~loving the fluid with the removed solids from.said particles being clearled.
In a further particular aspect the present application, which is a divisional of copending Canadian Application No.
266,570, filed November 25, 1976, is concerned with the provislon of an electrofi,ltration process for removing hydrogenation catalyst and other undissolved solids from a stream of edible oil which has been subjected to catalytic hydrogenation, said process comprising:
(a) providing the stream of so hydrogenated edible oil at a sufficient temperature that organic solids such as ~ 8b-bm~
. . : , :, , ~
,. : -. :; .: . .
~0~03 stearine are in solution and cannot plug an electrofilter bed adapted to remove the undissolved solids carried therein;
(b) passing said stream of oil through a chemically inert bed having multitudinous flow channels between rigid masses of a solid material having a dlelectric constant not in excess of about 7;
~ c) establishing a d.c~ electrical field within said bed having an intensity suficient for removing the undissolved solids from said stream oE oil by electrically induced adhesion of the solids in said bed material; and (d) xemoving the purified oil stream with reduced undissolved solids content from said bed.
DESCRIPTION OF THE DRAWINGS
Figure 1 is a diagrammatical illustration, in flow schematic, of the present electrofilter system applied to a prior art -8c-bm~
'~
~0()903 hydrogenation plant for producing edible oil as an exarnple of an organic liquid;
Figure 2 is a vertical cross-section illustrating the construction of the electrofilter sho~n in the system of Figure l; and jl/,'`l-, -8d-:.::., ., : .
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: . :: .::
' :. :- ' :~' ' - :
)9~3 Figure 3 is a graphic comparison of several bed materials employea in the electrofilter of Figure 1 and a typical mechanical filtration relative to the Eilter disc impurities color of an edible oil puri.fied in the present electrofiltration system~
D~SCRIPTION OF SP~CIFIC EMBODIMENTS
The present electro~il-ter system will he described in the purification of one type oE organic liquid, namely, an edible oil. However, it will be apprecia-ted -that the invention is equally applicable and o:E utili-ty with other -types of organic liquids, e~g~, fa-ts, animal and veyetable ~A
oils. Referring now to Figure l, there is shown an embodiment of the present electrofilter system associated with an appropriate portion of a prior art hydrogenation plant, wherein edible oils are contacted with hydrogen at elevated tempera-ture and pressure in the presence of a finely-divided catalytic - material~ More particularly, the hydrogenation plant is enclosed within the chainline 12 with the designation of prior art being applied as an example o-f commercial operations~
An edible oil, such as soybean oil, is brought from storage through an inlet conduit 13 and a heat exchanger 14 directly into the hydrogenation converter 16. The hea-t exchanger 14 - raises the temperature of the edible oil to a suitable level, e.g., above 250 F. The converter 16 is a steel vessel usually with an upright axis which contains the charge of edible oil to be hydrogenated~ The edible oil in the converter is admixed with a suitable amount of metal catalyst.
In most instances, a dia-tomaceous earth or a filteraid material is intermixed with the catalyst iTI suitable bm~
.:
- . , ' :
.
:
~0~)9~3 proportions with an edible oil carrier in the catalyst mix tank 17. Then, this mixture is displaced by pump 18 through a control valve 19 into the converter 16. The converter 16 usually has an internal mixer arrangement for maintaining a suspension o:E the catalyst materials within the edible oil. Hydrogen is added to the converter 16. The hydrogenation reaction ta~es place over a suitable length of time, such as one hour, depending upon the mass of edible oil charge and the des:ired hydrogenation degree to be produced in t~e edible oil product, The converter 16 may be of any suitable size. For description, the converter 16 will receive an edible oil charge of about 40,000 pounds, and the hydrogenation catalyst material is of the nickel metal variety, which is introduced to a suitable concentration of between ~01 and ,5 percent by weight. The nickel catalyst is approximately 25% by weight of nickel with the remainder being Kieselguhr or other diatomaceous earth material, After the hydrogenation reaction is completed~ the contents of the converter 16 are moved through the valve 21 into a drop tank 22 where the hydrogenated edible oil product is held while being.processed for the removal of the finely-divided hydrogenation catalyst and other inorganic solids.
Presently, the contents of the drop tank 22 are moved through a control valve 23 by centrifugal pump 24~ an optional heat exchanger 26, and through a piping loop con-taining several control valves to the inlet 27 of the filter press 28.
The filter press is conventional with a plurality of filter elements, The filtered edible oil is removed from the filter bm:
, ~ ;. . -... .
~00903 press 2~ throu~h the outlets 29 or 31 dependlng upon whether the sections are operated in parallel or in separate sections. The outlets 2~ and 31 connect to a filtere* edible oil line 32 for directing this stream to subsequent processing for the removal of res.idual amounts of the hydrogenation catalyst and other inorganic solids.
For example, the filtered edible oil in the line 32 may contain about several parts per million of nickel metal (suspended and colloidal) so as to have a pronounced green-to-black colo.r, and several parts per million of lnorganic solids, such as filteraid, and a filter disc color of 6 or worse. Thus, the filter press 2~ cannot produce an acceptable edible oil product that could be used for human consumption The filtered edible oil in line 32 now usually is subjected to additional processing steps. One step is treatment with citric acid or phosphoric acid and a filteraid material, and filtration to remove the chelated hydrogenation catalyst.
Another step is a bleaching operation wherein a small amount of bleaching clay is added to the edible oil, and then filtered to provide the edible oil product. The edible oil product after one or more of these steps is an edible oil product directly suitable for consumer use Sometimes, this product is subjected also to a winterizing and/or deodorizing step to produce certain types of edible oils.
In the present invention, all mechanical filtration steps are avoided. The hydrogenated edible oil in the drop tank 22 is passed through the novel electrofilter system of the present invention . Referring specifically to that portion of Figure 1 outside the chainline 12, the edible oil from the bm:~
- : . -. ~
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. .
drop tank 22 is diverted through the block valve 33 in-to a raw oil line 34. The edible oil in the line 34, by use of the heat ex~hanger 26, is adjus-ted in temperature, usually above 150 F., so that organic solids, such as stearine, are in total solution in the edible oil stream and cannot plug the electrofilter. The line 34 connects in-to an inlet manifold 36 associated with the electroE~ ter 37. The manifold 36 h~s a plurality o~ motor control valves 35, 38, and 39, whose functions will be hereinafter described. With this arrangement o~ the inlet mani~old 36, the edible oil is passed upwardly through the electrofilter 37 and removed through the outlet manifold 42 which includes motor control valves 43 and 44. However~ it may be desired to have the edible oil passed downwardly through the electrofilter 37 and the-functions of the inlet and outlet manifolds would then be reversed. The piping for the present system is arranged for this purpose as will be appreciated by examination of the respective manifolds and their connections in-to the system shown in Figure 1, - The electrofilter 37 is arranged so that substantially all of the solids, including the hydrogenation catalyst, filteraid, dia-tomaceous earth, etc., and any insoluble organic solids, are removed from the edible oil stream The electrofilter 37 has a selected bed forming an inner electrode space subjected to a high intensity d.c. electric field for removing substantially all of these solids from the edible oil. The purified edible oil stream is removed through a product line 46 and a three-way control valve 47 into an edible oil product conduit 48 for removal to a subsequent bm:
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.... , ,~ . , : - ~
, . ~ .; . . , ,:
~iO0~(~3 utilization~ Preferably, the edible oil product line ~6 includes a moni~or of the purified edible oil product ~rom the electrofilter 37 to detexmine the approach of a suddenly increased solids content which occurs on the approach of solids-fillup in the bed of the electrofilter 37.
The present invention involves the selection of a certain type of material :Eormin~ -the bed o~ the electro-filter 37. The bed is chemically inert and has multitudinou.s flow channels between rigid masses of a solid material. The bcd material should havc a dielec-tric constant no-t in excess of about 7. The bed material should have sufficient rigidity so that in operation it cannot be compressed in a degree to reduce the flow channels, thereby producing an unacceptable pressure drop across the bed.
One of the cha.racteristics of the electrofil-ter 37 with this selected bed is that substan-tially all of the solids, including even colloidal nickel and filteraid materials, are removed .rom all the edible oil passing into the product line ~6, and this purity is maintained until the bed has accumulated its capacit~ of removed solids as the solids-fillup condition :~
is approached. As this solids-fillup condition is approached - in the bed of the electrofilter 37~ no significant changes occur in the electrical parameters or measurable physical operation conditions concerning the electrofilter~ However, there is a sudden increase in the solids content of the trea~ed edible oil. More particulaxly, -the pressure drop across the eletrof.ilter 37 is small and does not change within -the measurement error of conventional pressure gauges. In addition, no significant change in electrical parame-ters, voltage or ~r 1 3 ! bm:~
. , : ' , ~ .
~1~0~(~3 current, occurs in the high vol~age el~c-tric field imposed upon the bed within the electrofilter 37~ These phenomena of the electrofil-ter 37 are more appar~nt from -the following discussion of the preferred design and operation of ~he elec-trofilter 37.
The edible oil treated in the electrofilter 37 enters the product line 46 in such a completely puriEied form, relatively free oE inor~anic solids, colloidal me-tals, etc~, that it has a unique appearance classified by experienced workers in the food indus-try as "br:ight and clear" in appearance. Edible oil of -this bri~ht and clear appearance has a filter disc impurity number generally of about 10~
The reason for this unexpected product result is not completely understood except that the electrofilter 37 produces substantially complete removal of nickel catalyst, colloidal nickel, and other solids from the edible oil, In addition, the electrofilter 37 maintains the production of outstanding edible oil product unitl the solids-fillup condition of the bed of the electrofilter 37 is reached. Only at this solids-fillup condition does the edible oil entering the outletmanifold 42 rapidly deteriorate towards the proper-ties of the raw edible oil flow in the line 34 from the drop tanic 22, As a result, the electrofilter 37 for maximum efficiency and best operation requires a mechanism to predict the onset of this rapid deterioration in edible oil quality when solids-fillup of the electrofiiter bed is reached. One means of accomplishing this result is by a fixed time cleaning cycle. Alternatively, the initial appearance of a small amount of inorganic solids in the edible oil within the product line =~ bm:~
... ..
9(93 46 can be detected as solids-fillup condition is approached, l~hen the electrofilter 37 is operating satisfactorily, the edible oil in product line 4~ is bright and clear in appearance and also shows no Tyndall effect~ At the very onset of solids-*illup in the bed of the electrofilter 37, a slight Tyndall effect occurs in the edible oil, If desired, a sight glass 49 is placed in the product line 46 to de-tect this Tyndall effect. A narrow beam, high intensity light, throu~h the sight glass 49 displays the occurrence of the Tyndall effect. At this t:ime~ the electrofilter 37 is "shu~ down" for a selective cleaning of the bed by the through removal of adhering inorganic solids.
If desired, the monitoring of the edible oil stream for the occurrence of increased solids content can be undertaken by a monitor 51, including an optical cell 52 in the product line 46, to provide an output signal 53, The - monitor 51 may be a nephalometer. The output signal can give a visual or arcual indication to an operator. Preferably, the output signal is adapted to adjust the various valves and other switching functions for cleaning the electrofilter 37 The controller 54 upon receipt of the output signal can provide a plurality of output signals 56 to operate the various control valves associated with the elec-trofilter 37t conduct the stepwise sequence of cleaning steps in the electrofilter 37, and control the operation of a high voltage power supply 40 which is associated with the electrofilter 37. The controller 54 may be convenient and employ either pneumatic or electrical control signals 56 in the necessary sequencing functions for the desired control of the various elements associated with ~ -15-- `' bm ',l .
V~
the electrofilter 37. The d.c. electrical field in the electrofil-ter 37 is removed from the bed material Eor the cleaning process.
The bed material in the electrofilter 37 is cleaned at least in par-t, but preferably in its entirety by use oE
a cleaning fluid. Also, the bed material may be cleaned in place, externally or in any manner whexein -the cleaning fluid flow removes solids Erom the material. If desired, the cleanillg Eluid rna~ be a portion of the raw edible oil in line 3~ -taken from the drop tank 22. In other instances, it may be desired to use other fluids -Eor cleaning -the bed material of the electrofilter, such as edible oil product taken from the conduit 48. The cleaning fluid can be used in a single pass mode but preferably is recirculated in the cleaning process. In one example, edible oil as a cleaning fluid is placed into the charge tank 57 wherein its temperature can be elevated as desired by use of a steam heating system 58.
Then, the pump 59 moves the edible oil through the cleaning line 61, and with the block valve 62 in a closed position, the edible oil flows into the inlet manifold 36 to pass upwardly through the electrofilter 37 into the outlet manifold 42. The circulating edible oil returns in the line 46 through the three-way valve 47, the return conduit 63 through block valve 64 and then into the charge tank 57.
However, the electrofil-ter may be also cleaned with downflowing edible oil. The circulating flow through the cleaning the line 61 of edible oil is adjusted in rate so that the bed of electrofilter 37 is only sllghtly expanded but no-t displaced or mechanically abraided in the absence of the d.c. electric field. The edible oil in the charge tank 57 containing the bm:~
: ' ' : -: . . ~ : : . i: `
. i . . ` ': : ' .: ' `'' , ~ ' , : :` .
- .,. - ` ` ~: :: ."
9qP3 removed solids can be passed through the filter press 28 -for recovery of the edible oil which may then be recycled throu~h line 34 and the electrofilter 37. Al~ernatively, this mixture of edible oil and solids inclu~ing catalyst may be recycled into the converter 16 Eor reuse.
Preferably, the cleaning process is carried out in the electrofilter 37 by first terminating the E:Low through the line 34 of the edible oil Erom the drop tank 22. Then, the valved manifolds are arranged so that a flow of nitorgen from the line 66 is passed clownwardly through the electrofil-ter 37 to displace the residual liquid volume of purified edible oil into the produc-t line 46 and through the valve 47 into the edible oil conduit ~8. In this manner, the amoun-t of "slippage" or recycle of purified edible oil is minimized in the use of the electrofilter 37. As long as the power supply 40 is energized and an electric field exists in the bed material of the electrofilter 37, the adhering solids will not be displaced from the bed by the flow of nitrogen.
Then, the flow of nitrogen through line 66 is terminated and the power supply 40 is de-energized. The cleaning fluid can now be circulated through the electrofilter 37 as previously described.
The volume of the circulating cleaning :cluid is not as critical as the flow rate through the bed of the electrofilter 37 which will usually be in the range of at least 16 inches per minute super-ficial velocity through the bed material. Under those condi-tions, -the volume of recirculating cleaning fluid may be as small as three times the liquid volumetric capacity of the electrofilter 37. The _ .,~ I
bm;i~
::- :, : - , ~0~99~3 optical properties of the cleaning fluicl and entxained solids flowing through th.e line 46 can be employed to determine when ultimate cleaning of the bed material has cccurred since solids amounts become constan-t. For example, the monitor 51 reaches a peak reading of opacity which indicates the encl of the eleaning eycle. At this time, the cleaning fluid is removed from the electrofilter 37 by switchin~ the necessary valves to be displaced by the ineoming edible oil in line 34.
Preferably, the cleaning fluid is cl.isplaced from -the eleetro-filter 37 by a small ~uantity oE the edible oil produc-t from the product line 46. Al.ternatively, nitrogen :is applied through line 66 (as previously deseribed) to displace the liquid eontents of the eleetrofilter 37 downwardly through the manifold 36 and into the various lines and conduits for its recovery. Now, the bed material of the eleetrofilter :~
37 is elean and ean be returned to purification of the raw edible oil in line 34. The power supply 40 is energized, the valves adjusted to reinstate the operation of electrofilter 37, and the flow of the edible oil through the eonduit 34 from the drop tank 22 is resumed. Thus, the eleetrofilter 37 employs a selected bed material whieh not only produees optimum cleaning of the edible oil, but also permits ready eleaning of adhering solids.
The electrofilter 37 has a suitable construetion whieh in one embodiment is illustrated in vertieal seetion in Figure 2. The eleetrofilter 37 comprises an upright vessel 71 having inlet connections 72 connected to the inlet manifold 36 and an outlet distributor 73 eonnected to the outlet manifold 42. Preferablyr the inlet 72 is provided by a . ~ , ~- bm~
9~)3 plurality of well screens 74 which are dimensioned so as to prevent the passage of the material 76 comprisiny the bed 77.
Energized electrodes are positioned within the bed 77 and may take any usual form. For example, an inlet bushing 78 extends upwardly into the vessel 71 and carries a spider 79 on which are mounted in a concentric arrangement an çnergized rod 81, and metal cylinders 82, 83 and 84. Th~ rod 81 is connected by a lead 86 to the power supply 40 so that the electrodes carried on spider 79 are energiæed to a d.c. potential relative to the grounded shell of the vessel 71. A similar system of grounded concentric electrodes is suspended from a spider 87 supported upon a mounting bracket 88 carried about the internal perimetry of the vessel 71. Suspended from the spider 87 in concentric relationship are a plurality of cylindrical electrodes 89, 91, and 92. It will be apparent that the concentric relationship of the energized and grounded cylindrical electrodes provide for establishing an electrical field within the bed 77. For example, the spacing between the energized and grounded electrodes can be one inch with a like spacing about the rod electrode 81 and to the internal cylindrical surface of the metal shell of the vessel 71. With this arrangement, the power supply 40 should provide at leas-t 20 kilovolts per inch d.c. electrical potential to lead 86.
Preferably, the power supply 40 provides a d.c. potential of at least 40 kilovolts per inch within the bed 77. Excessive high intensity potentials in the d.c. electric field within the bed 77 should be avoided. Excessively high d.c. potentials could lead to gas (hydrogen) ionization and arcing within the electrofilter 37. The finely-divided solids carried in the bm ~
~, .-.
edible oil into the bed 77 axe acted upon by the d.c. electric field which electrically induces the adhesion of these solids onto the surfaces of particles 76. For practical purposes, no solids can escape the bed 77 in the presence of the ~.c.
elec-tric field un-til the solids-fillup condition is reached.
The electrically in~uced adhesion of solids is so great a force that a flow of nitrogen gas e~ual in rate to cleaning fluid flows cannot remove them. However, removal of the d.c.
electxic field allows a simple washing of the bed to remove completely these solids. The electrofilter 37 is a system similar to known electrofilters haviny particulate materials in their inner electrode spaces. However, the particular selection of the particles ~6 forming the bed-77 of the present electrofilter 37 produces an electrofilter system unique in apparatus and process, and this system produces une~xcted purification of organic liquids, such as oil streams, into a bright and clear product equal to commercial products obtained by multistep filtration procedures.
More particularly, the bed 77 of the electrofilter 37 is preferably comprised of chemically inert, hard granular particles of a rigid, and substantially incompressible material. Furthermore, these particles are in the majority non-spheroidal with a relatively discontinuous surEace configuration and a dielectric constant not in excess of about 7 (at 1 kilohertz~. The term "non-spheroidal" is intended to include by definition particles other than true spheres, such as oval and other non-round shapes having minor to major axes in ratios exceeding 4 to 6. By the terminology "relatively discontinuous surface configuration" is meant a surface that is not planar or unbroken such as the surface ~ .
~, bm ~
,- , ~ .
~0~03 of a glass be~cl, and p~rticularly included are multifaceted particles haviny meeting edges be-tween multitudes o-f s~all surfaces which may bé planar, concave, convex and combinations thereof, regular or ixregular in arrangement.
The exact reason for the novel functioning of the bed 77 in the electrofilter 37 cannot be determined with an exact scientific definition. Ilowever, it is helieved that the particularly selected particles 76 in conjunction with the electrical characteristics of the organic liquids (e.c3., edible oil) and the contaminating solids, such as the metal hydrogenation catalyst and filteraid, interrelate to prod~lce the novel results of the present invention. For example, edible oils have a dielectric constant of about 3.5.
The diatomaceous earth carrier (Kieselguhr), the metal hydrogenation catalyst, and filtera~d all have a dielectric constant of about 4. The metal hydrogenation catalyst and the filteraid materials have h~ghly developed pore surfaces which appear to be completely saturated wi-th edible oil.
The particles 76 which are selected for the purpose of the present invention also have a dielectric constant not greatly in excess of about 7, and preferably below about 5. Thus, all of the dielectric materials within the elec-trofilter 37 have very similar dielectric constantsr and all these materials have extremely high resistivity (e.g., 1 x 10 ohm-cm) and dielectric strength (e.g., above 10 kv, dc/mm). It is believed that these dielectric properties permit the bed 77 to function exceptionally within the high intensity d.c.
e]ectric field for electrically inducing the tenaceous adhesion of the solids, such as filteraid, to the par-ticles 76. However, .~ ~, 1 1 5. bm,"~
, .
)9Q3 terminating the d.c. electric field within the bed 77 allows the adhering s~lids to be easily removed by a relatively lo~
rate of flow of a cleaning fluid without disruption of th~
particles 76. For example, the elec-trofilter 37 will operate to remove solids with a flow o:E 12 inches per minute super-Eicial velocity of edible oil through the bed 77. However, the particles 76 in the bed 77 are cleaned thoxoughly (wi.th the d.c. electric field removed) at the flow rate of above abou-t 1~ inches per minute super:Eicial velocity w;.th ed;.ble oil as the cleanin~ flu~d. The bed 77 does not need to be made turbulent or suffer particle movement, but pre:Eerably, it merely expands slightly during the flow of cleaning fluid.
The particles 76 should be chemically inert and not contamina-te the edible oil. The particles 76 should have a relatively discontinuous surface configration in contrast to a highly polished smooth surface such as glass bead or marble.
In addition, the particles 76 should have a relatively high density or specific gravity and a substantial hardness co~.pared to the solids which are to ~e removed. Par-ticles ;
selected for use in the present electrofiltration sys-tem are preferably selected from materials in the group consisting of a mineral containing crystalline silicon dioxide such as flint, garnet, granite and fused quartz. These particles 76 selected from this mineral group have a hardness value of at least 7 on the Mohs scale of ha.rdness, a specific gravity between about 2.5 and about 2.9, a:dielectric constant of about 4, and a discontinuous surface configuration provided in nature. The particles 76 may range in size from about 1 mm to about 13 mm for good results. A crushed flint with an - -.
-~s bm~
'~ , :.. ,.' .. ..
' ~.' ,,: ' : , , ' 09~3 avera~e (50 percentile) particle size (smallest dimension) of 2.5 mm gives excellent results~ These particles in the electrofilter 37 will not contaminate the edible oil during either elec-troEi:Ltration or the cleaning cycle for removing adhering solids from the bed 77. In addition, these particles provide an unexpected ease in cleaning the adhering solids rom the bed 77 with a cleaning fluid.
An experimental electrofilter system was placed into a commercial edible oil refinery ancl -tested with several edible oils and bed ma-terials -to document the outstanding results. The experimen~al system was essentially similar to that illustrated in Figure 1 using the electrofilter 37 shown in Figure 2. The electrofi]ter was a cylindrical metal vessel having a 15 inch internal diameter with a 30 inch total vertical height. The vessel was placed on an upright axis and arranged with electrodes as is shown in Figure 2.
The concentric electrodes had an engagement length (taken in the vertical) of 14 inches. The interior of the vessel was substantially filled with selected particles according to the guidelines of the present invention. A one inch spacing of the electrodes existed over their engagement length. The electrodes electrically confined in the bed l.~ cubic feet of these particles. The power supply energized selectively these electrodes to be-tween 20 and 40 kilovolts. An edible oil stream of soybean oil was taken directly from the drop tank of the commercial operation. The drop tank held the hydrogenation edible oil which contained nickel metal in -the amount of several hundred parts per million and solids of several hundred parts per million. The experimental bm G;~-,~
- , .. , ~ : .
09(~3 electrofilter system was operated on this edible oil charge under pr~cise test procedures on three types of particle media, desi~nated as F~ M-l, and G-l. These media were commercial Flintabrise~M brane sandblasting materials which are commercially available from Clemtex Limited o~ ~anada at Ilouston, Texas, More particularly, the medium F-ll was a crushed flint roc~ with an average ~50 percen-ti:Le) particle size (least dimension) of 2.5 millimeters, The medium M-l was a commerci~l "No l marine sand" which had been screened 0 50 tha-t all particle sizes were between 8 and 20 mesh on Tyle.r s~andard screens. The medium G-l was a river gravel (grani-te) which had been screened to sizes between one-fourth and one-half inch. These media are all minerals.containing crystalline silicon dioxide, have specific gravities between abou-t 2.5 and about 2.9, dielectric constants less than about 5 and usually about 4, and high dielectric stengths, A11 media were scrupulously cleaned by carefully screening, water-washing, and air-drying so that no possible contamination of the edible oil stream could occur. ~ach medium was placed within the experimental electrofilter and subjected to test conditions of the samé nature as described for the electrofilter 37, The incoming raw edible oil stream was taken directly from the drop tank 22 and passed upwardly through the electrofilter at a rate of about 9 gallons per minute and at temperatures between 150 and 200 F. The product edible oil stream from the electrofilter was tested in accordance with the filter disc impurities test, analyzecl for nickel content, and visual appearance. The total throughput volume of the electrofilter was recorded until the onset of product edible oil degradation .
bm:~
, - , , ; ,: - .
, : :
: : : ,: ::. , 9~3 by increased solids content arising :Erom the onset of solids-fillup of the bed of the electrofilter as detected by the initial observance of a Tyndall ef f ec t, The data f.rorn these tests of the media are set forth in the following Tables 1, 2 and 3.
T~BIE 1 Medi~n F-ll Fil-tex Disc Ni./p~Vol/~a~ Ap~e 40 kv @ 0.13-0.30 an~ps 8-~ - 178 C].ear Rate 7.5 - 9 gFrn eclible oil 10 1.0 326 Very Clear @ 165 F. 10 .7 823 Cl~r Bed loading 6~4Lbs,/ft.3 10 ~ 1010 Clear - 1295 Clear 3 . 4 1416 Clear 9 - 1656 Clear
4 - 1895 Gray Tint - . TA~E 2 Medi~n ~1 Filter Disc Ni/ppmVol/gal Appearance 40 kv @ 0~2-0.22 amps 8 - 98 Clec~c Rate 6 - 7 gEm edible oil 7 - 168 Clear @ 185 - 192 F~ 10 . - - ~7ery Clear ~3ed loading 3.8 lbs~/ft.3 10 - 359 Very Clear - - - 408 Very Clear - - Very Clear - 654 Very Clear - - 925 Dark Gray bm ~
- .~; - ~ , . . .
.-- . : -:.:. : : . - :, ,. :
- : . ~ .: : , Medium G-l Filter Disc Ni/ppm Vol/gal Appearance . ~,, . . . :
30 kv @ 6.0 - 3.0 amps. 10 0.2 170 Clear*
~ate 8 - 9 gpm Edible oil 10 1,1 441 Clear @ 202 - 194 F. g~ - 580 Clear Bed Ioadin~ 7~3 lbs./ft.9 9 - 855 Clear 9 ~ 993 Clear - - 1131 Clear - - 1166 Clear lQ 8-~ - 1276 Clear 8-~0~9 1399 Clear 6 - 1523 Hazy Slight Tyndall effect Inspection of the three Tables illustrates the unique operation of the electrofilter system of the present invention in producing a product edible oil ~hi-ch consi$tently contains no inorganic solids and also has a nickel content of about one part per million, Additionally, the edible oil product was characterized by employees af the food industry as "bright and clear". No Tyndall effect was observed in "clear" appearance in the edible oil product. Unexpectedly~ the product edible oil had a "clear" appearance until the filter disc color went from 10 to 8 when the Tyndall effect indicated the approach of a solids-fillup condition in the bed of the electrofilter~
Some slight Tyndall effect was indicated initially with the medium G-l, but this was believed to have occurred as a result of the start-up operation on the excessively larye sizes of the media employed in the bed of the electrofilter . .~ . .
~ bm:
. . .: . ~ ,. , ... . : :
V9~3 The data from the above Tables i~ represented graphically in Fi~ure 3, wherein the throughput capacity of the experimental electrofilter is displayed as one axis while the other axis displays the filter disc impurities number of the edible oil product. It is noted that the medium F-ll gave outstanding results, and it is preferred for the purposes of the present invention. The other media, G-l and M-l, also gave acceptable results~ However, the medium M-l did not have the capacity to remove inoryanic solids as do m~clia F-ll or G-l. All three media do indicate that the edibl~ oil product maintains outstanding puri-ty until the onset of solids-fillup of the bed in the electrofilter.
Then, the deterioration by increased inorganic solids content in the edible oil is very sudden and pronounced. The curve deno~ed "A" is one example of the filtered edible oil produced by a commercial filter press operation in an edible oil plant wherein the filter disc impurity varies from about 2 to about 6. The .nitial nonlinear portion of the media F-ll and M-l curves (until about 400 gallons throughput was reached) is believed to result from bringing a relatively small volume pilot plant unit onto equilibrium conditions at 9 gallons per minute connected to a drop tank having several ten thousands pounds of hydrogenated edible oil.
.
Slight fluctuations in temperature and pressure occurred during the startup which may also e~plain these abnormalities.
An acceptable edible oil product in the commercial operations, after bleaching or acid treating, and several filtrations, has a filter disc impurity color o-f 9. In comparison, the electrofilter of the present invention produces ~ -27-. ,~, , .
bm ,3,.
.... . . ;" . . . ~ . . -~- , , ' - -, ~ .
~()9~)3 the maximum quality of edible oil product in one quick step which may take less than two minutes in comrnercial operations.
The edible oil product frc~m the electrofilter system of the present invention at any ti~e before the onset of solids--fillup of the bed has a filter disc color of 1~ on an average basis, a nickel content of about 1 ppm, and a visual appearance of brigh-t and clear. This edible o:il product from -the electrofilter, without any subsequent treatment, is equal. in chemical and physical prope.rties ~AO the commercial procluc-t obtain~d by scveral filtra~:ion steps ta]~ing several hours within the present day commercial food industry plant.
In addition the edible oil product from electrofiltration is substantially free from all suspended and colloidal inorganic and orgar,ic solids. For example, the nickel content of the edible oil. taken from the drop tank 22 is in the range of several hundred parts per million. It is believed that the colloidal nickel content of this oil is substantially in the tens of parts per million. However, the edible oil product provided by the experimental electrofilter always averaged in the range of about one part per million or less of ni-ckel content. ~hus, edible oil product produced by the system of this invention is equal in appearance, and physical and chemical properties to that edible oil product of the commercial plant.
Returning to Figure 1, the electrofilter 37 upon initial installation should be scrupulously cleaned so that the particulate bed does not contain any type of deleterious material ~hich can enter the edible oil. For this purpose, the electrofilter 37 can be flushed with a heated volume of .
bm:;.
: . -, . ' ' -: ' . : : -~. : . - ,, , - , :
9~3 commercial edible oil from the charge tank 57, cleaning line 61 and throuyh the valved manifolas. In addition, stea~
can be applied throu~h the line 66 to displace congealed edible oil from the electrofiltcr ~7 and/or rernove any other types of organic materials from the bed and/or raise the temperature o~ the bed to such a degree tha~ a stream of nitro~en will bring it in a subs-tantially dry condition.
The edible oil, stream and drain-down liquid Erom the elec-trofilter 37 in this cleaning step may be passed to a blowdown tank 96 through the drain line 94 for sultable disposal.
In addition, the described arrangemen-t for cleaning the electrofilter 37 is important in the case of an inadvertent displacement into the drop tank 22 of improperly hydrogenated material, soap, or fatty material of such undesired characteristics that it would contaminate the electrofilter bed 77. In this instance, the use of the system as an initial cleanup can be employed to remove such deleterious or undesired soaps, acids and the like from the bed of the electrofilter ~7.
Although the specific organic liqui.d has been described as an edible oil, the present invention is not limited to such non-petroleum oil and is equally applicable to other types, such as fats, animal and vegetable oils, and related organic liquids.
From the foregoing, it will be apparent that there has been provided an electrofiltration system of appara-tus and process well adapted for removing inorganic solids from organic liquid streams. In particular, the system can be bm:'`
operated for extended periods of time with a relatlvely - simple cleaning procedure. No contamination of the organic liquid product can occur from the electroEilter system durin~ operation or cleanup. In addltion, the organic liquid product prepared quickly in one electrofiltration s-tep is equal to commercial produc-ts conventionally obtained by multistep filtration. It w111 be ~mderstood that certain features and alterations of the present system may be employed without departing from the spirit of this invention. This is contemplated by, ~nd is within, the scope oE the appended claims. It is intended that the present invention is to be ~aken as an illustration of the present system.
bm:J, -.. - .. : ,.:::-.. : . . . -,. : ,.
- .~; - ~ , . . .
.-- . : -:.:. : : . - :, ,. :
- : . ~ .: : , Medium G-l Filter Disc Ni/ppm Vol/gal Appearance . ~,, . . . :
30 kv @ 6.0 - 3.0 amps. 10 0.2 170 Clear*
~ate 8 - 9 gpm Edible oil 10 1,1 441 Clear @ 202 - 194 F. g~ - 580 Clear Bed Ioadin~ 7~3 lbs./ft.9 9 - 855 Clear 9 ~ 993 Clear - - 1131 Clear - - 1166 Clear lQ 8-~ - 1276 Clear 8-~0~9 1399 Clear 6 - 1523 Hazy Slight Tyndall effect Inspection of the three Tables illustrates the unique operation of the electrofilter system of the present invention in producing a product edible oil ~hi-ch consi$tently contains no inorganic solids and also has a nickel content of about one part per million, Additionally, the edible oil product was characterized by employees af the food industry as "bright and clear". No Tyndall effect was observed in "clear" appearance in the edible oil product. Unexpectedly~ the product edible oil had a "clear" appearance until the filter disc color went from 10 to 8 when the Tyndall effect indicated the approach of a solids-fillup condition in the bed of the electrofilter~
Some slight Tyndall effect was indicated initially with the medium G-l, but this was believed to have occurred as a result of the start-up operation on the excessively larye sizes of the media employed in the bed of the electrofilter . .~ . .
~ bm:
. . .: . ~ ,. , ... . : :
V9~3 The data from the above Tables i~ represented graphically in Fi~ure 3, wherein the throughput capacity of the experimental electrofilter is displayed as one axis while the other axis displays the filter disc impurities number of the edible oil product. It is noted that the medium F-ll gave outstanding results, and it is preferred for the purposes of the present invention. The other media, G-l and M-l, also gave acceptable results~ However, the medium M-l did not have the capacity to remove inoryanic solids as do m~clia F-ll or G-l. All three media do indicate that the edibl~ oil product maintains outstanding puri-ty until the onset of solids-fillup of the bed in the electrofilter.
Then, the deterioration by increased inorganic solids content in the edible oil is very sudden and pronounced. The curve deno~ed "A" is one example of the filtered edible oil produced by a commercial filter press operation in an edible oil plant wherein the filter disc impurity varies from about 2 to about 6. The .nitial nonlinear portion of the media F-ll and M-l curves (until about 400 gallons throughput was reached) is believed to result from bringing a relatively small volume pilot plant unit onto equilibrium conditions at 9 gallons per minute connected to a drop tank having several ten thousands pounds of hydrogenated edible oil.
.
Slight fluctuations in temperature and pressure occurred during the startup which may also e~plain these abnormalities.
An acceptable edible oil product in the commercial operations, after bleaching or acid treating, and several filtrations, has a filter disc impurity color o-f 9. In comparison, the electrofilter of the present invention produces ~ -27-. ,~, , .
bm ,3,.
.... . . ;" . . . ~ . . -~- , , ' - -, ~ .
~()9~)3 the maximum quality of edible oil product in one quick step which may take less than two minutes in comrnercial operations.
The edible oil product frc~m the electrofilter system of the present invention at any ti~e before the onset of solids--fillup of the bed has a filter disc color of 1~ on an average basis, a nickel content of about 1 ppm, and a visual appearance of brigh-t and clear. This edible o:il product from -the electrofilter, without any subsequent treatment, is equal. in chemical and physical prope.rties ~AO the commercial procluc-t obtain~d by scveral filtra~:ion steps ta]~ing several hours within the present day commercial food industry plant.
In addition the edible oil product from electrofiltration is substantially free from all suspended and colloidal inorganic and orgar,ic solids. For example, the nickel content of the edible oil. taken from the drop tank 22 is in the range of several hundred parts per million. It is believed that the colloidal nickel content of this oil is substantially in the tens of parts per million. However, the edible oil product provided by the experimental electrofilter always averaged in the range of about one part per million or less of ni-ckel content. ~hus, edible oil product produced by the system of this invention is equal in appearance, and physical and chemical properties to that edible oil product of the commercial plant.
Returning to Figure 1, the electrofilter 37 upon initial installation should be scrupulously cleaned so that the particulate bed does not contain any type of deleterious material ~hich can enter the edible oil. For this purpose, the electrofilter 37 can be flushed with a heated volume of .
bm:;.
: . -, . ' ' -: ' . : : -~. : . - ,, , - , :
9~3 commercial edible oil from the charge tank 57, cleaning line 61 and throuyh the valved manifolas. In addition, stea~
can be applied throu~h the line 66 to displace congealed edible oil from the electrofiltcr ~7 and/or rernove any other types of organic materials from the bed and/or raise the temperature o~ the bed to such a degree tha~ a stream of nitro~en will bring it in a subs-tantially dry condition.
The edible oil, stream and drain-down liquid Erom the elec-trofilter 37 in this cleaning step may be passed to a blowdown tank 96 through the drain line 94 for sultable disposal.
In addition, the described arrangemen-t for cleaning the electrofilter 37 is important in the case of an inadvertent displacement into the drop tank 22 of improperly hydrogenated material, soap, or fatty material of such undesired characteristics that it would contaminate the electrofilter bed 77. In this instance, the use of the system as an initial cleanup can be employed to remove such deleterious or undesired soaps, acids and the like from the bed of the electrofilter ~7.
Although the specific organic liqui.d has been described as an edible oil, the present invention is not limited to such non-petroleum oil and is equally applicable to other types, such as fats, animal and vegetable oils, and related organic liquids.
From the foregoing, it will be apparent that there has been provided an electrofiltration system of appara-tus and process well adapted for removing inorganic solids from organic liquid streams. In particular, the system can be bm:'`
operated for extended periods of time with a relatlvely - simple cleaning procedure. No contamination of the organic liquid product can occur from the electroEilter system durin~ operation or cleanup. In addltion, the organic liquid product prepared quickly in one electrofiltration s-tep is equal to commercial produc-ts conventionally obtained by multistep filtration. It w111 be ~mderstood that certain features and alterations of the present system may be employed without departing from the spirit of this invention. This is contemplated by, ~nd is within, the scope oE the appended claims. It is intended that the present invention is to be ~aken as an illustration of the present system.
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Claims (32)
PROPERTY OR PRIVILEGE IS CLAIMED ARE DEFINED AS FOLLOWS:
1. An electrofiltration process for removing hydrogenation catalyst and other undissolved solids from a stream of edible oil which has been subjected to catalytic hydrogenation, said process comprising:
a. providing the stream of so hydrogenated edible oil at a temperature of at least about 150°F.;
b. passing said stream of oil through a chemically inert bed having multitudinous flow channels between rigid masses of a solid material having a dielectric constant not in excess of about 7;
c. establishing a d.c. electrical field within said bed having an intensity sufficient of removing the undissolved solids from said stream of oil by electrically induced adhesion of the solids in said bed material;
d. removing the purified oil stream with reduced undissolved solids content from said bed; and e. cleaning at selected intervals at least a portion of said material of adhering solids by interruption of said electrical field, passing a cleaning fluid through the material to remove adhering solids from said material and removing the fluid with the removed solids from said material.
a. providing the stream of so hydrogenated edible oil at a temperature of at least about 150°F.;
b. passing said stream of oil through a chemically inert bed having multitudinous flow channels between rigid masses of a solid material having a dielectric constant not in excess of about 7;
c. establishing a d.c. electrical field within said bed having an intensity sufficient of removing the undissolved solids from said stream of oil by electrically induced adhesion of the solids in said bed material;
d. removing the purified oil stream with reduced undissolved solids content from said bed; and e. cleaning at selected intervals at least a portion of said material of adhering solids by interruption of said electrical field, passing a cleaning fluid through the material to remove adhering solids from said material and removing the fluid with the removed solids from said material.
2. The electrofiltration process of claim 1 wherein said cleaning of said material and adhering solids is undertaken when the purified stream of hydrogenated edible oil approaches conditions of increased solids content by solids-fillup of said bed.
3. The electrofiltration process of claim 1 wherein immediately prior to cleaning said bed, a dry, inert non-oxidizing gas is passed through said bed with said d.c.
electrical field established therein to displace the purified organic liquid from said bed without displacement of the adhering solids.
electrical field established therein to displace the purified organic liquid from said bed without displacement of the adhering solids.
4. The electrofiltration process of claim 1 wherein said material comprises particles of a mineral containing crystalline silicon dioxide, said mineral having a hardness value of at least 7 on the Mohs scale of hardness, a specific gravity being about 2.5 and about 2.9, a dielectric constant of about 4 and a discontinuous surface configuration provided by nature.
5. The eletrofiltration process of claim 4 wherein said particles are crushed flint with average particle size of about 2.5 mm.
6. The electrofiltration process of claim 4 wherein the cleaning fluid is the purified hydrogenated edible oil adjusted in temperature until organic solids are in solution and cannot plug said bed.
7. The electrofiltration process of claim 6 wherein immediately after cleaning of said bed material with the purified hydrogenated edible oil, a dry, inert non-oxidizing gas is passed through said bed to displace the purified hydrogenated edible oil serving as the cleaning fluid from said bed prior to establishment of said d.c. electrical field.
8. An electrofiltration process for removing solids from an organic liquid stream comprising:
a. passing said liquid stream through a bed of chemicaly inert, hard granular particles of a rigid, substantially incompressible material, said particles being non-spheroidal with a relatively discontinuous surface configuration and a dielectric constant not in excess of about 7;
b. establishing a d.c. electrical field within said bed having an intensity sufficient for removing the solids from the organic liquid stream by electrically induced adhesion of the solids on said particles;
c. removing the purified organic liquid stream with reduced solids content from said bed; and d. cleaning at selected intervals at least a portion of said particles of adhering solids by interrupting said electrical field, passing a cleaning fluid through the bed to remove adhering solids from said particles and removing the fluid with the removed solids from said particles being cleaned.
a. passing said liquid stream through a bed of chemicaly inert, hard granular particles of a rigid, substantially incompressible material, said particles being non-spheroidal with a relatively discontinuous surface configuration and a dielectric constant not in excess of about 7;
b. establishing a d.c. electrical field within said bed having an intensity sufficient for removing the solids from the organic liquid stream by electrically induced adhesion of the solids on said particles;
c. removing the purified organic liquid stream with reduced solids content from said bed; and d. cleaning at selected intervals at least a portion of said particles of adhering solids by interrupting said electrical field, passing a cleaning fluid through the bed to remove adhering solids from said particles and removing the fluid with the removed solids from said particles being cleaned.
9. The electrofiltration process of claim 8 wherein said cleaning of the particles of adhering solids is under-taken when the purified organic liquid stream approaches conditions of increased solids content by solids-fillup of said bed.
10. The electrofiltration process of claim 9 wherein said particles are crushed flint with average particle size of about 2.5 mm.
11. The electrofiltration process of claim 1 wherein the purified said hydrogenated edible oil stream from said bed is optically scanned to detect when the purified organic liquid stream degrades to a predetermined optical quality by increased solids content from solids-fillup of said bed and wherein when said predetermined optical quality is detected said electrical field is interrupted, a cleaning fluid is passed through said bed to remove adhering solids from said particles and the cleaning fluid with the removed solids is removed from said bed.
12. The electrofiltration process of claim 4 wherein said mineral is selected from the group consisting of flint, garnet, granite and fused quartz.
13. The electrofiltration process of claim 1 wherein said material comprises hard granular particles of a rigid substantially incompressible material, said particles being non-spheroidal and with a relatively discontinuous surface configuration.
14. The electrofiltration process of claim 13 wherein said particles are those of a mineral containing crystalline silicon dioxide, said mineral having a hardness value of at least 7 on the Mohs scale of hardness, a specific gravity between about 2.5 and about 2.9 and a dielectric constant of about 4.
15. The electrofiltration process of claim 14 wherein said mineral is selected from the group consisting of flint, garnet, granite and fused quartz.
16 The electrofiltration process of claim 13 wherein said stream of hydrogenated edible oil is passed through said bed at a superficial rate of about 12 inches per minute during removal of solids from said stream.
17. The electrofiltration process of claim 14 wherein the cleaning fluid is purified said hydrogenated edible oil adjusted in temperature until said organic solids are in solution and cannot plug said bed.
18. The electrofiltration process of claim 17 wherein said purified hydrogenated edible oil providing the cleaning fluid is passed through said bed at a superficial rate of at least 16 inches per minute during removal of the adhering solids from the particles.
19. The electrofiltration process of claim 13 wherein the purified said hydrogenated edible oil stream from said bed is optically scanned to detect when the purified organic liquid stream degrades to a predetermined optical quality by increased solids content from solids-fillup of said bed and wherein said predetermined optical quality is detected said electrical field is interrupted, a cleaning fluid is passed through said bed to remove adhering solids from said particles and the cleaning fluid with the removed solids is removed from said bed.
20. The electrofiltration process of claim 19 wherein the sequence of steps including the interruption of the electrical field, and the passing and removal of the cleaning fluid is initiated automatically in response to a signal indicating that said predetermined optical quality has been detected.
21. The process of claim 19 wherein, prior to interrupting said electrical field, a dry, inert, non-oxidizing gas is passed through said bed with the d.c. electrical field established to displace the purified said hydrogenated edible oil from said bed without displacement of the adhering solids.
22. The electrofiltration process of claim 11 wherein the sequence of steps including the interruption of the electrical field, and the passing and removal of the cleaning fluid is initiated automatically in response to a signal indicating that said predetermined optical quality has been detected.
23. The electrofiltration process of claim 8 wherein said particles are those of a mineral containing crystalline silicon dioxide, said mineral having a hardness value of at least 7 on the Mohs scale of hardness, a specific gravity between about 2.5 and about 2.9 and a dielectric constant of about 4.
24. The electrofiltration process of claim 23 wherein said mineral is selected from the group consisting of flint, garnet, granite and fused quartz.
25. The electrofiltration process of claim 24 wherein said particles are crushed flint with average particle size of about 2.5 mm.
26. The electrofiltration process of claim 8 wherein said organic liquid stream is passed through said bed at a superficial rate of about 12 inches per minute during removal of solids from said stream.
27. The electrofiltration process of claim 23 wherein the cleaning fluid is the purified organic liquid.
28. The electrofiltration process of claim 27 wherein the organic liquid stream providing the cleaning fluid is passed through said bed at a superficial rate of at least 16 inches per minute during removal of the adhering solids from the particles.
29. The electrofiltration process of claim 8 wherein the purified organic liquid stream from said bed is optically scanned to detect when the purified organic liquid stream degrades to a predetermined optical quality by increased solids content from solids-fillup of said bed and wherein when said predetermined optical quality is detected, said electrical field is interrupted, a cleaning fluid is passed through said bed to remove adhering solids from said particles and the cleaning fluid with the removed solids is removed from said bed.
30. The electrofiltration process of claim 29 wherein the sequence of steps including the interruption of the electrical field and the passing and removal of the cleaing fluid is initiated automatically in response to a signal indicating that said predetermined optical quality has been detected
31. The process of claim 8 wherein, prior to interrupting said electrical field, a dry, inert, non-oxidizing gas is passed through said bed to displace the purified organic liquid from said bed without displacement of the adhering solids.
32. An electrofiltration process for removing hydrogenation catalyst and other undissolved solids from a stream of edible oil which has been subjected to catalytic hydrogenation, said process comprising:
a. providing the stream of so hydrogenated edible oil at a temperature of at least about 150°F.;
b. passing said stream of oil through a chemically inert bed having multitudinous flow channels between rigid masses of a solid material having a dielectric constant not in excess of about 7;
c. establishing a d.c. electrical field within said bed having an intensity sufficient for removing the undissolved solids from said stream of oil by electrically induced adhesion of the solids in said bed material; and d. removing the purified oil stream with reduced undissolved solids content from said bed.
a. providing the stream of so hydrogenated edible oil at a temperature of at least about 150°F.;
b. passing said stream of oil through a chemically inert bed having multitudinous flow channels between rigid masses of a solid material having a dielectric constant not in excess of about 7;
c. establishing a d.c. electrical field within said bed having an intensity sufficient for removing the undissolved solids from said stream of oil by electrically induced adhesion of the solids in said bed material; and d. removing the purified oil stream with reduced undissolved solids content from said bed.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CA346,790A CA1100903A (en) | 1975-11-28 | 1980-02-29 | Electrofiltration system for purifying organic liquids |
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US636,261 | 1975-11-28 | ||
| US05/636,261 US4040926A (en) | 1975-11-28 | 1975-11-28 | Electrofiltration process for purifying organic liquids |
| CA266,570A CA1097259A (en) | 1975-11-28 | 1976-11-25 | Electrofiltration system for purifying organic liquids |
| CA346,790A CA1100903A (en) | 1975-11-28 | 1980-02-29 | Electrofiltration system for purifying organic liquids |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1100903A true CA1100903A (en) | 1981-05-12 |
Family
ID=27164795
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA346,790A Expired CA1100903A (en) | 1975-11-28 | 1980-02-29 | Electrofiltration system for purifying organic liquids |
Country Status (1)
| Country | Link |
|---|---|
| CA (1) | CA1100903A (en) |
-
1980
- 1980-02-29 CA CA346,790A patent/CA1100903A/en not_active Expired
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