CA1096545A - Photocurable composition for coating - Google Patents

Abstract

A photocurable composition suitable for coatings comprising a polythiol and two different polyenes. These coatings compositions are suitable for coating polycarbonate articles.

Description

5~ 8SP-~2~g This invention is directed to a photocurable composition suitable for coatings comprising a polythiol, and two dif-ferent polyenes. These coating compositions are suitable for coating polycarbonate articles. ~--Commercial liquid coating compositions are available.
Many of these coating compositions are not suitable for coating polycarbonate articles since they are not com-patible with the polycarbonate. Also, the uncured coating may adversely affect the polycarbonate article by stress cracking and crazing it, by causing crack propogatlon into the polycarbonate as a result of brittleness of the coating itself and/or by reducing the properties of the polymer generally such as, for example, impact resistance, elonga-tion, tensile strength and so on. Further, several coatings while compatible with the polycarbonate have little or no chemical barrier properties and/or poor adhesion.
Therefore, a successful coating for polycarbonate articles must be compatible with the polycarbonate and provide barrier or other desirable surface properties while main-taining mechanical or other properties of the polymer sub-strate and themselves provide chemically resistant surfaces.
Also, the cured coating, in this particular application, should particularly provide the coated polycarbonate article with anti-skid properties in addition to the chemical barrier properties necessary to prevent crazing of the subs-trate polycarbonate in chemically aggressive environments.
The instant invention is concerned with a photocurable composition suitable for coating polycarbonate articles comprising a polythio and two different polyenes. These coating compositions are especially suitable for coating polycarbonates. Upon curing, the coatings provide a poly-carbonate article with antiskid properties, chemical re-- 1 - 'i~

~965~5 8SP-224g sistance, scratch resistance and chemical barrier properties resulting in stress-crazing resistance. Also, the coating composition of the instant invention allows the poly-carbonate substrate to retain its inherent desirable physical properties (particularly impact resistance) by which it is distinguished.
. The photocurable coating composition comprises:
(a) a polythiol of the general formula:

Rl ( 2 )a wherein Rl and R2 are organic moieties containing no reactive carbon-to-carbon unsaturation and a is 2 to 4;
. (b) a polyene of the general formula:

~, O
~, 11 R3 ( COR4-CH C~2)b wherein R3 and R4 are organic moieties containing no reactive carbon-to-carbon unsaturation and b is 2 or greater; and (c) a polyene of the general formula:

B HO-R ~ ~C-R ~CH=CH J

wherein R6 and R7 are organic moieties containing no reactive carbon-to-carbon unsaturation and c is 1 or greater, and wherein (a) and (b) plus (c) are used in stoichiometric amounts.
The polythiols of (a) are prepared by reacting an ester of thiol containing acids of the formula HS-R2COOH wherein R2 is an organic moiety containing no reactive carbon-to-carbon unsaturation, with polyphydroxy compounds of structureRl (OH)a wherein Rl is an organic moiety containing no re-active carbon-to-carbon unsaturation and a is 2 to 4. These 4~ 8SP-224~

components react under conditions known in the art and as are set forth in U.S. Patent No. 3,661,744 dated May 9,1972.
Preferably, the polythiol of (a) has the following general formula: O

1 ( CH OC-R SH) wherein Rl and R2 are straight chain aliphatic moieties con-taining no reactive carbon-to-carbon unsaturation and a is

2 to 4.
The polyenes of (b) and (c) are prepared by methods known in the art and as set forth in U.S. Patent No.3,661,744 dated May 9, 1972. Preferred polyenes of type (b) have the following general formula:

~~ . .
R3 (- COCH2CH=CH2)b herein R3 and b are as defined above.
o/~go~ ~ s Most preferably, the polyenes of (b) are oli~amc~ of diallyl phthalate having residual unsaturation of the type represented by the general formula:

R7 ( OC COCH2CH=CH2)b O O

wherein R7 is an organic moiety derived from diallyl phtha-late by oligimerization and b is an integer of 2 or greater.
The polyenes of (c) preferably have the following general formula: CH3 0'f~ 1 0 ~ ~ "
HO-R60C~ -- ~ ~ NCOR7 2 ~ 545 8SP-2248 wherein R6 and R7 are defined as above.

Most preferably, the polyenes of (c) are of the formula:
R "1~3 H-R6OCN ~ NCOC~I2CH=CH2 wherein R6 is as defined above and has a molecular weight of about 1000.
The photocurable composition is a liquid polymer and may be formulated for use as 100 percent solids, or disposed in organic solvents, or as dispersions or emulsions in aqueous media, prior to curing.
The curable liquid polymer compositions prior to curing may readily be pumped, poured, siphoned, brushed, sprayed, doctored, or otherwise handled as desired. Following application, curing in place to the polycarbonate article may be effected either very rapidly or extremely slowly as desired by manipulation of the compounding ingredients and the method of curing.
The curing reaction may be initiated by most actinic light sources that disassociate or abstract a hydrogen atom from an SH group, or accomplish the equivalent thereof.
Generally, the rate of the curing reaction may be increased by increasing the temperature of the composition at the time~
of initiation of cure. In many applications, however, the curing is accomplished conveniently and economically by operating at ordinary room temperature conditions.
By proper choice of type and concentration of photo-curing rate accelerator for initiation, the curing period required for conversion of the polythiol-polyenes com-position from the liquid to the solid state may be varied greatly as desired. In combination with suitable ac-ce:Lerators or retarders, the curing period may vary from about a second or less to about 30 days or more. In general, ~ ~g 6 5 ~ ~ 8SP-2Z48 short curing periods are achieved in applications where thin films of curable compositions are required, such as in the field of coatings whereas the long curing periods are achieved and desired where more massive layers of composi-tion are required, such as in the field of elastomeric sealants.
A class of actinic light useful herein is ultraviolet light and other forms of actinic radiation which are normally found in radiation emitted from the sun or from artificial sources such as Type RS Sunlamps, carbon arc lamps, xenon arc lamps, mercury vapor lamps, tungsten halide lamps and the like. Ultraviolet radiation may be used most efficiently if the photocurable coating composition contains a suitable photocuring rate accelerator. Curing periods may be ad-justed to be very short and hence commercially economical by proper choice of ultraviolet source, photocuring rate accelerator and concentration thereof, temperature and molecular weight, and reactive group functionality of the polyene and polythiol.
Conventional curing inhibitors or retarders which may be used in order to stabilize the components or curable com-positions so as to prevent premature onset of curing may in-clude hydroquinone; p-tert-butyl catechol; 2,6-di tert-butyl-p-methylphenol; phenothiazine; N-phenyl-2-naphthyla-mine; inert gas atmosphere such as helium, argon, nitrogen and carbon dioxide; vacuum, and the like.
It is understood to be within the scope of this invention that the photocuring rate accelerator may be present as a separate and distinct component such as azobenzene, as a mi~ture of two or more separate components, such as benzo-phenone; benzanthrone; anthrone and dibenzosuberone; carbon tetrachloride and phenanthrene; and the like, or in chemically ~654~ 8SP-224~

form within the molecular strcture of either the polyenes or the polythio. An example of this latter condition wherein the photocuring rate accelerator is present not as a separate component, but rather in a form chemically combined within the polyene component is the following structure which contains four reactive carbon-to-carbon unsaturated groupings and one diaryl ketone grouping per average molecule:

O O
,. -CH2=CH-CH20-C C-OCH2CH=CH2 CH2=CH-CH2O-C- ~ C ~ 2 2 O O
It is further understood that the polyenes, the polythiol or the photocuring rate accelerator may be formed in situ in the photocurable composition without departing from the spirit of this invention.
Specifically useful herein are chemical photocuring rate accelerators such as benzophenone, acetophenone, acenaphthene-quinone, o-methyoxy benzophenone, thioxanthen-9-one, xanthen-9-one, 7-H-Benz (de) anthracen-7-one., dibenzosuberone, 1-napthhaldehyde, 4,4'-bis (dimethylamino) benzophenone, fluorene-0-one, l'-acetonaphthane, antraquinone, l-indanone, 2-tert-butyl anthraquinone, valerophenone, hexanophenone, 3-phenyl-butyrophenone, p-morpholinopropiophenone, 4-morpholino-benzophenone, p-diacetylbenzene, 4-amino-benzophenone, 4'-methoxyacetophenone, benzaldehyde, ~ -tetralone, 9,ace-tylphenanthrene, 2-acetylphenanthrone, 10-thioxanthenone, 3-acetylphenanthrene, 3-acetylphenanthrene, 3-acetylindole, 1,3,5-triacetylbenzene and the like, including blends thereof, to greatly reduce the exposure times.
The curing rate accelerators are usually added in an amount ranging from about 0.005 to about 50 percent by weight of the photocurable composition, with a preferred 8SP-Z~4~
:~9~45 range being from about 0.05 to about 25 percent by weight.
Preferred photocuring rate accelerators are the aldehyde and ketone carbonyl compounds having at least one aromatic o nucleus attached directly to the -C- group.
The compositions to be cured, i.e., (converted to solid resins or elastomers) in accord with the present invention may, if desired, include such additives as antioxidants, accelerators, dyes, inhibitors, activators, fillers, pig-ments, antistatic agents, flame-retardant agents, thickeners, thixotropic agents, surface-active agents, viscosity modifiers, extending oils, plasticizers,tackifiers and the like within the scope of this invention. Such additives are usually preblended with the polyene or polythiol prior to or during the compounding step. Operable fillers include natural and synthetic resins, carbon black, glass fibers, wood flour, clay, silica, alumina, carbonates, oxides, hydroxides, sili-cates, glass flakes, glass beads, borates, phosphates, dia-tomaceous earth, talc, kaolin, barium sulfate, calcium sulfate, calcium carbonate, antimony oxide and the like.
The aforesaid additives may be present in quantities up to 500 parts or more per 100 parts polymer by weight and pre-ferably about 0.0005 to about 300 parts on -the same basis.
A useful method of compounding is to prepare in an ambient atmosphere by conventional mixing techniques but in the absence of actinic radiation a composition consisting of polyenes, antioxidant (to inhibit spontaneous oxygen-initiated curing), polythiol, UV sensitizer of photoinitiator, and other inert additives. This composition may be stored in the dark for extended periods of time, but on exposure to actinic radiation (e.g., ultraviolet light, sunlight, etc.) will cure controllably and in a very short time period to 5 8sP-2~4a solid polythioether products.
The coating composition of the instant invention may be applied to the polycarbonate surface by any conventional coating technique such as roll, curtain or spray.
In the practice of this invention, any of the aromatic polycarbonates can be employed herein. These are homo-polymers and copolymers and mixtures thereof that are pre-pared by reacting a dihydrice phenol with a carbonate precursor. Typical of some of the dihydric phenols that may be employed in the practice of this invention are bis-phenol-A, (2,2-bis(4-hydroxyphenyl) propane), bis (4-hydroxyphenyl) methane, 2,2-bis(4-hydroxy-3-methylphenyl) propane, 4,4-bis(4-hydroxyphenyl) heptane 2,2-(3,5,3'-tetra-chloro-4,4'-dihydroxydiphenyl) propane, 2,2-3,5,3',5'-tetra-bromo-4,4'-dihydroxydiphenyl) propane, (3,3'-dichloro 4,4'-dihydroxyphenyl) methane. Other dihydric phenols of the bisphenol type are also available and are disclosed in U.S.
No.2,999,835 dated September 12, 1961, U.S. 3,028,365 dated April 3, 1962, and U.S. Patent No. 3,334,154 dated August 1, 1967.
It is, of course, possible to employ two or more different dihydric phenols or a copolymer of a dihydric phenol with a glycol or with hydroxy or acid terminated polyester, or with a dibasic acid in the event a carbonate copolymer or interpolymer rather than a homopolymer is desired for use in the preparation of the aromatic car-bonate polymers of this invention. Also employed in the practice of this lnvention may be blends of any of the above materials to provide the aromatic carbonate polymer.
The carbonate precursor may be either a carbonyl halide, a carbonate ester of a haloformate. The carbonyl halides which can be employed hereln are carbonyl bromide, car-~6~5 ~SP-224Z

bonyl chloride and mixtures thereof. Typical of the car-bonate esters which may be employed herein are diphenyl carbonate, di-(halophenyl) carbonates such as di-(chloro-phenyl) carbonate, di-(bromophenyl) carbonate, di-(trichloro-phenyl) carbonate, di-(tribromophenyl) carbonate, etc., di-(alkylphenyl) carbonate such as di(tolyl) carbonate, etc., di~(naphthyl) carbonate, di-(chloronaphthyl) carbonate, phenyl tolyl carbonate, chlorophenyl chloronaphthyl carbonate, etc., or mixtures thereof. The haloformates suitable for use herein include bis-haloformates of dihydric phenols (bis-chloroformates of hydroquinone, etc.) or glycols (bishalo-formates of ethylene glycol, neopentyl glycol, polyethylene glycol, etc.). While other carbonate precurso~5will occur to those skilled in the art, carbonyl chloride, also known as phosegene, is preferred.
Also included are the polymeric derivatives of a dih-ydric phenol, a dicarboxylic acid and carbonic acid. These are disclosed in U.S. Patent No. 3,169,121 dated February 9, 1965.
The aromatic carbonate polymers of this invention may be prepared by employing a molecular weight regulator, an acid acceptor and a catalyst. The molecular weight regulators which can be employed in carrying out the process of this invention include monohydric phenols such as phenol, chroman-T, paratertiarybutylphenol, parabromophenol, primary and secondary amines, etc. Preferably, phenol is employed as the molecular weight regulator.
A suitable acid acceptor may be either an organic or an inorganic acid acceptor. A suitable organic acid acceptor is a tertiary amine and includes such materials as pyridine, trieth~lamine, dimethylaniline, tributylamine, etc. The inorganic acid acceptor may be one which can be either a ~965915 ~sp-2248 carbonate, a bicarbonate, or a phosphate of an alkali or alkaline earth metal.
The catalysts which are employed herein can be any of the suitable catalysts that aid the polymerization of bisphenol-A with phosgene. Suitable catalysts include tertiary amines such as for example, triethylamine, tripropylamine, N,N-dimethylaniline, quaternary ammonium compounds such as, for example, tetraethylammonium bromide, xetyl triethyl ammonium bromide, tetra-n-heptylammonium iodide, tetra-n-propyl ammonium bromide, tetramethylammonium chloride, tetramethyl ammonium hydroxide, tetra-n-butylammonium iodide, benzyltri-methylammonium chloride and quaternary phosphonium compounds such as for example, n-butyltriphenyl phosphonium bromide and methyltriphenyl phosphonium bromide.
Also, included herein are branched polycarbonates wherein a polyfunctional aromatic compound is reacted with the dih-ydric phenol and carbonate precursor to provide a thermoplastic randomly branches polycarbonate.
These polyfunctional aromatic compounds contain at least three functional groups which are carboxyl, carboxylic an-hydride, haloformyl or mixtures thereof. Examples of these polyfunctional aromatic compounds which may be employed in the practice of this invention include: trimellitic anhydride, trimellitic acid, trimellityl trichloride, 4-chloroformyl phthalic anhydride, pyromellitic acid, pyromellitic dian-hydride, mellitic acid, mellitic anhydride, trimesic acid, benzophenonetetracarboxylic acid, benzophenonetetracarboxylic anhydride and the like. The preferred polyfunctional aro-matic compounds are trimellitic anhydride or trimellitic acid, or their haloformyl derivatives.
Also, included herein are blends of a linear poly-carbonate and a branched polycarbonate.

~965~5 8SP-2248 The following examples are set forth to illustrate more clearly the principle and practice of this invention to those skilled in the art. Unless otherwise specified, where parts or percents are mentioned, they are parts or percents by weight.
Example 1 A sample of a polycarbonate of 2,2'-bis-(4-hydroxyphenyl) propane having an intrinsic viscosity of 0.57 deciliters is molded into these specimens of 4" x 4" x 1/4" and tested for toughness and stress-crazing.
The toughness of the specimen is determined by moving the fingernails of a hand back and forth across the test specimen with medium pressure and observing whether or not the coating scratches.
The stress-crazing of the 4" x 4" x 1/4" specimen is determined by placing it on a material, such as an equivalent size of carpet, placing a steel ball in the center of the combination and applying a load plate of 100 lbs. to the steel ball. The sample is allowed to remain under stress for 7 days~ The sample of polycarbonate is then examined around the stress point for any sign of stress crazing.
The polycarbonate of this example i5 molded into a test specimen of 10" x 10" x 1/4" and tested for its anti-skid properties. The anti-skid rating is determined by placing three 7/8" diameter steel balls, welded together to form a triangle, on the test specimen and raising one end of the specimen vertically while keeping the opposite end on the horizontal plane. The distancs in inches to which the edge is raised vertically when the weight slides down the sample is recorded.
A value of 7-8 is considered acceptable.
The test results are summarized in Table I.
Example 2 Sheets of 4" x 4" x 1/4" and 10" x 10" x 1/4", made from the polycarbonate of Example 1, were coated with a ~9~5~5 ~SP-~24~

coating which is a mixture of a stoichiometric amount of a thiol of the formula: 0

3 H2C ( CH20CCH2CH2SH)3 and a polyene of the formula:

~LC OCH2CH=CH2 in a thickness in the range of 0.5 mils to 2.5 mils and cured with ultraviolet light for 60 seconds. The coated sheets were tested as described in Example 1 and also tested for coating adhesion.
The coating adhesion is measured on the coated sh~et with scotch tape. In the unscribed coating adhesion test, a strip of scotch tape is applied to the surface of the coating, taking care to hold one end of the strip away from the surface. The tape is removed rapidly by pulling the free end at a 90~ angle away from the surface. Removal of the coating with the tape is considered adhesion failure. In the scribed coating adhesion test, the coating surface is scribed with a sharp instrument such as a razor blade or a Gardner cross-cut (lattice cutting) tester. ~ -The scribed area consists of two sets of parallel scribes 1-2 mm.
apart, perpendicular to each other~ The scotch tape is applied (as above) over the~scribed area and removed in the same manner as above. The coating is then examined for partial or complete removal of the squares or no change.
Example 3 Sheets of 4" x 4" x 1/4" and 10" x 10" x 1/4" made from the polycarbonate of Example 1, were coated with a coating which is a mixture of a stoichiometric amount of the thiol of Example 2 and a polyene of the formula:

~396~ 8SP-2248 H0 C H OC~ - ( ~ CC3H6 1 OCN ~ ~ NCOCH2CH=CH2 where n is an integer wherein the molecular weight is equal to 1000, in a thickness in the range of 9.5 mils to 2.5 mils and cured with ultraviolet light for 60 seconds. The coated sheets were tested as described in Examples 1 and 2. ~he results are set forth in Table I.
Example 4 Sheets of 4" x 4" x 1/4" and 10" x 10" x 1/4'~ made from the polycarbonate of Example 1 were coated with a coating which is a mixture of a stoichiometric amount of the thiol of Example 2 ; and a stoichiometric amount of the combination of a polyene of the formula:

--COCH2CH=CH2 ~--COCH CH=CH

and a polyene of the formula: CH3 H0 ~C3H60CN ~ 3 6 ~ ~ ~CcH2cH=cH2 where n is an integer wherein the molecular weight is equal to 1000, in a thickness in the range of 0.5 mils to 2.5 mils and cured ~ith ultraviolet light for 60 seconds. The coated sheets were tested as described in Examples 1 and 2. The results are set forth in Table I.

Example 1 Example 2 Example 3 Example 4 Toughness Pass ~'ail Pass Pass Stress Crazing Fail Pass Fail Pass Anti-Skid 3-4 6-8 7-8 7-8 Adhesion ~/A Pass Fail Pass Although the above examples have shown various modi-fications of the present invention, other variations are possible in the light of the above teachings. It is therefore to be understood that changes may be made in the particular embodiments of the invention described which are within the full intended scope of the invention as defined by the appended claims.

Claims (8)

The embodiments of the invention in which an exclusive property or privilege is claimed are defined as follows:

1. A photocurable coating composition comprising:
(a) a polythiol of the general formula:

wherein R1 and R2 are organic moieties containing no reactive carbon-to-carbon unsaturation and a is 2 to 4;
(b) a polyene of the general formula:

wherein R3 and R4 are organic moieties containing no reactive carbon-to-carbon unsaturation and b is 2 or greater; and (c) a polyene of the general formula:

wherein R6 and R7 are organic moieties containing no reactive carbon-to-carbon unsaturation and c is 1 or greater, and wherein (a) and (b) plus (c) are used in stoichiometric amounts.

2. A coated polycarbonate article having a coating thereon comprising:
(a) a polythiol of the general formula:

wherein R1 and R2 are organic moieties containing no reactive carbon-to-carbon unsaturation and a is 2 to 4;
(b) a polyene of the general formula:

wherein R3 and R4 are organic moieties containing no reactive carbon-to-carbon unsaturation and b is 2 or greater; and (c) a polyene of the general formula:

wherein R6 and R7 are organic moieties containing no reactive carbon-to-carbon unsaturation and c is 1 or greater, and wherein (a) and (b) plus (c) are used in stoichiometic amounts.

3. The coated polycarbonate article of claim 2 in the form of a sheet.

4. The coated polycarbonate article of claim 2 wherein the polythiol of (a) has the following formula:

wherein R1 and R2 are straight chain aliphatic moieties containing no reactive carbon-to-carbon unsaturation and a is 2 to 4.

5. The coated polycarbonate article of claim 2 wherein the polyene of (b) is an oligomer of diallyl phthalate having residual unsaturation of the type represented by the general formula:

wherein R7 is an organic moiety derived from diallyl phthalate by oligomerization and b is an integer of 2 or greater.

6. The coated polycarbonate article of claim 2 wherein the polyene of (b) is of the formula:

.

7. The coated polycarbonate article of claim 2 wherein the polyene of (c) is of the formula:

wherein R6 and R7 are organic moieties containing no reactive carbon-to-carbon unsaturation.

8. The coated polycarbonate article of claim 2 wherein the polyene of (c) of the formula:

wherein R6 is an organic moiety containing no reactive carbon-to-carbon unsaturation and has a molecular weight of about 1000.