CA1085341A - Method of deuterium isotope separation and enrichment - Google Patents
Method of deuterium isotope separation and enrichmentInfo
- Publication number
- CA1085341A CA1085341A CA281,969A CA281969A CA1085341A CA 1085341 A CA1085341 A CA 1085341A CA 281969 A CA281969 A CA 281969A CA 1085341 A CA1085341 A CA 1085341A
- Authority
- CA
- Canada
- Prior art keywords
- deuterium
- molecules
- enriched
- olefin
- depleted
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229910052805 deuterium Inorganic materials 0.000 title claims abstract description 105
- YZCKVEUIGOORGS-OUBTZVSYSA-N Deuterium Chemical compound [2H] YZCKVEUIGOORGS-OUBTZVSYSA-N 0.000 title claims abstract description 97
- 238000000034 method Methods 0.000 title claims abstract description 50
- 238000005372 isotope separation Methods 0.000 title abstract description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 16
- 238000000926 separation method Methods 0.000 claims abstract description 13
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 8
- 125000004431 deuterium atom Chemical group 0.000 claims abstract 4
- 150000001336 alkenes Chemical class 0.000 claims description 26
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 24
- 241000894007 species Species 0.000 claims description 19
- -1 3-cyclopentenyl Chemical group 0.000 claims description 7
- 230000005855 radiation Effects 0.000 claims description 6
- 238000000354 decomposition reaction Methods 0.000 claims description 4
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 claims description 4
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 3
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims description 3
- 239000000047 product Substances 0.000 abstract description 15
- 239000000126 substance Substances 0.000 abstract description 6
- 238000010521 absorption reaction Methods 0.000 abstract description 5
- 239000007858 starting material Substances 0.000 abstract description 5
- 238000004821 distillation Methods 0.000 abstract description 3
- 239000007795 chemical reaction product Substances 0.000 abstract description 2
- 239000012141 concentrate Substances 0.000 abstract description 2
- 238000001311 chemical methods and process Methods 0.000 abstract 1
- 238000001704 evaporation Methods 0.000 abstract 1
- 230000008020 evaporation Effects 0.000 abstract 1
- 238000005007 materials handling Methods 0.000 abstract 1
- 238000005192 partition Methods 0.000 abstract 1
- XLYOFNOQVPJJNP-ZSJDYOACSA-N Heavy water Chemical compound [2H]O[2H] XLYOFNOQVPJJNP-ZSJDYOACSA-N 0.000 description 14
- 230000008569 process Effects 0.000 description 13
- LPIQUOYDBNQMRZ-UHFFFAOYSA-N cyclopentene Chemical compound C1CC=CC1 LPIQUOYDBNQMRZ-UHFFFAOYSA-N 0.000 description 10
- 230000003197 catalytic effect Effects 0.000 description 8
- 150000001975 deuterium Chemical group 0.000 description 8
- 238000006243 chemical reaction Methods 0.000 description 7
- 239000003054 catalyst Substances 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 150000003254 radicals Chemical class 0.000 description 6
- RGSFGYAAUTVSQA-UHFFFAOYSA-N pentamethylene Natural products C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 5
- 230000003595 spectral effect Effects 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 230000009102 absorption Effects 0.000 description 4
- 125000004429 atom Chemical group 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 229910052739 hydrogen Inorganic materials 0.000 description 4
- 238000001228 spectrum Methods 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- 125000002433 cyclopentenyl group Chemical group C1(=CCCC1)* 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 230000000155 isotopic effect Effects 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 239000002516 radical scavenger Substances 0.000 description 3
- 238000005215 recombination Methods 0.000 description 3
- 230000006798 recombination Effects 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- ZSWFCLXCOIISFI-UHFFFAOYSA-N cyclopentadiene Chemical compound C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000010494 dissociation reaction Methods 0.000 description 2
- 230000005593 dissociations Effects 0.000 description 2
- 230000004992 fission Effects 0.000 description 2
- 239000012634 fragment Substances 0.000 description 2
- ZZUFCTLCJUWOSV-UHFFFAOYSA-N furosemide Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC(C(O)=O)=C1NCC1=CC=CO1 ZZUFCTLCJUWOSV-UHFFFAOYSA-N 0.000 description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
- 238000002329 infrared spectrum Methods 0.000 description 2
- 230000005445 isotope effect Effects 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 238000004064 recycling Methods 0.000 description 2
- 238000007086 side reaction Methods 0.000 description 2
- 239000000741 silica gel Substances 0.000 description 2
- 229910002027 silica gel Inorganic materials 0.000 description 2
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 2
- 238000004611 spectroscopical analysis Methods 0.000 description 2
- XTHPWXDJESJLNJ-UHFFFAOYSA-N sulfurochloridic acid Chemical compound OS(Cl)(=O)=O XTHPWXDJESJLNJ-UHFFFAOYSA-N 0.000 description 2
- HFGHRUCCKVYFKL-UHFFFAOYSA-N 4-ethoxy-2-piperazin-1-yl-7-pyridin-4-yl-5h-pyrimido[5,4-b]indole Chemical compound C1=C2NC=3C(OCC)=NC(N4CCNCC4)=NC=3C2=CC=C1C1=CC=NC=C1 HFGHRUCCKVYFKL-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-VVKOMZTBSA-N Dideuterium Chemical compound [2H][2H] UFHFLCQGNIYNRP-VVKOMZTBSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 1
- 102000003800 Selectins Human genes 0.000 description 1
- 108090000184 Selectins Proteins 0.000 description 1
- 229910052770 Uranium Inorganic materials 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000003377 acid catalyst Substances 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- ULYZAYCEDJDHCC-UHFFFAOYSA-N isopropyl chloride Chemical compound CC(C)Cl ULYZAYCEDJDHCC-UHFFFAOYSA-N 0.000 description 1
- 150000002605 large molecules Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- SNMVRZFUUCLYTO-UHFFFAOYSA-N n-propyl chloride Chemical compound CCCCl SNMVRZFUUCLYTO-UHFFFAOYSA-N 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- AAEVYOVXGOFMJO-UHFFFAOYSA-N prometryn Chemical compound CSC1=NC(NC(C)C)=NC(NC(C)C)=N1 AAEVYOVXGOFMJO-UHFFFAOYSA-N 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 239000000700 radioactive tracer Substances 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229910001961 silver nitrate Inorganic materials 0.000 description 1
- 150000003384 small molecules Chemical class 0.000 description 1
- 239000003930 superacid Substances 0.000 description 1
- 238000011282 treatment Methods 0.000 description 1
- DNYWZCXLKNTFFI-UHFFFAOYSA-N uranium Chemical compound [U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U] DNYWZCXLKNTFFI-UHFFFAOYSA-N 0.000 description 1
- 238000005292 vacuum distillation Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D59/00—Separation of different isotopes of the same chemical element
- B01D59/34—Separation by photochemical methods
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B5/00—Water
- C01B5/02—Heavy water; Preparation by chemical reaction of hydrogen isotopes or their compounds, e.g. 4ND3 + 7O2 ---> 4NO2 + 6D2O, 2D2 + O2 ---> 2D2O
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biophysics (AREA)
- Inorganic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
- Gas Separation By Absorption (AREA)
- Lasers (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US05/706,252 US4081339A (en) | 1976-07-19 | 1976-07-19 | Method of deuterium isotope separation and enrichment |
| US706,252 | 1976-07-19 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1085341A true CA1085341A (en) | 1980-09-09 |
Family
ID=24836829
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA281,969A Expired CA1085341A (en) | 1976-07-19 | 1977-07-04 | Method of deuterium isotope separation and enrichment |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US4081339A (OSRAM) |
| JP (1) | JPS5327796A (OSRAM) |
| CA (1) | CA1085341A (OSRAM) |
| DE (1) | DE2732573A1 (OSRAM) |
| FR (1) | FR2358916A1 (OSRAM) |
| GB (1) | GB1556331A (OSRAM) |
| IT (1) | IT1077409B (OSRAM) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4213836A (en) * | 1977-10-04 | 1980-07-22 | The United States Of America As Represented By The United States Department Of Energy | Laser-induced separation of hydrogen isotopes in the liquid phase |
| US4171251A (en) * | 1977-12-01 | 1979-10-16 | United Technologies Corporation | Laser photochemical separation of hydrogen isotopes |
| GB2017067B (en) * | 1978-03-24 | 1982-08-25 | Benson S W | Deuterium isotope separation |
| US4287037A (en) * | 1978-04-04 | 1981-09-01 | The United States Of America As Represented By The United States Department Of Energy | Deuterium enrichment by selective photo-induced dissociation of an organic carbonyl compound |
| US4139439A (en) * | 1978-05-31 | 1979-02-13 | The United States Of America As Represented By The Secretary Of The Navy | Hydrogen isotope separation |
| US4257860A (en) * | 1978-09-19 | 1981-03-24 | The United States Of America As Represented By The United States Department Of Energy | Deuterium enrichment by selective photoinduced dissociation of a multihalogenated organic compound |
| EP0017020B1 (en) * | 1979-04-02 | 1983-05-18 | Allied Corporation | Process for hydrogen isotope separation using hydrofluorocarbons |
| US4411755A (en) * | 1980-11-28 | 1983-10-25 | Herman Irving P | Laser-assisted isotope separation of tritium |
| US4399011A (en) * | 1981-01-03 | 1983-08-16 | The United States Of America As Represented By The Secretary Of The Navy | Separation of hydrogen isotopes |
| CA1158224A (en) * | 1981-12-04 | 1983-12-06 | Edward A. Symons | Process for the exchange of hydrogen isotopes between streams of liquid water and gaseous halohydrocarbon and an apparatus therefor |
| US20050226808A1 (en) * | 2004-04-12 | 2005-10-13 | King Fahd University Of Petroleum And Minerals | Laser photo-catalytic process for the production of hydrogen |
| RU2531178C2 (ru) * | 2012-12-18 | 2014-10-20 | Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования "Воронежский государственный университет" (ФГБОУ ВПО "ВГУ") | Способ лазерного разделения изотопов водорода |
| CN106422774B (zh) * | 2016-10-19 | 2017-11-03 | 河南无极生物工程技术有限公司 | 一种生产低氘水的方法 |
| CN119350300A (zh) * | 2024-12-25 | 2025-01-24 | 西安瑞联新材料股份有限公司 | 一种用于有机电致发光材料的氘代化合物 |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3983020A (en) * | 1973-01-26 | 1976-09-28 | The Regents Of The University Of California | Isotopic separation by photopredissociation |
| US3904500A (en) * | 1973-12-17 | 1975-09-09 | Us Energy | Hydrogen isotope separation from water |
| US3947335A (en) * | 1975-03-04 | 1976-03-30 | The United States Of America As Represented By The United States Energy Research And Development Administration | Isotope separation by selective photodissociation of glyoxal |
| US4025408A (en) * | 1976-05-28 | 1977-05-24 | The United States Of America As Represented By The United States Energy Research And Development Administration | Deuterium separation by infrared-induced addition reaction |
-
1976
- 1976-07-19 US US05/706,252 patent/US4081339A/en not_active Expired - Lifetime
-
1977
- 1977-07-04 CA CA281,969A patent/CA1085341A/en not_active Expired
- 1977-07-04 GB GB27828/77A patent/GB1556331A/en not_active Expired
- 1977-07-18 FR FR7721961A patent/FR2358916A1/fr active Granted
- 1977-07-19 JP JP8571177A patent/JPS5327796A/ja active Pending
- 1977-07-19 IT IT25861/77A patent/IT1077409B/it active
- 1977-07-19 DE DE19772732573 patent/DE2732573A1/de not_active Withdrawn
Also Published As
| Publication number | Publication date |
|---|---|
| DE2732573A1 (de) | 1978-01-26 |
| JPS5327796A (en) | 1978-03-15 |
| US4081339A (en) | 1978-03-28 |
| FR2358916B1 (OSRAM) | 1982-10-22 |
| IT1077409B (it) | 1985-05-04 |
| FR2358916A1 (fr) | 1978-02-17 |
| GB1556331A (en) | 1979-11-21 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKEX | Expiry |