CA1066026A - Redox treatment of alunite ore - Google Patents
Redox treatment of alunite oreInfo
- Publication number
- CA1066026A CA1066026A CA222,358A CA222358A CA1066026A CA 1066026 A CA1066026 A CA 1066026A CA 222358 A CA222358 A CA 222358A CA 1066026 A CA1066026 A CA 1066026A
- Authority
- CA
- Canada
- Prior art keywords
- ore
- roasting
- resulting
- liquid
- aluminum hydroxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229910052934 alunite Inorganic materials 0.000 title claims abstract description 13
- 239000010424 alunite Substances 0.000 title claims abstract description 13
- KPZTWMNLAFDTGF-UHFFFAOYSA-D trialuminum;potassium;hexahydroxide;disulfate Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Al+3].[Al+3].[Al+3].[K+].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O KPZTWMNLAFDTGF-UHFFFAOYSA-D 0.000 title claims abstract description 13
- 238000000034 method Methods 0.000 claims abstract description 24
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims abstract description 18
- 239000000203 mixture Substances 0.000 claims abstract description 14
- 230000001590 oxidative effect Effects 0.000 claims abstract description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 12
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims abstract description 11
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims abstract description 9
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 9
- 230000009467 reduction Effects 0.000 claims abstract description 9
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 8
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 8
- 238000002386 leaching Methods 0.000 claims abstract description 8
- 230000001376 precipitating effect Effects 0.000 claims abstract description 7
- 230000036571 hydration Effects 0.000 claims abstract description 6
- 238000006703 hydration reaction Methods 0.000 claims abstract description 6
- 150000004763 sulfides Chemical class 0.000 claims abstract description 5
- XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical class S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229910052815 sulfur oxide Inorganic materials 0.000 claims abstract description 5
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims abstract description 4
- 230000018044 dehydration Effects 0.000 claims abstract description 4
- 238000006297 dehydration reaction Methods 0.000 claims abstract description 4
- 229910052700 potassium Inorganic materials 0.000 claims abstract description 4
- 239000011591 potassium Substances 0.000 claims abstract description 4
- 239000013078 crystal Substances 0.000 claims abstract description 3
- 239000007788 liquid Substances 0.000 claims description 23
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 18
- 239000007787 solid Substances 0.000 claims description 18
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 11
- 238000001556 precipitation Methods 0.000 claims description 10
- 230000029087 digestion Effects 0.000 claims description 9
- 239000000377 silicon dioxide Substances 0.000 claims description 9
- 150000008044 alkali metal hydroxides Chemical class 0.000 claims description 7
- 239000002002 slurry Substances 0.000 claims description 7
- 239000003570 air Substances 0.000 claims description 6
- 238000010438 heat treatment Methods 0.000 claims description 6
- 239000006228 supernatant Substances 0.000 claims description 6
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 4
- 229910002091 carbon monoxide Inorganic materials 0.000 claims description 4
- 230000003647 oxidation Effects 0.000 claims description 4
- 238000007254 oxidation reaction Methods 0.000 claims description 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 229930195733 hydrocarbon Natural products 0.000 claims description 3
- 150000002430 hydrocarbons Chemical class 0.000 claims description 3
- 239000001257 hydrogen Substances 0.000 claims description 3
- 229910052739 hydrogen Inorganic materials 0.000 claims description 3
- 238000010899 nucleation Methods 0.000 claims description 3
- 239000001301 oxygen Substances 0.000 claims description 3
- 229910052760 oxygen Inorganic materials 0.000 claims description 3
- OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 claims description 3
- 229910052939 potassium sulfate Inorganic materials 0.000 claims description 3
- 235000011151 potassium sulphates Nutrition 0.000 claims description 3
- 239000012670 alkaline solution Substances 0.000 claims description 2
- 239000000470 constituent Substances 0.000 claims description 2
- -1 sodium aluminum silicates Chemical class 0.000 claims description 2
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims 2
- GNFTZDOKVXKIBK-UHFFFAOYSA-N 3-(2-methoxyethoxy)benzohydrazide Chemical compound COCCOC1=CC=CC(C(=O)NN)=C1 GNFTZDOKVXKIBK-UHFFFAOYSA-N 0.000 claims 1
- 239000003513 alkali Substances 0.000 claims 1
- 239000007791 liquid phase Substances 0.000 claims 1
- 239000002244 precipitate Substances 0.000 claims 1
- 238000005475 siliconizing Methods 0.000 claims 1
- 239000007790 solid phase Substances 0.000 claims 1
- 238000000926 separation method Methods 0.000 description 5
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- 239000003518 caustics Substances 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 238000013019 agitation Methods 0.000 description 2
- 229940037003 alum Drugs 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 2
- DNEHKUCSURWDGO-UHFFFAOYSA-N aluminum sodium Chemical compound [Na].[Al] DNEHKUCSURWDGO-UHFFFAOYSA-N 0.000 description 2
- 238000010420 art technique Methods 0.000 description 2
- 238000002425 crystallisation Methods 0.000 description 2
- 230000008025 crystallization Effects 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 2
- 229940072033 potash Drugs 0.000 description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
- 235000015320 potassium carbonate Nutrition 0.000 description 2
- 238000006722 reduction reaction Methods 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 235000017550 sodium carbonate Nutrition 0.000 description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 description 2
- 235000011121 sodium hydroxide Nutrition 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000002562 thickening agent Substances 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 241001632422 Radiola linoides Species 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 235000011126 aluminium potassium sulphate Nutrition 0.000 description 1
- 229940000425 combination drug Drugs 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000007429 general method Methods 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- GRLPQNLYRHEGIJ-UHFFFAOYSA-J potassium aluminium sulfate Chemical compound [Al+3].[K+].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O GRLPQNLYRHEGIJ-UHFFFAOYSA-J 0.000 description 1
- 235000011118 potassium hydroxide Nutrition 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F7/00—Compounds of aluminium
- C01F7/02—Aluminium oxide; Aluminium hydroxide; Aluminates
- C01F7/04—Preparation of alkali metal aluminates; Aluminium oxide or hydroxide therefrom
- C01F7/06—Preparation of alkali metal aluminates; Aluminium oxide or hydroxide therefrom by treating aluminous minerals or waste-like raw materials with alkali hydroxide, e.g. leaching of bauxite according to the Bayer process
- C01F7/0686—Preparation of alkali metal aluminates; Aluminium oxide or hydroxide therefrom by treating aluminous minerals or waste-like raw materials with alkali hydroxide, e.g. leaching of bauxite according to the Bayer process from sulfate-containing minerals, e.g. alunite
Landscapes
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Geochemistry & Mineralogy (AREA)
- Geology (AREA)
- Inorganic Chemistry (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US453234A US3890425A (en) | 1974-03-21 | 1974-03-21 | Redox treatment of alunite ore |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1066026A true CA1066026A (en) | 1979-11-13 |
Family
ID=23799721
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA222,358A Expired CA1066026A (en) | 1974-03-21 | 1975-03-18 | Redox treatment of alunite ore |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US3890425A (index.php) |
| JP (1) | JPS5529932B2 (index.php) |
| AR (1) | AR202445A1 (index.php) |
| BR (1) | BR7501674A (index.php) |
| CA (1) | CA1066026A (index.php) |
| ES (1) | ES435869A1 (index.php) |
| FR (1) | FR2274560A1 (index.php) |
| GB (1) | GB1466225A (index.php) |
| NO (1) | NO142392C (index.php) |
Families Citing this family (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4008307A (en) * | 1975-06-02 | 1977-02-15 | Southwire Company | Production of monobasic potassium phosphate by ion exchange |
| US3996334A (en) * | 1975-06-02 | 1976-12-07 | Southwire Company | Process for recovering aluminum from alunite |
| US4033842A (en) * | 1975-08-28 | 1977-07-05 | Southwire Company | Production of monobasic potassium phosphate by electrodialysis |
| US3996333A (en) * | 1975-08-28 | 1976-12-07 | Southwire Company | Method for dehydrating ores |
| US4057611A (en) * | 1975-12-24 | 1977-11-08 | Southwire Company | Process for recovering aluminum from alunite |
| US4093700A (en) * | 1976-02-04 | 1978-06-06 | Southwire Company | Process for reduction of alunite ore in aluminum recovery process |
| US4029737A (en) * | 1976-04-09 | 1977-06-14 | Southwire Company | Redox treatment of alunite ore |
| US4075068A (en) * | 1976-07-12 | 1978-02-21 | Southwire Company | Process for the recovery of aluminum from alunite |
| US4117077A (en) * | 1976-09-13 | 1978-09-26 | Gakif Zakirovich Nasyrov | Process for alunite treatment |
| US4064217A (en) * | 1976-09-30 | 1977-12-20 | Hartman George J | Process for recovering aluminum from alunite ore |
| US4173622A (en) * | 1978-01-03 | 1979-11-06 | Fmc Corporation | Zeolite A crystals of uniformly small particle size and the manufacture thereof |
| US4230678A (en) * | 1979-02-14 | 1980-10-28 | Earth Sciences, Inc. | Process for recovering aluminum from alunite |
| US4618480A (en) * | 1984-08-15 | 1986-10-21 | Resource Technology Associates | Recovery of alumina values from alunite ore |
| AUPO376296A0 (en) * | 1996-11-20 | 1996-12-12 | Comalco Aluminium Limited | Removal of silica from bauxite |
| RU2446103C1 (ru) * | 2010-08-02 | 2012-03-27 | Государственное образовательное учреждение высшего профессионального образования "Санкт-Петербургский государственный горный институт имени Г.В. Плеханова (технический университет)" | Способ получения глинозема из кианитового концентрата |
| RU2489503C1 (ru) * | 2012-03-12 | 2013-08-10 | Федеральное государственное бюджетное учреждение науки Институт химии и технологии редких элементов и минерального сырья им. И.В. Тананаева Кольского научного центра Российской академии наук (ИХТРЭМС КНЦ РАН) | Способ переработки кианитового концентрата |
| CN115305362B (zh) * | 2022-07-18 | 2023-06-13 | 承德燕北冶金材料有限公司 | 一种提钒尾渣还原挥发脱除碱金属的方法 |
| CN118127342B (zh) * | 2024-05-08 | 2024-06-28 | 东北大学 | 一种含硫铝土矿湿法脱硫的方法 |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1195655A (en) * | 1916-08-22 | Poration | ||
| US1070324A (en) * | 1912-01-13 | 1913-08-12 | Howard F Chappell | Manufacture of sulfate of potash and alumina. |
| US1191105A (en) * | 1916-01-18 | 1916-07-11 | Paul R Hershman | Process of producing alluminate from alunite. |
| US1189254A (en) * | 1916-03-21 | 1916-07-04 | Mineral Products Corp | Production of aluminates from alunite. |
| US2120840A (en) * | 1934-08-20 | 1938-06-14 | Bohn Aluminium & Brass Corp | Cyclic process for treating alunite |
| US2398425A (en) * | 1943-04-27 | 1946-04-16 | Elnathan H Steinman | Process for treating alunite ores and the like |
| US3652208A (en) * | 1970-05-04 | 1972-03-28 | Trw Inc | Alumina extraction from alumino-silicate ores and potassium sulfate ores |
-
1974
- 1974-03-21 US US453234A patent/US3890425A/en not_active Expired - Lifetime
-
1975
- 1975-03-13 NO NO750860A patent/NO142392C/no unknown
- 1975-03-18 CA CA222,358A patent/CA1066026A/en not_active Expired
- 1975-03-20 BR BR1674/75A patent/BR7501674A/pt unknown
- 1975-03-20 JP JP3419075A patent/JPS5529932B2/ja not_active Expired
- 1975-03-20 FR FR7508716A patent/FR2274560A1/fr active Granted
- 1975-03-21 AR AR258084A patent/AR202445A1/es active
- 1975-03-21 GB GB1197875A patent/GB1466225A/en not_active Expired
- 1975-03-21 ES ES435869A patent/ES435869A1/es not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5529932B2 (index.php) | 1980-08-07 |
| NO142392B (no) | 1980-05-05 |
| BR7501674A (pt) | 1975-12-16 |
| GB1466225A (en) | 1977-03-02 |
| NO750860L (index.php) | 1975-09-23 |
| AU7911975A (en) | 1976-09-16 |
| US3890425A (en) | 1975-06-17 |
| JPS50131895A (index.php) | 1975-10-18 |
| FR2274560A1 (fr) | 1976-01-09 |
| NO142392C (no) | 1980-08-20 |
| FR2274560B1 (index.php) | 1977-04-15 |
| AR202445A1 (es) | 1975-06-06 |
| ES435869A1 (es) | 1976-12-16 |
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