CA1062606A - Dual temperature exchange systems - Google Patents

Abstract

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ABSTRACT OF THE DISCLOSURE
The present invention provides in an integrated system for concentrating a desired material exchangeable between two separate fluid substances containing said material and another material exchangeable therewith, at least one of said fluid substances being in liquid phase, said system including (a) a first enrichment section comprising a first stage operating system having at least one pair of dual temperature exchange hot and cold towers and a prescribed feed supply of one of said fluid substances, (b) an intermediate enrichment section comprising an operating system of at least a second stage of dual temperature exchange hot and cold towers, and (c) a final enrichment section comprising a system for further enriching at least one of the enriched fluids from said intermediate enrichment section to a prescribed final product concentration, the improvement which provides for modification to increase the quantity of final product output without physical alteration of the intermediate and final enrichment sections, wherein (1) the hot and cold towers of the first enrichment section include countercurrent contact exchange elements sufficient to provide that when the volume of enriched fluids withdrawn from said first enrichment section and delivered to said second enrichment section is fractionally reduced, such reduced quantity will transport to the intermediate enrichment section substantially the same amount of the desired material at an increased concentra-tion, and (2) the final enrichment section is of sufficient capacity to produce a final product of the prescribed concentra-tion when said volume of enriched fluids delivered to said second enrichment section is not so fractionally reduced.

Description

This application is a dlvisional application of Copending application No. 137,812 filed March 22, 1372.
The present invention relates to improvements in dual temperature exchange systems for concentrating a desired material by exchanging, at different temperatures, said deslred material .
with another material between chemically different lighter and heavier fluids, e.g. gas and liquid, which are physically separable from each other and whlch are each capable of contalning each of said materials.
In such dual temperature exchange systems, for instance, as disclosed in my prior U.S. Patents ~o. 2,787,52~ issued April 2, 1957; No. 2,895,803 issued July 21, 1959; and No.
3,142,540 issued July 28, 1964, a system is employed which comprises one or more stages of hot and cold tower pairs for contacting of said lighter and heavier fluids in countercurrent relationship. In such known systems one of the two fluids is supplied from an external source and is fed to the first tower of the first stage pair of towers, enriched in the desired material to be concentrated by preferential exchange therein, impoverished in the said desired material in the second tower of said pair to a concentration of the desired material less than that of said feed supply fluid, and discharged from the system. The other fluid is continuously circulated through the pair of towers to become enriched in the desired material in the second tower of said pair and to become impoverished in that material in the first tower of said pair. Such a system may comprise a plurality of similar or different concentrating stages of known species, and a portion of the flow of one or ., - I
both of the enriched fluids being passed between said towers 30 in a stage other than the last is also impoverished in the des-ired material during such passage by sub~ecting it to extraction of desired material therefrom in the following stage or other concentrating treatment. A portion of the enriched flow of one ,-, - 1 -.

~0626~)6 of the fluids is withdrawn as product from that part of the system in which its concentration of the desired material is high.
Also, in such dual temperature exchange systems, as is shown by the above mentioned prior patents, various provisions are made for moving the process fluids and adjusting the temperatures thereof as required by the process, which employ - fluid pumping means, heating and cooling means, and indirect and/or direct contact heat exchange means provided to meet the particular requirements of the system.
; The present invention, severally and interdependently in various combinations, improves productivity when the feed supply fluid is abundantly available at relatively low cost and/or to reduce equipment costs when the character of the feed supply fluid would impose costly requirements for the ` equipment in contact therewith in dual temperature exchange systems; minimizes the area of contact of the equipment with .., such feed supply fluid; isolates such feed supply fluid in such ~ minimized area and excludes it from mixing with other similar ~ 20 process fluids in the system; and/or increases the fraction of the desired material extracted from the feed supply fluid in an economical manner; each of which increases the operating efficiency and/or decreasing the overall cost of the system per unit quantity of product.
To this end the improvements of the present invention are concerned with the inter-relationship of the flow paths of '' the auxiliary fluid and the fluids contacting the same in any stage of such a system, particularly in a first stage or a single ::i ; stage system. The principles of these improvements are typically exemplified by their application to the concentration of deuter-. , .
; ium by countercurrent exchange reactions between the isotopés of hydrogen at appropriate low and high temperatures, in hydrogen ;2606 sulfide gas (H2S) and water (H20), and wherein water is the feed supply and hydrogen sulfide is the auxiliary fluid employed in the process. In such application the heating and cooling and pumping of the fluids being passed through the cold and hot temperature towers may be accomplished in any suitable manner, e.g. in the manners disclosed in the aforesaid prior patents, or in any other manner herein disclosed or known to those skilled in the art, and the improvements of the present invention pertaining to the inter-relationship of flow paths in the said first stage are for the most part independent of the particular manners of so moving and conditioning the process fluids. In embodiments of the present invention, and in the prior art, the flow path of the total flow of the auxiliary fluid (e.g. H2S) passes through the entire extent of both the hot and cold towers of the pair of tower-s, and in accordance with the prior art the flow path of the total flow of the other fluid (e.g. water) does likewise in countercurrent relation to the auxiliary fluid. In accordance with the .~ present invention, however, the flow path of the feed supply fluid ~e.g. water) does not pass through the entire extent of the first and second towers of the pair. Thus: i `~ (a~ In a first embodiment of the present invention the feed supply fluid (e.g. feed water) passes only through the lower portion of the second (e.g. hot) tower wherein it transfers the entire production quantity of the desired material (e.g. deuterium) to the auxiliary fluid (e.g. H2S) and is then discharged from the system, the auxiliary fluid (e.g. H2S) thence undergoing the exchange reactions with a separate circulation of other fluid (e.g. water) in the remainder of its flow path.
(b) In a second embodiment, modifying said first embodiment, two feed supplies to the system are employed, one thereof is utilized as in said first embodiment, and the other ., ~

1~6Z606 thereof is employed in lieu of the separate circulation of said first embodiment to contact the auxiliary fluid in the ; remainder of its flow path and is then discharged from the system.
~c) In a third embodiment, further modifying said second embodiment, the two feed supplies are handled as in said second embodiment except that the second feed supply fluid after contacting the auxiliary fluid in said remainder of its flow path is combined with the first feed supply fl~id passing in contact with the auxiliary fluid in said lower portion of the second tower and is discharged from the system ~ ~
therewith. ?
(d) In a fourth embodiment, the arrangement is 7 similar to said third embodiment except that the second feed supply fluid is not combined with the first feed supply fluid, and said lower portion of the second tower is divided into two ~ ;
separate flow sections in which said first and second feed supply fluids are separately contacted with parallel branches of said flow of auxiliary fluid.
(e) In a fifth embodiment, the arrangement is similar ¦
to that of said first embodiment except that the separate i circulation of other fluid (e.g. water) which contacts gaseous ;3~ auxiliary fluid in said remainder of its flow path is supplied ~ ~ with additional other fluid, either as feed supply fluid or as .
condensate from the cooling of the hot saturated auxiliary fluid, and the surplus of other fluid thus provided is combined with said first feed supply fluid as in the third embodiment.
(f) In a sixth embodiment the arrangement is similar j~
to that of the fifth embodiment except that the surplus of other t~' 30 fluid is not combined with the first feed supply fluid as in the 1 third embodiment, but instead is separately contacted with a branched flow of auxiliary fluid as in the fourth embodiment.

. ,; .

l~Z60f~
(g) In a seventh embodim~t, the arrangement is similar to the prior art system except that instead of the entire feed supply fluid stream being discharged from the stage after passing through the second tower, a portion thereof is recirculated to the first tower, where it is mixed with the incoming supply of feed fluid. The said stream after passing through the second tower has a concentration of the desired material lower than that in the incoming feed fluid supply delivered in the first tower. Thus, in this embodiment, by recirculating a part of said impoverished feed supply fluid and mixing it with the incoming feed fluid supply the concen-tration of the desired material in the feed supply fluid at the top of the first tower is less than in the incoming feed fluid, thereby reducing the concentration of the desired material in the auxiliary fluid passing from the first tower ¦ -; to the second tower, and in turn reducing the concentration of the desired material in the feed supply fluid stream being discharged from the second tower, thus increasing the fraction of the desired material extracted from the incoming feed fluid.
(h) In an eighth embodiment the arrangement is similar to the seventh embodiment except that the incoming supply of feed fluid is introduced at the level in the first tower at which the recirculated feed supply fluid stream has become partially enriched to substantially the same concentration of the desired material as that of the incoming feed fluid.
(i) In ninth and tenth embodiments, the arrangement ~ is similar to the third embodiment except that a portion of the J~, feed supply fluid stream being discharged from the second tower is recirculated to the top of the first tower and combined with incoming supply of feed fluid as in the seventh embodiment or as in the eighth embodimenti and similar modifications of the fourth, fifth and sixth embodiments are also contemplated by the invention.

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1()6Z606 (j) In further embodiments of the invention, the arrange~ents are similar to the sixth embodiment further modified as in the ninth or tenth embodiments except that the feed supply fluid stream recirculated to the top of the first tower is derived from the surplus of other fluid which was kept isolated from said first feed supply fluid and separately contacted with a branched flow of the auxiliary fluid.
In copending parent application No. 137,812 there is disclosed in a method for producing a fluid containing a first material concentrated therein, by exchanging at two different temperatures said first material with a second -.,, :
. material between chemically different first and second fluld ,7' phases which are physically separable from eacn other and -:
which are each capable of containing each of said materials, ~:
said materials being isotopic, said method being of the type in which ~ (a) said second fluid phase is passed through each :~ of the second and first units, in that order, of a pair of .~ .
exchange units, and in which (b) flows of said first fluid phase are passed in ~ -` countercurrent contact with said second fluid phase in said .
~ first and second units of said pair, :~ (c) said first and second units being maintained at different temperatures to cause said second fluid phase to become enriched in said first material in passing through said second unit, and to become impoverished in said first material in passing through said first unit of said pair, and to cause ~ the first fluid phase to become enriched in said first material in passing through said first unit and to become impoverished in , .. .
said first material in passing through said second unit of said pair of units, and in which a part of at least one of the ~.

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enriched fluids passing between said units is withdrawn; the improve-ment which comprises:-(d) delivering a first flow of said first fluid phase containing said materials from a source thereof and passing said flow in countercurrent exchange with said impov- e erished second fluid in a first delivery-to-discharge path through a portion only of said second unit proximate to its end at which said fluids are most impoverished in said first material, and ~e). passing a second flow of first fluid phase in a second delivery-to-discharge path exclusive of said first path in countercurrent exchange with said second fluid phase in other portions of said first unit and second unit of said pair of units and as an enriched flow between said units. The above cope~din~ application also disclosed and claimed improved apparatus for producing a fluid containing a first material . .
concentrated therein, by exchanging at two different temperatures .
said first material with a second material between chemically different first and second fluid phases which are physically .
separable from each other and which are each capable of contain-ing each of said materials; said apparatus being of the type which comprises:
(a) a pair of exchange lmits and means connected there-to for passing said second fluid phase through each of the second and first units of said pair in that order, and for also passing flows of said first fluid phase in countercurrent contact with ~aid second fluid phase in said first and second units of said ~.
pair, :
~; 30 ~b) means for maintaining said first and second units at different temperatures to cause said second fluid phase to become enriched in said first material in passing through said ' .
, ~ 7 ~ ! ~

.
~ . . , ,. . , - ~ ~
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106Z~06 second unit, and to become impoverished in said first material in passing through said first unit, of said pair, and to cause the first fluid phase to become enriched in said first material in passing through said first unit and to become inpoverished in said first material in passing through said second unit of : said pair of units, and .
~c) means connecte~ to said units for withdrawing a :~
part of at least one of the enriched fluids passing between :~
said units;
and the improvement comprising, in combination with the fore-going:
(d) first means including conduits connected to said second units for delivering a first flow of said first fluid ' phase containing said materials from a source thereof and . passing said flow in countercurrent exchange with said impover-s ished second fluid in a first delivery-to-discharge path through ~ a portion only of said second unit proximate to its end at .
~ which said fluids are most impoverished in said first material, and 'd (e) second means comprising conduits connected to . 20 said units for passing a second flow of first fluid phase in a ~ second delivery-to-discharge path exclusive of said first path in counterucrrent exchange with said second fluid phase in other .. A portions of said first unit and second unit of said pair of units and as an enriched flow between said units.
~ The present invention provides in an integrated system !
.~ for concentrating a desired material exchangeable between two :;~,, , separate fluid substances containing said material and another material exchangeable therewith, at least one of said fluid :~j substances being in liquid phase, said system including (a) a first enrichment section comprising a first stage . operating system hauing at least one pair of dual temperature ;
exchange hot and cold towers and a prescribed feed supply of one . .

', : ' ' ,~: ' ~06Z606 of said fluid substances, (b) an intermediate enrichment section comprising an operating system of at least a second stage of dual temperature exchange hot and cold towers, and ~c) a final enrichment section comprising a system for further enriching at least one of the enriched fluids from said intermediate enrichrnent section to a prescribed final product concentration, the improvement which provides for modification to increase the quantity of final product output without physical alteration of ~; the intermediate and final enrichment sections, wherein (1) the hot and cold towers of the first enrichment section include countercurrent contact exchange elements sufficient to provide that when the volume of enriched fluids withdrawn from said first enrichment section and delivered to , j/J7/ern7ed/~ 7~
sald~enrichment section is fractionally reduced, such reduced quantity will transport to the intermediate enrichment section substantially the same amount of the desired material at an increased concentration, and

(2) the final enrichment section is of sufficient capacity to produce a final product of the prescribed concentra-tion when said volume of enriched fluids delivered to said i~7ter~e~ e sccend enrichment section is not so fractionally reduced.
In the accompanying drawings: -, Fig. 1 is a simplified diagram of a typical prior art arrangement of the hot and cold towers Tl and T2 of a single stage dual temperature exchange system or of the first or a following stage of a plural stage dual temperature exchange system wherein: the fluids between the towers are enriched in the desired material; the inter-tower fluids processing system, e.g.
pumps, valves,heating and cooling means, with or without addition-al concentrating means, is indicated by single brackets for : ~ _ g .
:'', 1~260~;
simplicity; and tne withdrawal of product fluid Lrom the system is indicated by the arrow P;
Flgs. 2 through 8 are slmilar diagrams of systems employing various typical embodiments of the invention;
Figs. 5a and ~a are similar diagrams of modified physical embodiments of the systems of Figs. 5 and 8, being , ~ the same as Figs. 5 and 8 above the planes A-A and B-B, `` respectively;
Figs. 9 and 9 (alt), are abbreviated and extended process flow diagrams of the same first stage of a system accor~
ding to the invention, in which the hot and cold towers may be a single given diameter tower or a plurality of lesser diameter towers in parallel, such parallelism being indicated in Fig. 9 by the bracket-like "gang" symbols, indicating that allpartsbetween7 :, . .

... . . .. .. .
. . .
:' .;", .

: , , '"

~I ~
.~ .
''' ~ .~

.: :. ~ , . ~ ~ . . .
:, ; . .
- - . . : .

; .. . . . . . . : - . , ,;,', . .: : - : . - : , .
: ~. . , : , . -, ,- : . . ~ . : :

the oppositely facing brackets may be present in multiple parallel relation, as more completely illustrated in Fi~. 9 ~alt~; and Fig. 10 is a similar process flow diagram of the second and third stages of an enrichment system, which may be fed from, and dischar~e to, the first stage of Fig. 9 or 9(alt);
and may in turn feed, and receive discharge from, further con-centrating and product finishing stages, which may be as set forth in any of my aforesaid prior patents.
Referring to the drawings, as above noted, Fig. 1 is typical of the prior art systems using the dual temperature process, wherein enrichment of the desired material by counter-current direct contact exchanges between a feed supply fluid and an auxiliary fluid is effected. The feed supply fluid ,t (e.g. water) is delivered at al to the tower Tl which is kept a~ a temperature (e.g. cold) to effect enrichment of the feed supply fluid and impoverishment of the auxiliary fluid AFl (e.g. H2S) in a desired material (e.g. deuterium) and thence passes via bl to the intertower fluids processing system cl from which the product P is withdrawn and from which the main ¦feed supply fluid flow passes via dl to the tower T2 which is kept at a temperature (e.g. hot) for impoverishment of the feed supply fluid and enrichment of the auxiliary fluid, and thence fdischarged at el. Thus both fluids passing from the towers to the system cl are enriched in the desired material. In Fig. 1, assuming the fluids concerned are liquid water and gaseous hydrogen sulfide, and that the water is the feed supply fluid, ~ -the solid line flow path would indicate the water and the broken ¦~
line flow path would indicate the auxiliary fluid. With the same ~ 30 fluids, if H2~ were assumed to be the feed supply fluid, and - water the circulating auxiliary fluid, then the significance ofthe solid and broken lines would be reversed, with corresponding reversal of the ends and temperatures of the towers Tl and T2.
In Fig. 1, the valve symbols, fl~ gl and hl, are included to indicate that the auxiliary fluid may be recirculated in full ` or in part or not at all, between the towers, depending on the particular species of system being employed and whether the illustrated stage is a single stage or the first or subsequent stage of a system.
The quantity of the desired material which may be extracted from the feed supply fluid in a system according to Fig. 1, is limited (in the ideal case) according to the following relationship: Q = (l-Kl/K2), where Q is the maximum fraction of the desired material in the incoming feed substance which may be extracted, Kl is the equilibrium distribution of the desired material between the phase comprising the feed ; substance and the phase comprising the auxiliary substance at the first temperature zone conditions, and K2 is the e~uilibrium distribution between said phases at the second temperature zone ¦
conditions.
Fig. 2 illustrates a first embodiment of the present invention which is particularly useful where the character of the feed supply fluid would impose costly requirements for the apparatus, i.e. for expensive materials of construction of the parts in contact therewith, e.g. where said feed supply is a corrosive solution such as sea-water. This embodiment minimizes , the area of such contact, confines the said feed supply fluid to such minimized area, and prevents mixing of said feed supply -~ fluid with other process fluids of the system except in such confined area. To this end, in the embodiment of Fig. 2, the feed-to-disposal path ~is confined to the lower portion only of the tower T2, entering the same via a2 at a level below the partitioning device s2 extending across the tower which permits passage only of the auxiliary fluid AF2, the other fluid -- .

exchanging with the auxiliary fluid AF2 in the upper section of tower T2, being withdrawn from above the partitioning device s2 for recirculation through the tower Tl via conduit m2. In this Fig. 2 embodiment if a secondary non~corrosive feed supply source is available (e.g. essentially pure water or water free . .
of corrosive contaminents) a feed F therefrom may be added to the fluid being recirculated via m2, as indicated by the valve r j2 in line a 2, in which case an amount equivalent to that added will be withdrawn from the circulation, as via the conduit with valve k2. This withdrawn quantity, as shown, may be combined with the primary feed supply fluid supplied at a2, and may pass I therewith through the lower part of the tower T2 and to discharge :~ via e2. When the total flow of feed fluid phase passing through the lower part of the tower T2 to discharge D is greater than the flow thereof passing through the upper part of tower T2, the j~
augmenting by the combination of the flow of feed fluid phase improves the efficiency of the lower portion of the tower T2 by making available for exchange with the auxiliary fluid phase a larger quantity of the desired material (e.g. deuterium).
20 The valves f2, g2, and h2 have the same significance in this L
figures as do the correspondingly lettered valves in Fig. 1. ~ ;
Thus by this combination a greater productivity may 1~ -be obtained with a given tower size, and/or for a given pro~
j ductivity the relative size of the lower section of the tower T2 ~, may be reduced. Except when otherwise stated, the descriptions ;~ herein refer to steady state conditions.
In a modified mode of operation of the system of Fig. 2, t' ' the flow of the secondary non-corrosive feed supply fluid phase through the lower portion of tower T2 may be eliminated ~e.g. by `- -. 30 closing the valve k2), the introduction of the secondary feed fluid may be effected in the section c2 ~e.g. by condensation of feed supply fluid vapors from the auxiliary fluid flow therein), . . .. - ~ . . : : :
:. . : , 10f~ ;06 and in such case the excess of secondary feed fluid phase delivered f~om tower T2 by way of conduit m2 over the quantity thereof to be introduced into the tower T1, may be discharged from the system by way of conduit a'2 controlled by valve j2.
The embodiment of Fig. 3 is quite similar to that of Fig. 2, and includes corresponding parts designated by corresponding letter symbols with the ascribed symbol "3".
As again, the primary feed supply fluid may be confined to the lower portion of the tower T2 between a3 and e3 and may contact the auxiliary fluid AF3 only therein, the auxiliary fluid AF3 partially enriched by this contact, then passes through the segregator s3 and contacts the secondary feed supply fluid in the upper portion of the tower T2 and in the other portions of the system. In this Fig. 3 arrangement, the secondary feed supply fluid enters the stage at a 3, this feed supply fluid ` phase leaving tower T2 via m3 may be delivered from the stage, as through valve n3, or may be combined with the primary feed supply fluid by way of valve k3. When the primary and secondary feed supply fluids at a3 and m3 have the same concentration of the desired material, and have the same flow rates, then the system of Fig. 3 will effect er.richment in substantlally the same manner as that of Fig. 1, with the improvement that the primary feed fluid from a3 is confined to the circuit a3-e3, and (in the case of sea-water, for example) does not contact other parts of the apparatus. In this embodiment also, when the flow from a3 to e3 is in greater ~uantity than that through m3, an increase in efficiency of the por~ion of the tower below the separator s3 is obtained.
The embodiment of Fig. 4 is adapted for use under conditions in which the primary feed supply fluid entering at a4 is of a quality comparable with that of the secondary feed supply fluid introduced at a'4, and in this case no segregator 1(~6Z606 corresponding to the separator s3 is required. Thus in this !
instance the primary feed supply i5 introduced directly into the tower T2--through a conventional distributor (not shown) to prevent channelling--and augments the flow of feed fluid phase in the lower portion of the tower T2 for improving the efficiency thereof. In this instance, the flow in the lower portion of the tower T2 is essentially equal to the sum of the flows in a4 and a'4, and the amount of feed fluid phase intro-duced through a4 may be varied up to several times the quantity supplied at a 4, in accordance with the degree of augmented flow desired in the lower part of the tower T2 and the capability I of the contacting equipment to accommodate the fluid flows, bearing in mind that the fluid exiting at c4 may not become impoverished to less than the equilibrium value determined by the concentration of the auxiliary fluid AF4 entering the tower T2, and that the auxiliary fluid AF4, when it reaches the level a4, cannot have attained a concentration greater than that corresponding to equilibrium with the feed supply fluid phase at that level. ' ; 20 The embodiment-of Fig. 5 is similar to that of Fig. 2 but the lower portion of the tower T2 is divided into separated parallel sections x5 and y5, in which the two feed supply fluids 1,~
are separately contacted with branched parts of the auxiliary fluid`AF5, which parts are then combined above the separator s5, the primary feed supply fluid from a5 being confined to the region within x5 by the separator s5. By this arrangement, impoverished secondary feed supply fluid which has entered the system either by way of a 5 or otherwise, e.g. by condensation ; from the auxiliary fluid AF5 in the systems c5, may be withdrawn via r5 (at minimum concentration of the desired material, e.g.
equal to that in e5), for appropriate use, e.g. for precondition-ing the auxiliary fluid AF5 by use of heating and humidifying provisions as set forth herein and in the patents above.
The same result as that accomplished in the embodimel-t of Fig. 5 may be attained with the modified construction of Fig. 5a wherein all parts above the plane A-A are the same as those above said plane in Fig. 5, and the corresponding parts below the plane are designated by corresponding letter ~ -symbols with their own ascribed designations. This Fig. 5a construction is desirable, especially where the flow r5a is a minor quantity as compared to the flow e5a. The valved by-pass q5a is provided for the purpose hereinafter described in connection with Fig. 9; and may be provided for corresponding flows in the other embodiments.
Fig. 6 illustrated another modification of the system ', of Fig. 1 the use of which is particularly advantageous where 1 the available supply of the feed substance is restricted and/or ~ ,-where the cost of treatment of the feed supply for use in the system is significant. By extending the exchange path of the circulating auxiliary substance in both of said different temper-ature zones and by recirculating a portion of the fluid phase , 20 comprising the feed substance through said exchange path according to this modification it is possible to increase the t .,.~ , j' '.
fraction of the desired material which may be extracted from ~ -the feed supply over that afforded by the system of Fig. 1.
In the embodiment of this improvement as illustrated in Fig. 6, a fluid phase comprising the supply of feed substance ~;i is passed in a feed-to-disposal path (F-D) through both said

3 different temperature towers Tl and T2 in countercurrent contact :;~
exchange relation to the auxiliary fluid phase AF6, said path traversing at least a part of the first temperature tower Tl for enriching the feed substance in said desired material and then the second temperature tower T2 for depleting the so enriched J
.; , - 16 ~

1(~6~606 feed substance of said desired material; said supply of feed substance i9 delivered to tower Tl; and said feed fluid phase leaving the second temperature tower is divided, a part thereof being recirculated via m'6 to said first temperature tower Tl, said recirculated feed fluid phase traversing the entire counter-current contact exchange path of said auxiliary substance in both of said different temperature towers. In the preferred embodiment of this modification, said supply of feed substance is delivered to said first temperature tower from a6 via valve j'6 and is 10 mixed with said recirculated feed fluid phase from m'6 at the place where the concentration of the desired material in the feed fluid phase in tower Tl is partially enriched to about the same concentration of the desired material as that in the feed supply fluid delivered via a6.
The fraction of the desired material which may be extracted from the feed supply fluid from a6 by use of this modification is independent of the limltations of the system of Fig. 1 and is expressed substantially by the following relationship: Q = (l-Xw/Xf), where Q is the fraction of the desired material in the feed substance supply which may be Z extracted, Xf is the concentration of the desired material in .~ . !
the feed substance supply, and Xw is the concentration of the desired material in the feed substance which passes from said second temperature zone. Variation in prescription of the fraction of the desired material to be extracted is reflected in variable apparatus requirements as effected by the ratio of the quantities of feed substance recirculated via m 6 and ~:. I
feed substance supplied to the system via a6.
.,~ , In an alternative to the preferred Fig. 6 arrange- ¦
ment, the feed supply fluid from a6 may be commingled with the more impoverished feed supply phase fluid recirculating via m 6, and both these fluids may be introduced into the ~6Z6~6 top of the tower Tl. While this arrangement may be advantage-ous in certain circumstances, it is not wholly independent of the limitations of Fig. 1, above discussed, and in effect is a compromise between the Fig. 1 arran~ement and that of the pre-ferred embodiment of Fig. 6.
~s is also illustrated in Fig. 6, when the auxiliary fluid recirculation AF6 is provided with a feed for additional auxiliary fluid partially enriched in the desired material as compared with the recirculated portion AF6, it is preferred to ; 10 introduce the latter by way of valve h'6 to the level in the tower T2 where the fluid AF6 has been partially enriched to substantially that of the added supply of auxiliary fluid.
However, with less independence from the limitations of Fig. 1, such added auxiliary fluid may be introduced through valve h6 to be mixed with the recirculated fluid AF6 before it enters the ii tower T2. In either embodiment a quantity of the auxiliary fluid, equivalent to that added, is withdrawn as via valve g6.
The embodiment of Fig. 7 combines advantages of those of Figs. 6 and 4, i.e. it affords the advantages of augmented flow of feed supply fluid in the lower portion of tower T2, with ~, the advantage of recirculation of feed supply fluid via m 7 and 6;
introduction of secondary feed supply fluid via j'7 to a point t of substantially equal concentration in the tower Tl. ~' ; The embodiment of Fig. 8 combines advantages of the embodiment of Figs. 7 and 5. The auxiliary fluid AF8 circulates through the entire extent of the towers T2 and Tl . The feed ' supply fluid path F-D is confined to the tower portion x8 by the separator s8, and the flow of auxiliary fluid AF8 is branched i;~
and divided between the tower portions x8 and y8. The feed supply fluid phase passing in tower T2 is in part recirculated via m8 .~ i, between levels in towers T2 and Tl, where its concentration is ,~
substantially equal to that of feed supply a8 which is greater r . .

106;2606 than the concentration of the feed supply fluid phase in r8 and e8, and in other part passed throuyh the tower portion y8.
The more impoverished feed supply fluid phase thus obtained from r8 is recirculated via m'8 to the top of tower Tl, wherein it is partially enriched to the concentration of the secondary feed supply, which is introduced via valve j'8 if available and used, in which case substantially the same quantity of feed fluid ~-phase is withdrawn from the recirculation via k8 or via u8.
The same result as that accomplished in the embodiment of Fig. 8 may be obtained with modified constructions, e.g. as ~h exemplified in Fig. 8a, wherein all parts above the plane ~-B
are the same as those above that plane in Eig. 8, and the '~
corresponding parts below that plane are designated by corres-ponding letter symbols with their own ascribed designations.
This Fig. 8a combination locates the tower portion x8a externally of the main tower T2 leaving the lower part of the main tower T2 for portion y8a. This arrangement is desirable especially when the flow e8a is to constitute only a minor amount as com- ~i pared to the flow r8a. The withdrawal to m8 in Fig. 8a is from a suitable collector s'8, which separates that part of the fluid phase to be withdrawn from the other contacting phase in the tower. It will be appreciated that instead of locating the tower portion x8a externally, it may be located internally of the main tower and the tower portion y8a may be located ex~er-: nally following the scheme of y5a in Fig. 5a, and that the structure schemes of Fig. 5a or 8a may also be applied to any of the embodiments of Figs. 2, 3, 5 and 8 hereof.
In Fig. 9 -- or Fig. 9 (alt) -- there is shown the process flow diagram of the first stage of a system according to the invention, in which the hot and cold towers of the pair are each made up of a plurality of lesser diameter towers in parallel, such parallelism in Fig. 9 being indicated by the 19 ~

.. ,- . . - - - , :
- . . . . . . .

;Z606 bracket-like "gan~" symbols, indicating that all parts between the oppositely facing brackets may be present in multiple parallel relation, as more completely illustrated in Fig. 9 (alt).
These figures and Fig. 10 illustrate the first, second and third stages of a heavy water plant of the dual temperature hydrogen sulfide water-type, embodying the invention. Such heavy water plant comprises a feed and effluent treatment section, which provides a treated water, e.g. sea-water which has been cleaned, deaerated, decarbonated, heated, and saturated with --hydrogen sulfide at the hot tower temperature and pressure, e.g. 130 C and 325 p.s.i., and thereby also provided with a dissolved salt component of hydrosulfide and sulfide ions. As shown in Fig. 9, this feed-water is delivered by pipe 55A to the feed section lower portion of the hot tower, corresponding to portion X5a of Fig. Sa above, from which the effluent sea water~
impo~erished in deuterium content, is discharged via pipe 34A
to the effluent treatment section of the system above mentioned, wherein heat is recovered from the effluent for in part heating ., I
the said feed water being supplied via pipe 55A, and dissolved hydrogen sulfide gas is recovered from the effluent and return-ed via pipe 42A for reuse as auxiliary fluid in the system.

Still referring to Figs. 9 and ~ (alt), since the ~ first stage equipments are duplicated in parallel, only one of .~
them need be described. This one comprises cold tower TC-101-2 " and hot tower T~-101-2, with accessory equipment. Between the cold and hot towers is a dehumidification system, shown as constructed integral with the cold tower, wherein water is condensed and heat is recovered from the hot H2S gas, the heat recovery being effected at a plurality of consecutively lower temperatures by separate branches of a cyclic flow of water and condensate hereinafter more fully described.
The enrichment systems shown in Fig . 9 or 9 (alt) and :

,, ~ . . . ` ,, ~ ! ` . , -. ': : , ` ` ' ` - ` ' .- ~ . ' , .
':`

lg6~606 10, are those directly involved in the initial concentration of deuterium ox1de in natural water e.g. sea-water, from about 0.015 mol % to approximately 7 mol percent, as D~O, when provided with the two parallel stage 1 hot and cold tower pair units as shown in Fig. 9 (alt); and to approximately 15 mol percent when four such parallel units are provided.
Stage 1, Figs. 9 and 9 (alt), contains a set of towers, F
or a plurality of sets of towers operating in parallel. Each ; set consists of a hot tower TH-101-2 operating at the hot temperature, e~g. 130 Cr a cold tower TC-101-2 operating at the cold temperature, e.g. 30 C, and a recycle tower T-102-2 which corresponds to the lower hot tower section ySa in Fig. 5a.
Inside all towers are countercurrent contacting elements, e g.
perforated plates called sieve trays, which provide intimate countercurrent contact of the liquid and gas streams. Each set of towers operates with its own H2S compressor, C-101-2, process water pumps, heat exchangers and gas separators, as shown.
` The said stage 1 cold tower vessels in this embodiment are vertical pressure vessels approximately 20 feet in diameter L
and approximately 185 feet high. Each said vessel comprises, in the form shown, a cold tower or water enriching exchange section and a dehumidification section for hydrogen sulfide gas :, !
cooling constructed therebelow.
~he said stage 1 hot tower vessels are vertical pressure vessels approximately 22 feet in diameter and approx-imately 200 feet high. Each said vessel, in the form shown, comprises a hot tower or water impoverishing exchange section ; which includes the sea-water feed section and the parallel external recycle section; and a humidlficatlon section for gas heating and humidifying is constructed in the lower part of the vessel.
Each of the said exchange sections of the stage 1 .

hot and cold tower pairs in this illustrative embodiment, for the purpose hereinaft~r described, is provided with a total of 130~ of the calculated number of plates that would be employed if the illustrated two tower pairs in Fig. 9 (alt~ were to be operated at output rates to effect a 3-fold enrichment of deuterium content of the water delivered to the second stage as compared to the sea water feed supply.
Seal trays are provided at the bottom and at the top of the feed sections in the hot towers. As indicated in connection with the separator sSa in Fig. 5a, gas can pass upward through the seal trays, but water cannot pass through them to the other sections of the tower. The feed section is equipped with a mist eliminator and a wash tray (not shown) to remove entrained sea-water spray from H2S process gas ascending through the seal tray.
The stage 1 recycle towers T-102-2 corresponding to elements y5a in Fig. 5a, are vertical pressure vessels approximately ll feet in diameter and approximately 50 feet high, provided with trays for countercurrent exchange between the fluids as in the other sections of the towers.
All tower shells are made of carbon steel. The hot tower sea-water feed sections are internally clad with Inconel (trademark). All sieve trays are made of stainless steel except in the hot tower feed sections where the trays are also made of Inconel (trademark). The lower portion of the hot tower, comprising the parallel feed section and recycle tower section as shown, accounts for about 20~ of the total number of theoretical trays or contacting elements in the hot tower.
Gas from the top of stage 1 cold tower TC-101-2, via 41A, which also receives via 42A a stream of H2S from the effluent system as above noted, passes via 38A from the discharge ' - ;
.

1~6Z6()6 of the stage 1 gas compressor C-101-2 to the bottom of the humidification section of the stage 1 hot tower TH-101-2, where it flows upward through the humidification section in counter-current direct contact with a cyclic flow of hot water, and is thereby heated and humidified by evaporation of ~Jater from said cyclic flow. Steam injected via 114A into the hot tower at the top of the humidification section further heats and humidifies the gas to hot tower conditions. A portion of the hot gas is withdrawn via 56A for use in the feed water saturator above mentioned, where accumulations of inert gases are also purged ; from the process gas of the system. A minor portion of the so heated and humidified gas via 58A is passed to the recycle tower T 102-2, thereby bypassing the feed section of the hot tower. This gas enters the bottom of the recycle tower and passes upward, stripping deuterium from the countercurrent flow of process water therein. This deuterium-enriched gas leaves the top of the recycle tower and reenters the hot tower via 59A, at the bottom of the process water impoverishing or deuterium r ~ ~ , stripping section, above the feed section.
Parallel to the recycle tower flow most of the heated ., ~
and humidified gas continues upward through the seal tray at the bottom of the sea-water feed section of the hot tower and through said feed section, stripping deuterium from the sea-water feed. This enriched gas continues upward to the stripping section through the seal tray at the top of said feed section, mingling with additional gas recycled via 59A fromthe gas separa-tors associated with the liquid heating elements of the system and from said recycle tower. The gas stxips more deuterium from the process water in the stripping section and then leaves the top of the hot tower via 39A.
Said yas flow via 39A is split between the stage 1 cold tower and the stage 2 hot tower. One part thereof enters the dehumdification section under the stage 1 cold tower via - 2~ -4OA and passes upward, becoming cooled and dehumidified by the countercurrent cold water flows. The cooled, dehumidified gas continues upward through the water enrichiny section of tower TC-101-2, transferring deuterium to the process water therein.
Additional gas returning from the stage 2 cold tower, via ~lB, Fig. 10 and 51A, Fig. 9, enters the bottom of the cold tower Ç
of stage 1 where it joins the gas flow from the dehumidification section. The gas leaves the top of the cold tower via 41A, and is returned to the bottom of the hot tower by the stage 1 gas compressor C-101-2. 3 Feedwater (e.g. treated sea-water) is pumped from the feedwater H2S saturate by pump P-003-2 and via 55A enters ?
the top of the feed section of the stage 1 hot tower~ and deuterium is stripped therefrom by the countercurrent flow of ~ H2S gas passing therethrough. The deuterium depleted feedwater : then discharges via 54A and 8A to the effluent treating system referred to above. In the illustrative embodiment of Fig. 9 and 9 (alt) the quantity of sea-water delivered via 55A to the feed section is about 115% of the quantity of process water ~0 delivered via 9A to the cold tower.
` A portion of the water discharged via lOA from the t~
dehumidification section below the stage 1 cold tower is pumped by the hot tower feed pump P-108-2 to the top of the stage 1 - hot tower via llA. This water f lows downward in the hot tower, transferring deuterium to the countercurrent flow of hot process gas therein, and is thus withdrawn from the bottom of the strip-ping section of the hot tower above the upper seal tray of the feed section via 107A, and is split into three streams. The main stream via 37A, 46A and 9A is returned to the cold tower as process water. The second stream via 103A, 104A enters the recycle tower. The third stream via 103A, 105A is ~elivered to serve as wash water for gas entrainment elimination in the hot i, ; ,~
,. :

~06Z60~;

tower feed section as a~oresaid, and then mixed with sea-water feed supply. In this illustrative embodiment the total quantity of water passincJ through the parallel sections of the lower portion of the hot tower is almost 150~ o~ the quantity of water passing through the cold tower.
The water entering the recycle tower from 104a passes t downward, transferring deuterium to the countercurrent flow of r hot humidified gas supplied via 58A, is discharged from the bottom of the recycle tower, and is pumped by the pump P-106-2 via 102A to the top of the humidification section to provide water for humidification of the gas recirculating from the cold ~`
tower to the hot tower.
Process water entering the top of the stage 1 cold tower via 9A is supplied from process water withdrawn from above r the feed section of the hot tower via 107A as aforesaid. This , water is pumped by pump P-105-2 via 37A through a recycle heat .:, , ,- , exchanger train E-105- and two recycle coolers E-116- and E-106-before entering at the top of the cold tower via 9A. It is t joined by a recycled impoverished water s-tream withdrawn via 23A, ~`
24A, 113A from the bottom of the humidification section. This . ~.,.
recycled stream not only serves to prevent the buildup of dissolved salts from the water evaporation in the humidification section, but also in part may provide means for effecting a re- ;~
duction in the concentration of deuterium in the fluids at the .. ~ ~.
top of the cold tower and in turn at the bottom of the hot tower whereby a greater degree of recovery of the deuterium from the feed supply may be achieved as described above for the system - of Fig. 8.
Another aspect of the present invention is the by-pass pipe preceding the intake of the feedwater pump P-003-2 which extends thereto from the discharge pipe 8A for recycling through the feed section all or part or none of the sea-water '. ' , , .
5~ . -- : . ~ . . , " `
- - ' ' ' ' ' . : '~ . :

~06Z606 discharge via pipe 8A. Suitable valves for control thereof are provided. Use of this by-pass is particularly advantageous to avoid shutdown of operation of the entire system when the feed supply becomes wholly or partially unavailable for delivery to the system. Shutdown is costly in that the enriched fluids in the towers drain and mix with the depleted fluids requiring an extensive and costly period to resume operations and to reestablish the steady state enrichment gradients in the towers.
Since both the sea-water feed and discharge flows to and from - 10 the feed section are at substantially identical conditions, except as to enrichment, no further treatment is required for such recycling to maintain the entire system in stable operation, inasmuch as the other flows of the process water and gas through the towers comprise circulations operating independently of the feed supply. In addition, the sea-water recycle provides ad-vantages during normal operation of the system to effect an increased extraction of the deuterium contained in the feed - which may be utilized to increase the productivity of the 1 system or to reduce the quantity of sea water to be treated for delivery to the system or both. Use of the sea-water recycle ¦~
serves to lower the concentration of the sea-water supply to the feed section, which in turn reduces the enrichment attained by the gas at the top of the feed section, which in turn effects a greater impoverishment in the process water recycling from the hot tower via 107A to the cold tower via 9A and in turn effects greater impoverishment of the gas recirculating from the cold tower to the hot tower, whereby the water discharging from the bottom of the hot tower, e.g. sea-water from the bottom of the ..
feed section, is more impoverished with a resultant increase in the extraction of deuterium per unit quantity of the sea-water feed supplied to the feed section.
The relation of the by-pass preceding the intake ... .

, ~0~i260~i of the ~eed-water pump P-003-2 corresponds to the valved by-pass q5a shown in Eig. 5a.
The process water flows downward throuyh the cold tower and is enriched with deuterium as it contacts the countercurrent flow of deuterium enriched H2S gas therein.
This cold deuterium enriched water, mixed with the cooled recycling water flows from 14A, 17A and 20A, is heated in the dehumidification system below the cold tower and is dis-charged therefrom,together with the condensate formed by cooling of the hot humidified gas from 40A, via 10A. One part thereof via llA is uassed to the top of the stage 1 hot tower as heated process water; and a second part thereof via r 12A is passed to the branched heat exchanger train E-101-, E-102-, E-103- wherein it is differentially cooled and returned in the three streams 14A, 17A and l9A-20A to the levels of corresponding temperature in the dehumidification section.
The water flows to the humidification section under the hot tower TH-101-2 consist of the flow via 102A from the recycle tower and the flow via 31A of circulated water of the

4 branches 35A, 3~A, 43A and 24A of the second cyclic flow ~!".' ' ' :~ r~ -system, which branches are withdrawn from the countercurrent f;
,.~ - t humidification section in three streams, upper, middle and lower, by the pumps, P-104-2, P-103-2 and P-102-2.
, .
- The discharges from these pumps pass through the indirect contact heat exchangers E-101-, E-102-, E-103- and E-105- in differential series, as shown, to recover heat from ~I the above described branched cyclic flow associated with the ;' dehumidification section and from the process water being recycled from the hot tower to the cold tower via 107A. In the course of the heating in these several heat exchangers, H2S gas is evolved from the water. The heated streams are therefore passed through gas separators D-101-, D-102-, D-103-2~ -. .

~ . - , :
.

and D-105- ~rom which the collected gas is returned via 59A to the hot tower. Parts of the water in 35A, 34A and 43~ pass to corresponding differential heat exchangers in stages 2 and 3 in parallel arranyement to those in stage 1, and the combined heated streams return via 31A to the humidification section below the stage 1 hot tower.
Deuterium enriched process water passing through the dehumidification section from the cold tower TC-101-2 cools and dehumidifies the countercurrent gas stream from 40A. The water is withdrawn from the bottom of the dehumidification section via lOA and a part thereof is passed, via pump P-107-2 and 12A, to the heat exchanger means E-101- as above described. A portion of the discharge from such heat exchanger means is returned to the dehumidification section via 13A and 14A as the lower dehumid-ification stream. The remainder passes via 13A and 15A through a second heat exchanger means E-102- and a portion is delivered via 16A and 17A as the middle dehumidification stream. The rest of the dehumidification water via 16A and 18A passes through a J
third heat exchanger means E-103- and two coolers E-114-2 and ; 20 E-104-2. A portion of this water, via 20A, is passed to the dehumidifier section as the upper dehumidifcation stream; the ,~
rest is pumped to the top of the cold tower of stage 2 via 52A
and 9B.
Stage 2, Fig. 10, operates with one set of towers;
a hot tower TH-201 and a cold tower TC-201. The stage 2 hot tower is a vertical pressure vessel consisting only of a water - impoverishing or deuterium stripping section. It is approximately18 feet in diameter and approximately 130 feet high. The cold tower is part of a pressure vessel approximately 16 feet in diameter and approximately 195 feet high which includes the cold tower water enriching section over a hydrogen sulfide gas dehumidification section. Both towers are made of carbon steel 2~

'-' ' ' : ' lQ62606 and use stainless steel sieve trays.
There are no sea-water feed sections or gas humidification sections in stages subsequent to stage 1.
Hot humidified H2S gas from stage 1 via 38s supplies the process gas for higher numbered stages.
Deuterium enriched H2S gas from the stage 1 hot towers via 38B enters the bottom of the stage 2 hot tower and passes upward therein stripping more deuterium from the countercurrent flow of process water. The deuterium enriched gas leaves the stage 2 hot tower via 39B and is split into two streams via 38C
and 40B. The flow via 38C passes to the bottom of the stage 3 hot tower TH-301; the flow via 40B is delivered to the bottom of the dehumidifier section below the stage 2 cold tower TC-201.
The gas passes upward in this dehumidification section in countercurrent direct contact with a branched cyclic flow of cooling water and the water from the cold tower TC-201. In this dehumidification section the hot gas from 40B is coo~ed and de-' humidified and then passed into the cold tower where it merges with the gas recycled from stage 3 via 41C. The gas transfers its deuterium to the countercurrent flow of water and then leaves the cold tower via 41B, from which it was pumped to the cold tower of stage 1 by the stage 2 gas compressor C-201, via 51A, Figs. 9 and 9 (alt), above described.
Deuterium enriched process water from the stage 1 cold towers via 52A and gs is delivered into the top of the stage 2 cold tower TC-201, where it becomes further enriched by picking up deuterium from the countercurrent flow of process gas therein. This deuterium enriched water enters the stage 2 dehumidification section where it mixes with the recirculating branched flow of cooling water and with the condensate formed from the cooling of the hot gas therein.

The heated water withdrawn from the bottom of the ., .
:

. .. ~ :
- . - . . .. .. .... .:

i~62~;06 stage 2 ~ehumidifier section via lOB is split into two streams, one of which is pumped via 12B through branched circuits com-prising heat exchanger means E-201, E-202, E-203 and is returned at differential temperatures to corresponding temperature levels of the stage 2 dehumidification section via 14B, 17B and l9B-20B; the other being pumped by the pump P-208 to the stage 2 hot tower via llB.
Process water recycled ~rom stage 3 via 23C joins the process water stream from llB to the top of the hot tower TH-201 and these combined streams flow downward in the tower TH-201 and are stripped of deuterium by the countercurrent flow of H2S gas therein. The process water is discharged from the -bottom of this hot tower via 23B and is returned to the stage 1 hot towers by pump P-201.
The greater part of the process water withdrawn via lOB from the dehumidification section at the bottom of the stage 2 cold tower is recycled via 12B. This water is cooled and introduced into the dehumidification section below the cold tower TC-201 in three streams, as above described. In more detail, the pump P-202 pumps the water via 12s through the heat recovery exchanger means E-201, cooling the water. A portion of the so cooled water via 13B and 14B passes to the dehumidifi-cation section as the lower stream thereto; the rest is pumped by the pump P-204 to the heat recovery exchanger means E-202, and a portion of the further cooled water therefrom via 16B and 17B becomes the middle dehumidification steam; the remainder thereof via 16B, 18B passing through heat exchanger means E-203 and thence through two coolers E-214 and E-204. A portion of the stream of cold water from E-204 passes via pump P-303 and 9C to the top of the stage 3 cold tower TC-301 as process water; and the remainder enters the top of the stage 2 dehumidification section via 2OB.

- ~ 30 -- : , , .~ . .
- : - i ~

106:2606 Stage 3, following stage 2 in Fig. 10, is essentially a repetition of stage 2 operating at a higher degree of enrich-ment and with relatively smaller volumes of fluids in correspond-ingly smaller apparatus, and the arrangement of the like ele-ments of stage 2; the items of equipment being designated by the same reference numerals in a "300" series as compared to those in a "200" series in stage 2 and a "100" series in stage 1;
and the corresponding piping of the stages being designated by like numerals but with the ascribed "C" for stage 3, "B" for stage 2, and "A" for stage 1.
As indicated in connection with the stage 3 diagram, Fig. 10, this stage may be followed by one or more further enrichment stages. As there indicated such may be of the dual temperature exchange type employed in the earlier stages, but ;~ the invention is not limited in this regard and further enrich~

, ment may be effected in any appropriate way. Since the stages t herein described may effect some 500 to 1000 fold enrichment representing more than 90% of the total capital and operating costs to achieve a final product concentrate of 99.8 mol percent D2O, the type of system utilized for the final enrichment whether it be of any of the known dual temperature types, water distill~
ation types, or electrolytic types, or combinations thereof, is not of major importance and forms no part of the present invention.
Another aspect of the present invention indicated in Figs. 9 and 10, resides in improvements which enable a multiple stage plant to be established for the production of final product at one rate, e.g. 200 tons per year, with provision for a reduct-` ion or expansion of its capacity by addition or subtraction of : ~ .
parallel first stage hot and cold tower pair systems, withoutneed for altering the volumetric equipment in the following . .
stages.
. . .

, . . :

In Figs. 9 (alt) and 10, the illustrated stages comprising a first stage having two identical parallel tower pair systems and second, third and fourth stages of one pair each are capable of enriching material sufficient to yield 200 tons per year of final product; by effecting a 3-fold enrich-ment of the deuterium content of the process water delivered via 9B (Fig. 9 (alt) and Fig. 10) to the second stage cold tower, t as compared to the sea-water feed entering the first stage via 55A; followed by a further 9-fold enrichment in stage 2, a further 16.2-fold enrichment in stage 3, leaving only a 16.1 fold enrichment to be imparted by the final enrichment system to achieve the approximately 7,000-fold enrichment constituting the final product.
According to the expansion concept of the present ~ invention, by adding two additional sets of stage 1 sections ; connected between the "gang" symbols of Fig. 9, and maintaining the same total volume flows from stage 1 to the following stages, i.e. halving the volume flows from each of said tower pairs of stage 1 to the second stage, the former 3-fold enrichment in the first stage is increased to a 6-fold enrichment, without adding any additional equipment in the subsequent stages. To achieve this result the tower pair sections of the first stage are constructed with sufficient trays in the hot and cold towers to accommodate a 6-fold enrichment at half the contemplated volumetric withdrawal rate of fluids to the second stage, and `' until such time as the third and fourth parallel sections are installed, the withdrawal rates from the first and second parallel sections are set at twice the rates contemplated for the 6-fold enrichment, thus delivering four units of volume at 30 3-fold enrichment rather than two units of volume at 6-fold enrich-ment, at a nominal sacrifice of optimum tower efficiency. Thus when the third and fourth ganged sections are installed, the _ 32 _ ~06;2606 total withdrawal to the second stage previously supplied from two first stage sections, is divided between the four first ~' stag~ sections, thus reducing the withdrawal rate per section to that at which each section affords a 6-fold enrichment at full efficiency as originally contemplated. When gas is transferred between the first and second stages as shown, jl the reduced withdrawal of gas from the individual sections ~ -of the first stage results in about a 25% increase in the gas flows in each of the dehumidifying sections below the cold towers of the first stage. Thus when third and fourth tower pair units are added, the heat recovery exchangers E-101-, E-102-, and ¦~
E-103 , have their capacities increased proportionately by added parallel units thereof as indicated at XE-101-, XE-122-, and XE-123-, with similar increase in the coolers E-114- and E-104- as indicated at XE-124, to condition the increased gas flow.
Conversely, with the first stage consisting o~ ¦
"ganged" parallel sections it becomes possible to shut down for maintenance, or otherwise, less than all of the "ganged"
sections of the first stage, provided the ultimate size of 5 ` the final enrichment treatment (by whatever method) is con-structed to accommodate substantially the same volume of input, 5 but at a reduced concentration proportionally corresponding to the minimum concentration to be delivered to the second stage from the first stage at such time. In light of the quite small quantities of fluids to be handled by the final enrichment system for the ultimate product, the cost of providing it with such capability is essentially nominal. With such arrangement . the enrichment multiplication factor of the intermediate stage-s . I
remains substantially constant with constant volume total input ~ from the parallel first stage sections and constant volume output ;; to the final enrichment system. Also with this arrangement, :' ~ 33 -I ., -1062606i during such partial shutdown there is no need to reduce the extra capacities of the heat recovery exchangers XE-101-, etc., as the excess capacit~ thereof actually increases the overall efficiency of the heat recovery system in such circumstances, with consequent reduction in the quantity of steam required to be supplied via 114A.
Thus by this improvement of the present invention the limited additional capital investment of 25%, more or less, of the exchange portions of the hot and cold towers of the first stage only of the initial plant, with no significant added investment in any other part of the initial plant, provides a plant which can be expanded to double its initial product output capacity at only a fraction of the cost of duplicating a plant without such improvement; and similar ; advantages may be obtained in other embodiments of this invention contemplating other capacity expansions, e g. from a single pair of first stage towers to two, three, four or even more pairs thereof as contemplated by the "gang" symbols in Fig. 9, for which purpose, the extra plates required to be installed in the initial plant to provide for multiplications of the enrichment by stage 1 in such proportions progressively decrease as the . .
degree of enrichment increases.
As an alternative of this aspect of the invention, the tower units of the initial construction may be constructed with-out the additional plate capacity, and may be extended by the connection of further tower sections in series therewith to pro-vide said additional capacity at the time the further first stage - tower units are connected in parallel therein.
r ~ ' 34_ ' .

Claims (3)

THE EMBODIMENTS OF THE INVENTION IN WHICH AN EXCLUSIVE
PROPERTY OR PRIVILEGE IS CLAIMED ARE DEFINED AS FOLLOWS:

1. In an integrated system for concentrating a desired material exchangeable between two separable fluid sub-stances containing said material and another material exchangeable therewith, at least one of said fluid substances being in liquid phase, said system including (a) a first enrichment section comprising a first stage operating system having at least one pair of dual tempera-ture exchange hot and cold towers and a prescribed feed supply of one of said fluid substances, and connected thereto (b) an intermediate enrichment section comprising an operating system of at least a second stage of dual temperature exchange hot and cold towers, and connected thereto (c) a final enrichment section comprising a system for further enriching at least one of the enriched fluids from said intermediate enrichment section to a prescribed final product concentration, the improvement which provides for modification to increase the quantity of final product output without physical alteration of the intermediate and final enrichment sections wherein:
(1) the hot and cold towers of said first enrichment section comprise enrichment means which include therein counter-current contact exchange elements sufficient in number to provide that when the volume of enriched fluids withdrawn from said first enrichment section and delivered to said intermediate enrichment section is fractionally reduced such reduced volume will transport to the intermediate enrichment section substantially the same amount of the desired material at an increased concentration, and (2) said final enrichment section comprises enrichment means of sufficient capacity to produce a final product of the prescribed concentration when said volume of enriched fluids delivered to said intermediate enrichment section is not so fractionally reduced.

2. An improved integrated system as claimed in Claim 1, wherein:
(3) said first enrichment section includes a second of said first stage operating systems, similarly having a pre-scribed feed supply of one of said fluid substances, and having its fluid outputs to the second stage connected in parallel with those of the first stage operating system referred to in clause (a), and (4) the first enrichment section comprises means for proportioning its output volume between said parallel first stage systems so that the total output of said first enrichment section to said intermediate enrichment section is substantially the same with or without the parallel connection referred to in clause (3), whereby the concentration of the desired material in said total output is increased, and the quantity of final product produced in said final enrichment section is proportion-ately greater with said parallel connection.

3. An improved integrated system as claimed in Claim 2, wherein:
(5) one of said fluids is in gas phase and said first enrichment section comprises means for delivering an enriched hot portion of said gas phase to the hot tower portion of said intermediate enrichment section, and (6) each of said first stage operating systemscomprises heat exchanger means for cooling the remainder of said gas phase with condensation of vapor of said liquid phase substance there-from, the capacity of said heat exchanger means being sufficiently great to accommodate the load imposed thereon with or without the parallel connection referred to in clauses (3) and (4).