BRPI0915369A2 - process for enrichment of hydrogen synthesis gas and use of a catalyst containing zinc and aluminum oxides - Google Patents

process for enrichment of hydrogen synthesis gas and use of a catalyst containing zinc and aluminum oxides

Info

Publication number
BRPI0915369A2
BRPI0915369A2 BRPI0915369A BRPI0915369A BRPI0915369A2 BR PI0915369 A2 BRPI0915369 A2 BR PI0915369A2 BR PI0915369 A BRPI0915369 A BR PI0915369A BR PI0915369 A BRPI0915369 A BR PI0915369A BR PI0915369 A2 BRPI0915369 A2 BR PI0915369A2
Authority
BR
Brazil
Prior art keywords
enrichment
synthesis gas
catalyst containing
containing zinc
aluminum oxides
Prior art date
Application number
BRPI0915369A
Other languages
Portuguese (pt)
Inventor
Niels Christian Schjødt
Original Assignee
Haldor Topsoe As
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Haldor Topsoe As filed Critical Haldor Topsoe As
Publication of BRPI0915369A2 publication Critical patent/BRPI0915369A2/en
Publication of BRPI0915369B1 publication Critical patent/BRPI0915369B1/en
Publication of BRPI0915369B8 publication Critical patent/BRPI0915369B8/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/48—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents followed by reaction of water vapour with carbon monoxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/005—Spinels
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/06—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of zinc, cadmium or mercury
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/80—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with zinc, cadmium or mercury
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/06—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
    • C01B3/12—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide
    • C01B3/16—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide using catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/10—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of rare earths
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0233—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a steam reforming step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0283—Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0405—Purification by membrane separation
    • C01B2203/041—In-situ membrane purification during hydrogen production
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1076—Copper or zinc-based catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1094—Promotors or activators
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
BRPI0915369A 2008-07-03 2009-06-15 process for enriching hydrogen synthesis gas and using a catalyst containing zinc and aluminum oxides BRPI0915369B8 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DKPA200800935 2008-07-03
DKPA200800935 2008-07-03
PCT/EP2009/004288 WO2010000387A1 (en) 2008-07-03 2009-06-15 Process for operating hts reactor

Publications (3)

Publication Number Publication Date
BRPI0915369A2 true BRPI0915369A2 (en) 2015-11-03
BRPI0915369B1 BRPI0915369B1 (en) 2019-09-24
BRPI0915369B8 BRPI0915369B8 (en) 2020-02-04

Family

ID=40983342

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI0915369A BRPI0915369B8 (en) 2008-07-03 2009-06-15 process for enriching hydrogen synthesis gas and using a catalyst containing zinc and aluminum oxides

Country Status (12)

Country Link
US (1) US8404156B2 (en)
EP (2) EP2300359B1 (en)
KR (1) KR101529906B1 (en)
CN (1) CN102083745B (en)
BR (1) BRPI0915369B8 (en)
CA (1) CA2729736C (en)
ES (2) ES2549382T3 (en)
MX (1) MX2010014351A (en)
PL (2) PL2300359T3 (en)
RU (1) RU2516546C2 (en)
WO (1) WO2010000387A1 (en)
ZA (1) ZA201009233B (en)

Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL2008313C2 (en) 2012-02-17 2013-09-02 Stichting Energie Water gas shift process.
GB201501952D0 (en) * 2015-02-05 2015-03-25 Johnson Matthey Plc Process
BR112018008318A2 (en) 2015-10-29 2018-10-30 Johnson Matthey Public Limited Company catalyst precursor, methods for preparing catalyst precursor and for producing a catalyst, water-gas displacement catalyst, and process for increasing hydrogen content
GB201519139D0 (en) 2015-10-29 2015-12-16 Johnson Matthey Plc Process
GB201519133D0 (en) 2015-10-29 2015-12-16 Johnson Matthey Plc Process
KR102438434B1 (en) * 2016-02-02 2022-09-01 토프쉐 에이/에스 ATR-based ammonia process and plant
GB201603298D0 (en) * 2016-02-25 2016-04-13 Johnson Matthey Plc Process
AR107702A1 (en) 2016-02-29 2018-05-23 Haldor Topsoe As RENEWAL WITH LOW AMOUNT OF STEAM / CARBON
AU2018231412B2 (en) * 2017-03-07 2023-06-15 Haldor Topsøe A/S Ammonia process using advanced shift process
CN110831892A (en) * 2017-07-13 2020-02-21 托普索公司 Process and catalyst for producing ammonia synthesis gas
CN108435182B (en) * 2017-08-16 2021-01-15 西安向阳航天材料股份有限公司 Preparation method of copper-based low-temperature shift catalyst
PL235786B1 (en) * 2017-09-29 2020-10-19 Grupa Azoty Spolka Akcyjna Zinc promoted catalyst of carbon monoxide steam conversion and method for obtaining it
PL234182B1 (en) * 2017-09-29 2020-01-31 Inst Nowych Syntez Chemicznych Zinc promoted catalyst of carbon monoxide steam conversion and method for obtaining it
BR102020020748A2 (en) 2020-10-08 2022-04-19 Petróleo Brasileiro S.A. - Petrobras Methods of preparation of high temperature water gas displacement catalysts, catalysts and process for carbon monoxide reduction
EP4251315A1 (en) 2020-11-24 2023-10-04 Topsoe A/S Process for producing hydrogen from co-rich gases
JP2023550313A (en) * 2020-11-24 2023-12-01 トプソー・アクチエゼルスカベット Improved water gas shift catalyst
US20240002223A1 (en) 2020-11-24 2024-01-04 Topsoe A/S Method of starting-up a water gas shift reactor
BR102020025161A2 (en) * 2020-12-09 2022-06-21 Petróleo Brasileiro S.A. - Petrobras METHOD OF PREPARING A HIGH TEMPERATURE GAS DISPLACEMENT CATALYST AND PROCESS TO REDUCE THE CONTENT OF CARBON MONOXIDE
US20240116756A1 (en) 2022-10-06 2024-04-11 Air Products And Chemicals, Inc. Process and System for Water-Gas Shift Conversion of Synthesis Gas with High CO Concentration

Family Cites Families (11)

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Publication number Priority date Publication date Assignee Title
FR2567866B1 (en) * 1984-07-20 1987-01-02 Shell Int Research PROCESS FOR THE PREPARATION OF A HYDROGEN-RICH GAS
EP0361648B1 (en) 1988-07-22 1993-04-07 Imperial Chemical Industries Plc Hydrogen production including a shift reaction process
GB8817480D0 (en) 1988-07-22 1988-08-24 Ici Plc Hydrogen
GB9225372D0 (en) * 1992-12-04 1993-01-27 British Petroleum Co Plc Oxide compositions
EP1149799B1 (en) 2000-04-27 2003-10-08 Haldor Topsoe A/S Process for the production of a hydrogen rich gas
GB0121680D0 (en) * 2001-09-08 2001-10-31 Ici Plc Catalysts
US6627572B1 (en) * 2002-03-22 2003-09-30 Sud-Chemie Inc. Water gas shift catalyst
US20040105804A1 (en) * 2002-11-29 2004-06-03 Industrial Technology Research Institute Catalyst for water-gas shift reaction and method for converting carbon monoxide and water to hydrogen and carbon dioxide
ES2381105T3 (en) * 2003-02-05 2012-05-23 Haldor Topsoe A/S Procedure for the treatment of synthesis gas
AU2004226237B2 (en) * 2003-04-01 2009-08-13 Haldor Topsoe A/S Process for the preparation of a hydrogen-rich stream
JP2004321924A (en) * 2003-04-24 2004-11-18 Toyota Central Res & Dev Lab Inc Catalyst for water gas shift reaction

Also Published As

Publication number Publication date
BRPI0915369B1 (en) 2019-09-24
CN102083745B (en) 2014-04-02
US8404156B2 (en) 2013-03-26
PL2300359T3 (en) 2016-01-29
RU2011103674A (en) 2012-08-10
WO2010000387A1 (en) 2010-01-07
PL2924002T3 (en) 2019-09-30
MX2010014351A (en) 2011-05-03
EP2924002B1 (en) 2019-04-24
KR101529906B1 (en) 2015-06-18
EP2300359B1 (en) 2015-08-26
CA2729736A1 (en) 2010-01-07
US20110101279A1 (en) 2011-05-05
KR20110039422A (en) 2011-04-18
RU2516546C2 (en) 2014-05-20
CN102083745A (en) 2011-06-01
ZA201009233B (en) 2012-04-25
ES2728916T3 (en) 2019-10-29
CA2729736C (en) 2015-09-15
EP2924002A1 (en) 2015-09-30
BRPI0915369B8 (en) 2020-02-04
EP2300359A1 (en) 2011-03-30
AU2009266113A1 (en) 2010-01-07
ES2549382T3 (en) 2015-10-27

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Legal Events

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B06F Objections, documents and/or translations needed after an examination request according [chapter 6.6 patent gazette]
B06T Formal requirements before examination [chapter 6.20 patent gazette]

Free format text: O DEPOSITANTE DEVE RESPONDER A EXIGENCIA FORMULADA NESTE PARECER POR MEIO DO SERVICO DE CODIGO 206 EM ATE 60 (SESSENTA) DIAS, A PARTIR DA DATA DE PUBLICACAO NA RPI, SOB PENA DO ARQUIVAMENTO DO PEDIDO, DE ACORDO COM O ART. 34 DA LPI.PUBLIQUE-SE A EXIGENCIA (6.20).

B06A Patent application procedure suspended [chapter 6.1 patent gazette]
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16C Correction of notification of the grant [chapter 16.3 patent gazette]

Free format text: REF. RPI 2542 DE 24/09/2019 QUANTO AO INVENTOR.