BRPI0913160A2 - catalyst for gas phase catalytic oxidation of aromatic hydrocarbons forming aldehydes, carboxylic acids and / or carboxylic acid anhydrides, especially phthalic acid anhydride, as well as a method for the manufacture of such a catalyst - Google Patents

catalyst for gas phase catalytic oxidation of aromatic hydrocarbons forming aldehydes, carboxylic acids and / or carboxylic acid anhydrides, especially phthalic acid anhydride, as well as a method for the manufacture of such a catalyst

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Publication number
BRPI0913160A2
BRPI0913160A2 BRPI0913160A BRPI0913160A BRPI0913160A2 BR PI0913160 A2 BRPI0913160 A2 BR PI0913160A2 BR PI0913160 A BRPI0913160 A BR PI0913160A BR PI0913160 A BRPI0913160 A BR PI0913160A BR PI0913160 A2 BRPI0913160 A2 BR PI0913160A2
Authority
BR
Brazil
Prior art keywords
catalyst
manufacture
well
gas phase
aromatic hydrocarbons
Prior art date
Application number
BRPI0913160A
Other languages
Portuguese (pt)
Inventor
Josef Breimair
Original Assignee
Josef Breimair
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Josef Breimair filed Critical Josef Breimair
Publication of BRPI0913160A2 publication Critical patent/BRPI0913160A2/en
Publication of BRPI0913160B1 publication Critical patent/BRPI0913160B1/en

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66—Silver or gold
    • B01J23/68—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/063—Titanium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/20—Vanadium, niobium or tantalum
    • B01J23/22—Vanadium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66—Silver or gold
    • B01J23/68—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/682—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with vanadium, niobium, tantalum or polonium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66—Silver or gold
    • B01J23/68—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/683—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum or tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/195—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with vanadium, niobium or tantalum
    • B01J27/198—Vanadium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/195—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with vanadium, niobium or tantalum
    • B01J27/198—Vanadium
    • B01J27/199—Vanadium with chromium, molybdenum, tungsten or polonium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0215—Coating
    • B01J37/0219—Coating the coating containing organic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0215—Coating
    • B01J37/0221—Coating of particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0215—Coating
    • B01J37/0228—Coating in several steps
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B41/00—Formation or introduction of functional groups containing oxygen
    • C07B41/08—Formation or introduction of functional groups containing oxygen of carboxyl groups or salts, halides or anhydrides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/255—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of compounds containing six-membered aromatic rings without ring-splitting
    • C07C51/265—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of compounds containing six-membered aromatic rings without ring-splitting having alkyl side chains which are oxidised to carboxyl groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/77—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom ortho- or peri-condensed with carbocyclic rings or ring systems
    • C07D307/87—Benzo [c] furans; Hydrogenated benzo [c] furans
    • C07D307/89—Benzo [c] furans; Hydrogenated benzo [c] furans with two oxygen atoms directly attached in positions 1 and 3
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Catalysts (AREA)
BRPI0913160-4A 2008-08-29 2009-07-24 CATALYST FOR CATALYTIC OXIDATION OF GAS PHASE PHASE OF AROMATIC HYDROCARBONS FORMING ALDEIDS, CARBOXYLIC ACIDS AND / OR ANIDRIDS, ESPECIALLY ANXYRID OF PHYTHESIC ASPHYPHYLES, AS A PHYSICAL AND ANALYZED BRPI0913160B1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE102008044890.7 2008-08-29
DE102008044890.7A DE102008044890B4 (en) 2008-08-29 2008-08-29 Catalyst for the catalytic gas phase oxidation of aromatic hydrocarbons to aldehydes, carboxylic acids and/or carboxylic anhydrides, in particular to phthalic anhydride, and process for producing such a catalyst
PCT/EP2009/005372 WO2010022830A2 (en) 2008-08-29 2009-07-24 Catalyst for the catalytic gas phase oxidation of aromatic hydrocarbons to form aldehydes, carboxylic acids and/or carboxylic acid anhydrides, in particular phthalic acid anhydride, and method for producing said type of catalyst

Publications (2)

Publication Number Publication Date
BRPI0913160A2 true BRPI0913160A2 (en) 2016-07-26
BRPI0913160B1 BRPI0913160B1 (en) 2018-03-27

Family

ID=41479607

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI0913160-4A BRPI0913160B1 (en) 2008-08-29 2009-07-24 CATALYST FOR CATALYTIC OXIDATION OF GAS PHASE PHASE OF AROMATIC HYDROCARBONS FORMING ALDEIDS, CARBOXYLIC ACIDS AND / OR ANIDRIDS, ESPECIALLY ANXYRID OF PHYTHESIC ASPHYPHYLES, AS A PHYSICAL AND ANALYZED

Country Status (7)

Country Link
EP (1) EP2321045A2 (en)
KR (1) KR101706790B1 (en)
CN (1) CN102196859B (en)
BR (1) BRPI0913160B1 (en)
DE (1) DE102008044890B4 (en)
TW (1) TWI518079B (en)
WO (1) WO2010022830A2 (en)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2011061132A1 (en) * 2009-11-20 2011-05-26 Basf Se Multilayer catalyst for producing carboxylic acids and/or carboxylic acid anhydrides with vanadium antimonate in at least one catalyst layer, and method for producing phthalic acid anhydride with a low hot-spot temperature
DE102013202048A1 (en) * 2013-02-07 2013-04-18 Basf Se Preparing catalytically active composition useful for preparing a catalyst, comprises e.g. thermally treating geometrical precursor bodies formed by a mixture obtained by uniformly mixing e.g. a spray-dried powder and molybdenum oxide
EP3047904A1 (en) 2015-01-22 2016-07-27 Basf Se Catalyst system for oxidation of o-xylene and/or naphthalene to phthalic anhydride
CN107999107A (en) * 2016-10-28 2018-05-08 中国石油化工股份有限公司 A kind of maleic anhydride catalyst and its preparation method and application
DE102017202351A1 (en) * 2017-02-14 2018-08-16 Clariant International Ltd Catalyst material for the oxidation of hydrocarbons with antimony-doped titanium dioxide
NL2018890B1 (en) * 2017-05-10 2018-11-15 Admatec Europe B V Additive manufacturing of metal objects
CN109110910A (en) * 2018-08-31 2019-01-01 江苏新亿源环保科技有限公司 A kind of preparation method of high catalytic property suspension step biofilter material
CN109158119A (en) * 2018-09-14 2019-01-08 中海油天津化工研究设计院有限公司 A kind of catalyst and preparation method for durol oxidation
CN109369544B (en) * 2018-12-05 2022-06-03 兰州大学 Method for preparing 5-methylpyrazine-2-carboxylic acid by catalytic oxidation
CN114100651B (en) * 2020-08-25 2023-12-08 中国石油化工股份有限公司 Catalyst for preparing maleic anhydride by benzene oxidation and preparation method and application thereof
CN114539207B (en) * 2020-11-24 2023-09-19 万华化学(四川)有限公司 Method for preparing lactide and catalyst
CN114682278B (en) * 2020-12-29 2023-09-01 中国石油化工股份有限公司 Anti-phosphorus loss vanadium phosphorus oxide catalyst
IT202100021746A1 (en) 2021-08-11 2023-02-11 Polynt S P A Multilayer catalytic bed for the production of phthalic anhydride.

Family Cites Families (12)

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Publication number Priority date Publication date Assignee Title
NL134884C (en) 1965-05-18
DE2106796C3 (en) 1971-02-12 1981-09-24 Wacker-Chemie GmbH, 8000 München Process for the production of fixed bed catalysts with a coating of vanadium pentoxide and titanium dioxide
DE2925682A1 (en) 1979-06-26 1981-01-29 Basf Ag VANADINE PENTOXIDE, TITANIUM DIOXIDE, PHOSPHORUS, RUBIDIUM AND / OR CAESIUM AND Possibly. ZIRCONDIOXIDE CONTAINING CARRIER CATALYST
US4864036A (en) 1984-06-29 1989-09-05 Exxon Research & Engineering Company Process for preparing aromatic carboxylic anhydride
JPS63253080A (en) 1987-04-10 1988-10-20 Nippon Steel Chem Co Ltd Production of phthalic anhydride
US5169820A (en) 1990-03-16 1992-12-08 Nippon Shokubai Kagaku Kogyo Co., Ltd. Catalyst for producing phthalic anhydride
US5235071A (en) 1991-07-10 1993-08-10 Nippon Shokubai Co., Ltd. Catalyst for producing phthalic anhydride and process by using the same
DE4343449C2 (en) 1993-12-20 1998-01-15 Friatec Keramik Kunststoff Process for electric welding
DE19851786A1 (en) 1998-11-10 2000-05-11 Basf Ag Multimetal oxide containing silver and vanadium oxide and its use
DE102004014918A1 (en) 2004-03-26 2005-10-13 Basf Ag Catalyst with a silver vanadium oxide phase and a promoter phase
DE102008011011A1 (en) * 2008-02-01 2009-08-06 Breimair, Josef, Dr. Catalyst for the catalytic gas-phase oxidation of aromatic hydrocarbons to aldehydes, carboxylic acids and / or carboxylic anhydrides, in particular to phthalic anhydride
CN101938086B (en) * 2010-08-25 2013-03-27 南京大学 Method for constructing cascade superlattice mode-locked laser

Also Published As

Publication number Publication date
TWI518079B (en) 2016-01-21
EP2321045A2 (en) 2011-05-18
KR101706790B1 (en) 2017-02-15
CN102196859A (en) 2011-09-21
DE102008044890A1 (en) 2010-03-04
DE102008044890B4 (en) 2023-09-14
BRPI0913160B1 (en) 2018-03-27
CN102196859B (en) 2014-08-06
WO2010022830A3 (en) 2010-05-20
TW201012805A (en) 2010-04-01
WO2010022830A2 (en) 2010-03-04
KR20110050694A (en) 2011-05-16

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B07A Application suspended after technical examination (opinion) [chapter 7.1 patent gazette]
B07A Application suspended after technical examination (opinion) [chapter 7.1 patent gazette]
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]
B21F Lapse acc. art. 78, item iv - on non-payment of the annual fees in time

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B24J Lapse because of non-payment of annual fees (definitively: art 78 iv lpi, resolution 113/2013 art. 12)

Free format text: EM VIRTUDE DA EXTINCAO PUBLICADA NA RPI 2594 DE 24-09-2020 E CONSIDERANDO AUSENCIA DE MANIFESTACAO DENTRO DOS PRAZOS LEGAIS, INFORMO QUE CABE SER MANTIDA A EXTINCAO DA PATENTE E SEUS CERTIFICADOS, CONFORME O DISPOSTO NO ARTIGO 12, DA RESOLUCAO 113/2013.