BRPI0910059B1 - solid composition for pest control - Google Patents

Abstract

SOLID COMPOSITION FOR PEST CONTROL The present invention relates to an anthranilamide formulation compound to enhance the effects of pest control. A solid pest control composition comprising an amorphous anthranilamide compound or its salt as an active pesticidal ingredient, a surfactant and / or a surfactant and a mineral carrier.

Description

TECHNICAL FIELD

The present invention relates to a solid pest control composition, comprising an anthranilamide compound whose pesticidal activity is increased.

PREVIOUS TECHNIQUE

Anthranilamide type insecticides are known to be useful for controlling pests, such as Lepidoptera, and Patent Document 1 describes as their formulations, various formulations such as an emulsifier, a wetting powder, a dust or granules. In addition, Patent Document 2 describes as an formulation that enhances the effect of the compound to control pests, an oily suspension containing a hydrophobic solvent. Patent Document 1: WO 2005/077934 Patent Document 2: WO 2007/081553

DESCRIPTION OF THE INVENTION PROBLEMS TO BE SOLVED BY THE INVENTION

Many pesticides including anthranilamide compounds have characteristic spectra and effects respectively, however they have some problems in which the effects are often inadequate for certain pests, their residual activities are sometimes poor and the effects are not satisfactorily maintained for a certain period of time. time, and that adequate pesticide effects cannot practically be achieved. Therefore, it was desired to increase the control effects through a formulation method.

MEANS TO SOLVE THE PROBLEMS

The present inventors have conducted several studies to solve the above problems, and as a result have found that the pest control effects are markedly enhanced by making an anthranilamide compound that is amorphous. Therefore, the present invention has been accomplished. That is, the present invention relates to a solid pest control composition that is characterized by comprising an amorphous anthranilamide compound or a salt thereof as an active ingredient in a pesticide, a surfactant or a vehicle. In addition, the present invention relates to a wettable powder or water-dispersible granules comprising the above components.

EFFECTS OF THE INVENTION

The pesticidal composition of the present invention makes it possible to increase the effects of the anthranilamide compound and to control pests with a low dose of the compound.

BRIEF DESCRIPTION OF THE DRAWINGS

Figure 1 is a powder X-ray diffraction image of Example 1.

Figure 2 is a powder X-ray diffraction image from Comparative Example 1.

BEST MODE FOR CARRYING OUT THE INVENTION

The composition of the present invention comprises at least one amorphous anthranilamide compound or its salt, a surfactant and a vehicle.

em que R1 é halogênio, alquila ou ciano, A é alquila que pode ser substituída por C3^ cicloalquila e m é de 0 a 4.The anthranilamide compound or a salt thereof used in the present invention can, for example, be an anthranilamide compound represented by formula (I) or its salt:

where R1 is halogen, alkyl or cyano, A is alkyl that can be replaced by C3 ^ cycloalkyl and is 0 to 4.

In formula (I), the alkyl or alkyl moiety of R1 and A can be straight or branched. As a specific example, Ci.6alkyl, such as methyl, ethyl, propyl, isopropyl, butyl, pentyl or hexyl, can be mentioned. In addition, halogen such as R1 can, for example, be each fluorine, chlorine or bromine atom. The salt of the anthranilamide compound includes all types of salt, as long as they are agriculturally acceptable. Examples thereof include alkali metal salts, such as a sodium salt and a potassium salt; alkaline earth metal salts such as a magnesium salt and a calcium salt; ammonium salts such as dimethylammonium salt and a triethyl ammonium salt; inorganic acid salts such as a hydrochloride, a perchlorate, a sulfate and a nitrate; and salts of organic acid such as an acetate and a methane sulphate. The anthranilamide compound is preferably the following compounds: (1) 3-Bromo-N- (2-bromo-4-chloro-6- (1-cyclopropylethylcarbamoyl) phenyl) - 1- (3-chloropyridin-2-yl) - 1 H-pyrazol-5-carboxamide (Compound 1) (2) 3-Bromo-N- (4-chloro-2- (1-cyclopropylethylcarbamoyl) - 6-methylphenyl) -1- (3-chloropyridin-2-yl ) -1 H-pyrazol-5-carboxamide (Compound 2) (3) 3-Bromo-N- (2-bromo-4-chloro-6- (cyclopropylmethylcarbamoyl) phenyl) - 1- (3-chloropyridin-2-yl ) -1 H-pyrazol-5-carboxamide (Compound 3) (4) 3-Bromo-N- (4-chloro-2-methyl-6- (methylcarbamoyl) phenyl) - 1- (3-chloropyridin-2-yl ) -1 H-pyrazol-5-carboxamide (Compound 4) (5) 3-Bromo-1- (3-chloropyridin-2-yl) - N- (4-cyano-2-methyl-6- (methylcarbamoyl) phenyl ) - 1 H-pyrazol-5-carboxamide (Compound 5) The content of the anthranilamide compound or its salt in the composition is from 1 to 90% by weight, preferably from 5 to 80% by weight. The anthranilamide compound or its salt has an average particle size of 0.01 to 100 μm, preferably 0.1 to 100 μm, and its crystalline form is amorphous.

The crystal form of the compound is preferably complete amorphous, however, it may partially contain crystals. "Amorphous (a)" means a solid state that has no regular alignment of atoms that make up a substance, and is a solid state that shows a halo diffraction pattern when measured by a powder X-ray diffraction apparatus. Amorphous has the same meaning as non-crystalline.

The amorphous substance can be prepared by drying treatment, mechanochemical treatment or solid dispersion treatment. As the drying, spray drying or lyophilization treatment can be mentioned. In addition, the amorphous substance can also be obtained by heating and melting an original substance, followed by cooling. As the mechanochemical treatment, spraying by means of a machine, such as a grinding machine, or mixed spraying with a polymer, such as cellulose, can be mentioned. An a-morphic substance can also be obtained by dissolving an original substance together with a saccharide or a polymer in a solvent, followed by distillation of the solvent (treatment by dispersion of solid).

In addition, in addition to the anthranilamide compound as an active ingredient, the composition of the present invention may contain other pesticides. Such other pesticides can, for example, be an insecticide, a miticide, a nematicide, a soil pesticide or a fungicide.

As the surfactant used in the present invention, one or more surfactants selected from the group consisting of a nonionic surfactant and an anionic surfactant can be used.

Like the non-ionic surfactant used in the present invention, the following surfactants can be mentioned.

Polyoxyalkylene surfactant: a polyoxyalkylene alkyl ether, a C8-18 alkyl polyoxyethylene ether, a C8-alkyl alkyl polyoxyethylene ether, a C8-18 alkyl phenyl polyoxyethylene ether, a (mono, di or tri) phenyl phenyl ether of polyoxyethylene, one (mono, di or tri) benzyl phenyl ether of polyoxyethylene, one (mono, di or tri) benzyl phenyl ether of polyoxypropylene, one (mono, di or tri) styrylphenyl ether of polyoxyethylene, one (mono, di or tri) styrylphenyl polyoxyprolylene ether, a polymer of a (mono, di or tri) polyoxyethylene ether, a polyoxyethylene polyoxypropylene block polymer, a polyoxyethylene polyoxyethylene Cs-w block polymer ether, an ether of the polyoxyethylene block polymer of c8-i2 alkyl phenylpoloxyethylene polyoxypropylene, a bis-phenyl ether of polyoxyethylene, an ester of polyoxyethylene resin acid, an ester of polyoxyethylene C8-aliphatic acid, an ester of polyoxyethylene sorbitan C8-18 aliphatic acid , an oxide adduct of ethylene ester of aliphatic glycolic acid, an adduct of ethylene oxide castor oil, an adduct of ethylene oxide cured castor oil or an adduct of ethylene oxide amide of C8-18 aliphatic acid, for example, to be mentioned.

Polyhydric alcohol surfactant: an ester of aliphatic glycerol acid, an ester of aliphatic acid of pentaerythritol, an ester of aliphatic acid of Ce-18 sorbitan, an ester of aliphatic acid of sucrose, an alkyl ether of polyhydric alcohol, an aliphatic acid alkanolamide, an alkyl glycoside or an alkyl polyglycoside can, for example, be mentioned.

Among the nonionic surfactants above, C8.18 alkyl polyoxyethylene ether, C8-alkyl alkyl aryl polyoxyethylene, C8.18 alkyl phenyl polyoxyethylene ether and C8.18 aliphatic polyoxyethylene acid ester are preferred.

Like the anionic surfactant, the following surfactants can be mentioned.

Carboxylic acid surfactant: a polyacrylic acid, a polymethacrylic acid, a polymalleic acid, a polymalleic anhydride, an olefin copolymer (for example, isobutylene or diisobutylene) with maleic acid or maleic acid anhydride; a copolymer of acrylic acid with itaconic acid; a copolymer of methacrylic acid with itaconic acid; a styrene copolymer with maleic acid or maleic acid anhydride; a copolymer of acrylic acid with methacrylic acid; a copolymer of acrylic acid with methyl acrylate; a copolymer of acrylic acid with a vinyl acetate; a copolymer of acrylic acid with maleic acid or maleic acid anhydride; an N-methyl C1-18 aliphatic acid sarcocinate, a carboxylic acid such as a resin acid or a C1-28 aliphatic acid; or a salt of such a carboxylic acid can, for example, be mentioned.

Sulfuric acid ester surfactant: a C1-18 alkyl sulfuric acid ester, a C02.18 polyoxyethylene sulfuric acid ester, a polyoxyethylene alkyl aryl ether sulfuric acid ester, an ester of polyoxyethylene aryl ether sulfuric acid , an ester of polyoxyethylene-Cβ-12 alkyl phenyl ether sulfuric acid, an ester of polyoxyethylene C & .12 alkyl phenyl ether sulfuric acid, an ester of polyoxyethylene phenyl phenyl ether sulfuric acid, an ester of acid sulfuric acid of polyoxyethylene benzylphenyl ether, an ester of sulfuric acid of polyoxyethylene stylphenyl ether, an ester of sulfuric acid of the polyoxyethylene polystyrene ether polymer, an ester of sulfuric acid of the polyoxyethylene polyoxyethylene block polymer, an sulfated oil ester, an aliphatic acid ester sulfated, a sulfuric acid ester such as sulfated aliphatic acid or sulfated olefin or a salt of such a sulfuric acid ester can, for example, be mentioned .

Sulfonic acid surfactant: a C12-22 alkyl sulfonic acid, a Ce-12 alkyl aryl sulfonic acid, a C8-12 alkylbenzene sulfonic acid, a formaldehyde condensate of a C8_12 alkylbenzene sulfonic acid, a condensate of cresol sulfonic acid formaldehyde, a Ci4.i6 a-olefin sulfonic acid, a C8-12 alkyl sulfosuccinic acid, a lignin sulfonic acid, a C8.12 alkyl phenyl ether sulfonic acid, a polyoxyethylene aryl sulfonic acid, an ester medium of sulfosuccinic acid polyoxyethylene C12-18 alkyl ether, a naphthalene sulfonic acid, a C1-6 alkyl naphthalene sulfonic acid, a formaldehyde condensate of naphthalene sulfonic acid, a formaldehyde condensate of a C1-6 alkyl naphthalene sulfonic acid, a formaldehyde condensate of sulfonic acid from creosote oil, a disulfonic acid C8.i2 alkyl diphenyl ether, sulfonic acid such as a copolymer of methacrylic acid with a polystyrene sulfonic acid and styrene acid su lphonic, or a salt of such sulfonic acid.

Phosphoric acid ester surfactant: an ester of C8.12 alkyl phosphoric acid, an ester of C12-18 polyoxyethylene phosphoric acid, an ester of C8.12 polyoxyethylene phosphoric acid, an alkyl phenyl ether, an phosphoric acid ester of polyoxyethylene polymer C8-12 alkyl phenyl ether, an ester of the polyoxyethylene phenyl phenyl ether phosphoric acid, an ester of the polyoxyethylene benzyl phenyl ether phosphoric acid, an ester of the polyoxyethylene styrene phenyl ether phosphoric acid, an ester of the polyoxyethylene polymer phosphoric acid ether, a phosphoric acid ester of the polyoxyethylene polyoxypropylene block polymer, a phosphatidylcholine, a phosphatidylethanolimine or a phosphoric acid condensate (such as tripolyphosphoric acid) or a salt of such a phosphoric acid ester can, for example, be mentioned.

The salt of the anionic surfactant can, for example, be an alkali metal (such as lithium, sodium or potassium), an alkaline earth metal (such as calcium or magnesium), ammonium or each amine (such as alkylamine, cycloalkylamine or alkanolamine) .

Among the anionic surfactants above, the ester salt of polyoxyethylene alkyl aryl ether sulfuric acid, the ester salt of polyoxyethylene aryl ether sulfuric acid, the salt of C12-22 alkyl sulfonate, the salt of C8.12 alkylbenzene sulfonate are preferred , the C8-12 alkyl sulfosuccinate salt, the lignin sulfonate salt, the polyoxyethylene aryl sulfonate salt and the naphthalene sulfonate salt formalin condensate.

The surfactant is preferably at least one selected from the group consisting of a C 8-18 alkyl polyoxyethylene ether, a C 8. ■ polyoxyethylene alkyl aryl ether, a polyoxyethylene C8.18 alkyl phenyl ether, a polyoxyethylene C8.i8 aliphatic ester, a polyoxyethylene sulfuric acid ester salt, alkyl aryl ether, an ester salt of sulfuric acid polyoxyethylene aryl ether, a salt of C12-22 alkyl sulfonate, a salt of C8.12 alkyl benzene sulfonate, a salt of C8.12 alkyl sulfosuccinate, a lignin sulfonate salt, a polyoxyethylene aryl sulfonate and a formalin condensate of naphthalenesulfonate salt.

The content of the surfactant in the composition is 0.5 to 40% by weight, preferably 1 to 20% by weight.

The vehicle that can be used in the present invention can, for example, be a mineral vehicle, a vegetable vehicle or a polymeric vehicle.

The mineral carrier can, for example, be a kaolin, such as kaolinite, dickite, nacrite or halosite; a streamer such as chrysolite, Lizardo, antigorite or amesite; a montmorillonite such as sodium montmorillonite, calcium montmorillonite or magnesium montmorillonite; a smectite such as saponite, hectorite, sauconite or beidelite; a mica such as pyrophyllite, talc, agalmatolite, muscovite, fengite, sericite or illite; a silica such as cristobalite or quartz; a hydromagnesium silicate such as bentonite, atapulgite or sepiolite; a calcium carbonate such as dolomite or fine powder of calcium carbonate; a sulfuric acid mineral such as gypsum or calcium sulfate; zeolite; boiling stone; volcanic tuffs; vermiculite; laponite; pumice stone; diatomaceous earth; acid clay; activated clay; clay; a synthetic vehicle such as white carbon or titanium dioxide.

The vegetable carrier can, for example, be cellulose, bark, flour, wood flour, starch, rice bran, wheat bran or soy powder.

The polymer carrier can, for example, be methyl cellulose, gum arabic, hydroxypropyl cellulose, hydroxypropyl methyl cellulose, a dextran, sodium alginate, sodium carboxymethyl cellulose, propylene glycol alginic acid ester, polyvinyl pyrrolidone, polyvinyl alcohol, carboxyvinyl polymer, sodium gauze or dextrin. Like other vehicles, urea, lactose, ammonium sulfate, sucrose, sodium chloride, sodium sulfate, sodium carbonate, potassium carbonate, potassium pyrophosphate, sodium tripolyphosphate, maleic acid, fumaric acid, citric acid and malic acid can , for example, be mentioned.

Among the vehicles above, the mineral vehicle is preferred, and the mineral vehicle is preferably at least one selected from the group consisting of kaolin, talc, calcium carbonate, diatomaceous earth, clay and white carbon.

The content of the carrier based on the wetting powder of the present invention is usually 3 to 95% by weight, preferably 10 to 90% by weight.

The formulation of the composition of the present invention can, for example, be a powder, non-moving dust, granules, microgranules, microcapsule formulation, a wetting powder or water-dispersible granules. The formulation is preferably the wettable powder or water-dispersible granules.

The above composition can be prepared by combining one or more components selected from the group consisting of disintegrants, stabilizers, pH control agents, dyes and odor masking agents, in addition to the amorphous anthranilamide compound or its salt, the surfactant and the vehicle.

Now, methods for producing preferred formulations of the composition of the present invention will be described.

(1) Wetting Powder

The wetting powder of the present invention is a powder composition comprising an amorphous anthranilamide compound or its salt, a surfactant and a carrier and usually can be prepared by mixing the above components through a mixer, such as a V-shaped mixer. humectable powder so prepared usually has an average particle size of at most 50 μm.

(2) Water Dispersible Granules

The water-dispersible granules of the present invention are a solid granular composition comprising an amorphous anthranilamide compound or its salt, a surfactant and a vehicle.

Such water-dispersible granules can be prepared using a granulation method that is commonly used to prepare formulations of agricultural chemicals. The granulation method can, for example, be an extrusion granulation method, an impregnation granulation method, a compression granulation method, a stirring granulation method, a fluidized granulation method, a granulation method by rotation or a spray granulation method.

An example of the method for preparing water-dispersible granules using the extrusion granulation method will be described below.

An amorphous anthranilamide compound or its salt, a surfactant and a vehicle are mixed, and then usually 0.1 to 100% by weight of water is added dropwise or sprayed to the mixture, followed by kneading to prepare the kneaded mixture. Then, the kneaded mixture is granulated by a granulation machine, dried, sized and sieved to obtain water-dispersible granules.

The granulation machine used in the granulation can, for example, be a basket-type extrusion granulation machine or a dome-type extrusion granulation machine, and the drying machine can, for example, be a fluidized drying machine or a bed-type drying machine. The calibration machine can, for example, be a Marumerizer, a pin mill or a mincing machine, and the screening machine can, for example, be Gyro Shifters or an electromagnetic vibration type screening machine. The water dispersible granules thus produced have an average particle size of usually about 0.3 to 10 mm, preferably about 0.3 to 5 mm.

The composition of the present invention is preferably the composition below. (1) A composition comprising an amorphous anthranilamide compound or its salt, a nonionic surfactant and / or an anionic surfactant and a mineral carrier. (2) A composition comprising an amorphous anthranilamide compound or its salt, at least one surfactant selected from the group consisting of a C8.18 alkyl polyoxyethylene ether, a C8.- | 8 alkyl aryl polyoxyethylene ether, a C8.i8 alkyl phenyl polyoxyethylene ether, an ester of C8.18 aliphatic polyoxyethylene acid, an ester salt of polyoxyethylene sulfuric acid alkyl aryl ether, a ester salt of polyoxyethylene aryl ether sulfuric acid, a salt of C12- 22 alkyl sulfonate, a C8.12 alkyl benzene sulfonate salt, a C8.12 alkyl sulfosuccinate salt, a ligin sulfonate salt, a polyoxyethylene aryl sulfonate salt and a naphthalenesulfonate salt formalin condensate; and at least one vehicle selected from the group consisting of kaolin, talc, calcium carbonate, diatomaceous earth, clay and white carbon. (3) The composition according to (1) or (2) above, comprising from 1 to 90% by weight of the amorphous anthranilamide compound or its salt, from 0.5 to 40% by weight of the surfactant and 3 95% by weight of the vehicle. (4) The composition according to (3) above, comprising the amorphous anthranilamide compound or its salt, the C8-18 polyoxyethylene alkyl ether, the C8-18 alkyl phenyl polyoxyethylene ether, the ester salt of polyoxyethylene alkyl aryl ether sulfuric acid, the alkyl benzene sulfonate salt, clay and white carbon.

The composition of the present invention is usually diluted with water and used for spray treatments. Although the dilution ratio varies depending on the content of the active ingredient in the composition, places to be applied, etc., the composition is usually diluted from 5 to 100,000 times, preferably from 10 to 100,000 times, more preferably from 50 to 10,000 times.

EXAMPLES

Now, the present invention will be described in detail with reference to the Examples and Test Examples, however it should be understood that the present invention is not restricted to them. In addition, the following vehicles and surfactants were used in the Examples. Carplex CS-7: white carbon (produced by Evonik Degussa Japan) Sorpol 5073: polyoxyethylene sulfuric acid ester alkyl aryl ether ■ ammonium salt and polyoxyethylene alkyl ether (produced by Toho Chemical Industry Co., Ltd.) Sorpol 5060: sodium salt of alkylbenzene sulfonic acid (produced by Toho Chemical Industry Co., Ltd.) Noigen EA-33: polyoxyethylene dodecyl phenyl ether (produced by Daichi Kog-yo Seiyaku Co., Ltd.)

EXAMPLE 1

5% by weight of Carplex CS-7 was mixed with the compound (1), and the mixture was sprayed in a mortar using an Ishikawa-type agitator (produced by Ishikawa Kojo: type AGA) for 15 minutes. 2.2 g of the sprayed product obtained (average particle size: 9.2 μm) were mixed with 1.2 g of Sorpol 5073, 0.8 g of Sorpol 560, 0.4 g of Noigen EA-33, 6 g of Carplex CS-7 and 29.4 g of clay, followed by spraying mixed using a centrifugal spraying machine (produced by NIHONSEIKI KAISHA LTD .: Φ screen: 1 mm, 10,000 rpm) to obtain a wetting powder containing 5 % by weight of the compound (1). The pulverized product obtained through mortar spraying had an average particle size of 9.2 μm, and as a result of the measurement of powder X-ray diffraction, the crystal form was amorphous. Figure 1 shows the result of powder X-ray diffraction. The measurement of powder X-ray diffraction was performed using RINT 1200 (Cu-Ka1) (produced by Rigaku Corporation).

EXAMPLE 2

0.53 g of compound (1) was mixed with 0.3 g of Sorpol 5073, 0.2 g of Sorpol 5060, 0.1 g of Noigen EA-33, 1.5 g of Carplex CS-7 and 7, 4 g of clay, and then the mixture was sprayed in a mortar using an Ishikawa type grinding machine for 15 minutes to obtain a wet powder containing 5% by weight of the compound (1). In addition, the crushed product obtained through mortar spraying was subjected to powder X-ray diffraction measurement and, as a result, only peaks derived from clay were observed, and a peak derived from compound (1) was not observed.

COMPARATIVE EXAMPLE 1

The crystal compound (1) was sprayed using a Turbo Opposite Jet Mill (TJ-60, produced by Turbo Kogyo Co., LTD.). Then, 2.1 g of fine particles of the compound obtained (1) (average particle size: 2 μ) were mixed with 1.2 g of Sorpol 5073, 0.8 g of Sorpol 5060, 0.4 g of Noigen EA -33, 6 g of Carplex CS-7 and 29.5 g of clay, and then the mixture was sprayed in a mixed way using a centrifugal spray machine (produced by NIHONSEIKI KAISHA LTD .: diameter of 1 mm screen, 10,000 rpm) to obtain a wettable powder containing 5% of the compound (1).

In addition, the product sprayed by a turbo opposed jet mill (turbo counter jet mill) was subjected to powder X-ray diffraction measurement and, as a result, was crystalline. Figure 2 shows the result of powder X-ray diffraction.

TEST EXAMPLE 1

Efficacy against silver leaf whitefly

(1) Preparation of Sample Solutions

Compositions obtained in Examples 1 and 2 and Comparative Example 1 (active ingredient: 5% by weight) were diluted 4,000 times with water, respectively, to prepare 12.5 ppm of test liquids.

(2) Effectiveness Test

Adults of the silver leaf whitefly were released on cucumber with only one real leaf left and the other leaves cut and left in the pot, and allowed to lay eggs for about 24 hours. After that, the pot was left for 9 days in a constant temperature chamber at 25 ° C with lighting. The number of first instinct nymphs was counted, and then the 12.5 ppm test liquid was sprayed evenly over the leaf by hand spraying. After treatment, the pot was left in a constant temperature chamber at 25 ° C with lighting for 10 days, in which the number of nymphs of mature instar and the number of pupae were counted, and the control value was obtained through the following equation. Table 1 shows the test results. From Table 1, it is evident that the control effect of the formulation of the present invention is superior to that of the Comparative Example. Control value (%) = (1 - ((TaxCb) / (TbxCa))) x100 Ta: the number of nymphs of mature instar + the number of pupae after treatment of the treated section Tb: the number of nymphs of first urge before treatment in the treated section. Ca: the number of mature urge nymphs + the number of pupae after treatment in the untreated section. Cb: the number of first-instinct nymphs before treatment in the untreated section TABLE 1

INDUSTRIAL APPLICABILITY

The agricultural chemical composition containing the anthranilamide compound of the present invention is useful for controlling pests.

The entire description of Japanese Patent Application No. 2008-075284 filed on March 24, 2008, including the specification, claims, drawings and summary, is hereby incorporated by reference in its entirety.

Claims (9)

1. Solid composition for pest control, characterized by the fact that it comprises an amorphous anthranilamide compound representing by formula (I): where: R1is halogen, alkyl or cyano; A is alkyl that can be replaced by C3-4 cycloalkyl, and m is 0-4; or its salt as a pesticidal active ingredient, a surfactant and a vehicle, the composition comprising from 1 to 90% by weight of amorphous anthranilamide compound or its salt, from 0.5 to 40% by weight of surfactant and from 3 to 95 % by weight of vehicle. 2. Composition according to claim 1, characterized by the fact that the anthranilamide compound is 3-bromo-N- (2-bromo-4-chloro-6- (1-cyclopropylethylcarbamoyl) phenyl) -1- (3 -chloropyridin-2-yl) -1H-pyrazol-5-carboxamide, 3-bromo-N- (4-chloro-2- (1-cyclopropylethylcarbamoyl) -6-methylphenyl) - 1- (3-chloropyridin-2-yl ) -1H-pyrazol-5-carboxamide, 3-bromo-N- (2-bromo-4-chloro-6- (cyclopropylmethylcarbamoyl) phenyl) -1- (3-chloropyridin-2-yl) -1H-pyrazol-5 - carboxamide, 3-bromo-N- (4-chloro-2-methyl-6- (methylcarbamoyl) phenyl) -1- (3-chloropyridin-2-yl) -1H-pyrazol-5-carboxamide or 3-bromo- 1- (3-chloropyridin-2-yl) - N- (4-cyano-2-methyl-6- (methylcarbamoyl) phenyl) -1H-pyrazol-5-carboxamide. 3. Composition according to claim 1, characterized by the fact that the surfactant is a non-ionic surfactant and / or an anionic surfactant. 4. Composition according to claim 1, characterized by the fact that the surfactant is at least one selected from the group consisting of a C8-18 alkyl polyoxyethylene ether, a C8-18 alkyl aryl polyoxyethylene ether, a C8-18 alkyl phenyl polyoxyethylene ether, an ester of polyoxyethylene C8-18 aliphatic acid, an ester salt of polyoxyethylene alkyl aryl ether, a ester salt of polyoxyethylene aryl ether sulfuric acid, a salt of C12-22 alkyl sulfonate, a C8-12 alkyl benzene sulfonate salt, a C8-12 alkyl sulfosuccinate salt, a lignin sulfonate salt, a polyoxyethylene aryl sulfonate salt and a naphthalenesulfonate salt formalin condensate. 5. Composition, according to claim 1, characterized by the fact that the vehicle is a mineral vehicle. 6. Composition, according to claim 1, characterized by the fact that the vehicle is at least one selected from the group consisting of kaolin, talc, calcium carbonate, diatomaceous earth, clay and white carbon. 7. Composition according to claim 1, characterized by the fact that it contains the amorphous anthranilamide compound or its salt, a nonionic surfactant and / or an anionic surfactant and a mineral vehicle. 8. Composition according to claim 1, characterized by the fact that it contains the amorphous anthranilamide compound or its salt, at least one surfactant selected from the group consisting of a C8-18 alkyl polyoxyethylene ether, a C8- 18 polyoxyethylene alkyl aryl ether, a polyoxyethylene C8-18 alkyl phenyl ether, a polyoxyethylene C8-18 aliphatic ester, a polyoxyethylene alkyl aryl ether sulfuric acid salt, a sulfuric acid ester salt polyoxyethylene aryl ether, a C12-22 alkyl sulfonate salt, a C8-12 alkyl benzene sulfonate salt, a C8-12 alkyl sulfosuccinate salt, a lignin sulfonate salt, a polyoxyethylene aryl sulfonate salt and a condensate of naphthalenesulfonate formalin. 9. Composition according to claim 1, characterized by the fact that it is a wettable powder or granules dispersible in water.

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