BRPI0405915A - catalytic process for the destruction of contaminants in water using hydrogen peroxide and heterogeneous catalyst - Google Patents

catalytic process for the destruction of contaminants in water using hydrogen peroxide and heterogeneous catalyst

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Publication number
BRPI0405915A
BRPI0405915A BRPI0405915-8A BRPI0405915A BRPI0405915A BR PI0405915 A BRPI0405915 A BR PI0405915A BR PI0405915 A BRPI0405915 A BR PI0405915A BR PI0405915 A BRPI0405915 A BR PI0405915A
Authority
BR
Brazil
Prior art keywords
hydrogen peroxide
water
heterogeneous catalyst
contaminants
destruction
Prior art date
Application number
BRPI0405915-8A
Other languages
Portuguese (pt)
Inventor
Regina De Fatima Peral Moreira
Vivian Stumpf Madeira
Humberto Jorge Jose
Tirzha Lins Porto Dantas
Original Assignee
Univ Fed De Santa Catarina Ufsc
Carbonifera Criciuma S A
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Univ Fed De Santa Catarina Ufsc, Carbonifera Criciuma S A filed Critical Univ Fed De Santa Catarina Ufsc
Priority to BRPI0405915-8A priority Critical patent/BRPI0405915B1/en
Publication of BRPI0405915A publication Critical patent/BRPI0405915A/en
Publication of BRPI0405915B1 publication Critical patent/BRPI0405915B1/en

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  • Catalysts (AREA)
  • Treatment Of Water By Oxidation Or Reduction (AREA)

Abstract

"PROCESSO CATALìTICO PARA A DESTRUIçãO DE CONTAMINANTES EM áGUA UTILIZANDO PERóXIDO DE HIDROGêNIO E CATALISADOR HETEROGêNEO". A presente invenção refere-se a um processo de tratamento de águas contendo contaminantes orgânicos que utiliza um catalisador heterogêneo à base de óxidos e hidróxidos de ferro suportados em carvão mineral betuminoso, que catalisa a decomposição do peróxido de hidrógenio, gerando radicais livres que oxidam não seletivamente os contaminantes orgânicos dissolvidos. O catalisador trata-se de um processo que utiliza um sólido que catalisa a decomposição de peróxido de hidrogênio, produzindo radicais hidroxil e hidroperoxil altamente oxidantes e que são os responsáveis pela destruição de compostos orgânicos presentes em águas. O processo proposto consiste no contato da água a ser tratada com o catalisador heterogêneo e pela adição de peroxido de hidrogênio. O catalisador heterogêneo é um compósito à base de óxidos e hidróxidos de ferro suportados em carvão mineral betuminoso, que é ativo para decompor peróxido de hidrogênio e gerar radicais livres oxidantes, que então decompõem compostos orgânicos dissolvidos em águas. O processo pode ser utilizado em reator de feito fixo, ajustando o tempo de residência para valores superiores a 10 minutos; ou em reatores agitados."CATALYTIC PROCESS FOR DESTRUCTION OF CONTAMINANTS IN WATER USING HYDROGEN PEROXIDE AND HYPEROGENIC CATALYST". The present invention relates to a water treatment process containing organic contaminants using a heterogeneous catalyst based on bituminous coal oxides and iron hydroxides, which catalyzes the decomposition of hydrogen peroxide, generating free radicals that oxidize non-oxidising. selectively dissolved organic contaminants. The catalyst is a process that uses a solid that catalyzes the decomposition of hydrogen peroxide, producing highly oxidizing hydroxyl and hydroperoxyl radicals that are responsible for the destruction of organic compounds present in water. The proposed process consists of contacting the water to be treated with the heterogeneous catalyst and the addition of hydrogen peroxide. Heterogeneous catalyst is a composite based on bituminous coal oxides and hydroxides of iron, which is active to decompose hydrogen peroxide and generate oxidizing free radicals, which then decompose organic compounds dissolved in water. The process can be used in a fixed reactor, adjusting the residence time to values greater than 10 minutes; or in stirred reactors.

BRPI0405915-8A 2004-12-21 2004-12-21 CATALYTIC PROCESS FOR DESTRUCTION OF CONTAMINANTS IN WATER USING HYDROGEN PEROXIDE AND HYPEROGENIC CATALYST BRPI0405915B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
BRPI0405915-8A BRPI0405915B1 (en) 2004-12-21 2004-12-21 CATALYTIC PROCESS FOR DESTRUCTION OF CONTAMINANTS IN WATER USING HYDROGEN PEROXIDE AND HYPEROGENIC CATALYST

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
BRPI0405915-8A BRPI0405915B1 (en) 2004-12-21 2004-12-21 CATALYTIC PROCESS FOR DESTRUCTION OF CONTAMINANTS IN WATER USING HYDROGEN PEROXIDE AND HYPEROGENIC CATALYST

Publications (2)

Publication Number Publication Date
BRPI0405915A true BRPI0405915A (en) 2006-10-03
BRPI0405915B1 BRPI0405915B1 (en) 2014-03-11

Family

ID=37038402

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI0405915-8A BRPI0405915B1 (en) 2004-12-21 2004-12-21 CATALYTIC PROCESS FOR DESTRUCTION OF CONTAMINANTS IN WATER USING HYDROGEN PEROXIDE AND HYPEROGENIC CATALYST

Country Status (1)

Country Link
BR (1) BRPI0405915B1 (en)

Also Published As

Publication number Publication date
BRPI0405915B1 (en) 2014-03-11

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Legal Events

Date Code Title Description
B06A Notification to applicant to reply to the report for non-patentability or inadequacy of the application according art. 36 industrial patent law
B09A Decision: intention to grant
B16A Patent or certificate of addition of invention granted

Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 21/12/2004, OBSERVADAS AS CONDICOES LEGAIS.

B21F Lapse acc. art. 78, item iv - on non-payment of the annual fees in time

Free format text: REFERENTE A 10A ANUIDADE. PAGAR RESTAURACAO.

B24J Lapse because of non-payment of annual fees (definitively: art 78 iv lpi, resolution 113/2013 art. 12)

Free format text: EM VIRTUDE DA EXTINCAO PUBLICADA NA RPI 2343 DE 01-12-2015 E CONSIDERANDO AUSENCIA DE MANIFESTACAO DENTRO DOS PRAZOS LEGAIS, INFORMO QUE CABE SER MANTIDA A EXTINCAO DA PATENTE E SEUS CERTIFICADOS, CONFORME O DISPOSTO NO ARTIGO 12, DA RESOLUCAO 113/2013.