BR9914335B1 - Hair care makeup that produces volume. - Google Patents

Description

"VOLUME PRODUCING HAIR CARE COMPOSITION"

Field of the Invention

This invention relates to an improved formulation for treating hair. In particular, the compositions of this invention incorporate a selected type of siloxysilicate polymer (known as desilicone MQ resins) in hair care formulations, which may be used as a bulking agent in hair. This case relates to a co-pending case, filed the same day as this case as power of attorney document IR 6232M and owned by the same company as this case (U.S. Serial Number not yet assigned).

Background of the Invention

Research on improved hair care products is a continuous research. As hair types vary, so do the types of products that are useful in working with different hair types. One such product category, desired by the public to create a fuller look for their hair, is known as the hair volume production agent. Previous attempts to add volume to the hair involved using fixer-based sprays, gels or mousses to enhance styling and create volume. These products operate by combining the hair together in a fixed, volumically enhanced architecture. Such products often have the disadvantage of causing the hair to become stiff or excessively sticky, and generally do not allow the user to reshape the hair without removing and reapplying it. The adhesive character of these hair volume producing agents can create difficulties in remodeling. Additionally, such fixative base products may initially have a volume producing effect, but continued use of these products over time may result in hair accumulation resulting in loss of hair volume. The problem is amplified for people with thin hair, because these hair type is especially sensitive getting heavy due to deposits of hair care products.

The consumer wants hair-volume production products, other than permanent curling products, or hair-based hairpins or styling gels. The consumer wants an impressive volume production in the hair, which can add volume, or otherwise flatten or thin the hair, while retaining some ability to reshape the hair. In this way, volumizing agents, as used herein, do not create a permanent hair architecture, but allow hair to be reshaped and new volume provided.

An example of a retention aid for styling hair is PCT Patent Application Publication Number WO 95/06057 by Torgerson et al. This reference describes silicone grafted thermoplastic elastomeric copolymers and hair care compositions containing the same. These copolymers are useful in mousses and hair spray compositions. The copolymers described in this reference are dispersible or water or alcohol soluble thermoplastic elastomeric copolymers having one backbone and two or more hydrophilic polymer side chains and one or more polysiloxane side chains, wherein the copolymer comprises:

(a) 20-89.9% copolymerizable monomer units with

(b) and (c);

(b) 10-60% hydrophilic macromonomer units having a polymer moiety and a copolymerizable moiety with (a) and (c);

(c) 0.1 - 20% polysiloxane macromonomer units having a polymer moiety and a copolymerizable moiety with (a) and (b).

U.S. Patent 4,902. 499 from Bolich et al. teaches hair care compositions that have both improved styling retention and hair conditioning. The compositions comprise from 0.01-10% of a rigid silicone polymer and a volatile carrier. Suitable polymers include charged reinforced polydimethyl siloxane gums, crosslinked siloxanes, organic substituted siloxane gums, resin reinforced siloxanes, and crosslinked siloxane polymers.

U.S. Patent 5,817,302 describes low viscosity MQ silicone resins as a composition of matter and personal care products made with such MQ resins.

WO 95/31173 teaches the use of selected solid MQ resins (trimethylsiloxysilicates) in shampoos.

WO 94/08557 teaches the use of selected solid MQ resins (polytrimethylsiloxysilicates) in shampoos.

European Patent Application EP 0 0240 350 Bl to Synder etal. claims the use of compositions having capillary conditioning and styling retention properties, wherein the composition comprises (a) a rigid silicone polymer having a complex viscosity of at least 1 χ 10 Pascals seconds (1 χ 10 poise) selected from the which group consists of organic substituted siloxane gums, desilicone elastomers, charged reinforced polydimethyl siloxane gums, crosslinked siloxane resin-reinforced siloxanes; and (b) a volatile vehicle selected from water, straight or branched C10-C16 volatile hydrocarbons, and volatile silicones having a boiling point in the range 99-260 ° C, where if water is the only vehicle, 0 .50 - 50% by weight of a surfactant is also present and in which the use of a silicone polymer in the manufacture of an aqueous aerosol styling mousse composition in which the silicone polymer is in the form of a silicone is excluded. emulsion, which comprises an anionically stabilized anhydrous polyorganosiloxane.

Other attempts included the creation of hair thickeners. PCT Patent Application Publication No. WO 96/38120 to Grossmand describes a hair thickener and conditioner gelatin composition for topical application to hair. A formulation comprising an aqueous gelatin solution, a water soluble film-forming polymer, and an acid neutralizing agent to maintain the pH of the composition in the range of 6.0 - 9.5 is exposed. Suitable types of water-soluble film-forming polymers for use with this composition include polyvinylpyrrolidone (PVP), polyvinyl acetate, partially hydrolyzed polyvinyl acetate, vinyl acetate and PVP copolymers, polyvinyl alcohol, acrylate acrylate copolymers, PVP-acrylate-copolymers and ossimilars, wherein the polymers have an average molecular weight number in the range of 5,000 - 10,000 daltons.

Siloxane resins consisting of detriorganosiloxane units and silicon dioxide units are known commercially available materials and are employed in the formulation of various products, including adhesives, foaming agents, as well as personal care products; however, it is not believed that these compounds have been used commercially for hair care products of the type described herein. Such resins are sometimes referred to as "MQ resins" due to the presence of monovalent siloxane (M) units and quadrivalent or tetravalent silicon dioxide units (Q).

In view of the reactivity of the silyl hydride group, it is sometimes desired to include such groups in MQ type resins. Desiloxane resins composed of silicon dioxide units and units of the general formula HR1R2SiO½, where each of R1 and R2 may be the same or different and each is selected from hydrogen, a monovalent hydrocarbon and monovalent halo are often used due to high reactivity of silyl hydride functionality on them. These resins were used for organopolysiloxane elastomers. As precursors for other synthetic silicones, it is often desirable that these resins contain a limited number of silyl groups. US 3,772,247 describes organopolysiloxane resins consisting of R3R4R5SiO½ units, SiO2 units and HR3SiO and / orHSiO3 / 2 units, wherein each of R3, R4 and R5 are independently selected from the group consisting of alkyl groups. , aryl, alkaryl, alkenyl, cycloalkyl and cycloalkenyl. Although such resins have silyl hydride groups, they have a significant and measurable level of divalent or trivalent organosiloxyl groups.

U.S. Patent No. 4,774,310 to Rutler describes QM resins, which consist of R3R4R5SiOiz2 units and SiO2 units, wherein R35 R4e R5 are independently selected from the group consisting of alkyl, aryl, alcaryl, alkenyl, cycloalkyl and cycloalkenyl groups. The MQ resins of this reference are further reacted with disiloxanos using acid catalysis to produce MQ-type siloxane resins, where M: Q ratio is in the range of 0.4: 1 to 1: 1, and wherein the fraction of units interrupted by hydride of the general formula HaRn3.aSiOi / 2, wherein Rn is selected from the same group as defined for R3, R4 and R5 is in the range 0.1 -30 percent of the total number of M units present.

British Patent 2,297,757 to Berthiaume et al. Low viscosity organofunctionalities of the "MQ" type are mentioned as being useful as personal care products and cosmetics. These functionalized MQ silicone resins have the general formula:

<formula> formula see original document page 7 </formula>

wherein both R1 and R2 may be either a phenyl group or a C1-C2 alkyl group and both M1 and M2 are independently selected from the group consisting of phenyl, phenethyl, polyether, hydrogen and a C1-C23 alkyl group (which may also be include halogen substituted hydrocarbon radicals) and where z, y and ζ satisfy the following relationship: 0.5 <(x + y) / z <4.0 and one of χ and y can be zero.

Villamarin U.S. Patent 5,585,094 describes a method of semi-permanently conditioning hair in which a low viscosity oil-in-water emulsion of a mixture of two polysiloxane polymers is applied (one being a hydroxy terminated polysiloxane dimethyl and the other being a methyl hydrogen polysiloxane) in an acidic pH and in an unreacted state. Heat is preferably applied to crosslink the polymers.

U.S. Patent 4,963,348 to Bolich et al. Describes styling agents and compositions comprising adhesive copolymers with a volatile diluent to provide hair styling and retention.

There remains a need, however, to provide suitable compositions for use as hair volume producing agents that do not leave hair stiff or excessively sticky.

Accordingly, it is an object of the present invention to provide volume production compositions, which are not based on adhesion of hair fibers together to achieve volume increases. In particular, it is an important object of this invention to provide a hair volume producing agent which is capable of providing hair volume without substantial adhesion between the hair fibers. It is a further object of the invention to provide a hair volume producing agent which allows hair to be manipulated and new volume to be provided between washes. It is also an object of the present invention to provide compositions suitable for use as hair volume agents which are useful for increasing hair volume by a substantial amount. It is a further object of the present invention to provide compositions suitable for use as hair volume agents that use MQ resins and allow the hair to resist compression of the hair network. These and other objects of the invention will become apparent from the following description.

SUMMARY OF THE INVENTION The compositions of this invention are hair thinners, comprising:

(a) 0.01-15 weight percent (based on total weight of composition) of a selected liquid MQ resin having an M: Q ratio of 0.5 -1.5 and an average viscosity in the range 150 χ 10 3 -Ix 10 6 centipoises ("cps" or "cP") (for example from 1 -10% by weight, more particularly from 0.1 to 7.0% and more particularly from 0.1 -4% ); and

(b) from 85 to 99.99 weight percent (based on the total weight of the composition) of a hair care vehicle (also called a vehicle).

The compositions of this invention provide increased volume hair without significant stiffness, or excessive adhesion, or accumulation of product on the hair, which would contribute to the volume loss. The compositions of this invention may be produced in the form of a shampoo, conditioner, shampoo-conditioner combination (so called 2 in 1 products), sprays, liquid rinse creams, gels or mousses.

Detailed Description of the Invention

The compositions of this invention are produced with one or more liquid MQ resins having an M: Q ratio of 0.5 - 1.5 (also referred to as the χ + y / z ratio (for Formula IA) or x '/ z' ratio). if the segment χ and segment y are the same as in Formula IB) and a viscosity in the range of 1.0 χ 10 -3 - 1 χ 10 6 centipoises ("cps" or "cP") (or 1.0-1 1 χ 10 3 Pa -second); particularly 1.5 χ 10 -3 - 1 χ 106, more particularly from 1,000 - 100,000, even more particularly from 1000 - 50,000 cps, and even more particularly from 1,000 - 20,000 cps, such as from 2,000 - 14,000 cps, with one particular example being from 3,000 - 12,000 cps.

Although it is possible to use higher viscosity MQ resins (such as 50,000 - 100,000 cps) it is more convenient to use lower viscosities.

MQ resins suitable for use with this invention may be represented by formula IA:

<formula> formula see original document page 10 </formula>

wherein R4, R5, R6 and R7 are each independently selected from the group consisting of phenyl and C1-C12 branched and unbranched hydrocarbons, particularly CΙ-Ο 12 branched and unbranched alkyl, more particularly C1-alkyl. - C5 branched and unbranched C1-C5e especially methyl;

M1 and M2 are each independently from the group consisting of:

(a) hydrogen,

(b) phenyl,

(c) phenethyl,

(d) a polyether of Formula II:

<formula> formula see original document page 10 </formula>

where η is a number from 1-20 and the chain - (CH2) - may optionally contain 1 or 2 unsaturation; u and ν are integers, each independently selected from 0-20 as long as u + v> l; R10 is selected from C1-C20 alkyl; and R 11 is selected from the group consisting of H, -CH 3 and -C (O) CH 3; and

(e) branched and unbranched C1-C24 hydrocarbons, optionally substituted by a halogen substituted C1-C3 hydrocarbon radical, with a particular value for R2 being C1-C24 alkyl, especially methyl; and

wherein (x + y) / z is a number in the range 0.5 and 1.5, and is preferably 1; and values for R45 R5, R6, R75 χ, y, ζ, M1 and M2 are selected such that the MQ resin is a liquid having a viscosity of 1.0 χ 10 ^ 3 -1 χ 10 ^ 6, such that 1, 5 χ 10 ^ 3 - 1 χ 10 ^ 6 centipoises.

A particular type of MQ resin of formula IA, when χ and y are the same, may be represented by formula IB:

<formula> formula see original document page 11 </formula>

Formula IB

wherein R1 and R3 are each independently selected from the same group as defined for R4, R5, R6 and R7 of Formula IA; R2 is selected from the same group as described for M1 and M2; and x '/ z' is between 0.5 and 1.5.

A particular MQ useful in the invention is a liquid detrimethylsiloxysilicate polymer, especially with an M: Q ratio of 1 (e.g., a resin obtained from General Electric Company, Waterford, New York, as "MQ-A").

MQ resins useful in this invention should be distinguished from other types of MQ resins which do not have the desirable properties of the invention. As described in more detail below, it has been found that low viscosity liquid MQ resins with an M: Q ratio of 2 do not provide significant volume and do not exhibit significant adhesive character in the hair; Solid MQ resins with an M: Q ratio of 2 do not provide significant volume and also do not exhibit a significant adhesive character on the hair; and solid MQ resins with an M: Q ratio of 0.7 - 1.0 provide volume but do not exhibit a significant adhesive character on the hair.

The vehicle, in which the MQ resin is present, is a member selected from the group consisting of sprays, rinse creams, shampoos, conditioners, and "2 in 1" conditioner shampoos. In particular, these products may be formed with a volatile vehicle (i.e., a vehicle having a measurable vapor pressure) such as silicones, volatile C2 -C3 alcohols, isopropyl myristate and water, and mixtures thereof, provided that if water is not only vehicle, at least one surfactant is also used. A preferred class of vehicles are volatile silicones having a boiling point of between 99 ° C and 260 ° C. Ossilicones may be either linear or cyclic polydimethyl siloxanes, wherein the cyclic polydimethyl siloxanes contain from about 3 to about 7 desilyl atoms, more preferably 5. These volatile silicones may be used alone or in combination with other volatile carriers. A particular siliconvolatile is cyclomethicone (especially a D5 cyclomethicone).

If water is the only vehicle, a surfactant (from the group described below) in an amount of 0.1 - 50% by weight of the total composition is also present.

They can be used as shampoo vehicles to which the selected QM resin is added. Suitable shampoos include as many conditioning as regular shampoos. Particular shampoos include those formulated with a surfactant, a stabilizer and the selected liquid MQ resin as described above. Other optional ingredients such as thickeners, preservatives, fragrances, opacifiers, foam modifiers, etc. may be included in such formulations as cited below.

Suitable surfactants include:

(a) anionics as described in U.S. Patent 4,902,499 to Bolich et al. and U.S. Patent 4,963,348 to Bolich et al, both of which are incorporated herein by reference, such that

(i) alkyl and alkyl ether sulfates of formula R20OSO3M and R20O (C2H4O) wSO3M, where R20 is alkyl or alkenyl of 10-20 carbon atoms, w is a number from 1 to 10, and M is a water-soluble cation, such cheammonium, sodium, potassium and triethanolamine (ii) fatty acid reaction products (for example, those derived from coconut oil) esterified with sodium hydroxide-isethoic acid and neutralized;

(iii) succinamates (for example, disodium N-octadecylsulfosuccinates, tetrasodium N- (1,2-dicarboxyethyl) -N-octadecylsulfosuccinate, sodium sulfosuccinic acid diamyl ester, sodium sulfosuccinic acid dixysic ester and dioctyl sulfosuccinate ester;

(iv) olefin sulfonates having from 12 to 24 carbon atoms;

(b) amphoteric as described in U.S. Patent 4,902,499 to Bolich et al, and incorporated herein by reference, such that

(i) derivatives of aliphatic secondary and tertiary amines, wherein the aliphatic radical may be straight or branched, and wherein one of the substituents contains from 8 to 18 carbon atoms and one contains an anionic water solubilization group (eg, carboxy , sulfonate, sulfate, phosphate or phosphonate) with examples of such compounds including sodium 3-dodecyl aminopropionate, sodium 3-dodecylaminopropane sulfonate, N-alkyltaurines, higher N-alkyl aspartic acids (for example, products sold under the brand name "MIRANOL"). "as described in US Patent No. 5,028,378).

(ii) zwitterionic surfactants (broadly exemplified as derivatives of aliphatic quaternary ammonium, phosphonium and sulfonium compounds, wherein aliphatic radicals may be straight chain or amidified, and wherein one of the aliphatic substituents contains from 8 to 18 carbon atoms and one contains a group solubilization in anionic water (for example carboxy, sulfonate, sulfate, phosphate or phosphonate);

(iii) betaines, for example higher alkyl betaines, such as cocodymethyl carboxymethyl betaine, lauryl dimethyl carboxymethyl betaine, lauryl dimethyl alpha-carboxyethyl betaine, cetyl dimethyl carboxymethyl betaine, lauryl bis (2-hydroxyethyl) carboxymethyl betaine, stearyl bis (2-hydroxy) -propyl) carboxymethyl betaine, oleyl dimethyl-gamma-carboxypropyl betaine, lauryl bis (2-hydroxypropyl) alpha-carboxyethyl betaine, and cocamidopropyl betaine.

(c) nonionic surfactants, including those selected from the group described in U.S. Patent 4,741,855 to Grote et al., and incorporated herein by reference: these are:

(i) polyethylene oxide condensates of aquylphenols, wherein the alkyl phenol alkyl moiety has 6-12 carbons and may be chained or branched and the ethylene oxide moiety is present in an amount of 10-60 moles of ethylene oxide. per mol of alkyl phenol;

(ii) ethylene oxide condensation products with a product resulting from the reaction of propylene diamine-modified propylene oxide and ethylene according to the desired hydrophobic / hydrophilic balance (e.g., compounds containing 40-80% polyoxyethylene by weight, and tb had a molecular weight of 5,000-11,000 resulting from the reaction of ethylene oxide groups with a hydrophobic base consisting of the product of ethylene diamine and excess propylene oxide, where the base has a molecular weight of 2,500 -3,000);

(iii) C8-C18 aliphatic or branched aliphatic alcohols condensation products with ethylene oxide (for example, ethylene oxide / coconut alcohol condensate with 10-30 moles of ethyl alcohol oxide pormol of coconut alcohol, wherein the coconut fraction has 10-14 carbon atoms)

(iv) long chain tertiary amine oxides of formula (R) (R31) (R32) -N (O,

wherein R30 is an alkyl, alkenyl or monohydroxy C8-18 alkyls; which has 0-10 portions of ethylene and 0-1 portions of glyceryl; R 31 and R 32 may be the same or different and are each independently selected from the group consisting of C 1-3 alkyl with 0-1 hydroxy group. The arrow on the frame is a conventional representation of a semipolar bond. Examples of long chain amino acid oxides include cocamidopropylamine oxide and delauramine oxide.

(v) long chain tertiary phosphine oxides of Formula R 20 R 21 R 22 P (O, wherein R 20 contains a C 8-18 alkyl, alkenyl or monohydroxyalkyl radical; 0-10 portions of ethylene oxide and 0-1 portion of glyceryl; and R91 and R99 are, each independently C1-3 alkyl or monohydroxyalkyl The arrow in the formula is a conventional representation of a semipolar bond.

(vi) long chain dialkyl sulfoxides containing a 1-3 carbon short chain alkylalkyl or hydroxy alkyl (particularly methyl) and a long hydrophobic chain having a C8-20 alkyl, alkenyl, hydroxy alkyl or keto alkyl group of 0- 10 portions of ethylene oxide and 0-1 portion of glyceryl.

Stabilizers include one or more members selected from the group consisting of the following members, which are selected in detail so that the final amount of stabilizer added is in the range of 1.1-7.0%;

(a) long chain fatty alcohols of more than 14 carbons, for example C20-40, and mixtures of such long chain fatty alcohols (for example, a C> 14 alcohol and an ethane homopolymerPETROLITE C-7138 from Petrolite Corporation, St Louis, Missouri).

(b) steareth-20 acrylate / methacrylate copolymer (e.g., ACULYN® 22, from Rohm & Haas, Philadelphia, Pennsylvania); acrylate ecopolymer (eg acrylate copolymer (ACULYN®33); ACUSOL®-445, -810, and -830; ACRYSOL® ASE 75 from Rohm &Haas); crosslinked C 10-30 alkyl acrylate / acrylate epolymer (PEMULEN® polymer emulsifiers from BF Goodrich Company, Brecksville, Ohio, particularly products designated as TR-I and TR-2). For the acrylate decopolymer product (ACULYN® 33) (having a pH in the range 2.1-3.5), a neutralization stage is performed with sodium phosphate (such as phosphatodisodium), sodium hydroxide, or an amine. environmentally-friendly organic protein to increase the pH to approximately 6.5.

(c) agents described in U.S. Patent No. 5,015,415 (incorporated herein by reference) especially N5N-disubstituted phthalamic acids and their ammonium salts selected from the group consisting of Formula III:

<formula> formula see original document page 16 </formula>

wherein R24 and R25 may be the same or different and are each selected from the group consisting of C1-C40 branched straight chain alkyl groups, and C10-C4- straight chain and branched alkyl groups (e.g. wherein R24 and R25 are the same and are each selected from the group consisting of stearyl and hydrogenated tallow, such as STEPAN SAB-2 and STEPAN TAB®-2 from Stepan Company, Northfield, Illinois).

The stabilizing agents must be of a quality and purity acceptable for cosmetic use or purified as required to be cosmetically acceptable. Further discussion of some of these agents can be found in U.S. Patent 5,015,415 to Goze et al. and in our U.S. Serial Number copending patent application 08 / 933,521.

Shampoo carriers which may be used as carriers for the selected MQ resins described above may be produced as solutions, suspensions or emulsions containing a mild, aqueous, foaming detergent and conditioning composition comprising by weight the total weight of the composition:

(a) 4.00 - 60.00 percent of a desersive surfactant selected from the group consisting of at least one anionic detergent selected from the group consisting of C8-C18 alkyl sulfates, C 8-6 alkyl ethoxy ether sulfates -C18 containing 1-5 ethoxy namolecule groups, C10-C18 acyl isethionates, C10-C20 alkyl sulfonates, C10-C20 alkylene sulfonates, and mixtures thereof; and optionally at least one of:

(i) 0.10-5.00 percent of an anionic hydrotopic, C1 -C3 alkyl benzene sulfonate and C5 -C6 alkyl sulfate

(ii) 0.10 - 15.00 percent of an amphoteric surfactant selected from the group consisting of C8 -C18 alkyl betaines, C8 -C18 alkylsulfobetaines, C8 -C18 alkylstarch, C8 -C18 alkylalkyl starch C 2 -C 3 sulfobetaines, C 8 -C 18 alkyl amphacetates, C 8 -C 18 alkyl amphopropionates, cocoamidopropyl betaine, and mixtures thereof, and

(iii) 0.1 -4.0 percent of a nonionic surfactant, particularly a member of the group consisting of C8-C22 monoethanolamides and mixtures thereof and C8-C22 diethanolamides and mixtures thereof, especially cocamonoethanolamide and cocadiethanolamide ;

provided that the total amount of detersive surfactant does not exceed 60 weight percent of the total weight of the composition and preferably is in the range of 6-30 percent;

(b) 0.10 - 7.0 (more particularly 0.10 - 5.00) percent of a stabilizing agent selected from the group described above as stabilizing agents, particularly polyacrylic acid, polyacrylic acid derivatives, copolymer of acrylates, deacrylate copolymer derivatives, and polymeric emulsifiers, such as crosslinked polymer of C10-30 alkyl acrylate / deacrylates, with particular products including products bearing the ACULYN® 33, TAB®-2, SAB-2 and PEMULEN® trademarks; mixtures of ACULYN® 22-esteareth acrylate / meiacrylate copolymer and ACULYN® 33 product (such that in the 50/50 range) may also be used;

(c) optionally a quaternized cellulosic polymer (in particular at least one quaternized cellulosic polymer, for example, Polyquaternium-10);

(d) the balance as water or aqueous medium.

For conditioning shampoos, another ingredient may optionally be added as (e):

(e) 0.01 - 10.00 percent of a water-insoluble conditioning agent, which may be selected from the group, consisting of:

(i) 0.10 - 6.00 percent of a water-insoluble silicone selected from the group consisting of dimethicones and silicones, such as the silicones described in U.S. Patent No. 4,741,855, incorporated herein by reference; These include polyalkyl siloxanes, polyarylsiloxanes, polyalkylaryl siloxanes, polyester siloxane copolymers, the mixtures of the foregoing in amounts of from 0.1 - 10.00%, preferably from about 0.5 -5.0% - per polydimethylsiloxanes with viscosities at 25 ° C of 5-600,000 centistokes (eg 60,000 centistokes), available from General Electric Company as the Viscasil series and Dow Corning series as the Dow Corning 200 series, polymethylphenylsiloxanes having viscosities of 15-30,000 centistokes at 25 ° C (e.g., methylphenyl fluid SF 1075 from General Electric Company and Dow Corning 556 Cosmetic Quality Fluid from Dow Corning), propylene oxide modified edimethyl polysiloxane as well as ethylene oxide or mixtures of EO modified materials and POWDER;

(ii) a mixture of at least one of (d) (i) with 0.01 -3.00 percent of a cationic polymer such that a polyquaternary compound selected from the group consisting of quaternized cdulosic polymers (in particular at least a quaternized cellulosic polymer, for example, Polyquaternium (10);

(iii) non-cellulosic quaternium compounds (e.g.

Polychadenum -7); and

(iv) a mixture of at least one of (d) (i) with 0.01 -3.00 percent of a cationic polymer, such that a compostopoliquaternary, selected from the group, consisting of a mixture of at least a quaternized cellulosic polymer with a non-cellulosic quaternary polymeric conditioner;

Note that the use of certain silicones may require the use of a suspending or stabilizing agent as described herein and in patent literature.

Another particular type of shampoo can be produced by combining from 0.1% -15% MQ resin, 45-60% of a surfactant such that a synthetic surfactant of 0.5-7% of a stabilizer (based on in 100% active substance), and the remaining water. Suitable detonative examples include ammonium lauryl sulfate, ammonium laureth sulfate, triethylamine lauryl sulfate, triethylamine laureth sulfate, triethanolamine lauryl sulfate, triethanolamine laureth sulfate, monoethanolamine laureth sulfate, diethanol laureth sulfate, laureth sulfate sodium lauryl demonoglyceride sulfate, sodium lauryl sulfate, sodium laureth sulfate, potassium lauryl sulfate, potassium laureth sulfate, lauryl sarcosine, cocoilsarcosine, ammonium cocoyl sulfate, sodium cocoyl sulfate, sodium lauroyl sulfate, cocoil potassium sulphate, potassium lauroyl sulphate, triethanolamine lauroyl sulphate, triethanolamine lauroyl sulphate, monoethanolamine cocoyl sulphate, sodium monoethanolamine lauryl sulphate, sodium tridecyl benzene sulphonate, and others described in US Patent No. 4,902,499 from Bolich et al, in columns 4-6, incorporated herein by reference.

Another particular example of a suitable carrier for providing the compositions of the invention includes conditioners. Particular formulations are those produced with lipid, cationic surfactant and water materials. Such formulations may be found in U.S. 5,120,531, incorporated herein by reference.

Lipid carrier materials useful in the invention are water insoluble compounds which have both hydrophobic and hydrophilic portions. Examples of suitable lipid material are naturally or synthetically derived acids, derivatives of acid, alcohols, esters, ethers, ketones, alcohol ethoxylates and amides, with 12-22 and preferably 12-18 and 16-18 carbon chains. Specific examples include esters such as cetyl palmitate and glyceryl monostearate; alcohols, such as cetyl alcohol and stearyl alcohol. Particular delipid materials are (a) stearyl alcohol as a single delipid material and (b) a mixture of 55-65% cetyl alcohol and the remainder of stearyl alcohol. These lipid materials include naturally or synthetically derived fatty alcohols, fatty alcohol ethoxylates, and fatty esters.

Cationic surfactants useful in forming such conditioners include those described in U.S. Patent 5,120,531, mentioned above, as well as others. Particular examples include cationic surfactants containing hydrophilic quaternary ammonium or amino moieties, which are positively charged when dissolved in aqueous compositions, such as those of the general formula (R10) (Rn) (R12) (R13) N + 1 —X, where R10 is hydrogen an aliphatic group of 1-22 carbon atoms, or an aromatic aryl or alkylaryl group having 12-22 carbon atoms; R11 is an aliphatic group having from 1-22 carbon atoms; R19 and R13 are each independently selected from the group, which consists of alkyl groups having 1-3 carbon atoms; and X is a selected from the group consisting of halogen, acetate, phosphate, nitrate and alkylsulfate radicals. Aliphatic groups may contain, in addition to carbon and hydrogen atoms, ether bonds and other such groups as starch groups. Examples of quaternary ammonium salts include decetyl trimethyl ammonium chloride ("cetrimonium chloride", lauryl trimethylammonium chloride ("lautrimonium chloride"), tricetyl methyl ammonium chloride ("tricetylmonium chloride"), stearyl dimethyl benzyl ammonium chloride (" esteralconium chloride "), and dimethyl ammonium di chloride (partially hydrogenated tallow), distearyldimmonium chloride, etc.

A particular group of conditioning agents are selected from quaternary ammonium compounds, particularly dikethyldimonium chloride, distearyldimonium chloride and other materials as mentioned above under cationic surfactants.

Examples of conditioners to which MQ resin may be added are those produced with from 0.1 - 10.0% delipid material; 0.05 -5.0% cationic surfactant and water.

Hair rinse compositions may be formed by combining the MQ resin (or mixtures thereof) as described above with water (preferably distilled or deionized water) or a water / alcohol mixture such that in a ratio of 20%. : 1 -1: 2 as part of the vehicle. From 0.1-10% surfactant is also included. The carrier is present in an amount of from 75% -99.5% by weight, preferably from 85% -99%, and more particularly from about 90% -99% of the total composition.

Sprays may be formed by mixing 0.01-10% of the common MQ resin (or mixtures thereof) or more volatile materials, such as water, ethanol, cyclomethicone, as described above, with 0.1-10% at least one. surfactant if water is included in a significant amount and one or more of the optional ingredients described above.

Other particular examples of vehicles suitable for the application of the volume producing agents of the invention (which may be in the form of shampoos, conditioning agents, conditioning shampoos, sprays and the like are known to those skilled in the art, for example those described in US patent 3,577,517 to Kobot et al; US Patent 3,907,984 to Calvert et al; US Patent 4,012,501 to Farber; US Patent 4,223,009 to Chakrabarti et al; and US Patent 4,283,384 to Jacquet et al., all of which are incorporated herein by reference.

In addition to the basic formulations described above for shampoos and conditioners, it may also be desirable to add one or more of the following, including mixtures of each of such ingredients:

(a) viscosity control agents for shampoos:

polyvinyl alcohol, ethyl alcohol, acrylic acid polymers and copolymers, cellulosic ethers, diethanolamide or long chain fatty acid monoethanolamide (eg lauramide PEG 3), ethylene oxide and propylene oxide block polymers, sodium chloride, sodium sulfate water soluble polymers such as guar gum) particularly a thickening agent such as hydroxypropyl cellulose, guar hydroxypropyltrimmonium chloride, PEG-120 methyl glucose dioleate, pentaerythrityl tetraestearate, and xanthan gum.

(al) viscosity control agents for conditioners:

polyvinyl alcohol, ethyl alcohol, cellulosic ethers, polyacrylamides, water soluble polymers (such as hydroxyethylcellulose, guar gum and starch) particularly a thickening agent such as hydroxyethylcellulose, and guar hydropropyltrimmonium chloride.

(b) fragrances (perfumes), such as cosmologically acceptable fragrances, used in hair care products:

(c) preservatives, for example, anti-microbial agents, particularly a mixture of methylchloromeylisothiazolinone and ethylisothiasolinone (sold under the trademark KATHON (CG by Rohmand Haas, Philadelphia, Pennsylvania), but also including benzyl alcohol, ethyl paraben, propyl paraben, and imidazolidinyl urea , DMDM hydantoin, formalin, 2-bromo-2-nitropropane-1,3-diol ("Bronopol"), and combinations of the foregoing Particular examples may also include a enhancer such as tetracetic ethylenediamine acid or the salt form sodium ( Bronopol and EDTA (such as 0.04% Bronopol and 0.1% EDTA), formalin, DMDM hydantoin and EDTA (such as 0.1% deformalin, 0.45% DMDM hydantoin, and 0.2 % EDTA));

(d) colorants or coloring agents, pearlescent (such as ethylene glycol quististate, sodium octyl sulfate, titanium dioxide, oremic), and opacifying agents (such as glycol distearate, latex opacifiers, stearamide monoethanolamine stearate (MEA) ), sodium cetyl stearate, and lanolin derivatives) suitable for use with hair care products.

(e) pH adjusting agents, such as citric acid, sodium carbonate, etc:

(f) sequestering agents, such as ethylene diamine tetraacetic acid and sodium salts of the foregoing.

Such additives may be included on an individual basis in appropriate amounts, for example, in the range of about 0.1-60%, preferably about 0.5-40% by weight, of the total composition weight.

It will be appreciated by those skilled in the art that compositions formulated according to this invention may result in a lasting volume production effect over time, such that the use of products according to the invention may be alternated with other types of commercial shampoos for achieve and maintain the desired level of volume production. Although the increase in hair volume varies from person to person, in general, volume increases over a range of 10-40%, as measured by the Dummy volume test described below, can be achieved by consistent use of the compositions of this invention. In general, the effect on thin, thin hair will be more pronounced than on long, thick, thick hair.

It should also be noted that the compositions of this invention provide volume-producing effects without any substantial fixative (stickiness) or chemical adhesion between the fibers. In this way the hair can be reshaped by a new combination or by fluffing.

Such a procedure will not be effective with fixative treated hair, as it would result in breakage of the spot welds formed between the fixative hair and the consequent loss of the effect of producing a fixative style. The loss of fixation character in the compositions of the present invention can be assessed by ripple retention tests, one of which is described below.

Examples of formulations which may be produced according to the present invention include the following:

Shampoos:

Formulation A:

0.1 - 7.5%, particularly 0.1 - 5%, and more particularly 0.25 - 2.5% of a selected liquid MQ resin (s), and the remainder as a shampoo vehicle. For conditioning shampoos, from 0.1 to 3.0%, particularly from 0.1 to 2.0% of a conditioning agent may also be included.

Formulation B:

10-18% of a surfactant, especially an anionic surfactant, selected from the group consisting of lauryl ammonium lauryl sulfate, ammonium laureth sulphate, sodium lauryl ether sulphate, sodium laureth ether sulphate, lauryl ether sulphate laureth ammonium and mixtures of the foregoing;

0.25 -2.5% of a selected MQ resin;

0.10 - 5.00% of a stabilizing agent;

1-3% of an ingredient, which functions as a foam modifier and / or a viscosity modifier (for example, at least one member selected from the group consisting of cocamidodiethanolamine, cocamidomethanolamine and cocamidopropyl betaine); and

the remainder being water or another aqueous medium, the medium of which may include an effective amount of a preservative, as well as fragrance and coloring agents.

Formulation C:

10-20% of a mixed surfactant system comprising at least one anionic and at least one amphoteric surfactant in a ratio of 60:40 -40: 60 (examples of suitable anionics are the same as described in Formula B and examples of suitable amphoterics are decocamidopropyl amine oxide and cocamidopropyl betaine); 0.25-2.5% of a selected QM resin;

0.10 - 5.00% of a stabilizing agent; and

the remainder being water or another aqueous medium, the medium of which may include an effective amount of a preservative, as well as fragrance and coloring agents.

Conditioners;

0.1 -7.5%, particularly 0.1-5% and more particularly 0.2-2.5% of a selected liquid MQ resin (s), and the remainder as a vehicle for the composition. Formulation Ρ:

1-4% of a lipid material (e.g., stearyl alcohol, and mixtures of stearyl and cetyl alcohols);

1-3% of a quaternized compound (for example, at least one of diketyldimonium chloride; distearyldimonium chloride; and decetyltrimonium chloride); and the remaining water or other aqueous medium, the medium of which may include an effective amount of a preservative, as well as fragrance and coloring agents.

Spray for Volume Production:

0.01-7.5%, particularly 0.03-5.0% and, in particular, 0.05-2.0% of a selected MQ resin with a carrier vehicle such as ethanol.

Rinsing Creams for Volume Production:

0.1-7.5%, particularly 0.1-5.0% and more particularly 0.2-2.5% of a selected MQ resin with a vehicle, such as water, with an appropriate amount surfactant / stabilizer (eg ceteth -20 and cetrimonium chloride) to keep the emulsion stable (the amount of stabilizer depending on the amount of MQ resin used).

Hair Spray with Fixative Additive:

0.01 - 7.5%, particularly 0.05-2.0% of a selected liquid QM resin (s);

0.1-20%, particularly 0.5-15% of a volatile vehicle,

72.5-99.89%, particularly 83-99.45% of a carrier vehicle (which in itself may contain a volatile vehicle such as ethanol);

wherein each of the ingredients may be a single ingredient or mixtures thereof.

In general, the compositions of the present invention may be produced by conventional addition and mixing techniques. MQ resin can be added in various ways. In the case of shampoo formulations, aresine MQ may be added separately, either alone or mixed with cyclomethicone or dimethicone, as in the following examples.

Alternatively, the MQ resin may be added to the heated oil phase prior to the formation of any emulsion.

The compositions of the present invention make it easier for the hair to hold a particular model or configuration. Remarkably, the use of such compositions does not interfere with storage and appears to remain unchanged by the presence of conditioning agents. In addition, tests have shown that volume increases have not decreased over time, as can be the case with fasteners that accumulate on the hair.

Another feature of the invention is the ability to be formulated into compositions which are rinsed from the hair. Thus, although fixative-based bulking agents are usually formulated as hair-leaving products, this is not the case with the present invention, which may be formulated as products for hair-leaving or rinsing from hair. .

The compositions of this invention may also be used in combination with fixatives without losing the volume producing effect. Tests have shown that MQ resins written herein do not appear to interfere with the action of fixatives.

While the compositions of this invention have been described in terms of "comprising" it is also intended that the compositions include more restricted compositions in terms of "consisting of" and "consisting essentially of". Furthermore, while the inventive compositions have been described as "comprising", it should be understood that the compositions also include those produced by combining the related ingredients in the composition.

EXAMPLES

The following examples are included as illustrative of the invention, but should not be construed as limitations on it. Unless otherwise stated, all percentages are by weight based on 100% active substance level for all ingredients and all chemical and scientific terms have their usual and usual meanings. All temperatures are in degrees C. These conventions are also used throughout the rest of the patent application.

Examples 1-4 Conditioning Formulations

Conditioning formulations were produced using the types and amounts of materials listed in Table 1. In a suitable vessel, hydroxyethylcellulose was dispersed in distilled water at room temperature. C9-11 (EO 6: 1) alcohol ethoxylate ("C9-11 Pareth-6") was then added with mixing, and the resulting solution was heated to 75 ° C. Ceteth -20, steareth-20, stearyl alcohol, propyldimethylamine isostearamide, and dicethyldimonium chloride were combined in a suitable vessel and heated to 75 ° C with mixing. With both solutions at 75 ° C, the aqueous phase was then added to the oil phase with mixing. The resulting emulsifier was stirred at 75 ° C for 10 minutes, and then cooled to 60 ° C. Otrimethylsiloxysilicate was dissolved in cyclomethicone and added to the emulsion at 62 ° C. The emulsion was then cooled to 38 ° C, at which temperature, afragrance and preservative were added. The final formulation was finally cooled to room temperature. The MQ resin used was a trimethylsiloxysilicate ("MQ-A") obtained from GE.TABELA 1

<table> table see original document page 29 </column> </row> <table>

Example 5: Conditioning Formulation

A 300 g sample of a conditioning formulation was produced from the following materials: 0.50% hydroxyethylcellulose; 93.35% distilled water; 2.75% cetearyl alcohol, 0.50% stearamidopropyl dimethylamine; 0.15% depolyglyceryl-3-isostearate; 0.25% citric acid; Methyldibromoglutaronitrile and phenoxyethanol MERGUARD® 1200 DE Calgon Corporation, Pittsburgh, Pennsylvania); 0.15% glyceryl monostearate; 1, 50% deildearldimony chloride; 0.25% of the MQ resin described in Examples 1-4; 0.40% defragrance. In a suitable vessel, hydroxyethylcellulose and distilled water were combined with mixing. The solution was heated to 80 ° C. Stearyl alcohol, distearyldimony chloride, stearamidopropyl dimethylamine, glyceryl monostearate, and polyglyceryl-3 isostearate were combined in a separate vessel and heated to 80 ° C with mixing. When both mixtures reached 80 ° C, the aqueous phase was added to the oil phase with stirring. The resulting emulsion was cooled to 60 ° C, and the silicone QM resin was added with stirring. When the temperature reached 38 ° C, the fragrance and preservative were added. The final formulation was then resin at room temperature.

Examples 6-7: Shampoo Formulations

Shampoo formulations were produced using the types and quantities of materials described in Table II. In a suitable vessel, all fused together, less than 10% by weight of distilled water, tetrasodium EDTA, dibasic sodium phosphate ("disodium phosphate"), deammonium lauryl sulfate, deceth-3 disodium sulfate, sodium cumene sulfonate, ecocamidopropyl Betaine. The resulting solution was heated to 90 ° C, comagitation. In a small container, the 10 per cent remnants of distilled water and Polyquennium-10 were combined. The contents of the small container were then added to the above solution while it was under heating. Isosteareth-2, C20-C40 alcohols, distearyldimony chloride were combined and melted in a suitable vessel. Once melted, this mixture was added to an aqueous solution at 90 ° C, comagitation. The resulting emulsion was then resin at 60 ° C. Liquid Otrimethylsiloxysilicate (same MQ resin as described in Examples 1-4) was dissolved in cyclomethicone and added to the emulsion at 60 ° C with the mixture. The resulting mixture was then resin at 38 ° C, at which temperature the fragrance and preservative were added. The final formulation was then cooled to room temperature. Note that for Example 7 this procedure was used but no sodium deceth-3 sulfate, isosteareth-2, distearyldimonium chloride or cyclomethicone were used. TABLE II

<table> table see original document page 31 </column> </row> <table>

Example 8-9: Shampoo Formulations

Shampoo formulations were produced using the types and quantities of materials listed in table II. In a suitable vessel all distilled water minus 10% and sodium phosphate were combined and mixed for 10 minutes. Ammonium lauryl sulfate was added to the vessel and mixed for 5 minutes. The resulting solution was heated to 50 ° C. Remaining distilled water and Polyquartene-10 were premixed for 1-2 minutes and added to the pot with mixing for an additional 15 minutes. In a separate vessel, cocadiethanolamide ("cocamide DEA"), guar gum and distearyldimony chloride were combined and heated to 50 ° C with occasional stirring. When both bones reached 50 ° C, they were combined with mixing. Silicone MQ resin (the same resin as described in Examples 1-4) and dimethicone (included in the formulation) were added separately to the blended vessel for 15 minutes. The vessel was then allowed to start cooling. The acrylate copolymer ("ACULYN® 33") and the fragrance were premixed, and added to the emulsion. When the temperature of the mixture reached 38 ° C, the preservative was added. The final formulation was then cooled to room temperature.

TABLE III

<table> table see original document page 32 </column> </row> <table>

Examples 10-11: Shampoo Formulations

In a suitable vessel, all but 10% of distilled water, and sodium phosphate were combined. Ammonium lauryl sulfate has been added with mixing. The resulting solution was heated to 90 ° C. The remaining portion of the distilled water and Polyquennium-10 were premixed in a separate vessel for 1-2 minutes and added to the solution with mixing for an additional 15 minutes. In a separate vessel, acocadiethanolamide, C20-40 alcohols and distearyldimmonium chloride were melted and added to the solution with mixing. The resulting emulsion was then allowed to cool. Silicone MQ resin (same resin as descriptans Examples 1-4) and dimethicone (if used in the formulation) were added separately to the solution at 60 ° C with mixing. When the emulsion temperature reached 38 ° C, the fragrance and preservative were added. The final formula was then cooled to room temperature. TABLE IV

<table> table see original document page 33 </column> </row> <table>

Examples 12-13: Shampoo Formulations

In a suitable whole vessel, less than 10 percent of the distilled water and monobasic sodium phosphate were combined with mixing. Ammonium lauryl sulfate was added with mixing. The resulting solution was heated to 60 ° C. In a small container, the remaining 10 percent by weight of distilled water and Polyquartene-10 were combined. The contents of the small container were then added to the above solution while it was under heating with mixing for an additional 15 minutes. In a separate vessel, cocadiethanolamide, guar gum and distearyldimonium chloride were combined and fused. Once melted, this mixture was added to the aqueous solution at 60 ° C with stirring. Silicone QM resin (the same resin described in Examples 1-4) and dimethicone (if included in the formulation) were added separately to the emulsion with the mixture. Distearyl phthalic acid amide (TAB-2) was melted in a separate container and added to the mixture when cooled to 55 ° C. The resulting mixture was then cooled to 38 ° C, at which temperature the fragrance and preservative were added. The final formulation was then cooled to room temperature.

Claims (28)

1. Volume-producing hair care composition, characterized in that it comprises an effective amount of a Formula IA QM resin: <formula> formula see original document page 34 </formula> wherein: M1 and M2 are each independently , of the group consisting of: (a) hydrogen, (b) phenyl, (c) phenethyl, (d) a polyether of Formula II: -H2C- (Ch2) i1- (O-Ch (Rio) -Ch2) u- (OCh2-Ch2) v-OR1 1 Formula II wherein, η is a number from 1-20 and the chain - (CH2) - may optionally contain 1 or 2 unsaturation; u and ν are integers, each independently selected from 0-20, as long as u + ν> 1; R4, R5, R6 and R7 are each independently selected from the group consisting of phenyl and branched and unbranched Cl-12 hydrocarbons; R10 is selected from C1-C20 alkyl; and R11 is selected from the group consisting of H, -CH3 and -C (O) CHs; and (e) C1-C24 branched and unbranched hydrocarbons optionally substituted by a halogen substituted C1-C3 hydrocarbon radical; wherein (x + y) / z is a number in the range 0.5 and 1.5, and the values for R4, R5, R6, R7, x, y, z, M1 and M2 are selected such that the resin MQ is a liquid having a viscosity of 1.0 χ 10 -3 - 1 χ 106 centipoises, the composition further comprising: (f) 0.01-15 weight percent, based on the total weight of the composition, of an MQ resin of Formula IA; and (g) 85-99.9 weight percent, based on the total weight of the composition, of a hair care vehicle selected from the group comprising shampoo, conditioner, spray and rinse cream. Composition according to Claim 1, characterized in that the carrier is an aqueous based shampoo. Composition according to Claim 1, characterized in that the vehicle is an aqueous-based conditioner. Composition according to Claim 1, characterized in that the vehicle is a spray. Composition according to Claim 1, characterized in that the carrier is a rinsing cream. Composition according to Claim 1, characterized in that the viscosity of the MQ resin is in the range of 1.5χ 103 - 1 χ 106 centipoises. Composition according to Claim 1, characterized in that the viscosity of the MQ resin is in the range of -1000 - 100,000 centipoises. Composition according to Claim 1, characterized in that the viscosity of the MQ resin is in the range of -1000 - 50,000 centipoises. Composition according to Claim 1, characterized in that the resin MQ has Formula IB: wherein R2 is selected from the same group as M1; R1 and R3 are each independently selected from the same group as defined for R4; x '/ z' is a number in the range 0.5-1.5. Composition according to Claim 1, characterized in that M1 and M2 are each independently selected from the group consisting of C1 -C23 branched and unbranched alkyl. Composition according to Claim 10, characterized in that M1, M2, R4, R5, R6 and R7 are each methyl. Composition according to Claim 9, characterized in that R2 is selected from the group consisting of branched and unbranched C1-C23 alkyl. Composition according to Claim 12, characterized in that R 1, R 2, and R 3 are each methyl. Composition according to Claim 1, characterized in that (x + y) / ζ = 1. Composition according to Claim 9, characterized in that x '/ z' = 1. Composition according to Claim 13, characterized in that x '/ z' = 1. Composition according to Claim 1, characterized in that it further comprises a fastener. Composition according to Claim 2, characterized in that it comprises from 0.1 to 7.5 of the MQ resin. Composition according to Claim 18, characterized in that it comprises 0.1-5.0% of the MQ resin. Composition according to Claim 18, characterized in that it comprises 0.1 - 3.0% of MQ resin. Composition according to Claim 18, characterized in that it comprises 0.2 -2.5% of MQ resin. Composition according to Claim 18, characterized in that it further comprises 0.1 - 2.0% of a conditioning agent. Composition according to Claim 2, characterized in that it further comprises 4.00-60.00% of a detersive surfactant selected from the group consisting of at least one anionic detergent selected from the group consisting of sulfates. C 8 -C 8 alkyl, C 8 -C 18 alkyl ethoxy ether sulfates containing 1-5 ethoxy groups in the molecule, C 10 -C 18 acyl isethionates, C 10 -C 20 alkyl sulfonates, C 10 -C 20 alkylene sulfonates, and mixtures thereof; and optionally at least one of: (i) 0.10 - 5.00 percent of an anionic hydrotopic, C1 -C3 alkyl benzene sulfonate or C5 -C6 alkyl sulfate; (ii) 0.10 - 15.00 percent of a surfactant amphoterics selected from the group consisting of C8-C8 alkyl betaines, C8-C8 alkylsulfobetaines, C8-C18 alkylamido C2-C3 alkyl betaine, C8-C18 alkylamido alkyl C2-C18 alkylamphacetates, C8-C18 alkylamphopropionate, betaine, and mixtures thereof; and (ii) 0.1 -4.0 percent of a nonionic surfactant, provided that the total amount of detersive surfactant does not exceed 60 percent by weight of the total weight of the composition. Composition according to Claim 2, characterized in that it further comprises 0.10-5.00 per cent of a stabilizing agent. Composition according to Claim 3, characterized in that it further comprises lipid materials and at least one cationic surfactant. Composition according to Claim 25, characterized in that the at least one cationic surfactant is selected from the group consisting of cationic surfactants containing hydrophilic portions of quaternary ammonium or amino. Composition according to Claim 26, characterized in that the at least one cationic surfactant is selected from the group consisting of compositions of formula (R10) (Rn) (R12) (R13) N + 1 —X, wherein R10 is hydrogen, an aliphatic group of 1-22 carbon atoms, or an aryl or alkylaryl aromatic group having 12-22 carbon atoms; R11 is an aliphatic group having 1-22 carbon atoms; R 12 and R 13 are each independently selected from the group consisting of alkyl groups having 1-3 carbon atoms; and X is an anion selected from the group consisting of halogen, acetate, phosphate, nitrate and alkylsulfate radicals. Composition according to Claim 1, characterized in that the composition increases the hair volume by 10 to 40% as measured by the Dummy test as compared to a composition without MQ resin.