BR9710513B1 - compound, chelate complex and intermediate for preparation of macrocyclic tetradentate compounds. - Google Patents

compound, chelate complex and intermediate for preparation of macrocyclic tetradentate compounds.

Info

Publication number
BR9710513B1
BR9710513B1 BRPI9710513-9A BR9710513A BR9710513B1 BR 9710513 B1 BR9710513 B1 BR 9710513B1 BR 9710513 A BR9710513 A BR 9710513A BR 9710513 B1 BR9710513 B1 BR 9710513B1
Authority
BR
Brazil
Prior art keywords
compound
preparation
chelate complex
macrocyclic tetradentate
compounds
Prior art date
Application number
BRPI9710513-9A
Other languages
Portuguese (pt)
Other versions
BR9710513A (en
Inventor
Terrence J Collins
Scott W Gordon-Wylie
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed filed Critical
Publication of BR9710513A publication Critical patent/BR9710513A/en
Publication of BR9710513B1 publication Critical patent/BR9710513B1/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System compounds of the platinum group
    • C07F15/002—Osmium compounds
    • C07F15/0026—Osmium compounds without a metal-carbon linkage
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
    • B01J31/1815—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine with more than one complexing nitrogen atom, e.g. bipyridyl, 2-aminopyridine
    • B01J31/182—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine with more than one complexing nitrogen atom, e.g. bipyridyl, 2-aminopyridine comprising aliphatic or saturated rings
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B01J31/4015—Regeneration or reactivation of catalysts containing metals
    • B01J31/4023—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D257/00—Heterocyclic compounds containing rings having four nitrogen atoms as the only ring hetero atoms
    • C07D257/02—Heterocyclic compounds containing rings having four nitrogen atoms as the only ring hetero atoms not condensed with other rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D257/00—Heterocyclic compounds containing rings having four nitrogen atoms as the only ring hetero atoms
    • C07D257/10—Heterocyclic compounds containing rings having four nitrogen atoms as the only ring hetero atoms condensed with carbocyclic rings or ring systems
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/70—Oxidation reactions, e.g. epoxidation, (di)hydroxylation, dehydrogenation and analogues
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/10—Complexes comprising metals of Group I (IA or IB) as the central metal
    • B01J2531/16—Copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/10—Complexes comprising metals of Group I (IA or IB) as the central metal
    • B01J2531/17—Silver
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/10—Complexes comprising metals of Group I (IA or IB) as the central metal
    • B01J2531/18—Gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
    • B01J2531/62—Chromium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
    • B01J2531/64—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
    • B01J2531/66—Tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/70—Complexes comprising metals of Group VII (VIIB) as the central metal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/70—Complexes comprising metals of Group VII (VIIB) as the central metal
    • B01J2531/72—Manganese
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/70—Complexes comprising metals of Group VII (VIIB) as the central metal
    • B01J2531/74—Rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/821—Ruthenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/824—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/825—Osmium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/827—Iridium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/828—Platinum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/842—Iron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/845—Cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/847—Nickel
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts
BRPI9710513-9A 1996-07-22 1997-07-21 compound, chelate complex and intermediate for preparation of macrocyclic tetradentate compounds. BR9710513B1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US08/681,237 US5847120A (en) 1996-07-22 1996-07-22 Long-lived homogenous oxidation catalysts
PCT/US1997/012803 WO1998003263A1 (en) 1996-07-22 1997-07-21 Long-lived homogenous oxidation catalysts

Publications (2)

Publication Number Publication Date
BR9710513A BR9710513A (en) 2002-03-05
BR9710513B1 true BR9710513B1 (en) 2010-10-19

Family

ID=24734398

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI9710513-9A BR9710513B1 (en) 1996-07-22 1997-07-21 compound, chelate complex and intermediate for preparation of macrocyclic tetradentate compounds.

Country Status (21)

Country Link
US (2) US5847120A (en)
EP (1) EP0914206B1 (en)
JP (2) JP2000515152A (en)
KR (1) KR100491450B1 (en)
CN (1) CN1121906C (en)
AP (1) AP919A (en)
AT (1) ATE229372T1 (en)
AU (1) AU729102B2 (en)
BR (1) BR9710513B1 (en)
CA (1) CA2261589C (en)
DE (1) DE69717819T2 (en)
DK (1) DK0914206T3 (en)
ES (1) ES2188969T3 (en)
HK (1) HK1020176A1 (en)
IL (1) IL128150A0 (en)
NO (1) NO326043B1 (en)
NZ (1) NZ333797A (en)
OA (1) OA10960A (en)
PL (1) PL187534B1 (en)
PT (1) PT914206E (en)
WO (1) WO1998003263A1 (en)

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US6054580A (en) * 1996-07-22 2000-04-25 Carnegie Mellon University Long-lived homogenous amide containing macrocyclic compounds
JP2002505688A (en) * 1997-06-20 2002-02-19 カーネギー・メロン・ユニバーシティ Homogeneous oxidation catalysis using metal complexes
AU751049B2 (en) * 1998-04-15 2002-08-08 Shell Internationale Research Maatschappij B.V. Catalyst system for alpha-olefin oligomerization
US6861262B2 (en) * 2000-03-03 2005-03-01 Quest Diagnostics Investments Incorporated Composition and method for detecting an adulterant in an aqueous sample
GB0020846D0 (en) * 2000-08-23 2000-10-11 Unilever Plc Ligands for bleaching compositions and synthesis thereof
US6797196B2 (en) 2001-01-10 2004-09-28 Kao Corporation Bleaching formulation
GB0118936D0 (en) * 2001-08-02 2001-09-26 Unilever Plc Improvements relating to colour-safe fabric treatment compositions
WO2003014279A1 (en) * 2001-08-02 2003-02-20 Unilever Plc Composition comprising macrocyclic tetra-amido metal complex as bleaching catalyst
GB0205276D0 (en) * 2002-03-06 2002-04-17 Unilever Plc Bleaching composition
GB0205278D0 (en) * 2002-03-06 2002-04-17 Unilever Plc Composition comprising macrocyclic tetra-amido N-donor metal-ligand complex as bleaching catalyst
DE10227774A1 (en) * 2002-06-21 2004-01-08 Degussa Ag Use of transition metal complexes with nitrogen-containing multidentate ligands as a bleaching catalyst and bleaching agent composition
US7060818B2 (en) * 2003-02-21 2006-06-13 Carnegie Mellon University Synthesis of macrocyclic tetraamido compounds and new metal insertion process
US7989647B2 (en) * 2005-03-03 2011-08-02 South Dakota Soybean Processors, Llc Polyols derived from a vegetable oil using an oxidation process
CN100412080C (en) * 2005-04-06 2008-08-20 友达光电股份有限公司 Organo-metallic complex and organic LED and display containing the complex
EP1926682A4 (en) * 2005-06-21 2012-06-20 Crosslink Polymer Res Signal activated decontaminating coating
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US8715489B2 (en) * 2005-09-08 2014-05-06 Saudi Arabian Oil Company Process for oxidative conversion of organosulfur compounds in liquid hydrocarbon mixtures
US7744749B2 (en) * 2005-09-08 2010-06-29 Saudi Arabian Oil Company Diesel oil desulfurization by oxidation and extraction
US7842637B2 (en) * 2008-05-23 2010-11-30 Lumimove, Inc. Electroactivated film with polymer gel electrolyte
US8722881B2 (en) * 2009-10-13 2014-05-13 Board Of Trustees Of The University Of Arkansas Method of synthesis of tetradentate amide macrocycle ligand and its metal-complex
US8584757B2 (en) 2010-04-21 2013-11-19 Halliburton Energy Services, Inc. Method and composition for treating fluids before injection into subterranean zones
JP2013542171A (en) 2010-04-21 2013-11-21 ディスカス デンタル，エルエルシー How to clean and whiten teeth at the same time
US20150342839A1 (en) 2010-04-21 2015-12-03 Oraceutica LLC Compositions and methods for whitening teeth
US8888489B2 (en) 2012-10-23 2014-11-18 Oraceutical Llc Method of simultaneously cleaning and whitening teeth
US9320580B2 (en) 2013-04-21 2016-04-26 Oraceutical Llc Hand-held tooth whitening instrument with applicator reservoir for whitening composition and methods of using same
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US20180118590A1 (en) * 2015-04-24 2018-05-03 Auckland Uniservices Limited Oxidation method
AR104939A1 (en) 2015-06-10 2017-08-23 Chemsenti Ltd OXIDATIVE METHOD TO GENERATE CHLORINE DIOXIDE
AR104940A1 (en) 2015-06-10 2017-08-23 Chemsenti Ltd METHOD FOR GENERATING CHLORINE DIOXIDE
WO2017015145A2 (en) 2015-07-17 2017-01-26 SeLux Diagnostics, Inc. Dissociable transition-metal nanoparticles
EP3353157B1 (en) 2015-09-25 2021-11-24 Carnegie Mellon University Oxidation catalysts based on macrocyclic compounds
WO2017100442A1 (en) 2015-12-08 2017-06-15 SeLux Diagnostics, Inc. Nanoparticle amplifiers and uses thereof
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US5847120A (en) * 1996-07-22 1998-12-08 Carnegie Mellon University Long-lived homogenous oxidation catalysts

Also Published As

Publication number Publication date
DE69717819T2 (en) 2003-07-10
NZ333797A (en) 2000-06-23
EP0914206A1 (en) 1999-05-12
BR9710513A (en) 2002-03-05
NO326043B1 (en) 2008-09-08
IL128150A0 (en) 1999-11-30
ES2188969T3 (en) 2003-07-01
JP2000515152A (en) 2000-11-14
KR100491450B1 (en) 2005-05-25
PL187534B1 (en) 2004-07-30
KR20000067993A (en) 2000-11-25
HK1020176A1 (en) 2000-03-31
AP919A (en) 2000-12-29
JP2007016036A (en) 2007-01-25
CN1230903A (en) 1999-10-06
OA10960A (en) 2001-10-29
EP0914206B1 (en) 2002-12-11
AU4043697A (en) 1998-02-10
WO1998003263A1 (en) 1998-01-29
NO990268L (en) 1999-03-22
AP9901455A0 (en) 1999-03-31
CN1121906C (en) 2003-09-24
PL331315A1 (en) 1999-07-05
ATE229372T1 (en) 2002-12-15
CA2261589C (en) 2002-10-01
CA2261589A1 (en) 1998-01-29
DK0914206T3 (en) 2003-04-07
US5847120A (en) 1998-12-08
US6100394A (en) 2000-08-08
PT914206E (en) 2003-04-30
AU729102B2 (en) 2001-01-25
DE69717819D1 (en) 2003-01-23
NO990268D0 (en) 1999-01-21

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