BR9307544A - 2,2 ', 2 "-nitrile [triethyl-tris- (3,3', 5,5'-tetra-tert-butyl-1,1'-biphenyl -2,2'-diyl) beta-crystalline modification phosphite] - Google Patents

2,2 ', 2 "-nitrile [triethyl-tris- (3,3', 5,5'-tetra-tert-butyl-1,1'-biphenyl -2,2'-diyl) beta-crystalline modification phosphite]

Info

Publication number
BR9307544A
BR9307544A BR9307544A BR9307544A BR9307544A BR 9307544 A BR9307544 A BR 9307544A BR 9307544 A BR9307544 A BR 9307544A BR 9307544 A BR9307544 A BR 9307544A BR 9307544 A BR9307544 A BR 9307544A
Authority
BR
Brazil
Prior art keywords
diyl
phosphite
triethyl
biphenyl
tetra
Prior art date
Application number
BR9307544A
Other languages
Portuguese (pt)
Inventor
Stephen D Pastor
Sai P Shum
Original Assignee
Ciba Sc Holding Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ciba Sc Holding Ag filed Critical Ciba Sc Holding Ag
Publication of BR9307544A publication Critical patent/BR9307544A/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/49—Phosphorus-containing compounds
    • C08K5/51—Phosphorus bound to oxygen
    • C08K5/52—Phosphorus bound to oxygen only
    • C08K5/527—Cyclic esters
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
    • C07F9/6571—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms
    • C07F9/6574—Esters of oxyacids of phosphorus
    • C07F9/65746—Esters of oxyacids of phosphorus the molecule containing more than one cyclic phosphorus atom

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Anti-Oxidant Or Stabilizer Compositions (AREA)

Abstract

The beta crystalline modification of 2,2',2''-nitrilo[triethyl-tris-(3,3',5,5'-tetra-tert-butyl-1,1'-biphenyl-2,2'-diyl) phosphite] is obtained by crystallizing said compound from the melt at elevated temperatures. The beta crystalline form is an effective process stabilizer for polyolefins, particularly polypropylene.
BR9307544A 1992-11-30 1993-11-22 2,2 ', 2 "-nitrile [triethyl-tris- (3,3', 5,5'-tetra-tert-butyl-1,1'-biphenyl -2,2'-diyl) beta-crystalline modification phosphite] BR9307544A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US07/983,181 US5326802A (en) 1992-11-30 1992-11-30 Beta crystalline modification of 2,2',2"-nitrilo[triethyl-tris-(3,3',5,5'-tetra-tert-buytl-1,1'-biphenyl-2,2'-diyl)phosphite]
PCT/US1993/011320 WO1994012508A1 (en) 1992-11-30 1993-11-22 Beta crystalline modification of 2,2',2''-nitrilo[triethyl-tris-(3,3',5,5'-tetra-tert-butyl-1,1'-biphenyl-2,2'-diyl) phosphite]

Publications (1)

Publication Number Publication Date
BR9307544A true BR9307544A (en) 1999-06-15

Family

ID=25529827

Family Applications (1)

Application Number Title Priority Date Filing Date
BR9307544A BR9307544A (en) 1992-11-30 1993-11-22 2,2 ', 2 "-nitrile [triethyl-tris- (3,3', 5,5'-tetra-tert-butyl-1,1'-biphenyl -2,2'-diyl) beta-crystalline modification phosphite]

Country Status (16)

Country Link
US (2) US5326802A (en)
EP (1) EP0670842B1 (en)
JP (1) JPH08503946A (en)
AT (1) ATE148125T1 (en)
AU (1) AU687021B2 (en)
BR (1) BR9307544A (en)
CA (1) CA2148933A1 (en)
CZ (1) CZ137395A3 (en)
DE (1) DE69307735T2 (en)
ES (1) ES2099574T3 (en)
MX (1) MX9307466A (en)
RU (1) RU2123007C1 (en)
SK (1) SK279945B6 (en)
TW (1) TW313575B (en)
WO (1) WO1994012508A1 (en)
ZA (1) ZA938894B (en)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5405893A (en) * 1993-08-18 1995-04-11 Ciba-Geigy Corporation Gamma crystalline modification of 2.2',2"-nitrilo[triethyl-tris-(3,3',5,5'-t'-biphenyl-2,2'-diyl) phosphite]
EP0710677A3 (en) * 1994-11-03 1998-02-04 Ciba SC Holding AG Process for producing stabilized olefin polymers
US5486641A (en) * 1995-02-28 1996-01-23 Ciba-Geigy Corporation Solvent-free process for the preparation of the beta crystalline modification of 2,2',2"-nitrilo[triethyl-tris-(3,3',5,5',-tetra-tert-butyl-1,1'-biphenyl-2,2'-diyl) phosphite]
CZ126296A3 (en) * 1995-05-03 1996-11-13 Ciba Geigy Ag Amorphous and crystalline modifications of 1, 1°, 1°°-nitrilo{tri-2-propyl-tris£2,2°-ethylidenebis(4,6-ditert-butylphenyl)| phosphite, process of their preparation and their use for stabilizing organic materials
US5489636A (en) * 1995-05-03 1996-02-06 Ciba-Geigy Corporation Amorphous modification of 1,1',1"-nitrilo(tri-2-propyl-tris-[2,2'-ethylidene-bis(4,6-di-tert-butylphenyl] phosphite)
US5624983A (en) * 1995-11-02 1997-04-29 Ciba-Geigy Corporation Amorphous modification of 1,1',1"-nitrilo(triethyl-tris-[2,2'-methylene-bis(4,6-di-tert-butylphenyl)] phosphite)
EP0771814A1 (en) * 1995-11-02 1997-05-07 Ciba SC Holding AG Amorphous and crystalline modifications of 1,1',1"-nitrilo triethyl-tris[2,2'-methylene-bis(4,6-di-tert-butyl-phenyl)]phosphite
US5654455A (en) * 1995-12-21 1997-08-05 Ciba-Geigy Corporation Tris-phosphite ligands and their use in transitioin metal catalyzed processes
US5763512A (en) * 1996-03-29 1998-06-09 Ciba Specialty Chemicals Corporation Stabilization of polyamide, polyester and polyketone
DE19624424A1 (en) * 1996-06-19 1998-01-08 Hoechst Ag Process for the preparation of the alpha-kirstall modification of the 2,2 ', 2 "-nitrilo (triethyl-tris (3,3', 5,5'-tetra-tert-butyl-1,1'-biphenyl-2, 2'-diyl) phosphite) "
US5834541A (en) * 1997-05-02 1998-11-10 Montell North America Inc. Olefin polymer composition having low smoke generation and fiber and film prepared therefrom
US6184262B1 (en) * 1997-09-22 2001-02-06 R. T. Vanderbilt Company, Inc. Benzotriazole stabilizers for polyols and polyurethane foam
US6172153B1 (en) 1998-06-12 2001-01-09 Montell North America Inc. Olefin polymer composition having low smoke generation and fiber, film and fabric prepared therefrom
DE602004013584D1 (en) * 2003-06-19 2008-06-19 Basell Poliolefine Srl OLEFIN POLYMERS WITH STABILIZERS AND POLYOLEFIN FIBERS MANUFACTURED THEREOF
TWM501336U (en) 2015-02-11 2015-05-21 Good Year Hardware Co Ltd Structure of tool head connected pole
CA2990035A1 (en) * 2015-06-19 2016-12-22 Dow Technology Investments Llc Crystalline form of 6,6'[[3,3', 5,5'-tetrakis(1,1-dimethylethyl)-[1,1'-biphenyl]-2,2'-diyl]bis(oxy)bisdibenzo[d,f][1,3,2]-dioxaphosphepin with improved thermal stability

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4318895A (en) * 1979-11-05 1982-03-09 Mcdonnell Douglas Corporation Process for generating singlet-oxygen
US4374219A (en) * 1980-11-24 1983-02-15 Ciba-Geigy Corporation Alkanolamine ester of 1,1-biphenyl-2,2-diyl-and alkylidene-1,1-biphenyl-2,2-diyl-cyclic phosphites
US4318845A (en) * 1980-11-24 1982-03-09 Ciba-Geigy Corporation Alkanolamine esters of 1,1'-biphenyl-2,2'-diyl-and alkylidene-1,1'-biphenyl-2,2'-diyl-cyclic phosphites
US4683326A (en) * 1985-07-19 1987-07-28 Ciba-Geigy Corporation Solvent-free crystallization of pentaerythritol tetrakis-[3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate] and the novel alpha-crystalline form thereof

Also Published As

Publication number Publication date
RU2123007C1 (en) 1998-12-10
US5344860A (en) 1994-09-06
MX9307466A (en) 1994-05-31
SK279945B6 (en) 1999-06-11
SK71595A3 (en) 1995-09-13
AU5615794A (en) 1994-06-22
RU95114523A (en) 1997-06-27
CZ137395A3 (en) 1995-10-18
US5326802A (en) 1994-07-05
WO1994012508A1 (en) 1994-06-09
EP0670842B1 (en) 1997-01-22
TW313575B (en) 1997-08-21
EP0670842A1 (en) 1995-09-13
CA2148933A1 (en) 1994-06-09
ES2099574T3 (en) 1997-05-16
JPH08503946A (en) 1996-04-30
ZA938894B (en) 1994-08-01
DE69307735T2 (en) 1997-10-02
ATE148125T1 (en) 1997-02-15
DE69307735D1 (en) 1997-03-06
AU687021B2 (en) 1998-02-19

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