BR112022000493A2 - Methyl 2-[(4-methoxy-imino-tetralin-6-yl]prop-2-enoate derivatives, their chroman analogues, isochroman, 6,7,8,9-tetrahydrobenzo[7]annulene, 1h -isobenzofuran and indane, and similar compounds such as agrochemical fungicides - Google Patents
Methyl 2-[(4-methoxy-imino-tetralin-6-yl]prop-2-enoate derivatives, their chroman analogues, isochroman, 6,7,8,9-tetrahydrobenzo[7]annulene, 1h -isobenzofuran and indane, and similar compounds such as agrochemical fungicidesInfo
- Publication number
- BR112022000493A2 BR112022000493A2 BR112022000493A BR112022000493A BR112022000493A2 BR 112022000493 A2 BR112022000493 A2 BR 112022000493A2 BR 112022000493 A BR112022000493 A BR 112022000493A BR 112022000493 A BR112022000493 A BR 112022000493A BR 112022000493 A2 BR112022000493 A2 BR 112022000493A2
- Authority
- BR
- Brazil
- Prior art keywords
- methoxy
- methyl
- tetralin
- prop
- annulene
- Prior art date
Links
- 150000001875 compounds Chemical class 0.000 title abstract 7
- PQNFLJBBNBOBRQ-UHFFFAOYSA-N indane Chemical compound C1=CC=C2CCCC2=C1 PQNFLJBBNBOBRQ-UHFFFAOYSA-N 0.000 title abstract 4
- HEOQXHNKRXRCTO-UHFFFAOYSA-N 6,7,8,9-tetrahydro-5h-benzo[7]annulene Chemical compound C1CCCCC2=CC=CC=C21 HEOQXHNKRXRCTO-UHFFFAOYSA-N 0.000 title abstract 3
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical class [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 title abstract 3
- VZWXIQHBIQLMPN-UHFFFAOYSA-N chromane Chemical class C1=CC=C2CCCOC2=C1 VZWXIQHBIQLMPN-UHFFFAOYSA-N 0.000 title abstract 3
- 239000000417 fungicide Substances 0.000 title abstract 3
- HEBMCVBCEDMUOF-UHFFFAOYSA-N isochromane Chemical compound C1=CC=C2COCCC2=C1 HEBMCVBCEDMUOF-UHFFFAOYSA-N 0.000 title abstract 3
- SFLGSKRGOWRGBR-UHFFFAOYSA-N phthalane Chemical compound C1=CC=C2COCC2=C1 SFLGSKRGOWRGBR-UHFFFAOYSA-N 0.000 title abstract 3
- 239000003905 agrochemical Substances 0.000 title abstract 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 title abstract 2
- AICOOMRHRUFYCM-ZRRPKQBOSA-N oxazine, 1 Chemical compound C([C@@H]1[C@H](C(C[C@]2(C)[C@@H]([C@H](C)N(C)C)[C@H](O)C[C@]21C)=O)CC1=CC2)C[C@H]1[C@@]1(C)[C@H]2N=C(C(C)C)OC1 AICOOMRHRUFYCM-ZRRPKQBOSA-N 0.000 abstract 2
- -1 (e)-3-methoxy-2-[ Methyl (4z)-4-methoxyiminoisochroman-6-yl]prop-2-enoate Chemical compound 0.000 abstract 1
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 238000012512 characterization method Methods 0.000 abstract 1
- 150000002468 indanes Chemical class 0.000 abstract 1
- 239000000575 pesticide Substances 0.000 abstract 1
- 238000003786 synthesis reaction Methods 0.000 abstract 1
- 125000005329 tetralinyl group Chemical class C1(CCCC2=CC=CC=C12)* 0.000 abstract 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D311/00—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only hetero atom, condensed with other rings
- C07D311/02—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only hetero atom, condensed with other rings ortho- or peri-condensed with carbocyclic rings or ring systems
- C07D311/04—Benzo[b]pyrans, not hydrogenated in the carbocyclic ring
- C07D311/58—Benzo[b]pyrans, not hydrogenated in the carbocyclic ring other than with oxygen or sulphur atoms in position 2 or 4
- C07D311/68—Benzo[b]pyrans, not hydrogenated in the carbocyclic ring other than with oxygen or sulphur atoms in position 2 or 4 with nitrogen atoms directly attached in position 4
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/44—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
- A01N37/50—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids the nitrogen atom being doubly bound to the carbon skeleton
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/06—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings
- A01N43/08—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings with oxygen as the ring hetero atom
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/14—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings
- A01N43/16—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings with oxygen as the ring hetero atom
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/20—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom three- or four-membered rings
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C251/00—Compounds containing nitrogen atoms doubly-bound to a carbon skeleton
- C07C251/32—Oximes
- C07C251/34—Oximes with oxygen atoms of oxyimino groups bound to hydrogen atoms or to carbon atoms of unsubstituted hydrocarbon radicals
- C07C251/44—Oximes with oxygen atoms of oxyimino groups bound to hydrogen atoms or to carbon atoms of unsubstituted hydrocarbon radicals with the carbon atom of at least one of the oxyimino groups being part of a ring other than a six-membered aromatic ring
- C07C251/46—Quinone oximes
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C251/00—Compounds containing nitrogen atoms doubly-bound to a carbon skeleton
- C07C251/32—Oximes
- C07C251/50—Oximes having oxygen atoms of oxyimino groups bound to carbon atoms of substituted hydrocarbon radicals
- C07C251/52—Oximes having oxygen atoms of oxyimino groups bound to carbon atoms of substituted hydrocarbon radicals of hydrocarbon radicals substituted by halogen atoms or by nitro or nitroso groups
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D305/00—Heterocyclic compounds containing four-membered rings having one oxygen atom as the only ring hetero atoms
- C07D305/02—Heterocyclic compounds containing four-membered rings having one oxygen atom as the only ring hetero atoms not condensed with other rings
- C07D305/04—Heterocyclic compounds containing four-membered rings having one oxygen atom as the only ring hetero atoms not condensed with other rings having no double bonds between ring members or between ring members and non-ring members
- C07D305/08—Heterocyclic compounds containing four-membered rings having one oxygen atom as the only ring hetero atoms not condensed with other rings having no double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
- C07D307/77—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom ortho- or peri-condensed with carbocyclic rings or ring systems
- C07D307/87—Benzo [c] furans; Hydrogenated benzo [c] furans
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D311/00—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only hetero atom, condensed with other rings
- C07D311/02—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only hetero atom, condensed with other rings ortho- or peri-condensed with carbocyclic rings or ring systems
- C07D311/76—Benzo[c]pyrans
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Furan Compounds (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
- Plural Heterocyclic Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Pyridine Compounds (AREA)
Abstract
derivados de 2-[(4-metóxi-imino-tetralin-6-il]prop-2-enoato de metila, seus análogos de cromano, isocromano, 6,7,8,9-tetra-hidrobenzo[7]anuleno, 1h-isobenzofurano e indano, e compostos similares, como fungicidas agroquímicos. compostos de fórmula (i): (fórmula (i)) a fórmula (i) abrange, por exemplo, derivados de tetralina, cromano, isocromano, 6,7,8,9-tetra-hidrobenzo[7]anuleno, 1h-isobenzofurano e indanos. os compostos de fórmula (i) são úteis como pesticidas, especialmente como fungicidas. a presente descrição revela a síntese e a caracterização de compostos exemplificativos, bem como seus dados biológicos (por exemplo, páginas 53 a 78; exemplos 1 a 10; tabela t1; compostos 1.1 a 1.54; exemplos a e b). os compostos preferidos são, por exemplo: (e)-3-metóxi-2-[(4e)-4-metóxi-imino-7-metil-tetralin-6-il]prop-2-enoato de metila (exemplo 2; composto 1.6 da tabela t1): (fórmula (a)) (e)-3-metóxi-2-[(4z)-4-metóxi-iminoisocroman-6-il]prop-2- enoato de metila (exemplo 6; composto 1.39 da tabela t1): (fórmula (b))methyl 2-[(4-methoxy-imino-tetralin-6-yl]prop-2-enoate derivatives, their chroman analogues, isochroman, 6,7,8,9-tetrahydrobenzo[7]annulene, 1h -isobenzofuran and indane, and similar compounds such as agrochemical fungicides compounds of formula (i): (formula (i)) formula (i) encompasses, for example, derivatives of tetralin, chroman, isochroman, 6,7,8, 9-Tetrahydrobenzo[7]annulene, 1h-isobenzofuran and indanes. The compounds of formula (I) are useful as pesticides, especially as fungicides. The present description discloses the synthesis and characterization of exemplary compounds, as well as their biological data (e.g. pages 53 to 78; examples 1 to 10; table t1; compounds 1.1 to 1.54; examples a and b). Preferred compounds are, for example: (e)-3-methoxy-2-[(4e)-4 methyl-methoxy-imino-7-methyl-tetralin-6-yl]prop-2-enoate (example 2; compound 1.6 of table t1): (formula (a)) (e)-3-methoxy-2-[ Methyl (4z)-4-methoxyiminoisochroman-6-yl]prop-2-enoate (Example 6; compound 1.39 of tab she t1): (formula (b))
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GBGB1910037.9A GB201910037D0 (en) | 2019-07-12 | 2019-07-12 | Microbiocidal compounds |
PCT/EP2020/069509 WO2021009026A1 (en) | 2019-07-12 | 2020-07-10 | Methyl 2-[(4-methoxyimino-tetralin-6-yl]prop-2-enoate derivatives, chromane, isochromane, 6,7,8,9-tetrahydrobenzo[7]annulene, 1h-isobenzofurane and indane analogues thereof, and similar compounds, as agrochemical fungicides |
Publications (1)
Publication Number | Publication Date |
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BR112022000493A2 true BR112022000493A2 (en) | 2022-05-24 |
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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BR112022000493A BR112022000493A2 (en) | 2019-07-12 | 2020-07-10 | Methyl 2-[(4-methoxy-imino-tetralin-6-yl]prop-2-enoate derivatives, their chroman analogues, isochroman, 6,7,8,9-tetrahydrobenzo[7]annulene, 1h -isobenzofuran and indane, and similar compounds such as agrochemical fungicides |
Country Status (5)
Country | Link |
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AR (1) | AR119355A1 (en) |
BR (1) | BR112022000493A2 (en) |
GB (1) | GB201910037D0 (en) |
UY (1) | UY38778A (en) |
WO (1) | WO2021009026A1 (en) |
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MX2017012195A (en) | 2015-03-27 | 2018-01-09 | Syngenta Participations Ag | Microbiocidal heterobicyclic derivatives. |
MX2017012709A (en) | 2015-04-02 | 2017-11-23 | Bayer Cropscience Ag | Novel 5-substituted imidazole derivatives. |
LT3307707T (en) | 2015-06-15 | 2021-01-11 | Syngenta Crop Protection Ag | Halogen-substituted phenoxyphenylamidines and the use thereof as fungicides |
AR105640A1 (en) | 2015-08-12 | 2017-10-25 | Syngenta Participations Ag | MICROBICIDE HETEROBICYCLIC DERIVATIVES |
TN2018000054A1 (en) | 2015-08-14 | 2019-07-08 | Bayer Cropscience Ag | Triazole derivatives, intermediates thereof and their use as fungicides. |
HUE050030T2 (en) | 2015-10-02 | 2020-11-30 | Syngenta Participations Ag | Microbiocidal oxadiazole derivatives |
CN108137517B (en) | 2015-10-02 | 2022-04-12 | 先正达参股股份有限公司 | Microbicidal oxadiazole derivatives |
WO2017093348A1 (en) | 2015-12-02 | 2017-06-08 | Syngenta Participations Ag | Microbiocidal oxadiazole derivatives |
UY37062A (en) | 2016-01-08 | 2017-08-31 | Syngenta Participations Ag | DERIVATIVES OF ARYL OXADIAZOL FUNGICIDAS |
CR20180434A (en) | 2016-03-10 | 2018-11-21 | Syngenta Participations Ag | MICROBIOCIDE DERIVATIVES OF TYPE (UNCLE) CARBOXAMIDE OF QUINOLINE |
AR108745A1 (en) | 2016-06-21 | 2018-09-19 | Syngenta Participations Ag | MICROBIOCIDES OXADIAZOL DERIVATIVES |
ES2862453T3 (en) | 2016-10-06 | 2021-10-07 | Syngenta Participations Ag | Microbiocide oxadiazole derivatives |
WO2018153707A1 (en) | 2017-02-22 | 2018-08-30 | Basf Se | Crystalline forms of a strobilurin type compound for combating phytopathogenic fungi |
UY37623A (en) | 2017-03-03 | 2018-09-28 | Syngenta Participations Ag | DERIVATIVES OF OXADIAZOL THIOPHEN FUNGICIDES |
EA201992550A1 (en) | 2017-05-02 | 2020-04-14 | Басф Се | FUNGICIDIC MIXTURES CONTAINING SUBSTITUTED 3-PHENYL-5- (TRIFFORMETHYL) -1,2,4-OXADIAZOZOLES |
EP3638032A1 (en) | 2017-06-14 | 2020-04-22 | Syngenta Participations AG | Fungicidal compositions |
BR112020011083A2 (en) | 2017-12-04 | 2020-11-17 | Syngenta Participations Ag | microbiocidal phenylamidine derivatives |
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2019
- 2019-07-12 GB GBGB1910037.9A patent/GB201910037D0/en not_active Ceased
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2020
- 2020-07-06 AR ARP200101902A patent/AR119355A1/en unknown
- 2020-07-10 WO PCT/EP2020/069509 patent/WO2021009026A1/en active Application Filing
- 2020-07-10 UY UY0001038778A patent/UY38778A/en unknown
- 2020-07-10 BR BR112022000493A patent/BR112022000493A2/en unknown
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AR119355A1 (en) | 2021-12-15 |
UY38778A (en) | 2021-02-26 |
GB201910037D0 (en) | 2019-08-28 |
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