BR112019000025A2 - flame retardant mixtures, production and use thereof - Google Patents
flame retardant mixtures, production and use thereofInfo
- Publication number
- BR112019000025A2 BR112019000025A2 BR112019000025-9A BR112019000025A BR112019000025A2 BR 112019000025 A2 BR112019000025 A2 BR 112019000025A2 BR 112019000025 A BR112019000025 A BR 112019000025A BR 112019000025 A2 BR112019000025 A2 BR 112019000025A2
- Authority
- BR
- Brazil
- Prior art keywords
- flame retardant
- production
- retardant mixtures
- component
- relates
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K21/00—Fireproofing materials
- C09K21/06—Organic materials
- C09K21/12—Organic materials containing phosphorus
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/20—Compounding polymers with additives, e.g. colouring
- C08J3/203—Solid polymers with solid and/or liquid additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/0066—Flame-proofing or flame-retarding additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/53—Phosphorus bound to oxygen bound to oxygen and to carbon only
- C08K5/5313—Phosphinic compounds, e.g. R2=P(:O)OR'
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/53—Phosphorus bound to oxygen bound to oxygen and to carbon only
- C08K5/5377—Phosphinous compounds, e.g. R2=P—OR'
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/53—Phosphorus bound to oxygen bound to oxygen and to carbon only
- C08K5/5393—Phosphonous compounds, e.g. R—P(OR')2
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K21/00—Fireproofing materials
- C09K21/02—Inorganic materials
- C09K21/04—Inorganic materials containing phosphorus
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
- C08K2003/321—Phosphates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
- C08K2003/321—Phosphates
- C08K2003/328—Phosphates of heavy metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/38—Boron-containing compounds
- C08K2003/387—Borates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/005—Additives being defined by their particle size in general
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/006—Additives being defined by their surface area
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/01—Use of inorganic substances as compounding ingredients characterized by their specific function
- C08K3/016—Flame-proofing or flame-retarding additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/38—Boron-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/52—Phosphorus bound to oxygen only
- C08K5/5205—Salts of P-acids with N-bases
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/02—Fibres or whiskers
- C08K7/04—Fibres or whiskers inorganic
- C08K7/14—Glass
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/30—Flame or heat resistance, fire retardancy properties
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Inorganic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Fireproofing Substances (AREA)
Abstract
a presente invenção refere-se a uma mistura retardante de chama compreendendo: 99,9999% a 87% em peso de sais de ácido diorganilfosfínico como componente a) e 0,0001% a 13% em peso de ferro como componente b), onde a soma total de a) e b) é de 100% em peso. a invenção refere-se igualmente a métodos para a produção da mistura retardante de chama acima mencionada e ao seu uso.The present invention relates to a flame retardant mixture comprising: 99.9999 wt.% to 87 wt.% diorganylphosphinic acid salts as component a) and 0.0001 wt.% to 13 wt.% iron as component b), where the total sum of a) and b) is 100% by weight. The invention also relates to methods for producing the abovementioned flame retardant mixture and its use.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102016213282.2A DE102016213282A1 (en) | 2016-07-20 | 2016-07-20 | Flame retardant mixtures, their preparation and their use |
DE102016213282.2 | 2016-07-20 | ||
PCT/EP2017/067611 WO2018015253A1 (en) | 2016-07-20 | 2017-07-12 | Flame retardant mixtures, the production and the use thereof |
Publications (3)
Publication Number | Publication Date |
---|---|
BR112019000025A2 true BR112019000025A2 (en) | 2019-04-02 |
BR112019000025A8 BR112019000025A8 (en) | 2022-08-30 |
BR112019000025B1 BR112019000025B1 (en) | 2022-12-06 |
Family
ID=59366419
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BR112019000025-9A BR112019000025B1 (en) | 2016-07-20 | 2017-07-12 | FLAME RETARDANT MIXTURES, THEIR PRODUCTION METHODS, USES AND FLAME PROTECTED POLYMER MOLDING COMPOUNDS INCLUDING THEM |
Country Status (16)
Country | Link |
---|---|
US (1) | US11028324B2 (en) |
EP (1) | EP3487957B1 (en) |
JP (1) | JP6903733B2 (en) |
KR (1) | KR102497369B1 (en) |
CN (1) | CN107637605B (en) |
BR (1) | BR112019000025B1 (en) |
DE (1) | DE102016213282A1 (en) |
HK (1) | HK1245014A1 (en) |
MX (1) | MX2019000638A (en) |
MY (1) | MY191160A (en) |
PL (1) | PL3487957T3 (en) |
RU (1) | RU2019104539A (en) |
SG (1) | SG11201811638QA (en) |
TW (1) | TWI789354B (en) |
WO (1) | WO2018015253A1 (en) |
ZA (1) | ZA201808505B (en) |
Families Citing this family (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102016213281A1 (en) * | 2016-07-20 | 2018-01-25 | Clariant Plastics & Coatings Ltd | Flame retardant mixtures, their preparation and their use |
DE102016213282A1 (en) | 2016-07-20 | 2018-01-25 | Clariant Plastics & Coatings Ltd | Flame retardant mixtures, their preparation and their use |
DE102016221063B4 (en) * | 2016-10-26 | 2021-09-16 | BSH Hausgeräte GmbH | Household appliance with at least one plug for an electrical connection |
DE102017221039B4 (en) * | 2017-11-24 | 2020-09-03 | Tesa Se | Process for the production of a pressure sensitive adhesive based on acrylonitrile-butadiene rubber |
CN109337512B (en) * | 2018-09-30 | 2020-08-11 | 长春顺风新材料有限公司 | Environment-friendly water-soluble coating and preparation method thereof |
KR102006439B1 (en) * | 2019-01-16 | 2019-08-01 | (주)미산알앤씨 | Multi-Functional Spontaneous ignition inhibiting Foam Concentrate for bituminous coal |
CN110540691A (en) * | 2019-09-06 | 2019-12-06 | 安徽长远机电股份有限公司 | Powerful anti-crack cable plug material and preparation method thereof |
CN110819201A (en) * | 2019-11-25 | 2020-02-21 | 广西凯威铁塔有限公司 | Flame-retardant anticorrosive paint for outdoor power equipment and preparation method thereof |
KR102204944B1 (en) * | 2020-09-18 | 2021-01-21 | 이경윤 | Composition for Electric Wire and Cable with enhanced Flame Retardant |
RU2746013C1 (en) * | 2020-09-29 | 2021-04-05 | Акционерное общество Киембаевский горно-обогатительный комбинат "Оренбургские минералы" | Fire retardant composition for metal structures |
CN112210118B (en) * | 2020-10-12 | 2022-05-17 | 江苏利思德新材料有限公司 | High-heat-resistant high-shear-resistant high-flame-retardant halogen-free flame-retardant compound system and application thereof |
KR102521133B1 (en) | 2021-09-14 | 2023-04-13 | 군산대학교산학협력단 | Non-flammable electrolyte for the supercapacitor and the supercapacitor including the same |
CN114350948B (en) * | 2022-01-17 | 2022-10-04 | 中南大学 | Alpha-hydroxy-2-ethylhexyl phosphinic acid extractant, preparation method and application thereof |
WO2023215434A1 (en) * | 2022-05-06 | 2023-11-09 | Celanese International Corporation | Fiber reinforced thermoplastic polymer composition with flame retardant properties |
CN115232166B (en) * | 2022-08-16 | 2024-03-26 | 浙江工业大学 | Halogen-free flame-retardant antioxidant organic copper salt and preparation method and application thereof |
WO2024168827A1 (en) * | 2023-02-17 | 2024-08-22 | 中国科学院宁波材料技术与工程研究所 | Dialkylphosphinate composition, and preparation method therefor and use thereof |
Family Cites Families (23)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3450407A (en) | 1967-01-26 | 1969-06-17 | Albert J Russo | Anti-fumble trainer football |
DE10359814A1 (en) | 2003-12-19 | 2005-07-28 | Clariant Gmbh | Dialkylphosphinic salts |
DE10359815A1 (en) | 2003-12-19 | 2005-07-28 | Clariant Gmbh | Process for the preparation of dialkylphosphinic salts |
JP4581642B2 (en) * | 2004-11-18 | 2010-11-17 | 日立化成工業株式会社 | Metal-clad laminate and printed wiring board |
RU2541527C2 (en) | 2009-10-27 | 2015-02-20 | Басф Се | Heat aging-resistant polyamides with flame retardance |
DE102010018684A1 (en) | 2010-04-29 | 2011-11-03 | Clariant International Ltd. | Process for the preparation of mixtures of alkylphosphonous salts and dialkylphosphinic acid salts |
CN102092754B (en) | 2010-12-23 | 2012-08-15 | 内蒙古昶泰资源循环再生利用科技开发有限责任公司 | Method for removing impurity iron in aluminum sulfate solution through ion exchange |
TWI519634B (en) | 2011-01-25 | 2016-02-01 | Kaneka Corp | Flame retardant resin composition |
CN103665779B (en) | 2012-09-06 | 2016-06-01 | 杜邦公司 | Fire retardant copolyetherester compositions and the article comprising it |
CN103897215B (en) * | 2012-12-26 | 2016-08-24 | 金发科技股份有限公司 | A kind of composite flame-retardant agent and application thereof |
CN103172670B (en) | 2013-03-04 | 2015-09-30 | 广州金凯新材料有限公司 | A kind of monoalkyl/dialkylphosphinic salts and preparation method thereof |
CN104250440A (en) | 2013-06-28 | 2014-12-31 | 杜邦公司 | Flame-retardant polymer composition |
US20150183991A1 (en) * | 2013-11-20 | 2015-07-02 | Asahi Kasei Chemicals Corporation | Flame-retardant thermoplastic resin composition and molded article of the same |
CN103788125B (en) * | 2013-12-31 | 2015-02-11 | 邓娟 | Additive for polymer and preparation method for additive |
DE102014001222A1 (en) * | 2014-01-29 | 2015-07-30 | Clariant lnternational Ltd | Halogen-free solid flame retardant mixture and its use |
JP6335324B2 (en) | 2014-04-01 | 2018-05-30 | 中国科学院寧波材料技術与工程研究所 | Production method and product of dialkylphosphinate |
DE102015003825A1 (en) | 2015-03-25 | 2016-09-29 | Clariant International Ltd. | The invention relates to flame retardant mixtures and their preparation |
CN105061500A (en) | 2015-07-27 | 2015-11-18 | 广州金凯新材料有限公司 | Superfine particle size dialkylphosphinate, preparation method and applications thereof, and high polymer composition comprising dialkylphosphinate |
CN106423806B (en) | 2015-07-27 | 2021-05-28 | 斯凯孚公司 | Method for producing coatings |
DE102016203221A1 (en) * | 2016-02-29 | 2017-08-31 | Clariant Plastics & Coatings Ltd | Flame retardant polyamide composition |
DE102016213280B4 (en) | 2016-07-20 | 2024-03-07 | Clariant International Ltd | Diorganylphosphinic acid salts, a process for their preparation and their use |
DE102016213281A1 (en) * | 2016-07-20 | 2018-01-25 | Clariant Plastics & Coatings Ltd | Flame retardant mixtures, their preparation and their use |
DE102016213282A1 (en) | 2016-07-20 | 2018-01-25 | Clariant Plastics & Coatings Ltd | Flame retardant mixtures, their preparation and their use |
-
2016
- 2016-07-20 DE DE102016213282.2A patent/DE102016213282A1/en not_active Withdrawn
- 2016-10-17 CN CN201611272753.3A patent/CN107637605B/en active Active
-
2017
- 2017-06-07 TW TW106118921A patent/TWI789354B/en active
- 2017-07-12 EP EP17740723.6A patent/EP3487957B1/en active Active
- 2017-07-12 KR KR1020197004956A patent/KR102497369B1/en active IP Right Grant
- 2017-07-12 MX MX2019000638A patent/MX2019000638A/en unknown
- 2017-07-12 BR BR112019000025-9A patent/BR112019000025B1/en active IP Right Grant
- 2017-07-12 JP JP2019502082A patent/JP6903733B2/en active Active
- 2017-07-12 SG SG11201811638QA patent/SG11201811638QA/en unknown
- 2017-07-12 RU RU2019104539A patent/RU2019104539A/en not_active Application Discontinuation
- 2017-07-12 US US16/318,526 patent/US11028324B2/en active Active
- 2017-07-12 WO PCT/EP2017/067611 patent/WO2018015253A1/en unknown
- 2017-07-12 PL PL17740723.6T patent/PL3487957T3/en unknown
- 2017-07-12 MY MYPI2018003064A patent/MY191160A/en unknown
-
2018
- 2018-04-06 HK HK18104534.5A patent/HK1245014A1/en unknown
- 2018-12-18 ZA ZA2018/08505A patent/ZA201808505B/en unknown
Also Published As
Publication number | Publication date |
---|---|
EP3487957A1 (en) | 2019-05-29 |
ZA201808505B (en) | 2019-08-28 |
JP2019527746A (en) | 2019-10-03 |
MY191160A (en) | 2022-06-03 |
BR112019000025B1 (en) | 2022-12-06 |
MX2019000638A (en) | 2019-04-22 |
CN107637605A (en) | 2018-01-30 |
EP3487957B1 (en) | 2023-04-12 |
DE102016213282A1 (en) | 2018-01-25 |
KR20190032462A (en) | 2019-03-27 |
RU2019104539A (en) | 2020-08-21 |
HK1245014A1 (en) | 2018-08-24 |
KR102497369B1 (en) | 2023-02-10 |
CN107637605B (en) | 2021-01-05 |
PL3487957T3 (en) | 2023-09-11 |
US11028324B2 (en) | 2021-06-08 |
JP6903733B2 (en) | 2021-07-14 |
TWI789354B (en) | 2023-01-11 |
SG11201811638QA (en) | 2019-02-27 |
TW201815928A (en) | 2018-05-01 |
BR112019000025A8 (en) | 2022-08-30 |
WO2018015253A1 (en) | 2018-01-25 |
US20190316039A1 (en) | 2019-10-17 |
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