BR112018007776A2 - heterophasic propylene copolymers - Google Patents
heterophasic propylene copolymersInfo
- Publication number
- BR112018007776A2 BR112018007776A2 BR112018007776-3A BR112018007776A BR112018007776A2 BR 112018007776 A2 BR112018007776 A2 BR 112018007776A2 BR 112018007776 A BR112018007776 A BR 112018007776A BR 112018007776 A2 BR112018007776 A2 BR 112018007776A2
- Authority
- BR
- Brazil
- Prior art keywords
- propylene copolymers
- heterophasic propylene
- soluble fraction
- xylene soluble
- polypropylene composition
- Prior art date
Links
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/04—Monomers containing three or four carbon atoms
- C08F10/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/001—Multistage polymerisation processes characterised by a change in reactor conditions without deactivating the intermediate polymer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
- C08F210/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/647—Catalysts containing a specific non-metal or metal-free compound
- C08F4/649—Catalysts containing a specific non-metal or metal-free compound organic
- C08F4/6491—Catalysts containing a specific non-metal or metal-free compound organic hydrocarbon
- C08F4/6492—Catalysts containing a specific non-metal or metal-free compound organic hydrocarbon containing aliphatic unsaturation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
- C08F4/652—Pretreating with metals or metal-containing compounds
- C08F4/657—Pretreating with metals or metal-containing compounds with metals or metal-containing compounds, not provided for in groups C08F4/653 - C08F4/656
- C08F4/6574—Pretreating with metals or metal-containing compounds with metals or metal-containing compounds, not provided for in groups C08F4/653 - C08F4/656 and magnesium or compounds thereof
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/16—Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
- C08F2500/12—Melt flow index or melt flow ratio
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
- C08F2500/17—Viscosity
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/02—Heterophasic composition
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2308/00—Chemical blending or stepwise polymerisation process with the same catalyst
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Materials Engineering (AREA)
- Engineering & Computer Science (AREA)
- Crystallography & Structural Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Graft Or Block Polymers (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
trata-se de uma composição de polipropileno que compreende: a) de 50% em peso a 90% em peso de um homopolímero de propileno; b) de 10% em peso a 50% em peso de um copolímero de propileno com de 30,0% em peso a 70,0% em peso de unidades derivadas de etileno; em que a soma da quantidade de componente a) e b) é 100; e sendo que a composição tem: i) uma viscosidade intrínseca da fração solúvel em xileno a 25°c compreendida entre 2,2 e 4,0 dl/g; ii) uma mfr l (taxa de fluxo de massa do fundido de acordo com iso 1133, condição l, isto é, 230°c e 2,16 kg de carga) de 0,5 a 100 g/10 min; iii) uma fração solúvel em xileno que varia de 20% em peso a 50% em peso; sendo que a composição de polipropileno é obtida por um processo de polimerização em duas etapas em que o sistema de catalisador contém bismuto.It is a polypropylene composition comprising: a) from 50 wt% to 90 wt% of a propylene homopolymer; b) from 10 wt% to 50 wt% of a propylene copolymer with from 30.0 wt% to 70.0 wt% of ethylene derived units; wherein the sum of the quantity of component a) and b) is 100; and wherein the composition has: i) an intrinsic viscosity of the xylene soluble fraction at 25 ° C comprised between 2.2 and 4.0 dl / g; (ii) an mfr l (melt mass flow rate according to iso 1133, condition 1, ie 230 ° c and 2,16 kg load) of 0,5 to 100 g / 10 min; iii) a xylene soluble fraction ranging from 20 wt% to 50 wt%; wherein the polypropylene composition is obtained by a two step polymerization process wherein the catalyst system contains bismuth.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP15193228 | 2015-11-05 | ||
EP15193228.2 | 2015-11-05 | ||
PCT/EP2016/075684 WO2017076701A1 (en) | 2015-11-05 | 2016-10-25 | Heterophasic propylene copolymers |
Publications (2)
Publication Number | Publication Date |
---|---|
BR112018007776A2 true BR112018007776A2 (en) | 2018-10-30 |
BR112018007776B1 BR112018007776B1 (en) | 2022-08-09 |
Family
ID=54478602
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BR112018007776-3A BR112018007776B1 (en) | 2015-11-05 | 2016-10-25 | POLYPROPYLENE COMPOSITION AND AUTOMOTIVE INTERNAL ELEMENT INCLUDING THE SUCH COMPOSITION |
Country Status (7)
Country | Link |
---|---|
US (1) | US10316122B2 (en) |
EP (1) | EP3371255B1 (en) |
KR (1) | KR101963095B1 (en) |
CN (1) | CN108137888B (en) |
BR (1) | BR112018007776B1 (en) |
RU (1) | RU2721529C2 (en) |
WO (1) | WO2017076701A1 (en) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BR112019022774B1 (en) * | 2017-05-30 | 2023-03-07 | Basell Poliolefine Italia S.R.L | COMPOSITION OF POLYPROPYLENE AND AUTOMOTIVE INTERNAL ELEMENT COMPRISING IT |
CN111051422B (en) * | 2017-09-14 | 2021-01-26 | 巴塞尔聚烯烃意大利有限公司 | Permeable polymeric membrane |
US11834534B2 (en) | 2018-08-22 | 2023-12-05 | Basell Poliolefine Italia S.R.L. | Random propylene-ethylene copolymers |
CN115244124A (en) * | 2020-03-30 | 2022-10-25 | 巴塞尔聚烯烃意大利有限公司 | Propylene polymer composition |
BR112022024717A2 (en) * | 2020-06-30 | 2023-01-31 | Basell Poliolefine Italia Srl | COMPOSITION OF POLYPROPYLENE AND FOAMED ARTICLES |
JP2022064308A (en) * | 2020-10-13 | 2022-04-25 | ハンファ トータル ペトロケミカル カンパニー リミテッド | Polypropylene resin composition excellent in melt flowability and impact resistance |
Family Cites Families (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
IT1096661B (en) | 1978-06-13 | 1985-08-26 | Montedison Spa | PROCEDURE FOR THE PREPARATION OF SOLID SPHEROIDAL PRODUCTS AT AMBIENT TEMPERATURE |
IT1098272B (en) | 1978-08-22 | 1985-09-07 | Montedison Spa | COMPONENTS, CATALYSTS AND CATALYSTS FOR THE POLYMERIZATION OF ALPHA-OLEFINS |
IL127230A (en) | 1997-03-29 | 2004-07-25 | Montell Technology Company Bv | Magnesium dichloride-alcohol adducts, process for their preparation and catalyst components obtained therefrom |
BR9907139B1 (en) * | 1998-11-03 | 2008-11-18 | polyolefin composition and retainers produced from said composition. | |
TW200505985A (en) * | 2003-08-07 | 2005-02-16 | Basell Poliolefine Spa | Polyolefin composition having a high balance of stiffness and impact strength |
EP2062937A1 (en) * | 2007-11-26 | 2009-05-27 | Total Petrochemicals Research Feluy | Heterophasic propylene copolymer for corrugated sheet and cast film applications |
EP2077286A1 (en) * | 2008-01-07 | 2009-07-08 | Total Petrochemicals Research Feluy | Heterophasic propylene copolymer with improved creep behavior |
EP2108679A1 (en) * | 2008-04-10 | 2009-10-14 | Borealis Technology Oy | Low emission polymer composition |
US20120115995A1 (en) * | 2009-06-22 | 2012-05-10 | Klaus Lederer | Automotive interior article with reduced smell |
ES2479665T3 (en) * | 2009-11-19 | 2014-07-24 | Basell Poliolefine Italia S.R.L. | Process for the preparation of propylene polymer compositions, with impact resistance |
BR112013001644A2 (en) * | 2010-07-23 | 2016-05-24 | Basell Poliolefine Srl | propylene polymer compositions. |
BR112013008076B1 (en) | 2010-10-14 | 2020-06-09 | Basell Poliolefine Italia Srl | element for the automotive interior and use of a polypropylene composition |
EP2781548A1 (en) | 2013-03-19 | 2014-09-24 | Basell Poliolefine Italia S.r.l. | Mineral-filled polypropylene composition |
KR102138986B1 (en) * | 2014-03-14 | 2020-07-29 | 바셀 폴리올레핀 이탈리아 에스.알.엘 | Catalyst components for the polymerization of olefins |
-
2016
- 2016-10-25 KR KR1020187013245A patent/KR101963095B1/en active IP Right Grant
- 2016-10-25 EP EP16787818.0A patent/EP3371255B1/en active Active
- 2016-10-25 WO PCT/EP2016/075684 patent/WO2017076701A1/en active Application Filing
- 2016-10-25 US US15/768,875 patent/US10316122B2/en active Active
- 2016-10-25 BR BR112018007776-3A patent/BR112018007776B1/en active IP Right Grant
- 2016-10-25 CN CN201680061573.2A patent/CN108137888B/en active Active
- 2016-10-25 RU RU2018117616A patent/RU2721529C2/en active
Also Published As
Publication number | Publication date |
---|---|
WO2017076701A1 (en) | 2017-05-11 |
US10316122B2 (en) | 2019-06-11 |
RU2018117616A3 (en) | 2020-01-15 |
RU2721529C2 (en) | 2020-05-19 |
KR20180066195A (en) | 2018-06-18 |
CN108137888A (en) | 2018-06-08 |
CN108137888B (en) | 2020-04-10 |
EP3371255B1 (en) | 2019-07-24 |
US20190055333A1 (en) | 2019-02-21 |
BR112018007776B1 (en) | 2022-08-09 |
EP3371255A1 (en) | 2018-09-12 |
KR101963095B1 (en) | 2019-03-27 |
RU2018117616A (en) | 2019-11-14 |
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B06U | Preliminary requirement: requests with searches performed by other patent offices: procedure suspended [chapter 6.21 patent gazette] | ||
B06A | Patent application procedure suspended [chapter 6.1 patent gazette] | ||
B09A | Decision: intention to grant [chapter 9.1 patent gazette] | ||
B16A | Patent or certificate of addition of invention granted [chapter 16.1 patent gazette] |
Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 18/04/2018, OBSERVADAS AS CONDICOES LEGAIS |