BR112017015526B1 - cosmetic composition for the oxidation dyeing of keratin fibers, process for the dyeing of human keratin fibers and kit for the oxidation dyeing of keratin fibers - Google Patents

Abstract

A cosmetic composition for the oxidation dyeing of keratin fibers comprising one or more oxidation dyes, one or more cationic polymers, one or more amphoteric or zwitterionic surfactants, one or more nonionic surfactants selected from C6-C30 fatty acid alkanolamides, and one or more anionic surfactants in an amount of at least 1.5% by weight, with respect to the total weight of the composition. A process for dyeing keratin fibers using the composition and a suitable kit for implementing such a process are also provided.

Description

[001] The present invention relates to a cosmetic composition for the oxidation dyeing of keratin fibers, in particular human keratin fibers such as hair.

[002] More precisely, the object of the present invention is a cosmetic dyeing composition comprising one or more oxidation dyes, one or more cationic polymers and a particular combination of surfactants.

[003] The present invention also relates to a process for dyeing keratin fibers, in particular human keratin fibers such as hair, using the composition according to the invention.

[004] Finally, the present invention relates to a kit for the oxidation dyeing of keratin fibers, which is suitable for carrying out the process of the invention.

[005] Many people have been looking for a long time to change the color of their hair and, in particular, dye it, for example, in order to mask their gray hair.

[006] "Permanent" dyeing methods also known as oxidation dyeing, which utilize dye compositions containing oxidation dye precursors, commonly referred to as oxidation bases, such as ortho- or para-phenylenediamines, ortho- or para- aminophenols and heterocyclic compounds, were developed for dyeing human keratin fibers in a long-lasting way. These oxidation bases are colorless or weakly colored compounds which, when combined with oxidizing products, can give rise to colored compounds through an oxidative condensation process.

[007] It is also known that the tones obtained with these oxidation bases can be varied by combining them with couplers or color modifiers, the latter being specially selected from aromatic meta-diaminobenzenes, meta-aminophenols, meta-diphenols and certain heterocyclic compounds such as indole compounds.

[008] As an example of compositions known in the prior art, mention can be made of WO 2011/138838 which discloses a ready-to-use composition for the oxidation dyeing of keratin fibers comprising, in an aqueous medium, at least one dye of oxidation, at least one oxidizing agent and at least 1.5% by weight of at least one amphoteric surfactant.

[009] However, prior art compositions are not entirely satisfactory, and their performance qualities can be further improved, in particular with regard to working qualities (whether or not the composition is mixed with an oxidizing composition before of application), especially in terms of texture, ease of application and ease of spreading the composition over the keratin fibers. Furthermore, prior art compositions are not always sufficiently stable, and their coloring performances can also be further improved, especially in terms of intensity, homogeneity and selectivity of the dyeing obtained.

[0010] The Applicant has now found that the use of a cationic polymer together with a particular combination of surfactants makes it possible to obtain a cosmetic composition for the oxidation dyeing of keratin fibers, which can overcome the above disadvantages and which has other improved properties .

[0011] An object of the present invention is therefore a cosmetic composition for the oxidation dyeing of keratin fibers comprising: a) one or more oxidation dyes, b) one or more cationic polymers, c) one or more amphoteric surfactants or zwitterionics, d) one or more nonionic surfactants selected from C6-C30 fatty acid alkanolamides, and e) one or more anionic surfactants, in an amount of at least 1.5% by weight, relative to the total weight of the composition.

[0012] The composition according to the invention has excellent working qualities, and especially a particularly pleasant texture and a good viscosity (neither too thick nor too fluid, which facilitates its use). This property is very stable over time and does not decrease even after several months of storage at room temperature (25°C), as well as from low temperatures (such as 4°C) to high temperatures (such as 45°C).

[0013] The composition also has excellent foaming properties similar to those of a shampoo, whether or not mixed with a developer (or oxidizing) composition, and is very easy to apply and spread over hair tufts, in particular from the roots to the the ends. More particularly, the composition of the present invention allows for easy and quick foaming, such as immediately after hair massage. The foam is firm and creamy and allows for good dyeing performance. What's more, the foam stays on the hair without flying away.

[0014] Furthermore, the composition of the invention does not require pre-mixing with a developer composition or oxidizing or oxidizing composition. It allows it to be used simultaneously with a developer or oxidizer directly on the hair, without a pre-mix step.

[0015] Furthermore, it does not run and remains well localized at the application points, in particular at the roots, although it is very easy to rinse from the hair after application.

[0016] Furthermore, the composition of the invention has very good cosmetic properties and provides keratin fibers with excellent conditioning. In particular, after dyeing with such a composition, the hair becomes shiny, smooth, malleable and easy to disentangle.

[0017] Finally, the composition according to the invention has superior dyeing quality, especially in terms of intensity, homogeneity and selectivity of the dyeing obtained.

[0018] The composition of the invention is intended to be used in a process for dyeing keratin fibers as a ready-to-use composition, when it contains an oxidizing agent, or in combination with an oxidizing composition.

[0019] An object of the invention is therefore also a process for dyeing keratin fibers, which consists of applying to the keratin fibers the composition of the invention. Said composition can be applied sequentially or simultaneously with an oxidizing composition comprising one or more oxidizing agents.

[0020] Other features and advantages of the invention will appear more clearly on reading the description and examples that follow.

[0021] In the following text, unless otherwise indicated, the limits of a range of values are included in that range. The term "at least one" associated with an ingredient of the composition means "one or more".

The terms "oxyalkylenated", "oxyethylenated", "oxypropylenated" and "glycerolated" cover, respectively, mono- or poly-oxyalkylenated, oxyethylenated, oxypropylenated and glycerolated compounds, unless specifically mentioned.

[0023] The composition of the invention is advantageously transparent. The composition's transparency can be characterized by measuring its turbidity according to the NTU method using a Hach model 2100P turbidimeter at room temperature. The turbidity of the compositions of the invention is generally less than 400 NTU units and preferably less than 250 NTU units, more preferably less than 200 NTU.

[0024] As indicated above, the composition according to the invention comprises one or more oxidation dyes.

[0025] The oxidation dyes that can be used in the present invention are generally selected from oxidation bases, optionally combined with one or more couplers.

[0026] Preferably, the oxidation dyes comprise one or more oxidation bases.

[0027] Oxidation bases can be specially selected from para-phenylenediamines, bis(phenyl)alkylenediamines, para-aminophenols, ortho-aminophenols, heterocyclic bases, and their addition salts and mixtures thereof.

Among the para-phenylenediamines, examples which may be mentioned include para-phenylenediamine, para-tolylenediamine, 2-chloro-para-phenylenediamine, 2,3-dimethyl-para-phenylenediamine, 2,6-dimethyl-para-phenylenediamine , 2,6-diethyl-para-phenylenediamine, 2,5-dimethyl-para-phenylenediamine, N,N-dimethyl-para-phenylenediamine, N,N-diethyl-para-phenylenediamine, N,N-dipropyl-para-phenylenediamine , 4-amino-N,N-diethyl-3-methylaniline, N,N-bis(β-hydroxyethyl)-para-phenylenediamine, /4-N,N-bis(β-hydroxyethyl)amino-2-methylaniline, 4 -N,N-bis(β-hydroxyethyl)amino-2-chloroaniline, 2-β-hydroxyethyl-para-phenylenediamine, 2-fluoro-para-phenylenediamine, 2-isopropyl-para-phenylenediamine, N-(β-hydroxypropyl) -para-phenylenediamine, 2-hydroxymethyl-para-phenylenediamine, N,N-dimethyl-3-methyl-para-phenylenediamine, N,N-(ethyl-β-hydroxyethyl)-para-phenylenediamine, N-(β,y- dihydroxypropyl)-para-phenylenediamine, N-(4'-aminophenyl)-para-phenylenediamine, N-phenyl-para-phenylenediamine, 2-β-hydroxyethyloxy-para-phenylene odiamine, 2-β-acetylaminoethyl0xy-para-phenylenediamine, N-(β-methoxyethyl)-para-phenylenediamine, 4-aminophenylpyrrolidine, 2-thienyl-para-phenylenediamine, 2-β-hydroxyethylamino-5-aminotoluene and 3-hydroxy- 1-(4'-aminophenyl)pyrrolidine, and its addition salts with an acid.

[0029] Among the para-phenylenediamines mentioned above, para-phenylenediamine, para-tolylenediamine, 2-isopropyl-para-phenylenediamine, 2-β-hydroxyethyl-para-phenylenediamine, 2-β-hydroxyethyloxy-para-phenylenediamine, 2,6 -dimethyl-para-phenylenediamine, 2,6-diethyl-para-phenylenediamine, 2,3-dimethyl-para-phenylenediamine, N,N-bis(β-hydroxyethyl)-para-phenylenediamine, 2-chloro-para-phenylenediamine and 2-β-acetylaminoethyloxy-para-phenylenediamine, and its addition salts with an acid, are particularly preferred.

Among the bis(phenyl)alkylenediamines, examples that may be mentioned include N,N'-bis(β-hydroxyethyl)-N,N'-bis(4'-aminophenyl)-1,3-diaminopropanol, N, N'-bis(β-hydroxyethyl)-N,N'-bis(4'-aminophenyl)ethylenediamine, N,N'-bis(4-aminophenyl)tetramethylenediamine, N,N'-bis(β-hydroxyethyl)-N ,N'-bis(4-aminophenyl)tetramethylenediamine, N,N'-bis(4-methylaminophenyl)tetramethylenediamine, N,N'-bis(ethyl)-N,N'-bis(4'-amino-3'- methylphenyl)ethylenediamine, 1,8-bis(2,5-diaminophenoxy)-3,6-dioxaoctane and their addition salts.

Among the para-aminophenols, examples that may be mentioned include para-aminophenol, 4-amino-3-methylphenol, 4-amino-3-fluorophenol, 4-amino-3-chlorophenol, 4-amino-3-hydroxymethylphenol , 4-amino-2-methylphenol, 4-amino-2-hydroxymethylphenol, 4-amino-2-methoxymethylphenol, 4-amino-2-aminomethylphenol, 4-amino-2-(β-hydroxyethylaminomethyl)phenol and 4- amino-2-fluorophenol, and its addition salts with an acid.

Among the ortho-aminophenols, examples which may be mentioned include 2-aminophenol, 2-amino-5-methylphenol, 2-amino-6-methylphenol and 5-acetamido-2-aminophenol, and their addition salts.

[0033] Among the heterocyclic bases, examples which may be mentioned include pyridine derivatives, pyrimidine derivatives and pyrazole derivatives.

Among the pyridine derivatives which may be mentioned are the compounds described, for example, in patents GB 1 026 978 and GB 1 153 196, for example, 2,5-diaminopyridine, 2-(4-methoxyphenyl)amino- 3-aminopyridine and 3,4-diaminopyridine, and their addition salts.

[0035] Other pyridine oxidation bases which are useful in the present invention are the 3-aminopyrazolo[1,5-a]pyridine oxidation bases or their addition salts described, for example, in FR patent application 2 801 308. Examples which may be mentioned include pyrazolo[1,5-a]pyrid-3-ylamine, 2-(acetylamino)pyrazolo[1,5-a]pyrid-3-ylamine, 2-(morpholin-4-yl) pyrazolo[1,5-a]pyrid-3-ylamine, 3-aminopyrazolo[1,5-a]pyridine-2-carboxylic acid, 2-methoxypyrazolo[1,5-a]pyrid-3-ylamine, (3- aminopyrazolo[1,5-a]pyrid-7-yl)methanol, 2-(3-aminopyrazolo[1,5-a]pyrid-5-yl)ethanol, 2-(3-aminopyrazolo[1,5-a] pyrid-7-yl)ethanol, (3-aminopyrazolo[1,5-a]pyrid-2-yl)methanol, 3,6-diaminopyrazolo[1,5-a]pyridine, 3,4-diaminopyrazolo[1,5 -a]pyridine, pyrazolo[1,5-a]pyridine-3,7-diamine, 7-(morpholin-4-yl)pyrazolo[1,5-a]pyrid-3-ylamine, pyrazolo[1,5- a]pyridine-3,5-diamine, 5-(morpholin-4-yl)pyrazolo[1,5-a]pyrid-3-ylamine, 2-[(3-aminopyrazolo[1,5-a]pyrid-5 -yl)(2-hydroxyethyl)amino]ethanol, 2-[(3-aminopyrazolo[ 1,5-a]pyrid-7-yl)(2-hydroxyethyl)amino]ethanol, 3-aminopyrazolo[1,5-a]pyridin-5-ol, 3-aminopyrazolo[1,5-a]pyridin-4 -ol, 3-aminopyrazolo[1,5-a]pyridin-6-ol, 3-aminopyrazolo[1,5-a]pyridin-7-ol and its addition salts.

[0036] Among the pyrimidine derivatives that may be mentioned are the compounds described, for example, in patents DE 2359399; JP 88-169571; JP 05-63124; EP 0770375 or patent application WO 96/15765 such as 2,4,5,6-tetra-aminopyrimidine, 4-hydroxy-2,5,6-triaminopyrimidine, 2-hydroxy-4,5,6-triaminopyrimidine, 2 ,4-dihydroxy-5,6-diaminopyrimidine, 2,5,6-triaminopyrimidine and their addition salts and their tautomeric forms, when a tautomeric equilibrium exists.

Among the pyrazole derivatives that may be mentioned are the compounds described in patents DE 3843892 and DE 4133957 and patent applications WO 94/08969, WO 94/08970, FR-A-2 733 749 and DE 195 43 988, for example 4,5-diamino-1-methylpyrazole, 4,5-diamino-1-(β-hydroxyethyl)pyrazole, 3,4-diaminopyrazole, 4,5-diamino-1-(4'-chlorobenzyl)pyrazole, 4,5-diamino-1,3-dimethylpyrazole, 4,5-diamino-3-methyl-1-phenylpyrazole, 4,5-diamino-1-methyl-3-phenylpyrazole, 4-amino-1,3-dimethyl- 5-hydrazinopyrazole, 1-benzyl-4,5-diamino-3-methylpyrazole, 4,5-diamino-3-tert-butyl-1-methylpyrazole, 4,5-diamino-1-tert-butyl-3-methylpyrazole, 4,5-diamino-1-(β-hydroxyethyl)-3-methylpyrazole, 4,5-diamino-1-ethyl-3-methylpyrazole, 4,5-diamino-1-ethyl-3-(4'-methoxyphenyl) pyrazole, 4,5-diamino-1-ethyl-3-hydroxymethylpyrazole, 4,5-diamino-3-hydroxymethyl-1-methylpyrazole, 4,5-diamino-3-hydroxymethyl-1-isopropylpyrazole, 4,5-diamino- 3-methyl-1-isopropylpyrazole, 4-amino-5-(2'-aminoethyl)amino-1,3-dimethylpyrazole, 3,4,5-triaminopyrazole, 1-methyl-3, 4,5-triaminopyrazole, 3,5-diamino-1-methyl-4-methylaminopyrazole and 3,5-diamino-4-(β-hydroxyethyl)amino-1-methylpyrazole, and their addition salts. 4,5-Diamino-1-(β-methoxyethyl)pyrazole can also be used.

[0038] A 4,5-diaminopyrazole will preferably be used, and even more preferably 4,5-diamino-1-(β-hydroxyethyl)pyrazole and/or a salt thereof.

[0039] Pyrazole derivatives which may also be mentioned include diamino-N,N-dihydropyrazolopyrazolones and especially those described in patent application FR-A-2 886 136, such as the following compounds and their addition salts: ,3-diamino-6,7-dihydro-1H,5H-pyrazolo[1,2-a]pyrazol-1-one, 2-amino-3-ethylamino-6,7-dihydro-1H,5H -pyrazolo[1,2-a]pyrazol-1-one, 2-amino-3-isopropylamino-6,7-dihydro-1H,5H-pyrazolo[1,2-a]pyrazol-1-one, 2 -amino-3-(pyrrolidin-1-yl)-6,7-dihydro-1H,5H-pyrazolo[1,2-a]pyrazol-1-one, 4,5-diamino-1,2-dimethyl -1,2-dihydropyrazol-3-one, 4,5-diamino-1,2-diethyl-1,2-dihydropyrazol-3-one, 4,5-diamino-1,2-bis(2 -hydroxyethyl)-1,2-dihydropyrazol-3-one, 2-amino-3-(2-hydroxyethyl)amino-6,7-dihydro-1H,5H-pyrazolo[1,2-a]pyrazole -1-one, 2-amino-3-dimethylamino-6,7-dihydro-1H,5H-pyrazolo[1,2-a]pyrazol-1-one, 2,3-diamino-5,6,7 ,8-tetrahydro-1H,6H-pyridazino[1,2-a]pyrazol-1-one, 4-amino-1,2-diethyl-5-(pyrrolidin-1-yl)-1,2-dihydropyrazole -3-one, 4-amino-5-(3-dimethyl aminopyrrolidin-1-yl)-1,2-diethyl-1,2-dihydropyrazol-3-one or 2,3-diamino-6-hydroxy-6,7-dihydro-1H,5H-pyrazolo[1 ,2-a]pyrazol-1-one.

[0040] Use will preferably be made from 2,3-diamino-6,7-dihydro-1H,5H-pyrazolo[1,2-a]pyrazol-1-one and/or one of its salts.

[0041] Heterocyclic bases that will preferably be used include 4,5-diamino-1-(β-hydroxyethyl)pyrazole and/or 2,3-diamino-6,7-dihydro-1H,5H-pyrazolo[1, 2-a]pyrazol-1-one and/or a salt thereof.

[0042] Oxidation dyes may also comprise one or more couplers, which may be selected from those conventionally used for dyeing keratin fibers.

[0043] Among these couplers, mention can be made especially of meta-phenylenediamines, meta-aminophenols, meta-diphenols, naphthalene-based couplers, heterocyclic couplers, and also their addition salts, and mixtures thereof.

[0044] Examples that may be mentioned include 1,3-dihydroxybenzene, 1,3-dihydroxy-2-methylbenzene, 4-chloro-1,3-dihydroxybenzene, 2,4-diamino-1-(β- hydroxyethyloxy)benzene, 2-amino-4-(β-hydroxyethylamino)-1-methoxybenzene, 1,3-diaminobenzene, 1,3-bis(2,4-diaminophenoxy)propane, 3-ureidoaniline, 3-ureido-1- dimethylaminobenzene, sesamol, 1-β-hydroxyethylamino-3,4-methylenedioxybenzene, α-naphthol, 2-methyl-1-naphthol, 6-hydroxyindole, 4-hydroxyindole, 4-hydroxy-N-methylindole, 2-amino-3- hydroxypyridine, 6-hydroxybenzomorpholine, 3,5-diamino-2,6-dimethoxypyridine, 1-N-(β-hydroxyethyl)amino-3,4-methylenedioxybenzene, 2,6-bis(β-hydroxyethylamino)toluene, 6-hydroxyindoline , 2,6-dihydroxy-4-methylpyridine, 1-H-3-methylpyrazol-5-one, 1-phenyl-3-methylpyrazol-5-one, 2,6-dimethylpyrazolo[1,5-b]-1, 2,4-triazole, 2,6-dimethyl[3,2-c]-1,2,4-triazole and 6-methylpyrazolo[1,5-a]benzimidazole, their addition salts with an acid, and their mixtures.

[0045] In general, addition salts of oxidation bases and couplers that can be used within the context of the invention are especially selected from addition salts with an acid such as hydrochlorides, hydrobromides, sulfates, citrates, succinates, tartrates, lactates, tosylates, benzenesulfonates, phosphates and acetates.

[0046] The oxidation bases may advantageously represent from 0.0001% to 10% by weight relative to the total weight of the composition, preferably from 0.005% to 5% by weight and better still from 0.1% to 5% by weight .

[0047] Couplers, if they are present, may advantageously represent from 0.0001% to 10% by weight with respect to the total weight of the composition, and preferably from 0.005% to 5% by weight.

[0048] The composition of the invention further comprises one or more cationic polymers.

[0049] The term "cationic polymer" is intended to mean any polymer that comprises cationic groups and/or groups that can be ionized into cationic groups. Preferably, the cationic polymer is hydrophilic or amphiphilic. Preferred cationic polymers are selected from those which contain units comprising primary, secondary, tertiary and/or quaternary amine groups which may be part of the main polymer chain or may be generated by a side substituent directly attached thereto.

[0050] Among cationic polymers, mention can be made more particularly of:

[0051] (1) homopolymers or copolymers derived from acrylic or methacrylic esters or amides and comprising at least one of the units of the following formulas:

[0052] in which: - R3, which can be identical or different, means a hydrogen atom or a CH3 group; - A, which can be identical or different, represents a linear or branched divalent alkyl group of 1 to 6 carbon atoms, preferably 2 or 3 carbon atoms, or a hydroxyalkyl group of 1 to 4 carbon atoms; - R4, R5 and R6, which may be identical or different, represent an alkyl group containing from 1 to 18 carbon atoms or a benzyl group, and preferably an alkyl group containing from 1 to 6 carbon atoms; - R1 and R2, which may be identical or different, represent a hydrogen atom or an alkyl group containing from 1 to 6 carbon atoms, and preferably methyl or ethyl; - X means an anion derived from an inorganic or organic acid such as a methosulfate anion or a halide such as chloride or bromide.

[0053] Family (1) copolymers may also contain one or more units derived from comonomers that can be selected from the family of acrylamides, methacrylamides, diacetone acrylamides, acrylamides and methacrylamides substituted on nitrogen with C1-C4 alkyl, acrylic or methacrylic acids or their esters, vinyl lactams such as vinylpyrrolidone or vinylcaprolactam and vinyl esters. Among these copolymers of the family (1), mention can be made: - copolymers of acrylamide and of dimethylaminoethyl methacrylate quaternized with dimethyl sulphate or with a dimethyl halide, such as that sold under the name Hercofloc by the company Hercules, - copolymers of acrylamide and methacryloyloxyethyltrimethylammonium chloride, such as those sold under the name Bina Quat P 100 by the company Ciba Geigy, - the copolymer of acrylamide and methacryloyloxyethyltrimethylammonium methosulfate, such as the product sold under the name Reten by the company Hercules, - copolymers of quaternized or non-quaternized vinylpyrrolidone/acrylate or dialkylaminoalkyl methacrylate, such as the products sold under the name Gafquat by the ISP company, for example, Gafquat 734 or Gafquat 755, or alternatively the products known as Copolymer 845, 958 and 937. These polymers are described in detail in French patents 2 077 143 and 2 393 573, - terpolymer s of dimethylaminoethyl methacrylate/vinylcaprolactam/vinylpyrrolidone, such as the product marketed under the name Gaffix VC 713 by the ISP company, - vinylpyrrolidone/methacrylamidopropyldimethylamine copolymers, such as those sold under the name Styleze CC 10 by ISP, - vinylpyrrolidone copolymers / dimethylaminopropyl- methacrylamide quaternized such as the product sold under the name Gafquat HS 100 by the ISP company, - preferably crosslinked polymers of methacryloyloxy(C1-C4) alkyl tri(C1-C4) alkylammonium salts, such as polymers obtained by the homopolymerization of dimethylaminoethyl methacrylate quaternized with methyl chloride, or by the copolymerization of acrylamide with dimethylaminoethyl methacrylate quaternized with methyl chloride, the homo- or copolymerization being followed by cross-linking with an olefinically unsaturated compound, in particular methylenebisacrylamide. A cross-linked acrylamide/methacryloyloxyethyltrimethylammonium chloride copolymer (20/80 by weight) in the form of a dispersion comprising 50% by weight of said copolymer in mineral oil can more particularly be used. This dispersion is sold under the name Salcare® SC 92 by the company Ciba. A cross-linked methacryloyloxyethyltrimethylammonium chloride homopolymer comprising about 50% by weight of the homopolymer in mineral oil or a liquid ester can also be used. These dispersions are marketed under the names Salcare® SC 95 and Salcare® SC 96 by the company Ciba.

[0054] (2) Cationic polysaccharides, in particular cationic celluloses and cationic galactomannan gums. Among cationic polysaccharides, one can more particularly mention cellulose ether derivatives comprising quaternary ammonium groups, cationic cellulose copolymers or cellulose derivatives grafted with a water-soluble quaternary ammonium monomer and cationic galactomannan gums.

[0055] Cellulose ether derivatives comprising quaternary ammonium groups are described in particular in patent FR 1 492 597 and mention may be made of polymers sold under the name Ucare Polymer JR (JR 400 LT, JR 125 and JR 30M) or LR (LR 400 Or LR 30M) by the company Amerchol. These polymers are also defined in the CTFA dictionary as hydroxyethylcellulose quaternary ammoniums that have reacted with an epoxide substituted with a trimethylammonium group.

[0056] Cationic cellulose copolymers or cellulose derivatives grafted with a water-soluble quaternary ammonium monomer are described in particular in US patent 4 131 576, and mention may be made of hydroxyalkyl celluloses, for example hydroxymethyl-, hydroxyethyl- or hydroxypropylcelluloses grafted, in particular, with a salt of methacryloylethyltrimethylammonium, methacrylamidopropyltrimethylammonium, dimethyldiallylammonium or hydroxypropyltrialkylammonium, for example 2-hydroxypropyl trimethylammonium chloride. Commercial products corresponding to this definition are more particularly those marketed under the names Celquat L 200 and Celquat H 100 by the company National Starch, or hydroxyethyl cellulose-2-hydroxypropyl trimethyl ammonium chloride ether (INCI name: Polyquaternium-10), such as the product marketed under the name Polyquta 400KC by the company KCI.

[0057] Cationic galactomannan gums are more particularly described in US patents 3 589 578 and 4 031 307 and mention may be made of guar gums comprising cationic trialkylammonium groups. Use is made, for example, of guar gums modified with a 2,3-epoxypropyltrimethylammonium salt (eg a chloride). Such products are, in particular, sold under the names Jaguar C13 S, Jaguar C 15, Jaguar C 17 and Jaguar C162 by the company Rhodia.

[0058] (3) Polymers composed of piperazinyl units and divalent alkylene or hydroxyalkylene groups containing straight or branched chains, optionally interrupted by oxygen, sulfur or nitrogen atoms or by aromatic or heterocyclic rings, and also the products of oxidation and/ or quaternization of these polymers.

[0059] (4) Water-soluble polyaminoamides prepared in particular by polycondensation of an acidic compound with a polyamine; these polyaminoamides may be cross-linked by an epihalohydrin, a diepoxide, a dianhydride, an unsaturated dianhydride, a bis-unsaturated derivative, a bis-halohydrin, a bisazetidinium, a bishaloacyldiamine or an alkyl bishalide or alternatively by a oligomer resulting from the reaction of a bifunctional compound reactive towards a bishalohydrin, a bisazetidinium, a bishaloacyldiamine, an alkyl bishalide, an epihalohydrin, a diepoxide or a bis-unsaturated derivative; the crosslinking agent being used in proportions ranging from 0.025 to 0.35 mol per amine group of the polyaminoamide; these polyaminoamides can be alkylated or, if they comprise one or more tertiary amine functions, quaternized.

[0060] (5) Polyaminoamide derivatives resulting from the condensation of polyalkylene polyamines with polycarboxylic acids followed by alkylation with difunctional agents. Mention can be made, for example, of adipic acid/dialkylaminohydroxyalkyldialkenyltriamine polymers in which the alkyl group comprises from 1 to 4 carbon atoms and preferably indicates methyl, ethyl or propyl. Among these derivatives, mention can be made more particularly of the adipic acid/dimethylaminohydroxypropyl/diethylenetriamine polymers marketed under the name Cartaretine F, F4 or F8 by the Sandoz company.

[0061] (6) Polymers obtained by reacting a polyalkylenepolyamine comprising two primary amine groups and at least one secondary amine group with a dicarboxylic acid selected from diglycolic acid and saturated aliphatic dicarboxylic acids having from 3 to 8 carbon atoms; the molar ratio of polyalkylenepolyamine to dicarboxylic acid preferably being between 0.8:1 and 1.4:1; the resulting polyaminoamide being reacted with epichlorohydrin in a molar ratio of epichlorohydrin to secondary amine group of the polyaminoamide preferably between 0.5:1 and 1.8:1. Polymers of this type are marketed in particular under the name Hercosett 57 by the company Hercules Inc. or alternatively under the name PD 170 or Delsette 101 by the company Hercules in the case of the adipic acid/epoxypropyl/diethylenetriamine copolymer.

[0062] (7) Cyclopolymers of alkyldiallylamine or dialkyldiallylammonium, such as homopolymers or copolymers comprising, as the main constituent of the chain, units corresponding to the formula (PI) or (PII):

[0063] where: - k and t are equal to 0 or 1, the sum k + t being equal to 1; - R12 means a hydrogen atom or a methyl group; - R10 and R11, independently of one another, mean an alkyl group containing from 1 to 6 carbon atoms, a hydroxyalkyl group in which the alkyl group contains from 1 to 5 carbon atoms, a C1-C4 amidoalkyl group ; or alternatively R10 and R11 may indicate, together with the nitrogen atom to which they are attached, heterocyclic groups such as piperidyl or morpholinyl; R10 and R11, independently of one another, preferably denote an alkyl group containing from 1 to 4 carbon atoms; - Y- is an anion such as bromide, chloride, acetate, borate, citrate, tartrate, bisulfate, bisulfite, sulfate or phosphate.

[0064] Mention can be made more particularly of the homopolymer of dimethyldiallylammonium salt (for example, chloride), for example, marketed under the name Merquat 100 by the company Nalco (and its low weight medium molar mass counterparts) and the copolymers of diallyldimethylammonium (eg chloride) and acrylamide salts, marketed in particular under the name Merquat 550 or Merquat 7SPR.

[0065] (8) quaternary diammonium polymers comprising repeating units of formula:

[0066] in which: - R13, R14, R15 and R16, which may be identical or different, represent aliphatic, alicyclic or arylaliphatic groups comprising from 1 to 20 carbon atoms or C1-4 aliphatic hydroxyalkyl groups, or else R13, R14 , R15 and R16, together or separately, form, with the nitrogen atoms to which they are attached, heterocycles optionally comprising a second heteroatom other than nitrogen, or else R13, R14, R15 and R16 represent a linear or C1-C6 alkyl group branched substituted by a nitrile, ester, acyl, amide or group -CO-O-R17-D or -CO-NH-R17-D, where R17 is an alkylene and D a quaternary ammonium group; - A1 and B1 represent divalent polymethylene groups comprising from 2 to 20 carbon atoms which may be linear or branched, and saturated or unsaturated, and which may contain, attached or inserted into the main chain, one or more aromatic rings, or one or plus oxygen or sulfur atoms or sulfoxide, sulfone, disulfide, amino, alkylamino, hydroxyl, quaternary ammonium, ureido, amide or ester groups, and -X- means an anion derived from an inorganic or organic acid; it being understood that A1, R13 and R15 can form, with the two nitrogen atoms to which they are attached, a piperazine ring.

[0067] Furthermore, if A1 means a linear or branched saturated or unsaturated alkylene or hydroxyalkylene group, B1 can also mean a group (CH2)n-CO-D-OC-(CH2)n- where D means: a) a glycol residue of the formula -OZO-, in which Z means a group based on linear or branched hydrocarbon, or a group corresponding to one of the following formulas: -(CH2-CH2-O)x-CH2-CH2- and -[CH2-CH(CH3)-O]y-CH2-CH(CH3)-, where x and y stand for an integer from 1 to 4, representing a defined and unique degree of polymerization, or any number from 1 to 4 representing a degree polymerization medium; b) a bis-secondary diamine residue, such as a piperazine derivative; c) a bis-primary diamine residue of the formula: -NH-Y-NH-, wherein Y means a straight or branched hydrocarbon-based group, or else the divalent group -CH2-CH2-SS-CH2-CH2- ; d) a ureylene group of formula: -NH-CO-NH-.

[0068] Preferably, X- is an anion such as chloride or bromide. These polymers have a number average molar mass (Mn) generally between 1000 and 100,000.

[0069] Mention can be made more particularly of polymers that are composed of repeating units corresponding to the formula:

[0070] wherein R1, R2, R3 and R4, which may be identical or different, mean an alkyl or hydroxyalkyl group having approximately 1 to 4 carbon atoms, n and p are integers ranging from approximately 2 to 20 and X - is an anion derived from an inorganic or organic acid.

[0071] A compound of formula (PIV) which is particularly preferred is one for which R1, R2, R3 and R4 represent a methyl group and en = 3, p = 6 and X = Cl, which is known as hexadimethrine chloride according to the INCI nomenclature (CTFA).

[0072] (9) Polyquaternary ammonium polymers comprising units of formula (PV):

[0073] in which: - R18, R19, R20 and R21, which may be identical or different, represent a hydrogen atom or a methyl, ethyl, propyl, β-hydroxyethyl, β-hydroxypropyl or -CH2CH2(OCH2CH2) group pOH, where p equals 0 or an integer between 1 and 6, with the proviso that R18, R19, R20 and R21 do not simultaneously represent a hydrogen atom, - res, which may be identical or different, are numbers integers between 1 and 6, - q is equal to 0 or an integer between 1 and 34, - X- means an anion such as a halide, - A means a dihalide radical or preferably represents -CH 2 - CH2-O-CH2-CH2-.

[0074] Examples that may be mentioned include the products Mirapol® A 15, Mirapol® AD1, Mirapol® AZ1 and Mirapol® 175 marketed by the company Miranol.

[0075] (10) Quaternary polymers of vinylpyrrolidone and vinylimidazole, for example, the products marketed under the names Luviquat® FC 905, FC 550 and FC 370 by the company BASF.

[0076] (11) Polyamines such as Polyquart® H marketed by Cognis, referred to under the name polyethylene glycol tallow polyamine (15) in the CTFA dictionary.

(b) opcionalmente uma ou mais unidades correspondentes à fórmula (B) abaixo:

[0077] (12) Polymers comprising in its structure: (a) one or more units corresponding to formula (A) below:

(b) optionally one or more units corresponding to formula (B) below:

[0078] In other words, these polymers can be selected in particular from homopolymers or copolymers comprising one or more vinylamine-derived units and optionally one or more vinylformamide-derived units.

[0079] Preferably, these cationic polymers are selected from polymers comprising, in their structure, from 5 mol% to 100 mol% of units corresponding to the formula (A) and from 0 to 95 mol% of units corresponding to the formula ( B), preferably from 10 mol% to 100 mol% of units corresponding to formula (A) and from 0 to 90 mol% of units corresponding to formula (B).

[0080] These polymers can be obtained, for example, through the partial hydrolysis of polyvinylformamide. This hydrolysis can be carried out in an acidic or a basic medium.

[0081] The weighted average molecular weight of said polymer, measured by light scattering, can range from 1000 to 3,000,000 g/mol, preferably from 10,000 to 1,000,000 and more particularly from 100,000 to 500,000 g/mol.

[0082] The cationic charge density of these polymers can range from 2 to 20 meq/g, preferably from 2.5 to 15 meq/g and more particularly from 3.5 to 10 meq/g.

[0083] Polymers comprising units of formula (A) and optionally units of formula (B) are sold, in particular, under the name Lupamin by the company BASF, for example, without limitation, products sold under the names Lupamin 9095, Lupamin 5095, Lupamin 1095, Lupamin 9030 (or Luviquat 9030) and Lupamin 9010.

[0084] Other cationic polymers that can be used in the context of the invention are cationic proteins or cationic protein hydrolysates, polyalkyleneimines, in particular polyethyleneimines, polymers comprising vinylpyridine or vinylpyridinium units, polyamine and epichlorohydrin condensates, quaternary polyureylenes and chitin derivatives .

[0085] Preferably, the cationic polymers are selected from those of the family (2) mentioned above. Particularly preferred cationic polymers for use in the compositions of the present invention are quaternized hydroxyalkylcelluloses such as quaternized hydroxyethylcelluloses. The most particularly preferred polymers are those known under the INCI name of Polyquaternium-10.

[0086] The composition of the invention preferably contains from 0.1 to 5% by weight of cationic polymers, more preferably from 0.2 to 2.5% by weight, relative to the total weight of the composition.

[0087] The composition of the invention further comprises one or more amphoteric or zwitterionic surfactants.

[0088] Amphoteric or zwitterionic surfactants, which are preferably silicone-free, can be especially derived from aliphatic secondary or tertiary amines, optionally quaternized, wherein the derivatives of the aliphatic group are a linear or branched chain comprising from 8 to 22 atoms of carbon, said amine derivatives containing at least one anionic group, for example a carboxylate, sulfonate, sulfate, phosphate or phosphonate group.

[0089] Mention can be made in particular of alkyl betaines (C8-C20), alkylsulfobetaines (C8-C20), alkyl starches (C8-C20) alkyl betaines (C3-C8) and alkyl starches (C8-C20) alkylsulfobetaines (C6-C8).

[0090] Among the optionally quaternized secondary or tertiary aliphatic amine derivatives that may be used, as defined above, there may also be mentioned compounds having the respective structures (V) and (VI) below:

[0091] in which formula: - Ra represents a group of C10-C30 alkyl or alkenyl derived from an acid RaCOOH preferably present in the hydrolyzed coconut oil, or a group of heptyl, nonyl or undecyl; - Rb represents a beta-hydroxyethyl group; and - Rc represents a carboxymethyl group; - M+ represents a cationic counterion derivative of an alkali metal or alkaline earth metal such as sodium, an ammonium ion or an ion derived from an organic amine, and - X- represents an organic or mineral anionic counterion such as that selected from halides, acetates, phosphates, nitrates, (C1-C4) alkyl sulfates, (C1-C4) alkylsulfonates or (C1-C4) alkylarylsulfonates, in particular methyl sulfate and ethyl sulfate; or alternatively M+ and X-are absent;

[0092] in whose formula: - B represents the group -CH2CH2OX'; - B' represents the group -(CH2)zY', with z = 1 or 2; - X' represents the group -CH2COOH, -CH2-COOZ', -CH2CH2COOH, -CH2CH2-COOZ', or a hydrogen atom; - Y' represents the group -COOH, -COOZ', -CH2CH(OH)SO3H or the group -CH2CH(OH)SO3Z'; - Z' represents a cationic counterion derived from an alkali metal or alkaline earth metal, such as sodium, an ammonium ion or an ion derived from an organic amine; - Ra' represents a C10-C30 alkyl or alkenyl group of an acid Ra'-COOH which is preferably present in coconut oil or in hydrolyzed linseed oil, or an alkyl group, especially a C17 group, and its isoform. , or an unsaturated C17 group.

[0093] These compounds are classified in the CTFA dictionary, 5th edition, 1993, under the name disodium cocoamphodiacetate, disodium lauroamphodiacetate, disodium caprylanphodiacetate, disodium capryloamphodiacetate, disodium cocoamphodipropionate, disodium disodium dispropion dipropionate, disodium disodium lauroamphodipropionate, disodium capryloamphodiacetate, disodium capryloamphodiacetate. disodium, lauroamphodipropionic acid and cocoamphodipropionic acid.

[0094] By way of example, mention can be made of the cocoamphodiacetate marketed by the company Rhodia under the trade name Miranol® C2M Concentrate.

[0095] Use can also be made of the compounds of formula (VII):

[0096] in which formula: - Y'' represents the group -COOH, -COOZ', - CH2CH(OH)SO3H or the group -CH2CH(OH)SO3Z'; - Rd and Re represent, independently of one another, a C1-C4 alkyl or hydroxyalkyl radical; - Z'' represents a cationic counterion derived from an alkali metal or alkaline earth metal, such as sodium, an ammonium ion or an ion derived from an organic amine; - Ra'' represents a C10-C30 alkyl or alkenyl group of an acid Ra''-COOH which is preferably present in coconut oil or hydrolyzed linseed oil; - n and n' stand for, independently of each other, an integer ranging from 1 to 3.

[0097] Among the compounds of formula (VII), one can mention the compound classified in the CTFA dictionary under the name of sodium diethylaminopropyl cocoaspartamide and marketed by the company Chimex under the name Chimexane HB.

[0098] These compounds can be used alone or as mixtures.

[0099] Among the amphoteric or zwitterionic surfactants mentioned above, the use is preferably made of (C8-C20) alkylbetaines, (C8-C20) alkylsulfobetaines, (C8-C20) alkylamido (C3C8) alkylbetaines and (C8-C20) alkylamido (C6-C8) alkylsulfobetaines, more preferably from (C8-C20) alkylbetaines and even more preferably from cocoylbetaines.

[00100] The composition of the invention preferably comprises said amphoteric or zwitterionic surfactants in an amount of 0.01 to 15% by weight, more preferably from 0.1 to 10% by weight, and even more preferably from 1 to 5% by weight weight, based on the total weight of the composition.

[00101] The composition of the invention further comprises one or more nonionic surfactants selected from alkanolamides of C6-C30 fatty acids.

[00102] Such surfactants can be selected from mono-alkanolamides and di-alkanolamides of C8-C30 fatty acids, and preferably from mono-alkanolamides and di-alkanolamides of C8-C18 fatty acids.

[00103] Alkanol groups can have 1 to 10 carbon atoms, and preferably 2 to 5 carbon atoms.

[00104] Mention can be made, for example, of cocamide monoethanolamine, cocamide diethanolamine, cocamide mono-isopropanolamine.

[00105] According to a particularly preferred embodiment, said non-ionic surfactant is cocamide mono-isopropanolamine.

[00106] The composition of the invention preferably comprises said nonionic surfactants selected from C6-C30 fatty acid alkanolamides in an amount ranging from 0.05 to 5% by weight, more preferably from 0.1 to 1% by weight, in in relation to the total weight of the composition.

[00107] The composition according to the invention further comprises one or more anionic surfactants.

[00108] The term "anionic surfactant" means a surfactant which comprises, like ionic or ionizable groups, only anionic groups. These anionic groups are preferably selected from the following groups: - COOH, -COO-, -SO3H, -SO3-, -OSO3H, -OSO3-, -PO2H2, -PO2H-, -PO22-, -P(OH)2, =P(O)OH, -P(OH)O-, =P(O)O-, =POH, =PO-, the anionic parts comprising a cationic counterion such as an alkali metal, an alkaline earth metal or a ammonium.

[00109] As examples of anionic surfactants that can be used in the composition according to the invention, mention can be made of alkyl sulfates, alkyl ether sulfates, alkyl starch ether sulfates, alkylaryl polyether sulfates, monoglyceride sulfates, alkylsulfonates, alkylamide sulfonates, alkylaryl sulfonates, α-olefin sulfonates, paraffin sulphonates, alkyl sulfosuccinates, alkyl ether sulfosuccinates, alkyl amide sulfosuccinates, alkyl sulfoacetates, acylsarcosinates, acylglutamates, polyalkylsulfosuccinate salts, polyalkylthiosulfosuccinates of monoalkyl ester, acyl lactylates, salts of uronic D-galactosides, salts of carboxylic acids of alkyl ether, carboxylic acid salts of alkylaryl ether, carboxylic acid salts of alkylamido ether, and the corresponding unsalified forms of all these compounds ; the alkyl and acyl groups of all these compounds comprising from 6 to 40 carbon atoms and the aryl group which means a phenyl group.

These compounds can be oxyethylenated and then preferably comprise from 1 to 50 ethylene oxide units.

The salts of C6-C24 alkyl monoesters of polycarboxylic acids can be selected from C6-C24 alkyl polyglycoside citrates, C6-C24 alkyl polyglycoside tartrates and C6C24 alkyl polyglycoside sulfosuccinates.

[00112] When anionic surfactants are in salt form, they can be selected from alkali metal salts such as sodium or potassium salt and preferably the sodium salt, ammonium salts, amine salts and in particular salts of amino alcohol or alkaline earth metal salts such as magnesium salts.

[00113] Examples of amino alcohol salts which may be especially mentioned include salts of monoethanolamine, diethanolamine and triethanolamine, salts of monoisopropanolamine, diisopropanolamine or triisopropanolamine, salts of 2-amino-2-methyl-1-propanol, salts of 2- amino-2-methyl-1,3-propanediol and tris(hydroxymethyl)aminomethane salts.

Alkali metal or alkaline earth metal salts, and in particular sodium or magnesium salts, are preferably used.

[00115] Preferred anionic surfactants are selected from alkyl sulfates (C6-C30), alkyl ether sulfates (C6-C30), alkyl starch ether sulfates (C6-C30), polyether alkylaryl sulfates and monoglyceride sulfates, all these compounds optionally comprising from 1 to 20 ethylene oxide units; and more preferably from alkyl sulfates (C12-C20) and alkyl ether sulfates (C12-C20) comprising from 2 to 20 ethylene oxide units, and even more preferably from 1 to 4 ethylene oxide units, especially in the form alkali metal, ammonium, amino alcohol and alkaline earth metal salts, or a mixture of these compounds. Better still, it is preferable to use a polyoxyethylenized sodium lauryl ether sulfate, such as sodium lauryl ether sulfate containing 2 or 2.2 moles of ethylene oxide.

[00116] The amount of said anionic surfactants in the composition of the invention is at least 1.5% by weight, more preferably at least 3% by weight, relative to the total weight of the composition. This amount preferably ranges from 5 to 30% by weight, more preferably from 5 to 15% by weight, relative to the total weight of the composition.

[00117] The composition of the invention may further contain one or more additional nonionic surfactants other than the above-described alkanolamides of C6-C30 fatty acids.

[00118] Nonionic surfactants that can be used in the compositions are described, for example, in the Handbook of Surfactants by M.R. Porter, published by Blackie & Son (Glasgow and London), 1991, pp. 116-178.

[00119] Examples of nonionic surfactants that may be mentioned include the following nonionic surfactants: - oxyalkylenated alkylphenols (C8-C24); - C8-C40, saturated or unsaturated, linear or branched, oxyalkylenated or glycerolated alcohols, comprising one or two fatty chains; - saturated or unsaturated, linear or branched, oxyalkylenated C8-C30 fatty acid amides; - esters of saturated or unsaturated, linear or branched C8-C30 acids and polyethylene glycols; - esters of C8-C30 saturated or unsaturated, linear or branched acids and sorbitol, preferably oxyethylenated; - sucrose fatty acid esters; - (C8-C30)alkyl(poly)glycosides, (C8-C30)alkenyl(poly)glycosides, which are optionally oxyalkylenated (0 to 10 oxyalkylene units) and comprising from 1 to 15 glucose units, alkyl esters (C8- C30) (poly)glycosides; - oxyethylenated saturated or unsaturated vegetable oils; - condensates of ethylene oxide and/or of propylene oxide, inter alia, alone or as mixtures; - N-(C8-C30)alkylglucamine and N-(C8-C30) acylmethylglucamine derivatives; - aldobionamides; - amine oxides; - oxyethylenated and/or oxypropylenated silicones; - and its mixtures.

[00120] Oxyalkylene units are more particularly oxyethylene or oxypropylene units, or a combination thereof, preferably oxyethylene units.

[00121] The number of moles of ethylene oxide and/or propylene oxide preferably ranges from 1 to 250, more particularly from 2 to 100 and better still from 2 to 50; the number of moles of glycerol varies especially from 1 to 50 and even better from 1 to 10.

[00122] Advantageously, the non-ionic surfactants according to the invention do not comprise any oxypropylene units.

[00123] As examples of glycerolated nonionic surfactants, the use is preferably made of monoglycerolized or polyglycerolized C8-C40 alcohols, comprising from 1 to 50 moles of glycerol and preferably from 1 to 10 moles of glycerol.

[00124] As examples of compounds of this type, mention may be made of lauryl alcohol containing 4 moles of glycerol (INCI name: Polyglyceryl-4 Lauryl Ether), lauryl alcohol containing 1.5 moles of glycerol, oleyl alcohol containing 4 moles of glycerol (INCI name: Polyglyceryl-4 Oleyl Ether), oleyl alcohol containing 2 moles of glycerol (INCI name: Polyglyceryl-2 Oleyl Ether), cetearyl alcohol containing 2 moles of glycerol, cetearyl alcohol containing 6 moles of glycerol, oleyl/cetyl alcohol containing 6 moles of glycerol, and octadecanol containing 6 moles of glycerol.

Among the glycerol alcohols, it is more particularly preferable to use the C8/C10 alcohol containing 1 mol of glycerol, the C10/C12 alcohol containing 1 mol of glycerol and the C12 alcohol containing 1.5 mol of glycerol.

[00126] The additional non-ionic surfactants, when they are present in the composition of the invention, are preferably present in a total amount ranging from 0.01 to 1% by weight, with respect to the total weight of the composition.

[00127] The composition of the invention may further comprise one or more cationic surfactants.

[00128] The term "cationic surfactant" means a surfactant that is positively charged when it is contained in the composition according to the invention. This surfactant can carry one or more positive permanent charges or can contain one or more cationizable functions in the compositions.

[00129] Cationic surfactants are preferably selected from optionally polyoxyalkylenated primary, secondary or tertiary fatty amines, or their salts, and quaternary ammonium salts and their mixtures.

[00130] Fatty amines generally comprise at least one hydrocarbon-based chain C8-C30.

[00131] Among the cationic quaternary ammonium surfactants, those which are preferred are: - tetra-alkylammonium salts, for example, dialkyldimethylammonium or alkyltrimethylammonium salts wherein the alkyl group contains approximately 12 to 22 carbon atoms, in particular beheyltrimethylammonium, distearyldimethylammonium, cetyltrimethylammonium or benzyldimethylstearylammonium salts, or, on the other hand, the palmitylamidopropyltrimethylammonium salt, the stearamidopropyltrimethylammonium salt, the stearamidopropyldimethylcetearylammonium salt, or the stearamidopropyldimethyl(myristyl acetate) salt (commercialized by the name Cerammonium) Van Dyk company. It is particularly preferable to use the chloride salts of these compounds. - imidazoline quaternary ammonium salts, for example, marketed under the name Rewoquat® W 75 by the company Rewo; - di- or triquaternary ammonium salts, eg Finquat CT-P, available from the Finetex company (Quaternium 89), and Finquat CT, available from the Finetex company (Quaternium 75). - quaternary ammonium salts containing at least one ester function, such as diacyloxyethyldimethylammonium, diacyloxyethyl(hydroxyethyl)methylammonium, monoacyloxyethyldi(hydroxyethyl)methylammonium, triacyloxyethylmethylammonium or monoacyloxyethyl(hydroxyethyl)dimethylammonium (in particular methyl chloride or sulfate) salts, and its mixtures. Acyl groups preferably contain from 14 to 18 carbon atoms and are more particularly obtained from a vegetable oil, such as palm oil or sunflower oil. When the compound contains several acyl groups, these groups can be identical or different.

[00132] Such compounds are, for example, sold under the names Dehyquart® by the company Henkel, Stepanquat® by the company Stepan, Noxamium® by the company Ceca or Rewoquat® WE 18 by the company Rewo-Witco.

[00133] The composition according to the invention may contain, for example, a mixture of quaternary ammonium monoester, diester and triester with a majority by weight of diester salts.

[00134] Use can also be made of the ammonium salts containing at least one ester function which are described in patents USA-4 874 554 and US-A-4 137 180.

[00135] Use can be made of behenoylhydroxypropyltrimethylammonium chloride, supplied by Kao under the name Quatarmin BTC 131.

[00136] Preferably, ammonium salts containing at least one ester function contain two ester functions.

[00137] Among the quaternary ammonium salts containing at least one ester function, which can be used, it is preferable to use dipalmitoylethylhydroxyethylmethylammonium salts.

[00138] The composition of the present invention may further contain one or more fatty substances.

[00139] The term "fatty substance" means an organic compound that is insoluble in water at normal temperature (25°C) and atmospheric pressure (760 mmHg) (solubility less than 5% by weight, preferably less than 1 % and even more preferably less than 0.1%). They have in their structure at least one hydrocarbon-based chain comprising at least 6 carbon atoms or a sequence of at least two siloxane groups. Furthermore, fatty substances are generally soluble in organic solvents under the same conditions of temperature and pressure, for example, chloroform, dichloromethane, carbon tetrachloride, ethanol, benzene, toluene, tetrahydrofuran (THF), liquid petrolatum or decamethylcyclopentasiloxane.

[00140] More particularly, fatty substances are selected from C6-C16 hydrocarbons, hydrocarbons containing more than 16 carbon atoms, non-silicone oils of animal origin, vegetable or synthetic oils of the triglyceride type, fluorinated oils, fatty alcohols, fatty acid and/or fatty alcohol esters other than triglycerides and vegetable waxes, silicone-free waxes other than fatty alcohols and silicones, and mixtures thereof.

[00141] According to a preferred embodiment, the composition of the invention contains one or more oils, i.e., one or more fatty substances that are liquid at room temperature (25°C) and atmospheric pressure (760 mmHg, i.e. 1.013 x 105 Pa).

[00142] Preferably, the oils are selected from linear or branched liquid hydrocarbons, of mineral or synthetic origin, containing more than 16 carbon atoms, and especially liquid petrolatum, hydrogenated polyisobutene, alkanes C6-C16; triglyceride oils of vegetable origin; liquid fatty acids and/or fatty alcohol esters; liquid fatty alcohols; and its mixtures.

[00143] Particularly preferred oils are selected from liquid fatty alcohols comprising from 8 to 20 carbon atoms. A more particularly preferred oil is octyldodecanol.

[00144] Fatty substances can be present in an amount ranging from 0.05% to 10% by weight, preferably from 0.1% to 10% by weight, better still from 0.2% to 5% by weight even better from 0.2% to 2% by weight, relative to the total weight of the composition.

[00145] The composition according to the invention advantageously comprises water, in a content greater than or equal to 40% by weight relative to the total weight of the composition.

[00146] The water content in the composition of the invention preferably ranges from 40% to 95% by weight, more preferably from 40% to 80% by weight, relative to the total weight of the composition.

[00147] The composition according to the invention may also comprise one or more water-soluble organic solvents (solubility greater than or equal to 5% in water at 25°C and at atmospheric pressure).

[00148] Examples of water-soluble organic solvents which may be mentioned include linear or branched and preferably saturated monoalcohols or diols comprising from 2 to 10 carbon atoms, such as ethyl alcohol, isopropyl alcohol, hexylene glycol (2-methyl- 2,4-pentanediol), neopentyl glycol and 3-methyl-1,5-pentanediol, butylene glycol, dipropylene glycol and propylene glycol; aromatic alcohols such as phenylethyl alcohol; polyols containing more than two hydroxyl functions, such as glycerol; polyol ethers, for example ethylene glycol monomethyl, monoethyl and monobutyl ether, propylene glycol or ethers thereof, for example propylene glycol monomethyl ether; and also diethylene glycol alkyl ethers, especially C1-C4 alkyl ethers, for example diethylene glycol monoethyl ether or monobutyl ether, alone or as a mixture.

[00149] The water-soluble organic solvents, when they are present, generally represent between 1% and 20% by weight with respect to the total weight of the composition according to the invention, and preferably between 5% and 10% by weight.

The composition according to the invention preferably further comprises one or more alkaline agents.

[00151] Alkali agents can be specially selected from aqueous ammonia, alkali metal carbonates or bicarbonates, organic amines with a pKb at 25°C of less than 12, in particular less than 10 and even more advantageously less than that 6; of the salts of the amines mentioned above with acids such as carbonic acid or hydrochloric acid, it should be noted that it is the pKb corresponding to the most basic function.

Preferably, the amines are selected from alkanolamines, in particular comprising a primary, secondary or tertiary amine function, and one or more linear or branched C1C8 alkyl groups bearing one or more hydroxyl radicals; of oxyethylenated and/or oxypropylenated ethylenediamines, and of amino acids and compounds having the following formula:

[00153] wherein W is a C1-C6 alkylene residue optionally substituted with a hydroxyl group or a C1-C6 alkyl radical; RX, Ry, Rz and Rt, which can be identical or different, represent a hydrogen atom or a C1-C6 alkyl, hydroXiC1-C6 alkyl or C1-C6 aminoalkyl radical.

[00154] According to an embodiment of the invention, the composition according to the invention comprises aqueous ammonia and/or at least one alkanolamine and/or at least one basic amino acid, more advantageously aqueous ammonia and/or at least one alkanolamine, such as as monoethanolamine, or mixtures thereof.

[00155] Advantageously, the content of alkaline agents ranges from 0.01% to 30% by weight, preferably from 0.1% to 20% by weight and better still from 1% to 10% by weight relative to the total weight of makeup. It should be noted that this content is expressed as NH3 when the alkaline agent is aqueous ammonia.

[00156] The pH of the composition of the invention is preferably greater than or equal to 8, preferably ranges from 8 to 12, and more preferably from 9 to 11.

[00157] It can be adjusted by adding acidifying agents, such as hydrochloric acid, (ortho) phosphoric acid, sulfuric acid, boric acid, and also carboxylic acids, for example, acetic acid, lactic acid or citric acid or sulfonic acids. Alkaline agents such as those mentioned above can also be used.

[00158] The composition according to the invention may also comprise one or more direct dyes.

[00159] Examples of particularly suitable direct dyes which may be mentioned include nitrobenzene dyes; direct azo dyes; direct azomethine tinctures; direct methine dyes; direct azacarbocyanine tinctures, for example tetraazacarbocyanines (tetraazapentamethins); quinone and, in particular, direct tinctures of anthraquinone, naphthoquinone or benzoquinone; direct azine dyes; direct xanthene dyes; direct triarylmethane dyes; direct indoamine dyes; direct indigoid dyes; phthalocyanine direct dyes, porphyrin direct dyes and natural direct dyes, alone or as mixtures. In particular, mention can be made of direct dyes among: azo; methine; carbonyl; azine; nitro (hetero)aryl; tri(hetero)arylmethane; porphyrin; phthalocyanine and natural direct dyes, alone or as mixtures.

[00160] Direct dyes may represent from 0.0001% to 10% by weight and preferably from 0.005% to 5% by weight relative to the total weight of the composition.

[00161] The composition according to the invention may also comprise one or more cosmetic adjuvants.

[00162] For example, the composition may comprise one or more additives that are well known in the art, such as anionic, nonionic or amphoteric polymers or mixtures thereof, agents for preventing hair loss, vitamins and provitamins including panthenol, protectants sunscreens, mineral or organic pigments, sequestrants, plasticizers, solubilizers, acidifying agents, mineral or organic thickeners, especially polymeric thickeners, opacifiers, antioxidants, hydroxy acids, pearlescent agents, fragrances and preserving agents.

[00163] Needless to say, a person skilled in the art will take care to select this or these optional additional compounds such that the advantageous properties intrinsically associated with the invention are not substantially adversely affected by the anticipated additions.

[00164] The above adjuvants can generally be present in an amount, for each of them, between 0 and 20% by weight with respect to the total weight of the composition.

[00165] According to an embodiment of the invention, the composition further comprises one or more oxidizing agents. The composition is then said to be "ready to use" in the sense that it does not require the use of a separate oxidizing composition.

[00166] Advantageously, the oxidizing agents used in the context of the invention are chemical oxidizing agents different from atmospheric oxygen.

[00167] Oxidizing agents are preferably selected from the group formed by hydrogen peroxide, urea peroxide, alkali metal bromates or ferricyanides, peroxygenated salts, for example, persulfates, perborates, peracids and their precursors and alkali metal or alkaline earth metal percarbonates ,and more particularly hydrogen peroxide.

[00168] Oxidizing agents may represent from 0.01% to 20%, preferably from 0.1% to 10% and better still from 2% to 8% by weight, relative to the total weight of the composition.

The compositions according to the invention may be in the form of liquids, gels or fluids or thick creams.

[00170] They advantageously have a viscosity, measured at room temperature and atmospheric pressure, ranging from 10 to 100 UD, preferably from 20 to 80 UD, and even more preferably from 50 to 70 UD, when using the rotor 3 under 200 rpm for 30 seconds. The viscosity of the composition of the present invention is measured using a ProRheo R180 machine from Prorheo company, Roter 3 is used adapted with the viscosity of the composition to be tested (the rotor is selected to have a measurement between 10 and 100 for the UD deviation unit ), the measurement being taken after 30 seconds of turning the rotor inside the composition, with a shear rate of 200s-1. UD values can then be converted to Poises (1 Poise = 0.1 Pa.s) with a correspondence table.

[00171] The invention also relates to the use of the composition as described above for dyeing keratin fibres, in particular hair.

[00172] Another object of the invention is a process for dyeing human keratin fibers, in particular hair, using the composition as described above.

[00173] According to a first preferred embodiment of the invention, the composition is "ready to use", that is, it already contains at least one oxidizing agent.

[00174] In this case, the dyeing process of the invention consists of applying the composition "ready to use" on the keratin fibers.

[00175] According to a second preferred embodiment, the dyeing process of the invention consists in applying the composition as described above on the keratin fibers, said composition being applied with a separate oxidizing composition.

[00176] The oxidizing composition that is used in this embodiment of the process of the invention comprises one or more oxidizing agents.

[00177] The oxidizing agents of the oxidizing composition are as defined above, that is, they are preferably selected from the group formed by hydrogen peroxide, urea peroxide, alkali metal bromates or ferricyanides, peroxygenated salts, for example, persulfates, perborates , peracids and their precursors, and alkali metal or alkaline earth metal percarbonates, and more particularly hydrogen peroxide.

[00178] The oxidizing agents may represent from 0.01% to 20%, preferably from 0.1% to 10% and even better from 2% to 8% by weight, relative to the total weight of the oxidizing composition.

[00179] In a variant of the second embodiment above, the composition according to the invention is mixed at the time of use with the oxidizing composition as described above.

[00180] More particularly, by "mixed" is meant the action of placing the composition of the present invention in a container or palm, together with the oxidizing composition as described above, with or without stirring.

[00181] According to a preferred variant of the second embodiment, the composition of the present invention is placed in a container or palm together with the oxidizing composition as described above, without agitation.

[00182] In fact, due to the excellent foaming properties of the composition of the invention, it is particularly advantageous and convenient to apply on the keratin fibers the composition of the invention and an oxidizing composition without the need to shake them in a container or palm , but apply them directly to the hair and allow the mixture thus formed on the hair to foam, for example, by massaging with your fingers.

Regardless of the process used and the number of compositions used, the compositions described above, optionally mixed in advance, are applied to wet or dry keratin fibers.

[00184] The compositions are generally left in place on the fibers for a time generally ranging from 1 minute to 1 hour and preferably 5 minutes to 30 minutes.

[00185] The temperature during the process is conventionally between 20 and 80°C and preferably between 20 and 60°C. After the treatment, the human keratin fibers are advantageously rinsed with water. They can be additionally washed with a shampoo, followed by rinsing with water, before being dried or allowed to dry.

[00186] The process can be repeated several times in order to obtain the desired coloration.

[00187] Another object of the invention relates to a multi-compartment device, or a kit for dyeing keratin fibers, comprising at least two compartments: - a first compartment containing a dye composition as described above; and - a second compartment containing an oxidizing composition as described above.

[00188] According to an embodiment of the invention, the kit also comprises an additional compartment containing an additional composition comprising one or more treatment agents.

[00189] The kit compositions are packed in separate compartments, which may optionally be accompanied by suitable identical or different means of application, such as fine brushes, coarse brushes or sponges.

[00190] The above-mentioned kit can also be equipped with means that allow the release in the hair of the desired mixture, such as, for example, the device described in patent FR 2 586 913.

[00191] The following examples are provided only as illustrations of the present invention.

EXAMPLES: Example 1

[00192] The dyeing compositions according to this document were prepared from the ingredients indicated in the table below (in which the contents are indicated in grams of active material in relation to the total weight of the composition):

[00193] Composition C4 corresponds to the invention, while compositions C1 to C3 correspond to comparative compositions.

[00194] The above compositions were tested for the following properties:

[00195] Storage stability of the composition: storage stability was performed by leaving compositions C1 to C4 at 4°C, room temperature (25°C) and 45°C for 2 months. Then, C1 to C4 were left at 37°C for 6 months to assess long term stabilities.

[00196] Composition viscosity: The viscosities of compositions C1 to C4 were measured at 25°C, using a ProRheo R180 machine from the company Prorheo, the Roter 3 was used adapted to the viscosity of the product to be tested (the rotor is selected to have a measurement between 10 and 100 for the deviation of the UD unit), the measurement being taken after 30 seconds of rotating the rotor within the composition, with a shear rate of 200s-1. UD values can then be converted to Poises (1 Poise = 0.1 Pa.s) with a correspondence table.

[00197] Ease of application on keratin fibers: the ease of application on hair of compositions C1 to C4 was measured by 3 hair combers using compositions C1 to C4 to dye the hair. 30 g of compositions C1 to C4 were poured into the palm of the hair dressers, respectively, together with the same amount of an oxidizer containing 6% hydrogen peroxide. Without mixing, the hair combers applied the products (compositions C1 to C4 mixed with oxidizers) immediately onto the medium length hair, ie the hair length is at the shoulder. The hair was massaged and foam was formed. After 15 minutes, the hair with the products mentioned above was rinsed with water.

[00198] For each property, a score was assigned to each composition on a scale ranging from 1 to 5 as follows 1: very bad 2: not good 3: acceptable 4: good 5: perfect

[00199] The results are shown in the table below:

[00200] The above results clearly show that the particular combination of surfactants of the composition of the invention allows to achieve superior performances in terms of working qualities and stability.

Example 2

[00201] A dyeing composition according to the invention was prepared from the ingredients indicated in the table below (in which the contents are indicated in grams of active material in relation to the total weight of the composition):

[00202] 30 g of the composition prepared above was poured into a palm together with 30 g of an oxidizer containing 6% hydrogen peroxide. Without mixing, the compositions were immediately applied to medium length hair, ie the hair length is at the shoulder. The hair was massaged and foam was formed. After 15 minutes the hair was rinsed with water.

[00203] The viscosity of the composition mentioned above is 63.8 UD, using the measurement method disclosed in example 1 above. It allows the composition to remain in the palm without floating. And what's more, when it mixes with the oxidizer in the hair, it allows the mixture and foam to stay on the hair without falling or flying.

[00204] The turbidity of the composition mentioned above is 6 NTU, using the measurement method disclosed in the above description.

[00205] It is a clear and transparent composition, which is very pleasing to consumers.

[00206] The composition mentioned above is stable for 2 months at 4°C, room temperature and 45°C.

[00207] The inventors noted that without waiting for a long period of time, the hair was dyed as expected. Within 15 minutes of staying in the hair, the gray hair was covered perfectly.

Claims (14)

1. Cosmetic composition for the oxidation dyeing of keratin fibers, characterized in that it comprises, in relation to the total weight of the composition: (a) from 0.0001% to 10% by weight of one or more oxidation dyes, (b) from 0.1% to 5% by weight of one or more cationic polymers selected from cationic polysaccharides, (c) from 0.01% to 15% by weight of one or more amphoteric or zwitterionic surfactants, (d) ) from 0.05% to 5% by weight of one or more nonionic surfactants selected from C6C30 fatty acid alkanolamides, and (e) at least 1.5% by weight of one or more anionic surfactants, wherein the Oxidation dyes comprise one or more oxidation bases selected from para-phenylenediamines, bis(phenyl)alkylenediamines, para-aminophenols, ortho-aminophenols, heterocyclic bases, and their addition salts and mixtures thereof, wherein the amphoteric surfactants or zwitterionics are selected from alkylbetaines (C8-C20), alkylsulfobetaines (C8- C20), alkyl starch (C8-C20) alkyl betaines (C3-C8) and alkyl starch (C8C20) alkylsulfobetaines (C6-C8), wherein said anionic surfactants are selected from alkyl sulfates (C6-C30), ether sulfates alkyl (C6-C30), alkyl starch ether sulfates (C6-C30), polyalkylaryl ether sulfates and monoglyceride sulfates, all these compounds optionally comprising from 1 to 20 ethylene oxide units. 2. Composition according to claim 1, characterized in that the oxidation dyes comprise one or more couplers, preferably selected from metaphenylenediamines, meta-aminophenols, metadiphenols, naphthalene-based couplers, heterocyclic couplers, and the their addition salts, and their mixtures. 3. Composition according to claim 1 or 2, characterized in that the cationic polymers are selected from cationic celluloses and cationic galactomannan gums. 4. Composition according to claim 3, characterized in that the cationic polymers are selected from quaternized hydroxyalkylcelluloses, more preferably from quaternized hydroxyethylcelluloses and even more preferably from hydroxyethylcellulose-2-hydroxypropyl trimethyl ammonium chloride ether. 5. Composition according to any one of claims 1 to 4, characterized in that the amphoteric or zwitterionic surfactants are selected from alkylbetaines (C8-C20) and, even more preferably, the composition comprises cocoylbetaine. 6. Composition according to any one of claims 1 to 5, characterized in that said nonionic surfactants are selected from monoalkanolamides and dialkanolamides of C8-C30 fatty acids, preferably from monoalkanolamides and dialkanolamides of C8 fatty acids -C18, and preferably the composition comprises cocamide monoisopropanolamine. 7. Composition according to any one of claims 1 to 6, characterized in that said anionic surfactants are selected from alkyl sulfates (C12-C20) and alkyl ether sulfates (C12-C20) comprising from 2 to 20 ethylene oxide units, and preferably from 1 to 4 ethylene oxide units, especially in the form of alkali metal, ammonium, amino alcohol and alkaline earth metal salts, or a mixture of these compounds. 8. Composition according to any one of claims 1 to 7, characterized in that it comprises said anionic surfactants in an amount of at least 3% by weight, and preferably in an amount ranging from 5 to 30% by weight , more preferably from 5 to 15% by weight, relative to the total weight of the composition. 9. Composition according to any one of claims 1 to 8, characterized in that it further comprises one or more fatty substances, preferably selected from oils, and more preferably selected from liquid fatty alcohols comprising from 8 to 20 carbon atoms, and even more preferably, the composition comprises octyldodecanol. 10. Composition according to any one of claims 1 to 9, characterized in that it further comprises one or more oxidizing agents preferably selected from the group formed by hydrogen peroxide, urea peroxide, alkali metal bromates or ferricyanides, peroxygenated salts, for example, alkali metal or alkaline earth metal persulfates, perborates, peracids and their precursors, and more preferably hydrogen peroxide. 11. Process for dyeing human keratin fibers, in particular hair, characterized in that the composition as defined in claim 10 is applied on said keratin fibers. 12. Process for dyeing human keratin fibers, in particular hair, characterized in that a composition as defined in any one of claims 1 to 10 is applied on said keratin fibers sequentially or simultaneously with a separate oxidizing composition comprising one or more oxidizing agents preferably selected from the group consisting of hydrogen peroxide, urea peroxide, alkali metal bromates or ferricyanides, peroxygenated salts, for example, persulfates, perborates, peracids and their precursors, and alkali metal or metal percarbonates alkaline earth, and more particularly hydrogen peroxide. 13. Process according to claim 12, characterized in that the composition as defined in any one of claims 1 to 10 is applied to the keratin fibers with an oxidizing composition, preferably without stirring. 14. Kit for the oxidation dyeing of keratin fibers, characterized in that it comprises at least two compartments: - a first compartment containing a dye composition as defined in any one of claims 1 to 10; and - a second compartment containing an oxidizing composition as defined in claim 12.